WO2017094729A1 - 食品包装用フィルム及び化粧箱付食品包装用小巻フィルム - Google Patents
食品包装用フィルム及び化粧箱付食品包装用小巻フィルム Download PDFInfo
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- WO2017094729A1 WO2017094729A1 PCT/JP2016/085434 JP2016085434W WO2017094729A1 WO 2017094729 A1 WO2017094729 A1 WO 2017094729A1 JP 2016085434 W JP2016085434 W JP 2016085434W WO 2017094729 A1 WO2017094729 A1 WO 2017094729A1
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- film
- food packaging
- mass
- resin
- food
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- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/08—Homopolymers or copolymers of vinylidene chloride
Definitions
- the present invention relates to a food packaging film and a food packaging small roll film with a decorative box.
- Patent Document 1 discloses that assimilation between food and container to be packaged and a film is prevented, the end face of the film can be easily discriminated, and the films on the end face, or the food, container and the film are more closely attached than necessary.
- a food packaging film is disclosed in which embossing is applied to a predetermined portion of a film for the purpose of preventing the above.
- An object of the present invention is to provide a food packaging film and a food packaging small roll film with a cosmetic box that are identifiable even when mixed in food and are excellent in film-forming property and productivity.
- the present invention provides a food packaging film containing a thermoplastic resin, a blue colorant, and a white colorant.
- the content of the blue colorant is preferably 0.45 to 2.2% by mass based on the total amount of the film.
- the content of the white colorant is preferably 0.15 to 0.55% by mass based on the total amount of the film.
- the thermoplastic resin may be at least one selected from the group consisting of polyvinyl chloride resins, polyvinylidene chloride resins, polyolefin resins, polyester resins, and polyamide resins.
- the film may contain 70% by mass or more of at least one selected from the group consisting of a polyvinyl chloride resin, a polyvinylidene chloride resin and a polyolefin resin as a thermoplastic resin based on the total amount of the film.
- the film may be a film that allows the packaged food to be visually recognized from the outside.
- the total light transmittance of the film may be 70% or more.
- the present invention also includes the above food packaging film, a core material in which the food packaging film is wound, and a cosmetic box in which the food packaging film and the core material are stored.
- a food packaging small roll film with a decorative box provided with a blade for cutting the packaging film.
- the film according to the present embodiment contains a thermoplastic resin, a blue colorant, and a white colorant, and is suitably used as a food packaging film.
- the thermoplastic resin is polyvinyl chloride resin such as polyvinyl chloride; polyvinylidene chloride resin such as polyvinylidene chloride; polyolefin resin such as saponified polyethylene, polypropylene, ethylene-vinyl acetate copolymer; butadiene-styrene copolymer Polystyrene resins such as polymers, acrylonitrile-styrene copolymers, polystyrene, styrene-butadiene-styrene copolymers, styrene-isoprene-styrene copolymers, styrene-acrylic acid copolymers; polyethylene terephthalate, polyethylene naphthalate, Polyester resins such as polybutylene terephthalate; polyamide resins such as 6-nylon, 6,6-nylon, and 12-nylon;
- the thermoplastic resin is preferably a polyvinyl chloride resin
- polyvinyl chloride resin a polyvinyl chloride resin having an average polymerization degree of 700 to 1300 is preferable from the viewpoint of excellent film moldability, heat resistance and fluidity.
- the average degree of polymerization in this specification means an average degree of polymerization measured according to JIS K6720-2.
- the polyvinyl chloride resin may be a vinyl chloride homopolymer (polyvinyl chloride resin) from the viewpoint of excellent mechanical properties, and for the purpose of imparting other properties, other vinyl chloride and other copolymerizable with this may be used. It may be a copolymer with a monomer.
- the copolymer may be a graft copolymer, a block copolymer or a random copolymer.
- Examples of other monomers include olefins such as ethylene, propylene, and polybutene; vinyl esters of saturated acids such as vinyl acetate and vinyl laurate; alkyl esters of unsaturated acids such as methyl acrylate and methyl methacrylate; lauryl Alkyl vinyl ethers such as vinyl ether; maleic acid, acrylonitrile, styrene, methylstyrene, vinylidene fluoride; and the like.
- the polyvinyl chloride resin is a copolymer
- the content of vinyl chloride units in the copolymer may be 10% by mass or more based on the total amount of monomer units, and is preferably 30 from the viewpoint of excellent mechanical properties. It is at least 50% by mass, more preferably at least 50% by mass.
- the upper limit of the content of vinyl chloride units in the copolymer is not particularly limited, and may be 99% by mass or less based on the total amount of monomer units, for example.
- the polyvinyl chloride resin may be, for example, a polymer blend with a three-dimensional polymer of acrylonitrile-butadiene-styrene, a post-treatment product with alcohol, or a post-treatment product with a chlorine-containing compound.
- the content of the vinyl chloride unit in the polyvinyl chloride resin may be 10% by mass or more based on the total amount of the resin.
- the polyvinylidene chloride-based resin may be a vinylidene chloride homopolymer (polyvinylidene chloride resin), for example, a copolymer containing, as monomer units, vinylidene chloride and other monomers copolymerizable with vinylidene chloride. It's okay.
- Other monomers include vinyl chloride, acrylic acid esters of acrylic acid and alcohols having 1 to 8 carbon atoms, methacrylic acid esters of methacrylic acid and alcohols having 1 to 8 carbon atoms, vinyl esters of aliphatic carboxylic acids, unsaturated Aliphatic carboxylic acids, olefins, vinyl ethers and the like may be used.
- the copolymer of vinylidene chloride and vinyl chloride belongs to the polyvinylidene chloride resin.
- the content of the vinylidene chloride unit in the polyvinylidene chloride resin is, for example, 60% by mass or more, 70% by mass or more, or 80% by mass or more based on the total amount of the monomer units from the viewpoint of film moldability and heat resistance. It's okay.
- the upper limit of the content of the vinylidene chloride unit in the polyvinylidene chloride resin is not particularly limited, and may be, for example, 99% by mass or less based on the total amount of monomer units.
- the content of vinylidene chloride units can be measured with a nuclear magnetic resonance (NMR) apparatus.
- the weight average molecular weight of the polyvinylidene chloride resin may be, for example, 40,000 to 180,000, 60000 to 160000, or 80000 to 140000.
- the weight average molecular weight of the polyvinylidene chloride resin can be measured by GPC method using polystyrene having a known molecular weight as a standard substance.
- the conditions of the GPC method used for measuring the weight average molecular weight of the polyvinylidene chloride resin are as follows.
- a gel chromatograph Alliance GPC2000 manufactured by Waters Co. is used as a measuring device.
- a sample obtained by dissolving a polyvinylidene chloride resin in tetrahydrofuran so as to be 0.5% by weight is used as a sample.
- Mobile phase Tetrahydrofuran Detector: Differential refractometer Flow rate: 1.0 mL / min Column temperature: 20 ° C Injection volume: 500 ⁇ L
- the film may further contain a plasticizer.
- the plasticizer include epoxidized linseed oil, epoxidized soybean oil, epoxidized oil such as epoxidized fatty acid alkyl ester, adipic acid ester having a linear or branched alkyl group having 6 to 10 carbon atoms, tributyl acetylcitrate, Hydroxypolycarboxylic acid esters such as acetylated triethyl, fatty acid dibasic acid esters such as dinormalbutyl sebacate, glycol esters such as pentaerythritol ester and diethylene glycol benzoate, phosphate esters such as triphenyl phosphate and tricresyl phosphate Glycerin diacetomonolaurate, chlorinated paraffin, polyester plasticizer and the like.
- plasticizers are used alone or in combination of two or more.
- the content of the plasticizer is appropriately adjusted within a range of, for example, 20 to 50 parts by mass with respect to 100 parts by mass of the polyvinyl chloride resin, depending on the type of food to be packaged, the packaging form, the packaging method, and the like. .
- polyolefin resins examples include polyethylene resins, and polyethylene resins include low density polyethylene, linear low density polyethylene, linear ultra low density polyethylene, medium density polyethylene, high density polyethylene, and ethylene as monomer units. It may be a copolymer. Specifically, the polyethylene resin has 3 to 10 carbon atoms such as ethylene and propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-heptene, 1-octene, and the like.
- ⁇ -olefins vinyl esters such as vinyl acetate and vinyl propionate, unsaturated carboxylic acid esters such as methyl acrylate, ethyl acrylate, methyl methacrylate and ethyl methacrylate, unsaturated compounds such as conjugated dienes and non-conjugated dienes; It may be a copolymer with one or more selected from the above.
- the content of ethylene units in the polyethylene resin may be 50% by mass or more based on the total amount of monomer units.
- the content of the thermoplastic resin may be 70% by mass or more or 75% by mass or more and 85% by mass or less or 80% by mass or less based on the total amount of the film from the viewpoint of excellent productivity.
- the content of polyvinyl chloride resin, polyvinylidene chloride resin or polyolefin resin is preferably in the above range, and the content of polyvinyl chloride resin, polyvinylidene chloride resin or polyethylene resin is in the above range. It is more preferable that
- the blue colorant is, for example, a colorant having a maximum absorption wavelength in the visible light region (380 to 750 nm) at 600 to 750 nm.
- the absorbance of the blue colorant at the maximum absorption wavelength in the visible light region is preferably at least 2 times, more preferably at least 3 times the absorbance at 470 nm.
- the blue colorant may be copper phthalocyanine (copper phthalocyanine blue), iron (III) hexacyanoferrate (ii), a cobaltous oxide / aluminum oxide mixture, indigo, ultramarine, or the like.
- the content of the blue colorant is preferably 0.45% by mass or more, more preferably 0.6% by mass or more, still more preferably 0.75% by mass or more, based on the total amount of the film, from the viewpoint of further excellent discrimination. Especially preferably, it is 1.0 mass% or more.
- the content of the blue colorant is preferably 2.2% by mass or less, more preferably 2.0% by mass or less, and further preferably 1.9%, based on the total amount of the film, from the viewpoint of further improving the film forming property and productivity. It is not more than mass%, particularly preferably not more than 1.8 mass%.
- the content of the blue colorant is preferably 0.45 to 2.2% by mass, 0.45 to 2.0% on the basis of the total amount of the film, from the viewpoint that it is further excellent in all of distinguishability, film forming property and productivity.
- % By mass, 0.45 to 1.9% by mass, 0.45 to 1.8% by mass, 0.6 to 2.2% by mass, 0.6 to 2.0% by mass, 0.6 to 1.9% Mass%, 0.6-1.8 mass%, 0.75-2.2 mass%, 0.75-2.0 mass%, 0.75-1.9 mass%, 0.75-1.8 %
- the content of the blue colorant is preferably greater than the content of the white colorant described below.
- the white colorant is, for example, a colorant having an absorbance of 0.3 or less (scatters visible light) in the entire visible light region (380 nm to 750 nm).
- the white colorant may be titanium oxide, titanium oxide-barium sulfate, titanium oxide-magnesium silicate, titanium oxide-calcium sulfate, or zinc oxide.
- the content of the white colorant is preferably 0.15% by mass or more, more preferably 0.2% by mass or more, still more preferably 0.25% by mass or more, based on the total amount of the film, from the viewpoint of further excellent discrimination. Especially preferably, it is 0.3 mass% or more.
- the content of the white colorant is preferably 0.55% by mass or less, more preferably 0.5% by mass or less, and still more preferably 0.45 on the basis of the total amount of the film from the viewpoint of further improving the film forming property and productivity. It is not more than mass%, particularly preferably not more than 0.4 mass%.
- the content of the white colorant is preferably 0.15 to 0.55% by mass, 0.15 to 0.5% on the basis of the total amount of the film, from the viewpoint that it is further excellent in all of distinguishability, film forming property, and productivity.
- the film may further contain other components in addition to the thermoplastic resin, the blue colorant and the white colorant.
- Other components include antifogging agents, heat stabilizers, light stabilizers, lubricants, fillers, plate-out prevention agents, antioxidants, mold release agents, viscosity reducing agents, surfactants, blue colorants and white colorants.
- Coloring agents other than the agents, fluorescent agents, surface treatment agents, crosslinking agents, processing aids, pressure-sensitive adhesives, antistatic agents, ultraviolet absorbers, antiblocking agents and the like can be mentioned.
- the film may be composed of one layer containing a thermoplastic resin, a blue colorant and a white colorant, or may be composed of a plurality of layers.
- the film may include, for example, a first surface layer, an intermediate layer, and a second surface layer in this order.
- the intermediate layer may contain a blue colorant and a white colorant.
- the film may further include, for example, an adhesive layer containing an acid-modified polyolefin resin or the like in order to improve the adhesion between the layers, and contains a polyamide-based resin in order to improve the heat resistance of the film.
- a heat-resistant layer may be further provided.
- the thermoplastic resin is a polyvinyl chloride resin
- the film is preferably composed of one layer containing a thermoplastic resin (polyvinyl chloride resin), a blue colorant and a polyglycerol fatty acid ester.
- the thickness of the film is preferably 5 ⁇ m or more, more preferably 6 ⁇ m or more from the viewpoint of efficiently blocking food from the outside air, and from the viewpoint of excellent handleability, the thickness is preferably 25 ⁇ m or less, more preferably 12 ⁇ m. It may be the following.
- the total light transmittance of the film is preferably 70% or more, more preferably 75% or more, from the viewpoint of excellent food visibility.
- the total light transmittance of the film is preferably 85% or less, more preferably 80% or less, and still more preferably 79% or less, from the viewpoint of further excellent discrimination for food.
- the total light transmittance of the film is calculated according to the following formula based on the total transmitted light amount measured according to JIS K7361-1.
- Total light transmittance (%) (total transmitted light amount) / (incident light amount) ⁇ 100
- a composition containing a thermoplastic resin, a blue colorant, and a white colorant is mixed by a mixer such as a V-type blender, a ribbon blender, a Henschel mixer, and a super mixer, and further mixed rolls and banbury as necessary.
- the composition is obtained by kneading with a kneader such as a mixer or a kneader, and then manufactured by, for example, extrusion molding.
- the composition is supplied to a hopper of an extruder, and a target film is obtained by an inflation method, a T-die method, or the like.
- the film is wound up while being produced, and the wound film is further rewinded (made in a small roll shape) for each desired length such as 20 m, 50 m, etc., and packed in a cosmetic box. It is said. That is, the film in the present embodiment may be in the form of a food packaging small roll film, or may be in the form of a food packaging small roll film with a decorative box.
- a food packaging small roll film 1 with a cosmetic box includes a food packaging film 2, a core material 3 in which the food packaging film 2 is small wound, and a food packaging film. 2 and a cosmetic box 4 in which the core material 3 is housed, and the cosmetic box 4 may be provided with a blade portion 5 for cutting the food packaging film 2.
- the material of the core material 3 and the decorative box 4 is not particularly limited. From the viewpoint of easily recognizing the color of the film 2 from the outside, at least a part of the decorative box 4 is preferably transparent or has a hole that does not impair the function of the box.
- the film is composed of a plurality of layers
- the film is obtained by putting the constituent materials of each layer into separate extruders, melt-extruding them, and co-extruding each layer by inflation, T-die method or the like and laminating them.
- the film described above is a film that allows the packaged food to be visually recognized from the outside.
- the film is a film (stretch film) having stretchability (also referred to as stretchability).
- the film according to the present embodiment may be a food sorting film used for sorting food. If the film which concerns on this embodiment is used, two or more types of foodstuffs can be classified into at least two groups according to the kind of foodstuff. That is, for example, the first food is wrapped with the film according to the present embodiment and sorted into the first group, while the second food is a film having a color different from that of the film according to the present embodiment or colorless. It can be packaged with film and sorted into a second group.
- first allergic substance when there is a first food containing a first allergic substance and a second food containing a second allergic substance, the first allergic substance has allergic symptoms.
- First food is sorted into a first group, which is a food group provided to a person who is not present, while a food group is provided to a person who does not have an allergic symptom against a second allergic substance. Sort the second food into two groups. In the above example, it is possible to suppress the occurrence of an accident in which a person who has allergic symptoms with respect to the first or second allergic substance is provided with the allergic substance.
- surface is a value of solid content conversion, and represents the mass%.
- Examples 7 to 15 and Comparative Examples 5 to 6> A resin composition is prepared using the following thermoplastic resin, blue colorant, white colorant and various additives shown in Tables 3 and 4, and each resin composition is extruded with an inflation film forming apparatus to form a film having a thickness of 9 ⁇ m. Produced.
- surface is a value of solid content conversion, and represents the mass%.
- Thermoplastic resin a1 Polyvinyl chloride resin (manufactured by Taiyo PVC Co., Ltd., “TH-1000”, average degree of polymerization: 1000)
- Thermoplastic resin a2 Polyethylene resin (manufactured by Prime Polymer Co., Ltd., “Neozex 0234N”)
- White colorant c1 Titanium oxide (manufactured by Sakai Chemical Industry Co., Ltd., “FTR-700”)
- Additive d1 Dioctyl adipate (manufacture
- Total light transmittance (%) (total transmitted light amount) / (incident light amount) ⁇ 100
- evaluation of distinguishability A piece of 3 mm to 10 mm square was produced from the obtained film, and it was visually observed whether the piece of the film could be identified when the film was mixed into food.
- the evaluation criteria are as follows. In addition, if evaluation is A or B, it can be said that it is excellent in distinguishability. A: It is very easy to identify the film for food. B: It is easy to identify the film for food. C: It is difficult to distinguish a film from food.
- SYMBOLS 1 Small roll film for food packaging with a cosmetic box, 2 ... Film for food packaging, 3 ... Core material, 4 ... Cosmetic box, 5 ... Blade part.
Abstract
Description
カラム:東ソー株式会社製TSKgel GMHHR-H(S)HT 30cm×2、TSKgel GMH6-HTL 30cm×2
移動相:テトラヒドロフラン
検出器:示差屈折計
流速:1.0mL/分
カラム温度:20℃
注入量:500μL
全光線透過率(%)=(全透過光量)/(入射光量)×100
表1,2に示す熱可塑性樹脂、青色着色剤、白色着色剤及び各種添加剤をスーパーミキサーに投入した後、攪拌しながら材料温度を常温から130℃まで昇温し、混合した後、70℃まで冷却した時点で取り出して樹脂組成物を調製し、各樹脂組成物をTダイ(幅350mm、ギャップ0.4mm)を装着したΦ40mm単軸押出機(L/D=20)にて、樹脂温度200℃で押出し、厚み8μmのフィルムを作製した。なお、表中の数値は固形分換算の値であり、質量%を表す。
表3,4に示す以下の熱可塑性樹脂、青色着色剤、白色着色剤及び各種添加剤を用いて樹脂組成物を調製し、各樹脂組成物をインフレーション製膜装置で押出し、厚み9μmのフィルムを作製した。なお、表中の数値は固形分換算の値であり、質量%を表す。
熱可塑性樹脂a2:ポリエチレン系樹脂(株式会社プライムポリマー製、「ネオゼックス0234N」)
塩化ビニリデン系樹脂a3:塩化ビニリデンと塩化ビニルとの共重合体(塩化ビニリデン/塩化ビニル(質量比)=90/10)、重量平均分子量:80000
青色着色剤b1:銅フタロシアニン(銅フタロシアニンブルー、大日精化工業株式会社製、「NX-053ブルー」)
白色着色剤c1:酸化チタン(堺化学工業株式会社製、「FTR-700」)
添加剤d1:アジピン酸ジオクチル(新日本理化株式会社製、「サンソサイザーDOA」)
添加剤d2:エポキシ化大豆油(三和合成化学株式会社製、「ケミサイザーSE-100」)
添加剤d3:グリセリン脂肪酸エステル(理研ビタミン株式会社製、「XO-100」)
添加剤d4:Ca/Zn系安定剤(株式会社ADEKA製、「SC-308E」)
添加剤d5:セバシン酸ジブチル(豊国製油株式会社製、「DBS」)
添加剤d6:アセチルクエン酸トリブチル(旭化成ファインケム株式会社製、「ATBC」)
日本電色工業社製ヘーズメーター(型式:NDH5000)にてJIS K7361-1に準拠してフィルムの全透過光量を測定し、下記式に従ってフィルムの全光線透過率を算出した。
全光線透過率(%)=(全透過光量)/(入射光量)×100
得られたフィルムから3mm~10mm角の破片を作製し、食品へフィルムを混入させた際に、フィルムの破片を識別できるかを目視で観察した。評価基準は、以下のとおりである。なお、評価がA又はBであれば、識別性に優れているといえる。
A:食品に対してフィルムを識別することが極めて容易である。
B:食品に対してフィルムを識別することが容易である。
C:食品に対してフィルムを識別することが困難である。
Tダイ押出機にて、各樹脂組成物を樹脂温度200℃で押出してフィルムの成形を行い、得られたフィルムの外観を観察することで製膜性を評価した。評価基準は、以下のとおりである。なお、評価がA又はBであれば、製膜性に優れているといえる。
A:ほぼ均一の厚みのフィルムが得られ、24時間の押出でヤケが発生しなかった。
B:フィルムの厚みにわずかにむらが見られ、24時間の押出でヤケが発生した。
C:フィルムの厚みむらが激しく、8時間の押出でヤケが発生した。
Tダイ押出機にて、各樹脂組成物を樹脂温度200℃で押出してフィルムの成形を行う際に生じる生産トラブル(穴開き、フィルム切れ及びスリット不具合)の24時間あたりの発生回数をカウントすることで生産性を評価した。評価基準は、以下のとおりである。なお、評価がA又はBであれば、生産性に優れているといえる。
A:生産トラブル回数が0~2回
B:生産トラブル回数が3~4回
C:生産トラブル回数が5回以上
Claims (8)
- 熱可塑性樹脂と、青色着色剤と、白色着色剤と、を含有する食品包装用フィルム。
- 前記青色着色剤の含有量が、フィルム全量基準で0.45~2.2質量%である、請求項1に記載の食品包装用フィルム。
- 前記白色着色剤の含有量が、フィルム全量基準で0.15~0.55質量%である、請求項1又は2に記載の食品包装用フィルム。
- 前記熱可塑性樹脂が、ポリ塩化ビニル系樹脂、ポリ塩化ビニリデン系樹脂、ポリオレフィン系樹脂、ポリエステル系樹脂及びポリアミド系樹脂からなる群より選ばれる少なくとも1種である、請求項1~3のいずれか一項に記載の食品包装用フィルム。
- 前記熱可塑性樹脂として、ポリ塩化ビニル系樹脂、ポリ塩化ビニリデン系樹脂及びポリオレフィン系樹脂からなる群より選ばれる少なくとも1種をフィルム全量基準で70質量%以上含有する、請求項1~4のいずれか一項に記載の食品包装用フィルム。
- 前記フィルムが、包装した食品を外部から視認可能なフィルムである、請求項1~5のいずれか一項に記載の食品包装用フィルム。
- 前記フィルムの全光線透過率が70%以上である、請求項1~6のいずれか一項に記載の食品包装用フィルム。
- 請求項1~7のいずれか一項に記載の食品包装用フィルムと、前記食品包装用フィルムが小巻された芯材と、前記食品包装用フィルム及び前記芯材が収納された化粧箱とを備え、
前記化粧箱には、前記食品包装用フィルムを切断するための刃部が設けられている、化粧箱付食品包装用小巻フィルム。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/779,882 US20180312313A1 (en) | 2015-11-30 | 2016-11-29 | Food packaging film, and gift-boxed small roll of food packaging film |
CN201680069821.8A CN108291040B (zh) | 2015-11-30 | 2016-11-29 | 食品包装用膜和带包装盒的食品包装用卷膜 |
SG11201804531RA SG11201804531RA (en) | 2015-11-30 | 2016-11-29 | Food packaging film, and gift-boxed small roll of food packaging film |
EP16870666.1A EP3385310B1 (en) | 2015-11-30 | 2016-11-29 | Food packaging film, and gift-boxed small roll of food packaging film |
JP2017554115A JP7089367B2 (ja) | 2015-11-30 | 2016-11-29 | 食品包装用フィルム及び化粧箱付食品包装用小巻フィルム |
KR1020187018230A KR20180088691A (ko) | 2015-11-30 | 2016-11-29 | 식품 포장용 필름 및 상자 구비 식품 포장용 소권취 필름 |
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PCT/JP2015/083644 WO2017094083A1 (ja) | 2015-11-30 | 2015-11-30 | 食品包装用フィルム |
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CN (1) | CN108291040B (ja) |
SG (1) | SG11201804531RA (ja) |
TW (1) | TWI747859B (ja) |
WO (2) | WO2017094083A1 (ja) |
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JP2019099785A (ja) * | 2017-11-28 | 2019-06-24 | 三菱ケミカル株式会社 | 食品包装用フィルム、食品用ストレッチフィルム、食品用小巻ラップフィルム及び食品包装用フィルムの製造方法 |
WO2020262249A1 (ja) * | 2019-06-24 | 2020-12-30 | 昭和電工マテリアルズ株式会社 | ストレッチ包装用フィルム |
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WO2017094083A1 (ja) * | 2015-11-30 | 2017-06-08 | 日立化成株式会社 | 食品包装用フィルム |
EP3251974B1 (en) * | 2015-11-30 | 2019-06-05 | Hitachi Chemical Company, Ltd. | Food packaging film |
CN112519359B (zh) * | 2020-11-05 | 2023-02-03 | 江西春光新材料科技股份有限公司 | 一种高阻隔复合硬片及其制备方法 |
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2016
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- 2016-11-29 US US15/779,882 patent/US20180312313A1/en not_active Abandoned
- 2016-11-29 JP JP2017554115A patent/JP7089367B2/ja active Active
- 2016-11-29 SG SG11201804531RA patent/SG11201804531RA/en unknown
- 2016-11-29 KR KR1020187018230A patent/KR20180088691A/ko unknown
- 2016-11-29 WO PCT/JP2016/085434 patent/WO2017094729A1/ja active Application Filing
- 2016-11-29 CN CN201680069821.8A patent/CN108291040B/zh active Active
- 2016-11-29 EP EP16870666.1A patent/EP3385310B1/en active Active
- 2016-11-30 TW TW105139348A patent/TWI747859B/zh active
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Also Published As
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CN108291040B (zh) | 2021-08-24 |
US20180312313A1 (en) | 2018-11-01 |
EP3385310B1 (en) | 2021-07-21 |
JPWO2017094083A1 (ja) | 2017-11-30 |
JP2017100800A (ja) | 2017-06-08 |
JP6195046B1 (ja) | 2017-09-13 |
JPWO2017094729A1 (ja) | 2018-09-20 |
EP3385310A1 (en) | 2018-10-10 |
EP3385310A4 (en) | 2018-11-21 |
WO2017094083A1 (ja) | 2017-06-08 |
JP7089367B2 (ja) | 2022-06-22 |
SG11201804531RA (en) | 2018-06-28 |
JP7028544B2 (ja) | 2022-03-02 |
TW201726774A (zh) | 2017-08-01 |
CN108291040A (zh) | 2018-07-17 |
KR20180088691A (ko) | 2018-08-06 |
TWI747859B (zh) | 2021-12-01 |
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