WO2018097701A3 - 탈수소화 촉매 - Google Patents
탈수소화 촉매 Download PDFInfo
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- WO2018097701A3 WO2018097701A3 PCT/KR2018/001532 KR2018001532W WO2018097701A3 WO 2018097701 A3 WO2018097701 A3 WO 2018097701A3 KR 2018001532 W KR2018001532 W KR 2018001532W WO 2018097701 A3 WO2018097701 A3 WO 2018097701A3
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- WIPO (PCT)
- Prior art keywords
- catalyst
- dehydrogenation catalyst
- metal
- dehydrogenation
- decline
- Prior art date
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- 239000003054 catalyst Substances 0.000 title abstract 6
- 238000006356 dehydrogenation reaction Methods 0.000 title abstract 5
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 230000007423 decrease Effects 0.000 abstract 2
- 230000002708 enhancing effect Effects 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 239000000571 coke Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
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Abstract
본 발명은 지지체에 백금족 금속, 보조금속, 알칼리 금속 또는 알칼리 토금속 성분이 담지된 탈수소화 촉매로서, 보조금속에 대한 백금의 몰비는 0.5~1.49이고, 촉매를 KOH로 적정 시 20~150 μmol KOH/g 촉매의 산점량을 갖는 것을 특징으로 하는 탈수소화 촉매에 관한 것으로, 본 발명에 따른 탈수소화 촉매는 탈수소 반응에서 수소비 하향시 코크가 급속히 증가하는 현상을 방지함으로써 공정 생산량이 향상되어 수소/탄화수소비 하향 조건에서 운전이 가능해져서 공정 경제성을 향상시킬 수 있다.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201880000267.7A CN110352093A (zh) | 2018-02-01 | 2018-02-06 | 脱氢催化剂 |
US15/762,666 US10960384B2 (en) | 2018-02-01 | 2018-02-06 | Dehydrogenation catalyst |
SA518400582A SA518400582B1 (ar) | 2018-02-01 | 2018-12-04 | محفز نزع الهيدروجين |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020180012719A KR101981886B1 (ko) | 2018-02-01 | 2018-02-01 | 탈수소화 촉매 |
KR10-2018-0012719 | 2018-02-01 |
Publications (2)
Publication Number | Publication Date |
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WO2018097701A2 WO2018097701A2 (ko) | 2018-05-31 |
WO2018097701A3 true WO2018097701A3 (ko) | 2019-01-03 |
Family
ID=62195240
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/KR2018/001532 WO2018097701A2 (ko) | 2018-02-01 | 2018-02-06 | 탈수소화 촉매 |
Country Status (5)
Country | Link |
---|---|
US (1) | US10960384B2 (ko) |
KR (1) | KR101981886B1 (ko) |
CN (1) | CN110352093A (ko) |
SA (1) | SA518400582B1 (ko) |
WO (1) | WO2018097701A2 (ko) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019089958A1 (en) * | 2017-11-02 | 2019-05-09 | Uop Llc | Dehydrogenation process at reduced hydrogen to hydrocarbon ratios |
KR102162079B1 (ko) * | 2019-01-18 | 2020-10-07 | 효성화학 주식회사 | 촉매 담체의 제조방법 및 탈수소 촉매 |
US10981149B2 (en) * | 2019-03-18 | 2021-04-20 | Uop Llc | Dehydrogenation catalyst with optimum modifier profile index |
CN110237840B (zh) * | 2019-07-04 | 2020-09-15 | 中国科学院大连化学物理研究所 | 一种铂单原子催化剂的制备及其在丙烷脱氢制丙烯反应中的应用 |
US20210053034A1 (en) * | 2019-08-23 | 2021-02-25 | Uop Llc | Dehydrogenation catalyst composition |
US11000832B1 (en) * | 2020-03-13 | 2021-05-11 | Uop Llc | Dehydrogenation catalyst with minimized aromatic production |
WO2022018081A1 (en) | 2020-07-21 | 2022-01-27 | Basf Se | A zeolite catalyst and use thereof for the dehydrogenation of alkanes |
CN113171801A (zh) * | 2020-11-30 | 2021-07-27 | 谷育英 | 一种低碳烷烃脱氢制烯烃的催化剂及其制备方法和应用 |
KR102523345B1 (ko) * | 2020-12-04 | 2023-04-18 | 희성촉매 주식회사 | 담체 기공이 조절된 탈수소화 촉매 |
US20230026153A1 (en) * | 2021-07-15 | 2023-01-26 | Uop Llc | Catalyst for propane dehydrogenation to propylene |
CN114425327B (zh) * | 2021-12-31 | 2023-12-05 | 杭州凯大催化金属材料股份有限公司 | 一种丙烷脱氢催化剂的制备方法 |
CN114733521A (zh) * | 2022-04-11 | 2022-07-12 | 恩索(苏州)科技有限公司 | 一种双晶型载体的烷烃非氧化脱氢催化剂 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20100078465A (ko) * | 2008-12-30 | 2010-07-08 | 주식회사 효성 | 탈수소화 촉매 |
KR20100078460A (ko) * | 2008-12-30 | 2010-07-08 | 주식회사 효성 | 산화 탈수소 촉매, 및 이를 이용한 프로판으로부터 프로필렌의 제조방법 |
KR20110078818A (ko) * | 2009-12-31 | 2011-07-07 | 주식회사 효성 | 탈수소 에어로젤 촉매 |
KR20120077688A (ko) * | 2010-12-31 | 2012-07-10 | 주식회사 효성 | 선택도가 향상된 탈수소화 반응용 금속 촉매 |
JP2013203646A (ja) * | 2012-03-29 | 2013-10-07 | Sumitomo Metal Mining Co Ltd | 高純度硫酸ニッケルの製造方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1072525A (en) * | 1975-05-22 | 1980-02-26 | Exxon Research And Engineering Company | Catalysts, method of making said catalysts and uses thereof |
US4914075A (en) * | 1988-12-05 | 1990-04-03 | Uop | Dehydrogenation catalyst composition |
CN1032678C (zh) * | 1992-12-21 | 1996-09-04 | 中国石油化工总公司 | 饱和烃类脱氢用催化剂 |
DE19609954A1 (de) * | 1996-03-14 | 1997-09-18 | Basf Ag | Verfahren zur Dehydrierung von sekundären cyclischen Alkoholen |
US6635598B2 (en) * | 2000-04-20 | 2003-10-21 | Indian Petrochemicals Corporation Limited | Stable and selective dehydrogenation catalyst and a process for the preparation thereof |
DE10047642A1 (de) * | 2000-09-26 | 2002-04-11 | Basf Ag | Verfahren zur Dehydrierung von Kohlenwasserstoffen |
US6756340B2 (en) * | 2002-04-08 | 2004-06-29 | Uop Llc | Dehydrogenation catalyst composition |
FR2875716B1 (fr) * | 2004-09-28 | 2007-08-03 | Inst Francais Du Petrole | Nouveaux supports composites alumine sur alumine |
KR100761512B1 (ko) * | 2006-08-22 | 2007-10-04 | 주식회사 효성 | 금속 촉매를 이용한 디메틸나프탈렌의 탈수소화 공정 |
JP5096751B2 (ja) * | 2007-01-26 | 2012-12-12 | クラリアント触媒株式会社 | 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法 |
CN102218314B (zh) * | 2010-04-15 | 2012-11-14 | 中国石油化工股份有限公司 | 用于丙烷脱氢过程中氢气选择氧化催化剂及其制备方法 |
MX2014006135A (es) | 2011-11-21 | 2015-09-07 | Reliance Ind Ltd | Catalizador compuesto para deshidrogenacion de hidrocarburos y forma de preparacion. |
US9266091B2 (en) * | 2012-03-29 | 2016-02-23 | Uop Llc | Reforming catalysts with tuned acidity for maximum aromatics yield |
CN104755167B (zh) | 2012-08-28 | 2018-08-07 | 陶氏环球技术有限责任公司 | 催化剂组合物和用于烷烃脱氢的再活化方法 |
CN104525195B (zh) * | 2014-12-30 | 2018-01-05 | 中国石油天然气股份有限公司 | 一种异丁烷脱氢制异丁烯用催化剂及其制备方法与应用 |
AU2016202495B2 (en) * | 2015-04-23 | 2020-05-21 | Reliance Industries Limited | Multi-metallic catalyst system and use of the same in preparing upgraded fuel from biomass |
TWI549749B (zh) * | 2015-05-07 | 2016-09-21 | China Petrochemical Dev Corp Taipei Taiwan | A catalyst composition for preparing o-phenylphenol and a process for preparing o-phenylphenol using the catalyst composition |
-
2018
- 2018-02-01 KR KR1020180012719A patent/KR101981886B1/ko active IP Right Grant
- 2018-02-06 US US15/762,666 patent/US10960384B2/en active Active
- 2018-02-06 WO PCT/KR2018/001532 patent/WO2018097701A2/ko active Application Filing
- 2018-02-06 CN CN201880000267.7A patent/CN110352093A/zh active Pending
- 2018-12-04 SA SA518400582A patent/SA518400582B1/ar unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20100078465A (ko) * | 2008-12-30 | 2010-07-08 | 주식회사 효성 | 탈수소화 촉매 |
KR20100078460A (ko) * | 2008-12-30 | 2010-07-08 | 주식회사 효성 | 산화 탈수소 촉매, 및 이를 이용한 프로판으로부터 프로필렌의 제조방법 |
KR20110078818A (ko) * | 2009-12-31 | 2011-07-07 | 주식회사 효성 | 탈수소 에어로젤 촉매 |
KR20120077688A (ko) * | 2010-12-31 | 2012-07-10 | 주식회사 효성 | 선택도가 향상된 탈수소화 반응용 금속 촉매 |
JP2013203646A (ja) * | 2012-03-29 | 2013-10-07 | Sumitomo Metal Mining Co Ltd | 高純度硫酸ニッケルの製造方法 |
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SA518400582B1 (ar) | 2021-09-08 |
US20190232255A1 (en) | 2019-08-01 |
US10960384B2 (en) | 2021-03-30 |
WO2018097701A2 (ko) | 2018-05-31 |
KR101981886B1 (ko) | 2019-05-23 |
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