WO2018186294A1 - 電子線発生装置、および、電子線適用装置 - Google Patents
電子線発生装置、および、電子線適用装置 Download PDFInfo
- Publication number
- WO2018186294A1 WO2018186294A1 PCT/JP2018/013640 JP2018013640W WO2018186294A1 WO 2018186294 A1 WO2018186294 A1 WO 2018186294A1 JP 2018013640 W JP2018013640 W JP 2018013640W WO 2018186294 A1 WO2018186294 A1 WO 2018186294A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electron beam
- chamber
- power transmission
- photocathode
- transmission member
- Prior art date
Links
- 238000010894 electron beam technology Methods 0.000 title claims abstract description 166
- 230000005540 biological transmission Effects 0.000 claims abstract description 199
- 230000004913 activation Effects 0.000 claims abstract description 101
- 239000000463 material Substances 0.000 claims description 121
- 238000004381 surface treatment Methods 0.000 claims description 75
- 230000007246 mechanism Effects 0.000 claims description 55
- 230000033001 locomotion Effects 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 230000008602 contraction Effects 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000003574 free electron Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 238000001227 electron beam curing Methods 0.000 claims description 3
- 238000000609 electron-beam lithography Methods 0.000 claims description 3
- 238000001093 holography Methods 0.000 claims description 3
- 238000007689 inspection Methods 0.000 claims description 3
- 238000005136 cathodoluminescence Methods 0.000 claims description 2
- 238000002003 electron diffraction Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 description 28
- 238000000034 method Methods 0.000 description 26
- 239000007789 gas Substances 0.000 description 20
- 230000004048 modification Effects 0.000 description 14
- 238000012986 modification Methods 0.000 description 14
- 238000010586 diagram Methods 0.000 description 11
- 208000028659 discharge Diseases 0.000 description 10
- 239000004065 semiconductor Substances 0.000 description 10
- 230000005291 magnetic effect Effects 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- 230000006870 function Effects 0.000 description 7
- 241000769223 Thenea Species 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 229910052792 caesium Inorganic materials 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000005284 excitation Effects 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 229910052701 rubidium Inorganic materials 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000013307 optical fiber Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 239000012780 transparent material Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003779 heat-resistant material Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052594 sapphire Inorganic materials 0.000 description 2
- 239000010980 sapphire Substances 0.000 description 2
- 229910001285 shape-memory alloy Inorganic materials 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- -1 Cs 2 CrO 4 Chemical class 0.000 description 1
- 229910005540 GaP Inorganic materials 0.000 description 1
- 229910005542 GaSb Inorganic materials 0.000 description 1
- 229910000673 Indium arsenide Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003302 ferromagnetic material Substances 0.000 description 1
- RPQDHPTXJYYUPQ-UHFFFAOYSA-N indium arsenide Chemical compound [In]#[As] RPQDHPTXJYYUPQ-UHFFFAOYSA-N 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910000595 mu-metal Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000006862 quantum yield reaction Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000004043 responsiveness Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 238000004347 surface barrier Methods 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
- H01J1/88—Mounting, supporting, spacing, or insulating of electrodes or of electrode assemblies
- H01J1/94—Mountings for individual electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/02—Details
- H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
- H01J37/147—Arrangements for directing or deflecting the discharge along a desired path
- H01J37/15—External mechanical adjustment of electron or ion optical components
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J3/00—Details of electron-optical or ion-optical arrangements or of ion traps common to two or more basic types of discharge tubes or lamps
- H01J3/02—Electron guns
- H01J3/021—Electron guns using a field emission, photo emission, or secondary emission electron source
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/02—Details
- H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
- H01J37/06—Electron sources; Electron guns
- H01J37/073—Electron guns using field emission, photo emission, or secondary emission electron sources
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/26—Electron or ion microscopes; Electron or ion diffraction tubes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/26—Electron or ion microscopes; Electron or ion diffraction tubes
- H01J37/28—Electron or ion microscopes; Electron or ion diffraction tubes with scanning beams
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/26—Electron or ion microscopes; Electron or ion diffraction tubes
- H01J37/295—Electron or ion diffraction tubes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/30—Electron-beam or ion-beam tubes for localised treatment of objects
- H01J37/305—Electron-beam or ion-beam tubes for localised treatment of objects for casting, melting, evaporating, or etching
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/30—Electron-beam or ion-beam tubes for localised treatment of objects
- H01J37/31—Electron-beam or ion-beam tubes for localised treatment of objects for cutting or drilling
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/30—Electron-beam or ion-beam tubes for localised treatment of objects
- H01J37/315—Electron-beam or ion-beam tubes for localised treatment of objects for welding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/30—Electron-beam or ion-beam tubes for localised treatment of objects
- H01J37/317—Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/30—Electron-beam or ion-beam tubes for localised treatment of objects
- H01J37/317—Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation
- H01J37/3174—Particle-beam lithography, e.g. electron beam lithography
Definitions
- the present invention relates to an electron beam generation apparatus and an electron beam application apparatus, and more particularly to an electron beam generation apparatus and an electron beam application apparatus in which a photocathode holder can move relative to an activation container.
- GaAs-type photocathode electron beam sources have so far been used as spin-polarized electron beam sources with a high degree of polarization, and physical particle and hadron physics experiments (precise measurement of the Weinberg angle).
- a 1 kW infrared free electron laser as a high-intensity electron beam source capable of high current with high repetition and short pulses.
- the GaAs photocathode electron beam source has become a promising candidate for a high-brightness electron beam source capable of large current with low emittance (area occupied by the beam in the phase space) used in the next generation accelerator for radiation source, It is considered as the only practical high-performance spin-polarized electron beam source in the “International Linear Collider Project”, a linear next-generation accelerator future project that approaches the mystery of the birth of the universe.
- GaAs type photocathode electron beam sources are regarded as promising electron beam sources for next-generation electron microscopes because of their high repetition rate, short pulse, high brightness, and high spin polarization.
- a GaAs type photocathode electron beam source has a negative electron affinity (Negative Electron Affinity (hereinafter, “negative electron affinity” may be referred to as “NEA”) surface: a vacuum level lower than the conduction band bottom. Is used).
- NAA Negative Electron Affinity
- FIG. 1 shows the concept of electron beam generation from a GaAs-type photocathode electron beam source. A three-step model of (1) excitation process, (2) diffusion process, and (3) escape process, which will be described next, is described below. (See Non-Patent Document 1).
- Excitation light is incident on the photocathode to excite valence band electrons to the conduction band (excitation process).
- Electrons excited to the conduction band diffuse to the surface (diffusion process).
- the GaAs semiconductor has an electron affinity of about 4 eV (energy difference between the vacuum level and the conduction band bottom), and the following process is required to form the NEA surface state.
- a p-type doped GaAs semiconductor is heated in vacuum to remove and clean surface impurities such as oxides and carbides. As a result, band bending is generated in the surface region, and the vacuum level can be lowered by about half ( ⁇ B) of the band gap of the semiconductor.
- ⁇ B half
- cesium is first vapor-deposited so that a minute photocurrent can be obtained on the crystal surface. Repeat alternately until obtained.
- the NEA surface state can be formed by lowering the remaining vacuum level ( ⁇ D) (see Non-Patent Document 1).
- the NEA surface state means that the energy level of the vacuum level of the photocathode is lower than the energy level of the conduction band bottom by the above process. However, even if the energy level of the vacuum level of the photocathode is higher than the energy level at the bottom of the conduction band, electrons can be emitted from the photocathode into the vacuum. Even after the photocathode is processed to the NEA surface state, if the electron emission is continued, the energy level of the vacuum level of the photocathode returns from a lower level to a higher level than the energy level at the bottom of the conduction band. May be released.
- “electron affinity reduction process” means a process for reducing the energy level of the vacuum level of the photocathode to a level at which electrons can be emitted.
- “electron affinity reduction treatment” refers to “EA surface treatment”
- “electron affinity reduction treatment” refers to a state where the energy level of the vacuum level of the photocathode has been reduced to a level at which electrons can be emitted.
- surface refers to a state where the energy level of the vacuum level of the photocathode has been reduced to a level at which electrons can be emitted.
- the EA surface deteriorates due to adsorption of residual gases such as trace amounts of H 2 O, CO, CO 2 , and backflow of ionized residual gases to the EA surface. Therefore, in order to stably extract an electron beam from a photocathode for a long period of time, an ultra-high vacuum is required for processing and maintenance. Further, the amount of electrons that can be extracted from the photocathode that has been subjected to the EA surface treatment is finite, and after emitting a certain amount of electron beam, the surface of the photocathode needs to be subjected to the EA surface treatment again.
- a conventional electron gun using an EA surface-treated photocathode includes at least an EA surface treatment chamber, an electron gun chamber, and an EA surface-treated photocathode transport means.
- the EA surface-treated photocathode needs to be loaded into the electron gun without being exposed to the outside air while maintaining the ultra-high vacuum state after performing the EA treatment in an ultra-high vacuum.
- the EA surface treatment needs to be performed again on the photocathode, but conventionally, the EA surface treatment chamber and the electron gun chamber had to be provided separately. The reason is that the conventional EA surface treatment employs a method of directly depositing the surface treatment material on the photocathode in the chamber.
- the EA surface treatment material is converted into the electron gun chamber. This is because the EA surface treatment material adhering to various devices in the chamber, particularly in the vicinity of the electrode, causes generation of a field emission dark current, and the function of the electron gun is remarkably deteriorated.
- the EA surface treatment chamber and the electron gun chamber are provided separately, first, two chambers are required to be in an ultra-high vacuum state, and further, photo processed in the EA surface treatment chamber while maintaining the ultra-high vacuum state. Since a transfer means for transferring the cathode to the electron gun chamber is necessary, there is a problem that the electron gun apparatus becomes very large.
- the EA surface-treated photocathode is moved and mounted from the EA surface treatment chamber to the electron gun chamber, and the EA surface treatment is performed from the electron gun chamber during the re-EA surface treatment of the photocathode. Since it is necessary to move and attach to the chamber, it is necessary to design the apparatus precisely and to perform an appropriate operation so that the photocathode does not fall off during transport, and there is a problem that apparatus management becomes complicated.
- Patent Document 1 Japanese Patent No. 5880821
- an activation container for performing a process for reducing the electron affinity of the photocathode material is disposed in the vacuum chamber. That is, in Patent Document 1, a chamber for generating an electron beam and a chamber for performing EA surface treatment are shared.
- Patent Document 1 describes that a driving means is provided to change the position of the photocathode holder.
- a driving unit such as a motor is attached to the activation container or attached to the inside of the vacuum chamber.
- the motor when the motor is arranged in the vacuum chamber, the following problems occur.
- the motor includes a magnetic field generating member such as a magnet. For this reason, the trajectory of electrons taken out from the photocathode material is bent by the magnetic field generating member.
- an object of the present invention is to provide an electron beam generator and an electron beam application apparatus that are easy to maintain.
- an optional object of the present invention is to provide an electron beam generator in which an activation container is disposed in a vacuum chamber, and by providing no motor for generating a magnetic field in the vacuum chamber, the trajectory of the electron beam is desired.
- An object of the present invention is to provide an electron beam generator and an electron beam application device that can suppress deviation from the orbit.
- the present invention relates to the following electron beam generator and electron beam application.
- the power transmission member in the chamber is A rotating member;
- the activation container includes: A first hole through which electrons emitted from the photocathode material or the photocathode material can pass; The electron beam generator according to any one of (1) to (9), further including a second hole through which the in-chamber power transmission member is inserted.
- the vacuum chamber includes a stretchable part, The electron beam generator according to any one of (1) to (10), wherein the photocathode holder or the activation container moves by expanding and contracting the expansion and contraction portion.
- An electron beam application apparatus including the electron beam generator according to any one of (1) to (13) above,
- the electron beam application apparatus comprises: Electron gun, Free electron laser accelerator, electronic microscope, Electron holography equipment, Electron beam drawing device, Electron diffraction device, Electron beam inspection equipment, Electron beam metal additive manufacturing equipment, Electron beam lithography equipment, Electron beam processing equipment, Electron beam curing device, Electron beam sterilizer, Electron beam sterilizer, Plasma generator, Atomic element generator, Spin polarized electron beam generator, Cathodoluminescence device, or An electron beam application device that is a reverse photoelectron spectrometer.
- FIG. 1 shows the concept of electron beam generation from a GaAs photocathode electron beam source.
- FIG. 2 shows a procedure for forming the EA surface state.
- FIG. 3 is a schematic cross-sectional view of the electron beam generator according to the first embodiment.
- FIG. 4 is a schematic cross-sectional view of the electron beam generator according to the first embodiment.
- FIG. 5 is a schematic cross-sectional view showing an example of a drive source.
- FIG. 6 is a conceptual diagram illustrating an example of an extendable part.
- FIG. 7 is a schematic cross-sectional view of an electron beam generator according to the second embodiment.
- FIG. 8A is an enlarged view of the area AR in FIG.
- FIG. 8B is an enlarged view of the area AR ′ in FIG. 7.
- FIG. 8A is an enlarged view of the area AR in FIG.
- FIG. 8B is an enlarged view of the area AR ′ in FIG. 7.
- FIG. 8A is an enlarged view of the area AR
- FIG. 9 is a schematic cross-sectional view of an electron beam generator according to the third embodiment.
- FIG. 10A and FIG. 10B are diagrams schematically showing an example of the heating means.
- FIG. 11 is a diagram schematically illustrating an example of the direction control unit.
- FIG. 12 is a diagram schematically illustrating an example of electrode arrangement.
- FIG. 13 is a functional block diagram of the electron beam application apparatus.
- the direction in which the photocathode holder 3 moves toward the first hole 44-1 of the activation container 4 is defined as the Z direction.
- the direction in which the electrons emitted from the photocathode (photocathode material) travel may be defined as the Z direction.
- the Z direction is, for example, a vertically downward direction, but the Z direction is not limited to the vertically downward direction.
- FIG. 3 and 4 are schematic cross-sectional views of the electron beam generator 1 according to the first embodiment.
- FIG. 5 is a schematic cross-sectional view showing an example of the drive source 7a.
- FIG. 6 is a conceptual diagram illustrating an example of an extendable part.
- FIG. 3 shows the position of the photocathode holder 3 when performing the EA surface treatment
- FIG. 4 shows the position of the photocathode holder 3 when performing the electron beam generation processing.
- the hatched portion indicates the vacuum region in the vacuum chamber 2.
- an arrow D1 indicates a direction in which electrons emitted from the photocathode (that is, photocathode material A) travel.
- Electron beam generator 1 is an apparatus that generates an electron beam in a vacuum atmosphere.
- a vacuum atmosphere is realized in the vacuum chamber 2.
- the electron beam generator 1 may be a device that generates an electron beam under a high voltage. In this case, the traveling direction of the electrons emitted from the photocathode depends on the electric field in the vacuum chamber when a high voltage is applied.
- the electron beam generator 1 includes a vacuum chamber 2, a photocathode holder 3, an activation container 4, and an in-chamber power transmission member 5b arranged in the vacuum chamber.
- the vacuum chamber 2 is a member for forming a vacuum atmosphere in the electron beam generator 1.
- the pressure inside the vacuum chamber 2 is set to 10 ⁇ 5 Pa or less, for example.
- a vacuum pump 91 is used.
- the vacuum pump 91 is prepared separately from the electron beam generator 1 and is connected to the electron beam generator 1 via a pipe.
- the gas supply apparatus 92 which supplies the gas used for EA surface treatment may be connected to the vacuum chamber 2 via piping.
- the gas supplied by the gas supply device 92 is, for example, oxygen, NF 3 , N 2 or the like.
- the shape of the vacuum chamber 2 is not particularly limited, and the shape of the vacuum chamber 2 is, for example, a cylindrical shape.
- the vacuum chamber 2 includes a body portion 20, a top portion 21, and a bottom portion.
- the material of the vacuum chamber 2 is, for example, a metal such as stainless steel, titanium, or mu metal, or a non-metal such as glass, sapphire, or ceramic.
- the photocathode holder 3 is disposed in the vacuum chamber 2 and supports the photocathode material A. In the example shown in FIG. 3, the photocathode holder 3 is disposed in an activation container 4 disposed in the vacuum chamber 2.
- the photocathode holder 3 is movable relative to the activation container 4.
- the surface treatment material B is deposited on the photocathode material A by activating (vaporizing) the surface treatment material B supported by the activation container 4. It is possible.
- the photocathode holder 3 is in the position shown in FIG. 4, the photocathode material A supported by the photocathode holder 3 is irradiated with light to generate electrons (electron beams) from the photocathode material A. It is possible to make it.
- the material of the photocathode holder 3 there are no particular restrictions on the material of the photocathode holder 3.
- a material of the photocathode holder 3 for example, molybdenum, titanium, tantalum, stainless steel or the like can be used.
- the photocathode material A for forming the photocathode is not particularly limited as long as it is a material capable of EA surface treatment.
- the photocathode material A include III-V group semiconductor materials and II-V group semiconductor materials. Specifically, AlN, Ce 2 Te, GaN, K 2 CsSb, AlAs, GaP, GaAs, GaSb, InAs and the like are exemplified.
- Other examples of the photocathode material A include metals, and specific examples include Mg, Cu, Nb, LaB 6 , SeB 6 , Ag, and the like.
- a photocathode can be produced by subjecting the photocathode material A to EA surface treatment.
- the electron excitation light can be selected in the near ultraviolet-infrared wavelength region corresponding to the gap energy of the semiconductor.
- electron beam source performance quantitative yield, durability, monochromaticity, time responsiveness, spin polarization
- the light source used for electronic excitation is not limited to a laser of high output (watt class) -high frequency (several hundred MHz) -short pulse (several hundred femtoseconds). Even with a relatively inexpensive laser diode, it is possible to generate an unprecedented high-performance beam.
- the photocathode material A When the electron beam generator 1 is used, the photocathode material A is irradiated with light.
- the photocathode material A emits electrons when it receives light.
- the emitted electrons move along the Z direction by a voltage applied between the photocathode holder 3 and the anode 82.
- the photocathode material A is disposed at a position where the photocathode material A can be irradiated with light.
- the photocathode material A is disposed on the bottom surface of the photocathode holder 3.
- the photocathode holder 3 is moved between the position shown in FIG. 3 and the position shown in FIG. 4, so that a driving force is applied to the photocathode holder 3. Is granted.
- the activation container 4 is disposed in the vacuum chamber 2 and supports the surface treatment material B that reduces the electron affinity of the photocathode material A.
- the surface treatment material B is activated (vaporized). Then, the activated (vaporized) surface treatment material B is deposited on the photocathode material A.
- the activation container 4 includes a first hole 44-1.
- the first hole 44-1 is a hole through which the photocathode material A supported by the photocathode holder 3 can pass, or a hole through which electrons emitted from the photocathode material A can pass.
- the size of the first hole 44-1 may be at least as large as electrons can pass.
- the diameter of the first hole 44-1 is, for example, from the viewpoint of facilitating processing or from the viewpoint of facilitating adjustment of the positional relationship between the electrons emitted from the photocathode material A and the first hole 44-1. They are 1 nm or more and 10 mm or less, More preferably, they are 50 micrometers or more and 5 mm or less.
- the size of the first hole 44-1 is the above numerical value. It may be larger than the upper limit of the range.
- a material of the activation container 4 for example, a heat-resistant material such as glass, molybdenum, ceramic, sapphire, titanium, tungsten, tantalum, and stainless steel (for example, a heat-resistant material that can withstand heat of 300 ° C. or higher, more preferably 400 ° C. Material).
- a heat-resistant material such as glass, molybdenum, ceramic, sapphire, titanium, tungsten, tantalum, and stainless steel (for example, a heat-resistant material that can withstand heat of 300 ° C. or higher, more preferably 400 ° C. Material).
- the shape of the activation container 4 should just be a shape which can support the surface treatment material B inside.
- the shape of the activation container 4 is, for example, a cylindrical shape.
- both generation of an electron beam and EA surface treatment can be performed in a single vacuum chamber 2. That is, in the state shown in FIG. 3, if the activation container 4 or the surface treatment material B itself is heated to activate (vaporize) the surface treatment material B, the surface treatment material B becomes the photocathode material A. Vapor deposited. Thus, EA surface treatment can be performed. Also, in the state shown in FIG. 4, if the photocathode material A is irradiated with light, an electron beam can be generated.
- the surface treatment material B means a material capable of EA surface treatment of the photocathode material.
- the surface treatment material B is not particularly limited as long as it can be subjected to EA surface treatment.
- elements constituting the surface treatment material B include Li, Na, K, Rb, Cs, Te, and Sb.
- Li, Na, K, Rb, and Cs ignite spontaneously and cannot be stored or used.
- Li, Na, K, Rb, and Cs must be used in the form of a composite element of these elements and a compound containing these elements.
- the surface treatment material B when an element selected from Li, Na, K, Rb, and Cs is used as the surface treatment material B, a compound such as Cs 2 CrO 4 , Rb 2 CrO 4 , Na 2 CrO 4 , or K 2 CrO 4 is used. It is preferable to use a combination of reducing agents that suppress the generation of impurity gases.
- the surface treatment material B is vaporized in the activation container 4 by using a heating means and is deposited on the photocathode material A.
- the activation container 4 is fixed to the inner wall surface of the vacuum chamber 2 and cannot move relative to the wall surface of the vacuum chamber 2. Then, driving force is transmitted from the in-chamber power transmission member 5 b to the photocathode holder 3, and the photocathode holder 3 moves relative to the activation container 4.
- the activation container 4 may be fixed in the vacuum chamber 2 via a support member as in a third embodiment described later.
- the photocathode holder 3 may be fixed to the wall surface of the vacuum chamber 2, and the driving force may be transmitted from the in-chamber power transmission member 5 b to the activation container 4. In this case, the activation container 4 moves relative to the photocathode holder 3.
- the in-chamber power transmission member 5 b is a member that is disposed in the vacuum chamber 2 and transmits a driving force to the photocathode holder 3 or the activation container 4.
- the in-chamber power transmission member 5b is a non-magnet member.
- the number of in-chamber power transmission members 5b arranged in the vacuum chamber 2 is one, and the one in-chamber power transmission member 5b is a non-magnet member.
- N is a natural number of 1 or more
- the N chamber power transmission members 5b are non-magnets. It is a member.
- the non-magnet member is a member that is not permanently magnetized, or a member that has a low degree of permanent magnetization even if it is permanently magnetized, and does not generate a magnetic field (or a weak magnetic field). It means a member that has no influence on the electron beam trajectory of emitted electrons or has a slight influence on the electron beam trajectory of electrons emitted from the photocathode material.
- a metal that cannot be permanently magnetized such as copper, titanium, stainless steel, or aluminum, is used as the material of the in-chamber power transmission member 5b.
- the member when a material such as iron or nickel that can be permanently magnetized is used as a material of at least a part of the in-chamber power transmission member 5b, the member is used for the electron beam orbit. It is placed in a position that does not affect it.
- the in-chamber power transmission member 5b is preferably a non-magnet member. For this reason, the in-chamber power transmission member 5b does not substantially affect the electron beam trajectory. In this way, the electron beam trajectory is prevented from deviating from the desired trajectory.
- Configuration example 1 is a configuration example related to the energy generation unit 7.
- the energy generation unit 7 generates mechanical energy that drives the in-chamber power transmission member 5b. And the mechanical energy produced
- the “in-chamber power transmission member 5b” in the present specification means a member for “transmitting” mechanical energy generated by the energy generation unit 7 to the photocathode holder 3, such as a motor. It is different from the driving means that generates the driving force by itself.
- the in-chamber power transmission member 5b and the photocathode holder 3 are one member produced by integral molding.
- the in-chamber power transmission member 5b and the photocathode holder 3 may be separately manufactured, and both may be connected via an arbitrary coupling means.
- the energy generation unit 7 is a drive source 7a (drive source), and generates mechanical energy.
- the drive source 7a is, for example, an actuator.
- the actuator is, for example, an actuator (pneumatic actuator, hydraulic actuator, etc.) driven by fluid pressure, an electric actuator, or a solenoid actuator.
- FIG. 5 shows an example in which the drive source 7a is a fluid pressure driven actuator.
- the actuator includes a cylinder 76 and a piston 78.
- Piston 78 is arrange
- the piston 78 also functions as the holeless wall 24 connected to the telescopic portion 22.
- the piston 78 moves when fluid such as air or oil is supplied from the pump P into the first chamber C1 of the cylinder 76 or when fluid such as air or oil is discharged from the first chamber C1.
- the piston 78 is connected to the in-chamber power transmission member 5b. For this reason, when the piston 78 moves, the in-chamber power transmission member 5b also moves.
- the cylinder 76 includes a first chamber C1 and a second chamber C2.
- the piston 78 is driven by a differential pressure between the pressure P 1 in the first chamber C1 and the pressure P 2 in the second chamber C2.
- P 0 is an internal pressure in the vacuum chamber 2.
- at least the pressure receiving surfaces of the cylinder 76 and the piston 78 function as a power transmission member outside the chamber.
- valve V is disposed in the pipe connecting the pump P and the first chamber C1, and the flow rate of the fluid flowing through the pipe is adjusted by the valve V.
- the photocathode holder 3 When using an actuator as the drive source 7a, it is easy to position the photocathode holder 3 at a desired position.
- the flow rate of the fluid supplied to the fluid pressure actuator, the current supplied to the electric actuator, the current supplied to the solenoid actuator, or the like is controlled.
- the energy generation unit 7 (more specifically, the drive source 7a) is disposed outside the vacuum chamber 2. For this reason, even when the energy generation unit 7 includes a magnetic field generation member such as a magnet, the interference of the magnetic field generation member with the electron beam trajectory is minimized. Further, when the energy generating unit 7 does not include a magnetic field generating member, the energy generating unit 7 does not interfere with the electron beam trajectory.
- the energy generation unit 7 (more specifically, the drive source 7a) is disposed outside the vacuum chamber 2, even when the inside of the vacuum chamber 2 is at a high temperature, An increase in temperature of the energy generator 7 is suppressed. For this reason, the energy generation part 7 is hard to break down. Furthermore, even if the energy generation unit 7 fails, the energy generation unit 7 can be easily repaired. For example, even if the failure of the energy generation unit 7 is found after the vacuum chamber 2 is in a high vacuum state, the energy generation unit 7 is repaired while maintaining the high vacuum state in the vacuum chamber 2. Is possible.
- the energy generation unit 7 (more specifically, the drive source 7a) is a linear actuator.
- the energy generation unit 7 may be a rotary actuator.
- a mechanism for converting the rotational driving force of the rotary actuator into a linear motion of the photocathode holder may be provided.
- the energy generation unit 7 may be a manual operation member instead of a drive source such as an actuator. In this case, mechanical energy is generated by human power.
- the driving force is applied to the photocathode holder and the photocathode holder moves with respect to the activation container.
- a driving force may be applied to the activation container so that the activation container moves relative to the photocathode holder.
- photocathode holder and “activation container” may be read as “activation container” and “photocathode holder”, respectively.
- Configuration example 2 is a configuration example related to the power transmission mechanism 5.
- the energy generation unit 7 applies a driving force to the photocathode holder 3 via the power transmission mechanism 5.
- the photocathode holder 3 moves relative to the activation container 4.
- the power transmission mechanism 5 includes a shaft disposed between the energy generation unit 7 and the photocathode holder 3.
- the power transmission mechanism 5 is not limited to a shaft.
- the power transmission mechanism 5 may include a gear mechanism, a screw mechanism, a link mechanism, a crank mechanism, a joint mechanism such as a universal joint, or a combination thereof.
- the power transmission mechanism 5 includes an outside-chamber power transmission member 5a disposed outside the vacuum chamber and an in-chamber power transmission member 5b disposed inside the vacuum chamber.
- the power transmission member 5a outside the chamber and the power transmission member 5b inside the chamber are connected to each other through the holeless wall 24 (holeless wall) of the vacuum chamber 2 so that power can be transmitted.
- the in-chamber power transmission member 5b may be referred to as a first power transmission member
- the outside-chamber power transmission member 5a may be referred to as a second power transmission member.
- the degree of vacuum in the vacuum chamber cannot be avoided.
- the external chamber power transmission member 5a and the in-chamber power transmission member 5b are connected via the holeless wall 24 (hole wall) of the vacuum chamber 2 so as to be able to transmit power. For this reason, the degree of vacuum in the vacuum chamber does not deteriorate.
- the electron beam generator 1 may include a guide member 52 that guides the movement of the in-chamber power transmission member 5b.
- the guide member 52 extends along the first direction (for example, the Z direction), and guides the movement of the in-chamber power transmission member 5b along the first direction. The presence of the guide member 52 prevents the photocathode holder 3 from tilting when the photocathode holder 3 moves.
- the guide member 52 is fixed to the vacuum chamber 2 (more specifically, the upper end portion of the guide member 52 is fixed to the top portion 21 of the vacuum chamber 2).
- the number of guide members 52 is preferably two or more from the viewpoint of suppressing the inclination of the photocathode holder 3.
- the number of guide members 52 may be one.
- the central axis of the in-chamber power transmission member 5b coincides with the central axis AX1 of the photocathode holder 3. For this reason, the power transmission mechanism 5 can be simplified.
- the power transmission mechanism 5 transmits the driving force from the energy generation unit 7 to the photocathode holder 3 has been described.
- the power transmission mechanism 5 may transmit the power from the energy generation unit to the activation container 4.
- “photocathode holder” and “activation container” may be read as “activation container” and “photocathode holder”, respectively.
- the movement of the in-chamber power transmission member 5b is a movement in the direction along the Z direction.
- the in-chamber power transmission member 5b does not move in the direction perpendicular to the Z direction.
- the power transmission mechanism 5 can be simplified.
- the in-chamber power transmission member 5b does not move in the direction perpendicular to the Z direction, the degree of freedom of arrangement of other components in the vacuum chamber 2 is high.
- the in-chamber power transmission member 5b may be movable in a direction perpendicular to the Z direction.
- Configuration example 3 is a configuration example related to the stretchable part 22.
- the vacuum chamber 2 includes the expansion / contraction part 22.
- the photocathode holder 3 is moved by expanding / contracting the expansion-contraction part 22 using the driving force from the energy generation part 7.
- the photocathode holder 3 in the vacuum chamber 2 can be driven by changing the volume of the vacuum chamber 2. Note that the degree of vacuum in the vacuum chamber 2 does not deteriorate due to the presence of the stretchable portion 22.
- the stretchable part 22 includes a bellows (bellows member). One end portion of the stretchable portion 22 is connected to the power transmission mechanism 5 (more specifically, the holeless wall 24), and the other end portion of the stretchable portion 22 is connected to the vacuum chamber 2 (more specifically, vacuum). The flange 2a of the chamber 2 is connected.
- the stretchable part 22 is provided on the top part 21 of the vacuum chamber 2. When both the expansion / contraction part 22 and the energy generation part 7 are arranged on the top part 21 of the vacuum chamber 2, the entire structure of the electron beam generator 1 can be simplified.
- the stretchable portion 22 may be configured by an inner cylinder 220, an outer cylinder 222, and a film 224 that connects the inner cylinder 220 and the outer cylinder 222.
- the power transmission mechanism 5 transmits the driving force from the energy generation unit 7 to the photocathode holder 3 has been described.
- the power transmission mechanism 5 may transmit the driving force from the energy generation unit to the activation container 4.
- “photocathode holder” and “activation container” may be read as “activation container” and “photocathode holder”, respectively.
- a configuration example 4 will be described with reference to FIGS. 3 and 4.
- the configuration example 4 is a configuration example related to the arrangement of the light sources 80.
- the light source 80 is disposed outside the vacuum chamber 2.
- the light from the light source 80 is applied to the photocathode material A through a light transmission window 81 disposed on the wall of the vacuum chamber 2.
- the light transmission window 81 is disposed on the Z direction side with respect to the photocathode holder 3.
- the light source 80 may be disposed on the side opposite to the Z direction from the photocathode holder. That is, light may be input from the back surface 3a side of the photocathode holder 3 (that is, the surface side opposite to the surface on which the photocathode material A is disposed).
- the photocathode holder 3 may be provided with a hole through which light can pass or a light transmitting material (for example, a transparent material).
- a light transmitting material for example, a transparent material.
- the light source 80 is disposed outside the vacuum chamber 2.
- the end may be disposed within the vacuum chamber 2 (alternatively, the light exit end of the optical fiber may be disposed outside the vacuum chamber).
- Configuration example 5 A configuration example 5 will be described with reference to FIGS. 3 and 4.
- the configuration example 5 is a configuration example related to the anode 82 and the power supply unit 83.
- the electron beam generator 1 includes an anode 82 and a power supply unit 83 that applies a voltage between the anode 82 and the photocathode holder 3 (cathode electrode).
- the anode 82 is disposed in the vacuum chamber 2, and the power supply unit 83 is disposed outside the vacuum chamber 2.
- the anode of the power supply unit 83 is electrically connected to the anode 82, and the cathode of the power supply unit 83 is electrically connected to the photocathode holder 3 via the in-chamber power transmission member 5b.
- the in-chamber power transmission member 5b also functions as a conductive member.
- any one of the above-described configuration examples 1 to 5 may be employed.
- any two of the above-described configuration examples 1 to 5 may be employed in the first embodiment.
- Configuration Examples 1 and 2 Configuration Examples 1 and 3, Configuration Examples 1 and 4, Configuration Examples 1 and 5, Configuration Examples 2 and 3, Configuration Examples 2 and 4, Configuration Examples 2 and 5 Configuration Examples 3 and 4, Configuration Examples 3 and 5, or Configuration Examples 4 and 5 may be employed.
- any three or more of the above-described configuration examples 1 to 5 may be employed.
- the electrical insulating member 30 is provided between the outside-chamber power transmission member 5 a and the holeless wall 24, and the container that houses the power transmission mechanism 5 is also formed of the electrical insulating member 30. . Note that the position of the electrical insulating member 30 shown in FIG.
- the position between the anode 82 and the photocathode holder 3 other than the circuit formed by [power source 83 -anode 82 -photocathode holder 3] As long as it is possible to prevent generation of a circuit through which electricity flows, it may be provided anywhere. For example, you may form a part of trunk
- the power supply unit 83 is connected to the anode 82 and the in-chamber power transmission member 5b, but a circuit of [power supply unit 83-anode 82-photocathode holder 3] is formed. For example, you may connect to another member.
- one end of the power source 83 may be connected to the flange portion 21a and electrically connected to the photocathode holder 3 via the guide member 52 and the in-chamber power transmission member 5b.
- a circuit for heating the surface treatment material B may be formed in addition to the circuit formed by [power supply unit 83 ⁇ anode 82 ⁇ photocathode holder 3].
- the introduction terminal is fixed to the flange 21a, and the introduction terminal end inside the vacuum region and the heating means (described later) of the surface treatment material B may be connected by an electric wire.
- the photocathode holder 3 may be provided with a heater for heating the photocathode 4.
- the introduction terminal may be fixed to the flange 21a, and the end of the introduction terminal inside the vacuum region and the heater may be connected by an electric wire.
- a resin with a large amount of gas release cannot be used in an ultra-high vacuum. Therefore, it is preferable that the electric wire is not an electric wire covered with a resin, but a bare wire with exposed metal and a tube made of an insulating material such as ceramic or a rosary insulator as necessary.
- the combination of the relatively moving members includes, for example, the in-chamber power transmission member 5b and the guide member 52, the in-chamber power transmission member 5b, and the flange portion 21a.
- the surface treatment is not particularly limited as long as adhesion between metals does not occur and the friction coefficient can be reduced.
- DLC Diamond like carbon
- TiN coating TiN coating
- TiCN coating TiCN coating
- CrN coating S-AH coating
- S-AH coating S-AH coating
- the non-metallic material is not particularly limited as long as it has resistance in a high-temperature vacuum environment, and examples thereof include ceramics and C / C composites.
- FIG. 7 is a schematic cross-sectional view of the electron beam generator 1 according to the second embodiment.
- FIG. 8A is an enlarged view of the area AR in FIG.
- FIG. 8B is an enlarged view of the area AR ′ in FIG.
- the specific configurations of the power transmission mechanism 5 and the energy generation unit 7 are different from the specific configurations of the power transmission mechanism and the energy generation unit in the first embodiment. Therefore, in 2nd Embodiment, it demonstrates centering on the power transmission mechanism 5 and the energy generation part 7, and the description which becomes repeated about another structure is abbreviate
- the in-chamber power transmission member 5b is arranged at a position eccentric from the central axis AX1 of the photocathode holder 3.
- light from the light source 80 can be introduced into the photocathode material A from the back surface 3 a side of the photocathode holder 3.
- the rod 3b of the photocathode holder 3 has a light introduction hole or a light transmitting material ( Preferably, it is made of a transparent material.
- the light source 80 is disposed outside the vacuum chamber 2. For this reason, the light source 80 is not exposed to the harsh environment in the vacuum chamber 2.
- the light source 80 is disposed outside the vacuum chamber 2
- at least a part of the vacuum chamber 2 may be made of a light transmitting material (for example, a transparent material). Then, light from the light source 80 may be introduced into the vacuum chamber 2 through the light transmitting material.
- the arrangement of the light sources 80 is not limited to the example shown in FIG.
- the light source 80 may be disposed in the vacuum chamber 2. Further, the position of the light source 80 may be the same as the position of the light source in the first embodiment.
- the in-chamber power transmission member 5 b includes a rotating member 533 that can rotate around an axis parallel to the first direction (Z direction), and the rotation of the rotating member 533 is linearly moved by the photocathode holder 3. (For example, movement along the first direction).
- the conversion mechanism includes a male screw portion 533 c provided on the rotating member 533 and a female screw portion 3 c provided on the photocathode holder 3. The male screw portion 533c and the female screw portion 3c are screwed together.
- the in-chamber power transmission member 5 b includes a universal joint 54.
- positioning of the power transmission mechanism 5 increases.
- the in-chamber power transmission member 5 b includes two universal joints 54.
- the number of universal joints 54 provided in the in-chamber power transmission member 5b is not limited to two.
- the number of universal joints 54 may be one or may be three or more.
- a universal joint is used as the in-chamber power transmission member 5b is shown, but other members may be used as long as they can transmit power in the chamber.
- a metal wire or the like may be used as a member that transmits rotation in the same manner as the universal joint.
- the electron beam generator 1 may include a shield 88 that suppresses the occurrence of discharge from the protrusions in the vacuum chamber 2 as necessary.
- a part of the in-chamber power transmission member 5 b is covered with the activation container 4, and a portion of the in-chamber power transmission member 5 b exposed to the outside of the activation container 4 is anoded by the shield 88.
- the shield 88 is between the anode 82 and at least a part of the in-chamber power transmission member 5b (specifically, a portion of the in-chamber power transmission member 5b exposed to the outside of the activation container 4). Is arranged. For this reason, generation
- the shape and arrangement of the shield 88 are arbitrary as long as generation of discharge from the in-chamber power transmission member 5b can be suppressed.
- the outer surface 88a of the shield 88 is a smooth curved surface. Further, the outer surface 88a of the shield 88 has no corners.
- the material of the shield 88 it is preferable to use a material that does not easily generate electric discharge.
- the material of the shield 88 is, for example, titanium, molybdenum, stainless steel, TiN, or the like.
- the surface of the shield 88 may be coated with titanium, molybdenum, stainless steel, TiN, or the like.
- the activation container 4 functions as a first shield that covers a part of the in-chamber power transmission member 5b
- the shield 88 covers the other part of the in-chamber power transmission member 5b. 2 functions as a shield.
- the shield 88 functioning as the second shield may be omitted.
- the shield 88 may be omitted because the risk of discharge is reduced when the applied voltage is low.
- FIG. 8A is an enlarged view of the area AR in FIG.
- the energy generating unit 7 is a manual operation member 7b.
- the operation knob 72 of the manual operation member 7b when the operation knob 72 of the manual operation member 7b is rotated, the outside-chamber power transmission member 5a rotates around the rotation axis AX2.
- the holeless wall 24 revolves around the rotation axis AX2. Since the holeless wall 24 is fixed to the bellows 74, it cannot rotate.
- the first shaft 531 of the in-chamber power transmission member 5b rotates around the rotation axis AX2. In this way, the driving force (in other words, mechanical energy) from the energy generating unit 7 is transmitted to the in-chamber power transmission member 5b via the out-chamber power transmission member 5a.
- the chamber external power transmission member 5a and the internal chamber power transmission member 5b have no holes in the vacuum chamber 2, as in the configuration example 2 of the first embodiment. It is connected via a wall 24 so that power can be transmitted. For this reason, the degree of vacuum in the vacuum chamber 2 does not deteriorate.
- the in-chamber power transmission member 5b includes a plurality of shafts 53 and a plurality of universal joints 54. More specifically, the rotation of the first shaft 531 is transmitted to the second shaft 532 via the first universal joint 541. The rotation of the second shaft 532 is transmitted to the third shaft (rotating member 533) via the second universal joint 542. The photocathode holder 3 moves linearly as the third shaft (rotating member 533) rotates.
- the second embodiment has the same effects as the first embodiment.
- the in-chamber power transmission member 5b when the in-chamber power transmission member 5b is arranged at a position eccentric from the central axis of the photocathode holder 3, the degree of freedom of arrangement of the light source and the like is improved. To do.
- the in-chamber power transmission member 5b includes a rotating member 533 and a conversion mechanism that converts rotation of the rotating member into linear movement of the photocathode holder 3. Therefore, the positioning control of the photocathode holder 3 is facilitated.
- the degree of freedom of arrangement of the power transmission mechanism including the in-chamber power transmission member 5b is improved. To do.
- the electron beam generator 1 when the electron beam generator 1 includes the shield 88, the occurrence of discharge from the in-chamber power transmission member 5b and the like is suppressed.
- the external chamber power transmission member 5a and the in-chamber power transmission member 5b are connected via the holeless wall 24 of the vacuum chamber 2 so as to transmit power. In this case, the deterioration of the degree of vacuum in the vacuum chamber is effectively suppressed.
- the power transmission mechanism 5 transmits the driving force from the energy generation unit to the photocathode holder 3
- the power transmission mechanism 5 may transmit the driving force from the energy generation unit to the activation container 4.
- the energy generating unit 7 is the manual operation member 7b
- the operation knob 72 or the like may be driven by a motor or a rotary actuator.
- the energy generation unit 7 in the second embodiment is the drive source 7a.
- the second embodiment as in the first embodiment, with respect to a member that is disposed so as to be relatively movable with another member in the vacuum region, one or both members that are relatively moved are subjected to surface treatment or non-treatment. You may produce with a metal material. Examples of the combination of the members that move relative to each other in the second embodiment include the first shaft 531 and the flange portion 21a, the male screw portion 533c and the female screw portion 3c, the guide member 52, and the rod 3b.
- FIG. 8B is an enlarged view of the area AR ′ in FIG. 7 and is a diagram showing another example of a circuit for supplying electricity to the heater.
- the wire forming the circuit is preferably a bare wire.
- the bare wire is also movable in the vacuum region, and may come into contact with another member to cause a short circuit or disconnection. Therefore, you may enable it to electrically connect the member and member which move relatively by a contact system.
- the introduction terminal 60a, the first terminal block 62, the second terminal block 63, the connection portion 64 that connects the first terminal block 62 and the second terminal block 63 by the contact method, and connecting them Bare wires 61a and 61b are included.
- the introduction terminal 60a is penetrated and fixed so as to be insulated from the flange 21a, and can be connected to the electric wire at the vacuum region inner end 60a1 and the vacuum region outer end 60a2.
- the first terminal block 62 is fixed so that one end is insulated from the flange 21a.
- the vacuum region inner end 60a1 of the introduction terminal 60a and the first terminal block 62 are connected by a bare wire 61a.
- the second terminal block 63 is fixed to the photocathode holder 3.
- the first terminal block 62 is provided with a contact portion 64 that contacts the second terminal block 63.
- the contact portion 64 is preferably formed of a material having a biasing force so as to always contact the second terminal block 63 such as a leaf spring or a coil.
- the contact portion 64 may be provided on the second terminal block 63 so as to contact the first terminal block 62. And by connecting the 2nd terminal block 63 and the heater 3d with the bare wire 61b, electricity can be sent to the heater 3d from the outside of a vacuum chamber.
- the heating means (described later) for the surface treatment material B may be connected using the bare wire 61c and the vacuum region inner end 60b1 of the introduction terminal 60b that is penetrated and fixed so as to be insulated from the flange 21a.
- the first terminal block 62 and the second terminal block 63 that move relative to each other are contacted and energized by the contact portion 64, and the bare wires 61a to 61c connect the members that do not move relative to each other. is doing. Therefore, in the embodiment shown in FIG. 8B, there is no fear of short circuit or disconnection due to the bare wire arranged in the vacuum region coming into contact with other members.
- the embodiment shown in FIG. 8B may be adopted in the first embodiment.
- the embodiment shown in FIG. 8B shows an example of a specific aspect of the contact method, and other forms may be employed as long as the relatively moving member and the member are contacted and energized by the contact method.
- FIG. 9 is a schematic cross-sectional view of the electron beam generator 1 according to the third embodiment.
- the third embodiment differs from the electron beam generator in the first embodiment in that the stretchable portion 26 constitutes a part of the body of the vacuum chamber 2.
- the specific configurations of the activation container 4, the power transmission mechanism 5, and the energy generation unit 7 are the specific configurations of the activation container, the power transmission mechanism, and the energy generation unit in the first embodiment. And different. Therefore, in 3rd Embodiment, it demonstrates centering on the expansion-contraction part 26, the activation container 4, the power transmission mechanism 5, and the energy generation part 7, and the description which repeats about another structure is abbreviate
- the stretchable part 26 (for example, bellows) constitutes a part of the body part of the vacuum chamber 2. More specifically, the expansion / contraction part 26 is disposed between the first flange part 58 connected to the vacuum chamber 2 and the second flange part 28 connected to the vacuum chamber 2, and the first flange part 58 The second flange portion 28 is connected. For this reason, the first flange portion 58 is movable relative to the second flange portion 28.
- the in-chamber power transmission member 5b that moves together with the first flange portion 58 also moves relative to the second flange portion 28.
- the photocathode holder 3 connected to the in-chamber power transmission member 5b moves relative to the activation container 4.
- the in-chamber power transmission member 5b is a shaft.
- the in-chamber power transmission member 5b and the photocathode holder 3 are one member produced by integral molding.
- the in-chamber power transmission member 5b and the photocathode holder 3 may be separately manufactured, and both may be connected via an arbitrary coupling means.
- the in-chamber power transmission member 5b is fixed to the top of the vacuum chamber 2 (more specifically, the top flange portion 21a).
- the in-chamber power transmission member 5b may be fixed to the body 20 of the vacuum chamber 2.
- the outside-chamber power transmission member 5 a includes a first flange portion 58 connected to the vacuum chamber 2.
- the outside-chamber power transmission member 5 a includes a screw rod 59.
- the first flange portion 58 is provided with a screw hole 58 c that is screwed with the screw rod 59.
- the first flange portion 58 moves linearly (for example, moves in the Z direction).
- the distance between the first flange part 58 and the second flange part 28 changes, and the expansion / contraction part 26 expands and contracts.
- the screw rod 59 is connected to the energy generation unit 7.
- the energy generating unit 7 is a manual operation member 7b.
- the screw rod 59 rotates around the central axis of the screw rod.
- the body portion 20a may be an electrically insulating member.
- the electron beam generator 1 may include a guide member 580 (for example, a guide rod) that guides the movement of the first flange portion 58.
- the guide member 580 is disposed so as to penetrate the through hole 58 d of the first flange portion 58.
- the number of guide members 580 may be one or two or more.
- the vacuum chamber 2 includes the expansion / contraction part 26. For this reason, it is possible to move the in-chamber power transmission member 5b (and the photocathode holder 3) in the vacuum chamber 2 by changing the volume of the vacuum chamber 2. Even if the volume of the vacuum chamber 2 is changed, the degree of vacuum in the vacuum chamber 2 does not deteriorate.
- the activation container 4 will be described.
- the activation container 4 is attached to the vacuum chamber 2 via a support member 42.
- the activation container 4 is suspended and supported by a plurality of support members 42.
- the activation container 4 includes a first hole 44-1 through which photocathode material A or electrons emitted from photocathode material A can pass.
- the activation container 4 includes a second hole 44-2 through which the in-chamber power transmission member 5b is inserted.
- the second hole 44-2 is provided on the surface opposite to the surface where the first hole 44-1 is provided. More specifically, the first hole 44-1 is provided on the lower surface of the activation container 4, and the second hole 44-2 is provided on the upper surface of the activation container 4.
- the second hole 44-2 may be provided on the side surface of the activation container 4 (see FIG. 7).
- the activation container 4 is supported by the vacuum chamber 2 via the support member 42.
- the support member 42 preferably supports the activation container 4 from the side opposite to the side where the anode 82 is disposed.
- the activation container 4 is preferably disposed between the support member 42 and the anode 82.
- the third embodiment has the same effects as the first embodiment.
- the stretchable part 26 (for example, bellows) constitutes a part of the body of the vacuum chamber 2, the stretchable part is simply stretched.
- the in-chamber power transmission member 5b can be moved. Moreover, since the movement of the in-chamber power transmission member 5b is limited to a linear movement, the power transmission mechanism 5 can be simplified.
- the volume of the activation container 4 when the activation container 4 is attached to the vacuum chamber 2 via the support member 42, the volume of the activation container 4 may be reduced. it can.
- the activation container 4 includes a second hole 44-2 through which the in-chamber power transmission member 5b is inserted, in addition to the first hole 44-1. It may be.
- the surface treatment material B may be released out of the activation container 4 through the second hole 44-2. Therefore, in addition, the surface treatment material B may be less likely to be released from the second hole 44-2 by increasing the outer diameter of the photocathode holder 3.
- the power transmission mechanism 5 transmits the driving force from the energy generation unit 7 to the photocathode holder 3 .
- the power transmission mechanism 5 may transmit the driving force from the energy generation unit 7 to the activation container 4.
- the energy generating unit 7 is the manual operation member 7b
- the operation knob 72 or the like may be driven by a motor or a rotary actuator.
- the energy generation unit 7 in the third embodiment is the drive source 7a.
- the power transmission mechanism 5 in the embodiment may be a power transmission mechanism that converts the vibration of the power transmission member outside the chamber into the movement of the power transmission member inside the chamber.
- a vibration source such as an ultrasonic motor may be used as the energy generation unit 7.
- the driving force is transmitted to the power transmission member in the chamber thermally.
- the in-chamber power transmission member is made of a shape memory alloy.
- the in-chamber power transmission member made of the shape memory alloy can be expanded and contracted.
- the photocathode holder 3 or the activation container 4 connected to the in-chamber power transmission member moves.
- the photocathode holder 3 moves relative to the activation container 4.
- the energy generation unit is configured by a heat source.
- generation part (heat source) produces
- the heat source may be disposed in the vacuum chamber or may be disposed outside the vacuum chamber.
- Modification 3 of the power transmission mechanism In the above-described first to third embodiments and the first modification of the power transmission mechanism, an example in which the power transmission member outside the chamber transmits the driving force to the power transmission member in the chamber purely mechanically.
- the second modification of the power transmission mechanism an example in which the driving force is transmitted thermodynamically to the in-chamber power transmission member has been described.
- at least a part of the transmission of the driving force to the in-chamber power transmission member may be performed magnetically or electromagnetically.
- the outside-chamber power transmission member disposed outside the vacuum chamber 2 includes a magnet
- the in-chamber power transmission member disposed within the vacuum chamber includes a ferromagnetic material attracted to the magnet.
- the in-chamber power transmission member can be moved by moving the outside-chamber power transmission member.
- a manual operation member for manually moving the power transmission member outside the chamber may be employed as the energy generation unit 7, or the power transmission member outside the chamber may be moved by non-human power.
- the drive source for making it may be employ
- the magnet is disposed outside the vacuum chamber 2. For this reason, the interference with the electron beam orbit of a magnet remains to the minimum.
- power transmission The mechanism is preferably a purely mechanical power transmission mechanism.
- the power transmission member outside the chamber transmits the driving force purely mechanically to the power transmission member within the chamber.
- Heating means The heating means for activating the surface treatment material B will be described with reference to FIGS. 10 (a) and 10 (b).
- FIG. 10A and FIG. 10B are diagrams schematically showing an example of the heating means.
- the heating means 95 heats and vaporizes the surface treatment material B.
- the heating means 95 may indirectly heat the surface treatment material B disposed inside by heating the entire activation container 4 or may directly heat only the surface treatment material B.
- a heating means such as an electric heating coil is disposed in the activation container 4, or a method of heating the activation container 4 by heating the entire vacuum chamber 2 using an electric heating coil, a lamp heater, or the like. Is mentioned.
- FIG. 10A shows an example in which the heating means 95 is incorporated in the surface treatment material B.
- a heating means 95 such as a heating wire is inserted through the center of the surface treatment material B, and a longitudinal notch 96 is formed in the surface treatment material B.
- the heating means 95 is energized, as shown in FIG. 10B, the notch 96 becomes larger due to heating, and the vaporized gas of the surface treatment material B is released from the enlarged notch 96.
- the vaporized gas of the surface treatment material B is emitted from the notches 96 with directivity, so that the vaporized gas can be directed only in the direction of the photocathode material A.
- FIG. 11 is a diagram schematically showing an example of the direction control means 97.
- two directional control plates 98 are arranged so as to sandwich the surface treatment material B.
- the angle at which the vaporized surface treatment material B scatters can be adjusted to an angle larger than 0 degree and smaller than 90 with respect to the surface connecting the ends of the first holes 44-1.
- the number of direction control plates 98 is not limited to two.
- the number of direction control plates 98 may be one, or three or more.
- FIG. 12 is a diagram schematically illustrating an example of electrode arrangement.
- the activation vessel 4 is formed of a conductive material, and the photocathode holder 3 is used without being in contact with the activation vessel 4 to be used as a three-pole structure. You can also.
- the voltage VA of the photocathode and the voltage VB of the activation container 4 may be set to VA ⁇ VB, and both VA and VB may be 0 V or less.
- EA surface treatment method An example of the EA surface treatment method for the photocathode material A arranged in the electron beam generator 1 according to the embodiment will be described.
- the EA surface treatment method is executed by the following procedures (1) to (3), for example.
- the relative positional relationship between the photocathode holder 3 and the activation container 4 is, for example, the positional relationship shown in FIG. 3, the positional relationship shown in FIG. 7, or the position shown in FIG. Set to relationship.
- the photocathode holder 3 on which the photocathode material A is supported is heated in a vacuum at 300 to 700 ° C. for 10 minutes to 1 hour to remove surface impurities such as oxides and carbides and clean them.
- the heating temperature and time are appropriately adjusted according to the photocathode material used. Thereby, band bending is caused in the photocathode material A, and the vacuum level can be lowered by about half ( ⁇ B) of the band gap of the semiconductor forming the photocathode.
- the surface treatment material B is deposited so that a minute photocurrent is obtained on the crystal surface of the photocathode material A.
- an EA surface state can be formed by lowering the remaining vacuum level ( ⁇ D).
- the addition of the gas is performed, for example, by spraying the gas supplied from the gas supply device 92 onto the photocathode material A.
- a plurality of types of surface treatment materials B for example, Cs and Te, Cs, and Sb are vapor-deposited on the photocathode material A, it is not always necessary to add gas.
- FIG. 13 is a functional block diagram of the electron beam application apparatus 100.
- the electron beam application apparatus 100 is an apparatus that causes the electrons generated by the electron beam generator 1 to fly in a desired direction.
- the electron beam application apparatus 100 may be an apparatus that irradiates electrons toward a target.
- the electron beam application apparatus 100 includes an electron beam generator 1.
- the electron beam application apparatus 100 includes, for example, an electron gun, a free electron laser accelerator, an electron microscope such as a transmission electron microscope or a scanning electron microscope, an electron beam holography apparatus, an electron beam drawing apparatus, an electron beam diffraction apparatus, and an electron beam inspection apparatus.
- Electron beam metal additive manufacturing equipment (3D printer), electron beam lithography equipment, other electron beam processing equipment (crosslinking, polymerization, deposition, etching, surface modification, etc.), electron beam curing equipment, electron beam sterilization equipment, electron
- 3D printer Electron beam metal additive manufacturing equipment
- electron beam lithography equipment other electron beam processing equipment (crosslinking, polymerization, deposition, etching, surface modification, etc.), electron beam curing equipment, electron beam sterilization equipment, electron
- a line sterilizer a plasma generator, an atomic element (radical) generator, a spin-polarized electron beam generator, an analyzer (a cathode luminescence device, a reverse photoelectron spectrometer), and the like.
- a publicly known or well-known configuration may be adopted for a configuration other than the electron beam generator 1. For this reason, description about each apparatus is abbreviate
- Electron beam generator 2 ... Vacuum chamber, 3 ... Photo cathode holder, 3a ... Back surface, 3b ... Rod, 3c ... Female thread part, 3d ... Heater, 4 ... Activation container, 5 ... Power transmission mechanism, 5a ... Chamber External power transmission member, 5b ... In-chamber power transmission member, 7 ... Energy generation unit, 7a ... Drive source, 7b ... Manual operation member, 10 ... Electron gun, 11 ... EA surface treatment chamber, 12 ... Electron gun chamber, 13 ... Conveying means, 20 ... barrel portion, 20a ... trunk portion, 21 ... top portion, 21a ... flange portion, 22 ...
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Electron Sources, Ion Sources (AREA)
- Common Detailed Techniques For Electron Tubes Or Discharge Tubes (AREA)
Abstract
Description
(1)フォトカソードへ励起光を入射し、価電子帯電子を伝導帯へ励起する(励起過程)。
(2)伝導帯へ励起された電子は、表面へと拡散する(拡散過程)。
(3)表面まで到達した電子は、表面障壁をトンネルし、真空中へ脱出する(脱出過程)。
(1)初めにp型ドーピングのGaAs半導体を真空中で加熱し、酸化物や炭化物などの表面不純物を除去し清浄にする。これにより、表面領域にバンドベンディングを生じさせ、真空準位を半導体のバンドギャップの半分程度(φB)下げることができる。
(2)次に結晶表面に微小の光電流が得られるように、図2に示すように、まずセシウムを蒸着し、その後、光電流の飽和毎にセシウム蒸着と酸素付加を最大の光電流が得られるまで交互に繰り返す。この方法により、残りの真空準位(φD)を下げることで、NEA表面状態を形成することができる(非特許文献1参照)。
前記真空チャンバー内に配置され、フォトカソード材料を支持するフォトカソードホルダーと、
前記真空チャンバー内に配置され、前記フォトカソード材料の電子親和力を低下させる表面処理材料を支持する活性化容器と、
前記真空チャンバー内に配置され、前記フォトカソードホルダーまたは前記活性化容器に駆動力を伝達するチャンバー内動力伝達部材と
を具備し、
前記フォトカソードホルダーは、前記活性化容器に対して相対移動可能である
電子線発生装置。
(2)前記チャンバー内動力伝達部材を駆動する機械的エネルギーを生成するエネルギー生成部を更に具備し、
前記エネルギー生成部は、前記真空チャンバーの外に配置されている
上記(1)に記載の電子線発生装置。
(3)前記エネルギー生成部は、駆動源または手動操作部材である
上記(2)に記載の電子線発生装置。
(4)前記真空チャンバーの外に配置されるチャンバー外動力伝達部材を更に具備し、
前記チャンバー外動力伝達部材と、前記チャンバー内動力伝達部材とは、前記真空チャンバーの孔無し壁を介して動力伝達可能に接続されている
上記(1)乃至(3)のいずれか一つに記載の電子線発生装置。
(5)前記チャンバー外動力伝達部材は、前記チャンバー内動力伝達部材に、駆動力を純機械的に伝達する
上記(4)に記載の電子線発生装置。
(6)前記チャンバー内動力伝達部材は、前記フォトカソードホルダーの中心軸から偏心した位置に配置されている
上記(1)乃至(5)のいずれか一つに記載の電子線発生装置。
(7)前記真空チャンバー内に配置され、かつ、第1方向に沿って延在するガイド部材を更に具備し、
前記ガイド部材は、前記チャンバー内動力伝達部材の前記第1方向に沿う移動を案内する
上記(1)乃至(6)のいずれか一つに記載の電子線発生装置。
(8)前記チャンバー内動力伝達部材は、
回転部材と、
前記回転部材の回転を、前記フォトカソードホルダーまたは前記活性化容器の直線移動に変換する変換機構と
を有する
上記(1)乃至(7)のいずれか一つに記載の電子線発生装置。
(9)前記真空チャンバー内に配置されたアノードと、
前記真空チャンバー内の突起物からの放電の発生を抑制するシールドと
を更に具備し、
前記シールドは、前記アノードと、前記チャンバー内動力伝達部材の少なくとも一部との間に配置されている
上記(1)乃至(8)のいずれか一つに記載の電子線発生装置。
(10)前記活性化容器は、
前記フォトカソード材料から放出される電子または前記フォトカソード材料が通過可能な第1孔と、
前記チャンバー内動力伝達部材が挿通される第2孔と
を有する
上記(1)乃至(9)のいずれか一つに記載の電子線発生装置。
(11)前記真空チャンバーは、伸縮部を含み、
前記伸縮部を伸縮させることにより、前記フォトカソードホルダーまたは前記活性化容器が移動する
上記(1)乃至(10)のいずれか一つに記載の電子線発生装置。
(12)前記伸縮部は、前記真空チャンバーの胴部の一部を構成しているか、あるいは、前記真空チャンバーの頂部に取り付けられている
上記(11)に記載の電子線発生装置。
(13)前記チャンバー内動力伝達部材を駆動する熱エネルギーを生成するエネルギー生成部を更に具備する
上記(1)に記載の電子線発生装置。
(14)上記(1)乃至(13)のいずれか一つに記載の電子線発生装置を含む電子線適用装置であって、
前記電子線適用装置は、
電子銃、
自由電子レーザー加速器、
電子顕微鏡、
電子線ホログラフィー装置、
電子線描画装置、
電子線回折装置、
電子線検査装置、
電子線金属積層造形装置、
電子線リソグラフィー装置、
電子線加工装置、
電子線硬化装置、
電子線滅菌装置、
電子線殺菌装置、
プラズマ発生装置、
原子状元素発生装置、
スピン偏極電子線発生装置、
カソードルミネッセンス装置、または、
逆光電子分光装置
である
電子線適用装置。
本明細書において、フォトカソードホルダー3が活性化容器4の第1孔44-1に向かって移動する方向をZ方向と定義する。代替的に、フォトカソード(フォトカソード材料)から放出された電子が進行する方向をZ方向と定義してもよい。Z方向は、例えば、鉛直下向き方向であるが、Z方向は、鉛直下向き方向には限定されない。
図3乃至図6を参照して、第1の実施形態における電子線発生装置1について説明する。図3および図4は、第1の実施形態における電子線発生装置1の概略断面図である。図5は、駆動源7aの一例を示す概略断面図である。図6は、伸縮部の一例を示す概念図である。なお、図3は、EA表面処理を実行する際のフォトカソードホルダー3の位置を示し、図4は、電子線の発生処理を実行する際のフォトカソードホルダー3の位置を示している。また、図4において、斜線部分は、真空チャンバー2内の真空領域を示している。さらに、図4において、矢印D1は、フォトカソード(すなわち、フォトカソード材料A)から放出された電子が進行する方向を示している。
図3乃至図6を参照して、第1の実施形態において、付加的に採用可能な構成例について説明する。
図3を参照して、構成例1について説明する。構成例1は、エネルギー生成部7に関する構成例である。
図3を参照して、構成例2について説明する。構成例2は、動力伝達機構5に関する構成例である。
図3乃至図6を参照して、構成例3について説明する。構成例3は、伸縮部22に関する構成例である。構成例3では、真空チャンバー2は、伸縮部22を含む。そして、構成例3では、エネルギー生成部7からの駆動力を用いて伸縮部22を伸縮させることにより、フォトカソードホルダー3を移動させる。
図3および図4を参照して、構成例4について説明する。構成例4は、光源80の配置に関する構成例である。
図3および図4を参照して、構成例5について説明する。構成例5は、アノード82と、電源部83に関する構成例である。
図7乃至図9を参照して、第2の実施形態について説明する。図7は、第2の実施形態における電子線発生装置1の概略断面図である。図8Aは、図7における領域ARの拡大図である。図8Bは、図7における領域AR’の拡大図である。
図9を参照して、第3の実施形態について説明する。図9は、第3の実施形態における電子線発生装置1の概略断面図である。
実施形態における動力伝達機構5は、チャンバー外動力伝達部材の振動を、チャンバー内動力伝達部材の移動に変換する動力伝達機構であってもよい。この場合、エネルギー生成部7としては、超音波モーター等の振動源(駆動源)を用いればよい。
上述の第1の実施形態乃至第3の実施形態、および、動力伝達機構の変形例1では、チャンバー外動力伝達部材が、チャンバー内動力伝達部材に、駆動力を純機械的に伝達する例について説明された。代替的に、チャンバー内動力伝達部材への駆動力の伝達の少なくとも一部は、非機械的に行われてもよい。
上述の第1の実施形態乃至第3の実施形態、および、動力伝達機構の変形例1では、チャンバー外動力伝達部材が、チャンバー内動力伝達部材に、駆動力を純機械的に伝達する例について説明された。また、動力伝達機構の変形例2では、チャンバー内動力伝達部材に、駆動力が熱力学的に伝達される例について説明された。代替的に、チャンバー内動力伝達部材への駆動力の伝達の少なくとも一部は、磁気的または電磁気的に行われてもよい。
図10乃至図12を参照して、上述の各実施形態において採用可能なその他の構成について説明する。
図10(a)および図10(b)を参照して、表面処理材料Bを活性化するための加熱手段について説明する。図10(a)および図10(b)は、加熱手段の一例を模式的に示す図である。
図11を参照して、気化した表面処理材料B(表面処理材料Bの気化ガス)の飛散方向を制御する方向制御手段97について説明する。図11は、方向制御手段97の一例を模式的に示す図である。
図12を参照して、電極の配置の一例について説明する。図12は、電極の配置の一例を模式的に示す図である。
実施形態における電子線発生装置1内に配置されたフォトカソード材料AのEA表面処理方法の一例について説明する。EA表面処理方法は、例えば、次の(1)~(3)の手順により実行される。なお、EA表面処理に際しては、フォトカソードホルダー3と活性化容器4との相対位置関係は、例えば、図3に示される位置関係、図7に示される位置関係、あるいは、図9に示される位置関係に設定される。
(2)フォトカソード材料Aの結晶表面に微小の光電流が得られるように、表面処理材料Bを蒸着する。その後、光電流の飽和毎に表面処理材料Bの蒸着と、必要に応じて酸素、NF3、N2等の気体の付加を最大の光電流が得られるまで交互に繰り返す。この方法により、残りの真空準位(φD)を下げることで、EA表面状態を形成することができる。気体の付加は、例えば、ガス供給装置92から供給される気体を、フォトカソード材料Aに吹き付けることによって行われる。なお、複数種類の表面処理材料B、例えば、Cs及びTe、Cs及びSb等をフォトカソード材料Aに蒸着する場合は、気体の付加は必ずしも必要ない。
(3)一定時間電子の放出を行った後、上記(2)の手順を行うことで、EA表面の再処理を行う。
図13を参照して、電子線適用装置100(electron beam applicator)について説明する。図13は、電子線適用装置100の機能ブロック図である。
Claims (14)
- 真空チャンバーと、
前記真空チャンバー内に配置され、フォトカソード材料を支持するフォトカソードホルダーと、
前記真空チャンバー内に配置され、前記フォトカソード材料の電子親和力を低下させる表面処理材料を支持する活性化容器と、
前記真空チャンバー内に配置され、前記フォトカソードホルダーまたは前記活性化容器に駆動力を伝達するチャンバー内動力伝達部材と
を具備し、
前記フォトカソードホルダーは、前記活性化容器に対して相対移動可能である
電子線発生装置。 - 前記チャンバー内動力伝達部材を駆動する機械的エネルギーを生成するエネルギー生成部を更に具備し、
前記エネルギー生成部は、前記真空チャンバーの外に配置されている
請求項1に記載の電子線発生装置。 - 前記エネルギー生成部は、駆動源または手動操作部材である
請求項2に記載の電子線発生装置。 - 前記真空チャンバーの外に配置されるチャンバー外動力伝達部材を更に具備し、
前記チャンバー外動力伝達部材と、前記チャンバー内動力伝達部材とは、前記真空チャンバーの孔無し壁を介して動力伝達可能に接続されている
請求項1乃至3のいずれか一項に記載の電子線発生装置。 - 前記チャンバー外動力伝達部材は、前記チャンバー内動力伝達部材に、駆動力を純機械的に伝達する
請求項4に記載の電子線発生装置。 - 前記チャンバー内動力伝達部材は、前記フォトカソードホルダーの中心軸から偏心した位置に配置されている
請求項1乃至5のいずれか一項に記載の電子線発生装置。 - 前記真空チャンバー内に配置され、かつ、第1方向に沿って延在するガイド部材を更に具備し、
前記ガイド部材は、前記チャンバー内動力伝達部材の前記第1方向に沿う移動を案内する
請求項1乃至6のいずれか一項に記載の電子線発生装置。 - 前記チャンバー内動力伝達部材は、
回転部材と、
前記回転部材の回転を、前記フォトカソードホルダーまたは前記活性化容器の直線移動に変換する変換機構と
を有する
請求項1乃至7のいずれか一項に記載の電子線発生装置。 - 前記真空チャンバー内に配置されたアノードと、
前記真空チャンバー内の突起物からの放電の発生を抑制するシールドと
を更に具備し、
前記シールドは、前記アノードと、前記チャンバー内動力伝達部材の少なくとも一部との間に配置されている
請求項1乃至8のいずれか一項に記載の電子線発生装置。 - 前記活性化容器は、
前記フォトカソード材料から放出される電子または前記フォトカソード材料が通過可能な第1孔と、
前記チャンバー内動力伝達部材が挿通される第2孔と
を有する
請求項1乃至9のいずれか一項に記載の電子線発生装置。 - 前記真空チャンバーは、伸縮部を含み、
前記伸縮部を伸縮させることにより、前記フォトカソードホルダーまたは前記活性化容器が移動する
請求項1乃至10のいずれか一項に記載の電子線発生装置。 - 前記伸縮部は、前記真空チャンバーの胴部の一部を構成しているか、あるいは、前記真空チャンバーの頂部に取り付けられている
請求項11に記載の電子線発生装置。 - 前記チャンバー内動力伝達部材を駆動する熱エネルギーを生成するエネルギー生成部を更に具備する
請求項1に記載の電子線発生装置。 - 請求項1乃至13のいずれか一項に記載の電子線発生装置を含む電子線適用装置であって、
前記電子線適用装置は、
電子銃、
自由電子レーザー加速器、
電子顕微鏡、
電子線ホログラフィー装置、
電子線描画装置、
電子線回折装置、
電子線検査装置、
電子線金属積層造形装置、
電子線リソグラフィー装置、
電子線加工装置、
電子線硬化装置、
電子線滅菌装置、
電子線殺菌装置、
プラズマ発生装置、
原子状元素発生装置、
スピン偏極電子線発生装置、
カソードルミネッセンス装置、または、
逆光電子分光装置
である
電子線適用装置。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201880021419.1A CN110462780B (zh) | 2017-04-05 | 2018-03-30 | 电子射线产生装置以及电子射线应用装置 |
EP18781434.8A EP3608939A4 (en) | 2017-04-05 | 2018-03-30 | ELECTRONIC RADIATOR AND DEVICE FOR APPLYING ELECTRONIC BEAMS |
KR1020197030987A KR102327112B1 (ko) | 2017-04-05 | 2018-03-30 | 전자선 발생 장치, 및, 전자선 적용 장치 |
US16/500,789 US11302507B2 (en) | 2017-04-05 | 2018-03-30 | Electron beam generator and electron beam applicator |
JP2019500602A JP6501285B2 (ja) | 2017-04-05 | 2018-03-30 | 電子線発生装置、および、電子線適用装置 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017075602 | 2017-04-05 | ||
JP2017-075602 | 2017-04-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2018186294A1 true WO2018186294A1 (ja) | 2018-10-11 |
Family
ID=63713131
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2018/013640 WO2018186294A1 (ja) | 2017-04-05 | 2018-03-30 | 電子線発生装置、および、電子線適用装置 |
Country Status (6)
Country | Link |
---|---|
US (1) | US11302507B2 (ja) |
EP (1) | EP3608939A4 (ja) |
JP (1) | JP6501285B2 (ja) |
KR (1) | KR102327112B1 (ja) |
CN (1) | CN110462780B (ja) |
WO (1) | WO2018186294A1 (ja) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020194445A1 (ja) * | 2019-03-25 | 2020-10-01 | 株式会社ニコン | 加工システム |
WO2020250604A1 (ja) | 2019-06-10 | 2020-12-17 | 株式会社Photo electron Soul | 電子銃、電子線適用装置、および、電子銃の制御方法 |
WO2021033519A1 (ja) | 2019-08-20 | 2021-02-25 | 株式会社Photo electron Soul | フォトカソードキット、電子銃および電子線適用装置 |
WO2021059918A1 (ja) | 2019-09-24 | 2021-04-01 | 株式会社Photo electron Soul | 電子銃、電子線適用装置、フォトカソードから射出された電子ビームの射出軸確認方法、および、フォトカソードから射出された電子ビームの射出軸合わせ方法 |
KR20210118223A (ko) * | 2019-02-17 | 2021-09-29 | 케이엘에이 코포레이션 | 자외선 및 가시광선 파장의 플라즈몬 포토캐소드 이미터 |
TWI741685B (zh) * | 2019-08-02 | 2021-10-01 | 大陸商中微半導體設備(上海)股份有限公司 | 等離子體刻蝕設備 |
WO2021210382A1 (ja) | 2020-04-16 | 2021-10-21 | 株式会社Photo electron Soul | 電子銃、電子線適用装置、および、電子ビームの射出方法 |
JP2022518886A (ja) * | 2019-01-29 | 2022-03-17 | フリーメルト エービー | 付加製造方法およびビームダンプを用いた装置 |
US11842879B2 (en) | 2020-09-09 | 2023-12-12 | Photo Electron Soul Inc. | Electron gun, electron gun component, electron beam applicator, and alignment method |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6744694B1 (ja) * | 2019-12-03 | 2020-08-19 | 株式会社ソディック | 表面改質装置および表面改質方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS588021B2 (ja) | 1974-05-03 | 1983-02-14 | スペクトラ フイジツクス インコ−ポレ−テツド | フゴウラベルオヨミトルホウホウ オヨビソウチ |
JPH09298032A (ja) * | 1996-04-30 | 1997-11-18 | Hamamatsu Photonics Kk | 電子ビーム発生装置 |
WO2002001597A1 (fr) * | 2000-06-27 | 2002-01-03 | Ebara Corporation | Appareil d'inspection a faisceau de particules chargees et procede de fabrication d'un dispositif utilisant cet appareil d'inspection |
JP2015022810A (ja) * | 2013-07-16 | 2015-02-02 | 国立大学法人名古屋大学 | 電子親和力の低下処理装置に用いられる活性化容器及びキット、該キットを含む電子親和力の低下処理装置、フォトカソード電子ビーム源、並びに、フォトカソード電子ビーム源を含む電子銃、自由電子レーザー加速器、透過型電子顕微鏡、走査型電子顕微鏡、電子線フォログラフィー顕微鏡、電子線描画装置、電子線回折装置及び電子線検査装置 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4969556A (en) * | 1988-05-10 | 1990-11-13 | Hajime Ishimaru | Vacuum container |
KR101377106B1 (ko) | 2005-02-17 | 2014-03-25 | 가부시키가이샤 에바라 세이사꾸쇼 | 전자선장치 |
CN101726161A (zh) | 2008-10-30 | 2010-06-09 | 上海舒博拉尼制药设备有限公司 | 一种冻干机全自动在线取样的方法 |
JP5918999B2 (ja) * | 2012-01-06 | 2016-05-18 | 株式会社日立ハイテクノロジーズ | 真空容器を備えた荷電粒子線照射装置 |
GB2517671A (en) * | 2013-03-15 | 2015-03-04 | Nikon Metrology Nv | X-ray source, high-voltage generator, electron beam gun, rotary target assembly, rotary target and rotary vacuum seal |
JP6264145B2 (ja) * | 2014-03-28 | 2018-01-24 | 株式会社島津製作所 | X線発生装置 |
JP2016021344A (ja) * | 2014-07-15 | 2016-02-04 | 中外炉工業株式会社 | プラズマ処理装置、及びそのプラズマ処理装置を用いたプラズマ処理方法 |
CN104851768B (zh) | 2015-04-15 | 2017-01-25 | 南京康众光电科技有限公司 | 一种静态多源冷阴极x射线仪 |
-
2018
- 2018-03-30 KR KR1020197030987A patent/KR102327112B1/ko active IP Right Grant
- 2018-03-30 WO PCT/JP2018/013640 patent/WO2018186294A1/ja active Search and Examination
- 2018-03-30 JP JP2019500602A patent/JP6501285B2/ja active Active
- 2018-03-30 EP EP18781434.8A patent/EP3608939A4/en active Pending
- 2018-03-30 US US16/500,789 patent/US11302507B2/en active Active
- 2018-03-30 CN CN201880021419.1A patent/CN110462780B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS588021B2 (ja) | 1974-05-03 | 1983-02-14 | スペクトラ フイジツクス インコ−ポレ−テツド | フゴウラベルオヨミトルホウホウ オヨビソウチ |
JPH09298032A (ja) * | 1996-04-30 | 1997-11-18 | Hamamatsu Photonics Kk | 電子ビーム発生装置 |
WO2002001597A1 (fr) * | 2000-06-27 | 2002-01-03 | Ebara Corporation | Appareil d'inspection a faisceau de particules chargees et procede de fabrication d'un dispositif utilisant cet appareil d'inspection |
JP2015022810A (ja) * | 2013-07-16 | 2015-02-02 | 国立大学法人名古屋大学 | 電子親和力の低下処理装置に用いられる活性化容器及びキット、該キットを含む電子親和力の低下処理装置、フォトカソード電子ビーム源、並びに、フォトカソード電子ビーム源を含む電子銃、自由電子レーザー加速器、透過型電子顕微鏡、走査型電子顕微鏡、電子線フォログラフィー顕微鏡、電子線描画装置、電子線回折装置及び電子線検査装置 |
Non-Patent Citations (2)
Title |
---|
MRS-J NEWS, vol. 20, no. 2, May 2008 (2008-05-01) |
See also references of EP3608939A4 |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7485309B2 (ja) | 2019-01-29 | 2024-05-16 | フリーメルト エービー | 付加製造方法およびビームダンプを用いた装置 |
JP2022518886A (ja) * | 2019-01-29 | 2022-03-17 | フリーメルト エービー | 付加製造方法およびビームダンプを用いた装置 |
KR20210118223A (ko) * | 2019-02-17 | 2021-09-29 | 케이엘에이 코포레이션 | 자외선 및 가시광선 파장의 플라즈몬 포토캐소드 이미터 |
KR102615663B1 (ko) | 2019-02-17 | 2023-12-19 | 케이엘에이 코포레이션 | 자외선 및 가시광선 파장의 플라즈몬 포토캐소드 이미터 |
US11495428B2 (en) * | 2019-02-17 | 2022-11-08 | Kla Corporation | Plasmonic photocathode emitters at ultraviolet and visible wavelengths |
JP7396349B2 (ja) | 2019-03-25 | 2023-12-12 | 株式会社ニコン | 加工システム |
WO2020194445A1 (ja) * | 2019-03-25 | 2020-10-01 | 株式会社ニコン | 加工システム |
JPWO2020194445A1 (ja) * | 2019-03-25 | 2020-10-01 | ||
WO2020250604A1 (ja) | 2019-06-10 | 2020-12-17 | 株式会社Photo electron Soul | 電子銃、電子線適用装置、および、電子銃の制御方法 |
TWI741685B (zh) * | 2019-08-02 | 2021-10-01 | 大陸商中微半導體設備(上海)股份有限公司 | 等離子體刻蝕設備 |
EP3951831A4 (en) * | 2019-08-20 | 2022-06-22 | Photo Electron Soul Inc. | PHOTOCATHODE SET, ELECTRON GUN AND ELECTRON BEAM APPLICATION DEVICE |
WO2021033519A1 (ja) | 2019-08-20 | 2021-02-25 | 株式会社Photo electron Soul | フォトカソードキット、電子銃および電子線適用装置 |
WO2021059918A1 (ja) | 2019-09-24 | 2021-04-01 | 株式会社Photo electron Soul | 電子銃、電子線適用装置、フォトカソードから射出された電子ビームの射出軸確認方法、および、フォトカソードから射出された電子ビームの射出軸合わせ方法 |
US12080507B2 (en) | 2019-09-24 | 2024-09-03 | Photo Electron Soul Inc. | Electron gun, electron beam applicator, emission axis verification method for electron beam emitted from photocathode, and emission axis alignment method for electron beam emitted from photocathode |
WO2021210382A1 (ja) | 2020-04-16 | 2021-10-21 | 株式会社Photo electron Soul | 電子銃、電子線適用装置、および、電子ビームの射出方法 |
US11842879B2 (en) | 2020-09-09 | 2023-12-12 | Photo Electron Soul Inc. | Electron gun, electron gun component, electron beam applicator, and alignment method |
Also Published As
Publication number | Publication date |
---|---|
EP3608939A1 (en) | 2020-02-12 |
JP6501285B2 (ja) | 2019-04-17 |
JPWO2018186294A1 (ja) | 2019-06-27 |
US20210035766A1 (en) | 2021-02-04 |
KR20190128699A (ko) | 2019-11-18 |
KR102327112B1 (ko) | 2021-11-16 |
EP3608939A4 (en) | 2020-03-25 |
CN110462780A (zh) | 2019-11-15 |
CN110462780B (zh) | 2022-05-06 |
US11302507B2 (en) | 2022-04-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2018186294A1 (ja) | 電子線発生装置、および、電子線適用装置 | |
JP5808021B2 (ja) | 電子親和力の低下処理装置に用いられる活性化容器及びキット、該キットを含む電子親和力の低下処理装置、フォトカソード電子ビーム源、並びに、フォトカソード電子ビーム源を含む電子銃、自由電子レーザー加速器、透過型電子顕微鏡、走査型電子顕微鏡、電子線ホログラフィー顕微鏡、電子線描画装置、電子線回折装置及び電子線検査装置 | |
EP3618094B1 (en) | X-ray tube and x-ray generation device | |
CN104364876B (zh) | X射线辐射源及其应用和用于产生x射线辐射的方法 | |
JP2010186694A (ja) | X線源、x線発生方法およびx線源製造方法。 | |
JPWO2019077970A1 (ja) | イオン源及びイオン注入装置 | |
CN113692634B (zh) | 光电阴极套组、电子枪及电子射线应用装置 | |
TWI696206B (zh) | 電子射線產生裝置以及電子射線應用裝置 | |
CN115380355A (zh) | 电子枪、电子射线应用装置以及电子束的射出方法 | |
JP5441235B2 (ja) | 回転ターゲット式電子線補助照射レーザアブレーション成膜装置及び回転ターゲット式電子線照射成膜装置 | |
JP2011233498A (ja) | プラズマ光源とプラズマ光発生方法 | |
JP7319865B2 (ja) | カソード | |
TW201101363A (en) | A compound anode target material for X-ray tubes with micro-generation of X-rays without utilizing the micro-focused e-beam to achieve micro X-ray focal emissions | |
TW202228178A (zh) | 電子槍、電子槍用元件、電子射線應用裝置及對位方法 | |
JP2014186943A (ja) | 集束イオンビーム装置 | |
JP3438024B2 (ja) | 真空蒸着装置における蒸発源及びその加熱方法 | |
JP2012140711A (ja) | 回転ターゲット式電子線補助照射レーザアブレーション成膜装置及び回転ターゲット式電子線照射成膜装置 | |
JP2012191113A (ja) | プラズマ光源及びプラズマ光源の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 18781434 Country of ref document: EP Kind code of ref document: A1 |
|
DPE1 | Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101) | ||
ENP | Entry into the national phase |
Ref document number: 2019500602 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 20197030987 Country of ref document: KR Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2018781434 Country of ref document: EP Effective date: 20191105 |