UA98661C2 - Способ активации катализатора процесса фишера-тропша - Google Patents
Способ активации катализатора процесса фишера-тропшаInfo
- Publication number
- UA98661C2 UA98661C2 UAA201002004A UAA201002004A UA98661C2 UA 98661 C2 UA98661 C2 UA 98661C2 UA A201002004 A UAA201002004 A UA A201002004A UA A201002004 A UAA201002004 A UA A201002004A UA 98661 C2 UA98661 C2 UA 98661C2
- Authority
- UA
- Ukraine
- Prior art keywords
- fischer
- catalyst
- activation
- tropsch catalyst
- iron
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Изобретение относится к отрасли катализа процесса Фишера-Тропша, в частности активации катализатора Фишера-Тропша. Способ активации катализатора процесса Фишера-Тропша на основе железа, который содержит железо в состоянии позитивного окисления, контактирование в реакторе указанного катализатора на основе железа с восстановительным газом, выбранным из группы, которая состоит из СО и комбинации Ни CO, при молярном соотношении Ни CO от 100:1 до 1:100, при температуре как минимум 245 °C и ниже 280 °C, при давлении восстановительного газа более 0,5 МПа и не более чем 2,2 МПа и при среднечасовой скорости (GHSV) подачи всего газа, который подают в реактор, как минимум 6000 мл(норм.)/г кат./час, с восстановлением железа, которое находится в состоянии окисления в катализаторе.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ZA200706647 | 2007-08-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
UA98661C2 true UA98661C2 (ru) | 2012-06-11 |
Family
ID=40351239
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
UAA201002004A UA98661C2 (ru) | 2007-08-10 | 2008-08-05 | Способ активации катализатора процесса фишера-тропша |
UAA201001352A UA96820C2 (ru) | 2007-08-10 | 2008-08-05 | Трехфазный низкотемпературный процесс фишера-тропша |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
UAA201001352A UA96820C2 (ru) | 2007-08-10 | 2008-08-05 | Трехфазный низкотемпературный процесс фишера-тропша |
Country Status (7)
Country | Link |
---|---|
US (2) | US8513312B2 (ru) |
CN (2) | CN101796166B (ru) |
AU (2) | AU2008288199B2 (ru) |
RU (2) | RU2450044C2 (ru) |
UA (2) | UA98661C2 (ru) |
WO (2) | WO2009022261A2 (ru) |
ZA (2) | ZA201000617B (ru) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7915193B2 (en) * | 2007-08-30 | 2011-03-29 | Rentech, Inc. | Method for activating strengthened iron catalyst for slurry reactors |
US10086365B2 (en) | 2007-08-30 | 2018-10-02 | Res Usa, Llc | Strengthened iron catalyst for slurry reactors |
AU2009329087B2 (en) * | 2008-12-18 | 2013-07-18 | Sasol Technology (Pty) Limited | Method for the preparation of a hydrocarbon synthesis catalyst material and the use thereof in a hydrocarbon synthesis process |
FR2984346B1 (fr) * | 2011-12-14 | 2013-12-27 | IFP Energies Nouvelles | Procede de fabrication d'hydrocarbures avec chargement en continu du catalyseur |
CN102553657B (zh) * | 2012-01-06 | 2013-11-20 | 神华集团有限责任公司 | 费托催化剂的还原方法 |
CN103418393B (zh) * | 2012-05-16 | 2016-02-10 | 中国石油化工股份有限公司 | 费托合成重质烃的催化剂及其制备方法 |
CN102863983B (zh) * | 2012-09-20 | 2014-12-10 | 神华集团有限责任公司 | 一种费托合成催化剂活化及开工方法 |
US9643164B2 (en) | 2013-06-28 | 2017-05-09 | Dow Global Technologies Llc | Iron-based catalysts and treatment process therefor for use in Fischer-Tropsch reactions |
CN104549559B (zh) * | 2013-10-28 | 2017-03-15 | 中国石油化工股份有限公司 | 流化床合成气直接制备低碳烯烃铁基催化剂的活化方法 |
BR112016021696B1 (pt) * | 2014-03-24 | 2020-11-10 | Sasol Technology Proprietary Limited | síntese de fischer-tropsch |
CN105080570B (zh) * | 2014-05-14 | 2017-10-27 | 中国石油化工股份有限公司 | 流化床合成气直接制备低碳烯烃铁基催化剂的再生方法 |
EP3186341B1 (en) | 2014-07-28 | 2019-03-20 | Sasol Technology Proprietary Limited | Production of oilfield hydrocarbons |
RU2628199C1 (ru) * | 2016-06-07 | 2017-08-15 | Общество с ограниченной ответственностью "ЛАН-ПРОЕКТ" | Способ сжатия данных |
GB201614363D0 (en) * | 2016-08-23 | 2016-10-05 | Bp Plc | Fischer-tropsch catalyst performance enhancement process |
GB201702248D0 (en) * | 2017-02-10 | 2017-03-29 | Bp Plc | Start-up procedure for a fischer-tropsch process |
CN110201673B (zh) * | 2018-02-28 | 2022-02-18 | 国家能源投资集团有限责任公司 | 还原铁基费托合成催化剂的方法和还原态铁基费托合成催化剂 |
CN110361499A (zh) * | 2018-04-09 | 2019-10-22 | 国家能源投资集团有限责任公司 | 铁基费托合成催化剂活性评价的方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7452844B2 (en) * | 2001-05-08 | 2008-11-18 | Süd-Chemie Inc | High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis |
US7361619B2 (en) * | 2003-04-11 | 2008-04-22 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst production |
CN1803281A (zh) * | 2006-01-24 | 2006-07-19 | 吕毅军 | 用于费托合成反应工艺的含助剂瑞尼铁催化剂及其制法 |
US7544719B2 (en) * | 2006-07-12 | 2009-06-09 | Rentech, Inc. | Method for activating an iron-based fischer-tropsch catalyst |
-
2008
- 2008-08-05 ZA ZA201000617A patent/ZA201000617B/xx unknown
- 2008-08-05 US US12/672,981 patent/US8513312B2/en not_active Expired - Fee Related
- 2008-08-05 AU AU2008288199A patent/AU2008288199B2/en not_active Ceased
- 2008-08-05 UA UAA201002004A patent/UA98661C2/ru unknown
- 2008-08-05 CN CN200880102983.2A patent/CN101796166B/zh not_active Expired - Fee Related
- 2008-08-05 RU RU2010107701/04A patent/RU2450044C2/ru not_active IP Right Cessation
- 2008-08-05 AU AU2008288198A patent/AU2008288198B2/en not_active Ceased
- 2008-08-05 WO PCT/IB2008/053134 patent/WO2009022261A2/en active Application Filing
- 2008-08-05 WO PCT/IB2008/053135 patent/WO2009022262A2/en active Application Filing
- 2008-08-05 UA UAA201001352A patent/UA96820C2/ru unknown
- 2008-08-05 RU RU2010107699/04A patent/RU2450043C2/ru not_active IP Right Cessation
- 2008-08-05 CN CN200880102982A patent/CN101868518A/zh active Pending
- 2008-08-05 US US12/672,983 patent/US8716160B2/en not_active Expired - Fee Related
-
2010
- 2010-01-27 ZA ZA201000928A patent/ZA201000928B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
AU2008288199B2 (en) | 2011-08-18 |
AU2008288199A1 (en) | 2009-02-19 |
RU2010107701A (ru) | 2011-09-20 |
CN101796166B (zh) | 2015-01-28 |
US8716160B2 (en) | 2014-05-06 |
UA96820C2 (ru) | 2011-12-12 |
AU2008288198B2 (en) | 2011-08-18 |
CN101796166A (zh) | 2010-08-04 |
CN101868518A (zh) | 2010-10-20 |
RU2450044C2 (ru) | 2012-05-10 |
AU2008288198A1 (en) | 2009-02-19 |
WO2009022261A3 (en) | 2009-06-25 |
US20110275512A1 (en) | 2011-11-10 |
WO2009022262A2 (en) | 2009-02-19 |
US20110178189A1 (en) | 2011-07-21 |
ZA201000617B (en) | 2010-10-27 |
RU2010107699A (ru) | 2011-09-10 |
US8513312B2 (en) | 2013-08-20 |
WO2009022261A2 (en) | 2009-02-19 |
ZA201000928B (en) | 2010-10-27 |
WO2009022262A3 (en) | 2009-06-25 |
RU2450043C2 (ru) | 2012-05-10 |
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