WO2017187638A1 - 非水電解質二次電池 - Google Patents
非水電解質二次電池 Download PDFInfo
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- WO2017187638A1 WO2017187638A1 PCT/JP2016/063492 JP2016063492W WO2017187638A1 WO 2017187638 A1 WO2017187638 A1 WO 2017187638A1 JP 2016063492 W JP2016063492 W JP 2016063492W WO 2017187638 A1 WO2017187638 A1 WO 2017187638A1
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- negative electrode
- active material
- electrode active
- material layer
- battery
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Definitions
- the present invention relates to a non-aqueous electrolyte secondary battery.
- the non-aqueous electrolyte secondary battery according to the present invention is used, for example, as a driving power source or auxiliary power source for motors of vehicles such as electric vehicles, fuel cell vehicles, and hybrid electric vehicles.
- non-aqueous electrolyte secondary batteries with a low environmental load are being used not only for portable devices, but also for power supply devices for electric vehicles such as hybrid vehicles (HEV), electric vehicles (EV), and fuel cell vehicles.
- HEV hybrid vehicles
- EV electric vehicles
- fuel cell vehicles fuel cell vehicles.
- a lithium ion secondary battery directed to application to an electric vehicle is required to have a large capacity and a large area.
- a battery using a material that is alloyed with Li as a negative electrode active material has higher energy density than a battery using a carbon material such as conventional graphite, and thus is expected as a negative electrode active material for vehicle applications.
- a lithium ion secondary battery using a material that forms an alloy with Li for the negative electrode has a large expansion and contraction at the negative electrode during charge and discharge.
- the volume expansion is about 1.2 times in the case of graphite material
- Si and Li when Si and Li are alloyed, the transition from the amorphous state to the crystalline state is about 4 times. Therefore, there is a problem in that the cycle life of the electrode is reduced.
- the capacity and the cycle durability are in a trade-off relationship, and there is a problem that it is difficult to improve the high cycle durability while exhibiting a high capacity.
- a negative electrode active material for a lithium ion secondary battery including an amorphous alloy having the formula: Si x M y Al z has been proposed (see, for example, Patent Document 1).
- M represents Mn, Mo, Nb, W, Ta, Fe, Cu, It is a metal composed of at least one of Ti, V, Cr, Ni, Co, Zr, and Y.
- paragraph “0018” describes that, by minimizing the content of metal M, a good cycle life is exhibited in addition to high capacity. Further, it is described that a good cycle life is exhibited by mixing a graphite material having a small expansion.
- the negative electrode active material layer includes a plurality of negative electrode active materials having different theoretical charge / discharge capacities, that is, carbon such as graphite, which is an existing negative electrode active material. It has been found that this is caused by including a material and a silicon material having a higher capacity than the carbon material.
- the non-uniformity of the binder per unit area at the structure level of each of the electrode and the battery can increase the capacity and the capacity of the battery. As the area increases, it becomes more noticeable exponentially. As a result, it has been found that the current is locally concentrated in the negative electrode surface, and as a result, the deterioration is caused by producing different portions in the negative electrode surface.
- the few binders have a low binding property inside the electrode. Expansion increases.
- the portion where the binder is large has a high binding property inside the electrode, so that the expansion of the electrode is small.
- the distance between the positive electrode and the negative electrode is shortened at a position where the expansion of the electrode is large, and the distance between the positive electrode and the negative electrode is increased at a position where the expansion of the electrode is small.
- the reaction is accelerated because the resistance is small and the amount of current is increased at a position where the distance between the electrodes is short, and the reaction is difficult to proceed because the resistance is increased and the amount of current is decreased at a position where the distance between the electrodes is long. That is, reaction non-uniformity occurs in the negative electrode surface.
- reaction amount is large, acceleration of a side reaction with the electrolytic solution and acceleration of deterioration of the active material occur, so that the cycle durability of the battery is remarkably lowered.
- the binding property is small at the portion where the binder is small, the active material is detached in the charging / discharging process, thereby reducing the cycle durability.
- the present invention provides a sufficient charge / discharge cycle in a non-aqueous electrolyte secondary battery having a large capacity and a large area even when a mixture of a high-capacity Si material and a carbon material having a small expansion is used as the negative electrode active material.
- the object is to provide a means by which properties can be achieved.
- the present inventors have conducted intensive research to solve the above problems.
- the ratio of the battery volume to the rated capacity and the rated capacity are used as an index representing a large battery having a large capacity and a large area, and these are set within a predetermined range, and the dispersion of the dispersibility of the binder in the negative electrode active material layer It has been found that the above-mentioned problems can be solved by controlling the value within a predetermined range, and the present invention has been completed.
- the present invention includes a mixture of a small amount of Si material and a large amount of carbon material as a negative electrode active material in a large battery having a rated capacity of 3 Ah or more and a ratio of the battery volume to the capacity of 10 cm 3 / Ah or less.
- a nonaqueous electrolyte secondary battery in which the dispersion of the dispersibility of the binder in the layer is within 10%.
- the dispersion of the dispersibility of the binder in the negative electrode active material layer is within 10%, in the large battery, the variation in expansion amount during charging in the negative electrode surface is reduced.
- the phenomenon in which the non-uniformity of reactivity with Li ions due to an increase in the distance between the positive electrode and the negative electrode and a decrease in the certain area is suppressed, and the cycle durability of the battery is suppressed. Will improve.
- the dispersion of the dispersibility of the binder in the negative electrode active material layer to be within 10%, in the above-described large battery, the portion where the binder is insufficient in the negative electrode active material layer is reduced. This can prevent the active material from falling off and improve the cycle durability of the battery.
- FIG. 1 is a schematic cross-sectional view showing a basic configuration of a lithium ion secondary battery that is not a flat type (stacked type) bipolar type, which is an embodiment of a nonaqueous electrolyte secondary battery according to the present invention.
- 1 is a perspective view illustrating an appearance of a flat lithium ion secondary battery that is a typical embodiment of a nonaqueous electrolyte secondary battery according to the present invention.
- FIG. 3A is a perspective view of a rectangular negative electrode which is a constituent member of a flat (stacked) bipolar lithium ion secondary battery, which is an embodiment of the nonaqueous electrolyte secondary battery according to the present invention. It is.
- 3B is a cross-sectional view taken along a diagonal line (a dashed line) connecting diagonal lines in the rectangular negative electrode surface of FIG. 6 is a diagram showing the relationship between the binder distribution and the capacity retention rate for Comparative Examples 1-1 to 1-5 (mixing ratio of Si material 0 mass%) divided into small batteries and large batteries.
- Examples 2-1 to 2-2 and Comparative Examples 2-1 to 2-5 mixed ratio of Si material: 10% by mass
- the relationship between the binder distribution and the capacity retention rate is divided into small batteries and large batteries. It is drawing which shows.
- Examples 3-1 to 3-2 and Comparative Examples 3-1 to 3-5 mixing ratio of Si material: 20% by mass
- the relationship between the binder distribution and the capacity retention rate is divided into small batteries and large batteries. It is drawing which shows.
- the value of the ratio of the battery volume (the product of the projected area of the battery including the battery outer package and the thickness of the battery) to the rated capacity is 10 cm 3 / Ah or less, and the rated capacity is 3 Ah or more.
- a non-aqueous electrolyte secondary battery A positive electrode in which a positive electrode active material layer containing a positive electrode active material is formed on the surface of the positive electrode current collector; A negative electrode in which a negative electrode active material layer containing a negative electrode active material is formed on the surface of the negative electrode current collector; A separator;
- a power generation element including The negative electrode active material layer has the following formula (1):
- the Si material is selected from the group consisting of SiO x (x represents the number of oxygen satisfying the valence of Si) which is a mixture of amorphous SiO 2 particles and Si particles and a Si-containing alloy)
- the carbon material is one or more selected from the group consisting of graphite, non-graphitizable carbon, and amorphous carbon, and ⁇ and ⁇ are each of the components in the negative electrode active material layer
- the difference between the maximum value and the minimum value of the area ratio (%) occupied by the binder in the visual field area of each image of the cross section of the negative electrode active material layer when a plurality of arbitrary locations in the negative electrode active material layer surface are selected is within 10%.
- a non-aqueous electrolyte secondary battery is provided.
- the lithium ion secondary battery of this embodiment the voltage of the cell (single cell layer) is large, and high energy density and high output density can be achieved. Therefore, the lithium ion secondary battery of the present embodiment is excellent as a vehicle driving power source or an auxiliary power source. As a result, it can be suitably used as a lithium ion secondary battery for a vehicle driving power source or the like. In addition to this, the present invention can be sufficiently applied to lithium ion secondary batteries for portable devices such as mobile phones.
- the lithium ion secondary battery When the lithium ion secondary battery is distinguished by its form / structure, it can be applied to any conventionally known form / structure such as a stacked (flat) battery or a wound (cylindrical) battery. Is. By adopting a stacked (flat) battery structure, long-term reliability can be secured by a sealing technique such as simple thermocompression bonding, which is advantageous in terms of cost and workability.
- a solution electrolyte type battery using a solution electrolyte such as a nonaqueous electrolyte solution for the electrolyte layer, a polymer battery using a polymer electrolyte for the electrolyte layer, etc. It can be applied to any conventionally known electrolyte layer type.
- the polymer battery is further divided into a gel electrolyte type battery using a polymer gel electrolyte (also simply referred to as gel electrolyte) and a solid polymer (all solid) type battery using a polymer solid electrolyte (also simply referred to as polymer electrolyte). It is done.
- FIG. 1 shows an overall structure of a flat (stacked) lithium ion secondary battery (hereinafter also simply referred to as “stacked battery”), which is a typical embodiment of the nonaqueous electrolyte secondary battery of the present invention. It is the cross-sectional schematic diagram which represented typically.
- stacked battery flat (stacked) lithium ion secondary battery
- the stacked battery 10 of the present embodiment has a structure in which a substantially rectangular power generation element 21 in which a charge / discharge reaction actually proceeds is sealed inside a laminate sheet 29 that is an exterior body.
- the positive electrode in which the positive electrode active material layer 15 is disposed on both surfaces of the positive electrode current collector 12, the electrolyte layer 17, and the negative electrode active material layer 13 is disposed on both surfaces of the negative electrode current collector 11. It has a configuration in which a negative electrode is laminated. Specifically, the negative electrode, the electrolyte layer, and the positive electrode are laminated in this order so that one positive electrode active material layer 15 and the negative electrode active material layer 13 adjacent thereto face each other with the electrolyte layer 17 therebetween. .
- the adjacent positive electrode, electrolyte layer, and negative electrode constitute one unit cell layer 19. Therefore, it can be said that the stacked battery 10 shown in FIG. 1 has a configuration in which a plurality of single battery layers 19 are stacked and electrically connected in parallel.
- the negative electrode current collector 13 on the outermost layer located on both outermost layers of the power generation element 21 is provided with the negative electrode active material layer 13 only on one side, but the active material layer may be provided on both sides. . That is, instead of using a current collector dedicated to the outermost layer provided with an active material layer only on one side, a current collector having an active material layer on both sides may be used as it is as an outermost current collector.
- the outermost positive electrode current collector is positioned on both outermost layers of the power generation element 21, and one side of the outermost positive electrode current collector or A positive electrode active material layer may be disposed on both sides.
- the positive electrode current collector 12 and the negative electrode current collector 11 are attached to the positive electrode current collector plate 27 and the negative electrode current collector plate 25 that are electrically connected to the respective electrodes (positive electrode and negative electrode), and are sandwiched between the end portions of the laminate sheet 29. Thus, it has a structure led out of the laminate sheet 29.
- the positive electrode current collector 27 and the negative electrode current collector 25 are ultrasonically welded to the positive electrode current collector 12 and the negative electrode current collector 11 of each electrode via a positive electrode lead and a negative electrode lead (not shown), respectively, as necessary. Or resistance welding or the like.
- the active material layers (13, 15) contain an active material, and further contain other additives as necessary.
- the positive electrode active material layer 15 includes a positive electrode active material.
- the positive electrode active material is not particularly limited, but preferably includes a lithium nickel composite oxide or a spinel lithium manganese composite oxide, and more preferably includes a lithium nickel composite oxide.
- the ratio of the total amount of the lithium nickel composite oxide and the spinel lithium manganese composite oxide in the total amount of 100% by mass of the positive electrode active material contained in the positive electrode active material layer is preferably 50% by mass or more. Preferably it is 70 mass% or more, More preferably, it is 85 mass% or more, More preferably, it is 90 mass% or more, Most preferably, it is 95 mass% or more, Most preferably, it is 100 mass%.
- lithium nickel complex oxide is not specifically limited as long as it is a complex oxide containing lithium and nickel.
- a typical example of a composite oxide containing lithium and nickel is lithium nickel composite oxide (LiNiO 2 ).
- a composite oxide in which some of the nickel atoms of the lithium nickel composite oxide are substituted with other metal atoms is more preferable.
- NMC composite lithium-nickel-manganese-cobalt composite oxide
- oxide (Also referred to as “oxide”) has a layered crystal structure in which a lithium atomic layer and a transition metal (Mn, Ni, and Co are arranged in order) are alternately stacked via an oxygen atomic layer.
- a lithium atomic layer Li atomic layer
- a transition metal Mn, Ni, and Co are arranged in order
- One Li atom is contained per atom, and the amount of Li that can be taken out is twice that of the spinel-type lithium manganese oxide, that is, the supply capacity is doubled, so that a high capacity can be obtained.
- LiNiO 2 since it has higher thermal stability than LiNiO 2 , it is particularly advantageous among the nickel-based composite oxides used as the positive electrode active material.
- the NMC composite oxide includes a composite oxide in which a part of the transition metal element is substituted with another metal element.
- Other elements in that case include Ti, Zr, Nb, W, P, Al, Mg, V, Ca, Sr, Cr, Fe, B, Ga, In, Si, Mo, Y, Sn, V, Cu , Ag, Zn, etc., preferably Ti, Zr, Nb, W, P, Al, Mg, V, Ca, Sr, Cr, more preferably Ti, Zr, P, Al, Mg, From the viewpoint of improving cycle characteristics, Ti, Zr, Al, Mg, and Cr are more preferable.
- a represents the atomic ratio of Li
- b represents the atomic ratio of Ni
- c represents the atomic ratio of Mn
- d represents the atomic ratio of Co
- x represents the atomic ratio of M. Represents. From the viewpoint of cycle characteristics, it is preferable that 0.4 ⁇ b ⁇ 0.6 in the general formula (1).
- the composition of each element can be measured by, for example, inductively coupled plasma (ICP) emission spectrometry.
- ICP inductively coupled plasma
- Ni nickel
- Co cobalt
- Mn manganese
- Ti or the like partially replaces the transition metal in the crystal lattice. From the viewpoint of cycle characteristics, it is preferable that a part of the transition element is substituted with another metal element, and it is particularly preferable that 0 ⁇ x ⁇ 0.3 in the general formula (1). Since at least one selected from the group consisting of Ti, Zr, Nb, W, P, Al, Mg, V, Ca, Sr, and Cr is dissolved, the crystal structure is stabilized. It is considered that the battery capacity can be prevented from decreasing even if the above is repeated, and that excellent cycle characteristics can be realized.
- b, c and d are 0.44 ⁇ b ⁇ 0.51, 0.27 ⁇ c ⁇ 0.31, 0.19 ⁇ d ⁇ 0.26. It is preferable that it is excellent in balance between capacity and durability.
- the lithium nickel composite oxide such as NMC composite oxide can be prepared by selecting various known methods such as coprecipitation method and spray drying method.
- the coprecipitation method is preferably used because the complex oxide according to this embodiment is easy to prepare.
- a nickel-cobalt-manganese composite oxide is manufactured by a coprecipitation method as in the method described in JP 2011-105588 A, and then nickel- It can be obtained by mixing and firing a cobalt-manganese composite oxide and a lithium compound. This will be specifically described below.
- the raw material compound of the composite oxide for example, Ni compound, Mn compound and Co compound is dissolved in an appropriate solvent such as water so as to have a desired composition of the active material.
- the Ni compound, Mn compound, and Co compound include sulfates, nitrates, carbonates, acetates, oxalates, oxides, hydroxides, and halides of the metal elements.
- Specific examples of the Ni compound, Mn compound, and Co compound include, but are not limited to, nickel sulfate, cobalt sulfate, manganese sulfate, nickel acetate, cobalt acetate, and manganese acetate.
- Ti, Zr, Nb as a metal element that substitutes a part of the layered lithium metal composite oxide constituting the active material so as to have a desired active material composition.
- W, P, Al, Mg, V, Ca, Sr, and a compound containing at least one metal element such as Cr may be further mixed.
- the coprecipitation reaction can be performed by neutralization and precipitation reaction using the above raw material compound and an alkaline solution.
- the metal composite hydroxide and metal composite carbonate containing the metal contained in the said raw material compound are obtained.
- the alkaline solution for example, an aqueous solution of sodium hydroxide, potassium hydroxide, sodium carbonate, ammonia or the like can be used, but sodium hydroxide, sodium carbonate or a mixed solution thereof is preferably used for the neutralization reaction. .
- an aqueous ammonia solution or an ammonium salt is preferably used for the complex reaction.
- the addition amount of the alkaline solution used for the neutralization reaction may be an equivalent ratio of 1.0 with respect to the neutralized content of all the metal salts contained, but it is preferable to add the alkali excess together for pH adjustment.
- the addition amount of the aqueous ammonia solution or ammonium salt used for the complex reaction is preferably such that the ammonia concentration in the reaction solution is in the range of 0.01 to 2.00 mol / l.
- the pH of the reaction solution is preferably controlled in the range of 10.0 to 13.0.
- the reaction temperature is preferably 30 ° C. or higher, more preferably 30 to 60 ° C.
- the composite hydroxide obtained by the coprecipitation reaction is then preferably suction filtered, washed with water and dried.
- the particle size of the composite hydroxide can be controlled by adjusting the conditions (stirring time, alkali concentration, etc.) for carrying out the coprecipitation reaction, which is the secondary electrode of the positive electrode active material finally obtained. It affects the average particle size (D50 (A)) of the particles.
- the nickel-cobalt-manganese composite hydroxide is mixed with a lithium compound and fired to obtain a lithium-nickel-manganese-cobalt composite oxide.
- the Li compound include lithium hydroxide or a hydrate thereof, lithium peroxide, lithium nitrate, and lithium carbonate.
- the firing treatment may be performed in one stage, but is preferably performed in two stages (temporary firing and main firing).
- a composite oxide can be obtained efficiently by two-stage firing.
- the pre-baking conditions are not particularly limited, and differ depending on the lithium raw material, so that it is difficult to uniquely define them.
- the factors for controlling the average primary particle size and crystallite size are particularly important as the firing temperature and firing time during firing (temporary firing and main firing in the case of two stages). By adjusting based on the following tendency, the average primary particle diameter and crystallite diameter can be controlled. That is, when the firing time is lengthened, the average primary particle diameter and crystallite diameter increase. Further, when the firing temperature is increased, the average primary particle size and crystallite size are increased.
- the temperature rising rate is preferably 1 to 20 ° C./min from room temperature.
- the atmosphere is preferably in air or in an oxygen atmosphere.
- the pre-baking temperature is preferably 500 to 900 ° C., more preferably 600 to 800 ° C., further preferably 650. ⁇ 750 ° C.
- the pre-baking time is preferably 0.5 to 10 hours, more preferably 4 to 6 hours.
- the conditions for the main firing are not particularly limited, but the rate of temperature rise is preferably from room temperature to 1 to 20 ° C./min.
- the atmosphere is preferably in air or in an oxygen atmosphere.
- the firing temperature is preferably 800 to 1200 ° C., more preferably 850 to 1100 ° C., and further preferably 900 to 1050. ° C.
- the pre-baking time is preferably 1 to 20 hours, more preferably 8 to 12 hours.
- a method of previously mixing with nickel, cobalt, manganate Any means such as a method of adding nickel, cobalt and manganate simultaneously, a method of adding to the reaction solution during the reaction, a method of adding to the nickel-cobalt-manganese composite oxide together with the Li compound may be used.
- the lithium nickel composite oxide can be produced by appropriately adjusting the reaction conditions such as pH of the reaction solution, reaction temperature, reaction concentration, addition rate, and stirring time.
- Spinel-based lithium manganese composite oxide is a composite oxide that typically has a composition of LiMn 2 O 4 and has a spinel structure and essentially contains lithium and manganese.
- conventionally known knowledge such as JP-A-2000-77071 can be referred to as appropriate.
- a positive electrode active material other than the above-described lithium nickel composite oxide or spinel lithium manganese composite oxide may be used.
- the optimum particle size is different for expressing the unique effect of each active material, the optimum particle size for expressing each unique effect is determined. What is necessary is just to blend and use, and it is not necessary to make the particle diameter of all the active materials uniform.
- the average particle diameter of the positive electrode active material contained in the positive electrode active material layer 15 is not particularly limited, but is preferably 6 to 11 ⁇ m, more preferably 7 to 10 ⁇ m in terms of secondary particle diameter from the viewpoint of increasing the output.
- the average particle diameter of the primary particles is 0.4 to 0.65 ⁇ m, more preferably 0.45 to 0.55 ⁇ m.
- the “particle diameter” in the present specification means the maximum distance L among the distances between any two points on the particle outline.
- the average particle diameter the average particle diameter of particles observed in several to several tens of fields using an observation means such as a scanning electron microscope (SEM) or a transmission electron microscope (TEM). A value calculated as a value is adopted.
- the positive electrode active material layer preferably contains a binder and a conductive additive. Further, if necessary, it further contains other additives such as an electrolyte (polymer matrix, ion-conductive polymer, electrolyte solution, etc.) and a lithium salt for increasing the ion conductivity.
- a binder and a conductive additive.
- other additives such as an electrolyte (polymer matrix, ion-conductive polymer, electrolyte solution, etc.) and a lithium salt for increasing the ion conductivity.
- the content of the positive electrode active material that can function as an active material is preferably 85 to 99.5% by mass.
- Binder Although it does not specifically limit as a binder used for a positive electrode active material layer, for example, the following materials are mentioned. Polyethylene, polypropylene, polyethylene terephthalate (PET), polyether nitrile, polyacrylonitrile, polyimide, polyamide, cellulose, carboxymethyl cellulose (CMC) and its salts, ethylene-vinyl acetate copolymer, polyvinyl chloride, styrene-butadiene rubber (SBR) ), Isoprene rubber, butadiene rubber, ethylene / propylene rubber, ethylene / propylene / diene copolymer, styrene / butadiene / styrene block copolymer and hydrogenated product thereof, styrene / isoprene / styrene block copolymer and hydrogenated product thereof.
- Thermoplastic polymers such as products, polyvinylidene fluoride (P
- the binder content in the positive electrode active material layer is preferably 1 to 10% by mass, more preferably 1 to 8% by mass.
- the conductive assistant refers to an additive that is blended in order to improve the conductivity of the positive electrode active material layer or the negative electrode active material layer.
- Conductive aids include carbon blacks such as acetylene black, ketjen black, and furnace black, carbon powders such as channel black, thermal black, and graphite, and various carbon fibers such as vapor grown carbon fiber (VGCF). And carbon materials such as expanded graphite.
- the content of the conductive additive in the positive electrode active material layer is preferably 1 to 10% by mass, more preferably 1 to 8% by mass.
- electrolyte salt examples include Li (C 2 F 5 SO 2 ) 2 N, LiPF 6 , LiBF 4 , LiClO 4 , LiAsF 6 , LiCF 3 SO 3 and the like.
- Examples of the ion conductive polymer include polyethylene oxide (PEO) and polypropylene oxide (PPO) polymers.
- the compounding ratio of the components contained in the positive electrode active material layer is not particularly limited.
- the blending ratio can be adjusted by appropriately referring to known knowledge about lithium ion secondary batteries.
- the positive electrode (positive electrode active material layer) can be applied by any one of a kneading method, a sputtering method, a vapor deposition method, a CVD method, a PVD method, an ion plating method, and a thermal spraying method in addition to a method of applying (coating) a normal slurry. Can be formed.
- the negative electrode active material layer 13 has the following formula (1)
- the Si material is selected from the group consisting of SiO x (x represents the number of oxygen satisfying the valence of Si) which is a mixture of amorphous SiO 2 particles and Si particles and a Si-containing alloy)
- the carbon material is one or more selected from the group consisting of graphite, non-graphitizable carbon, and amorphous carbon, and ⁇ and ⁇ are each of the components in the negative electrode active material layer
- ⁇ and ⁇ are each of the components in the negative electrode active material layer
- One of the characteristics is that it contains a negative electrode active material expressed by mass%, and 80 ⁇ ⁇ + ⁇ 98, 0.1 ⁇ ⁇ ⁇ 40, and 58 ⁇ ⁇ ⁇ 97.9.
- the negative electrode active material layer 13 includes, as a negative electrode active material, a material selected from the group consisting of SiO x and a Si-containing alloy (collectively referred to as “Si material”) and a carbon material.
- the Si material means SiO x (x represents the number of oxygen satisfying the valence of Si) and Si-containing alloy which are a mixture of amorphous SiO 2 particles and Si particles. Only 1 type of these may be used as Si material, and 2 or more types may be used together. Hereinafter, these Si materials will be described in detail.
- SiO x is a mixture of amorphous SiO 2 particles and Si particles, and x represents the number of oxygen satisfying the valence of Si. There is no restriction
- the SiO x may be an electrically conductive SiO x particles the surface of the SiO x particulate is coated with a conductive material by mechanical surface fusion treatment.
- Si in the SiO x particles can easily desorb and insert lithium ions, and the reaction in the active material can proceed more smoothly.
- the content of the conductive substance in the conductive SiO x particles is preferably 1 to 30% by mass, and more preferably 2 to 20% by mass.
- SiO x in accordance with the manufacturing method according to this embodiment of SiO x is not particularly limited, it can be produced by utilizing the production of conventionally known various. That is, since there is almost no difference in the amorphous state / characteristics depending on the manufacturing method, various manufacturing methods can be applied.
- Si powder and SiO 2 powder are blended at a predetermined ratio as raw materials, and mixed, granulated and dried mixed granulated raw materials are heated in an inert gas atmosphere (830 ° C. or higher) or heated in vacuum (1 , 100 ° C. or higher and 1,600 ° C. or lower) to generate (sublimate) SiO.
- Gaseous SiO generated by sublimation is vapor-deposited on the deposition substrate (substrate temperature is 450 ° C. or more and 800 ° C. or less) to deposit SiO precipitates.
- the SiO x powder is obtained by removing the SiO deposit from the deposition substrate and pulverizing it using a ball mill or the like.
- X value can be determined by X-ray fluorescence analysis. For example, it can be obtained by using a fundamental parameter method in fluorescent X-ray analysis using O-K ⁇ rays.
- RIX3000 manufactured by Rigaku Corporation
- conditions for the fluorescent X-ray analysis for example, rhodium (Rh) may be used as a target, the tube voltage may be 50 kV, and the tube current may be 50 mA. Since the x value obtained here is calculated from the intensity of the O-K ⁇ ray detected in the measurement region on the substrate, it becomes an average value in the measurement region.
- Si-containing alloy is not particularly limited as long as it is an alloy with another metal containing Si, and conventionally known knowledge can be appropriately referred to.
- Si-containing alloy Si x Ti y Ge z A a , Si x Ti y Zn z A a , Si x Ti y Sn z A a , Si x Sn y Al z A a , and Si x Sn y V z A a , Si x Sn y C z A a , Si x Zn y V z A a , Si x Zn y Sn z A a , Si x Zn y Al z A a , Si x Zn y C zA a, Si x Al y C z a a and Si x Al y Nb z a a ( wherein, a is unavoidable impurities.
- these Si-containing alloys as the negative electrode active material, by appropriately selecting the predetermined first additive element and the predetermined second additive element, the phase transition of amorphous-crystal is suppressed during Li alloying. Thus, the cycle life can be improved. This also makes the capacity higher than that of a conventional negative electrode active material, for example, a carbon-based negative electrode active material.
- the average particle diameter of the SiO x or Si-containing alloy that is a Si material is not particularly limited as long as it is approximately the same as the average particle diameter of the negative electrode active material included in the existing negative electrode active material layer 13.
- the secondary particle diameter D50 is preferably in the range of 1 to 20 ⁇ m.
- the secondary particle diameter D90 is preferably in the range of 5 to 100 ⁇ m.
- the value obtained by the laser diffraction method is used as the secondary particle diameter of the Si material.
- a spherical shape, an ellipse shape, a cylindrical shape, a polygonal column shape, a scale shape, an indefinite shape etc. may be sufficient.
- Manufacturing method of Si containing alloy It does not restrict
- Examples of the method for producing the Si-containing alloy include the following production methods, but are not limited thereto.
- a process for obtaining a mixed powder by mixing raw materials of an Si-containing alloy is performed.
- the raw material of the alloy is mixed in consideration of the composition of the obtained Si-containing alloy.
- the form of the alloy is not particularly limited as long as the ratio of elements necessary for the Si-containing alloy can be realized.
- the element simple substance which comprises Si containing alloy can be mixed with the target ratio, the alloy which has the target element ratio, a solid solution, or an intermetallic compound can be used.
- raw materials in a powder state are mixed. Thereby, the mixed powder which consists of a raw material is obtained.
- Examples of alloying methods include a solid phase method, a liquid phase method, and a gas phase method.
- a mechanical alloy method for example, a mechanical alloy method, an arc plasma melting method, a casting method, a gas atomizing method, a liquid quenching method, an ion beam sputtering method, a vacuum method, and the like.
- Examples include vapor deposition, plating, and gas phase chemical reaction.
- the alloying process is preferably performed by a mechanical alloy method because the phase state can be easily controlled.
- a step of melting the raw material and a step of rapidly cooling and solidifying the molten material may be included.
- a structure composed of a parent phase / silicide phase can be obtained.
- the alloying treatment time is preferably 24 hours or more, more preferably 30 hours or more, still more preferably 36 hours or more, still more preferably 42 hours or more, and particularly preferably 48 hours. That's it.
- the upper limit of the time for alloying process is not set in particular, it may usually be 72 hours or less.
- the alloying treatment by the method described above is usually performed in a dry atmosphere, but the particle size distribution after the alloying treatment may be very large or small. For this reason, it is preferable to perform the grinding
- the particle diameter can be controlled by appropriately subjecting the particles obtained by the alloying treatment to classification, pulverization and the like.
- classification methods include wind classification, mesh filtration, and sedimentation.
- the pulverization conditions are not particularly limited, and the pulverization time, rotation speed, and the like using an appropriate pulverizer (for example, a device that can be used in a mechanical alloy method, such as a planetary ball mill) may be set as appropriate.
- An example of pulverization conditions is an example in which pulverization is performed at a rotational speed of 200 to 400 rpm for 30 minutes to 4 hours using a pulverizer such as a planetary ball mill.
- the negative electrode active material layer can be formed by applying a negative electrode active material slurry containing a negative electrode active material, a binder, a conductive additive, a solvent, and the like on a current collector.
- pulverization may be performed.
- the pulverizing means is not particularly limited, and known means can be appropriately employed.
- the pulverization conditions are not particularly limited, and pulverization time, rotation speed, and the like may be set as appropriate.
- An example of pulverization conditions is an example in which pulverization is performed at a rotational speed of 200 to 400 rpm for 30 minutes to 4 hours using a pulverizer such as a planetary ball mill.
- the pulverization treatment may be performed in several times with a cooling time in between for the purpose of preventing the solvent from being heated and denatured by the pulverization treatment.
- the carbon material that can be used in the present invention is one or more selected from the group consisting of graphite, non-graphitizable carbon, and amorphous carbon.
- graphite which is highly crystalline carbon such as natural graphite and artificial graphite; non-graphitizable carbon such as hard carbon; and ketjen black, acetylene black, channel black, lamp black, oil furnace black, thermal black 1 type, or 2 or more types selected from amorphous carbon such as carbon black.
- graphite such as natural graphite and artificial graphite is preferably used.
- Si materials such as SiO x and Si-containing alloys may not be uniformly arranged in the negative electrode active material layer.
- the potential or capacity each SiO x or Si-containing alloy is expressed differently in the individual.
- the SiO x or Si-containing alloy of the negative electrode active material layer includes a SiO x or Si-containing alloy that reacts with excessive lithium ion, SiO x or Si-containing alloy which does not react with lithium ions occur. That is, non-uniformity of reaction with lithium ions of the SiO x or Si-containing alloy in the negative electrode active material layer occurs.
- the SiO x or Si-containing alloy that reacts excessively with lithium ions acts excessively, so that the electrolyte solution decomposes or excessively expands due to a significant reaction with the electrolytic solution, and the SiO x or Si-containing alloy.
- the destruction of the structure can occur.
- cycle characteristics may be deteriorated.
- the SiO x or Si-containing alloy when the SiO x or Si-containing alloy is mixed with a carbon material, the above problem can be solved. More specifically, by mixing the SiO x or Si-containing alloy with the carbon material, it may be possible to uniformly dispose the SiO x or Si-containing alloy in the negative electrode active material layer. As a result, it is considered that any SiO x or Si-containing alloy in the negative electrode active material layer exhibits the same reactivity and can prevent deterioration of cycle characteristics.
- the initial capacity can be reduced by reducing the content of SiO x or Si-containing alloy in the negative electrode active material layer.
- the carbon material itself has reactivity with lithium ions, the degree of decrease in the initial capacity is relatively small. That is, the negative electrode active material according to the present embodiment has a large effect of improving the cycle characteristics as compared with the effect of reducing the initial capacity.
- the carbon material is unlikely to undergo a volume change when reacting with lithium ions as compared with a Si material such as SiO x or a Si-containing alloy. Therefore, even when the volume change of the SiO x or Si-containing alloy is large, the influence of the volume change of the negative electrode active material due to the lithium reaction should be relatively minor when the negative electrode active material is taken as a whole. Can do. Such an effect can also be understood from the results of Examples in which the cycle characteristics increase as the carbon material content increases (the Si material content decreases).
- the amount of electricity consumed (Wh) can be improved by containing a carbon material. More specifically, the carbon material has a relatively low potential compared with SiO x . As a result, the relatively high potential of the Si material can be reduced. Then, since the electric potential of the whole negative electrode falls, power consumption (Wh) can be improved. Such an action is particularly advantageous when used for a vehicle application, for example.
- the shape of the carbon material is not particularly limited, and may be spherical, elliptical, cylindrical, polygonal, scaly, indefinite, or the like.
- the average particle diameter of the carbon material is not particularly limited, but the secondary particle diameter D50 is preferably 5 to 50 ⁇ m, and more preferably 5 to 25 ⁇ m.
- the value obtained by the laser diffraction method is used as the secondary particle diameter of the carbon material.
- the average particle diameter of the carbon material may be the same as or different from the average particle diameter of the Si material, but the difference is preferable. . More preferably, the average particle size of the Si material is smaller than the average particle size of the carbon material.
- the ratio (A / C) of the secondary particle diameter D50 (A) of the Si material to the secondary particle diameter D50 (C) of the carbon material is preferably less than 0.5, and is 0.3 or less.
- D50 (C) of the secondary particle diameter of the carbon material is relatively larger than D50 (A) of the secondary particle diameter of the Si material, the carbon material particles are uniformly arranged, and the carbon material particles are arranged between the carbon material particles. Since the Si material is arranged, the Si material can be uniformly arranged in the negative electrode active material layer.
- the particle size of the Si material having a relatively large capacity is equivalent to the particle size of the carbon material having a small capacity, the capacity distribution in the negative electrode active material layer surface can be evenly dispersed evenly. Will be prone to variations. Therefore, by reducing the particle size of the Si material having a relatively large capacity, variation in capacity within the negative electrode active material layer surface can be reduced.
- the lower limit value of A / C is not particularly limited, but is, for example, 0.01 or more.
- negative electrode active materials other than the two types of negative electrode active materials described above may be used in combination.
- the negative electrode active material that can be used in combination include lithium-transition metal composite oxides (for example, Li 4 Ti 5 O 12 ), metal materials, lithium alloy negative electrode materials, and the like. Of course, other negative electrode active materials may be used.
- the negative electrode active material layer contains a negative electrode active material represented by the following formula (1).
- the Si material is selected from the group consisting of SiO x (x is the number of oxygens satisfying the valence of Si), which is a mixture of amorphous SiO 2 particles and Si particles, and a Si-containing alloy. 1 type or 2 types or more.
- the carbon material is one or more selected from the group consisting of graphite, non-graphitizable carbon, and amorphous carbon. ⁇ and ⁇ represent mass% of each component in the negative electrode active material layer, and 80 ⁇ ⁇ + ⁇ ⁇ 98, 0.1 ⁇ ⁇ ⁇ 40, and 58 ⁇ ⁇ ⁇ 97.9.
- the content ( ⁇ ) of the Si material in the negative electrode active material layer is 0.1 to 40% by mass.
- the carbon material content ( ⁇ ) is 58 to 97.9% by mass.
- the total content ( ⁇ + ⁇ ) is 80 to 98% by mass.
- the mixing ratio of the Si material and the carbon material of the negative electrode active material is not particularly limited as long as the above-described content specification is satisfied, and can be appropriately selected according to a desired application.
- the effect of this form is effectively expressed by making the Si material content relatively small and the carbon material content relatively large as the mixing ratio of the Si material and the carbon material. It can be done.
- the content of the Si material ( ⁇ ) in the negative electrode active material is preferably in the range of 0.5 to 40% by mass, more preferably 1 to 30% by mass, and still more preferably 1 to 20% by mass. .
- the content of the Si material in the negative electrode active material layer is less than 0.1% by mass, it is difficult to obtain a high initial capacity.
- the content of the Si material exceeds 40% by mass, high cycle characteristics cannot be obtained.
- the content of the carbon material ( ⁇ ) in the negative electrode active material is preferably in the range of 58 to 97.5% by mass, more preferably 68 to 97% by mass, and still more preferably 78 to 97% by mass.
- the content of the carbon material in the negative electrode active material layer is less than 58% by mass, high cycle characteristics cannot be obtained.
- the content of the carbon material exceeds 97.9% by mass, it is difficult to obtain a high initial capacity.
- the content ( ⁇ + ⁇ ) of the Si material and the carbon material in the negative electrode active material layer is not particularly limited as long as the above-mentioned content regulations are satisfied, and can be appropriately selected according to a desired application.
- the content ( ⁇ + ⁇ ) of the Si material and the carbon material in the negative electrode active material layer is preferably in the range of 80 to 98% by mass, more preferably 85 to 97% by mass, and still more preferably 90 to 97% by mass. . If the content of the Si material and the carbon material in the negative electrode active material layer is less than 80% by mass, the weight energy density is lowered, which is not preferable. On the other hand, if the content of the Si material and the carbon material exceeds 98% by mass, the binder and the conductive additive are insufficient, which causes a decrease in battery performance.
- the negative electrode active material layer essentially contains a binder.
- the binder contained in the negative electrode active material layer preferably contains an aqueous binder.
- water-based binders can be greatly reduced in capital investment on the production line and can reduce the environmental burden because water is generated during drying. There is an advantage.
- the water-based binder refers to a binder using water as a solvent or a dispersion medium, and specifically includes a thermoplastic resin, a polymer having rubber elasticity, a water-soluble polymer, or a mixture thereof.
- the binder containing water as a dispersion medium refers to a polymer that includes all expressed as latex or emulsion and is emulsified or suspended in water.
- a polymer latex that is emulsion-polymerized in a system that self-emulsifies.
- kind a polymer latex that is emulsion-polymerized in a system that self-emulsifies.
- water-based binders include styrene polymers (styrene-butadiene rubber (SBR), styrene-vinyl acetate copolymer, styrene-acrylic copolymer, etc.), acrylonitrile-butadiene rubber, and methyl methacrylate-butadiene rubber.
- SBR styrene-butadiene rubber
- styrene-vinyl acetate copolymer styrene-acrylic copolymer
- acrylonitrile-butadiene rubber acrylonitrile-butadiene rubber
- methyl methacrylate-butadiene rubber methyl methacrylate-butadiene rubber
- (Meth) acrylic polymers (polyethyl acrylate, polyethyl methacrylate, polypropyl acrylate, polymethyl methacrylate (methyl methacrylate rubber), polypropyl methacrylate, polyisopropyl acrylate, polyisopropyl methacrylate, polybutyl acrylate, polybutyl methacrylate, Polyhexyl acrylate, Polyhexyl methacrylate, Polyethylhexyl acrylate, Polyethylhexyl methacrylate, Polylauryl acrylate, Polyra Yl methacrylate), polytetrafluoroethylene, polyethylene, polypropylene, ethylene-propylene copolymer, polybutadiene, butyl rubber, fluororubber, polyethylene oxide, polyepichlorohydrin, polyphosphazene, polyacrylonitrile, polystyrene, ethylene-propylene-diene copolymer
- the water-based binder includes at least one rubber-based binder selected from the group consisting of styrene-butadiene rubber (SBR), acrylonitrile-butadiene rubber, methyl methacrylate-butadiene rubber, and methyl methacrylate rubber from the viewpoint of binding properties. It is preferable to include. Furthermore, it is preferable that the water-based binder contains styrene-butadiene rubber (SBR) because of good binding properties.
- SBR styrene-butadiene rubber
- a thickener When using an aqueous binder, it is preferable to use a thickener together. This is because the water-based binder has a strong binding property (binding effect), but the thickening is not sufficient. Therefore, a sufficient thickening effect cannot be obtained simply by adding an aqueous binder to the aqueous slurry during electrode production. Therefore, thickening is imparted to the aqueous binder by using a thickener that is excellent in thickening.
- the thickener is not particularly limited. For example, polyvinyl alcohol (average polymerization degree is preferably 200 to 4000, more preferably 1000 to 3000, and saponification degree is preferably 80 mol%.
- styrene-butadiene rubber suitable as a water-based binder
- thickeners suitable for use in combination with styrene-butadiene rubber include polyvinyl alcohol and modified products thereof, starch and modified products thereof, cellulose derivatives (carboxymethylcellulose (CMC), methylcellulose, hydroxyethylcellulose, and the like) Salt), polyvinylpyrrolidone, polyacrylic acid (salt), or polyethylene glycol.
- SBR styrene-butadiene rubber
- CMC carboxymethyl cellulose
- salt thereof CMC (salt)
- SBR styrene-butadiene rubber
- CMC carboxymethyl cellulose
- the content of the aqueous binder in the binder used for the negative electrode active material layer is preferably 80 to 100% by mass, preferably 90 to 100% by mass, It is preferable that it is mass%.
- the binder other than the water-based binder include binders used for the positive electrode active material layer.
- the amount of the binder contained in the negative electrode active material layer is not particularly limited as long as it can bind the active material, but is preferably 0 with respect to 100% by mass of the total amount of the negative electrode active material layer. 0.5 to 15% by mass, more preferably 1 to 10% by mass, further preferably 1 to 8% by mass, particularly preferably 2 to 4% by mass, and most preferably 2.5 to 3%. 0.5% by mass. Since the water-based binder has a high binding force, the active material layer can be formed with a small amount of addition as compared with the organic solvent-based binder.
- the amount of the thickener contained in the negative electrode active material layer includes the content ratio of the aqueous binder (SBR) and the thickener, the amount of binder contained in the negative electrode active material layer, and the negative electrode active material layer. It is calculated
- the difference between the maximum value and the minimum value of the area ratio (%) occupied by the binder in the visual field area of each image of the cross section of the negative electrode active material layer when a plurality of arbitrary locations in the negative electrode active material layer plane are selected is 10. % Or less. That is, in the case of a large-sized battery having a large capacity and a large area, in the negative electrode active material layer surface, when there are a lot of binders and a few places, a binder-less part has a low binding property inside the electrode. The expansion of the electrode increases. On the other hand, the portion where the binder is large has a high binding property inside the electrode, so that the expansion of the electrode is small.
- the distance between the positive electrode and the negative electrode is shortened at a position where the expansion of the electrode is large, and the distance between the positive electrode and the negative electrode is increased at a position where the expansion of the electrode is small.
- the reaction is accelerated because the resistance is small and the amount of current is increased at a position where the distance between the electrodes is short, and the reaction is difficult to proceed because the resistance is increased and the amount of current is decreased at a position where the distance between the electrodes is long. That is, reaction non-uniformity occurs in the negative electrode active material layer surface.
- acceleration of a side reaction with the electrolytic solution and acceleration of deterioration of the active material occur, so that the cycle durability of the battery is remarkably lowered.
- controlling the dispersion of the binder dispersibility to within 10% has solved the above problem, and can be said to have greatly improved the cycle durability of the battery. .
- binding dispersion variation within 10% in a large battery having a large capacity and a large area, variation in expansion amount during charging in the negative electrode active material layer surface is small.
- the phenomenon in which the non-uniformity of reactivity with Li ions due to an increase in the distance between the positive electrode and the negative electrode and a decrease in the certain area is suppressed, and the cycle durability of the battery is suppressed. Will improve.
- the dispersion of the dispersibility of the binder in the negative electrode active material layer is within 10%, in the above-described large battery, the portion where the binder is insufficient in the negative electrode active material layer is reduced. This prevents the active material from falling off and improves the cycle durability of the battery.
- Difference between the maximum value and the minimum value of the area ratio (%) occupied by the binder in the visual field area of each image of the cross section of the negative electrode active material layer when a plurality of arbitrary locations in the surface of the negative electrode active material layer are selected (dispersibility of the binder) Is preferably within 9.4%, more preferably within 5%, and particularly preferably within 3.6%.
- the arbitrary position in the negative electrode active material layer surface is the vicinity of the end portion, the central portion, the end portion and the central portion in the negative electrode active material layer surface. It is only necessary to select so that the vicinity of the intermediate portion is included in a balanced manner.
- a plurality (two or more) of arbitrary locations in the negative electrode active material layer surface may be selected. From the viewpoint of measuring the dispersion of the binder dispersibility in the negative electrode active material layer surface as described above, five or more locations are available. Is preferred. Specifically, for example, in the negative electrode active material layer surface shown in FIG. 3A, the vicinity of the end portion, the central portion, and the intermediate portion between the end portion and the central portion in the negative electrode active material layer surface are included in a well-balanced manner. The location where the diagonal line (dotted line) is equally divided into 6 (locations with numbers 1 to 5 in FIG. 3A) can be selected as appropriate. However, it is not limited to the one shown in FIG.
- an end in the negative electrode active material layer surface may be selected, such as a location where the longitudinal axis passing through the center point in the negative electrode active material layer surface and the short axis are appropriately divided into six (or more).
- an end in the negative electrode active material layer surface may be selected, such as a location where the longitudinal axis passing through the center point in the negative electrode active material layer surface and the short axis are appropriately divided into six (or more).
- a place where the diagonal line (one-dot broken line) in the negative electrode active material layer surface shown in FIG. 3 (a) is equally divided into six (places numbered 1 to 5 in FIG.
- FIG. 3A shows a rectangular negative electrode which is a constituent member of a lithium ion secondary battery that is not a flat type (stacked type) bipolar type, which is an embodiment of the nonaqueous electrolyte secondary battery according to the present invention.
- FIG. 3B is a cross-sectional view taken along a diagonal line (a dashed line) connecting diagonal lines in the rectangular negative electrode surface of FIG.
- Each image of the negative electrode active material layer cross section corresponds to an arbitrary position in the negative electrode active material layer plane in the negative electrode active material layer cross section cut so as to include the arbitrary position in the negative electrode active material layer plane.
- Each image of the secondary electron image or the reflected electron image observed by the electron microscope of the cross section is used.
- each image of the cross-section of the negative electrode active material layer includes five or five places with the numbers 1 to 5 in FIG. 3B corresponding to the positions 1 to 5 in FIG.
- Each image of a secondary electron image or a reflected electron image observed with an electron microscope in the vicinity can be used.
- each image of the reflected electron image observed with an electron microscope at five places indicated by numerals 1 to 5 in FIG. 3B or in the vicinity thereof (hatched portion in the figure) was used.
- the visual field area of each image of the cross section of the negative electrode active material layer is the whole of each image of the reflected electron image observed by the electron microscope at an arbitrary position in the thickness direction of the cross section corresponding to an arbitrary position in the negative electrode active material layer plane.
- the area of the entire field of view can be used.
- the field area of each image of the negative electrode active material layer cross section is not particularly limited.
- the vertical (thickness direction) is the thickness of the negative electrode active material layer
- the horizontal (direction perpendicular to the thickness direction) is 100 ⁇ m.
- the rectangle is used. More preferably, a rectangle having a thickness of the negative electrode active material layer and a width of 50 ⁇ m is used.
- a rectangle having a thickness of the negative electrode active material layer and a width of 25 ⁇ m is used.
- the “field-of-view area of each image of the cross section of the negative electrode active material layer” the entire backscattered electron image observed by an electron microscope at five locations shown in FIG. 3B or in the vicinity thereof (shaded portion in the drawing). The area of the entire field of view (the vertical is the thickness of the negative electrode active material layer and the horizontal is a rectangular area of 100 ⁇ m) was used.
- the method for calculating the area ratio (%) occupied by the binder in the visual field area of each image of the negative electrode active material layer cross section is not limited, but for example, the following image processing of the negative electrode active material layer cross section There is a method by. That is, after the negative electrode is subjected to cross-section processing by an arbitrary cross-section processing method, Os is added to the binder in the cross-section of the negative electrode active material layer.
- the secondary electron image or the reflected electron image observed by the electron microscope is set to a threshold value that distinguishes a portion other than the binder and the binder added with Os for the cross-sectional portion corresponding to an arbitrary place in the negative electrode active material layer surface.
- the method of binarizing and calculating can be used. Specifically, a secondary electron image or a reflected electron image is taken with an electron microscope using Os, and image processing software is used for the image.
- the image processing software is not limited. For example, AxioVision manufactured by Carl Zeiss, WinROOF manufactured by Mitani Corporation, Image-Pro manufactured by Media Cybernetics, and the like can be used.
- the amount of binder area in the visual field area of each image of the negative electrode active material layer cross section is calculated by setting an appropriate threshold that can distinguish the binder added with Os and the contrast other than the binder. can do.
- the contrast can be identified using the reflected electron image only by adding Os, but it is more preferable that the mapping is performed by using EDX.
- the above-described method using Os is a method that can be suitably used for a polymer (rubber) having an unsaturated double bond such as SBR that is a water-based binder in the binder. It is.
- an organic solvent-based binder such as PVDF can be calculated using fluorine instead of Os.
- an organic solvent-based binder such as PVDF can extract F (fluorine) by SEM-EDX mapping and calculate the area ratio (%) occupied by the binder by image processing.
- the above-described variation in the dispersibility of the binder is the content using one negative electrode, but it is preferable to perform the same variation measurement on a plurality of sheets, and more specifically, three or more sheets are preferable. More than one sheet is more preferable, and seven sheets or more are more preferable.
- the dispersion (stirring and mixing) time at the time of producing the negative electrode active material (aqueous) slurry may be mainly changed and adjusted.
- adjustment may be made mainly by changing the type and rotation speed of the dispersion mixer.
- the negative electrode active material layer has a conductive additive, an electrolyte (polymer matrix, ion conductive polymer, electrolytic solution, etc.), ion conductivity, etc. It further includes other additives such as lithium salts to enhance.
- the conductive assistant refers to an additive that is blended in order to improve the conductivity of the positive electrode active material layer or the negative electrode active material layer.
- carbon black such as acetylene black, ketjen black and furnace black
- carbon powder such as channel black, thermal black and graphite
- various carbon fibers such as vapor grown carbon fiber (VGCF; registered trademark)
- VGCF vapor grown carbon fiber
- Examples thereof include carbon materials such as expanded graphite.
- the content of the conductive additive in the negative electrode active material layer is preferably 1 to 10% by mass, more preferably 1 to 8% by mass.
- the lithium salt is contained in the negative electrode active material layer when the electrolyte described above penetrates into the negative electrode active material layer. Therefore, the specific form of the lithium salt that can be contained in the negative electrode active material layer is the same as the lithium salt that constitutes the electrolyte.
- the lithium salt Li (C 2 F 5 SO 2) 2 N, LiPF 6, LiBF 4, LiClO 4, LiAsF 6, LiCF 3 SO 3 , and the like.
- Non conductive polymer examples include polyethylene oxide (PEO) -based and polypropylene oxide (PPO) -based polymers.
- the compounding ratio of the components contained in the negative electrode active material layer is not particularly limited.
- the blending ratio can be adjusted by appropriately referring to known knowledge about lithium ion secondary batteries.
- the negative electrode (negative electrode active material layer) can be applied by any one of a kneading method, a sputtering method, a vapor deposition method, a CVD method, a PVD method, an ion plating method, and a thermal spraying method in addition to a method of applying (coating) a normal slurry. Can be formed.
- each active material layer (active material layer on one side of the current collector) is not particularly limited, and conventionally known knowledge about the battery can be appropriately referred to.
- the thickness of each active material layer is usually about 1 to 500 ⁇ m, preferably 2 to 100 ⁇ m, taking into consideration the intended use of the battery (emphasis on output, energy, etc.) and ion conductivity.
- each active material layer (positive electrode active material layer and negative electrode active material layer) is 10 to 45% by volume, preferably 15 to 40% by volume, more preferably 20 to 35% with respect to the total volume of the active material layer. It is in the range of volume%. If the porosity is within the above range, the pores of each active material layer are impregnated with the electrolyte solution inside each active material layer without damaging the characteristics and strength such as battery capacity, and the electrode reaction is promoted. This is because it can effectively function as a path for supplying the electrolytic solution (Li + ions).
- the difference between the maximum value and the minimum value of the area ratio (%) of vacancies in each image of the negative electrode active material layer cross section when a plurality of arbitrary locations in the negative electrode active material layer surface are selected is within 10%.
- the above problem is an inherent new problem that occurs only when a large battery having a large capacity and a large area is formed using a combination of Si material and carbon material.
- charging within the negative electrode active material layer surface can be controlled by controlling the dispersion of the above-mentioned binder within 10%. Since the variation in the amount of expansion of Si at the time becomes small, it is considered that the above problem has been solved. Thus, it can be said that the cycle durability of the battery can be greatly improved.
- Difference between the maximum value and the minimum value of the area ratio (%) of vacancies in each image of the cross section of the negative electrode active material layer (variation in the dispersibility of vacancies) when multiple arbitrary locations in the negative electrode active material layer surface are selected ) Is preferably within 10%, more preferably within 8.5%, even more preferably within 7%, particularly preferably within 6%, and particularly preferably within 5.3%.
- the arbitrary positions in the negative electrode active material layer surface are the vicinity of the end, the vicinity of the center, the end and the center in the negative electrode active material layer surface. What is necessary is just to select so that the intermediate part vicinity of a part may be included with sufficient balance.
- a plurality (two or more) of arbitrary locations in the surface of the negative electrode active material layer may be selected. From the viewpoint of measuring dispersion of vacancies in the surface of the negative electrode active material layer as described above, there are five locations. The above is preferable. Specifically, for example, in the negative electrode active material layer surface shown in FIG. 3A, the vicinity of the end portion, the central portion, and the intermediate portion between the end portion and the central portion in the negative electrode active material layer surface are included in a well-balanced manner. The location where the diagonal line (dotted line) is equally divided into 6 (locations with numbers 1 to 5 in FIG. 3A) can be selected as appropriate. However, the present invention is not limited to the one shown in FIG.
- 3A may further include a place obtained by dividing the other diagonal line crossing the diagonal line shown in FIG. 3A into six equal parts (or more). .
- a location in which the longitudinal axis passing through the center point in the negative electrode active material layer surface and the axial axis in the short direction may be appropriately divided into three equal parts or more, such as near the end in the negative electrode active material layer surface, the center
- the vicinity of the portion and the vicinity of the intermediate portion between the end portion and the central portion are included in a balanced manner.
- a place where the diagonal line (one-dot broken line) in the negative electrode active material layer surface shown in FIG. 3 (a) is equally divided into six (places numbered 1 to 5 in FIG. 3 (a)) is selected. did.
- Each image of the negative electrode active material layer cross section corresponds to an arbitrary position in the negative electrode active material layer plane in the negative electrode active material layer cross section cut so as to include the arbitrary position in the negative electrode active material layer plane.
- Each image of the secondary electron image or the reflected electron image observed by the electron microscope of the cross section is used.
- each image of the cross-section of the negative electrode active material layer includes five or five places with the numbers 1 to 5 in FIG. 3B corresponding to the positions 1 to 5 in FIG.
- Each image of a secondary electron image or a reflected electron image observed with an electron microscope in the vicinity can be used.
- each image of the reflected electron image observed with an electron microscope at five places indicated by numerals 1 to 5 in FIG. 3B or in the vicinity thereof (hatched portion in the figure) was used.
- the area of each image of the negative electrode active material layer cross section is the total of each image of the backscattered electron image observed by an electron microscope at an arbitrary position in the thickness direction of the cross section corresponding to an arbitrary position in the negative electrode active material layer plane ( The total field of view) can be used.
- the area of each image of the cross section of the negative electrode active material layer is not particularly limited.
- the vertical (thickness direction) is the thickness of the negative electrode active material layer
- the horizontal (direction perpendicular to the thickness direction) is 100 ⁇ m.
- a rectangle having a thickness of the negative electrode active material layer and a width of 25 ⁇ m is used.
- each image (area) of the cross section of the negative electrode active material layer reflected electron images observed by an electron microscope at five locations shown in FIG. 3B or in the vicinity thereof (shaded portions in the drawing).
- the entire area (the entire visual field) (the vertical area is the thickness of the negative electrode active material layer and the horizontal area is a rectangular area of 100 ⁇ m) was used.
- the method for calculating the area ratio (%) of vacancies in each image of the negative electrode active material layer cross section is not limited, but for example, the following image processing method of the negative electrode active material layer cross section may be used. is there. That is, after the negative electrode is subjected to cross-section processing by an arbitrary cross-section processing method, a secondary electron image or a reflected electron image observed by an electron microscope is obtained on the cross-sectional portion corresponding to an arbitrary position in the negative electrode active material layer surface. It is possible to use a method of binarizing and calculating with a threshold value that distinguishes solid parts other than holes.
- a secondary electron image or a reflected electron image is taken with an electron microscope, and image processing software is used for the image.
- the image processing software is not limited. For example, AxioVision manufactured by Carl Zeiss, WinROOF manufactured by Mitani Corporation, Image-Pro manufactured by Media Cybernetics, and the like can be used.
- AxioVision manufactured by Carl Zeiss, WinROOF manufactured by Mitani Corporation, Image-Pro manufactured by Media Cybernetics, and the like can be used.
- the binarization process by setting an appropriate threshold value that can distinguish the contrast between the solid portion and the vacancies, the amount of vacancies in the area of each image of the negative electrode active material layer cross section can be calculated.
- distribution of the porosity mentioned above was demonstrated using the negative electrode of 1 sheet, it is preferable to perform the same dispersion
- adjustment may be made mainly by changing the solid content ratio of the slurry, the dispersion time when the slurry is dispersed, and the number of rotations.
- the adjustment may be made mainly by changing the mixer type or the like.
- the current collectors (11, 12) are made of a conductive material.
- the size of the current collector is determined according to the intended use of the battery. For example, if it is used for a large battery that requires a high energy density, a current collector having a large area is used.
- the thickness of the current collector is usually about 1 to 100 ⁇ m.
- the shape of the current collector is not particularly limited.
- a mesh shape (such as an expanded grid) can be used.
- the negative electrode active material is formed directly on the negative electrode current collector 12 by sputtering or the like, it is preferable to use a current collector foil.
- a metal or a resin in which a conductive filler is added to a conductive polymer material or a non-conductive polymer material can be employed.
- examples of the metal include aluminum, nickel, iron, stainless steel, titanium, and copper.
- a clad material of nickel and aluminum, a clad material of copper and aluminum, or a plating material of a combination of these metals can be preferably used.
- covered on the metal surface may be sufficient.
- aluminum, stainless steel, copper, and nickel are preferable from the viewpoints of electronic conductivity, battery operating potential, and adhesion of the negative electrode active material by sputtering to the current collector.
- examples of the conductive polymer material include polyaniline, polypyrrole, polythiophene, polyacetylene, polyparaphenylene, polyphenylene vinylene, polyacrylonitrile, and polyoxadiazole. Since such a conductive polymer material has sufficient conductivity without adding a conductive filler, it is advantageous in terms of facilitating the manufacturing process or reducing the weight of the current collector.
- Non-conductive polymer materials include, for example, polyethylene (PE; high density polyethylene (HDPE), low density polyethylene (LDPE), etc.), polypropylene (PP), polyethylene terephthalate (PET), polyether nitrile (PEN), polyimide (PI), polyamideimide (PAI), polyamide (PA), polytetrafluoroethylene (PTFE), styrene-butadiene rubber (SBR), polyacrylonitrile (PAN), polymethyl acrylate (PMA), polymethyl methacrylate (PMMA) , Polyvinyl chloride (PVC), polyvinylidene fluoride (PVdF), or polystyrene (PS).
- PE polyethylene
- HDPE high density polyethylene
- LDPE low density polyethylene
- PP polypropylene
- PET polyethylene terephthalate
- PEN polyether nitrile
- PI polyimide
- PAI polyamideimide
- PA polyamide
- PTFE polytetraflu
- a conductive filler may be added to the conductive polymer material or the non-conductive polymer material as necessary.
- a conductive filler is inevitably necessary to impart conductivity to the resin.
- the conductive filler can be used without particular limitation as long as it has a conductivity.
- metals, conductive carbon, etc. are mentioned as a material excellent in electroconductivity, electric potential resistance, or lithium ion barrier
- the metal is not particularly limited, but at least one metal selected from the group consisting of Ni, Ti, Al, Cu, Pt, Fe, Cr, Sn, Zn, In, Sb, and K, or these metals It is preferable to contain an alloy or metal oxide containing.
- it includes at least one selected from the group consisting of acetylene black, vulcan, black pearl, carbon nanofiber, ketjen black, carbon nanotube, carbon nanohorn, carbon nanoballoon, and fullerene.
- the amount of the conductive filler added is not particularly limited as long as it is an amount capable of imparting sufficient conductivity to the current collector, and is generally about 5 to 35% by mass.
- the separator has a function of holding an electrolyte and ensuring lithium ion conductivity between the positive electrode and the negative electrode, and a function as a partition wall between the positive electrode and the negative electrode.
- separator examples include a separator made of a porous sheet made of a polymer or fiber that absorbs and holds the electrolyte and a nonwoven fabric separator.
- a microporous (microporous film) can be used as the separator of the porous sheet made of polymer or fiber.
- the porous sheet made of the polymer or fiber include polyolefins such as polyethylene (PE) and polypropylene (PP); a laminate in which a plurality of these are laminated (for example, three layers of PP / PE / PP) And a microporous (microporous membrane) separator made of a hydrocarbon resin such as polyimide, aramid, polyvinylidene fluoride-hexafluoropropylene (PVdF-HFP), glass fiber, and the like.
- PE polyethylene
- PP polypropylene
- a microporous (microporous membrane) separator made of a hydrocarbon resin such as polyimide, aramid, polyvinylidene fluoride-hexafluoropropylene (PVdF-HFP), glass fiber, and the like.
- the thickness of the microporous (microporous membrane) separator cannot be uniquely defined because it varies depending on the intended use. For example, in applications such as secondary batteries for driving motors such as electric vehicles (EV), hybrid electric vehicles (HEV), and fuel cell vehicles (FCV), it is 4 to 60 ⁇ m in a single layer or multiple layers. Is desirable.
- the fine pore diameter of the microporous (microporous membrane) separator is desirably 1 ⁇ m or less (usually a pore diameter of about several tens of nm).
- nonwoven fabric separator cotton, rayon, acetate, nylon, polyester; polyolefins such as PP and PE; conventionally known ones such as polyimide and aramid are used alone or in combination.
- the bulk density of the nonwoven fabric is not particularly limited as long as sufficient battery characteristics can be obtained by the impregnated electrolyte.
- the thickness of the nonwoven fabric separator may be the same as that of the electrolyte layer, and is preferably 5 to 200 ⁇ m, particularly preferably 10 to 100 ⁇ m.
- the separator includes an electrolyte.
- the electrolyte is not particularly limited as long as it can exhibit such a function, but a liquid electrolyte or a gel polymer electrolyte is used.
- a gel polymer electrolyte By using the gel polymer electrolyte, the distance between the electrodes is stabilized, the occurrence of polarization is suppressed, and the durability (cycle characteristics) is improved.
- the liquid electrolyte functions as a lithium ion carrier.
- the liquid electrolyte constituting the electrolytic solution layer has a form in which a lithium salt as a supporting salt is dissolved in an organic solvent as a plasticizer.
- organic solvent include carbonates such as ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), diethyl carbonate (DEC), and ethyl methyl carbonate.
- EC ethylene carbonate
- PC propylene carbonate
- DMC dimethyl carbonate
- DEC diethyl carbonate
- ethyl methyl carbonate ethyl methyl carbonate.
- Li (CF 3 SO 2) 2 N Li (C 2 F 5 SO 2) 2 N, LiPF 6, LiBF 4, LiClO 4, LiAsF 6, LiTaF such 6, LiCF 3 SO 3
- a compound that can be added to the active material layer of the electrode can be similarly employed.
- the liquid electrolyte may further contain additives other than the components described above.
- additives include, for example, vinylene carbonate, methyl vinylene carbonate, dimethyl vinylene carbonate, phenyl vinylene carbonate, diphenyl vinylene carbonate, ethyl vinylene carbonate, diethyl vinylene carbonate, vinyl ethylene carbonate, 1,2-divinyl ethylene carbonate.
- vinylene carbonate, methyl vinylene carbonate, and vinyl ethylene carbonate are preferable, and vinylene carbonate and vinyl ethylene carbonate are more preferable.
- These cyclic carbonates may be used alone or in combination of two or more.
- the gel polymer electrolyte has a configuration in which the above liquid electrolyte is injected into a matrix polymer (host polymer) made of an ion conductive polymer.
- a gel polymer electrolyte as the electrolyte is superior in that the fluidity of the electrolyte is lost and the ion conductivity between the layers is easily cut off.
- ion conductive polymer used as the matrix polymer (host polymer) examples include polyethylene oxide (PEO), polypropylene oxide (PPO), polyethylene glycol (PEG), polyacrylonitrile (PAN), polyvinylidene fluoride-hexafluoropropylene ( PVdF-HEP), poly (methyl methacrylate (PMMA), and copolymers thereof.
- PEO polyethylene oxide
- PPO polypropylene oxide
- PEG polyethylene glycol
- PAN polyacrylonitrile
- PVdF-HEP polyvinylidene fluoride-hexafluoropropylene
- PMMA methyl methacrylate
- the matrix polymer of gel electrolyte can express excellent mechanical strength by forming a crosslinked structure.
- thermal polymerization, ultraviolet polymerization, radiation polymerization, electron beam polymerization, etc. are performed on a polymerizable polymer (for example, PEO or PPO) for forming a polymer electrolyte using an appropriate polymerization initiator.
- a polymerization treatment may be performed.
- the separator is preferably a separator (a separator with a heat-resistant insulating layer) in which a heat-resistant insulating layer is laminated on a porous substrate such as a porous sheet separator or a nonwoven fabric separator.
- the heat resistant insulating layer is a ceramic layer containing inorganic particles and a binder.
- As the separator with a heat-resistant insulating layer a highly heat-resistant separator having a melting point or a heat softening point of 150 ° C. or higher, preferably 200 ° C. or higher is used.
- the separator is less likely to curl in the battery manufacturing process due to the effect of suppressing thermal shrinkage and high mechanical strength.
- the inorganic particles in the heat resistant insulating layer contribute to the mechanical strength and heat shrinkage suppressing effect of the heat resistant insulating layer.
- the material used as the inorganic particles is not particularly limited. Examples thereof include silicon, aluminum, zirconium, titanium oxides (SiO 2 , Al 2 O 3 , ZrO 2 , TiO 2 ), hydroxides and nitrides, and composites thereof. These inorganic particles may be derived from mineral resources such as boehmite, zeolite, apatite, kaolin, mullite, spinel, olivine and mica, or may be artificially produced. Moreover, only 1 type may be used individually for these inorganic particles, and 2 or more types may be used together. Of these, silica (SiO 2 ) or alumina (Al 2 O 3 ) is preferably used, and alumina (Al 2 O 3 ) is more preferably used from the viewpoint of cost.
- the basis weight of the heat-resistant particles is not particularly limited, but is preferably 5 to 15 g / m 2 . If it is this range, sufficient ion conductivity will be acquired and it is preferable at the point which maintains heat resistant strength.
- the binder in the heat-resistant insulating layer has a role of adhering the inorganic particles and the inorganic particles to the porous substrate (resin porous substrate layer). With the binder, the heat-resistant insulating layer is stably formed, and peeling between the porous substrate (porous substrate layer) and the heat-resistant insulating layer is prevented.
- the binder used for the heat-resistant insulating layer is not particularly limited.
- a compound such as butadiene rubber, polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), polyvinyl fluoride (PVF), or methyl acrylate can be used as the binder.
- PVDF polyvinylidene fluoride
- PTFE polytetrafluoroethylene
- PVF polyvinyl fluoride
- methyl acrylate methyl acrylate
- PVDF polyvinylidene fluoride
- these compounds only 1 type may be used independently and 2 or more types may be used together.
- the binder content in the heat-resistant insulating layer is preferably 2 to 20% by mass with respect to 100% by mass of the heat-resistant insulating layer.
- the binder content is 2% by mass or more, the peel strength between the heat-resistant insulating layer and the porous substrate (porous substrate layer) can be increased, and the vibration resistance of the separator can be improved.
- the binder content is 20% by mass or less, the gaps between the inorganic particles are appropriately maintained, so that sufficient lithium ion conductivity can be ensured.
- the thermal contraction rate of the separator with a heat-resistant insulating layer is preferably 10% or less for both MD and TD after holding for 1 hour at 150 ° C. and 2 gf / cm 2 .
- a current collector plate (tab) electrically connected to a current collector is taken out of a laminate film as an exterior material for the purpose of taking out current outside the battery.
- the material constituting the current collector plate is not particularly limited, and a known highly conductive material conventionally used as a current collector plate for a lithium ion secondary battery can be used.
- a constituent material of the current collector plate for example, metal materials such as aluminum, copper, titanium, nickel, stainless steel (SUS), and alloys thereof are preferable. From the viewpoint of light weight, corrosion resistance, and high conductivity, aluminum and copper are more preferable, and aluminum is particularly preferable. Note that the same material may be used for the positive electrode current collector plate (positive electrode tab) and the negative electrode current collector plate (negative electrode tab), or different materials may be used.
- the tabs 58 and 59 shown in FIG. 2 are not particularly limited.
- the positive electrode tab 58 and the negative electrode tab 59 may be drawn out from the same side, or the positive electrode tab 58 and the negative electrode tab 59 may be divided into a plurality of parts and taken out from each side, as shown in FIG. It is not limited to.
- a terminal may be formed using a cylindrical can (metal can).
- the seal portion is a member unique to the serially stacked battery and has a function of preventing leakage of the electrolyte layer. In addition to this, it is possible to prevent current collectors adjacent in the battery from coming into contact with each other and a short circuit due to a slight unevenness at the end of the laminated electrode.
- the constituent material of the seal part is not particularly limited, but polyolefin resin such as polyethylene and polypropylene, epoxy resin, rubber, polyimide and the like can be used. Among these, it is preferable to use a polyolefin resin from the viewpoints of corrosion resistance, chemical resistance, film-forming property, economy, and the like.
- ⁇ Positive terminal lead and negative terminal lead> As a material for the negative electrode and the positive electrode terminal lead, a lead used in a known laminated secondary battery can be used.
- the parts removed from the battery exterior material should be heat-insulating so that they do not affect products (for example, automobile parts, especially electronic devices) by touching peripheral devices or wiring and causing leakage. It is preferable to coat with a heat shrinkable tube or the like.
- a conventionally known metal can case can be used as the battery outer package.
- the power generation element 21 may be packed using a laminate film 29 as shown in FIG.
- the laminate film can be configured as a three-layer structure in which, for example, polypropylene, aluminum, and nylon are laminated in this order. By using such a laminate film, it is possible to easily open the exterior material, add the capacity recovery material, and reseal the exterior material.
- a laminate film is desirable from the viewpoint that it is excellent in high output and cooling performance, and can be suitably used for a battery for large equipment for EV and HEV.
- the exterior body is made of a laminate film containing aluminum (for example, Aluminum laminate sheet bags; see examples) are more preferred.
- a laminate film containing aluminum an aluminum laminate film in which the above-described polypropylene, aluminum, and nylon are laminated in this order can be used.
- FIG. 2 is a perspective view showing the appearance of a flat lithium ion secondary battery which is a typical embodiment of the secondary battery.
- a flat laminated battery having a structure in which the power generation element is enclosed in a battery outer package made of a laminate film containing aluminum.
- the flat lithium ion secondary battery 50 has a rectangular flat shape, and a positive electrode tab 58 and a negative electrode tab 59 for taking out electric power are drawn out from both sides thereof.
- the power generation element 57 is encased by the battery outer packaging material 52 of the lithium ion secondary battery 50, and the periphery thereof is heat-sealed. The power generation element 57 is sealed with the positive electrode tab 58 and the negative electrode tab 59 pulled out to the outside.
- the power generation element 57 corresponds to the power generation element 21 of the lithium ion secondary battery 10 shown in FIG. 1 described above.
- the power generation element 57 is formed by laminating a plurality of single battery layers (single cells) 19 composed of a positive electrode (positive electrode active material layer) 15, an electrolyte layer 17, and a negative electrode (negative electrode active material layer) 13.
- the lithium ion secondary battery is not limited to a stacked flat shape.
- the wound lithium ion secondary battery may have a cylindrical shape, or may have a shape that is a flattened rectangular shape by deforming such a cylindrical shape.
- a laminate film may be used for the exterior material, and the conventional cylindrical can (metal can) may be used, for example, It does not restrict
- the power generation element is covered with an aluminum laminate film. With this configuration, weight reduction can be achieved.
- the tabs 58 and 59 shown in FIG. 2 are not particularly limited.
- the positive electrode tab 58 and the negative electrode tab 59 may be drawn out from the same side, or the positive electrode tab 58 and the negative electrode tab 59 may be divided into a plurality of parts and taken out from each side, as shown in FIG. It is not limited to.
- a terminal may be formed using a cylindrical can (metal can).
- the battery storage space is about 170L. Since auxiliary devices such as batteries and charge / discharge control devices are stored in this space, the storage space efficiency of the battery is usually about 50%. The efficiency of battery loading in this space is a factor that governs the cruising range of electric vehicles. If the size of the battery is reduced, the loading efficiency is impaired, and the cruising distance cannot be secured.
- the battery structure in which the power generation element is covered with the exterior body is preferably large.
- the negative electrode active material layer is preferably rectangular (rectangular), and the length of the short side of the rectangle is preferably 100 mm or more.
- the length of the short side of the negative electrode active material layer refers to the side having the shortest length among the electrodes.
- the upper limit of the short side length is not particularly limited, but is usually 400 mm or less.
- the volume energy density of the battery is preferably 157 Wh / L or more, and the rated capacity is preferably 20 Ah or more.
- the nonaqueous electrolyte secondary battery according to this embodiment has a ratio of battery volume (product of the projected area and thickness of the battery including the battery outer casing) to the rated capacity of 10 cm 3 / Ah or less. And the rated capacity is 3 Ah or more.
- This large-sized battery has a large battery capacity per unit volume (10 Ah / cm 3 or more), in other words, a small battery volume per unit capacity (ratio of the battery volume to the rated capacity) (10 cm 3 / Ah or less),
- the battery capacity (rated capacity) is defined as being large (3 Ah or more).
- the use of a Si material and a carbon material in combination with the negative electrode active material prescribes a large battery that has a large capacity and expands more than ever.
- the value of the ratio of the battery volume to the rated capacity exceeds 10 cm 3 / Ah
- the capacity is small even if the variation occurs, and the influence of the variation is small.
- the ratio of the battery volume to the rated capacity may be less than 2 cm 3 / Ah.
- this embodiment uses a negative electrode active material with a small amount of Si material, and it is not easy to further increase the battery capacity per unit volume.
- the rated capacity is less than 3 Ah, the capacity is small and the influence of variation is small, and it is insufficient for a large-sized battery.
- the upper limit of the ratio of the battery volume (product of the projected area and thickness of the battery including the battery outer package) to the rated capacity is preferably 8 cm 3 / Ah or less.
- the lower limit of the ratio of the battery volume to the rated capacity (the product of the projected area and thickness of the battery including the battery outer package) is not particularly limited, but may be 2 cm 3 / Ah or more, Preferably, it is 3 cm 3 / Ah or more.
- the rated capacity is preferably 5 Ah or more, more preferably 10 Ah or more, further preferably 15 Ah or more, particularly preferably 20 Ah or more, and particularly preferably 25 Ah or more.
- the rated capacity of the battery is obtained as follows.
- the rated capacity of the test battery is measured by the following procedures 1 to 5 at a temperature of 25 ° C. and a voltage range of 3.0 V to 4.15 V after injecting the electrolytic solution and then standing for about 10 hours.
- the For batteries (products) such as commercial products, it has been 10 hours or more after the injection of the electrolyte, and therefore the rated capacity can be obtained by performing the following procedures 1 to 5.
- Procedure 2 After Procedure 1, charge for 1.5 hours with constant voltage charging and rest for 5 minutes. *
- Procedure 3 After reaching 3.0 V by constant current discharge of 0.1 C, discharge by constant voltage discharge for 2 hours, and then rest for 10 seconds. *
- Procedure 4 After reaching 4.1 V by constant current charging at 0.1 C, charge for 2.5 hours by constant voltage charging, and then rest for 10 seconds. *
- Procedure 5 After reaching 3.0 V by constant current discharge of 0.1 C, discharge at constant voltage discharge for 2 hours, and then stop for 10 seconds. *
- the discharge capacity (CCCV discharge capacity) in the discharge from the constant current discharge to the constant voltage discharge in the procedure 5 is defined as the rated capacity.
- the battery volume is obtained from the product of the projected area and thickness of the battery including the battery outer package.
- the projected area of the battery including the battery outer casing the projected area of the six batteries of the front, back, right side, left side, plane, and bottom can be obtained. Usually, this is the projected area of the battery on the flat or bottom surface when the battery is placed in the most stable state on the flat plate.
- the thickness of the battery including the battery outer package is measured at the time of full charge.
- eight or more places are measured in consideration of variation depending on the measurement place, and these are averaged. For example, in the example, the thickness of the battery including the battery outer package at or near the portion represented by the numerals 1 to 9 shown in FIG. 2 was measured and averaged.
- the aspect ratio of the rectangular electrode is preferably 1 to 3, and more preferably 1 to 2.
- the electrode aspect ratio is defined as the aspect ratio of the rectangular positive electrode active material layer.
- the manufacturing method in particular of a lithium ion secondary battery is not restrict
- a lithium ion secondary battery is not limited to this.
- the electrode (positive electrode and negative electrode) is prepared, for example, by preparing an active material slurry (positive electrode active material slurry or negative electrode active material slurry) and applying the active material slurry onto a current collector. It can be made by drying, then pressing.
- the active material slurry includes the above-described active material (positive electrode active material or negative electrode active material), a binder (in the case where an aqueous binder is used on the negative electrode side, it is desirable to use a thickener together), a conductive auxiliary agent, and a solvent.
- the vibration time and ultrasonic wavelength when stirring using ultrasonic vibration when preparing the negative electrode active material (aqueous) slurry Change and adjust.
- the dispersion (stirring and mixing) time at the time of producing the negative electrode active material (aqueous) slurry may be mainly changed and adjusted.
- the adjustment may be made mainly by changing the type of the dispersion mixer.
- adjustment may be made mainly by changing the dispersion time and the number of rotations at the time of slurry preparation.
- the adjustment may be made mainly by changing the type of the dispersion mixer or the drying speed after electrode coating.
- the solvent is not particularly limited, and N-methyl-2-pyrrolidone (NMP), dimethylformamide, dimethylacetamide, methylformamide, cyclohexane, hexane, water and the like can be used.
- NMP N-methyl-2-pyrrolidone
- the method for applying the active material slurry to the current collector is not particularly limited, and examples thereof include a screen printing method, a spray coating method, an electrostatic spray coating method, an ink jet method, and a doctor blade method.
- the method for drying the coating film formed on the surface of the current collector is not particularly limited as long as at least a part of the solvent in the coating film is removed.
- An example of the drying method is heating. Drying conditions (drying time, drying temperature, etc.) can be appropriately set according to the volatilization rate of the solvent contained in the applied active material slurry, the coating amount of the active material slurry, and the like. A part of the solvent may remain. The remaining solvent can be removed by a press process described later.
- the pressing means is not particularly limited, and for example, a calendar roll, a flat plate press, or the like can be used.
- the single cell layer can be produced by laminating the electrodes (positive electrode and negative electrode) produced in (1) via a separator (electrolyte layer).
- the power generation element can be produced by laminating the single cell layers in consideration of the output and capacity of the single cell layer, the output and capacity required for the battery, and the like.
- the structure of the battery various shapes such as a rectangular shape, a paper shape, a laminated shape, a cylindrical shape, and a coin shape can be adopted.
- the current collector and insulating plate of the component parts are not particularly limited, and may be selected according to the above shape.
- a stacked battery is preferable.
- a lead is joined to the current collector of the power generation element obtained above, and the positive electrode lead or the negative electrode lead is joined to the positive electrode tab or the negative electrode tab.
- a power generation element is placed in a laminate sheet so that the positive electrode tab and the negative electrode tab are exposed to the outside of the battery, and an electrolytic solution is injected with a liquid injector and then sealed in a vacuum to produce a stacked battery. sell.
- initial charge treatment, gas removal treatment, activation treatment, etc. are further required under the following conditions.
- the three sides of the laminate sheet (exterior material) are completely sealed in a rectangular shape by thermocompression when sealing in the production of the laminated battery of (4) so that the gas removal treatment can be performed. Stop (main sealing), and the remaining one side is temporarily sealed by thermocompression bonding.
- the remaining one side may be freely opened and closed by, for example, clip fastening, but from the viewpoint of mass production (production efficiency), it is preferable to temporarily seal the side by thermocompression bonding.
- thermocompression it is only necessary to adjust the temperature and pressure for pressure bonding.
- it can be opened by lightly applying force, and after degassing, it may be sealed again by thermocompression, or finally completely sealed by thermocompression ( Main sealing).
- the battery aging process (initial charging process) is preferably performed as follows. At 25 ° C., a constant current charging method is used for 0.05 C for 4 hours (SOC approximately 20%). Next, after charging to 4.45 V at a 0.1 C rate at 25 ° C., the charging is stopped, and the state (SOC is about 70%) is maintained for about 2 days (48 hours).
- thermocompression bonding Next, the following process is performed as the first (first) gas removal process. First, one side temporarily sealed by thermocompression bonding is opened, gas is removed at 10 ⁇ 3 hPa for 5 minutes, and then thermocompression bonding is performed again to perform temporary sealing. Further, pressurization with a roller (surface pressure 0.5 ⁇ 0.1 MPa) is performed, and the electrode and the separator are sufficiently adhered.
- the battery is charged at 25 ° C. by a constant current charging method until the voltage reaches 4.45 V at 0.1 C, and then discharged twice to 2.0 V at 0.1 C.
- a cycle of discharging to 2.0 V at 0.1 C once is 4.65 V at 0.1 C.
- the battery is charged until it reaches 0, and then discharged once at 0.1 C to 2.0 V.
- a cycle of charging at 0.1 C to 4.75 V by a constant current charging method at 25 ° C. and then discharging to 0.1 V at 0.1 C may be performed once.
- the constant current charging method is used as the activation processing method, and the electrochemical pretreatment method when the voltage is set as the termination condition is described as an example, but the charging method is a constant current constant voltage charging method. You may use. Further, as the termination condition, a charge amount or time may be used in addition to the voltage.
- thermocompression bonding Next, the following process is performed as the first (first) gas removal process. First, one side temporarily sealed by thermocompression bonding is opened, gas is removed at 10 ⁇ 3 hPa for 5 minutes, and then thermocompression bonding is performed again to perform main sealing. Further, pressurization with a roller (surface pressure 0.5 ⁇ 0.1 MPa) is performed, and the electrode and the separator are sufficiently adhered.
- the performance and durability of the obtained battery can be improved by performing the initial charging process, the gas removal process, and the activation process described above.
- the assembled battery is configured by connecting a plurality of batteries. Specifically, it is constituted by serialization and / or parallelization using at least two batteries. Capacitance and voltage can be freely adjusted by paralleling in series.
- a small assembled battery that can be attached and detached by connecting a plurality of batteries in series or in parallel. Then, a plurality of small assembled batteries that can be attached and detached are connected in series or in parallel to provide a large capacity and large capacity suitable for vehicle drive power supplies and auxiliary power supplies that require high volume energy density and high volume output density.
- An assembled battery having an output can also be formed. How many batteries are connected to make an assembled battery, and how many small assembled batteries are stacked to make a large-capacity assembled battery depends on the battery capacity of the mounted vehicle (electric vehicle) It may be determined according to the output.
- the nonaqueous electrolyte secondary battery of the present invention including the lithium ion secondary battery according to the present embodiment maintains a discharge capacity even when used for a long period of time, and has good cycle characteristics. Furthermore, the volume energy density is high. Vehicle applications such as electric vehicles, hybrid electric vehicles, fuel cell vehicles, and hybrid fuel cell vehicles require higher capacity, larger size, and longer life than electric and portable electronic devices. . Therefore, the lithium ion secondary battery (non-aqueous electrolyte secondary battery) can be suitably used as a vehicle power source, for example, a vehicle driving power source or an auxiliary power source.
- a battery or an assembled battery formed by combining a plurality of these batteries can be mounted on the vehicle.
- a plug-in hybrid electric vehicle having a long EV mileage or an electric vehicle having a long charge mileage can be formed by mounting such a battery.
- a car a hybrid car, a fuel cell car, an electric car (four-wheeled vehicles (passenger cars, trucks, buses, commercial vehicles, light cars, etc.) This is because it can be used for motorcycles (including motorcycles) and tricycles) to provide a long-life and highly reliable automobile.
- the application is not limited to automobiles.
- it can be applied to various power sources for moving vehicles such as other vehicles, for example, trains, and power sources for mounting such as uninterruptible power supplies. It is also possible to use as.
- a positive electrode active material layer was formed on the back surface to produce a positive electrode in which a positive electrode active material layer was formed on both surfaces of a positive electrode current collector (aluminum foil).
- the single-sided coating amount of the positive electrode active material layer was 24 mg / cm 2 (not including the foil).
- the density of the positive electrode active material layer was 3.5 g / cm 3 (excluding the foil).
- the aspect ratio of the electrode was 1.3.
- This NMC composite oxide was prepared by the following preparation method.
- This metal composite hydroxide and lithium carbonate were weighed so that the ratio of the total number of moles of metals other than Li (Ni, Mn, Co) and the number of moles of Li was 1: 1, and then mixed well.
- the temperature was raised at a rate of temperature increase of 5 ° C./min, calcined at 900 ° C. for 2 hours in an air atmosphere, then heated at a rate of temperature increase of 3 ° C./min, main baked at 920 ° C. for 10 hours, and cooled to room temperature.
- an NMC composite oxide which is a positive electrode active material having a composition of LiNi 0.5 Mn 0.3 Co 0.2 O 2 was obtained.
- the average secondary particle diameter of the obtained NMC composite oxide was 10 ⁇ m.
- negative electrode 2.1 Preparation of Negative Electrodes of Comparative Examples 1-1 to 1-7 Regarding the preparation of negative electrodes having different dispersibility (and dispersibility of pores) of SBR using styrene-butadiene rubber (SBR) as a binder, a negative electrode active material (Aqueous) It was adjusted by changing the dispersion (stirring / mixing) time or rotation speed during slurry preparation. In this way, as shown in Table 1, negative electrodes were produced in which the dispersion in the dispersion of SBR as the binder (and the dispersion in the dispersion of the pores) was changed.
- SBR styrene-butadiene rubber
- the “variation in the dispersibility of SBR as a binder” means a cross section of the negative electrode active material layer when a plurality of arbitrary locations (here, five locations shown in FIG. 3) are selected in the negative electrode active material layer surface.
- a location (a location indicated by numbers 1 to 5 in FIG. 3A) obtained by dividing the diagonal line (one-dot broken line) in the negative electrode active material layer surface shown in FIG.
- the negative electrode was subjected to cross-section processing by an arbitrary cross-section processing method along a diagonal line (one-dot broken line) in the negative electrode active material layer surface shown in 3 (a) (the cross-section is shown in FIG. 3 (b)).
- the difference between the maximum value and the minimum value of the area ratio (%) occupied by the binder (SBR) for each of these five images was calculated.
- the difference between the maximum value and the minimum value of the area ratio (%) occupied by the binder (SBR) for each of these five images is also simply referred to as “binder distribution (%)”.
- each image of the negative electrode active material layer cross section there are five or five places with the numbers 1 to 5 in FIG. 3B corresponding to the positions 1 to 5 in FIG.
- the backscattered electron image observed with an electron microscope in the vicinity was used.
- the “field-of-view area of each image of the negative electrode active material layer cross section” is the entire reflected electron image (the entire field of view) observed by an electron microscope at five locations shown in FIG. ) (The vertical is the thickness of the negative electrode active material layer and the horizontal is a rectangular area of 100 ⁇ m).
- the area ratio (%) occupied by the binder (SBR) in the negative electrode active material layer cross section was determined by the following method (calculating the area ratio occupied by the binder). That is, Os was added to the binder (SBR) in the cross section of the negative electrode active material layer. Thereafter, Os was added to the backscattered electron image observed by the electron microscope at the cross-sectional portions (5 hatched portions in 3 (b)) corresponding to 5 locations in FIG. 3 (a) in the negative electrode active material layer surface. It is calculated by binarization with a threshold value that distinguishes between the binder and the part other than the binder. Specifically, a secondary electron image or a reflected electron image was taken with an electron microscope using Os, and image processing software was used for the image.
- the “variation in the dispersibility of the vacancies” means that each of the cross sections of the negative electrode active material layer when a plurality of arbitrary locations (here, five locations shown in FIG. 3) are selected in the negative electrode active material layer surface. This is the difference between the maximum value and the minimum value of the area ratio (%) of holes in the image (5 places).
- a location (a location indicated by numbers 1 to 5 in FIG. 3A) obtained by dividing the diagonal line (one-dot broken line) in the negative electrode active material layer surface shown in FIG.
- the negative negative electrode was subjected to cross-section processing by an arbitrary cross-section processing method along a diagonal line (one-dot broken line) in the negative electrode active material layer surface shown in 3 (a) (the cross-section is shown in FIG. 3 (b)).
- the area ratio (%) of vacancies in each image of the cross-section of the cut negative electrode active material layer was calculated by the method shown below (method for calculating the area ratio of vacancies).
- the difference between the maximum value and the minimum value of the area ratio (%) of the pores was determined. In the following Tables 1 to 3, etc., the difference between the maximum value and the minimum value of the hole area ratio (%) for each of these five images is also simply referred to as “hole distribution (%)”.
- each image of the negative electrode active material layer cross section there are five or five places with the numbers 1 to 5 in FIG. 3B corresponding to the positions 1 to 5 in FIG.
- An electron image image size; a vertical area with a thickness of the negative electrode active material layer and a horizontal area of 100 ⁇ m) observed with an electron microscope in the vicinity (shaded area in the figure) was used.
- the area ratio (%) of vacancies in each image of the cross section of the negative electrode active material layer was obtained by the following method (calculation method of vacancy area ratio). That is, in the negative electrode active material layer surface, the backscattered electron image observed by the electron microscope is obtained with respect to the vacancies and vacancies at the cross-sectional portions corresponding to the five portions in FIG. It is calculated by binarizing with a threshold value for distinguishing solid portions other than holes. Specifically, a secondary electron image or a reflected electron image was taken with an electron microscope, and image processing software was used for the image. As image processing software, AxioVision manufactured by Carl Zeiss, WinROOF manufactured by Mitani Corporation, and Image-Pro manufactured by Media Cybernetics were used. In the binarization process, by setting an appropriate threshold that can distinguish the contrast between the solid portion and the pores, the amount of pores in the area of each image (5 locations) of the negative electrode active material layer cross section is calculated. did.
- Negative Electrode of Comparative Example 1-1 96% by mass of natural graphite as a negative electrode active material, 1% by mass of carbon black as a conductive additive, 2% by mass of SBR as a binder, and sodium salt of carboxymethylcellulose (referred to as Na salt of CMC) as a thickener 1% by mass was prepared. These were added to purified water, and stirred for 4 minutes at a rotational speed of 2000 rpm using a stirring defoamer to mix (sufficiently) to prepare a negative electrode active material (aqueous) slurry.
- carbon black Super-P (registered trademark) manufactured by IMERYS was used.
- As the binder latex of styrene-butadiene rubber was used, and the content of styrene-butadiene rubber (SBR) in the solid content in the binder was 2% by mass.
- the negative electrode active material (aqueous) slurry was applied to a copper foil (thickness: 10 ⁇ m) serving as a negative electrode current collector, dried at 120 ° C. for 3 minutes, and then compression molded with a roll press to produce a negative electrode.
- a negative electrode active material layer was formed on the back surface to prepare a negative electrode in which a negative electrode active material layer was formed on both sides of a negative electrode current collector (copper foil).
- the single-sided coating amount of the negative electrode active material layer was 9 mg / cm 2 (excluding the foil). That is, the coating amount on one side of the negative electrode active material layer was adjusted so that the A / C ratio was 1.20 with the positive electrode facing when the battery described later was manufactured.
- Comparative Example 1-1 Preparation of Negative Electrode of Comparative Example 1-2 Comparative Example 1-1 was the same as Comparative Example 1-1 except that the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 2 minutes. In the same manner, a negative electrode of Comparative Example 1-2 was produced. Further, the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 1-2 was 1.5 g / cm 3 (excluding the foil).
- Comparative Example 1 Preparation of Negative Electrode of Comparative Example 1-3 Comparative Example 1 was the same as Comparative Example 1-1 except that the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 1.5 minutes. In the same manner as in Example 1, a negative electrode of Comparative Example 1-3 was produced. The density of the negative electrode active material layer constituting the negative electrode of Comparative Example 1-3 was 1.5 g / cm 3 (excluding the foil).
- Negative Electrode of Comparative Example 1-4 A negative electrode of Comparative Example 1-4 was produced in the same manner as in Comparative Example 1-2.
- the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 1-4 was 1.5 g / cm 3 (excluding the foil).
- Negative Electrode of Comparative Example 1-5 A negative electrode of Comparative Example 1-5 was produced in the same manner as in Comparative Example 1-3.
- the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 1-5 was 1.5 g / cm 3 (excluding the foil).
- Comparative Example 1-1 was the same as Comparative Example 1-1 except that the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 3 minutes. In the same manner, a negative electrode of Comparative Example 1-6 was produced.
- the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 1-6 was 1.5 g / cm 3 (excluding the foil).
- Negative Electrode of Comparative Example 2-1 86.4% by mass of natural graphite and 9.6% by mass of a Si—Ti alloy as a negative electrode active material, 1% by mass of carbon black as a conductive additive, 2% by mass of SBR as a binder, and a thickener 1 mass% of CMC Na salt was prepared. These were added to purified water and stirred for 4 minutes at 2000 rpm using a mixer made by Sinky and mixed (sufficiently) to prepare a negative electrode active material (aqueous) slurry. As the carbon black, Super-P (registered trademark) manufactured by Imeris Corporation was used. The average particle diameter of natural graphite was 20 ⁇ m.
- Si—Ti alloy an alloy having a composition represented by Si 90 Ti 10 (unit: mass%) was used.
- This Si—Ti alloy was produced by a mechanical alloy method. Specifically, using a planetary ball mill device P-6 manufactured by Fricht, Germany, zirconia pulverized balls and alloy raw material powders were put into a zirconia pulverized pot and alloyed at 600 rpm for 48 hours (alloying treatment). ), And then pulverization was performed at 400 rpm for 1 hour. Si and Ti metal powders were used as alloy raw material powders. The average particle size of the obtained Si—Ti alloy powder was 1.5 ⁇ m.
- the alloying treatment is performed by applying high energy to the alloy raw material powder at high rotation (600 rpm).
- the pulverization process is a process of loosening secondary particles at a low rotation (400 rpm) (not alloyed in this process).
- the negative electrode active material (aqueous) slurry was applied to a copper foil (thickness: 10 ⁇ m) serving as a negative electrode current collector, dried at 120 ° C. for 3 minutes, and then compression molded with a roll press to produce a negative electrode.
- a negative electrode active material layer was formed on the back surface to prepare a negative electrode in which a negative electrode active material layer was formed on both sides of a negative electrode current collector (copper foil).
- the single-sided coating amount of the negative electrode active material layer was 7 mg / cm 2 (excluding the foil). That is, the coating amount on one side of the negative electrode active material layer was adjusted so that the A / C ratio was 1.20 with the positive electrode facing when the battery described later was manufactured.
- the density of the negative electrode active material layer was 1.6 g / cm 3 (not including the foil).
- the negative electrode active material layer is applied to the formula (1) which is ⁇ (Si material) + ⁇ (carbon material)
- the Si material is a Si—Ti alloy
- the average particle diameter of natural graphite, which is a carbon material was 24 ⁇ m.
- the average particle size of the Si—Ti alloy powder, which is a Si material was 1.5 ⁇ m.
- Comparative Example 2-1 was the same as Comparative Example 2-1, except that the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 2 minutes. In the same manner, a negative electrode of Comparative Example 2-2 was produced.
- the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 2-2 was 1.6 g / cm 3 (excluding the foil).
- Comparative Example 2 Preparation of Negative Electrode of Comparative Example 2-3 Comparative Example 2 was the same as Comparative Example 2-1, except that the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 1.5 minutes. In the same manner as in Example 1, a negative electrode of Comparative Example 2-3 was produced. Further, the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 2-3 was 1.6 g / cm 3 (excluding the foil).
- Negative Electrode of Comparative Example 2-4 A negative electrode of Comparative Example 2-4 was produced in the same manner as in Comparative Example 2-3.
- the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 2-4 was 1.6 g / cm 3 (excluding the foil).
- Comparative Example 2-1 was the same as Comparative Example 2-1, except that the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 1 minute. In the same manner, a negative electrode of Comparative Example 2-5 was produced.
- the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 2-5 was 1.6 g / cm 3 (excluding the foil).
- Example 2-1 Production of negative electrode of Example 2-1 A negative electrode of Example 2-1 was produced in the same manner as in Comparative Example 2-1.
- the density of the negative electrode active material layer constituting the negative electrode of Example 2-1 was 1.6 g / cm 3 (excluding the foil).
- Example 2-2 Production of Negative Electrode of Example 2-2 A negative electrode of Example 2-2 was produced in the same manner as Comparative Example 2-2.
- the density of the negative electrode active material layer constituting the negative electrode of Example 2-2 was 1.6 g / cm 3 (excluding the foil).
- Example 2-3 Production of Negative Electrode of Example 2-3
- the rotation speed during dispersion was changed from 2000 rpm to 1500 rpm while the dispersion (stir mixing) time during production of the negative electrode active material (aqueous) slurry was kept for 4 minutes.
- a negative electrode of Example 2-3 was made in the same manner as Comparative Example 2-1, except for the above. Further, the density of the negative electrode active material layer constituting the negative electrode of Example 2-3 was 1.6 g / cm 3 (excluding the foil).
- Negative Electrode of Example 2-4 In Comparative Example 2-1, the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 6 minutes, and the rotation speed during dispersion was further changed.
- a negative electrode of Example 2-4 was produced in the same manner as Comparative Example 2-1, except that the speed was changed from 2000 rpm to 1000 rpm.
- the density of the negative electrode active material layer constituting the negative electrode of Example 2-4 was 1.6 g / cm 3 (excluding the foil).
- Negative Electrode of Example 2-5 In Comparative Example 2-1, the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 2 minutes, and the rotation speed during dispersion was further changed.
- a negative electrode of Example 2-5 was produced in the same manner as Comparative Example 2-1, except that the speed was changed from 2000 rpm to 1500 rpm. Further, the density of the negative electrode active material layer of the negative electrode of Example 2-5 was 1.6 g / cm 3 (excluding the foil).
- Negative Electrode of Example 2-6 In Comparative Example 2-1, the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 2 minutes, and the rotation speed during dispersion was further changed.
- a negative electrode of Example 2-6 was produced in the same manner as in Comparative Example 2-1, except that the speed was changed from 2000 rpm to 1000 rpm. Further, the density of the negative electrode active material layer constituting the negative electrode of Example 2-6 was 1.6 g / cm 3 (excluding the foil).
- Comparative Example 2-1 Preparation of Negative Electrode of Comparative Example 2-6
- the dispersion (stirring and mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 1 minute, and the rotation speed during dispersion was further changed.
- a negative electrode of Comparative Example 2-6 was produced in the same manner as Comparative Example 2-1, except that the speed was changed from 2000 rpm to 1000 rpm. Further, the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 2-6 was 1.6 g / cm 3 (excluding the foil).
- Negative Electrode of Comparative Example 2-7 A negative electrode of Comparative Example 2-7 was produced in the same manner as in Comparative Example 2-6.
- the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 2-7 was 1.6 g / cm 3 (excluding the foil).
- Negative Electrode of Comparative Example 3-1 The negative electrode composition was 76.8% by mass of natural graphite and 19.2% by mass of Si—Ti alloy as the negative electrode active material, 1% by mass of carbon black as the conductive additive, and 2% by mass of SBR as the binder.
- a negative electrode active material (aqueous) slurry was prepared in the same manner as in Comparative Example 2-1, except that the content of ammonium salt of CMC was 1% by mass as a thickener.
- the negative electrode active material (aqueous) slurry was applied to a copper foil (thickness: 10 ⁇ m) serving as a negative electrode current collector, dried at 120 ° C. for 3 minutes, and then compression molded with a roll press to produce a negative electrode.
- a negative electrode active material layer was formed on the back surface to prepare a negative electrode in which a negative electrode active material layer was formed on both sides of a negative electrode current collector (copper foil).
- the single-sided coating amount of the negative electrode active material layer was 6.5 mg / cm 2 (excluding the foil). That is, the coating amount on one side of the negative electrode active material layer was adjusted so that the A / C ratio was 1.20 with the positive electrode facing when the battery described later was manufactured.
- the average particle diameter of natural graphite, which is a carbon material was 24 ⁇ m.
- the average particle size of the Si—Ti alloy powder, which is a Si material was 1.5 ⁇ m.
- Comparative Example 3-1 Preparation of Negative Electrode of Comparative Example 3-2 Comparative Example 3-1 was the same as Comparative Example 3-1, except that the dispersion (stirring mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 2 minutes. In the same manner, a negative electrode of Comparative Example 3-2 was produced. In addition, the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 3-2 was 1.63 g / cm 3 (excluding the foil).
- Comparative Example 3 was the same as Comparative Example 3-1, except that the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 1.5 minutes.
- a negative electrode of Comparative Example 3-3 was produced in the same manner as -1.
- the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 3-3 was 1.63 g / cm 3 (excluding the foil).
- Negative Electrode of Comparative Example 3-4 A negative electrode of Comparative Example 3-4 was produced in the same manner as in Comparative Example 3-3. Further, the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 3-4 was 1.63 g / cm 3 (excluding the foil).
- Comparative Example 3-1 Preparation of Negative Electrode of Comparative Example 3-5 Comparative Example 3-1 was the same as Comparative Example 3-1, except that the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 1 minute. In the same manner, a negative electrode of Comparative Example 3-5 was produced. Further, the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 3-5 was 1.63 g / cm 3 (excluding the foil).
- Example 3-1 Production of Negative Electrode of Example 3-1 A negative electrode of Example 3-1 was produced in the same manner as Comparative Example 3-1.
- the density of the negative electrode active material layer constituting the negative electrode of Example 3-1 was 1.63 g / cm 3 (excluding the foil).
- Negative Electrode of Example 3-2 A negative electrode of Example 3-2 was produced in the same manner as Comparative Example 3-2. Further, the density of the negative electrode active material layer constituting the negative electrode of Example 3-2 was 1.63 g / cm 3 (excluding the foil).
- Example 3-3 Production of Negative Electrode of Example 3-3
- the rotation speed during dispersion was changed from 2000 rpm to 1500 rpm while the dispersion (stir mixing) time during production of the negative electrode active material (aqueous) slurry was kept for 4 minutes.
- a negative electrode of Example 3-3 was made in the same manner as Comparative Example 3-1, except for the above.
- the density of the negative electrode active material layer constituting the negative electrode of Example 3-3 was 1.63 g / cm 3 (excluding the foil).
- Negative Electrode of Example 3-4 In Comparative Example 3-1, the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 6 minutes, and the rotation speed during dispersion was further changed.
- a negative electrode of Example 3-4 was produced in the same manner as Comparative Example 3-1, except that the speed was changed from 2000 rpm to 1000 rpm. Further, the density of the negative electrode active material layer constituting the negative electrode of Example 3-4 was 1.63 g / cm 3 (excluding the foil).
- Example 3-5 Production of Negative Electrode
- the dispersion (stir mixing) time during production of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 2 minutes, and the rotational speed during dispersion was further changed.
- a negative electrode of Example 3-5 was produced in the same manner as Comparative Example 3-1, except that the speed was changed from 2000 rpm to 1500 rpm.
- the density of the negative electrode active material layer constituting the negative electrode of Example 3-5 was 1.63 g / cm 3 (excluding the foil).
- Negative Electrode of Example 3-6 In Comparative Example 3-1, the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 2 minutes, and the rotation speed during dispersion was further changed.
- a negative electrode of Example 3-6 was produced in the same manner as Comparative Example 3-1, except that the speed was changed from 2000 rpm to 1000 rpm.
- the density of the negative electrode active material layer constituting the negative electrode of Example 3-6 was 1.63 g / cm 3 (excluding the foil).
- Comparative Example 3-1 Preparation of Negative Electrode of Comparative Example 3-6
- the dispersion (stir mixing) time during preparation of the negative electrode active material (aqueous) slurry was changed from 4 minutes to 1 minute, and the rotation speed during dispersion was further changed.
- a negative electrode of Comparative Example 3-6 was produced in the same manner as Comparative Example 3-1, except that the speed was changed from 2000 rpm to 1000 rpm. Further, the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 3-6 was 1.63 g / cm 3 (excluding the foil).
- Negative Electrode of Comparative Example 3-7 A negative electrode of Comparative Example 3-7 was produced in the same manner as in Comparative Example 3-6. Further, the density of the negative electrode active material layer constituting the negative electrode of Comparative Example 3-7 was 1.63 g / cm 3 (excluding the foil).
- the power generation element is inserted into an aluminum laminate sheet bag (length: 3.7 cm ⁇ width: 3.2 cm), which is a battery exterior material, so that the positive electrode current collecting plate and the negative electrode current collecting plate are exposed to the outside of the battery.
- the electrolytic solution was injected from the opening by a machine.
- This aluminum laminate sheet bag is made of two aluminum laminate sheets (a film sheet laminated with aluminum with PP film), and three of the four outer peripheries (outer edges) are sealed by thermocompression (seal) The remaining one side is unsealed (opening).
- the electrolyte solution 3 of 1.0 M LiPF 6 ethylene carbonate (EC) and diethyl carbonate (DEC): with respect to: (a volume ratio of DEC EC) mixed and dissolved in the solvent solution 100 parts by weight, 7 What added 1 mass part of vinylene carbonate which is an additive was used.
- the injection amount of the electrolytic solution was set to an amount that is 1.50 times the total pore volume (calculated by calculation) of the positive electrode active material layer, the negative electrode active material layer, and the separator.
- the power generation element is inserted into a bag made of aluminum laminate sheet (length 27.4 cm ⁇ width 17.4 cm) as a battery outer package so that the positive electrode current collector plate and the negative electrode current collector plate are exposed outside the battery. Injected.
- this aluminum laminate sheet bag two rectangular aluminum laminate sheets are overlapped, and three of the four sides of the outer periphery (outer edge portion) are sealed (sealed) by thermocompression bonding, and the remaining one side is not yet sealed. It is sealed (opening).
- the electrolyte solution 3 of 1.0 M LiPF 6 ethylene carbonate (EC) and diethyl carbonate (DEC): with respect to: (a volume ratio of DEC EC) mixed and dissolved in the solvent solution 100 parts by weight, 7 What added 1 mass part of vinylene carbonate which is an additive was used.
- the injection amount of the electrolytic solution was set to an amount that is 1.50 times the total pore volume (calculated by calculation) of the positive electrode active material layer, the negative electrode active material layer, and the separator.
- the rated capacity of a battery (test cell) was determined as follows.
- the rated capacity is left to stand for about 10 hours after injecting the electrolytic solution, and then in the following procedure 1 to 5 at a temperature of 25 ° C. and a voltage range of 3.0 V to 4.15 V. Measured by. *
- Procedure 2 After Procedure 1, the battery was charged with constant voltage charging for 1.5 hours and rested for 5 minutes. *
- the battery (test cell) volume was determined by the product of the projected area and thickness of the battery including the battery outer package. Among these, regarding the projected area of the battery including the battery outer casing, the projected area of the six batteries of the front, back, right side, left side, plane, and bottom can be obtained. In this example, the projected area of the battery on the bottom surface when the battery (test cell) was placed in the most stable state on the flat plate was used. In addition, the thickness of the battery including the battery outer case is fully charged, and in this embodiment, the procedure is performed up to step 4 in the same manner as in “4.2. The thickness of the later fully charged battery (test cell) was measured.
- this embodiment is a perspective view showing the appearance of the battery.
- the thickness of the battery including the battery case was measured at the locations represented by the numbers 1 to 9 shown in the figure or at 9 locations in the vicinity thereof, and the values were averaged.
- the thickness of the small battery was measured in the same manner. The obtained results are shown in the “cell volume” column in Tables 1 to 3 below.
- FIG. 4 shows small batteries (Comparative Examples 1-1 to 1) for Comparative Examples 1-1 to 1-5 (vacancy distribution 5.7% or less) in Table 1 in which the mixing ratio of the Si material is 0% by mass. -3) and large batteries (Comparative Examples 1-4 to 1-5).
- FIG. 5 shows small batteries (compared with Comparative Examples 2-1 to 2-5 and Examples 2-1 to 2-2 (vacancy distribution of 6.1% or less) in Table 2 having a mixing ratio of Si material of 10 mass%. The results are plotted separately for Comparative Examples 2-1 and 2-3) and large batteries (Examples 2-1 and 2-2, Comparative Examples 2-4 and 2-5).
- FIG. 4 shows small batteries (Comparative Examples 1-1 to 1) for Comparative Examples 1-1 to 1-5 (vacancy distribution 5.7% or less) in Table 1 in which the mixing ratio of the Si material is 0% by mass. -3) and large batteries (Comparative Examples 1-4 to 1-5).
- FIG. 5 shows small batteries (compared with Comparative Examples 2-1 to 2-5 and Examples 2-1 to 2-2 (vacancy distribution
- 6 shows a small battery for each of Comparative Examples 3-1 to 3-5 and Examples 3-1 to 3-2 (vacancy distribution of 6.1% or less) in Table 3 having a mixing ratio of Si material of 20 mass%. 6 is a drawing in which Comparative Examples 3-1 to 3-3) and large batteries (Examples 3-1 to 3-2 and Comparative Examples 3-4 to 3-5) are separately plotted.
- a battery using a negative electrode having a Si-based material ratio in the active material of 10% by mass has an advantage of superior durability as compared with Examples 3-1 to 3-6.
- the cycle durability of the battery can be further improved while maintaining a high capacity without significantly reducing the capacity of the battery (Examples 2-1 to 2-6).
- the binder distribution is It turns out that the effect of this invention is acquired by setting it as 10% or less. That is, with the above configuration, the distance between the positive electrode and the negative electrode increases locally, and deterioration due to the phenomenon of non-uniformity of reactivity with Li ions, which occurs when the distance decreases locally, is suppressed. . As a result, it is considered that the cycle durability of the battery was improved while maintaining a high capacity. In addition to the above, by further reducing the pore distribution to within 10%, deterioration due to the above phenomenon can be further suppressed. Therefore, it is considered that the cycle durability of the battery is further improved while maintaining a high capacity.
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Abstract
Description
正極集電体の表面に正極活物質を含む正極活物質層が形成されてなる正極と、
負極集電体の表面に負極活物質を含む負極活物質層が形成されてなる負極と、
セパレータと、
を含む発電要素を有し、
前記負極活物質層が、下記式(1):
負極活物質層面内における任意の場所を複数選択した場合における、負極活物質層断面の各像の視野面積においてバインダが占める面積比率(%)の最大値と最小値の差が10%以内であることを特徴する非水電解質二次電池が提供される。かかる構成を有することにより、上記発明の効果を有効に発現することができる。
図1は、本発明の非水電解質二次電池の代表的な一実施形態である、扁平型(積層型)のリチウムイオン二次電池(以下、単に「積層型電池」ともいう)の全体構造を模式的に表した断面概略図である。
活物質層(13、15)は活物質を含み、必要に応じてその他の添加剤をさらに含む。
正極活物質層15は、正極活物質を含む。本形態において、正極活物質は、特に制限されないが、リチウムニッケル系複合酸化物またはスピネル系リチウムマンガン複合酸化物を含むことが好ましく、リチウムニッケル系複合酸化物を含むことがより好ましい。なお、正極活物質層に含まれる正極活物質の全量100質量%に占めるリチウムニッケル系複合酸化物およびスピネル系リチウムマンガン複合酸化物の合計量の割合は、好ましくは50質量%以上であり、より好ましくは70質量%以上であり、さらに好ましくは85質量%以上であり、いっそう好ましくは90質量%以上であり、特に好ましくは95質量%以上であり、最も好ましくは100質量%である。
リチウムニッケル系複合酸化物は、リチウムとニッケルとを含有する複合酸化物である限り、その組成は具体的に限定されない。リチウムとニッケルとを含有する複合酸化物の典型的な例としては、リチウムニッケル複合酸化物(LiNiO2)が挙げられる。ただし、リチウムニッケル複合酸化物のニッケル原子の一部が他の金属原子で置換された複合酸化物がより好ましく、好ましい例として、リチウム-ニッケル-マンガン-コバルト複合酸化物(以下、単に「NMC複合酸化物」とも称する)は、リチウム原子層と遷移金属(Mn、NiおよびCoが秩序正しく配置)原子層とが酸素原子層を介して交互に積み重なった層状結晶構造を持ち、遷移金属Mの1原子あたり1個のLi原子が含まれ、取り出せるLi量が、スピネル系リチウムマンガン酸化物の2倍、つまり供給能力が2倍になり、高い容量を持つことができる。加えて、LiNiO2より高い熱安定性を有しているため、正極活物質として用いられるニッケル系複合酸化物の中でも特に有利である。
スピネル系リチウムマンガン複合酸化物は、典型的にはLiMn2O4の組成を有し、スピネル構造を有する、リチウムおよびマンガンを必須に含有する複合酸化物であり、その具体的な構成や製造方法については、特開2000-77071号公報等の従来公知の知見が適宜参照されうる。
正極活物質層に用いられるバインダとしては、特に限定されないが、例えば、以下の材料が挙げられる。ポリエチレン、ポリプロピレン、ポリエチレンテレフタレート(PET)、ポリエーテルニトリル、ポリアクリロニトリル、ポリイミド、ポリアミド、セルロース、カルボキシメチルセルロース(CMC)およびその塩、エチレン-酢酸ビニル共重合体、ポリ塩化ビニル、スチレン・ブタジエンゴム(SBR)、イソプレンゴム、ブタジエンゴム、エチレン・プロピレンゴム、エチレン・プロピレン・ジエン共重合体、スチレン・ブタジエン・スチレンブロック共重合体およびその水素添加物、スチレン・イソプレン・スチレンブロック共重合体およびその水素添加物などの熱可塑性高分子、ポリフッ化ビニリデン(PVdF)、ポリテトラフルオロエチレン(PTFE)、テトラフルオロエチレン・ヘキサフルオロプロピレン共重合体(FEP)、テトラフルオロエチレン・パーフルオロアルキルビニルエーテル共重合体(PFA)、エチレン・テトラフルオロエチレン共重合体(ETFE)、ポリクロロトリフルオロエチレン(PCTFE)、エチレン・クロロトリフルオロエチレン共重合体(ECTFE)、ポリフッ化ビニル(PVF)等のフッ素樹脂、ビニリデンフルオライド-ヘキサフルオロプロピレン系フッ素ゴム(VDF-HFP系フッ素ゴム)、ビニリデンフルオライド-ヘキサフルオロプロピレン-テトラフルオロエチレン系フッ素ゴム(VDF-HFP-TFE系フッ素ゴム)、ビニリデンフルオライド-ペンタフルオロプロピレン系フッ素ゴム(VDF-PFP系フッ素ゴム)、ビニリデンフルオライド-ペンタフルオロプロピレン-テトラフルオロエチレン系フッ素ゴム(VDF-PFP-TFE系フッ素ゴム)、ビニリデンフルオライド-パーフルオロメチルビニルエーテル-テトラフルオロエチレン系フッ素ゴム(VDF-PFMVE-TFE系フッ素ゴム)、ビニリデンフルオライド-クロロトリフルオロエチレン系フッ素ゴム(VDF-CTFE系フッ素ゴム)等のビニリデンフルオライド系フッ素ゴム、エポキシ樹脂等が挙げられる。これらのバインダは、単独で用いてもよいし、2種以上を併用してもよい。
導電助剤とは、正極活物質層または負極活物質層の導電性を向上させるために配合される添加物をいう。導電助剤としては、アセチレンブラック、ケッチェンブラック、ファーネスブラック等のカーボンブラック、チャンネルブラック、サーマルブラック、グラファイト等のカーボン粉末や、気相成長炭素繊維(VGCF;登録商標)等の種々の炭素繊維、膨張黒鉛などの炭素材料が挙げられる。活物質層が導電助剤を含むと、活物質層の内部における電子ネットワークが効果的に形成され、電池の出力特性の向上に寄与しうる。
電解質塩(リチウム塩)としては、Li(C2F5SO2)2N、LiPF6、LiBF4、LiClO4、LiAsF6、LiCF3SO3等が挙げられる。
負極活物質層13は、下記式(1)
SiOxは、アモルファスSiO2粒子とSi粒子との混合体であり、xはSiの原子価を満足する酸素数を表す。xの具体的な値について特に制限はなく、適宜設定されうる。
本形態に係るSiOxの製造方法としては、特に制限されるものではなく、従来公知の各種の製造を利用して製造することができる。すなわち、作製方法によるアモルファス状態・特性の違いはほとんどないため、ありとあらゆる作製方法が適用できる。
Si含有合金は、Siを含有する他の金属との合金であれば特に制限されず、従来公知の知見が適宜参照されうる。ここでは、Si含有合金の好ましい実施形態として、SixTiyGezAa、SixTiyZnzAa、SixTiySnzAa、SixSnyAlzAa、SixSnyVzAa、SixSnyCzAa、SixZnyVzAa、SixZnySnzAa、SixZnyAlzAa、SixZnyCzAa、SixAlyCzAaおよびSixAlyNbzAa(式中、Aは、不可避不純物である。さらに、x、y、z、およびaは、質量%の値を表し、0<x<100、0<y<100、0≦z<100、および0≦a<0.5であり、x+y+z+a=100である)が挙げられる。より好ましくは、上記式においてさらに0<z<100を満たすSi含有合金である。これらのSi含有合金を負極活物質として用いることで、所定の第1添加元素および所定の第2添加元素を適切に選択することによって、Li合金化の際に、アモルファス-結晶の相転移を抑制してサイクル寿命を向上させることができる。また、これによって、従来の負極活物質、例えば炭素系負極活物質よりも高容量のものとなる。
本形態に係るSi含有合金の製造方法としては、特に制限されるものではなく、従来公知の各種の製造を利用して製造することができる。Si含有合金の製造方法の一例として、以下のような製造方法が挙げられるが、これらに何ら制限されるものではない。
本発明に用いられうる炭素材料は、黒鉛、難黒鉛化炭素、非定形炭素からなる群から選択される1種または2種以上である。詳しくは、天然黒鉛、人造黒鉛等の高結晶性カーボンである黒鉛(グラファイト);ハードカーボン等の難黒鉛化炭素;およびケッチェンブラック、アセチレンブラック、チャンネルブラック、ランプブラック、オイルファーネスブラック、サーマルブラック等のカーボンブラックのような非定形炭素から選択される1種または2種以上である。これらのうち、天然黒鉛、人造黒鉛などの黒鉛を用いることが好ましい。
本形態において、負極活物質層は、バインダを必須に含むものである。負極活物質層に含まれるバインダとしては、水系バインダを含むのが好ましい。水系バインダは、原料としての水の調達が容易であることに加え、乾燥時に発生するのは水蒸気であるため、製造ラインへの設備投資が大幅に抑制でき、環境負荷の低減を図ることができるという利点がある。
本形態では、負極活物質層面内における任意の場所を複数選択した場合における、負極活物質層断面の各像の視野面積においてバインダが占める面積比率(%)の最大値と最小値の差が10%以内であることを特徴とするものである。すなわち、大容量かつ大面積を有する大型電池とした場合には、負極活物質層面内において、バインダの多い箇所と少ない箇所が存在する場合、バインダの少ない箇所は電極内部の結着性が小さいため、電極の膨張が大きくなる。一方で、バインダの多い箇所は電極内部の結着性が大きい為、電極の膨張が小さくなる。電極の膨張が大きい箇所では正極と負極の極間距離が短くなり、電極の膨張が小さい箇所では正極と負極の極間距離が長くなる。極間距離が短い箇所では抵抗が小さくなり電流量が多くなるために反応が加速され、極間距離の長い箇所では抵抗が大きくなり電流量が小さくなるため反応が進みにくくなる。すなわち、負極活物質層面内にて反応の不均一性が生じる。特に、反応量の多い箇所においては、電解液との副反応加速、活物質の劣化加速が生じるために、電池のサイクル耐久性が著しく低下する。また、バインダの少ない箇所は結着性が小さい為、充放電過程において活物質の脱離などが生じ、これによりサイクル耐久性が低下する。ことを見出した。これは、大型電池でない既存の電池では、特許文献1に記載のSi材料+炭素材料を併用することで、電池のサイクル耐久性が低下せず、上記した問題は生じなかった(表1~3参照)。即ち上記問題点は、Si材料+炭素材料を併用し、更に大容量かつ大面積を有する大型電池とした場合にのみ発生する固有の新規課題であることがわかった。ここうした固有の課題に対し、バインダの分散性のばらつきを10%以内に制御することで、上記問題を解消することができ、電池のサイクル耐久性を大幅に向上することができたものといえる。詳しくは、上記要件(バインダの分散性のばらつきを10%以内)を満足することで、大容量かつ大面積を有する大型電池において、負極活物質層面内での充電時の膨張量のバラツキが小さくなる。このことにより、正極と負極の極間距離がある箇所においては増加し、ある箇所においては減少することによる、Liイオンとの反応性の不均一性が生じる現象が抑えられ、電池のサイクル耐久性が向上する。また、負極活物質層内のバインダの分散性のばらつきを10%以内とすることで、上記大型電池において、負極活物質層内でバインダが不足する箇所が低減する。このことにより、活物質の脱落を防ぎ、電池のサイクル耐久性を向上させることができるものである。また、「負極活物質層面内における任意の場所を複数選択した場合における、負極活物質層断面の各像の視野面積においてバインダが占める面積比率(%)の最大値と最小値の差」を単に「バインダの分散性のばらつき」ともいう。
また、負極活物質層断面の各像の視野面積においてバインダが占める面積比率(%)を算出する方法としては、限定されるものではないが、例えば、以下に示す負極活物質層断面の画像処理による方法がある。すなわち、負極電極を任意の断面加工処理方法により断面加工した後、負極活物質層断面のバインダにOsを付加させる。その後、負極活物質層面内における任意の場所に対応する断面部分につき、電子顕微鏡により観察された二次電子像または反射電子像をOsが付加されたバインダとバインダ以外の箇所が区別される閾値にて2値化して算出する方法を用いることができる。詳しくは、Osを用いて電子顕微鏡にて二次電子像または反射電子像を撮像し、その画像に対し画像処理ソフトを用いる。画像処理ソフトは限定されるものではないが、例えば、カールツァイス製AxioVision、三谷商事製WinROOF、Media Cybernetics製Image-Proなどを用いることができる。二値化処理においては、Osを付加させたバインダと、バインダ以外のコントラストが区別されうる適当な閾値を設定することにより、負極活物質層断面の各像の視野面積におけるバインダの面積量を算出することができる。
導電助剤とは、正極活物質層または負極活物質層の導電性を向上させるために配合される添加物をいう。特に制限されないが、アセチレンブラック、ケッチェンブラック、ファーネスブラック等のカーボンブラック、チャンネルブラック、サーマルブラック、グラファイト等のカーボン粉末や、気相成長炭素繊維(VGCF;登録商標)等の種々の炭素繊維、膨張黒鉛などの炭素材料が挙げられる。活物質層が導電助剤を含むと、活物質層の内部における電子ネットワークが効果的に形成され、電池の出力特性の向上に寄与しうる。
リチウム塩は、上述した電解質が負極活物質層へと浸透することで、負極活物質層中に含まれることになる。したがって、負極活物質層に含まれうるリチウム塩の具体的な形態は、電解質を構成するリチウム塩と同様である。リチウム塩としては、Li(C2F5SO2)2N、LiPF6、LiBF4、LiClO4、LiAsF6、LiCF3SO3等が挙げられる。
イオン伝導性ポリマーとしては、例えば、ポリエチレンオキシド(PEO)系およびポリプロピレンオキシド(PPO)系のポリマーが挙げられる。
本形態では、負極活物質層面内における任意の場所を複数選択した場合における、負極活物質層断面の各像における空孔の面積比率(%)の最大値と最小値の差が10%以内であるのが好ましい。すなわち、大容量かつ大面積を有する大型電池とした場合には、負極活物質層面内において、空孔量の多い箇所と少ない箇所が存在する場合、空孔量の大きい箇所は空孔(空隙)によりSiの膨張を吸収することが可能となるため、小さい箇所に比べて電極厚みが小さくなる。これにより、Si系材料の多い箇所は正極と負極の極間距離が短くなるために、抵抗が小さくなり、電流量が多くなるため反応が加速され、負極活物質層面内にて反応の不均一性が生じる。反応量の多い箇所においては、電解液との副反応加速、活物質の劣化加速、セパレータの閉孔が生じるために、電池のサイクル耐久性が低下することを見出した。これは、大型電池でない既存の電池では、特許文献1に記載のSi材料+炭素材料を併用することで、電池のサイクル耐久性が低下せず、上記した問題は生じなかった(表1~3参照)。即ち上記問題点は、Si材料+炭素材料を併用し、更に大容量かつ大面積を有する大型電池とした場合にのみ発生する固有の新規課題であることがわかった。こうした固有の課題に対し、Si材料+炭素材料を併用し、更に大型電池とした場合において、上記したバインダの分散性のばらつきを10%以内に制御することで、負極活物質層面内での充電時のSiの膨張量のバラツキが小さくなることから、上記問題を解消できたものと考えられる。これにより上記電池のサイクル耐久性を大幅に向上することができたものといえる。ここで、更に上記要件(空孔の分散性のばらつき10%以内)を満足することで、大容量かつ大面積を有する大型電池において、負極活物質層面内での充電時の膨張量のバラツキがさらに小さくできる。このことにより、正極と負極の極間距離がある箇所においては増加し、ある箇所においては減少することによる、Liイオンとの反応性の不均一性が生じる現象が抑えられる。これにより電解液との副反応、活物質の劣化、セパレータの閉孔なども効果的に抑えることができる。その結果、電池のサイクル耐久性のより一層の向上が図れたものといえる。また「負極活物質層面内における任意の場所を複数選択した場合における、負極活物質層断面の各像における空孔の面積比率(%)の最大値と最小値の差」を単に「空孔の分散性のばらつき」ともいう。
また、負極活物質層断面の各像における空孔の面積比率(%)を算出する方法としては、限定されるものではないが、例えば、以下に示す負極活物質層断面の画像処理による方法がある。即ち、負極電極を任意の断面加工処理方法により断面加工した後、負極活物質層面内における任意の場所に対応する断面部分につき、電子顕微鏡により観察された二次電子像または反射電子像を空孔と空孔以外の固体部分が区別される閾値にて2値化して算出する方法を用いることができる。詳しくは、電子顕微鏡にて二次電子像または反射電子像を撮像し、その画像に対し画像処理ソフトを用いる。画像処理ソフトは限定されるものではないが、例えば、カールツァイス製AxioVision、三谷商事製WinROOF、Media Cybernetics製Image-Proなどを用いることができる。二値化処理においては、固体部分と空孔のコントラストが区別されうる適当な閾値を設定することにより、負極活物質層断面の各像の面積における空孔の面積量を算出することができる。
集電体(11、12)は導電性材料から構成される。集電体の大きさは、電池の使用用途に応じて決定される。例えば、高エネルギー密度が要求される大型の電池に用いられるのであれば、面積の大きな集電体が用いられる。
セパレータは、電解質を保持して正極と負極との間のリチウムイオン伝導性を確保する機能、および正極と負極との間の隔壁としての機能を有する。
リチウムイオン二次電池においては、電池外部に電流を取り出す目的で、集電体に電気的に接続された集電板(タブ)が外装材であるラミネートフィルムの外部に取り出されている。
シール部は、直列積層型電池に特有の部材であり、電解質層の漏れを防止する機能を有する。このほかにも、電池内で隣り合う集電体同士が接触したり、積層電極の端部の僅かな不ぞろいなどによる短絡が起こったりするのを防止することもできる。
負極および正極端子リードの材料は、公知の積層型二次電池で用いられるリードを用いることができる。なお、電池外装材から取り出された部分は、周辺機器や配線などに接触して漏電したりして製品(例えば、自動車部品、特に電子機器等)に影響を与えないように、耐熱絶縁性の熱収縮チューブなどにより被覆するのが好ましい。
電池外装体としては、従来公知の金属缶ケースを用いることができる。そのほか、図1に示すようなラミネートフィルム29を外装材として用いて、発電要素21をパックしてもよい。ラミネートフィルムは、例えば、ポリプロピレン、アルミニウム、ナイロンがこの順に積層されてなる3層構造として構成されうる。このようなラミネートフィルムを用いることにより、外装材の開封、容量回復材の添加、外装材の再封止を容易に行うことができる。高出力化や冷却性能に優れ、EV、HEV用の大型機器用電池に好適に利用することができるという観点から、ラミネートフィルムが望ましい。また、外部から掛かる発電要素への群圧を容易に調整することができ、所望の電解液層厚みへと調整容易であることから、外装体は、アルミニウムを含むラミネートフィルムからなるもの(例えば、アルミラミネートシート製バッグ;実施例参照)がより好ましい。アルミニウムを含むラミネートフィルムには、上記したポリプロピレン、アルミニウム、ナイロンがこの順に積層されてなるアルミラミネートフィル等を用いることができる。
図2は、二次電池の代表的な実施形態である扁平なリチウムイオン二次電池の外観を表した斜視図である。このリチウムイオン二次電池のように、本発明における好ましい実施形態によれば、アルミニウムを含むラミネートフィルムからなる電池外装体に前記発電要素が封入されてなる構成を有する扁平積層型ラミネート電池が提供される。
電気自動車の一回の充電による走行距離(航続距離)を考慮すると、電池の体積エネルギー密度は157Wh/L以上であることが好ましく、かつ定格容量は20Ah以上であることが好ましい。
定格容量は、試験用電池について、電解液を注入した後で、10時間程度放置し、その後、温度25℃、3.0Vから4.15Vの電圧範囲で、次の手順1~5によって測定される。なお、市販品などの電池(製品)については、電解液注入後10時間以上たっているので、次の手順1~5を行って定格容量を求めればよい。
リチウムイオン二次電池の製造方法は特に制限されず、公知の方法により製造されうる。具体的には、(1)電極の作製、(2)単電池層の作製、(3)発電要素の作製、および(4)積層型電池の製造を含む。以下、リチウムイオン二次電池の製造方法について一例を挙げて説明するが、これに限定されるものではない。
電極(正極または負極)は、例えば、活物質スラリー(正極活物質スラリーまたは負極活物質スラリー)を調製し、当該活物質スラリーを集電体上に塗布、乾燥し、次いでプレスすることにより作製されうる。前記活物質スラリーは、上述した活物質(正極活物質または負極活物質)、バインダ(負極側に水系バインダを用いる場合は増粘剤を併用するのが望ましい)、導電助剤および溶媒を含む。ここで、負極活物質層面内のバインダの分散性のばらつきを制御するには、主に負極活物質(水系)スラリー作製時に超音波振動を利用して撹拌する際の振動時間や超音波波長等を変えて調整すればよい。この他にも主に負極活物質(水系)スラリー作製時の分散(撹拌混合)時間などを変えて調整してもよい。或いは主に分散ミキサーの種類を変えて調整してもよいなど、特に制限されるものではない。また、負極活物質層面内の空孔の分散性のばらつきを制御するには、主にスラリー作成時の分散時間や回転数を変えて調整すればよい。この他にも主に分散ミキサーの種類や電極塗工後の乾燥速度を変えて調整してもよいなど、特に制限されるものではない。
単電池層は、(1)で作製した電極(正極および負極)を、セパレータ(電解質層)を介して積層させることにより作製されうる。
発電要素は、単電池層の出力および容量、電池として必要とする出力および容量等を適宜考慮し、前記単電池層を積層して作製されうる。
電池の構成としては、角形、ペーパー型、積層型、円筒型、コイン型等、種々の形状を採用することができる。また構成部品の集電体や絶縁板等は特に限定されるものではなく、上記の形状に応じて選定すればよい。しかし、本実施形態では積層型電池が好ましい。積層型電池は、上記で得られた発電要素の集電体にリードを接合し、これらの正極リードまたは負極リードを、正極タブまたは負極タブに接合する。そして、正極タブおよび負極タブが電池外部に露出するように、発電要素をラミネートシート中に入れ、注液機により電解液を注液してから真空に封止することにより積層型電池が製造されうる。
本実施形態では、上記により得られた積層型電池の性能および耐久性を高める観点から、さらに、以下の条件で初充電処理、ガス除去処理および活性化処理などを必要に応じて行ってもよい。この場合には、ガス除去処理ができるように、上記(4)の積層型電池の製造において、封止する際に、矩形形状にラミネートシート(外装材)の3辺を熱圧着により完全に封止(本封止)し、残る1辺は、熱圧着で仮封止しておく。残る1辺は、例えば、クリップ留め等により開閉自在にしてもよいが、量産化(生産効率)の観点からは、熱圧着で仮封止するのがよい。この場合には、圧着する温度、圧力を調整するだけでよいためである。熱圧着で仮封止した場合には、軽く力を加えることで開封でき、ガス抜き後、再度、熱圧着で仮封止してもよいし、最後的には熱圧着で完全に封止(本封止)すればよい。
電池のエージング処理(初充電処理)は、以下のように実施することが好ましい。25℃にて、定電流充電法で0.05C、4時間の充電(SOC約20%)を行う。次いで、25℃にて0.1Cレートで4.45Vまで充電した後、充電を止め、その状態(SOC約70%)で約2日間(48時間)保持する。
次に、最初(1回目)のガス除去処理として、以下の処理を行う。まず、熱圧着で仮封止した1辺を開封し、10±3hPaで5分間ガス除去を行った後、再度、熱圧着を行って仮封止を行う。さらに、ローラーで加圧(面圧0.5±0.1MPa)整形し電極とセパレータとを十分に密着させる。
次に、活性化処理法として、以下の電気化学前処理法を行う。
次に、最初(1回目)のガス除去処理として、以下の処理を行う。まず、熱圧着で仮封止した一辺を開封し、10±3hPaで5分間ガス除去を行った後、再度、熱圧着を行って本封止を行う。さらに、ローラーで加圧(面圧0.5±0.1MPa)整形し電極とセパレータとを十分に密着させる。
組電池は、電池を複数個接続して構成した物である。詳しくは少なくとも2つ以上の電池を用いて、直列化あるいは並列化あるいはその両方で構成されるものである。直列、並列化することで容量および電圧を自由に調節することが可能になる。
本実施形態に係るリチウムイオン二次電池をはじめとした本発明の非水電解質二次電池は、長期使用しても放電容量が維持され、サイクル特性が良好である。さらに、体積エネルギー密度が高い。電気自動車やハイブリッド電気自動車や燃料電池車やハイブリッド燃料電池自動車などの車両用途においては、電気・携帯電子機器用途と比較して、高容量、大型化が求められるとともに、長寿命化が必要となる。したがって、上記リチウムイオン二次電池(非水電解質二次電池)は、車両用の電源として、例えば、車両駆動用電源や補助電源に好適に利用することができる。
正極活物質としてNMC複合酸化物を94質量%、導電助剤としてアセチレンブラックを3質量%、バインダとしてポリフッ化ビニリデン(PVDF)を3質量%およびスラリー粘度調整溶媒であるN-メチル-2-ピロリドン(NMP)を適量混合して正極活物質スラリーを調製した。得られた正極活物質スラリーを正極集電体であるアルミニウム箔(厚さ:20μm)の表面に塗布し、120℃で3分間乾燥後、ロールプレス機で圧縮成形して平面形状が矩形の正極活物質層を作製した。裏面にも同様にして正極活物質層を形成して、正極集電体(アルミニウム箔)の両面に正極活物質層が形成されてなる正極を作製した。なお、正極活物質層の片面塗工量は24mg/cm2(箔を含まない)であった。また、正極活物質層の密度は3.5g/cm3(箔を含まない)であった。また、電極のアスペクト比(矩形状の正極活物質層の縦横比)は1.3であった。
硫酸ニッケル、硫酸コバルト、および硫酸マンガンを溶解した水溶液(1mol/L)に、60℃にて水酸化ナトリウムおよびアンモニアを連続的に供給してpHを11.3に調整し、共沈法によりニッケルとマンガンとコバルトとが50:30:20のモル比で固溶してなる金属複合水酸化物を作製した。
2.1.比較例1-1~比較例1-7の負極の作製
バインダとしてスチレン-ブタジエンゴム(SBR)を用い、該SBRの分散性(および空孔の分散性)の異なる負極の作製について、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間または回転速度を変えて調整した。このようにして、表1に示したようにバインダであるSBRの分散性のばらつき(さらには空孔の分散性のばらつき)を変えた負極を作製した。以下、各比較例につき説明する。
負極活物質として天然黒鉛96質量%、導電助剤としてカーボンブラック1質量%、バインダとしてSBR2質量%および増粘剤としてカルボキシメチルセルロースのナトリウム塩(CMCのNa塩という)1質量%を用意した。これらを精製水中に添加し、4分間、回転速度2000rpmで攪拌脱泡機を用いて撹拌混合して(十分に)分散されてなる負極活物質(水系)スラリーを調製した。なお、カーボンブラックには、IMERYS社製、Super-P(登録商標)を用いた。また、バインダには、スチレン-ブタジエンゴムのラテックスを用い、この中の固形分のスチレン-ブタジエンゴム(SBR)の含有量が2質量%となるようにした。
比較例1-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、2分間に変更した以外は、比較例1-1と同様にして比較例1-2の負極を作製した。また、比較例1-2の負極を構成する負極活物質層の密度は1.5g/cm3(箔を含まない)であった。
比較例1-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、1.5分間に変更した以外は、比較例1-1と同様にして比較例1-3の負極を作製した。また、比較例1-3の負極を構成する負極活物質層の密度は1.5g/cm3(箔を含まない)であった。
比較例1-2と同様の方法で比較例1-4の負極を作製した。また、比較例1-4の負極を構成する負極活物質層の密度は1.5g/cm3(箔を含まない)であった。
比較例1-3と同様の方法で比較例1-5の負極を作製した。また、比較例1-5の負極を構成する負極活物質層の密度は1.5g/cm3(箔を含まない)であった。
比較例1-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、3分間に変更した以外は、比較例1-1と同様にして比較例1-6の負極を作製した。また、比較例1-6の負極を構成する負極活物質層の密度は1.5g/cm3(箔を含まない)であった。
バインダであるSBRの分散性および空孔の分散性の異なる負極の作製について、バインダであるSBRの分散性については、主に負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を変えて調整した。また、空孔の分散性については、主に分散時間および分散時の回転数を変えて調整した。このようにして、表2に示したようにバインダであるSBRの分散性のばらつき、さらには空孔の分散性のばらつきを変えた負極を作製した。なお、SBRの分散性のばらつき、および空孔の分散性のばらつきの算出法は、「2.1.比較例1-1~比較例1-7の負極の作製」の項で説明した通りである。以下、各比較例及び実施例につき説明する。
負極活物質として天然黒鉛86.4質量%及びSi-Ti合金9.6質量%、導電助剤としてカーボンブラック1質量%、バインダとしてSBR2質量%並びに増粘剤としてCMCのNa塩1質量%を用意した。これらを精製水中に添加し、4分間、2000rpmでシンキー製ミキサーを用いて撹拌混合して(十分に)分散されてなる負極活物質(水系)スラリーを調製した。なお、カーボンブラックには、イメリス社製、Super-P(登録商標)を用いた。また、天然黒鉛の平均粒子径は20μmであった。
比較例2-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、2分間に変更した以外は、比較例2-1と同様にして比較例2-2の負極を作製した。また、比較例2-2の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、1.5分間に変更した以外は、比較例2-1と同様にして比較例2-3の負極を作製した。また、比較例2-3の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-3と同様にして比較例2-4の負極を作製した。また、比較例2-4の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、1分間に変更した以外は、比較例2-1と同様にして比較例2-5の負極を作製した。また、比較例2-5の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-1と同様にして実施例2-1の負極を作製した。また、実施例2-1の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-2と同様にして実施例2-2の負極を作製した。また、実施例2-2の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間のまま、分散時の回転速度を2000rpmから1500rpmに変更した以外は、比較例2-1と同様にして実施例2-3の負極を作製した。また、実施例2-3の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、6分間に変更し、さらに分散時の回転速度を2000rpmから1000rpmに変更した以外は、比較例2-1と同様にして実施例2-4の負極を作製した。また、実施例2-4の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、2分間に変更し、さらに分散時の回転速度を2000rpmから1500rpmに変更した以外は、比較例2-1と同様にして実施例2-5の負極を作製した。また、実施例2-5の負極の負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、2分間に変更し、さらに分散時の回転速度を2000rpmから1000rpmに変更した以外は、比較例2-1と同様にして実施例2-6の負極を作製した。また、実施例2-6の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、1分間に変更し、さらに分散時の回転速度を2000rpmから1000rpmに変更した以外は、比較例2-1と同様にして比較例2-6の負極を作製した。また、比較例2-6の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
比較例2-6と同様にして比較例2-7の負極を作製した。また、比較例2-7の負極を構成する負極活物質層の密度は1.6g/cm3(箔を含まない)であった。
バインダであるSBRの分散性および空孔の分散性の異なる負極の作製について、バインダであるSBRの分散性については、主に負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を変えて調整した。また、空孔の分散性については、主に分散時間および分散時の回転数を変えて調整した。このようにして、表3に示したようにバインダであるSBRの分散性のばらつき、さらには空孔の分散性のばらつきを変えた負極を作製した。なお、SBRの分散性のばらつき、および空孔の分散性のばらつきの算出法は、「2.1.比較例1-1~比較例1-7の負極の作製」の項で説明した通りである。以下、各比較例及び実施例につき説明する。
負極組成を、負極活物質として天然黒鉛76.8質量%及びSi-Ti合金19.2質量%、導電助剤としてカーボンブラック1質量%、バインダとしてSBR2質量%並びに増粘剤としてCMCのアンモニウム塩1質量%としたことを除き、比較例2-1と同様にして負極活物質(水系)スラリーを作製した。
比較例3-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、2分間に変更した以外は、比較例3-1と同様にして比較例3-2の負極を作製した。また、比較例3-2の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、1.5分間に変更した以外は、比較例3-1と同様にして比較例3-3の負極を作製した。また、比較例3-3の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-3と同様にして比較例3-4の負極を作製した。また、比較例3-4の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、1分間に変更した以外は、比較例3-1と同様にして比較例3-5の負極を作製した。また、比較例3-5の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-1と同様にして実施例3-1の負極を作製した。また、実施例3-1の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-2と同様にして実施例3-2の負極を作製した。また、実施例3-2の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間のまま、分散時の回転速度を2000rpmから1500rpmに変更した以外は、比較例3-1と同様にして実施例3-3の負極を作製した。また、実施例3-3の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、6分間に変更し、さらに分散時の回転速度を2000rpmから1000rpmに変更した以外は、比較例3-1と同様にして実施例3-4の負極を作製した。また、実施例3-4の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、2分間に変更し、さらに分散時の回転速度を2000rpmから1500rpmに変更した以外は、比較例3-1と同様にして実施例3-5の負極を作製した。また、実施例3-5の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、2分間に変更し、さらに分散時の回転速度を2000rpmから1000rpmに変更した以外は、比較例3-1と同様にして実施例3-6の負極を作製した。また、実施例3-6の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-1において、負極活物質(水系)スラリー作製時の分散(撹拌混合)時間を4分間から、1分間に変更し、さらに分散時の回転速度を2000rpmから1000rpmに変更した以外は、比較例3-1と同様にして比較例3-6の負極を作製した。また、比較例3-6の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
比較例3-6と同様にして比較例3-7の負極を作製した。また、比較例3-7の負極を構成する負極活物質層の密度は1.63g/cm3(箔を含まない)であった。
3.1.小型の電池(比較例1-1~1-3、1-6、比較例2-1~2-3、2-7、比較例3-1~3-3、3-7)
上記1で得られた正極及び上記2で得られた負極を活物質層面積;縦2.5cm×横2.0cmになるように切り出し、多孔質ポリプロピレン製セパレータ(厚さ25μm、空孔率55%)を介して積層し(正極1枚、負極2枚)、発電要素を作製した。得られた発電要素の各集電体に正極リードと負極リードを接合し、これらの正極リードまたは負極リードを、正極集電板または負極集電板に接合した。そして、正極集電板および負極集電板が電池外部に露出するように、発電要素を電池外装材であるアルミラミネートシート製バッグ(縦3.7cm×横3.2cm)に挿入し、注液機により開口部より電解液を注液した。このアルミラミネートシート製バッグは、2枚のアルミラミネートシート(アルミニウムをPPフィルムでラミネートしたフィルムシート)を重ねあわせ、この外周囲(外縁部)4辺のうち3辺を熱圧着で封止(シール)し、残る1辺を未封止(開口部)としたものである。また、電解液としては、1.0M LiPF6をエチレンカーボネート(EC)とジエチルカーボネート(DEC)との3:7(EC:DECの体積比)混合溶媒に溶解した溶液100重量部に対して、添加剤であるビニレンカーボネートを1質量部添加したものを用いた。ここで、電解液の注液量は、正極活物質層、負極活物質層およびセパレータの全空孔容積(計算により算出した)に対して1.50倍となる量とした。次いで、真空条件下において、両電極(集電体)にリードを介して接続された正極集電板と負極集電板が導出するようにアルミラミネートシート製バッグの開口部を熱圧着で封止し、ラミネート型リチウムイオン二次電池である試験用セルを完成させた。
上記1で得られた正極及び上記2で得られた負極を活物質層面積;縦25cm×横15cmになるように切り出し、多孔質ポリプロピレン製セパレータ(厚さ25μm、空孔率55%)を介して積層し(正極10枚、負極11枚)、発電要素を作製した。得られた発電要素の各集電体に正極リードと負極リードを接合し、これらの正極リードまたは負極リードを、正極集電板または負極集電板に接合した。そして、正極集電板および負極集電板が電池外部に露出するように、発電要素を電池外装材であるアルミラミネートシート製バッグ(縦27.4cm×横17.4cm)に挿入し電解液を注液した。このアルミラミネートシート製バッグは、2枚の矩形形状のアルミラミネートシートを重ねあわせ、この外周囲(外縁部)4辺のうち3辺を熱圧着で封止(シール)し、残る1辺を未封止(開口部)としたものである。また、電解液としては、1.0M LiPF6をエチレンカーボネート(EC)とジエチルカーボネート(DEC)との3:7(EC:DECの体積比)混合溶媒に溶解した溶液100重量部に対して、添加剤であるビニレンカーボネートを1質量部添加したものを用いた。ここで、電解液の注液量は、正極活物質層、負極活物質層およびセパレータの全空孔容積(計算により算出した)に対して1.50倍となる量とした。次いで、真空条件下において、両電極(集電体)にリードを介して接続された正極集電板または負極集電板が導出するようにアルミラミネートシート製バッグの開口部を熱圧着で封止し、ラミネート型リチウムイオン二次電池である試験用セルを完成させた。
4.1.電池特性の評価
上記で得られた各電池(試験用セル)を以下の条件で充放電試験を行うことで定格容量を計測し、また電池体積を測定し、さらにサイクル耐久性を評価した。
電池(試験用セル)の定格容量は、以下により求めた。
電池(試験用セル)体積は、電池外装体まで含めた電池の投影面積と厚みとの積により求めた。このうち、電池外装体まで含めた電池の投影面積に関しては、正面、背面、右側面、左側面、平面、底面の6つの電池の投影面積が得られるが、このうちの最大の電池の投影面積を用いればよく、本実施例では、電池(試験用セル)を平板上に最も安定した状態に置いた際の底面の電池の投影面積を用いた。また、電池外装体まで含めた電池の厚みは、満充電時として、本実施例では、上記「4.2.定格容量の計測」と同様にして手順4まで実施し、手順4の定電圧充電後の満充電状態の電池(試験用セル)の厚みを測定した。また、電池外装体まで含めた電池の厚みは、大型電池の場合、大面積であることから、測定箇所によるばらつきを考慮し、本実施例では、電池の外観を表した斜視図である図2中に示す1~9の数字で表した箇所ないしその近傍の9箇所で電池外装体まで含めた電池の厚みを測定し、これらを平均した値とした。小型電池の厚さも同様にして測定した。得られた結果を下記表1~3中の「セル体積」の欄に示す。
サイクル耐久性の評価では、上記3.電池の作製で得られた各電池(試験用セル)につき、1Cレートでの充放電を、25℃で100サイクル繰り返した。電池の評価の際、充電条件は、0.5Cレートにて最高電圧が4.2Vとなるまで充電した後、電流値が0.01Cとなるまで定電流定電圧充電法で行った。また、放電条件は、電池の最低電圧が3.0Vとなるまで0.5Cレートで放電する定電流放電法で行った。いずれも、常温常圧下(25℃、大気圧下)で行った。1サイクル目の放電容量に対する100サイクル目の放電容量の割合を「容量維持率(%)」として評価した。得られた結果を、下記表1~3中の「100cyc容量維持率(%)」の欄に示す。
11 負極集電体、
12 正極集電体、
13 負極活物質層、
15 正極活物質層、
17 電解質層(セパレータ)、
19 単電池層、
21、57 発電要素、
25 負極集電板、
27 正極集電板、
29、52 電池外装材、
58 正極タブ、
59 負極タブ。
Claims (7)
- 定格容量に対する電池体積(電池外装体まで含めた電池の投影面積と厚みの積)の比の値が10cm3/Ah以下で、定格容量が3Ah以上である非水電解質二次電池であって、
正極集電体の表面に正極活物質を含む正極活物質層が形成されてなる正極と、
負極集電体の表面に負極活物質を含む負極活物質層が形成されてなる負極と、
セパレータと、
を含む発電要素を有し、
前記負極活物質層が、下記式(1)
負極活物質層面内における任意の場所を複数選択した場合における、負極活物質層断面の各像の視野面積においてバインダが占める面積比率(%)の最大値と最小値の差が10%以内であることを特徴する非水電解質二次電池。 - 前記負極活物質層に含有されるバインダが、少なくともスチレン-ブタジエンゴムを含むことを特徴とする請求項1に記載の非水電解質二次電池。
- 前記負極活物質層面内における任意の場所を複数選択した場合における、負極活物質層断面の各像における空孔の面積比率(%)の最大値と最小値の差が10%以内であることを特徴する請求項1または2に記載の非水電解質二次電池。
- 前記正極活物質が、
一般式(1):LiaNibMncCodMxO2(但し、a、b、c、d、xは、0.9≦a≦1.2、0<b<1、0<c≦0.5、0<d≦0.5、0≦x≦0.3、b+c+d=1を満たし、Mは、Ti、Zr、Nb、W、P、Al、Mg、V、Ca、SrおよびCrからなる群から選ばれる少なくとも1種である)で表されるリチウムニッケル系複合酸化物を含むことを特徴とする請求項1~3のいずれか1項に記載の非水電解質二次電池。 - 電極形状が矩形状であり、矩形状の電極活物質層の縦横比として定義される電極のアスペクト比が1~3であることを特徴とする請求項1~4のいずれか1項に記載の非水電解質二次電池。
- 前記セパレータが、多孔質基体に耐熱絶縁層が積層されたセパレータであることを特徴とする請求項1~5のいずれか1項に記載の非水電解質二次電池。
- アルミニウムを含むラミネートフィルムからなる電池外装体に前記発電要素が封入されてなる構成を有する扁平積層型ラミネート電池であることを特徴とする請求項1~6のいずれか1項に記載の非水電解質二次電池。
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