WO2017131490A3 - 혼성 담지 촉매 및 이를 이용하는 올레핀 중합체의 제조 방법 - Google Patents

혼성 담지 촉매 및 이를 이용하는 올레핀 중합체의 제조 방법 Download PDF

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WO2017131490A3
WO2017131490A3 PCT/KR2017/000993 KR2017000993W WO2017131490A3 WO 2017131490 A3 WO2017131490 A3 WO 2017131490A3 KR 2017000993 W KR2017000993 W KR 2017000993W WO 2017131490 A3 WO2017131490 A3 WO 2017131490A3
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Prior art keywords
olefin polymer
supported catalyst
same
hybrid supported
preparing olefin
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PCT/KR2017/000993
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English (en)
French (fr)
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WO2017131490A2 (ko
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권현지
권헌용
홍대식
김대환
이승민
신은영
박성호
유영석
이진영
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주식회사 엘지화학
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Priority to US15/742,001 priority Critical patent/US10669356B2/en
Priority to CN201780002569.3A priority patent/CN108602908B/zh
Priority to EP17744611.9A priority patent/EP3312201B1/en
Publication of WO2017131490A2 publication Critical patent/WO2017131490A2/ko
Publication of WO2017131490A3 publication Critical patent/WO2017131490A3/ko

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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F10/06—Propene
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    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
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    • C08F4/00—Polymerisation catalysts
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    • C08F2420/00—Metallocene catalysts
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    • C08F2420/00—Metallocene catalysts
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    • C08F4/00—Polymerisation catalysts
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

본 발명은 혼성 담지 촉매 및 이를 이용한 올레핀 중합체의 제조 방법에 관한 것이다. 상기 혼성 담지 촉매를 이용하면 기존의 메탈로센 촉매로 중합된 올레핀 중합체의 우수한 기계적 강도는 유지하면서 기존의 올레핀 중합체 대비 현저하게 향상된 가공성을 나타내는 올레핀 중합체를 제공할 수 있다.
PCT/KR2017/000993 2016-01-27 2017-01-26 혼성 담지 촉매 및 이를 이용하는 올레핀 중합체의 제조 방법 WO2017131490A2 (ko)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US15/742,001 US10669356B2 (en) 2016-01-27 2017-01-26 Supported hybrid catalyst and method for preparing olefin polymer using the same
CN201780002569.3A CN108602908B (zh) 2016-01-27 2017-01-26 负载型复合催化剂及使用其制备烯烃聚合物的方法
EP17744611.9A EP3312201B1 (en) 2016-01-27 2017-01-26 Supported hybrid catalyst and method for preparing olefin polymer using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2016-0010098 2016-01-27
KR20160010098 2016-01-27

Publications (2)

Publication Number Publication Date
WO2017131490A2 WO2017131490A2 (ko) 2017-08-03
WO2017131490A3 true WO2017131490A3 (ko) 2018-08-02

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PCT/KR2017/000993 WO2017131490A2 (ko) 2016-01-27 2017-01-26 혼성 담지 촉매 및 이를 이용하는 올레핀 중합체의 제조 방법

Country Status (5)

Country Link
US (1) US10669356B2 (ko)
EP (1) EP3312201B1 (ko)
KR (1) KR101927460B1 (ko)
CN (1) CN108602908B (ko)
WO (1) WO2017131490A2 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101950462B1 (ko) 2016-02-24 2019-02-20 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
KR102140260B1 (ko) * 2016-12-22 2020-07-31 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
KR20200056800A (ko) * 2018-11-15 2020-05-25 롯데케미칼 주식회사 프로필렌 중합용 담지촉매 및 이를 이용하는 폴리프로필렌 수지의 제조방법
KR102602239B1 (ko) * 2019-01-28 2023-11-13 주식회사 엘지화학 폴리올레핀
KR102530448B1 (ko) * 2019-03-13 2023-05-08 주식회사 엘지화학 전이 금속 화합물 및 이를 포함하는 촉매 조성물
KR102475975B1 (ko) * 2019-10-17 2022-12-08 한화솔루션 주식회사 혼성 촉매 조성물, 이를 포함하는 촉매 및 이들의 제조방법

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