WO2018161612A1 - 一种氧化石墨烯丙纶耐热高强复合型材及其制备方法 - Google Patents
一种氧化石墨烯丙纶耐热高强复合型材及其制备方法 Download PDFInfo
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- WO2018161612A1 WO2018161612A1 PCT/CN2017/108498 CN2017108498W WO2018161612A1 WO 2018161612 A1 WO2018161612 A1 WO 2018161612A1 CN 2017108498 W CN2017108498 W CN 2017108498W WO 2018161612 A1 WO2018161612 A1 WO 2018161612A1
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- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
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- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/02—Layered products comprising a layer of synthetic resin in the form of fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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- B32—LAYERED PRODUCTS
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
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- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
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- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
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- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
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- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
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- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/52—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads thermal insulating, e.g. heating or cooling
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- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
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- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/56—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
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- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D23/00—General weaving methods not special to the production of any particular woven fabric or the use of any particular loom; Weaves not provided for in any other single group
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/12—Polypropene
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- C08L2201/00—Properties
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
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Definitions
- the invention belongs to the field of composite profiles, and in particular relates to a graphene oxide polypropylene heat-resistant high-strength composite profile and a preparation method thereof.
- Graphene Since the day when graphene was discovered, it has become a research hotspot, and has been widely used in fields such as supercapacitors, transparent electrodes, desalination, solar cells, and composite materials.
- Graphene consists of a carbon atom with a sp2 hybrid orbital to form a hexagonal honeycomb lattice. Its structural unit is a carbon six-membered ring, which is a two-dimensional material with a single layer of carbon atom thickness.
- Graphene has excellent mechanical, electrical and thermal properties.
- Polypropylene fiber referred to as polypropylene fiber, has the characteristics of low melting point, chemical corrosion resistance, high heat distortion temperature, etc. It is a common base material for thermoplastic composite materials. Graphene oxide polypropylene heat-resistant high-strength composite profiles can overcome some defects of a single polymer, impart special physical and chemical properties to the polymer, improve the overall performance of the polymer, and broaden the application field of the polymer. In order to obtain a polypropylene-based continuous fiber reinforced woven composite material with good forming effect.
- the present invention provides a graphene oxide polypropylene heat-resistant high-strength composite profile and a preparation method thereof.
- a graphene oxide polypropylene heat-resistant high-strength composite profile is a graphene oxide polypropylene-based reinforced plain weave composite resin material, which is made of a graphene oxide polypropylene machine plain weave fabric and a fiber heat insulating material. Layered spacer structure composite flat net, and finally resistant to resin composites
- the hot high-strength composite profile wherein the graphene oxide polypropylene machine plain weave fabric uses graphene oxide polypropylene filament fiber, and the graphene oxide has a weight percentage of 0.3-0.7% in the polypropylene filament fiber.
- Step 1 Preparation of a plain woven tissue fabric of graphene oxide polypropylene base machine: the graphene woven fabric of the graphene oxide polypropylene base fabric adopts graphene oxide polypropylene filament fiber, and the weight percentage of graphene oxide in the polypropylene fiber is 0.3-0.7%.
- the graphene oxide polypropylene multifilament is used as the warp and weft yarn, and the weaving is 45 -55 pieces / 5cm, weft density 30-40 pieces / 5cm plain weave, square meter weight is 500-700g / m2, thickness 0.06-0.20mm;
- Step 2 Preparation of graphene oxide polypropylene-based reinforced plain weave composite material:
- the insulating material is made into several flat nets of different thicknesses and densities, the heat insulation layer square weight is 150-220 g/m2, and the thickness is 0.10-0.25. Mm;
- a graphene woven polypropylene base machine plain weave cloth is coated thereon, and a non-woven net material is formed by dry-laid and needle-punching;
- the heat insulating layer material is asbestos, rock wool, glass fiber, silicon One or more of an alumina fiber, a high silica fiber, and an alumina fiber;
- Step 3 Preparation of a multi-layer graphene oxide polypropylene-based reinforced plain weave composite material: the multi-layer graphene oxide polypropylene-based reinforced plain weave composite material has two or more layers, and the main purpose is to increase the internal graphene oxide polypropylene of the composite material.
- Content through the needling reinforcement, the graphene oxide polypropylene-based reinforced plain weave composite material is subjected to positive and negative 2 times needling reinforcement, the needle density is 90-130 thorn/cm 2 , and the needle punching frequency is 220-280 thorn/min, first The secondary needle density was 2500 pieces/m, the second needle density was 2500 pieces/m, and the speed of the needle-punched fiber net was 1.8-2.0 m/min;
- Step 4 Preparation of resin composite material: the resin composite material is epoxy resin, and the epoxy resin and the curing agent are weighed according to a mass ratio of 2:1, preheated at 45-60 ° C for 10 min, and the epoxy resin quality is added. a 3-5% silane coupling agent and a 3-5% graphene oxide N-methylpyrrolidone dispersion (0.5%), stirred for 10 minutes, and vacuumed at 45-60 ° C for 30-40 minutes to remove bubbles in the epoxy resin; Adding 1-2% of the accelerator and acetone in the epoxy resin, stirring and mixing uniformly, immersing the multilayer graphene oxide polypropylene-based reinforced plain weave composite material, adding 40% of the epoxy resin mass fraction.
- Curing agent fully stirred, vacuum at 45-60 ° C for 30-40min, remove air bubbles; put into the blast drying oven: normal temperature 2h, then the temperature is 95 ° C-120 ° C for 4h to cure, finally get graphene oxide polypropylene Heat resistant high strength composite profiles.
- the curing agent added is one or more of a fatty amine, an aromatic, an aliphatic ring, a modified amine, an acid anhydride, a low molecular polyamide, and a latent amine curing agent.
- the silane coupling agent added is one or more of a silane coupling agent KH-560, a silane coupling agent A-172, and a composite aluminum titanium coupling agent.
- the epoxy accelerator added is one or more of the epoxy accelerator XH-610, the epoxy accelerator DMP-30, the BASF E-6623, and the epoxy curing accelerator EM-7604H.
- the epoxy accelerator XH-610 is one or more of the epoxy accelerator XH-610, the epoxy accelerator DMP-30, the BASF E-6623, and the epoxy curing accelerator EM-7604H.
- the epoxy accelerator XH-610 is one or more of the epoxy accelerator XH-610, the epoxy accelerator DMP-30, the BASF E-6623, and the epoxy curing accelerator EM-7604H.
- the graphene oxide polypropylene in the invention has excellent temperature resistance, heat transfer and high strength compared with the conventional polypropylene, and the impact resistance is also improved.
- the graphene oxide polypropylene fiber of the invention contains graphene oxide, and the graphene oxide on the surface of the fiber is easily anchored with the epoxy resin, thereby strengthening the combination of the multilayer graphene oxide polypropylene-based reinforced plain weave composite material and the resin.
- the silane coupling agent and the graphene oxide N-methylpyrrolidone dispersion in the epoxy resin are silane-modified on the graphene oxide in the resin to enhance the silane-modified graphene oxide and the multi-layer graphite oxide in the resin.
- a graphene oxide polypropylene heat-resistant high-strength composite profile wherein the composite profile is a graphene oxide polypropylene-based reinforced plain weave composite resin material, which is a layered interval of a graphene-based polypropylene-based plain weave fabric and a fiber heat insulating material. a composite composite flat net, and finally a heat-resistant high-strength composite profile made of a resin composite material, wherein the graphene oxide polypropylene machine plain weave fabric uses graphene oxide polypropylene filament fiber, and graphene oxide in polypropylene filament fiber The weight percentage is 0.3%.
- Step 1 Preparation of plain graph fabric of graphene oxide polypropylene machine:
- the graphene-based polypropylene machine plain weave fabric adopts graphene oxide polypropylene filament fiber, and the weight percentage of graphene oxide in polypropylene fiber is 0.3%, 210D, 24F; through the winding, twisting, twisting, shaping, warping, sizing, parallel shaft, piercing and warp, weaving and weaving process, the graphene oxide polypropylene multifilament is used as the warp and weft yarn, and the weaving is 45 pieces/ 5cm, weft density 30 / 5cm plain weave, square weight of 500g / m2, thickness 0.06mm.
- Step 2 Preparation of graphene oxide polypropylene-based reinforced plain weave composite material: the insulating material is made into several flat nets of different thicknesses and densities, the heat insulation layer square weight is 150g/m2, the thickness is 0.10mm; The plain polypropylene fabric machine is covered with a plain weave fabric, and the non-woven mesh material is dry-laid and needle-punched; the insulating layer material is asbestos, rock wool, glass fiber, aluminum silicate fiber, One or more of high silica fibers and alumina fibers.
- Step 3 Preparation of a multi-layer graphene oxide polypropylene-based reinforced plain weave composite material: the multi-layer graphene oxide polypropylene-based reinforced plain weave composite material has two or more layers, and the main purpose is to increase the internal graphene oxide polypropylene of the composite material.
- the graphene oxide polypropylene-based reinforced plain weave composite material was strengthened by positive and negative needle acupuncture, the needle density was 90 thorns/cm 2 , the needle punching frequency was 220 thorns/min, and the first needle density was It is 2500 pieces/m, the second needle density is 2500 pieces/m, and the speed of the needle-punched fiber net is 1.8m/min.
- Step 4 Preparation of resin composite material: the resin composite material is epoxy resin, and the epoxy resin and the curing agent are weighed according to a mass ratio of 2:1, preheated at 45 ° C for 10 min, and the epoxy resin mass fraction is 3%. Silane coupling agent and mass fraction 3% graphene oxide N-methylpyrrolidone dispersion (0.5%), stirring for 10min, vacuuming at 45 °C for 30min, removing bubbles in epoxy resin; adding epoxy resin quality in epoxy resin A 1% accelerator and acetone are mixed and mixed uniformly.
- the multilayer graphene oxide polypropylene-based reinforced plain weave composite material is immersed, and the curing agent with 40% epoxy resin content is added, and the mixture is fully stirred, and vacuum is applied at 45 ° C for 30 min. Remove air bubbles; put into a blast drying oven: at room temperature for 2h, then cure at a temperature of 95 °C for 4h, and finally obtain a graphene oxide polypropylene heat-resistant high-strength composite profile;
- the added curing agent is a fatty amine, aromatic, fat ring One or more of a class, a modified amine, an acid anhydride, a low molecular polyamide, and a latent amine curing agent;
- the silane coupling agent added is a silane coupling agent KH-560, a silane coupling agent A-172, One or more of the combined aluminum-titanium coupling agents;
- the epoxy accelerator added is epoxy accelerator XH-610, epoxy accelerator DMP-30, BASF E-6623, epoxy
- a graphene oxide polypropylene heat-resistant high-strength composite profile wherein the composite profile is a graphene oxide polypropylene-based reinforced plain weave composite resin material, which is a layered interval of a graphene-based polypropylene-based plain weave fabric and a fiber heat insulating material. a composite composite flat net, and finally a heat-resistant high-strength composite profile made of a resin composite material, wherein the graphene oxide polypropylene machine plain weave fabric uses graphene oxide polypropylene filament fiber, and graphene oxide in polypropylene filament fiber The weight percentage is 0.7%.
- Step 1 Preparation of a plain woven tissue of a graphene oxide polypropylene machine: the graphene woven polypropylene base woven fabric is made of graphene oxide polypropylene filament fiber, and the weight percentage of graphene oxide in the polypropylene fiber is 0.7%, 210D, 24F; through the winding, twisting, twisting, shaping, warping, sizing, parallel shaft, piercing and warp, weaving and weaving process, the graphene oxide polypropylene multifilament is used as the warp and weft yarn, and the weaving is 55 pieces. 5cm, weft density 40 / 5cm plain weave, square weight of 700g / m2, thickness of 0.20mm.
- Step 2 Preparation of graphene oxide polypropylene-based reinforced plain weave composite material:
- the insulating material is made into several flat nets of different thicknesses and densities, and the heat insulation layer has a square weight of 220 g/m 2 and a thickness of 0.25 mm;
- the plain polypropylene fabric machine is covered with a plain weave fabric, and the non-woven mesh material is dry-laid and needle-punched;
- the insulating layer material is asbestos, rock wool, glass fiber, aluminum silicate fiber, One or more of high silica fibers and alumina fibers.
- Step 3 Preparation of a multi-layer graphene oxide polypropylene-based reinforced plain weave composite material: the multi-layer graphene oxide polypropylene-based reinforced plain weave composite material has two or more layers, and the main purpose is to increase the internal graphene oxide polypropylene of the composite material.
- the graphene oxide polypropylene-based reinforced plain weave composite material was strengthened by positive and negative needle acupuncture, the needle density was 130 thorns/cm 2 , the needle punching frequency was 280 thorns/min, and the first needle density was It is 2500 pieces/m, the second needle density is 2500 pieces/m, and the speed of the needle-punched fiber net is 2.0m/min.
- Step 4 Preparation of resin composite material: the resin composite material is epoxy resin, and the epoxy resin and the curing agent are weighed according to a mass ratio of 2:1, preheated at 60 ° C for 10 min, and the epoxy resin mass fraction is added 3 - 5% silane coupling agent and mass fraction 5% graphene oxide N-methylpyrrolidone dispersion (0.5%), stirred for 10 min, vacuumed at 45-60 ° C for 40 min to remove bubbles in the epoxy resin; Epoxy resin mass fraction 2% accelerator, acetone, stir and mix evenly, immerse the multilayer graphene oxide polypropylene-based reinforced plain weave composite material, add 40% epoxy resin foaming agent, stir well Mix well, vacuum at 60 °C for 40min, remove air bubbles; put into the blast drying oven: at room temperature for 2h, then cure at 120 °C for 4h, finally obtain graphene oxide polypropylene heat-resistant high-strength composite profile; the added curing agent is One or more of a fatty amine, an aromatic
- a graphene oxide polypropylene heat-resistant high-strength composite profile wherein the composite profile is a graphene oxide polypropylene-based reinforced plain weave composite resin material, which is a layered interval of a graphene-based polypropylene-based plain weave fabric and a fiber heat insulating material. a composite composite flat net, and finally a heat-resistant high-strength composite profile made of a resin composite material, wherein the graphene oxide polypropylene machine plain weave fabric uses graphene oxide polypropylene filament fiber, and graphene oxide in polypropylene filament fiber The weight percentage is 0.4%.
- Step 1 Preparation of plain graph fabric of graphene oxide polypropylene base machine: the graphene-based polypropylene base machine plain weave fabric adopts graphene oxide polypropylene filament fiber, and the weight percentage of graphene oxide in polypropylene fiber is 0.4%, 210D, 24F; through the winding, twisting, twisting, shaping, warping, sizing, parallel shaft, piercing and warp, weaving and weaving process, using graphene oxide polypropylene multifilament as warp and weft yarn, weaving warp 49 5cm, weft density 36 / 5cm plain weave, square weight gram weight 600g / m2, thickness 0.10mm.
- Step 2 Preparation of graphene oxide polypropylene-based reinforced plain weave composite material:
- the insulating material is made into several flat nets of different thicknesses and densities, the heat insulation layer square weight is 190 g/m2, the thickness is 0.20 mm;
- Graphene polypropylene base machine plain weave fabric is covered on it, and it is dry-laid and needle-punched.
- the non-woven fabric material; the heat insulating layer material is one or more of asbestos, rock wool, glass fiber, aluminum silicate fiber, high silica fiber and alumina fiber.
- Step 3 Preparation of a multi-layer graphene oxide polypropylene-based reinforced plain weave composite material: the multi-layer graphene oxide polypropylene-based reinforced plain weave composite material has two or more layers, and the main purpose is to increase the internal graphene oxide polypropylene of the composite material.
- Content through the needling reinforcement, the graphene oxide polypropylene-based reinforced plain weave composite material was strengthened by positive and negative needle acupuncture, the needle density was 110 thorns/cm 2 , the needle punching frequency was 270 thorns/min, and the first needle density was It is 2500 pieces/m, the second needle density is 2500 pieces/m, and the speed of the needle-punched fiber net is 1.9m/min.
- Step 4 Preparation of resin composite material: the resin composite material is epoxy resin, and the epoxy resin and the curing agent are weighed according to a mass ratio of 2:1, preheated at 52 ° C for 10 min, and the epoxy resin mass fraction is 4%. Silane coupling agent and mass fraction of 4% graphene oxide N-methylpyrrolidone dispersion (0.5%), stirring for 10min, vacuuming at 52 °C for 36min, removing bubbles in epoxy resin; adding epoxy resin quality in epoxy resin The 1.5% accelerator and acetone were mixed and mixed uniformly. The multilayer graphene oxide polypropylene-based reinforced plain weave composite was immersed, and the curing agent with 40% epoxy resin content was added. The mixture was fully stirred and vacuumed at 54 ° C for 37 min.
- the bubbles are removed; placed in a blast drying oven: at room temperature for 2 h, and then cured at a temperature of 110 ° C for 4 h to finally obtain a graphene oxide polypropylene heat-resistant high-strength composite profile;
- the added curing agent is a fatty amine, aromatic, fat ring One or more of a class, a modified amine, an acid anhydride, a low molecular polyamide, and a latent amine curing agent;
- the silane coupling agent added is a silane coupling agent KH-560, a silane coupling agent A-172 One or more of the composite aluminum-titanium coupling agents;
- the epoxy accelerator added is epoxy accelerator XH-610, epoxy accelerator DMP-30, BASF E-6623, epoxy curing accelerator EM-7604H One or more of them.
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Abstract
本发明公开了一种氧化石墨烯丙纶耐热高强复合型材及其制备方法,所述复合型材是氧化石墨烯丙纶基增强平纹组织复合树脂材料,是氧化石墨烯丙纶基机平纹组织织布与纤维隔热材料制成层连间隔结构复合平网,最终与树脂复合材料制成的耐热高强复合型材。其制备方法包括如下步骤:氧化石墨烯丙纶基机平纹组织织布制备;氧化石墨烯丙纶基增强平纹组织复合材料制备;多层氧化石墨烯丙纶基增强平纹组织复合材料制备;树脂复合材料制备。本发明操作方便,性能优异,由于氧化石墨烯丙纶具有优异耐温性和传热性,耐温温度进一步提高,抗冲击性能也同时提高,从而获得性能优异的复合型材。
Description
本发明属于复合型材领域,具体涉及一种氧化石墨烯丙纶耐热高强复合型材及其制备方法。
从石墨烯发现那一天起,已经成为研究热点,在超级电容、透明电极、海水淡化、太阳能电池、复合材料等领域有广泛应用。石墨烯由碳原子以sp2杂化轨道组成六角型蜂巢晶格,其结构单元为碳六元环,是一种只有单层碳原子厚度的二维材料。石墨烯具有优异的机械、电学和热学性能。氧化石墨烯是石墨烯派生物,与石墨烯结构大体相同,氧化石墨烯含有羟基—OH、羧基—COOH、羰基C=O等官能团,可以与其它化学基团进行共价反应。
聚丙烯纤维,简称丙纶,具有熔点低、耐化学腐蚀、热变形温度高等特点,是热塑性复合材料的常用基体材料。氧化石墨烯丙纶耐热高强复合型材可以克服单一聚合物的一些缺陷,赋予聚合物特殊的物化性能,改善聚合物的综合性能,扩宽聚合物的应用领域。以期得到成型效果良好的丙纶基连续纤维增强机织复合材料。
发明内容
发明目的:本发明提供一种氧化石墨烯丙纶耐热高强复合型材及其制备方法。
技术方案:一种氧化石墨烯丙纶耐热高强复合型材,所述复合型材是氧化石墨烯丙纶基增强平纹组织复合树脂材料,是氧化石墨烯丙纶基机平纹组织织布与纤维隔热材料制成层连间隔结构复合平网,最终与树脂复合材料制成的耐
热高强复合型材,其中,所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶长丝纤维中氧化石墨烯重量百分比含量0.3-0.7%。
一种根据所述的氧化石墨烯丙纶耐热高强复合型材的制备方法,包括如下步骤:
步骤一、氧化石墨烯丙纶基机平纹组织织布制备:所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶纤维中氧化石墨烯重量百分比含量0.3-0.7%,210D,24F;通过络筒、并丝、捻丝、定型、整经、浆丝、并轴、穿结经、机织织造工序,以氧化石墨烯丙纶复丝为经纬纱线,织造经密45-55根/5cm,纬密30-40根/5cm的平纹组织,平方米克重为500-700g/㎡,厚度0.06-0.20mm;
步骤二、氧化石墨烯丙纶基增强平纹组织复合材料制备:将隔热材料,制成几种不同厚度与密度的平网,隔热层平方米克重为150-220g/㎡,厚度0.10-0.25mm;将氧化石墨烯丙纶基机平纹组织织布覆于其上,采用干法成网、针刺加固的方法非织造网材;所述隔热层材料为石棉、岩棉、玻璃纤维、硅酸铝纤维、高硅氧纤维和氧化铝纤维中的一种或几种;
步骤三、多层氧化石墨烯丙纶基增强平纹组织复合材料制备:所述多层氧化石墨烯丙纶基增强平纹组织复合材料为两层或两层以上,主要目的为增加复合材料内部氧化石墨烯丙纶含量;通过针刺加固将氧化石墨烯丙纶基增强平纹组织复合材料进行正反2次针刺加固,针刺密度为90-130刺/cm2,针刺频率220-280刺/min,第一次植针密度为2500枚/m,第二次植针密度为2500枚/m,针刺纤网的速度分别为1.8-2.0m/min;
步骤四、树脂复合材料制备:所述树脂复合材料为环氧树脂,将环氧树脂和固化剂按照质量比2:1称取,在45-60℃下预热10min,加入环氧树脂质量
分数3-5%硅烷偶合剂及质量分数3-5%氧化石墨烯N-甲基吡咯烷酮分散液(0.5%),搅拌10min,45-60℃抽真空30-40min,去除环氧树脂中气泡;在环氧树脂中依次加入环氧树脂质量分数1-2%的促进剂、丙酮,搅拌混合均匀,将多层氧化石墨烯丙纶基增强平纹组织复合材料浸入,加入环氧树脂质量分数40%的固化剂,充分搅拌均匀,45-60℃抽真空30-40min,去除气泡;放入鼓风干燥箱中:常温2h,然后温度为95℃-120℃下4h进行固化,最终得到氧化石墨烯丙纶耐热高强复合型材。
作为优化:所述步骤四中,加入的固化剂为脂肪胺类、芳香族、脂肪环类、改性胺类、酸酐类、低分子聚酰胺和潜伏性胺固化剂其中一种或几种。
作为优化:所述步骤四中,加入的硅烷偶合剂为硅烷偶联剂KH-560、硅烷偶联剂A-172、复合型铝钛偶联剂其中一种或几种。
作为优化:所述步骤四中,加入的环氧促进剂为环氧促进剂XH-610、环氧促进剂DMP-30、巴斯夫E-6623、环氧固化促进剂EM-7604H其中一种或几种。
有益效果:本发明的具体优势如下:
1、本发明中的氧化石墨烯丙纶与传统丙纶相比具有优异耐温、传热、高强效果,抗冲击性能也同时提高。
2、本发明氧化石墨烯丙纶纤维中含有氧化石墨烯,纤维表面氧化石墨烯易与环氧树脂锚定,从而强化多层氧化石墨烯丙纶基增强平纹组织复合材料与树脂的结合。
3、本发明在环氧树脂中加入硅烷偶合剂及氧化石墨烯N-甲基吡咯烷酮分散液对树脂中的氧化石墨烯进行硅烷修饰,从而增强树脂中的硅烷修饰氧化石墨烯与多层氧化石墨烯丙纶基增强平纹组织复合材料锚定,起到协同双锚定的效果。
下面结合具体实施例对本发明进行详细阐述。
具体实施例一:
一种氧化石墨烯丙纶耐热高强复合型材,所述复合型材是氧化石墨烯丙纶基增强平纹组织复合树脂材料,是氧化石墨烯丙纶基机平纹组织织布与纤维隔热材料制成层连间隔结构复合平网,最终与树脂复合材料制成的耐热高强复合型材,其中,所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶长丝纤维中氧化石墨烯重量百分比含量0.3%。
一种根据所述的氧化石墨烯丙纶耐热高强复合型材的制备方法,包括如下步骤:
步骤一、氧化石墨烯丙纶基机平纹组织织布制备:所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶纤维中氧化石墨烯重量百分比含量0.3%,210D,24F;通过络筒、并丝、捻丝、定型、整经、浆丝、并轴、穿结经、机织织造工序,以氧化石墨烯丙纶复丝为经纬纱线,织造经密45根/5cm,纬密30根/5cm的平纹组织,平方米克重为500g/㎡,厚度0.06mm。
步骤二、氧化石墨烯丙纶基增强平纹组织复合材料制备:将隔热材料,制成几种不同厚度与密度的平网,隔热层平方米克重为150g/㎡,厚度0.10mm;将氧化石墨烯丙纶基机平纹组织织布覆于其上,采用干法成网、针刺加固的方法非织造网材;所述隔热层材料为石棉、岩棉、玻璃纤维、硅酸铝纤维、高硅氧纤维和氧化铝纤维中的一种或几种。
步骤三、多层氧化石墨烯丙纶基增强平纹组织复合材料制备:所述多层氧化石墨烯丙纶基增强平纹组织复合材料为两层或两层以上,主要目的为增加复合材料内部氧化石墨烯丙纶含量;通过针刺加固将氧化石墨烯丙纶基增强平纹
组织复合材料进行正反2次针刺加固,针刺密度为90刺/cm2,针刺频率220刺/min,第一次植针密度为2500枚/m,第二次植针密度为2500枚/m,针刺纤网的速度分别为1.8m/min。
步骤四、树脂复合材料制备:所述树脂复合材料为环氧树脂,将环氧树脂和固化剂按照质量比2:1称取,在45℃下预热10min,加入环氧树脂质量分数3%硅烷偶合剂及质量分数3%氧化石墨烯N-甲基吡咯烷酮分散液(0.5%),搅拌10min,45℃抽真空30min,去除环氧树脂中气泡;在环氧树脂中依次加入环氧树脂质量分数1%的促进剂、丙酮,搅拌混合均匀,将多层氧化石墨烯丙纶基增强平纹组织复合材料浸入,加入环氧树脂质量分数40%的固化剂,充分搅拌均匀,45℃抽真空30min,去除气泡;放入鼓风干燥箱中:常温2h,然后温度为95℃下4h进行固化,最终得到氧化石墨烯丙纶耐热高强复合型材;加入的固化剂为脂肪胺类、芳香族、脂肪环类、改性胺类、酸酐类、低分子聚酰胺和潜伏性胺固化剂其中一种或几种;加入的硅烷偶合剂为硅烷偶联剂KH-560、硅烷偶联剂A-172、复合型铝钛偶联剂其中一种或几种;加入的环氧促进剂为环氧促进剂XH-610、环氧促进剂DMP-30、巴斯夫E-6623、环氧固化促进剂EM-7604H其中一种或几种。
具体实施例二:
一种氧化石墨烯丙纶耐热高强复合型材,所述复合型材是氧化石墨烯丙纶基增强平纹组织复合树脂材料,是氧化石墨烯丙纶基机平纹组织织布与纤维隔热材料制成层连间隔结构复合平网,最终与树脂复合材料制成的耐热高强复合型材,其中,所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶长丝纤维中氧化石墨烯重量百分比含量0.7%。
一种根据所述的氧化石墨烯丙纶耐热高强复合型材的制备方法,包括如下
步骤:
步骤一、氧化石墨烯丙纶基机平纹组织织布制备:所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶纤维中氧化石墨烯重量百分比含量0.7%,210D,24F;通过络筒、并丝、捻丝、定型、整经、浆丝、并轴、穿结经、机织织造工序,以氧化石墨烯丙纶复丝为经纬纱线,织造经密55根/5cm,纬密40根/5cm的平纹组织,平方米克重为700g/㎡,厚度0.20mm。
步骤二、氧化石墨烯丙纶基增强平纹组织复合材料制备:将隔热材料,制成几种不同厚度与密度的平网,隔热层平方米克重为220g/㎡,厚度0.25mm;将氧化石墨烯丙纶基机平纹组织织布覆于其上,采用干法成网、针刺加固的方法非织造网材;所述隔热层材料为石棉、岩棉、玻璃纤维、硅酸铝纤维、高硅氧纤维和氧化铝纤维中的一种或几种。
步骤三、多层氧化石墨烯丙纶基增强平纹组织复合材料制备:所述多层氧化石墨烯丙纶基增强平纹组织复合材料为两层或两层以上,主要目的为增加复合材料内部氧化石墨烯丙纶含量;通过针刺加固将氧化石墨烯丙纶基增强平纹组织复合材料进行正反2次针刺加固,针刺密度为130刺/cm2,针刺频率280刺/min,第一次植针密度为2500枚/m,第二次植针密度为2500枚/m,针刺纤网的速度分别为2.0m/min。
步骤四、树脂复合材料制备:所述树脂复合材料为环氧树脂,将环氧树脂和固化剂按照质量比2:1称取,在60℃下预热10min,加入环氧树脂质量分数3-5%硅烷偶合剂及质量分数5%氧化石墨烯N-甲基吡咯烷酮分散液(0.5%),搅拌10min,45-60℃抽真空40min,去除环氧树脂中气泡;在环氧树脂中依次加入环氧树脂质量分数2%的促进剂、丙酮,搅拌混合均匀,将多层氧化石墨烯丙纶基增强平纹组织复合材料浸入,加入环氧树脂质量分数40%的固化剂,充分搅
拌均匀,60℃抽真空40min,去除气泡;放入鼓风干燥箱中:常温2h,然后温度为120℃下4h进行固化,最终得到氧化石墨烯丙纶耐热高强复合型材;加入的固化剂为脂肪胺类、芳香族、脂肪环类、改性胺类、酸酐类、低分子聚酰胺和潜伏性胺固化剂其中一种或几种;加入的硅烷偶合剂为硅烷偶联剂KH-560、硅烷偶联剂A-172、复合型铝钛偶联剂其中一种或几种;加入的环氧促进剂为环氧促进剂XH-610、环氧促进剂DMP-30、巴斯夫E-6623、环氧固化促进剂EM-7604H其中一种或几种。
具体实施例三:
一种氧化石墨烯丙纶耐热高强复合型材,所述复合型材是氧化石墨烯丙纶基增强平纹组织复合树脂材料,是氧化石墨烯丙纶基机平纹组织织布与纤维隔热材料制成层连间隔结构复合平网,最终与树脂复合材料制成的耐热高强复合型材,其中,所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶长丝纤维中氧化石墨烯重量百分比含量0.4%。
一种根据所述的氧化石墨烯丙纶耐热高强复合型材的制备方法,包括如下步骤:
步骤一、氧化石墨烯丙纶基机平纹组织织布制备:所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶纤维中氧化石墨烯重量百分比含量0.4%,210D,24F;通过络筒、并丝、捻丝、定型、整经、浆丝、并轴、穿结经、机织织造工序,以氧化石墨烯丙纶复丝为经纬纱线,织造经密49根/5cm,纬密36根/5cm的平纹组织,平方米克重为600g/㎡,厚度0.10mm。
步骤二、氧化石墨烯丙纶基增强平纹组织复合材料制备:将隔热材料,制成几种不同厚度与密度的平网,隔热层平方米克重为190g/㎡,厚度0.20mm;将氧化石墨烯丙纶基机平纹组织织布覆于其上,采用干法成网、针刺加固的方
法非织造网材;所述隔热层材料为石棉、岩棉、玻璃纤维、硅酸铝纤维、高硅氧纤维和氧化铝纤维中的一种或几种。
步骤三、多层氧化石墨烯丙纶基增强平纹组织复合材料制备:所述多层氧化石墨烯丙纶基增强平纹组织复合材料为两层或两层以上,主要目的为增加复合材料内部氧化石墨烯丙纶含量;通过针刺加固将氧化石墨烯丙纶基增强平纹组织复合材料进行正反2次针刺加固,针刺密度为110刺/cm2,针刺频率270刺/min,第一次植针密度为2500枚/m,第二次植针密度为2500枚/m,针刺纤网的速度分别为1.9m/min。
步骤四、树脂复合材料制备:所述树脂复合材料为环氧树脂,将环氧树脂和固化剂按照质量比2:1称取,在52℃下预热10min,加入环氧树脂质量分数4%硅烷偶合剂及质量分数4%氧化石墨烯N-甲基吡咯烷酮分散液(0.5%),搅拌10min,52℃抽真空36min,去除环氧树脂中气泡;在环氧树脂中依次加入环氧树脂质量分数1.5%的促进剂、丙酮,搅拌混合均匀,将多层氧化石墨烯丙纶基增强平纹组织复合材料浸入,加入环氧树脂质量分数40%的固化剂,充分搅拌均匀,54℃抽真空37min,去除气泡;放入鼓风干燥箱中:常温2h,然后温度为110℃下4h进行固化,最终得到氧化石墨烯丙纶耐热高强复合型材;加入的固化剂为脂肪胺类、芳香族、脂肪环类、改性胺类、酸酐类、低分子聚酰胺和潜伏性胺固化剂其中一种或几种;加入的硅烷偶合剂为硅烷偶联剂KH-560、硅烷偶联剂A-172、复合型铝钛偶联剂其中一种或几种;加入的环氧促进剂为环氧促进剂XH-610、环氧促进剂DMP-30、巴斯夫E-6623、环氧固化促进剂EM-7604H其中一种或几种。
本发明不局限于上述最佳实施方式,任何人在本发明的启示下都可得出其他各种形式的产品,但不论在其形状或结构上作任何变化,凡是具有与本申请相同或相近似的技术方案,均落在本发明的保护范围之内。
Claims (5)
- 一种氧化石墨烯丙纶耐热高强复合型材,其特征在于:所述复合型材是氧化石墨烯丙纶基增强平纹组织复合树脂材料,是氧化石墨烯丙纶基机平纹组织织布与纤维隔热材料制成层连间隔结构复合平网,最终与树脂复合材料制成的耐热高强复合型材,其中,所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶长丝纤维中氧化石墨烯重量百分比含量0.3-0.7%。
- 一种根据权利要求1所述的氧化石墨烯丙纶耐热高强复合型材的制备方法,其特征在于:包括如下步骤:步骤一、氧化石墨烯丙纶基机平纹组织织布制备:所述氧化石墨烯丙纶基机平纹组织织布采用氧化石墨烯丙纶长丝纤维,丙纶纤维中氧化石墨烯重量百分比含量0.3-0.7%,210D,24F;通过络筒、并丝、捻丝、定型、整经、浆丝、并轴、穿结经、机织织造工序,以氧化石墨烯丙纶复丝为经纬纱线,织造经密45-55根/5cm,纬密30-40根/5cm的平纹组织,平方米克重为500-700g/㎡,厚度0.06-0.20mm;步骤二、氧化石墨烯丙纶基增强平纹组织复合材料制备:将隔热材料,制成几种不同厚度与密度的平网,隔热层平方米克重为150-220g/㎡,厚度0.10-0.25mm;将氧化石墨烯丙纶基机平纹组织织布覆于其上,采用干法成网、针刺加固的方法非织造网材;所述隔热层材料为石棉、岩棉、玻璃纤维、硅酸铝纤维、高硅氧纤维和氧化铝纤维中的一种或几种;步骤三、多层氧化石墨烯丙纶基增强平纹组织复合材料制备:所述多层氧化石墨烯丙纶基增强平纹组织复合材料为两层或两层以上,主要目的为增加复合材料内部氧化石墨烯丙纶含量;通过针刺加固将氧化石墨烯丙纶基增强平纹组织复合材料进行正反2次针刺加固,针刺密度为90-130刺/cm2,针刺频率220-280刺/min,第一次植针密度为2500枚/m,第二次植针密度为2500枚/m, 针刺纤网的速度分别为1.8-2.0m/min;步骤四、树脂复合材料制备:所述树脂复合材料为环氧树脂,将环氧树脂和固化剂按照质量比2:1称取,在45-60℃下预热10min,加入环氧树脂质量分数3-5%硅烷偶合剂及质量分数3-5%氧化石墨烯N-甲基吡咯烷酮分散液(0.5%),搅拌10min,45-60℃抽真空30-40min,去除环氧树脂中气泡;在环氧树脂中依次加入环氧树脂质量分数1-2%的促进剂、丙酮,搅拌混合均匀,将多层氧化石墨烯丙纶基增强平纹组织复合材料浸入,加入环氧树脂质量分数40%的固化剂,充分搅拌均匀,45-60℃抽真空30-40min,去除气泡;放入鼓风干燥箱中:常温2h,然后温度为95℃-120℃下4h进行固化,最终得到氧化石墨烯丙纶耐热高强复合型材。
- 根据权利要求2所述的氧化石墨烯丙纶耐热高强复合型材的制备方法,其特征在于:所述步骤四中,加入的固化剂为脂肪胺类、芳香族、脂肪环类、改性胺类、酸酐类、低分子聚酰胺和潜伏性胺固化剂其中一种或几种。
- 根据权利要求2所述的氧化石墨烯丙纶耐热高强复合型材的制备方法,其特征在于:所述步骤四中,加入的硅烷偶合剂为硅烷偶联剂KH-560、硅烷偶联剂A-172、复合型铝钛偶联剂其中一种或几种。
- 根据权利要求2所述的氧化石墨烯丙纶耐热高强复合型材的制备方法,其特征在于:所述步骤四中,加入的环氧促进剂为环氧促进剂XH-610、环氧促进剂DMP-30、巴斯夫E-6623、环氧固化促进剂EM-7604H其中一种或几种。
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