WO2019078653A3 - 변성 공액디엔계 중합체 및 이의 제조방법 - Google Patents

변성 공액디엔계 중합체 및 이의 제조방법 Download PDF

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Publication number
WO2019078653A3
WO2019078653A3 PCT/KR2018/012367 KR2018012367W WO2019078653A3 WO 2019078653 A3 WO2019078653 A3 WO 2019078653A3 KR 2018012367 W KR2018012367 W KR 2018012367W WO 2019078653 A3 WO2019078653 A3 WO 2019078653A3
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Prior art keywords
conjugated diene
modified conjugated
based polymer
preparing same
polymer
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PCT/KR2018/012367
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English (en)
French (fr)
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WO2019078653A2 (ko
Inventor
김지은
이은경
조대준
최원문
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주식회사 엘지화학
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Priority to JP2020506770A priority Critical patent/JP6918201B2/ja
Priority to CN201880060832.9A priority patent/CN111133044B/zh
Priority to EP18868760.2A priority patent/EP3699226B1/en
Priority to US16/651,653 priority patent/US11319386B2/en
Publication of WO2019078653A2 publication Critical patent/WO2019078653A2/ko
Publication of WO2019078653A3 publication Critical patent/WO2019078653A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/22—Incorporating nitrogen atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
    • C07C229/10—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C07C229/16—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of hydrocarbon radicals substituted by amino or carboxyl groups, e.g. ethylenediamine-tetra-acetic acid, iminodiacetic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/25—Incorporating silicon atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/43—Compounds containing sulfur bound to nitrogen
    • C08K5/44—Sulfenamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 화학식 1로 표시되는 변성제, 이의 제조방법, 상기 변성제 유래 작용기를 포함하는 고변성률의 변성 공액디엔계 중합체, 상기 중합체의 제조방법에 관한 것이다.
PCT/KR2018/012367 2017-10-20 2018-10-18 변성 공액디엔계 중합체 및 이의 제조방법 WO2019078653A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2020506770A JP6918201B2 (ja) 2017-10-20 2018-10-18 変性共役ジエン系重合体およびその製造方法
CN201880060832.9A CN111133044B (zh) 2017-10-20 2018-10-18 改性共轭二烯类聚合物及其制备方法
EP18868760.2A EP3699226B1 (en) 2017-10-20 2018-10-18 Modified conjugated diene-based polymer and method for preparing same
US16/651,653 US11319386B2 (en) 2017-10-20 2018-10-18 Modified conjugated diene-based polymer and method for preparing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2017-0136711 2017-10-20
KR20170136711 2017-10-20

Publications (2)

Publication Number Publication Date
WO2019078653A2 WO2019078653A2 (ko) 2019-04-25
WO2019078653A3 true WO2019078653A3 (ko) 2019-06-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2018/012367 WO2019078653A2 (ko) 2017-10-20 2018-10-18 변성 공액디엔계 중합체 및 이의 제조방법

Country Status (6)

Country Link
US (1) US11319386B2 (ko)
EP (1) EP3699226B1 (ko)
JP (1) JP6918201B2 (ko)
KR (1) KR102109837B1 (ko)
CN (1) CN111133044B (ko)
WO (1) WO2019078653A2 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102421536B1 (ko) * 2019-07-15 2022-07-15 주식회사 엘지화학 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물
CN113348185B (zh) * 2019-09-25 2023-08-01 株式会社Lg化学 改性共轭二烯类聚合物、其制备方法和包含该改性共轭二烯类聚合物的橡胶组合物
KR102685989B1 (ko) * 2019-10-31 2024-07-18 주식회사 엘지화학 신규 화합물, 이의 제조방법, 상기 화합물 유래 작용기를 포함하는 변성 공액디엔계 중합체 및 상기 중합체의 제조방법
CN113728023B (zh) * 2019-10-31 2023-06-06 株式会社Lg化学 改性剂、改性共轭二烯类聚合物及其制备方法
KR102666895B1 (ko) * 2019-11-21 2024-05-20 주식회사 엘지화학 변성 공액디엔계 중합체의 제조방법

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080033110A1 (en) * 2004-04-05 2008-02-07 Eiju Suzuki Modified Conjugated Diene Polymer, Polymerization Intitiator, Method of Producing the Same, and Rubber Composition
WO2011041534A1 (en) * 2009-09-30 2011-04-07 Bridgestone Corporation Functionalized polymers and methods for their manufacture
JP2012087200A (ja) * 2010-10-19 2012-05-10 Asahi Kasei Chemicals Corp 分岐変性共役ジエン系重合体の製造方法及び分岐変性共役ジエン系重合体組成物
JP2013060525A (ja) * 2011-09-13 2013-04-04 Asahi Kasei Chemicals Corp 変性共役ジエン系重合体の製造方法、及び変性共役ジエン系重合体組成物
KR20160076161A (ko) * 2014-12-22 2016-06-30 주식회사 엘지화학 관능기가 도입된 아미노실란계 말단변성제를 이용하는 고무 조성물의 제조방법 및 이에 따라 제조한 고무 조성물

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JPH0657767B2 (ja) 1987-01-28 1994-08-03 住友化学工業株式会社 変性ゴム組成物
JPH0657767A (ja) 1992-08-05 1994-03-01 Fujita Corp プレキャスト重力式擁壁の構築方法
JP5580997B2 (ja) * 2009-03-13 2014-08-27 株式会社ブリヂストン ゴム組成物及びタイヤ
JP2011079882A (ja) 2009-10-02 2011-04-21 Bridgestone Corp タイヤ
WO2013035589A1 (ja) 2011-09-08 2013-03-14 旭化成ケミカルズ株式会社 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、変性共役ジエン系重合体組成物、ゴム組成物及びタイヤ
KR101525347B1 (ko) 2014-03-10 2015-06-03 주식회사 엘지화학 변성 공액 디엔계 중합체 및 이의 제조방법
CN107074987B (zh) 2014-11-28 2020-05-19 Lg化学株式会社 改性的基于丁二烯的聚合物以及用于制备该聚合物的改性剂
KR20160065015A (ko) 2014-11-28 2016-06-08 주식회사 엘지화학 변성 부타디엔계 중합체 및 이의 제조에 유용한 변성제
KR101877100B1 (ko) * 2015-06-19 2018-07-10 주식회사 엘지화학 관능기가 도입된 아미노실란계 말단변성제를 이용하는 고무 조성물의 제조방법 및 이에 따라 제조한 고무 조성물
KR101868213B1 (ko) * 2015-12-18 2018-06-15 주식회사 엘지화학 변성 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물
KR20170136711A (ko) 2016-06-02 2017-12-12 주식회사 더더더 음성 제보를 위한 프로그램 및 기록매체

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080033110A1 (en) * 2004-04-05 2008-02-07 Eiju Suzuki Modified Conjugated Diene Polymer, Polymerization Intitiator, Method of Producing the Same, and Rubber Composition
WO2011041534A1 (en) * 2009-09-30 2011-04-07 Bridgestone Corporation Functionalized polymers and methods for their manufacture
JP2012087200A (ja) * 2010-10-19 2012-05-10 Asahi Kasei Chemicals Corp 分岐変性共役ジエン系重合体の製造方法及び分岐変性共役ジエン系重合体組成物
JP2013060525A (ja) * 2011-09-13 2013-04-04 Asahi Kasei Chemicals Corp 変性共役ジエン系重合体の製造方法、及び変性共役ジエン系重合体組成物
KR20160076161A (ko) * 2014-12-22 2016-06-30 주식회사 엘지화학 관능기가 도입된 아미노실란계 말단변성제를 이용하는 고무 조성물의 제조방법 및 이에 따라 제조한 고무 조성물

Also Published As

Publication number Publication date
CN111133044A (zh) 2020-05-08
CN111133044B (zh) 2021-10-29
KR20190044524A (ko) 2019-04-30
US20200308368A1 (en) 2020-10-01
EP3699226A4 (en) 2020-11-25
EP3699226B1 (en) 2021-06-30
KR102109837B1 (ko) 2020-05-13
WO2019078653A2 (ko) 2019-04-25
JP2020530013A (ja) 2020-10-15
JP6918201B2 (ja) 2021-08-11
US11319386B2 (en) 2022-05-03
EP3699226A2 (en) 2020-08-26

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