WO2017010473A1 - Composition détergente pour surfaces dures - Google Patents

Composition détergente pour surfaces dures Download PDF

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Publication number
WO2017010473A1
WO2017010473A1 PCT/JP2016/070514 JP2016070514W WO2017010473A1 WO 2017010473 A1 WO2017010473 A1 WO 2017010473A1 JP 2016070514 W JP2016070514 W JP 2016070514W WO 2017010473 A1 WO2017010473 A1 WO 2017010473A1
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WIPO (PCT)
Prior art keywords
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hard surface
cleaning composition
mass
surface cleaning
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PCT/JP2016/070514
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English (en)
Japanese (ja)
Inventor
吉川将士
土屋聖人
井上卓巳
Original Assignee
花王株式会社
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Priority to SG11201710761WA priority Critical patent/SG11201710761WA/en
Publication of WO2017010473A1 publication Critical patent/WO2017010473A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/82—Compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08—Liquid soap, e.g. for dispensers; capsuled
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents

Definitions

  • the present invention relates to a hard surface cleaning composition, a hard surface cleaning article, a floor cleaning method, and a method for reducing floor wipes of ceramic tiles.
  • the living environment facilities that surround us have various hard surfaces made of ceramics, plastics, metals, etc., and these hard surfaces are exposed to an environment where various dirt adheres in daily life.
  • the hard surface used as the floor is located at the bottom of the living environment equipment and is also the surface that people come into contact with on a daily basis. It has a difficult property.
  • Japanese Patent Application Laid-Open No. 2000-160199 discloses a hard surface cleaning composition that can be cleaned with as little effort as possible when removing dirt on the hard surface.
  • the present invention provides a hard surface cleaning composition having a good detergency and excellent finishing performance (hereinafter also simply referred to as finishing) that does not leave wiping lines after cleaning, and the cleaning composition.
  • a method for cleaning a floor is provided.
  • the present invention provides (a) ethanol [hereinafter referred to as component (a)] in an amount of 5% by mass to 23% by mass, (b) a polyether-modified silicone [hereinafter referred to as component (b)], and (c) a surfactant. [Hereinafter referred to as component (c)] and a hard surface cleaning composition containing water.
  • the present invention also relates to a hard surface cleaning article obtained by filling a spray container with the hard surface cleaning composition of the present invention.
  • the present invention also relates to a floor cleaning method in which the hard surface cleaning composition of the present invention is adhered to a floor and then the composition is wiped off.
  • the present invention also relates to a method for reducing the floor-wiping lines of a ceramic tile using the hard surface cleaning composition of the present invention.
  • ADVANTAGE OF THE INVENTION According to this invention, it has the favorable detergency and is excellent in the finishing property which does not leave a wiping line after washing
  • the present inventors use a specific amount of polyether-modified silicone and ethanol in addition to a surfactant, so that in the cleaning of hard surfaces, the wiping lines can be removed while satisfying the cleaning power.
  • a surfactant we have found that it is possible to achieve an excellent finish with no aesthetics.
  • the polyether-modified silicone is uniformly dissolved or dispersed in the composition containing ethanol, the wettability of the polyether-modified silicone and the quick drying property of the composition are improved. As a result, it is estimated that good detergency on the hard surface can be obtained and no wiping lines remain after washing.
  • the component (a) of the present invention is ethanol.
  • the component (b) of the present invention is a polyether-modified silicone.
  • a compound represented by the following general formula (b1) is preferable.
  • R 1 may be the same or different and each represents an alkyl group having 1 to 4 carbon atoms.
  • p represents a number from 0 to 1000
  • q represents a number from 1 to 1000.
  • X 1 and X 2 may be the same or different and each represents a hydroxy group, an alkyl group having 1 to 4 carbon atoms, or an alkoxy group.
  • R 2 represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or an acyl group having 2 to 4 carbon atoms.
  • a represents a number from 1 to 4
  • b represents a number from 1 to 100
  • c represents a number from 0 to 50.
  • R 1 is preferably a methyl group from the viewpoint of finish.
  • X 1 and X 2 are preferably an alkyl group having 1 to 3 carbon atoms, more preferably a methyl group, from the viewpoint of finish.
  • R 2 is preferably a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or an acyl group having 2 to 3 carbon atoms, more preferably a hydrogen atom, from the viewpoint of finish.
  • p is a number of 0 or more, preferably 1 or more, and 1000 or less, preferably 100 or less, more preferably 10 or less from the viewpoint of finish.
  • q is a number of 1 or more and 1000 or less, preferably 100 or less, more preferably 20 or less from the viewpoint of finish.
  • a is preferably a number of 1 or more and 3 or less from the viewpoint of finish.
  • b is 1 or more, preferably 2 or more, more preferably 3 or more, and 100 or less, preferably 50 or less, more preferably 30 or less, and still more preferably, from the viewpoint of finish.
  • the number is 15 or less, more preferably 8 or less.
  • c is a number of 0 or more and 50 or less, preferably 30 or less, more preferably 10 or less, still more preferably 3 or less, and 0 from the viewpoint of finish. Also good.
  • the HLB value of the compound represented by (b1) is preferably 4 or more, more preferably 6 or more, still more preferably 8 or more, and still more preferably 10.5 or more, from the viewpoint of detergency and finish. From the same viewpoint, it is preferably 20 or less, more preferably 18 or less, still more preferably 16 or less, still more preferably 15 or less, and still more preferably 14.5 or less.
  • HLB value molecular weight of polyoxyethylene in the compound represented by (b1) ⁇ 20 / (b1) molecular weight of the compound represented by a, b, c, p, q, R 1 , R 2 , X 1 and X 2 can be determined by NMR or the like.
  • the kinematic viscosity (mm 2 / s) of the component (b) is preferably 1 or more, more preferably 5 or more, still more preferably 10 or more from the viewpoint of detergency and finish, and from the same viewpoint, Preferably it is 1500 or less, More preferably, it is 1000 or less, More preferably, it is 500 or less, More preferably, it is 100 or less.
  • the kinematic viscosity of the component (b) is a value measured with an Ubbelohde viscometer (manufactured by Shibata Kagaku Co., Ltd.) at 25 ° C.
  • component (c) of the present invention is a surfactant.
  • Component (c) is used from the viewpoints of detergency, finish, and blending stability. Note that the polyether-modified silicone of component (b) is excluded from component (c).
  • the component (c) includes one or more surfactants selected from nonionic surfactants, anionic surfactants, amphoteric surfactants, and cationic surfactants, and preferably nonionic surfactants. 1 or more types of surfactant chosen from an agent, anionic surfactant, and an amphoteric surfactant are mentioned.
  • the hard surface cleaning composition of the present invention is preferably selected from a nonionic surfactant, an anionic surfactant, and an amphoteric surfactant as component (c) from the viewpoints of finish and cleaning properties. It contains at least one kind of surfactant, more preferably contains at least one selected from nonionic surfactants, and more preferably contains a glycoside type nonionic surfactant.
  • Nonionic surfactants include (1) polyoxyalkylene monoalkyl or alkenyl ethers, (2) glycoside nonionic surfactants (alkyl glycosides, etc.), (3) fatty acid alkanolamides, (4) sorbitan nonionics Examples thereof include one or more nonionic surfactants selected from surfactants, (5) alkyl monoglyceryl ethers, (6) fatty acid glycerin monoesters, (7) sucrose fatty acid esters, and (8) amine oxides.
  • the nonionic surfactant is selected from (1) polyoxyalkylene monoalkyl or alkenyl ether, (2) glycoside type nonionic surfactant (alkyl glycoside, etc.), and (8) amine oxide from the viewpoint of finish.
  • nonionic surfactants are preferred, and one or more nonionic surfactants selected from (1) polyoxyalkylene monoalkyl or alkenyl ethers and (2) glycoside type nonionic surfactants (alkyl glycosides, etc.) Surfactants are more preferred, and (2) glycoside nonionic surfactants (alkyl glycosides and the like) are even more preferred.
  • the above nonionic surfactant will be described more specifically.
  • the number of carbon atoms of the alkyl group or alkenyl group is preferably 6 or more, more preferably 8 from the viewpoints of detergency and finish. More preferably, it is 10 or more, more preferably 12 or more, and from the same viewpoint, it is preferably 22 or less, more preferably 18 or less, still more preferably 16 or less, and still more preferably 14 or less.
  • the average number of moles of alkylene oxide added is preferably more than 0, more preferably 1 or more, still more preferably 3 or more, and still more preferably, from the viewpoints of detergency and finish. From the same viewpoint, it is preferably 50 or less, more preferably 30 or less, still more preferably 20 or less, and still more preferably 15 or less.
  • the alkylene oxide is preferably at least one selected from ethylene oxide, propylene oxide, and butylene oxide, more preferably at least one selected from ethylene oxide and propylene oxide, from the viewpoints of detergency and finish. .
  • nonionic surfactant (1) include nonionic surfactants represented by the following general formula (c1).
  • R 11 represents a hydrocarbon group having 6 to 22 carbon atoms.
  • l and m represent the average number of moles added, l represents a number from 0 to 30, m represents a number from 0 to 30, and l and m are not 0 at the same time.
  • “/” Indicates that the ethyleneoxy group (C 2 H 4 O) and the propyleneoxy group (C 3 H 6 O) may be added to either random or block regardless of the order. ]
  • the carbon number of R 11 in the general formula (c1) is preferably 8 or more, more preferably 10 or more, still more preferably 12 or more, from the viewpoints of detergency and finish, and from the same viewpoint. , Preferably 18 or less, more preferably 17 or less, still more preferably 16 or less, and still more preferably 14 or less.
  • R 11 is preferably an alkyl group or an alkenyl group, and more preferably an alkyl group, from the viewpoints of detergency and finish.
  • alkyl group examples include various octyl groups (including 2-ethylhexyl group), various nonyl groups, various decyl groups, various undecyl groups, various dodecyl groups (lauryl group), various tridecyl groups, various tetradecyl groups, Examples include various pentadecyl groups, various hexadecyl groups, various heptadecyl groups, and various octadecyl groups.
  • alkenyl group examples include various octanyl groups, various nonanyl groups, various decanyl groups, various undecanyl groups, various dodecanyl groups, various tridecanyl groups, various tetradecanyl groups, various pentadecanyl groups, various hexadecanyl groups, various heptadecanyl groups, various octadecanyl groups (for example, Oleyl group, linole group).
  • the “various” means various isomers including n-, sec-, tert-, and iso-.
  • L in the general formula (c1) is preferably more than 0, more preferably 1 or more, still more preferably 3 or more, still more preferably 5 or more, and from the same viewpoint, from the viewpoints of detergency and finish. , Preferably 50 or less, more preferably 30 or less, still more preferably 20 or less, still more preferably 15 or less.
  • M in the general formula (c1) is preferably 0 or more, and preferably 10 or less, more preferably 5 or less, from the viewpoints of detergency and finish.
  • the nonionic surfactant represented by the polyoxyalkylene monoalkyl or alkenyl ether and the general formula (c1) preferably has an HLB value of 5 or more, more preferably from the viewpoints of detergency, finish and blending stability. Is 7 or more, more preferably 10 or more, and from the same viewpoint, it is preferably 20 or less, more preferably 18 or less, and still more preferably 16 or less.
  • the nonionic surfactant of (2) is preferably a nonionic surfactant represented by the following general formula (c2).
  • R 21 (OR 22 ) x G y (c2) [Wherein R 21 represents a linear or branched alkyl group having 6 to 18 carbon atoms, an alkenyl group, or an alkylphenyl group, preferably an alkyl group, and R 22 represents an alkylene group having 2 to 4 carbon atoms.
  • G represents a residue derived from a reducing sugar having 5 or 6 carbon atoms.
  • x represents an average added mole number, and is a number of 0 or more and 5 or less.
  • y represents a number whose average value is 1 or more and 5 or less. ]
  • R 21 is preferably 8 or more carbon atoms, more preferably 10 or more carbon atoms, and more preferably 16 or less carbon atoms, more preferably from the viewpoints of detergency, blending stability and finish. Is a linear or branched alkyl group of 14 or less.
  • x is preferably 0 or more and 2 or less, more preferably 0, from the viewpoints of detergency, blending stability, and finish.
  • y is preferably 1.1 or more, and preferably 1.5 or less, more preferably 1.4 or less, from the viewpoints of detergency, blending stability and finish.
  • y is a value measured by a proton NMR method.
  • G includes a residue derived from one or more monosaccharides selected from glucose and fructose from the viewpoint of availability and cost.
  • Examples of G include a residue derived from one or more polysaccharides selected from maltose and sucrose.
  • G is preferably a residue derived from one or more monosaccharides selected from glucose and fructose, and more preferably a residue derived from glucose.
  • the nonionic surfactant of (3) is preferably a nonionic surfactant represented by the following general formula (c3).
  • R 31 represents an alkyl group or an alkenyl group having 8 to 22 carbon atoms, preferably 10 to 18 carbon atoms
  • R 32 and R 33 may be the same or different and each represents a hydrogen atom or a methyl group.
  • S represents a number from 1 to 3
  • t represents a number from 0 to 3.
  • Sorbitan-based nonionic surfactant The nonionic surfactant of (4) is represented by the following general formula (c4-I) and the following general formula (c4-II): One or more nonionic surfactants selected from the following nonionic surfactants.
  • R 41 represents an alkylene group having 2 to 4 carbon atoms
  • R 42 independently represents an alkyl group or alkenyl group having 1 to 14 carbon atoms
  • the alkyl group and alkenyl group are Any of a chain, a branched chain, and a ring may be used
  • f, g, and h represent the average number of moles added, and the sum of f, g, and h is a number of 3 to 50.
  • R 41 is an alkylene group having 2 to 4 carbon atoms, preferably an ethylene group or a propylene group, and more preferably an ethylene group.
  • f, g and h are each independently preferably 0 or more from the viewpoints of detergency, blending stability and finish. , Preferably 50 or less, more preferably 30 or less.
  • the total of f, g and h is preferably 3 or more, more preferably 4 or more, and preferably 50 or less, more preferably 30 or less, from the viewpoints of detergency, blending stability and finish. is there.
  • Alkyl monoglyceryl ether The nonionic surfactant of (5) is preferably an alkyl monoglyceryl having a linear or branched alkyl group having 6 to 22 carbon atoms, more preferably 10 to 14 carbon atoms. Ether.
  • Fatty acid glycerin monoester examples include fatty acid glycerin monoesters whose fatty acid part is a fatty acid having 8 to 22 carbon atoms, preferably 10 to 14 carbon atoms. Preferably, it is a fatty acid glycerin monoester whose fatty acid moiety is a fatty acid having 8 to 22 carbon atoms, preferably 10 to 14 carbon atoms, having a linear or branched alkyl group.
  • the nonionic surfactant of (7) includes a sucrose fatty acid ester whose fatty acid part is a fatty acid having 8 to 18 carbon atoms, preferably 10 to 14 carbon atoms.
  • it is a sucrose fatty acid ester whose fatty acid moiety is a fatty acid having 8 to 18 carbon atoms, more preferably 10 to 14 carbon atoms, having a linear or branched alkyl group.
  • Nonionic surfactant of (8) examples include alkyl or alkenylamine oxide having a linear or branched alkyl group or alkenyl group having 6 to 24 carbon atoms.
  • Preferable amine oxides include amine oxides represented by the following general formula (c8).
  • R 81 represents a hydrocarbon group having 6 to 24 carbon atoms, preferably a linear or branched alkyl group or alkenyl group having 6 to 24 carbon atoms
  • R 82 and R 83 are the same or different.
  • D represents a group selected from —COO—, —CONH—, and —O—
  • E represents 1 to 5 carbon atoms.
  • anionic surfactant examples include an anionic surfactant having a polyoxyalkylene group, such as polyoxyalkylene alkyl ether sulfate, polyoxyalkylene alkenyl ether sulfate, polyoxyalkylene alkyl aryl ether sulfate, polyoxyalkylene alkenyl.
  • alkylene group is preferably an ethylene group or a propylene group, more preferably an ethylene group, and the alkyl group or alkenyl group preferably has 12 to 14 carbon atoms.
  • anionic surfactant examples include alkyl sulfates.
  • the alkyl group of the alkyl sulfate preferably has 10 to 14 carbon atoms.
  • the salt of the anionic surfactant include alkali metal salts such as sodium salt and potassium salt, ammonium salt and organic ammonium salt, and alkali metal salts are preferable.
  • Amphoteric surfactants include alkylamidopropyl-N, N-dimethylacetic acid betaine, alkylamidopropyl-N, N-dimethyl-2-hydroxypropylsulfobetaine, and alkylamidopropyl-N, N-dimethyl-propylsulfobetaine
  • alkylamidopropyl-N, N-dimethyl-propylsulfobetaine One or more kinds selected from, for example, lauric acid amidopropyl-N, N-dimethylacetic acid betaine, hydroxylauryl sulfobetaine, and lauric acid amidopropyl-N, N-dimethyl-2-hydroxypropyl betaine
  • lauric acid amidopropyl-N, N-dimethylacetic acid betaine hydroxylauryl sulfobetaine
  • lauric acid amidopropyl-N, N-dimethyl-2-hydroxypropyl betaine One or more selected,
  • Examples of the cationic surfactant include a monoalkyltrimethylammonium salt having one alkyl group having 8 to 16 carbon atoms, a dialkyldimethylammonium salt having two alkyl groups having 8 to 14 carbon atoms, and 8 or more carbon atoms. 14 or more selected from alkyldimethylbenzylammonium salts having one lower alkyl group, preferably alkyldimethylbenzylammonium salts having one alkyl group having 8 to 14 carbon atoms, more preferably An alkyldimethylbenzylammonium salt having one alkyl group having 12 carbon atoms.
  • the hard surface cleaning composition of the present invention is a liquid cleaning composition containing water.
  • the components (a) to (c) may be dissolved, dispersed or emulsified in water, but are preferably dissolved from the viewpoint of detergency and finish.
  • As the water ion-exchanged water or distilled water from which metal components have been removed, hypochlorous acid-sterilized water in which hypochlorous acid is dissolved in an amount of about 0.5 ppm to 10 ppm can be used. Water is the balance of the composition and is contained in an amount that makes the whole 100% by mass.
  • the component (a) is 5% by mass or more, preferably 6% by mass or more, more preferably 8% by mass or more, and further preferably 10% by mass from the viewpoint of finish. From the above, from the same viewpoint, the content is 23% by mass or less, preferably 20% by mass or less, more preferably 18% by mass or less, and still more preferably 15% by mass or less.
  • the component (b) is preferably 0.0008% by mass or more, more preferably 0.001% by mass or more, and further preferably 0.003% by mass from the viewpoint of finish. % Or more, and from the viewpoint of detergency and finish, it is preferably 3% by mass or less, more preferably 0.8% by mass or less, still more preferably 0.5% by mass or less, and still more preferably 0.1% by mass. Hereinafter, it is more preferably 0.08% by mass or less, still more preferably 0.05% by mass or less, and still more preferably 0.03% by mass or less.
  • the component (c) is preferably 0.005% by mass or more, more preferably 0.008% by mass or more, and still more preferably 0, from the viewpoints of detergency and finish. 0.01 mass% or more, more preferably 0.05 mass% or more, and from the viewpoint of finish, it is preferably 5 mass% or less, more preferably 3 mass% or less, still more preferably 1 mass% or less, and even more. Preferably it is 0.8 mass% or less, More preferably, it contains 0.5 mass% or less.
  • the mass ratio (a) / (b) of the component (a) and the component (b) is preferably 20 or more, more preferably 50 or more, from the viewpoint of finish. More preferably, it is 100 or more, more preferably 300 or more, still more preferably 500 or more, still more preferably 800 or more, and from the same viewpoint, it is preferably 20000 or less, more preferably 15000 or less, still more preferably It is 10,000 or less, more preferably 6000 or less.
  • This mass ratio is a mass ratio of the content of the component (a) to the content of the component (b).
  • the mass ratio (b) / (c) of the component (b) to the component (c) is preferably 0.001 or more, more preferably 0 from the viewpoint of finish. 0.003 or more, more preferably 0.005 or more, still more preferably 0.01 or more, still more preferably 0.03 or more, and preferably 10 or less, more preferably from the viewpoint of detergency and finish. Is 5 or less, more preferably 1 or less, and still more preferably 0.5 or less.
  • the mass ratio (b) / (nonionic surfactant) of component (b) to nonionic surfactant is preferably 0 from the viewpoint of finish.
  • 0.001 or more Preferably 10 or less, more preferably 5 or less, still more preferably 1 or less, still more preferably 0.5 or less.
  • the mass ratio (b) / ((b) component and glycoside type nonionic surfactant) is preferably 0.001 or more, more preferably 0.003 or more, still more preferably 0.005 or more, still more preferably 0.01 or more, and still more from the viewpoint of finish.
  • it is 0.03 or more, and from the viewpoint of detergency and finish, it is preferably 10 or less, more preferably 5 or less, still more preferably 1 or less, and even more preferably 0.5 or less.
  • the hard surface cleaning composition of the present invention is preferably 75% by mass or more, more preferably 80% by mass or more, and still more preferably 82% by mass or more, from the viewpoints of solubility, finish, and detergency. More preferably, it is 84% by mass or more, and preferably 94.8% by mass or less, more preferably 94% by mass or less, still more preferably 92% by mass or less, and still more preferably 90% by mass or less.
  • the hard surface cleaning composition of the present invention contains, as other components, a dispersant, a chelating agent, a thickener, a fragrance, a dye, a solvent, an antiseptic, etc., which are generally blended in hard surface cleaning agents. I can do it.
  • the hard surface cleaning composition of the present invention has a stock solution pH of 20 ° C., and is preferably 5 or more, more preferably 6 or more, and still more preferably 6.5 from the viewpoints of finish and metal product damage. From the viewpoint of minimizing the influence on the wax existing on the hard surface as described above, it is preferably 8 or less, more preferably 7.5 or less.
  • Such adjustments to pH include inorganic acids such as sulfuric acid, hydrochloric acid and phosphoric acid, organic acids such as malic acid, citric acid and acetic acid, sodium hydroxide, potassium hydroxide, magnesium hydroxide, sodium carbonate and potassium carbonate.
  • An organic alkali agent such as an inorganic alkali agent, monoethanolamine, 2-amino-2-methyl-1-propanol is used.
  • the cleaning composition has a buffering capacity, and it is preferable to contain an inorganic alkaline agent.
  • the content of the inorganic alkaline agent is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, and preferably 0.02% by mass or less, more preferably in the cleaning composition of the present invention. 0.01% by mass or less.
  • the hard surface cleaning composition of the present invention is suitable for wiping and cleaning. That is, the hard surface cleaning composition of the present invention is suitably used for cleaning hard surfaces (such as various articles, floors, walls, ceilings, etc.) such as living rooms, rooms, kitchens, bathrooms, toilets, and the like.
  • the composition of the present invention has no foaming, no scum, no traces, few wiping lines, excellent finish, and quick drying. Therefore, it is necessary to wipe with water (wipe twice). Absent. From these effects, the hard surface is preferably a floor. Examples of the hard surface include a hard surface composed of one or more materials selected from ceramics, plastics, wood, stones, and metals.
  • the present invention there is provided a method for cleaning a hard surface in which the hard surface cleaning composition of the present invention is applied to a hard surface and then wiped and cleaned. Furthermore, the present invention provides a floor cleaning method in which the hard surface cleaning composition of the present invention is adhered to the floor and then the composition is wiped off.
  • the floor include a floor made of at least one material selected from ceramics, plastic, wood, stone, and metal.
  • the floor is preferably a ceramic tile floor from the viewpoint that the effect of reducing the wiping lines can be realized more remarkably.
  • INDUSTRIAL APPLICABILITY According to the present invention, there is provided a method for reducing a floor wipe of a ceramic tile using the hard surface cleaning composition of the present invention.
  • This method is a method for reducing wiping lines generated by wiping off the cleaning composition after cleaning the floor of the ceramic tile using the cleaning composition, and the cleaning composition of the present invention is used as the cleaning composition.
  • This is a method for reducing the wiping lines after cleaning of a ceramic tile floor using a hard surface cleaning composition.
  • it is preferable to remove the composition applied to the hard surface from the hard surface using a cloth, a cloth, a nonwoven fabric, a mop, paper, or the like.
  • the hard surface cleaning composition of the present invention can be directly applied to a hard surface by spraying or the like without being diluted.
  • the hard surface cleaning composition of the present invention is preferably 10 times or more, more preferably 50 times or more, and preferably 200 times or less, more preferably 150 times or less diluted with water. It can also be applied to. And after applying this washing
  • the hard surface cleaning composition of the present invention per 1 m 2 of floor area.
  • To attach it is preferred to spray the composition to adhere to the floor. Thereafter, the composition adhering to the floor is wiped off with a mop, cloth or paper. After allowing the composition to adhere to the floor, it is preferably left for 60 seconds or less, more preferably 30 seconds or less, and then the composition is wiped off. It is preferable to wipe off the composition in a wet state.
  • the hard surface cleaning composition of the present invention or the cleaning liquid diluted as described above can be impregnated into a substrate and used as a cleaning article.
  • the cleaning article in which the substrate is impregnated with the hard surface cleaning composition or cleaning liquid of the present invention is preferable from the viewpoint of workability of the cleaning operation.
  • the substrate used in the cleaning article impregnated with the hard surface cleaning composition or cleaning liquid is flexible and can be impregnated with the hard surface cleaning composition or cleaning liquid.
  • a material having a sufficient strength and free from the generation of waste or the like is used.
  • Such a substrate examples include fiber structures composed of fibrous materials, such as various papers, nonwoven fabrics, woven fabrics, and knitted fabrics.
  • fibrous materials constituting these fiber structures include cellulosic fibers, modified cellulosic fibers, synthetic fibers, and mixtures of two or more thereof.
  • a porous structure for example, a sponge-like structure obtained by dispersing bubbles in a resin can be used as the substrate.
  • the cleaning method for wiping the hard surface using the cleaning material impregnated with the cleaning composition for hard surface or the cleaning liquid of the present invention is preferable for light cleaning of the hard surface from the viewpoint of workability of the cleaning work.
  • the cleaning article impregnated with the hard surface cleaning composition or cleaning liquid is obtained by impregnating the substrate with the hard surface cleaning composition or cleaning liquid in advance, or the dried substrate with the hard surface cleaning composition or Any of those obtained by impregnating the cleaning liquid just before use by spraying or the like may be used.
  • the surface to be cleaned may be cleaned using a sprayed cleaning article.
  • the cleaning article impregnated with the hard surface cleaning composition or cleaning liquid may be used by being mounted on a mop-shaped cleaning tool, or may be directly held and used for wiping. It is preferable to use a mop for washing the floor.
  • the impregnation ratio of the hard surface cleaning composition or cleaning liquid is determined from the standpoint of cleaning properties by the mass of the substrate [that is, the substrate in an unimpregnated state (dry state) Per mass basis] is preferably 100% by mass or more, more preferably 150% by mass or more, and preferably 1000% by mass or less, more preferably 500% by mass or less, More preferably, it is 400 mass% or less. If the impregnation rate is 100% by mass or more, sufficient cleaning performance against stains and dirt is obtained.
  • the amount of the cleaning composition discharged onto the surface to be cleaned is appropriate, and no dirt or dirt remains on the surface to be cleaned, and the cleaning surface is made of various materials such as wood-based materials. Can be used without any effect.
  • the basis weight before impregnation with the cleaning composition for hard surface or the cleaning liquid is the holding capacity of the cleaning agent necessary for cleaning a certain area and the operation of the sheet. From the viewpoint of property and cost, it is preferably 40 g / m 2 or more, more preferably 50 g / m 2 or more, and preferably 200 g / m 2 or less, and 150 g / m 2 or less. More preferably.
  • the hard surface cleaning composition or cleaning liquid of the present invention is separately used while spraying on the object to be cleaned or the cleaning article. Also good. A wider area can be cleaned by the method of use.
  • the present invention relates to a hard surface cleaning article obtained by filling a spray container with the hard surface cleaning composition of the present invention.
  • the spray container include a spray container equipped with a trigger sprayer (referred to as a trigger spray container).
  • the trigger type spray container include a container body containing the hard surface cleaning composition of the present invention, and a trigger type liquid ejector attached to the mouth of the container body.
  • a trigger sprayer that ejects the composition is attached to the mouth of the container body, and a vertical pipe and a horizontal pipe are formed inside the trigger sprayer, and the vertical pipe and the vertical pipe are formed in the vertical pipe.
  • spray container (I) in which a valve for blocking communication with the horizontal pipe is provided.
  • volume is preferably 0.1 ⁇ 0.28 cm 3 of the horizontal pipe in the spray container (I), the volume under the valve of the vertical pipe is preferably 0.06 ⁇ 0.19 cm 3.
  • the spray container (I) is provided with a cylinder at a lower position of the horizontal pipe, and a spin element is mounted at the tip of the horizontal pipe, and a nozzle having a nozzle hole is fitted at the tip of the spin element. It is fixed.
  • the spray container (I) pulls the trigger, discharges the air in the cylinder to the outside, and returns the trigger through the vertical pipe immersed in the hard surface cleaning composition of the present invention when the trigger is returned.
  • the liquid in the cylinder is pushed out and led to the vertical pipe, and the liquid flow is spun through the horizontal pipe and the spin element.
  • the trigger type spray container for example, a trigger spray container of “Bath Magiclin Foaming Spray” (Kao Co., Ltd.) washed and dried can be used.
  • the hard surface cleaning composition of the present invention is sprayed and adhered to the floor. It is preferable to use the hard surface cleaning article of the present invention for spraying.
  • the present invention provides a hard surface cleaning composition
  • a hard surface cleaning composition comprising (a) 5% by mass to 23% by mass of ethanol, (b) a polyether-modified silicone, (c) a surfactant, and water.
  • a cleaning composition for hard surfaces of the composition which has the composition and aspect described by the cleaning composition for hard surfaces of this invention. All the matters described in the hard surface cleaning composition of the present invention can be applied to the composition used for this purpose.
  • the present invention further discloses the following hard surface cleaning composition, hard surface cleaning article, and floor cleaning method.
  • Ethanol (hereinafter referred to as (a) component] is 5% by mass or more and 23% by mass or less, (b) polyether-modified silicone [hereinafter referred to as (b) component], (c) surfactant [hereinafter, ( c) component] and a hard surface cleaning composition containing water.
  • R 1 may be the same or different and each represents an alkyl group having 1 to 4 carbon atoms.
  • p represents a number from 0 to 1000
  • q represents a number from 1 to 1000.
  • X 1 and X 2 may be the same or different and each represents a hydroxy group, an alkyl group having 1 to 4 carbon atoms, or an alkoxy group.
  • R 2 represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or an acyl group having 2 to 4 carbon atoms.
  • a represents a number from 1 to 4
  • b represents a number from 1 to 100
  • c represents a number from 0 to 50.
  • the HLB value of the compound represented by (b1) is preferably 4 or more, more preferably 6 or more, still more preferably 8 or more, still more preferably 10.5 or more, and preferably 20 or less, more preferably 18
  • the hard surface cleaning composition according to ⁇ 2> further preferably 16 or less, more preferably 15 or less, and still more preferably 14.5 or less.
  • the kinematic viscosity (mm 2 / s) of the component (b) is preferably 1 or more, more preferably 5 or more, still more preferably 10 or more, and preferably 1500 or less, more preferably 1000 or less, still more preferably 500 or less.
  • the component is one or more surfactants selected from nonionic surfactants, anionic surfactants, amphoteric surfactants, and cationic surfactants, preferably nonionic surfactants,
  • the hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 4> above, which is one or more surfactants selected from an anionic surfactant and an amphoteric surfactant.
  • ⁇ 6> (C) As a component, it contains 1 or more types of surfactant chosen from a nonionic surfactant, an anionic surfactant, and an amphoteric surfactant, Preferably it is 1 or more types chosen from a nonionic surfactant.
  • Nonionic surfactant is (1) polyoxyalkylene monoalkyl or alkenyl ether, (2) glycoside type nonionic surfactant, (3) fatty acid alkanolamide, (4) sorbitan nonionic surfactant, (5 Preferably, it is one or more nonionic surfactants selected from: (1) polyoxyalkylene, (6) fatty acid glyceryl monoester, (7) sucrose fatty acid ester, and (8) amine oxide.
  • the carbon number of the alkyl group or alkenyl group of the polyoxyalkylene monoalkyl or alkenyl ether is 6 or more, preferably 8 or more, more preferably 10 or more, still more preferably 12 or more, and 22 or less, preferably 18 or less, more Preferably, it is 16 or less, More preferably, it is 14 or less,
  • the average addition mole number of the alkylene oxide of the polyoxyalkylene monoalkyl or alkenyl ether is more than 0, preferably 1 or more, more preferably 3 or more, more preferably 5 or more, and 50 or less, preferably 30 or less, more preferably
  • the polyoxyalkylene monoalkyl or alkenyl ether has an HLB value of 5 or more, preferably 7 or more, more preferably 10 or more, and 20 or less, preferably 18 or less, more preferably 16 or less.
  • the detergent composition for hard surfaces according to any one of the above.
  • R 21 (OR 22 ) x G y (c2) [Wherein R 21 represents a linear or branched alkyl group having 6 to 18 carbon atoms, an alkenyl group, or an alkylphenyl group, preferably an alkyl group, and R 22 represents an alkylene group having 2 to 4 carbon atoms.
  • G represents a residue derived from a reducing sugar having 5 or 6 carbon atoms.
  • x represents an average added mole number, and is a number of 0 or more and 5 or less.
  • y represents a number whose average value is 1 or more and 5 or less.
  • the anionic surfactant is an anionic surfactant having a polyoxyalkylene group, preferably polyoxyalkylene alkyl ether sulfate, polyoxyalkylene alkenyl ether sulfate, polyoxyalkylene alkyl aryl ether sulfate, polyoxy One or more selected from alkylene alkenyl aryl ether sulfates, polyoxyalkylene alkyl ether carboxylates, and polyoxyalkylene alkenyl ether carboxylates, more preferably polyoxyalkylene alkyl ether sulfates, polyoxyalkylene alkenyl ethers One or more selected from sulfates and polyoxyalkylene alkyl ether carboxylates, more preferably polyoxyalkylene alkyl ether sulfates, Alkyl sulfates, carbon atoms in the alkyl group is 10 to 14 alkyl sulfates, the ⁇ 5> or hard surface cleaning
  • ⁇ 14> Amphoteric surfactants from alkylamidopropyl-N, N-dimethylacetic acid betaine, alkylamidopropyl-N, N-dimethyl-2-hydroxypropylsulfobetaine, and alkylamidopropyl-N, N-dimethyl-propylsulfobetaine
  • alkylamidopropyl-N, N-dimethyl-propylsulfobetaine One or more selected, preferably one selected from amidopropyl laurate-N, N-dimethylacetate betaine, hydroxylauryl sulfobetaine, and amidopropyl laurate-N, N-dimethyl-2-hydroxypropylbetaine
  • the component (a) is 6% by mass or more, preferably 8% by mass or more, more preferably 10% by mass or more, and 20% by mass or less, preferably 18% by mass or less, more preferably 15% by mass or less.
  • the hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 14>.
  • the component (b) is preferably 0.0008% by mass or more, more preferably 0.001% by mass or more, still more preferably 0.003% by mass or more, and preferably 3% by mass or less, more preferably 0.8%. % By mass or less, more preferably 0.5% by mass or less, still more preferably 0.1% by mass or less, more preferably 0.08% by mass or less, still more preferably 0.05% by mass or less, and still more preferably 0%.
  • the hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 15>, which is contained in an amount of 0.03% by mass or less.
  • the component (c) is 0.005% by mass or more, preferably 0.008% by mass or more, more preferably 0.01% by mass or more, further preferably 0.05% by mass or more, and 5% by mass or less, preferably Is contained in an amount of 3% by mass or less, more preferably 1% by mass or less, still more preferably 0.8% by mass or less, and still more preferably 0.5% by mass or less.
  • a cleaning composition for hard surfaces preferably 0.008% by mass or more, more preferably 0.01% by mass or more, further preferably 0.05% by mass or more, and 5% by mass or less.
  • the mass ratio (a) / (b) between the component (a) and the component (b) is 20 or more, preferably 50 or more, more preferably 100 or more, still more preferably 300 or more, still more preferably 500 or more, even more.
  • the hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 17>, preferably 800 or more and 20000 or less, preferably 15000 or less, more preferably 10,000 or less, and still more preferably 6000 or less. .
  • the mass ratio (b) / (c) between the component (b) and the component (c) is 0.001 or more, preferably 0.003 or more, more preferably 0.005 or more, and still more preferably 0.01 or more.
  • a nonionic surfactant is contained as a component, and a mass ratio (b) / (nonionic surfactant) between the component (b) and the nonionic surfactant is 0.001 or more, preferably 0.003. Or more, more preferably 0.005 or more, still more preferably 0.01 or more, still more preferably 0.03 or more, and 10 or less, preferably 5 or less, more preferably 1 or less, still more preferably 0.5 or less.
  • the hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 18>, wherein
  • a glycoside nonionic surfactant is contained as a component, and the mass ratio (b) / (glycoside nonionic surfactant) between component (b) and glycoside nonionic surfactant is 0.001 or more. , Preferably 0.003 or more, more preferably 0.005 or more, still more preferably 0.01 or more, still more preferably 0.03 or more, and 10 or less, preferably 5 or less, more preferably 1 or less, further The hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 18>, which is preferably 0.5 or less.
  • the pH is 20 or higher, preferably 6 or higher, more preferably 6.5 or higher, and 8 or lower, preferably 7.5 or lower, according to any one of ⁇ 1> to ⁇ 22> above A cleaning composition for hard surfaces.
  • ⁇ 24> The hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 23>, which is used for wiping and cleaning.
  • the hard surface cleaning agent according to any one of ⁇ 1> to ⁇ 24>, wherein the hard surface is a hard surface composed of one or more materials selected from ceramics, plastics, wood, stones, and metals. Composition.
  • ⁇ 26> A method for cleaning a floor, wherein the hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 25> is attached to a floor, and then the composition is wiped off.
  • the hard surface cleaning composition is adhered to the floor as a cleaning solution diluted with water 10 times or more, preferably 50 times or more, and 200 times or less, preferably 150 times or less.
  • ⁇ 29> Any of the above ⁇ 26> to ⁇ 28>, wherein the hard surface cleaning composition is adhered to the floor at 0.5 g or more, preferably 1 g or more, and 50 g or less, preferably 20 g or less per 1 m 2 of the floor area.
  • ⁇ 31> The floor according to any one of ⁇ 26> to ⁇ 30>, wherein the hard surface cleaning composition is adhered to the floor and then left for 60 seconds or less, preferably 30 seconds or less, and then the composition is wiped off. Cleaning method.
  • ⁇ 32> The floor cleaning method according to any one of ⁇ 26> to ⁇ 31>, wherein the hard surface cleaning composition is sprayed and adhered to the floor.
  • a hard surface cleaning article comprising a spray container filled with the hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 25>.
  • ⁇ 35> A method for reducing wiping lines on a floor of a ceramic tile, wherein the hard surface cleaning composition according to any one of ⁇ 1> to ⁇ 25> is used.
  • ⁇ 36> A method for reducing wiping lines generated by wiping the floor of a ceramic tile with a cleaning composition and then wiping the cleaning composition, wherein the cleaning composition includes the above items ⁇ 1> to ⁇ 25.
  • the hard surface cleaning composition is adhered to the floor as a cleaning solution diluted 10 times or more, preferably 50 times or more, and 200 times or less, preferably 150 times or less with water.
  • the method for reducing wiping lines according to any one of the above.
  • ⁇ 40> The method for reducing wiping lines according to any one of ⁇ 35> to ⁇ 39>, wherein the cleaning composition for a hard surface is sprayed to adhere to the floor of the ceramic tile.
  • ⁇ 42> The method for reducing wiping lines according to any one of ⁇ 35> to ⁇ 41>, wherein the cleaning composition for a hard surface is sprayed to adhere to the ceramic tile floor.
  • composition containing (a) ethanol in an amount of 5% by mass to 23% by mass, (b) a polyether-modified silicone, (c) a surfactant, and water as a hard surface cleaning composition.
  • ⁇ 45> The use according to ⁇ 44>, wherein the spray container is a spray container equipped with a trigger sprayer.
  • Examples 1 to 18 and Comparative Examples 1 to 4 The cleaning composition for hard surfaces shown in Table 1 was prepared, and the following items were evaluated. The results are shown in Table 1. In addition, adjustment of pH (20 degreeC) of a composition was performed using sodium hydroxide and hydrochloric acid.
  • ⁇ Evaluation method> (1) Detergency Porcelain tile (Manufacturer: Foshan XiangYu Ceramic Co., Ltd., Product name: POLISHED PORCELAIN TILE, Grade: Premium, Color: White, Size 100mm x 100mm) Oleic acid colored by adding Sudan III (manufactured by Wako Pure Chemical Industries, Ltd., grade 1) to 0.5 g was dropped as a model stain (approx. 1 cm 2 ). . 2 g of the hard surface cleaning composition shown in Table 1 was adhered so as to uniformly contact the entire periphery of the model soil.
  • a paper wiper (pro wipes made by Daio Paper Co., Ltd., soft wiper S200, dimensions: 195 mm x 125 mm) is folded four times (dimensions: about 24 mm x 63 mm), and this is brought into contact with the center of the model dirt, and the middle and index fingers of an adult male Then, while pressing the folded paper wiper, it was wiped 10 times under a load of 1 ⁇ 0.1 kg so as to draw a circle with a diameter of about 50 mm centered on the model dirt. After wiping, the remaining state of the dirt after drying was visually observed and judged according to the following criteria. 5 points: Slightly soiled 4 points: Levels that remain slightly colored but not noticed 3 points: Levels that remain slightly colored but not concerned 2 points: Many colored parts remain 1 point: No dirt at all
  • a paper wiper (Pro wipe soft towel 4P manufactured by Daio Paper Co., Ltd., dimensions: 405 mm ⁇ 315 mm) was cut into a size of 30 mm ⁇ 100 mm to obtain a piece of paper.
  • the piece of paper is placed on porcelain tile (manufacturer: Foshan XiangYu Ceramic Co., Ltd., product name: POLISHED PORCELAIN TILE, Grade: Premium, color: black, dimensions 100 mm ⁇ 100 mm) and the length of one side of the tile and the piece of paper. It was placed so that the sides matched.
  • the paper piece is impregnated with 1 g of the hard surface cleaning composition shown in Table 1, and a load tile of 100 g having the same size (30 mm ⁇ 100 mm) as the paper piece is placed on the opposite side of the porcelain tile. It was moved in 3 seconds by pulling together with the paper piece. Thereafter, the load tile and the paper piece were removed, and the finish of the tile surface after drying was visually observed and judged according to the following criteria. 5 points: level with almost no wiping lines 4 points: level with slight wiping lines remaining but no concern 3 points: level with slight wiping lines remaining but 2 points: level with many wiping lines remaining 1 point : Level at which wiping lines remain on the entire surface
  • Polyether modified silicone 5 PEG / PPG-20 / 22 butyl ether dimethicone [polyether modified silicone in which R 2 is a butyl group, b is 20, and c is 22 in the general formula (b1)], Shin-Etsu Chemical Co., Ltd.
  • Polyether-modified silicone 6 PEG10 dimethicone [polyether-modified silicone in which R 2 is a hydrogen atom and b is 10 in general formula (b1), manufactured by Shin-Etsu Chemical Co., Ltd., KF6043, HLB15 (catalog value), motion Viscosity 400mm 2 / s
  • the viscosity of component (b) is a kinematic viscosity measured at 25 ° C. with an Ubbelohde viscometer (manufactured by Shibata Kagaku Co., Ltd.).
  • (B ′) component (comparison component of component (b))
  • Cyclic silicone cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd., KF995, silicone not modified with polyether, kinematic viscosity 4 mm 2 / s
  • Anion-modified silicone carboxy group-containing modified silicone (X Shin-Etsu Chemical Co., Ltd., X-22-3701E, kinematic viscosity 2,000 mm 2 / s, functional group equivalent 4,000 g / mol)
  • Nonionic Surfactant 1 Alkyl Polyglycoside [In the general formula (c2), R 21 is a linear alkyl group of 6 to 16, x is 0, G is a residue derived from glucose, y Is a nonionic surfactant having a molecular weight of 1.1], manufactured by BASF, Plantacare 2000UP
  • Nonionic surfactant 2 polyoxyalkylene alkyl ether [in the general formula (c1), R 11 is a linear primary alkyl group having 12 to 14 carbon atoms, l is 14, and m is 0.5, Nonionic surfactant having the structure: HLB15.3 R 11 O [(C 2 H 4 O) 7 (C 3 H 6 O) 0.5 (C 2 H 4 O) 7 ] H
  • Nonionic surfactant 3 polyoxyethylene alkyl ether [in the general formula (c1), R 11 is a branched secondary alkyl group having 12 to 14 carbon atoms, l is 7, m is 0]
  • Examples 1 to 18 of the present invention can achieve both detergency and finish as compared with Comparative Examples 1 to 4.
  • Comparing Examples 1 and 4 to 8 with Comparative Examples 1 and 4 it can be seen that Examples 1 and 4 to 8 using the polyether-modified silicone as component (b) as the silicone compound are more excellent in finish. .
  • Example 1 using polyether-modified silicone 1 having a component (b) of HLB11 and a kinematic viscosity of 20 mm 2 / s as the polyether-modified silicone is superior in finish. Recognize.
  • Example 1 using nonionic surfactant 1 which is a glycoside nonionic surfactant as component (c) is superior in finish.
  • Example 1 in which the content of the component (a) is 12% by mass is more excellent in finish.
  • Comparing Examples 1 and 13 to 16 it can be seen that Example 1 in which the content of the component (c) is 0.1% by mass is more excellent in finish.
  • Example 1 When Examples 1, 11, and 12 in which the content of the component (a) and the component (c) are the same and the mass ratio is different (a) / (b) are compared, the mass ratio of (a) / (b) is 1200. It can be seen that Example 1 and Example 11 which are 4000 are excellent in detergency and finish. When Examples 1 and 13 to 16 in which the contents of the component (a) and the component (b) are the same and the mass ratio (b) / (c) are different are compared, the mass ratio of (b) / (c) is 0. It can be seen that Example 1, which is 0.1, is excellent in detergency and finish.
  • Example 19 Porcelain tile (Manufacturer: Foshan XiangYu Ceramic Co., Ltd., Product name: POLISHED PORCELAIN TILE, Grade: Premium, Color: Black, Dimensions 60mm x 60mm) on the floor of the living room of a general family (family of 4) for 3 days It was installed and the entire family was run barefoot on it 10 times a day for 3 days to create 2 contaminated tiles.
  • Each of the hard surface cleaning compositions of Example 1 shown in Table 1 was filled in a trigger spray container of “Bath Magiclin Foaming Spray” (manufactured by Kao Corporation).
  • Spray nozzle is "wide foam”, sprayed 5 times per tile (spraying amount 4.5g), and mop immediately (mop installed: moon star mop replacement yarn, standard 24cm # 190, MIYAKO CO., LTD.
  • the product was subjected to 6 reciprocating cleanings, and the finish after drying (presence or absence of wiping lines) was determined according to the above criteria. The results were as follows.
  • Example 19 composition of Example 1): 5 points

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Abstract

La présente invention est une composition de détergent pour surfaces dures, qui contient (a) 5 à 23 % en masse d'éthanol, (b) du silicone modifiée par un polyéther, (c) un tensioactif, et de l'eau.
PCT/JP2016/070514 2015-07-14 2016-07-12 Composition détergente pour surfaces dures WO2017010473A1 (fr)

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