WO2017039235A1 - 에칭 내성이 우수한 i-선용 네가티브형 포토레지스트 조성물 - Google Patents
에칭 내성이 우수한 i-선용 네가티브형 포토레지스트 조성물 Download PDFInfo
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- WO2017039235A1 WO2017039235A1 PCT/KR2016/009494 KR2016009494W WO2017039235A1 WO 2017039235 A1 WO2017039235 A1 WO 2017039235A1 KR 2016009494 W KR2016009494 W KR 2016009494W WO 2017039235 A1 WO2017039235 A1 WO 2017039235A1
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/16—Coating processes; Apparatus therefor
- G03F7/162—Coating on a rotating support, e.g. using a whirler or a spinner
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/16—Coating processes; Apparatus therefor
- G03F7/168—Finishing the coated layer, e.g. drying, baking, soaking
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
- G03F7/2002—Exposure; Apparatus therefor with visible light or UV light, through an original having an opaque pattern on a transparent support, e.g. film printing, projection printing; by reflection of visible or UV light from an original such as a printed image
- G03F7/2004—Exposure; Apparatus therefor with visible light or UV light, through an original having an opaque pattern on a transparent support, e.g. film printing, projection printing; by reflection of visible or UV light from an original such as a printed image characterised by the use of a particular light source, e.g. fluorescent lamps or deep UV light
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/30—Imagewise removal using liquid means
- G03F7/32—Liquid compositions therefor, e.g. developers
- G03F7/322—Aqueous alkaline compositions
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/38—Treatment before imagewise removal, e.g. prebaking
Definitions
- the present invention relates to a negative photoresist composition for I-line having excellent etching resistance.
- Photoresist is used in a photolithography process for forming various patterns.
- the photoresist means a photosensitive resin capable of obtaining an image corresponding to an exposure pattern by changing the solubility in a developer by the action of light.
- NTD negative tone developer
- PTD Positive Tone Development
- the pattern forming method using the negative tone developer is to form a pattern by selectively dissolving and removing the non-exposed areas with a negative tone developer
- the pattern forming method using the positive tone developer is by selectively dissolving and removing the exposure area with a positive tone developer To form a pattern.
- the pattern forming method using the negative tone developer has a reversed pattern even in a contact hole pattern or a trench pattern, which is difficult to form due to insufficient exposure when compared with the pattern forming method using a positive tone developer, thereby forming a pattern when implementing the same pattern. Since an organic solvent is used as a developer for removing this easy and unexposed part, a photoresist pattern can be formed more effectively.
- a photolithography process using a photoresist composition generally includes a process of coating a photoresist on a wafer, a soft baking process of heating a coated photoresist to evaporate a solvent, an image of a light source passing through a photomask, A process of forming a pattern by a difference in solubility of an exposed portion and a non-exposed portion using a developing solution, and etching the same to complete a circuit.
- the photoresist composition is composed of a photo acid generator that generates an acid by excimer laser irradiation, a base resin, and other additives.
- the basic resin has a hydroxyl group in the phenolic structure, and polystyrene polymer, cresol polymer, and novolac polymer are basically used.
- As a photosensitive agent it is possible to generate acid (H + ) at a specific wavelength, and mainly sulfonium Organic acids and inorganic acids such as salts, sulfonyldiazo, benzosulfonyl, iodine, chlorine and carboxylic acid are mainly used.
- the negative photoresist prepared using the composition as described above does not form a desired shape due to the disadvantage that the photosensitive agent located below does not generate a sufficient amount of acid (H + ), and a finer pattern. In the case of forming a process, there is a problem that a worse profile is made.
- the light source mainly used in the above process is a wavelength region of 365 nm to 193 nm using I-ray, KrF excimer laser, and ArF excimer laser light source, and the shorter wavelength can form a finer pattern. It is known.
- conventional patents for I-ray negative photoresist technology include Korean Patent Publication No. 2013-0032071, "I-ray photoresist composition and fine pattern formation method using the same", US Patent Publication No. 5627011 " High resolution i-line photoresist of high sensitivity.
- An object of the present invention is to provide a negative photoresist composition for I-line exhibiting excellent etching resistance compared to the conventional negative photoresist for I-line.
- the present invention provides a negative photoresist composition for I-line comprising at least one member selected from the group consisting of compounds represented by the following formula (1) to (5).
- R may be the same or different from each other, and each independently acryloyl, aryl (Allyl), 3-ethoxyacryloyl, dimethylsilaneallyl, methylacryl (Methylacryl), trans-3- (benzoyl) acryl (trans-3- (Benzoyl) acryl, 3- (2furyl) acryl (3- (2furyl) acryl, 4- (benzyloxy) benzyl (4-benzyloxy) benzyl And 1,4-bisacryloylpiperazine (1,4-bisacryloylpiperazine).
- the compounds represented by Formula 1 to Formula 5 are each 1,4-hydroquinone (1,4-Hydroquinone), naphthalene-1,5-diol (Naphthalene-1,5- diol), bisphenolA, anthracene-9,10-diol and 1,1,1-tris (4-hydroxyphenyl) ethane (1,1,1-tris It is characterized in that the compound obtained by the substitution reaction of the monomer (4-hydroxyphenyl) ethane).
- the compounds represented by Formula 1 to Formula 5 are each characterized by having a weight average molecular weight of 100 to 20,000.
- the composition is based on the total weight of the composition, 5 to 50% by weight of the polymer resin, 0.1 to 10% by weight of at least one compound selected from the group consisting of compounds represented by Formula 1 to Formula 5, crosslinking agent 1 to 10% by weight, 0.1 to 10% by weight photoacid generator and 0.01 to 5% by weight acid diffusion inhibitor and the balance is characterized in that it comprises a solvent.
- the polymer resin is characterized in that at least one selected from the group consisting of phenolic polymer resin and cresol polymer resin containing a hydroxyl group.
- the phenolic polymer resin is 4-hydroxy-3-methyl benzoic acid (4-Hydroxy-3-methyl benzoic acid), 4-hydroxy-2-methyl benzoic acid (4-Hydroxy-2 -methyl benzoic acid), 5-hydroxy-2-methyl benzoic acid, 3,5-di-tert-butyl-4-hydroxy benzoic acid (3,5-Di- tert-butyl-4-hydroxy benzoic acid, 4-Hydroxy-3,5-dimethyl benzoic acid, 4-Hydroxy isophthalic acid , 2,4,6-hydroxy toluene, 2,4,6-trihydroxy benzoic acid monohydrate, 2,4, 6-trihydroxy benzaldehyde (2,4,6-Trihydroxy benzaldehyde), cresol polymer resins are o-cresol, para-cresol, m-cresol, epoxy ortho Epoxy o-cresol, Epoxy p-cresol and When characterized in that the meta-cresol (m-cresol)
- the crosslinking agent is tris (2,3-epoxypropyl) isocyanurate (Tris (2,3-epoxypropyl) isocyanurate), trimethylolmethanetriglycidylether, trimethylol Propanetriglycidyl ether (Trimethylolpropanetriglycidylether), hexamethylolmelamine (Hexamethylolmelamine), triethylol ethanetriglycidylether, hexamethoxymethylmelamine (Hexamethoxymethylmelamine), hexamethoxymethylamine methyl methoxyethylamine 2,4-diamino-1,3,5-triazine (tetramethylol 2,4-diamino-1,3,5-triazine), tetramethoxymethyl-2,4-diamino-1,3,5- Tetramethoxymethyl-2,4-diamino-1,3,5- Tetrameth
- the photoacid generator is tris (trichloromethyl) triazine, 1,1-bis (p-chlorophenyl) -2,2,2-trichloro Ethane (1,1-Bis (p-chlorophenyl) -2,2,2, -trichloroethane), tris (methanesulfonyl) benzene, 1,1-bis (chlorophenyl) -2, 2,2-trichloroethanol (1,1-Bis (chlorophenyl) -2,2,2, trichloroethanol, 2,4,6-tris (tribromomethyl) -s-triazine (2,4,6 -tris (tribromomethyl) -s-triazine), 2-methyl-4,6-bis (tribromomethyl) -s-triazine (2-methyl-4,6-bis (tribromomethyl) -s-triazine), 2-phenyl-4,6-bis (trichloromethyl) -s-
- the acid diffusion inhibitor is methyltriamine (Methyltriamine), ethyltriamine (ethyltriamine), dimethylamine (Dimethylamine), diethylamine (Diethylamine), trimethylamine (trimethylamine), triethylamine (Triethylamine), Tributylthamine (Tributhylamine), Methanoltriamine, Ethanoltriamine, Diethanolamine, Diethanolamine, Triethanolamine, Triethanolamine, Triethanolamine And tributanolamine (Tributhanolamine) is characterized in that it comprises one or more selected from the group consisting of.
- R may be the same or different from each other, and each independently acryloyl, aryl (Allyl), 3-ethoxyacryloyl, dimethylsilaneallyl, methylacryl (Methylacryl), trans-3- (benzoyl) acryl (trans-3- (Benzoyl) acryl, 3- (2furyl) acryl (3- (2furyl) acryl, 4- (benzyloxy) benzyl (4-benzyloxy) benzyl And 1,4-bisacryloylpiperazine (1,4-bisacryloylpiperazine).
- the compounds represented by Formula 1 to Formula 5 are each 1,4-hydroquinone (1,4-Hydroquinone), naphthalene-1,5-diol (Naphthalene-1,5- diol), bisphenolA, anthracene-9,10-diol and 1,1,1-tris (4-hydroxyphenyl) ethane (1,1,1-tris It is characterized in that the compound obtained by the substitution reaction of the monomer (4-hydroxyphenyl) ethane).
- the compounds represented by Formula 1 to Formula 5 are each characterized by having a weight average molecular weight of 100 to 20,000.
- the composition is based on the total weight of the composition, 5 to 50% by weight of the polymer resin, 0.1 to 10% by weight of at least one compound selected from the group consisting of compounds represented by Formula 1 to Formula 5, crosslinking agent 1 to 10% by weight, 0.1 to 10% by weight photoacid generator and 0.01 to 5% by weight acid diffusion inhibitor and the balance is characterized in that it comprises a solvent.
- the polymer resin is characterized in that at least one selected from the group consisting of phenolic polymer resin and cresol polymer resin containing a hydroxyl group.
- the phenolic polymer resin is 4-hydroxy-3-methyl benzoic acid (4-Hydroxy-3-methyl benzoic acid), 4-hydroxy-2-methyl benzoic acid (4-Hydroxy-2 -methyl benzoic acid), 5-hydroxy-2-methyl benzoic acid, 3,5-di-tert-butyl-4-hydroxy benzoic acid (3,5-Di- tert-butyl-4-hydroxy benzoic acid, 4-Hydroxy-3,5-dimethyl benzoic acid, 4-Hydroxy isophthalic acid , 2,4,6-hydroxy toluene, 2,4,6-trihydroxy benzoic acid monohydrate, 2,4, 6-trihydroxy benzaldehyde (2,4,6-Trihydroxy benzaldehyde), cresol polymer resins are o-cresol, para-cresol, m-cresol, epoxy ortho Epoxy o-cresol, Epoxy p-cresol and When characterized in that the meta-cresol (m-cresol)
- the crosslinking agent is tris (2,3-epoxypropyl) isocyanurate (Tris (2,3-epoxypropyl) isocyanurate), trimethylolmethanetriglycidylether, trimethylol Propanetriglycidyl ether (Trimethylolpropanetriglycidylether), hexamethylolmelamine (Hexamethylolmelamine), triethylol ethanetriglycidylether, hexamethoxymethylmelamine (Hexamethoxymethylmelamine), hexamethoxymethylamine methyl methoxyethylamine 2,4-diamino-1,3,5-triazine (tetramethylol 2,4-diamino-1,3,5-triazine), tetramethoxymethyl-2,4-diamino-1,3,5- Tetramethoxymethyl-2,4-diamino-1,3,5- Tetrameth
- the photoacid generator is tris (trichloromethyl) triazine, 1,1-bis (p-chlorophenyl) -2,2,2-trichloro Ethane (1,1-Bis (p-chlorophenyl) -2,2,2, -trichloroethane), tris (methanesulfonyl) benzene, 1,1-bis (chlorophenyl) -2, 2,2-trichloroethanol (1,1-Bis (chlorophenyl) -2,2,2, trichloroethanol, 2,4,6-tris (tribromomethyl) -s-triazine (2,4,6 -tris (tribromomethyl) -s-triazine), 2-methyl-4,6-bis (tribromomethyl) -s-triazine (2-methyl-4,6-bis (tribromomethyl) -s-triazine), 2-phenyl-4,6-bis (trichloromethyl) -s-
- the acid diffusion inhibitor is methyltriamine (Methyltriamine), ethyltriamine (ethyltriamine), dimethylamine (Dimethylamine), diethylamine (Diethylamine), trimethylamine (trimethylamine), triethylamine (Triethylamine), Tributylthamine (Tributhylamine), Methanoltriamine, Ethanoltriamine, Diethanolamine, Diethanolamine, Triethanolamine, Triethanolamine, Triethanolamine And tributanolamine (Tributhanolamine) is characterized in that it comprises one or more selected from the group consisting of.
- the negative photoresist composition for I-rays according to the present invention exhibits excellent etching resistance as compared to the conventional negative photoresist for I-rays, and thus is suitable for application to semiconductor processes.
- 'photoresist' is a mixture of a polymer and a photosensitizer, and its chemical properties are changed by light, so that when exposed to light of a certain wavelength, the solubility in a specific solvent is changed.
- the difference in the dissolution rate of the exposed portion and the non-exposed portion means that after a certain time of dissolution time, the undissolved portion remains to form a pattern.
- the term 'photolithographic process' refers to a mask in which a semiconductor is drawn using a property of the photoresist as described above between a light source and a photoresist film coated on a silicon wafer. Turning on means that the circuitry engraved in the mask is transferred to the photoresist.
- I-line means a light source having a wavelength region of 365nm.
- One embodiment of the present invention to provide a negative photoresist composition for I-line comprising at least one selected from the group consisting of compounds represented by the formula (1) to (5).
- R may be the same or different from each other, and each independently acryloyl, aryl (Allyl), 3-ethoxyacryloyl, dimethylsilaneallyl, methylacryl (Methylacryl), trans-3- (benzoyl) acryl (trans-3- (Benzoyl) acryl, 3- (2furyl) acryl (3- (2furyl) acryl, 4- (benzyloxy) benzyl (4-benzyloxy) benzyl And 1,4-bisacryloylpiperazine (1,4-bisacryloylpiperazine).
- Compounds represented by Formula 1 to Formula 5 are 1,4-hydroquinone (1,4-Hydroquinone), naphthalene-1,5-diol (Naphthalene-1,5-diol), bisphenol A (BisphenolA), Monomers in anthracene-9,10-diol and 1,1,1-tris (4-hydroxyphenyl) ethane (1,1,1-tris (4-hydroxyphenyl) ethane) It may be a compound obtained by a substitution reaction.
- Scheme 1 shows an example of a substitution reaction between a structure having a 1,4-hydroquinone (1,4-Hydroquinone) and a monomer as an example.
- Scheme 2 shows an example of a substitution reaction between a structure having a naphthalene-1,5-diol and a monomer based on Naphthalene-1,5-diol.
- Scheme 3 illustrates an example of a substitution reaction between a structure having a bisphenol A and a monomer.
- Scheme 4 shows an example of a substitution reaction of a structure having a structure based on anthracene-9,10-diol and a monomer.
- Scheme 5 shows an example of a substitution reaction of a structure having a basic structure of 1,1,1-tris (4-hydroxyphenyl) ethane (1,1,1-tris (4-hydroxyphenyl) ethane) and a monomer.
- XR represents a reactive monomer, wherein X is at least one selected from the group consisting of Cl, NH 2 , Br, OH and OCH 3 , R is acryloyl, aryl (Allyl), 3-ethoxyacryloyl, dimethylsilaneallyl, methylacryl, trans-3- (benzoyl) acryl, 3- (2puryl) acryl (3- (2furyl) acryl, 4- (benzyloxy) benzyl and 4-benzyloxy) benzyl and 1,4-bisacryloylpiperazine (1,4-bisacryloylpiperazine) It may be one or more.
- reactive monomers include acryloylchloride, aryl chloride, acryloyl bromide, aryl chloride dimethylsilrane, acrylic acid, bromoacetophenone, bromoacetophenone ), Anthraquinonecarbonyl chloride, arylbromidedimethylsilrane, chloroacetophenone, chloroanthracene, bromoanthracene, and bromoanthracene.
- the compounds represented by Chemical Formulas 1 to 3 obtained by the substitution reaction may each have a weight average molecular weight of 100 to 20,000.
- the negative photoresist composition for I-rays is 0.1 to 10% by weight of at least one compound selected from the group consisting of 5 to 50% by weight of the polymer resin, and compounds represented by Formulas 1 to 5, based on the total weight of the composition.
- 1 to 10% by weight of crosslinking agent, 0.1 to 10% by weight of photoacid generator and 0.01 to 5% by weight of acid diffusion inhibitor and the rest may include a solvent.
- At least one compound selected from the group consisting of compounds represented by Formulas 1 to 5 preferably comprises 0.1 to 10% by weight based on the total weight of the composition. If the compound is used at less than 0.1% by weight, there is no effect on increasing the etching resistance, and it is difficult to confirm the improvement in the performance aspects such as the profile, and when using the compound at more than 10% by weight, the etching resistance increases, but the pattern It is not preferable because it may cause problems such as poor quality and insufficient resolution.
- the polymer resin may be one or more selected from the group consisting of a phenol polymer resin and a cresol polymer resin containing a hydroxyl group.
- the phenolic polymer resin is 4-hydroxy-3-methyl benzoic acid (4-Hydroxy-3-methyl benzoic acid), 4-hydroxy-2-methyl benzoic acid (4-Hydroxy-2 -methyl benzoic acid), 5-hydroxy-2-methyl benzoic acid, 3,5-di-tert-butyl-4-hydroxy benzoic acid (3,5-Di- tert-butyl-4-hydroxy benzoic acid, 4-Hydroxy-3,5-dimethyl benzoic acid, 4-Hydroxy isophthalic acid , 2,4,6-hydroxy toluene, 2,4,6-trihydroxy benzoic acid monohydrate, 2,4, 6-trihydroxy benzaldehyde (2,4,6-Trihydroxy benzaldehyde), cresol polymer resins are o-cresol, para-cresol, m-cresol, epoxy ortho Epoxy o-cresol, epoxy p-cres ol) and epoxy m-cresol.
- the polymer resin preferably contains 5 to 50 wt% of the polymer resin, based on the total weight of the composition. If the polymer resin is used in less than 5% by weight, there is a problem in that high exposure energy is required during patterning and development, and when it is used in excess of 50% by weight, it is difficult to form a uniform pattern, resulting in residues. This can be.
- the crosslinking agent is tris (2,3-epoxypropyl) isocyanurate, trimethylolmethanetriglycidylether, trimethylolpropanetriglycidylether, Hexamethylolmelamine, Trimethylolethanetriglycidylether, Hexamethoxymethylmelamine, Hexamethoxyethylmelamine, Tetramethylol 2,4-diamino-1, 3,5-triazine (Tetramethylol 2,4-diamino-1,3,5-triazine), tetramethoxymethyl-2,4-diamino-1,3,5-triazine (Tetramethoxymethyl-2,4- diamino-1,3,5-triazine), tetramethylolglycoluril, Tetramethoxymethylglycoluril, Tetramethoxyethylglycoluril, Tetramethoxyethylglycoluril, Te
- the crosslinking agent preferably contains 1 to 10% by weight of the crosslinking agent, based on the total weight of the composition. If less than 1% by weight of the crosslinking agent is used, pattern formation may be impossible due to lack of residual film ratio, and if it exceeds 10% by weight, the pattern and the bridge between patterns due to excessive crosslinking may occur. Poor due to the phenomenon may appear.
- the photoacid generator is tris (trichloromethyl) triazine, 1,1-bis (p-chlorophenyl) -2,2,2-trichloroethane (1,1-Bis (p) -chlorophenyl) -2,2,2, -trichloroethane), tris (methanesulfonyl) benzene, 1,1-bis (chlorophenyl) -2,2,2-trichloroethanol (1 , 1-Bis (chlorophenyl) -2,2,2, -trichloroethanol, 2,4,6-tris (tribromomethyl) -s-triazine (2,4,6-tris (tribromomethyl) -s-triazine ), 2-methyl-4,6-bis (tribromomethyl) -s-triazine (2-methyl-4,6-bis (tribromomethyl) -s-triazine), 2-phenyl-4,6-bis (Tribromomethyl)
- the photoacid generator preferably contains 0.1 to 10% by weight of the photoacid generator based on the total weight of the composition. If less than 0.1 wt% of the photoacid generator is used, the pattern cannot be formed due to lack of crosslinking density, and if it exceeds 10 wt%, the pattern of the wall or corner of the pattern is poor due to excessive acid generation (LWR. Pattern failure problems such as LER) may occur.
- the acid diffusion inhibitor is methyltriamine (Methyltriamine), ethyltriamine (ethyltriamine), dimethylamine (Dimethylamine), diethylamine (Diethylamine), trimethylamine (Trimethylamine), triethylamine (Triethylamine), tributylamine (Tributhylamine ), Methanol triamine, ethanol triamine, ethanol triamine, dimethanolamine, diethanolamine, trimethanolamine, triethanolamine and tributanolamine It may be one containing at least one selected from the group consisting of.
- the acid diffusion inhibitor preferably comprises from 0.01 to 5% by weight of the acid diffusion inhibitor based on the total weight of the composition. If the acid diffusion inhibitor is used in an amount less than 0.01% by weight, excessive acid generation may cause a problem with a pattern such as a poor pattern (LWR, LER) on the wall or corner of the pattern. In this case, there is a problem that may occur when pattern formation is impossible.
- a pattern such as a poor pattern (LWR, LER) on the wall or corner of the pattern.
- the negative photoresist composition for I-rays of the present invention may be used in a range of 1,000 to 100,000 kPa depending on the type and amount of solvent used.
- the negative photoresist composition for I-rays is 10 to 90% by weight based on the weight of the solvent. After melting it can be used.
- the solvent may be ethylene glycol monomethyl ether (Ethyleneglycolmonomethylether), ethylene glycol monoethyl ether (Ethyleneglycolmonoethylether), methyl cellosolve acetate (Methylcellosolveacetate), ethyl cellosolve acetate (Ethylcellosolveacetate), diethylene glycol monomethyl ether (Diethyleneglycolmonomethyl ether) Diethyleneglycolmonoethylether, Propyleneglycolmethyletheracetate, Propyleneglycolpropyletheracetate, Diethyleneglycoldimethylether, Ethylactate, Toluene, Toluene Xylene, Methylethylketone, Cyclohexanone, 2-heptanone, 3-heptanone, 3-heptanone, 4-heptanone, etc. Can be used alone or in combination.
- the I-line negative photoresist composition of the present invention provided from the present invention comprises at least one member selected from the group consisting of compounds represented by Formula 1 to Formula 5, thereby being used in a semiconductor manufacturing process.
- the following suitable photoresist composition may be provided to implement a profile having excellent etching resistance even in an I-ray (365 nm) exposure source.
- Example 2 The experiment was carried out in the same manner as in Example 1 except that 32.0 g of naphthalene-1,5-diol was used instead of 1,4-hydroquinone. Finally, a white solid product having a weight average molecular weight of 213 having the same structure as in Chemical Formula 2 (R: acryloyl) was obtained. As a result of gel chromatography analysis, unreacted product was not confirmed.
- Example 2 The experiment was conducted in the same manner as in Example 1 except that 42.0 g of anthracene-9,10-diol was used instead of 1,4-hydroquinone. Finally, a white solid product having a weight average molecular weight of 263 having the same structure as in Chemical Formula 4 (R: acryloyl) was obtained. As a result of gel chromatography analysis, no reactant was identified.
- Example 2 The experiment was performed in the same manner as in Example 1 except that 61.2 g of 1,1,1-tris (4-hydroxyphenyl) ethane was used instead of 1,4-hydroquinone. Finally, a white solid product having a weight average molecular weight of 359 having the same structure as Formula 5 (R: acryloyl) was obtained. As a result of gel chromatography analysis, unreacted product was not identified.
- the prepared composition was filtered using a 0.1 ⁇ m Teflon syringe filter, coated on a silicon wafer using a spin coater, soft baked at 90 ° C. for 90 seconds, and then subjected to an exposure process at a 365 nm light source. After the exposure process, the baking process was performed at 110 ° C. for 90 seconds, followed by a process of developing with 2.38% tetramethylammonium hydroxide to form a pattern.
- the resolution of the wafers obtained in Examples 1 to 8 and Comparative Example 1 was L / S (Line, Space) using a Critical Dimension Scanning Microscope (CD-SEM) capable of observing the critical dimensions of the pattern. ) was confirmed by observing the minimum line width (resolution).
- CD-SEM Critical Dimension Scanning Microscope
- the etching resistance of the wafers obtained in Examples 1 to 8 and Comparative Example 1 was evaluated for etching resistance by using inductively coupled plasma reactive ion etching equipment (ICP-RIE; Inductively Coupled Plasma Reactive Ion Etching). At this time, the etching resistance measurement value was compared with the etching resistance measurement value of Comparative Example 1 by standardizing to 1.
- ICP-RIE inductively coupled plasma reactive ion etching equipment
- Examples 1 to 7 was confirmed that the etching resistance is superior to the conventionally known composition as in Comparative Example 1, the resolution is confirmed to be similar or improved depending on the compound selected could.
- Example 8 although the compound obtained from the substitution reaction example 5 was excessively added and the etching resistance was excellent, it was confirmed that the resolution was reduced.
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Abstract
Description
구 분 | 에칭 내성 | 해상도 (㎛) | |
실시예 | 1 | 0.98 | 0.5 |
2 | 0.95 | 0.4 | |
3 | 0.96 | 0.4 | |
4 | 0.94 | 0.35 | |
5 | 0.97 | 0.4 | |
6 | 0.90 | 0.35 | |
7 | 0.91 | 0.4 | |
8 | 0.78 | 0.8 | |
비교예 | 1 | 1.00 | 0.5 |
Claims (9)
- 하기 화학식 1 내지 화학식 5로 표시되는 화합물로 이루어진 군에서 선택된 1종 이상을 포함하는 것을 특징으로 하는 I-선용 네가티브형 포토레지스트 조성물.[화학식 1][화학식 2][화학식 3][화학식 4][화학식 5]상기 식에서, R은 서로 같거나 다를 수 있으며, 각각 독립적으로 아크릴로일(Acryloyl), 아릴(Allyl), 3-에톡시아크릴로일(3-Etoxyacryloyl), 다이메틸실란아릴(Dimethylsilaneallyl), 메틸아크릴(Methylacryl), 트랜스-3-(벤조일)아크릴(trans-3-(Benzoyl)acryl), 3-(2퓨릴)아크릴(3-(2furyl)acryl) 및 4-(벤질록시)벤질(4-(benzyloxy)benzyl)로 이루어진 군으로부터 선택되는 어느 하나이다.
- 제1항에 있어서, 상기 화학식 1 내지 화학식 5로 표시되는 화합물은 각각 1,4-하이드로퀴논(1,4-Hydroquinone), 나프탈렌-1,5-다이올(Naphthalene-1,5-diol), 비스페놀에이(BisphenolA), 안트라센-9,10-다이올(Anthracene-9,10-diol) 및 1,1,1-트리스(4-하이드록시페닐)에탄(1,1,1-tris(4-hydroxyphenyl)ethane)에 아크릴로일클로라이드를 치환 반응하여 얻은 화합물인 것을 특징으로 하는 I-선용 네가티브형 포토레지스트 조성물.
- 제1항에 있어서, 상기 화학식 1 내지 화학식 5로 표시되는 화합물은 각각 중량평균분자량이 163 내지 500인 것을 특징으로 하는 I-선용 네가티브형 포토레지스트 조성물.
- 제1항에 있어서, 상기 조성물은 조성물 총 중량에 대하여, 중합체 수지 5 내지 50 중량%, 화학식 1 내지 화학식 5로 표시되는 화합물로 이루어진 군에서 선택된 1종 이상의 화합물 0.1 내지 10 중량%, 가교제 1 내지 10 중량%, 광산발생제 0.1 내지 10 중량% 및 산확산방지제 0.01 내지 5 중량% 및 나머지는 용매를 포함하는 것을 특징으로 하는 I-선용 네가티브형 포토레지스트 조성물.
- 제4항에 있어서, 상기 중합체 수지는 수산기가 포함된 페놀 중합체 수지 및 크레졸 중합체 수지로 이루어진 군에서 선택되는 1종 이상인 것을 특징으로 하는 I-선용 네가티브형 포토레지스트 조성물.
- 제5항에 있어서, 상기 페놀 중합체 수지는 4-하이드록시-3-메틸 벤조산(4-Hydroxy-3-methyl benzoic acid), 4-하이드록시-2-메틸 벤조산(4-Hydroxy-2-methyl benzoic acid), 5-하이드록시-2-메틸 벤조산(5-Hydroxy-2-methyl benzoic acid), 3,5-디-터셔리-부틸-4-하이드록시 벤조산(3,5-Di-tert-butyl-4-hydroxy benzoic acid), 4-하이드록시-3,5-디메틸 벤조산(4-Hydroxy-3,5-dimethyl benzoic acid), 4-하이드록시 이소프탈릭산(4-Hydroxy isophthalic acid), 2,4,6-하이드록시 톨루엔(2,4,6-Hydroxy toluene), 2,4,6-트리하이드록시 벤조산 모노하이드레이트(2,4,6-Trihydroxy benzoic acid monohydrate), 2,4,6-트리하이드록시 벤즈알데히드(2,4,6-Trihydroxy benzaldehyde)로 이루어진 군에서 선택되는 1종 이상의 모노머로부터 얻어지는 것이고, 크레졸 중합체 수지는 오르소 크레졸(o-cresol), 파라 크레졸(p-cresol), 메타 크레졸(m-cresol), 에폭시 오르소 크레졸(Epoxy o-cresol), 에폭시 파라 크레졸(Epoxy p-cresol) 및 에폭시 메타 크레졸(Epoxy m-cresol)로 이루어진 군에서 선택되는 1종 이상의 모노머로부터 얻어지는 것을 특징으로 하는 I-선용 네가티브형 포토레지스트 조성물.
- 제4항에 있어서, 상기 가교제는 트리스(2,3-에폭시프로필)이소시아누레이트(Tris(2,3-epoxypropyl) isocyanurate), 트리메틸올메탄트리글리시딜에테르(Trimethylolmethanetriglycidylether), 트리메틸올프로판트리글리시딜에테르(Trimethylolpropanetriglycidylether), 헥사메틸올멜라민(Hexamethylolmelamine), 트리에틸올에탄트리글리시딜에테르(Trimethylolethanetriglycidylether), 헥사메톡시메틸멜라민(Hexamethoxymethylmelamine), 헥사메톡시에틸멜라민(Hexamethoxyethylmelamine), 테트라메틸올2,4-디아미노-1,3,5-트리아진(Tetramethylol 2,4-diamino-1,3,5-triazine), 테트라메톡시메틸-2,4-디아미노-1,3,5-트리아진(Tetramethoxymethyl-2,4-diamino-1,3,5-triazine), 테트라메틸올글리코우릴(Tetramethylolglycoluril), 테트라메톡시메틸글리코우릴(Tetramethoxymethylglycoluril), 테트라메톡시에틸글리코우릴(Tetramethoxyethylglycoluril), 테트라메틸올우레아(Tetramethylolurea), 테트라메톡시메틸우레아(Tetramethoxymethylurea), 테트라메톡시에틸우레아(Tetramethoxyethylurea) 및 테트라메톡시에틸2,4-디아미노-1,3,5-트리아진(Tetramethoxyethyl-2,4-diamino-1,3,5-troazine)으로 이루어진 군으로부터 선택되는 1종 이상인 것을 포함하는 것을 특징으로 하는 I-선용 네가티브형 포토레지스트 조성물.
- 제4항에 있어서, 상기 광산발생제는 트리스(트리클로로메틸)트리아진(Tris(trichloromethyl)triazine), 1,1-비스(p-클로로페닐)-2,2,2-트리클로로에탄(1,1-Bis(p-chlorophenyl)-2,2,2,-trichloroethane), 트리스(메탄설포닐)벤젠(Tris(methanesulfonyl)benzene), 1,1-비스(클로로페닐)-2,2,2-트리클로로에탄올(1,1-Bis(chlorophenyl)-2,2,2,-trichloroethanol, 2,4,6-트리스(트리브로모메틸)-s-트리아진(2,4,6-tris(tribromomethyl)-s-triazine), 2-메틸-4,6-비스(트리브로모메틸)-s-트리아진(2-methyl-4,6-bis(tribromomethyl)-s-triazine), 2-페닐-4,6-비스(트리브로모메틸)-s-트리아진(2-phenyl-4,6-bis(tribromomethyl)-s-triazine), 2-(4-메톡시-페닐)-4,6-비스(트리클로로메틸)-1,3,5-트리아진(2-(4-methoxy-phenyl)-4,6-bis(trichloromethyl)-1,3,5-triazine), 2,4,6-트리스(클로로메틸)1,3,5-트리아진(2,4,6,-tris(chloromethyl)1,3,5-triazine), 트리페닐설포늄트리플레이트(Triphenylsulfoniumtriflate), 및 트리브로모페닐설폰(Tribromopheylsulfone)으로 이루어진 군으로부터 선택되는 1종 이상인 것을 포함하는 것을 특징으로 하는 I-선용 네가티브형 포토레지스트 조성물.
- 제4항에 있어서, 상기 산확산방지제는 메틸트리아민(Methyltriamine), 에틸트리아민(ethyltriamine), 디메틸아민(Dimethylamine), 디에틸아민(Diethylamine), 트리메틸아민(Trimethylamine), 트리에틸아민(Triethylamine), 트리부틸아민(Tributhylamine), 메탄올트리아민(Methanoltriamine), 에탄올트리아민(Ethanoltriamine), 디메탄올아민(Dimethanolamine), 디에탄올아민(Diethanolamine), 트리메탄올아민(Trimethanolamine), 트리에탄올아민(Triethanolamine) 및 트리부탄올아민(Tributhanolamine)으로 이루어진 군으로부터 선택되는 1종 이상인 것을 포함하는 것을 특징으로 하는 I-선용 네가티브형 포토레지스트 조성물.
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KR101655947B1 (ko) * | 2016-03-22 | 2016-09-09 | 영창케미칼 주식회사 | 고해상도 및 고아스펙트비를 갖는 KrF 레이저용 네가티브형 포토레지스트 조성물 |
KR101877029B1 (ko) * | 2016-05-13 | 2018-07-11 | 영창케미칼 주식회사 | 화학증폭형 네가티브형 포토레지스트 조성물 |
KR102029127B1 (ko) * | 2019-02-08 | 2019-10-07 | 영창케미칼 주식회사 | 반도체 제조 공정에 있어서 실리콘 또는 실리콘 화합물 패턴을 형성하기 위한 신규 방법 |
KR102256837B1 (ko) | 2020-09-24 | 2021-05-28 | 영창케미칼 주식회사 | Center - Edge간 단차의 개선 및 LER 개선용 I-선용 네가티브형 포토레지스트 조성물공정 마진 개선용 I-선용 네가티브형 포토레지스트 조성물 |
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US20180246404A1 (en) | 2018-08-30 |
JP2018536885A (ja) | 2018-12-13 |
CN107924124B (zh) | 2020-12-15 |
US10539871B2 (en) | 2020-01-21 |
CN107924124A (zh) | 2018-04-17 |
KR101598826B1 (ko) | 2016-03-03 |
JP6602461B2 (ja) | 2019-11-06 |
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