WO2016125612A1 - 難燃剤組成物及び難燃性合成樹脂組成物 - Google Patents
難燃剤組成物及び難燃性合成樹脂組成物 Download PDFInfo
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- WO2016125612A1 WO2016125612A1 PCT/JP2016/051985 JP2016051985W WO2016125612A1 WO 2016125612 A1 WO2016125612 A1 WO 2016125612A1 JP 2016051985 W JP2016051985 W JP 2016051985W WO 2016125612 A1 WO2016125612 A1 WO 2016125612A1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- GDESWOTWNNGOMW-UHFFFAOYSA-N resorcinol monobenzoate Chemical compound OC1=CC=CC(OC(=O)C=2C=CC=CC=2)=C1 GDESWOTWNNGOMW-UHFFFAOYSA-N 0.000 description 1
- JPPLPDOXWBVPCW-UHFFFAOYSA-N s-(3-triethoxysilylpropyl) octanethioate Chemical compound CCCCCCCC(=O)SCCC[Si](OCC)(OCC)OCC JPPLPDOXWBVPCW-UHFFFAOYSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940045845 sodium myristate Drugs 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229960004025 sodium salicylate Drugs 0.000 description 1
- ZQOXGRIKWKXDIJ-UHFFFAOYSA-M sodium;1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZQOXGRIKWKXDIJ-UHFFFAOYSA-M 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- XTIVBOWLUYDHKE-UHFFFAOYSA-M sodium;cyclohexanecarboxylate Chemical compound [Na+].[O-]C(=O)C1CCCCC1 XTIVBOWLUYDHKE-UHFFFAOYSA-M 0.000 description 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- WUPCFMITFBVJMS-UHFFFAOYSA-N tetrakis(1,2,2,6,6-pentamethylpiperidin-4-yl) butane-1,2,3,4-tetracarboxylate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CC(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)CC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 WUPCFMITFBVJMS-UHFFFAOYSA-N 0.000 description 1
- NZNAAUDJKMURFU-UHFFFAOYSA-N tetrakis(2,2,6,6-tetramethylpiperidin-4-yl) butane-1,2,3,4-tetracarboxylate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CC(C(=O)OC1CC(C)(C)NC(C)(C)C1)C(C(=O)OC1CC(C)(C)NC(C)(C)C1)CC(=O)OC1CC(C)(C)NC(C)(C)C1 NZNAAUDJKMURFU-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- KEROTHRUZYBWCY-UHFFFAOYSA-N tridecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCOC(=O)C(C)=C KEROTHRUZYBWCY-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- ZYMHKOVQDOFPHH-UHFFFAOYSA-N trimethoxy(oct-1-enyl)silane Chemical compound CCCCCCC=C[Si](OC)(OC)OC ZYMHKOVQDOFPHH-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
- LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 description 1
- SPUXJWDKFVXXBI-UHFFFAOYSA-N tris(2-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)(C)C)OC1=CC=CC=C1C(C)(C)C SPUXJWDKFVXXBI-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- KPGXUAIFQMJJFB-UHFFFAOYSA-H tungsten hexachloride Chemical compound Cl[W](Cl)(Cl)(Cl)(Cl)Cl KPGXUAIFQMJJFB-UHFFFAOYSA-H 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- PSVXZQVXSXSQRO-UHFFFAOYSA-N undecaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO PSVXZQVXSXSQRO-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960003487 xylose Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- XSMMCTCMFDWXIX-UHFFFAOYSA-N zinc silicate Chemical compound [Zn+2].[O-][Si]([O-])=O XSMMCTCMFDWXIX-UHFFFAOYSA-N 0.000 description 1
- 235000019352 zinc silicate Nutrition 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/10—Organic materials containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/66—Substances characterised by their function in the composition
- C08L2666/84—Flame-proofing or flame-retarding additives
Definitions
- the present invention relates to a flame retardant composition for a synthetic resin and a flame retardant synthetic resin composition blended with the flame retardant composition. Specifically, the composition has less dusting and is easy to handle, and further has no caking and storage stability.
- the present invention relates to an excellent flame retardant composition and a flame retardant synthetic resin composition containing the flame retardant composition.
- Intomesent flame retardants have excellent flame retardancy, and are described in, for example, US2003 / 088000.
- Patent Document 1 in order to improve the powder properties and processability of this intimescent flame retardant, and the physical properties of the resin when blended with a resin, addition of higher aliphatic carboxylic acid esters, silicone oils and silane coupling agents The addition of has been proposed.
- Patent Documents 2 to 4 Patent Documents 2 to 4
- these conventional intumescent flame retardants have not been sufficiently solved for handling properties, such as powdering during use, and even when powdering can be improved, caking or the like occurs during storage and storage stability is maintained.
- There was a problem with the property and there was also a problem that had an adverse effect on the flame retardancy. Therefore, there has been a need for a flame retardant having little dusting and the like, excellent handling properties, no caking and the like, excellent storage stability, and excellent flame retardancy.
- an object of the present invention is to provide a flame retardant composition that has less dusting and excellent handling properties, and that has no caking or the like and excellent storage stability. Moreover, it is providing the flame-retardant synthetic resin composition excellent in the flame retardance which mix
- the present invention as the first invention, 20 to 50 parts by mass of the following component (A), 50 to 80 parts by mass of the following component (B) (however, the total of the components (A) and (B) is 100 parts by mass) ), A flame retardant composition containing 0.01 to 5.0 parts by mass of the following component (C) and 0.01 to 1.0 parts by mass of the following component (D).
- this invention provides the said flame retardant composition whose said (C) component is a silane coupling agent which has an epoxy group as a preferable form of 1st invention.
- the following (A) component is 20 to 50 parts by mass, and the following (B) component is 50 to 80 parts by mass (provided that the total of (A) and (B) components is 100 parts by mass) ),
- the present invention also provides, as a preferred form of the second invention, the flame retardant composition further containing 0.01 to 10 parts by mass of silicone oil as component (F).
- the present invention also provides the above-mentioned flame retardant composition containing 0.01 to 10 parts by mass of zinc oxide as component (G) as a preferred embodiment of the first and second inventions.
- this invention provides the flame retardant synthetic resin composition containing the synthetic resin and the flame retardant composition of the 1st invention or the 2nd invention as 3rd invention.
- the present invention provides, as a preferred form of the second invention, the flame retardant synthetic resin composition, wherein the synthetic resin is a polyolefin resin.
- this invention provides the molded object of the said flame-retardant synthetic resin composition as 4th invention.
- the present invention it is possible to provide a flame retardant composition that has less dusting and excellent handling properties, is excellent in storage stability without caking, etc., and can impart excellent flame retardancy to a synthetic resin. Moreover, according to this invention, the flame-retardant synthetic resin composition excellent in the flame retardance can be provided. Moreover, according to this invention, the molded object which has a flame retardance can be provided.
- the first invention and the second invention relate to a flame retardant composition.
- the flame retardancy is a property that a substance is difficult to ignite, and that the rate is very slow even after ignition and combustion continues, or that self-extinguishes thereafter.
- it means that it has at least a V-2 rank among the combustion ranks according to the UL-94V standard described in the examples, and the flame retardant composition contains one or more flame retardants Means a composition.
- the melamine salt used as the component (A) in the flame retardant composition of the first invention is selected from the group of melamine orthophosphate, melamine pyrophosphate, and melamine polyphosphate, and these may be used alone or in a mixture.
- melamine pyrophosphate is preferable in terms of flame retardancy, handling properties, and storage stability. When these are used in a mixture, the higher the content ratio of melamine pyrophosphate, the better.
- the molar ratio of melamine pyrophosphate to the melamine pyrophosphate is preferably 1: 2.
- salts of phosphoric acid and melamine can also be obtained by reacting the corresponding phosphoric acid or phosphate and melamine, respectively, but the melamine salt used in component (A) heats 1-melamine orthophosphate.
- Melamine pyrophosphate or melamine polyphosphate obtained by condensation is preferred, and melamine pyrophosphate is particularly preferred.
- the piperazine salt used as the component (B) in the flame retardant composition of the first invention is selected from the group of piperazine orthophosphate, piperazine pyrophosphate, piperazine polyphosphate, and these may be used alone or in a mixture.
- piperazine pyrophosphate is preferable from the viewpoint of flame retardancy, handling properties, and storage stability. When used in a mixture, the higher the content of piperazine pyrophosphate, the better.
- the ratio of pyrophosphoric acid to piperazine is preferably 1: 1 in terms of molar ratio.
- These phosphoric acid and piperazine salts can be obtained by reacting the corresponding phosphoric acid or phosphate with piperazine, respectively.
- the piperazine salt used in component (B) is obtained by heating 1 piperazine 2 orthophosphate. Piperazine pyrophosphate or piperazine polyphosphate obtained by condensation is preferred, and piperazine pyrophosphate is particularly preferred.
- the content of the component (A) and the component (B) in the flame retardant composition of the first invention is such that the total of the component (A) and the component (B) is 100 parts by mass, and the component (A) is 20 to 50 masses.
- the component (B) is 50 to 80 parts by mass, preferably the component (A) is 30 to 45 parts by mass, and the component (B) is 55 to 70 parts by mass.
- a silane coupling agent is used as the component (C).
- the silane coupling agent for example, as a silane coupling agent having an alkenyl group, vinyltrimethoxysilane, vinyltriethoxysilane, vinyltriacetoxysilane, vinyltris (2-methoxyethoxy) silane, vinylmethyldimethoxysilane, octenyl Examples include trimethoxysilane, allyltrimethoxysilane, and p-styryltrimethoxysilane.
- silane coupling agent having an acrylic group examples include 3-acryloxypropyltrimethoxysilane and 3-acryloxypropyltriethoxysilane.
- silane coupling agents having a methacryl group 3-methacryloxypropylmethyldimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-methacryloxypropylmethyldie Examples include xysilane, 3-methacryloxypropyltriethoxysilane, methacryloxyoctyltrimethoxysilane, etc.
- silane coupling agents having an epoxy group 2- (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 3-glycol Sidoxypropylmethyldimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropylmethyldiethoxysilane, 3-glycidoxypropyltriethoxysilane, glycidoxyoctyltrimethoxysilane, etc.
- silane coupling agent having an amino group N-2- (aminoethyl) -3-aminopropylmethyldimethoxysilane, N-2- (aminoethyl) -3-aminopropyltrimethoxysilane, 3-aminopropyltrimethoxy Lan, 3-aminopropyltriethoxysilane, 3-triethoxysilyl-N- (1,3-dimethyl-butylidene) propylamine, N-phenyl-3-aminopropyltrimethoxysilane, N, N′-bis [3 -(Trimethoxysilyl) propyl] ethylenediamine, hydrochloride of N- (vinylbenzyl) -2-aminoethyl-3-aminopropyltrimethoxysilane and the like, and silane coupling agents having an isocyanurate group include tris- (Trimethoxysilylpropyl) is
- silane coupling agent examples include 3-ureidopropyltrimethoxysilane and 3-ureidopropyltriethoxysilane.
- silane coupling agent having a sulfide group examples include bis (triethoxysilylpropyl) tetrasulfide, and thioesters.
- examples of the silane coupling agent having a group include 3-octanoylthio-1-propyltriethoxysilane, and examples of the silane coupling agent having an isocyanate group include 3-isocyanatopropyltriethoxysilane and 3-isocyanatopropyltrimethoxysilane. Can be mentioned.
- silane coupling agent having an epoxy group is preferable from the viewpoint of flame retardancy, handling properties, and further preventing aggregation of the flame retardant powder and improving storage stability.
- Glycidoxyoctyltrimethoxysilane is more preferable.
- silane coupling agent for example, as vinyltrimethoxysilane, KBM-1003 manufactured by Shin-Etsu Chemical Co., Ltd., manufactured by Montive Performance Materials Japan LLC. No. A-171, Z-6300 manufactured by Toray Dow Corning Co., Ltd., GENIOSIL XL10 manufactured by Asahi Kasei Wacker Silicone Co., Ltd., Silaace S210 manufactured by Nimi Shoji Co., Ltd., etc.
- KBE-1003 manufactured by Shin-Etsu Chemical Co., Ltd., A-151 manufactured by Montive Performance Materials Japan G.K., Z-6519 manufactured by Toray Dow Corning Co., Ltd., GENIOSIL manufactured by Asahi Kasei Wacker Silicone Co., Ltd. GF56, Sila Ace manufactured by Nimi Shoji Co., Ltd.
- vinyl triacetoxy silane GENIOSIL GF62 manufactured by Asahi Kasei Wacker Silicone Co., Ltd.
- vinyl tris (2-methoxyethoxy) silane manufactured by Montive Performance Materials Japan GK
- examples of the vinylmethyldimethoxysilane include A-2171 manufactured by Montive Performance Materials Japan GK, GENIOSIL XL12 manufactured by Asahi Kasei Wacker Silicone Co., Ltd., and octenyltrimethoxysilane.
- KBM-1083 manufactured by Shin-Etsu Chemical Co., Ltd. can be cited.
- allyltrimethoxysilane Z-6825 manufactured by Toray Dow Corning Co., Ltd.
- KBM-1403 manufactured by Shin-Etsu Chemical Co., Ltd. KBM-5103 is exemplified as 3-acryloxypropyltrimethoxysilane
- Shin-Etsu Chemical Co., Ltd. is exemplified as 3-methacryloxypropylmethyldimethoxysilane
- KBM-502 manufactured by Toray Dow Corning Co., Ltd., etc., and 3-methacryloxypropyltrimethoxysilane include KBM-503 manufactured by Shin-Etsu Chemical Co., Ltd.
- Examples include KBM-402 manufactured by Koshi Chemical Industry Co., Ltd., Z-6044 manufactured by Toray Dow Corning Co., Ltd., and Silaace S520 manufactured by Himi Shoji Co., Ltd., and examples of 3-glycidoxypropyltrimethoxysilane KBM-403 manufactured by Shin-Etsu Chemical Co., Ltd., A-187 manufactured by Montive Performance Materials Japan GK, Z-6040 manufactured by Toray Dow Corning Co., Ltd., manufactured by Asahi Kasei Wacker Silicone Co., Ltd.
- GENIOSIL GF80, Nylon Corporation Silaace S510, and the like, and 3-glycidoxypropylmethyldiethoxysilane include Shin-Etsu Chemical Co., Ltd. KBE-402, 3-glycidoxy Examples of propyltriethoxysilane include Shin-Etsu Chemical Co., Ltd. KBE-403, Montive Examples include A-1871 manufactured by Forance Materials Japan GK, GENIOSIL GF82 manufactured by Asahi Kasei Wacker Silicone Co., Ltd., and glycidoxyoctyltrimethoxysilane is KBM- manufactured by Shin-Etsu Chemical Co., Ltd. 4803.
- N-2- (aminoethyl) -3-aminopropylmethyldimethoxysilane examples include KBM-602 manufactured by Shin-Etsu Chemical Co., Ltd., and A- manufactured by Montive Performance Materials Japan LLC. 2120, GENIOSIL GF-95 manufactured by Asahi Kasei Wacker Silicone Co., Ltd., Silaace S310 manufactured by Nimi Shoji Co., Ltd., and the like.
- N-2- (aminoethyl) -3-aminopropyltrimethoxysilane Shin-Etsu Chemical KBM-603 manufactured by Kogyo Co., Ltd., Montive Par A-1120 manufactured by Forance Materials Japan GK, A-1122 manufactured by Montive Performance Materials Japan GK, Z-6020 manufactured by Toray Dow Corning Co., Ltd., Toray Dow Corning Co., Ltd. ) Z-6094 manufactured by Asahi Kasei Wacker Silicone Co., Ltd. GENIOSIL GF-91, Silami Ace S320 manufactured by Nimi Shoji Co., Ltd., and the like.
- As 3-aminopropyltrimethoxysilane Shin-Etsu Chemical Co., Ltd.
- -Aminopropyltriethoxysilane includes KBE-903, A-1100 manufactured by Tive Performance Materials Japan G.K., Z-6011 manufactured by Toray Dow Corning Co., Ltd., Silaace S330 manufactured by Nimi Shoji Co., Ltd., and the like.
- Examples of-(1,3-dimethyl-butylidene) propylamine include KBE-9103, Silaace S340 manufactured by Nimi Shoji Co., Ltd., and N-phenyl-3-aminopropyltrimethoxysilane includes Shin-Etsu Chemical Co., Ltd. KBM-573 manufactured by Co., Ltd., Y-9669 manufactured by Montive Performance Materials Japan GK, Z-6883 manufactured by Toray Dow Corning Co., Ltd. and the like, N, N'-Bis [3 -(Trimethoxysilyl) propyl] ethylenediamine includes Sila Ace X manufactured by Nimi Shoji Co., Ltd.
- N- (vinylbenzyl) -2-aminoethyl-3-aminopropyltrimethoxysilane hydrochloride includes KBM-575 manufactured by Shin-Etsu Chemical Co., Ltd., manufactured by Toray Dow Corning Co., Ltd.
- Z-6032, Silaace S350 manufactured by Nimi Shoji Co., Ltd., and tris- (trimethoxysilylpropyl) isocyanurate include KBM-9659 manufactured by Shin-Etsu Chemical Co., Ltd., and 3-mercapto As propylmethyldimethoxysilane, KBM-802 manufactured by Shin-Etsu Chemical Co., Ltd., Z-6852 manufactured by Toray Dow Corning Co., Ltd., and 3-mercaptopropyltrimethoxysilane manufactured by Shin-Etsu Chemical Co., Ltd.
- KBM-803, A-189 manufactured by Montive Performance Materials Japan GK Examples include Z-6062 manufactured by Le Dow Corning Co., Ltd., Silaace S810 manufactured by Nimi Shoji Co., Ltd., etc.
- 3-mercaptopropyltriethoxysilane A manufactured by Montive Performance Materials Japan GK -1891, Z-6911 manufactured by Toray Dow Corning Co., Ltd., and 3-ureidopropyltriethoxysilane include A-1160 manufactured by Montive Performance Materials Japan GK
- Examples of ureidopropyltrialkoxysilane include KBE-585 manufactured by Shin-Etsu Chemical Co., Ltd.
- examples of bis (triethoxysilylpropyl) tetrasulfide include KBE-846 manufactured by Shin-Etsu Chemical Co., Ltd.
- 3-Octanoylthio-1-propyltriethoxy Examples include A-LINK599 manufactured by Montive Performance Materials Japan GK, and 3-isocyanatopropyltriethoxysilane includes KBE-9007 manufactured by Shin-Etsu Chemical Co., Ltd., and Montive Performance Materials. A-1310, etc., manufactured by Japan Ltd., and 3-isocyanatopropyltrimethoxysilane include Y-5187 manufactured by Montive Performance Materials Japan LLC, and GENIOSIL manufactured by Asahi Kasei Wacker Silicone Co., Ltd. GF40 etc. are mentioned.
- the content of the (C) component silane coupling agent in the flame retardant composition of the first invention is 0.01 to 5.0 mass with respect to a total of 100 mass parts of the (A) component and the (B) component. From the viewpoint of flame retardancy, handling properties, and prevention of aggregation of the flame retardant powder to improve storage stability, it is preferably 0.05 to 3.0 parts by mass, more preferably 0.1 to 2. 0 parts by mass. If it is less than 0.01 parts by mass, the flame retardant powder aggregates and storage stability deteriorates. If it exceeds 5.0 parts by mass, the flame retardancy is adversely affected.
- the component (D) of the flame retardant composition of the first invention is an aliphatic dicarboxylic acid ether ester compound represented by the following general formula (1).
- n represents an integer of 2 to 6
- m represents an integer of 1 to 3
- R 1 represents an alkyl group having 1 to 6 carbon atoms.
- the alkyl group having 1 to 6 carbon atoms may be a linear alkyl group or a branched alkyl group.
- R 1 is preferably a butyl group from the viewpoints of flame retardancy, particularly handling properties and storage stability.
- n is preferably 4 from the viewpoints of flame retardancy, particularly handling properties and storage stability.
- m is preferably 2 from the viewpoints of flame retardancy, particularly handling properties and storage stability.
- aliphatic dicarboxylic acid ether ester compound represented by the general formula (1) of the first invention for example, the following compound No. 1-No. 22 and the like.
- the aliphatic dicarboxylic acid ether ester compound represented by the general formula (1) can be produced by a conventionally known method.
- Examples of the production method include aliphatic dicarboxylic acids having 4 to 8 carbon atoms and diethylene glycol monoalkyl ether, ethylene glycol monoalkyl ether or triethylene glycol monoalkyl ether having an alkyl group having 1 to 6 carbon atoms.
- an esterification reaction In the esterification reaction, a commonly used catalyst may be used.
- Examples of the aliphatic dicarboxylic acid having 4 to 8 carbon atoms used for the production include succinic acid, glutaric acid, adipic acid, pimelic acid, and suberic acid. These aliphatic dicarboxylic acids may be derivatives of aliphatic dicarboxylic acids (for example, acid anhydrides, alkyl esters, alkali metal salts, acid halides, etc.).
- diethylene glycol monoalkyl ethers having 1 to 6 carbon atoms in the alkyl group used in the production include diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monopentyl ether, diethylene glycol. Examples thereof include monohexyl ether and diethylene glycol monoisopropyl ether.
- Examples of ethylene glycol monoalkyl ether having 1 to 6 carbon atoms in the alkyl group include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether.
- Ethylene glycol monobutyl ether ethylene glycol
- examples thereof include pentyl ether, ethylene glycol monohexyl ether, and ethylene glycol monoisopropyl ether.
- triethylene glycol monoalkyl ethers having 1 to 6 carbon atoms in the alkyl group include triethylene glycol monomethyl ether and triethylene glycol.
- Examples include monoethyl ether, triethylene glycol monopropyl ether, triethylene glycol monobutyl ether, triethylene glycol monopentyl ether, triethylene glycol monohexyl ether, and triethylene glycol monoisopropyl ether.
- the compound No. 1 can be obtained by esterifying 1 mol of adipic acid and 2 mol of diethylene glycol monobutyl ether.
- the content of the aliphatic dicarboxylic acid ether ester compound as the component (D) in the flame retardant composition of the first invention is 0.01 to 1 with respect to 100 parts by mass in total of the components (A) and (B).
- 0.0 part by mass preferably from 0.05 to 0.5 part by mass, more preferably from 0.1 to 0.5 part by mass, even more preferably from the viewpoint of flame retardancy, handling properties, and storage stability 0.1 to 0.3 parts by mass.
- the amount is less than 0.01 parts by mass, dusting cannot be suppressed and handling properties are deteriorated.
- the amount exceeds 1.0 parts by mass the storage stability and flame retardancy are adversely affected.
- the flame retardant composition of the first invention preferably further contains zinc oxide as a flame retardant aid as the component (G).
- the zinc oxide may be surface-treated.
- Commercially available zinc oxide can be used, for example, one type of zinc oxide (manufactured by Mitsui Kinzoku Mining Co., Ltd.), partially coated zinc oxide (manufactured by Mitsui Kinzoku Mining Co., Ltd.), Nano Fine 50 (average particle size) And 0.02 ⁇ m ultrafine zinc oxide (manufactured by Sakai Chemical Industry Co., Ltd.), Nanofine K (ultrafine zinc oxide coated with zinc silicate having an average particle size of 0.02 ⁇ m: Sakai Chemical Industry Co., Ltd.) and the like. .
- the content of the zinc oxide of the component (G) in the flame retardant composition of the first invention is 0.01 from the viewpoint of flame retardancy with respect to 100 parts by mass of the total of the components (A) and (B). Is preferably 10 to 10 parts by mass, more preferably 0.5 to 10 parts by mass, and still more preferably 1.0 to 7.5 parts by mass.
- the flame retardant composition of the first invention may contain an anti-drip agent as necessary within a range not impairing the effects of the present invention.
- an anti-drip agent include a fluorine-based anti-drip agent, a layered silicate, and silicon rubber.
- fluorine-based anti-drip agent examples include, for example, fluorine-based resins such as polytetrafluoroethylene, polyvinylidene fluoride, and polyhexafluoropropylene, sodium perfluoromethanesulfonate, and potassium perfluoro-n-butanesulfonate.
- fluorine-based resins such as polytetrafluoroethylene, polyvinylidene fluoride, and polyhexafluoropropylene, sodium perfluoromethanesulfonate, and potassium perfluoro-n-butanesulfonate.
- Perfluoroalkanesulfonic acid alkali metal salt compounds such as salts, potassium perfluoro-t-butanesulfonate, sodium perfluorooctanesulfonate, calcium perfluoro-2-ethylhexanesulfonate, or alkali perfluoroalkanesulfonate Examples include earth metal
- layered silicate examples include smectite clay minerals such as montmorillonite, saponite, hectorite, beidellite, stevensite, nontronite, vermiculite, halloysite, swellable mica, talc, etc.
- a cation, a quaternary ammonium cation, or a phosphonium cation may be intercalated.
- a fluorine-based anti-drip agent is particularly preferable, and polytetrafluoroethylene is most preferable from the viewpoint of anti-drip properties.
- the content of the anti-drip agent is preferably 0.005 to 5 parts by mass, more preferably 0.01 to 100 parts by mass in total of the component (A) and the component (B). To 5 parts by mass, more preferably 0.05 to 3 parts by mass, and most preferably 0.1 to 1 part by mass. If it is less than 0.005 parts by mass, the drip prevention effect is not sufficient, and if it exceeds 5 parts by mass, the resin properties may be lowered.
- silicone oil may be blended as necessary in order to improve water resistance and the like within a range not impairing the effects of the present invention.
- Polysiloxane side chain, dimethyl silicone oil whose terminal is all methyl groups, polysiloxane side chain part methyl phenyl silicone oil, polysiloxane side chain part hydrogen is methyl hydrogen
- Examples include silicone oils and copolymers thereof, and amine modification, epoxy modification, alicyclic epoxy modification, carboxyl modification, carbinol modification, in which an organic group is introduced into a part of these side chains and / or terminals.
- Mercapto modification polyether modification, long chain alkyl modification, fluoroalkyl modification, higher fatty acid ester modification, higher fat Amide-modified, silanol-modified, diol-modified, it may be used phenol-modified and / or aralkyl modified modified silicone oil.
- silicone oils include, as dimethyl silicone oil, KF-96 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-965 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-968 (Shin-Etsu Chemical Co., Ltd.).
- silicone oil having methyl hydrogen silicone oil or methyl hydrogen polysiloxane structure KF-99 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-9901 (Shin-Etsu Chemical Co., Ltd.), HMS -151 (manufactured by Gelest), HMS-071 (manufactured by Gelest), HMS-301 (manufactured by Gelest), DMS-H21 (manufactured by Gelest), etc.
- methylphenyl silicone oil examples include KF- 50 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-53 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-54 (manufactured by Shin-Etsu Chemical Co., Ltd.), F-56 (manufactured by Shin-Etsu Chemical Co., Ltd.) and the like, and epoxy modified products include, for example, X-22-343 (manufactured by Shin-Etsu Chemical Co., Ltd.), X-22-2000 (manufactured by Shin-Etsu Chemical Co., Ltd.).
- KF-101 manufactured by Shin-Etsu Chemical Co., Ltd.
- KF-102 manufactured by Shin-Etsu Chemical Co., Ltd.
- KF-1001 manufactured by Shin-Etsu Chemical Co., Ltd.
- carboxyl-modified products for example, X-22 3701E (manufactured by Shin-Etsu Chemical Co., Ltd.), carbinol modified products, for example, X-22-4039 (manufactured by Shin-Etsu Chemical Co., Ltd.), X-22-4015 (manufactured by Shin-Etsu Chemical Co., Ltd.), amine-modified products
- KF-393 manufactured by Shin-Etsu Chemical Co., Ltd.
- the content is preferably 0.01 to 5.0 parts by mass, more preferably 0.05 to 100 parts by mass in total of the components (A) and (B). It is -3.0 mass parts, More preferably, it is 0.1-2.0 mass parts.
- the flame retardant composition of the first invention may be blended with a polyhydric alcohol compound as a flame retardant aid as necessary within a range not impairing the effects of the invention.
- the polyhydric alcohol compound is a compound in which a plurality of hydroxyl groups are bonded, for example, pentaerythritol, dipentaerythritol, tripentaerythritol, polypentaerythritol, neopentyl glycol, trimethylolpropane, ditrimethylolpropane, 1, 3,5-tris (2-hydroxyethyl) isocyanurate (THEIC), polyethylene glycol, glycerin, diglycerin, mannitol, maltitol, lactitol, sorbitol, erythritol, xylitol, xylose, sucrose (sucrose), trehalose, inositol, Fructose, maltose
- polyhydric alcohol compounds one or more selected from the group of pentaerythritol and pentaerythritol condensates such as pentaerythritol, dipentaerythritol, tripentaerythritol, and polypentaerythritol are preferred, and dipentaerythritol, pentaerythritol Condensates are particularly preferred and dipentaerythritol is most preferred.
- THEIC and sorbitol can also be used conveniently.
- the content is preferably 0.5 to 15 parts by mass, more preferably 2 to 12 parts per 100 parts by mass in total of the component (A) and the component (B). Parts by weight, more preferably 5 to 10 parts by weight.
- the flame retardant composition of the first invention may be blended with a lubricant as necessary within a range not impairing the effects of the invention.
- lubricants include pure hydrocarbon lubricants such as liquid paraffin, natural paraffin, micro wax, synthetic paraffin, low molecular weight polyethylene and polyethylene wax; halogenated hydrocarbon lubricants; fatty acid lubricants such as higher fatty acids and oxy fatty acids.
- Fatty acid amide type lubricants such as fatty acid amides and bis fatty acid amides
- ester type lubricants such as lower alcohol esters of fatty acids, polyhydric alcohol esters of fatty acids such as glycerides, polyglycol esters of fatty acids, fatty alcohol esters of fatty acids (ester waxes) ;
- Metal soap fatty alcohol, polyhydric alcohol, polyglycol, polyglycerol, fatty acid and polyhydric alcohol partial ester, fatty acid and polyglycol, polyglycerol partial ester lubricant, silicone oil, mineral oil, etc. It is. Two or more lubricants may be used.
- the content is preferably 0.05 to 10 parts by mass, more preferably 0.1 to 5 parts per 100 parts by mass in total of the component (A) and the component (B). Mass.
- one or more organic or inorganic flame retardants or flame retardant aids that do not contain halogen are further used as necessary within a range not impairing the effects of the invention.
- These flame retardants and flame retardant aids include triazine ring-containing compounds, metal hydroxides, phosphate ester flame retardants, condensed phosphate ester flame retardants, phosphate flame retardants, inorganic phosphorus flame retardants, dialkylphosphinic acids
- Examples include salts, silicone flame retardants, metal oxides, boric acid compounds, expansive graphite, other inorganic flame retardant aids, and other organic flame retardants.
- triazine ring-containing compound examples include melamine, ammelin, benzguanamine, acetoguanamine, phthalodiguanamine, melamine cyanurate, butylene diguanamine, norbornene diguanamine, methylene diguanamine, ethylene dimelamine, trimethylene dimelamine, tetra Examples include methylene dimelamine, hexamethylene dimelamine, and 1,3-hexylene dimelamine.
- metal hydroxide examples include magnesium hydroxide, aluminum hydroxide, calcium hydroxide, barium hydroxide, zinc hydroxide, Kismer 5A (trademark of magnesium hydroxide manufactured by Kyowa Chemical Industry Co., Ltd.) and the like.
- phosphate ester flame retardant examples include, for example, trimethyl phosphate, triethyl phosphate, tributyl phosphate, tributoxyethyl phosphate, trischloroethyl phosphate, trisdichloropropyl phosphate, triphenyl phosphate, tricresyl phosphate, cresyl diphenyl Phosphate, trixylenyl phosphate, octyl diphenyl phosphate, xylenyl diphenyl phosphate, trisisopropyl phenyl phosphate, 2-ethylhexyl diphenyl phosphate, t-butylphenyl diphenyl phosphate, bis- (t-butylphenyl) phenyl phosphate, tris- (t -Butylphenyl) phosphate, isopropylphenyldiphenylphosphate, bis- (iso
- Examples of the condensed phosphate ester flame retardant include 1,3-phenylene bis (diphenyl phosphate), 1,3-phenylene bis (dixylenyl phosphate), bisphenol A bis (diphenyl phosphate), and the like.
- Examples of the inorganic phosphorus flame retardant include red phosphorus.
- Examples of the dialkyl phosphinate include aluminum diethylphosphinate and zinc diethylphosphinate.
- Examples of the other inorganic flame retardant aids include inorganic compounds such as titanium oxide, aluminum oxide, magnesium oxide, hydrotalcite, and surface-treated products thereof. Specific examples thereof include, for example, TIPAQUE R-680 (trademark of titanium oxide manufactured by Ishihara Sangyo Co., Ltd.), Kyowa Mag 150 (trademark of magnesium oxide manufactured by Kyowa Chemical Industry Co., Ltd.), and DHT-4A (hydrotalcite: Kyowa).
- Various commercial products such as Chemical Industry Co., Ltd., Alkamizer 4 (trademark of zinc-modified hydrotalcite manufactured by Kyowa Chemical Industry Co., Ltd.) can be used.
- the flame retardant composition of the first invention contains a phenolic antioxidant, a phosphorus antioxidant, a thioether antioxidant, an ultraviolet absorber, a hindered amine light stabilizer, an antioxidant, etc., as necessary. May be. These components may be blended in advance in the flame retardant composition of the present invention, or may be blended in the synthetic resin when blended in the synthetic resin. It is preferable to stabilize the synthetic resin by blending these.
- phenolic antioxidant examples include 2,6-ditert-butyl-p-cresol, 2,6-diphenyl-4-octadecyloxyphenol, distearyl (3,5-ditert-butyl-4). -Hydroxybenzyl) phosphonate, 1,6-hexamethylenebis [(3,5-ditert-butyl-4-hydroxyphenyl) propionic acid amide], 4,4'-thiobis (6-tert-butyl-m-cresol ), 2,2′-methylenebis (4-methyl-6-tert-butylphenol), 2,2′-methylenebis (4-ethyl-6-tert-butylphenol), 4,4′-butylidenebis (6-tert-butyl) -M-cresol), 2,2'-ethylidenebis (4,6-ditert-butylphenol), 2,2'-ethylidenebis (4-secondarybutyl-6-tert-butylphenol)
- Examples of the phosphorus antioxidant include trisnonylphenyl phosphite, tris [2-tert-butyl-4- (3-tert-butyl-4-hydroxy-5-methylphenylthio) -5-methylphenyl].
- Phosphite tridecyl phosphite, octyl diphenyl phosphite, di (decyl) monophenyl phosphite, di (tridecyl) pentaerythritol diphosphite, di (nonylphenyl) pentaerythritol diphosphite, bis (2,4-di Tert-butylphenyl) pentaerythritol diphosphite, bis (2,6-ditert-butyl-4-methylphenyl) pentaerythritol diphosphite, bis (2,4,6-tritert-butylphenyl) pentaerythritol diphosphite Phosphite, bis (2,4-dicumylphenyl) pe Taerythritol diphosphite, tetra (tridecyl) isopropylidene diphenol diphosphit
- thioether-based antioxidant examples include dialkylthiodipropionates such as dilauryl thiodipropionate, dimyristyl thiodipropionate, distearyl thiodipropionate, and pentaerythritol tetra ( ⁇ -alkylmercaptopropionate).
- dialkylthiodipropionates such as dilauryl thiodipropionate, dimyristyl thiodipropionate, distearyl thiodipropionate, and pentaerythritol tetra ( ⁇ -alkylmercaptopropionate).
- the amount of these thioether-based antioxidants used is preferably 0.001 to 5% by mass, and 0.05 to 3% by mass in the synthetic resin composition when blended with the synthetic resin. % Is more preferable.
- Examples of the ultraviolet absorber include 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-octoxybenzophenone, and 5,5′-methylenebis (2-hydroxy-4-methoxybenzophenone).
- 2-Hydroxybenzophenones such as 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 2- (2′-hydroxy-3 ′, 5′-ditert-butylphenyl) -5-chloro Benzotriazole, 2- (2′-hydroxy-3′-tert-butyl-5′-methylphenyl) -5-chlorobenzotriazole, 2- (2′-hydroxy-5′-tert.
- Octylphenyl) benzotriazole 2- (2′-hydroxy-3 ′, 5′-dicumylphenyl) benzotriazole, 2,2′-methylenebis 4- (2′-hydroxyphenyl) such as 4-tert-octyl-6- (benzotriazolyl) phenol) and 2- (2′-hydroxy-3′-tert-butyl-5′-carboxyphenyl) benzotriazole )
- Benzotriazoles phenyl salicylate, resorcinol monobenzoate, 2,4-ditert-butylphenyl-3,5-ditert-butyl-4-hydroxybenzoate, 2,4-ditert-amylphenyl-3,5- Benzoates such as di-tert-butyl-4-hydroxybenzoate and hexadecyl-3,5-di-tert-butyl-4-hydroxybenzoate; 2-ethyl-2'-ethoxyoxanilide, 2-eth
- hindered amine light stabilizer examples include 2,2,6,6-tetramethyl-4-piperidyl stearate, 1,2,2,6,6-pentamethyl-4-piperidyl stearate, 2,2, 6,6-tetramethyl-4-piperidylbenzoate, bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis (1,2,2,6,6-tetramethyl-4-piperidyl) Sebacate, bis (1-octoxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate, tetrakis (2,2,6,6-tetramethyl-4-piperidyl) -1,2,3,4 -Butanetetracarboxylate, tetrakis (1,2,2,6,6-pentamethyl-4-piperidyl) -1,2,3,4-butanetetracarboxylate, bis (2,2 , 6,6-tetramethyl-4-piperidyl) -di (tridec
- anti-aging agent examples include naphthylamine, diphenylamine, p-phenyldiamine, quinoline, hydroquinone derivatives, monophenol, thiobisphenol, hindered phenol, and phosphite.
- the amount of these anti-aging agents used is preferably 0.001 to 5% by mass, more preferably 0.05 to 3% by mass in the synthetic resin composition when blended in the synthetic resin. .
- a reinforcing material may be blended as an optional component as long as the effects of the invention are not impaired. These components may be added to the synthetic resin when the flame retardant composition of the first invention is added to the synthetic resin.
- a fibrous, plate-like, granular or powdery material usually used for reinforcing a synthetic resin can be used.
- These reinforcing materials may be coated or focused with a thermoplastic resin such as an ethylene / vinyl acetate copolymer or a thermosetting resin such as an epoxy resin, or with a coupling agent such as aminosilane or epoxysilane. It may be processed.
- a thermoplastic resin such as an ethylene / vinyl acetate copolymer or a thermosetting resin such as an epoxy resin
- a coupling agent such as aminosilane or epoxysilane. It may be processed.
- a crystal nucleating agent may be further blended as an optional component as long as the effects of the invention are not impaired.
- the crystal nucleating agent those generally used as a polymer crystal nucleating agent can be appropriately used.
- an inorganic crystal nucleating agent or an organic crystal nucleating agent can be used. These components may be added to the synthetic resin when the flame retardant composition of the first invention is added to the synthetic resin.
- the inorganic crystal nucleating agent examples include kaolinite, synthetic mica, clay, zeolite, silica, graphite, carbon black, magnesium oxide, titanium oxide, calcium sulfide, boron nitride, calcium carbonate, barium sulfate, aluminum oxide, Mention may be made of metal salts such as neodymium oxide and phenylphosphonate. These inorganic crystal nucleating agents may be modified with an organic substance in order to enhance the dispersibility in the composition.
- organic crystal nucleating agent examples include sodium benzoate, potassium benzoate, lithium benzoate, calcium benzoate, magnesium benzoate, barium benzoate, lithium terephthalate, sodium terephthalate, potassium terephthalate, and oxalic acid.
- the flame retardant composition of the first invention may further contain an acrylic processing aid as an optional component as long as the effects of the present invention are not impaired.
- an acrylic processing aid one obtained by polymerizing one kind of (meth) acrylic acid ester or copolymerizing two or more kinds can be used. These components may be added to the synthetic resin when the flame retardant composition of the present invention is added to the synthetic resin.
- (meth) acrylic acid ester to be polymerized or copolymerized are methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, n-propyl acrylate, isopropyl acrylate, n-propyl methacrylate, isopropyl methacrylate, n-butyl acrylate, isobutyl
- acrylic acid esters such as acrylate, t-butyl methacrylate, n-hexyl acrylate, n-hexyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, dodecyl methacrylate, and tridecyl methacrylate.
- (meth) acrylic acid and (meth) acrylic acid ester containing a hydroxy group are also included.
- a plasticizer may be blended as an optional component as long as the effects of the present invention are not impaired.
- the plasticizer those generally used as polymer plasticizers can be appropriately used.
- polyester plasticizers, glycerin plasticizers, polycarboxylic acid ester plasticizers, polyalkylene glycol plasticizers and epoxies examples thereof include plasticizers.
- plasticizers These components may be added to the synthetic resin when the flame retardant composition of the first invention is added to the synthetic resin.
- additives that are usually used in synthetic resins as necessary, for example, crosslinking agents, antistatic agents, metal soaps, spotting agents, antifogging agents, plate-out prevention Agents, surface treatment agents, fluorescent agents, antifungal agents, bactericides, foaming agents, metal deactivators, mold release agents, pigments, processing aids other than acrylic processing aids, etc., do not impair the effects of the present invention. In a range, it can mix
- These components may be added to the synthetic resin when the flame retardant composition of the first invention is added to the synthetic resin.
- the flame retardant composition of the first invention may be prepared by mixing the components (A) to (D), the component (G) as necessary, and other optional components as necessary. Can be used. You may heat at the time of mixing. Examples of the mixer that can be used include a tumbler mixer, a Henschel mixer, a ribbon blender, a V-type mixer, a W-type mixer, a super mixer, and a Nauta mixer. Next, the second invention will be described. Note that the description in the first invention is applied as appropriate to points that are not particularly described in the second invention.
- the (A) component of the flame retardant composition of the second invention is the same as the melamine salt used as the (A) component in the flame retardant composition of the first invention, and (A) of the flame retardant composition of the first invention.
- the explanation for the components is applied as it is.
- the component (B) of the flame retardant composition of the present invention is the same as the piperazine salt used as the component (B) in the flame retardant composition of the first invention. ) The description of the component is applied as it is.
- the content of the component (A) and the component (B) in the flame retardant composition of the second invention is such that the total of the component (A) and the component (B) is 100 parts by mass, and the component (A) is 20 to 50 masses.
- Component (B) is 50 to 80 parts by mass, preferably component (A) is 30 to 45 parts by mass, and component (B) is 55 to 70 parts by mass.
- the component (E) of the flame retardant composition of the second invention is an aliphatic carboxylic acid ester compound represented by the following general formula (2).
- o represents an integer of 10 to 20
- R 2 represents an alkyl group having 1 to 8 carbon atoms.
- the alkyl group having 1 to 8 carbon atoms represented by R 2 may be a linear alkyl group or a branched alkyl group.
- R 2 is preferably an alkyl group having 2 to 6 carbon atoms, more preferably a butyl group, from the viewpoints of flame retardancy, particularly handling properties and storage stability.
- o is preferably 14 to 20, and more preferably 16, from the viewpoints of flame retardancy, particularly handling properties and storage stability.
- aliphatic carboxylic acid ester compound represented by the general formula (2) of the second invention for example, the following compound No. 23-No. Compounds such as 44.
- the aliphatic carboxylic acid ester compound represented by the general formula (2) of the present invention can be produced by a conventionally known method.
- an aliphatic carboxylic acid having 12 to 22 carbon atoms and an aliphatic alcohol having 1 to 8 carbon atoms may be esterified.
- a commonly used catalyst may be used.
- Examples of the aliphatic carboxylic acid having 12 to 22 carbon atoms used for the production include lauric acid, myristic acid, pentadecanoic acid, palmitic acid, heptadecanoic acid, stearic acid, arachidic acid, and behenic acid.
- the carboxylic acid may be a derivative of an aliphatic carboxylic acid (for example, acid anhydride, alkyl ester, alkali metal salt, acid halide, etc.).
- Examples of aliphatic alcohols having 1 to 8 carbon atoms used in the production include methanol, ethanol, propanol, isopropanol, n-butanol, isobutanol, sec-butanol, tert-butanol, n-amyl alcohol, sec -Amyl alcohol, isoamyl alcohol, tert-amyl alcohol, neopentyl alcohol, hexanol, heptanol, n-octanol, 2-octanol, 2-ethylhexanol and the like.
- the content of the aliphatic carboxylic acid ester compound as the component (E) in the flame retardant composition of the second invention is 0.01 to 1.0.1 with respect to 100 parts by mass in total of the components (A) and (B). 0 parts by mass, preferably from 0.05 to 0.5 parts by mass, more preferably from 0.1 to 0.5 parts by mass, and even more preferably from the viewpoint of flame retardancy, handling properties, and storage stability .1 to 0.3 parts by mass.
- the amount is less than 0.01 parts by mass, dusting cannot be suppressed and handling properties are deteriorated.
- the amount exceeds 1.0 parts by mass the storage stability and flame retardancy are adversely affected.
- the flame retardant powder is prevented from agglomerating, and from the viewpoint of improving storage stability and dispersibility in synthetic resin, silicone oil is further added as component (F). It is preferable to contain.
- silicone oil examples include silicone oils similar to the silicone oil added as necessary in order to improve water resistance and the like in the first invention.
- methyl hydrogen silicone oil is preferable from the viewpoints of preventing aggregation of the flame retardant powder, improving storage stability, and improving dispersibility in the synthetic resin.
- the content of the silicone oil of the component (F) in the flame retardant composition of the second invention is such that the flame retardant and the flame retardant powder are aggregated with respect to 100 parts by mass in total of the components (A) and (B).
- 0.01 to 5.0 parts by mass is preferable, 0.05 to 3.0 parts by mass is more preferable, and 0 More preferably, it is 1 to 2.0 parts by mass.
- the flame retardant composition of the second invention preferably contains zinc oxide as a flame retardant aid as the component (G).
- the component (G) is the same as the component (G) of the flame retardant composition of the first invention, and the description of the component (G) of the flame retardant composition of the first invention is applied as it is.
- the content of the zinc oxide as the component (G) in the flame retardant composition of the second invention is 0.01% from the viewpoint of flame retardancy with respect to 100 parts by mass of the components (A) and (B). Is preferably 10 to 10 parts by mass, more preferably 0.5 to 10 parts by mass, and still more preferably 1.0 to 7.5 parts by mass.
- the flame retardant composition of the second invention may be blended with a drip inhibitor similar to that of the flame retardant composition of the first invention, if necessary, as long as the effects of the present invention are not impaired.
- the anti-drip agent similar to the flame retardant composition of the invention can be preferably used.
- the content of the anti-drip agent is preferably 0.005 to 5 parts by mass, more preferably 0.005 parts by mass with respect to 100 parts by mass as a total of the components (A) and (B).
- the amount is from 01 to 5 parts by mass, more preferably from 0.05 to 3 parts by mass, still more preferably from 0.1 to 1 part by mass. If it is less than 0.005 parts by mass, the drip prevention effect is not sufficient, and if it exceeds 5 parts by mass, the resin properties may be lowered.
- the flame retardant composition of the second invention includes a polyhydric alcohol compound similar to that of the flame retardant composition of the first invention as a flame retardant aid as necessary within a range not impairing the effects of the present invention.
- a polyhydric alcohol compound similar to the flame retardant composition of the first invention may be preferably used.
- the content is preferably 0.5 to 15 parts by mass, more preferably 2 to 2 parts per 100 parts by mass in total of the components (A) and (B).
- the amount is 12 parts by mass, and more preferably 5 to 10 parts by mass.
- the content is preferably 0.05 to 10 parts by mass, more preferably 0.1 to 5 parts per 100 parts by mass in total of the component (A) and the component (B). Mass.
- the flame retardant composition of the second invention may further contain a hydrotalcite compound from the viewpoint of heat resistance, reduction of the corrosion risk of the processing machine, and weather resistance.
- the hydrotalcite compound refers to a carbonate and double carbonate compound of magnesium and / or zinc and aluminum.
- the hydrotalcite-based compound may be a natural product or a synthetic product. Examples of synthetic methods for synthetic products include known methods described in JP-B-46-2280, JP-B-50-30039, JP-B 51-29129, JP-A-61-174270, and the like. be able to.
- the hydrotalcite compound can be used without being limited by the crystal structure, the crystal particle system, the presence or absence of crystal water, the amount thereof, and the like.
- the hydrotalcite compound can also be treated with perchloric acid, and its surface is treated with a higher fatty acid such as stearic acid, a higher fatty acid metal salt such as an alkali metal oleate, or an organic sulfone such as an alkali metal dodecylbenzenesulfonate.
- a higher fatty acid such as stearic acid
- a higher fatty acid metal salt such as an alkali metal oleate
- an organic sulfone such as an alkali metal dodecylbenzenesulfonate.
- Those coated with acid metal salts, higher fatty acid amides, higher fatty acid esters or waxes can also be used.
- the compound represented by following General formula (3) is preferable.
- x1 and x2 each represent a number that satisfies the condition represented by the following formula, and m represents a real number. 0 ⁇ x2 / x1 ⁇ 10, 2 ⁇ x1 + x2 ⁇ 20)
- hydrotalcite-based compounds Commercially available products can be used as the above hydrotalcite-based compounds.
- DHT-4 hydrotalcite: manufactured by Kyowa Chemical Industry Co., Ltd.
- DHT-4A hydrotalcite: Kyowa Chemical Industry Co., Ltd.
- Magella-1 Hydrotalcite: manufactured by Kyowa Chemical Industry Co., Ltd.
- Alkamizer 1 Hydrokrotalcite: manufactured by Kyowa Chemical Industry Co., Ltd.
- Alkamizer 2 Hadrotalcite: Kyowa Chemical Industry Co., Ltd.
- Alkamizer 4 Alkamizer P-93) (Zinc-modified hydrotalcite: manufactured by Kyowa Chemical Industry Co., Ltd.)
- Alkamizer 7 Zinc-modified hydrotalcite: manufactured by Kyowa Chemical Industry Co., Ltd.
- Alkamizer 5 perchloric acid-treated hydrotalcite: manufactured by Kyowa Chemical Industry Co., Ltd.
- DHT-4A hydrotalcite: Chemical Industries Co.
- the content of the hydrotalcite compound in the flame retardant composition of the second invention is preferably 0.01 to 5 parts by mass with respect to 100 parts by mass in total of the component (A) and the component (B). From the viewpoint of the property, the corrosion risk reduction of the processing machine, and the weather resistance, it is more preferably 0.05 to 4 parts by mass, and still more preferably 0.1 to 2 parts by mass.
- the flame retardant powder is prevented from agglomerating within a range not impairing the effects of the invention, to improve storage stability, and to impart water resistance and heat resistance.
- the silane coupling agent similar to the component (C) of the flame retardant composition of the first invention may be blended, and among them, the flame retardant powder is prevented from agglomerating, improving the storage stability, water resistance and heat resistance.
- a silane coupling agent having an epoxy group is preferred.
- the commercial item similar to (C) component of the flame retardant composition of 1st invention can be used.
- the content thereof is preferably 0.01 to 5 with respect to 100 parts by mass in total of the component (A) and the component (B). 0.0 part by mass, more preferably 0.05 to 3.0 parts by mass, and still more preferably 0.1 to 2.0 parts by mass.
- one or more organic or inorganic flame retardants or flame retardant aids that do not contain halogen are further used as necessary within the range not impairing the effects of the present invention. be able to.
- these flame retardants and flame retardant aids the same triazine ring-containing compound, metal hydroxide, phosphate ester flame retardant, condensed phosphate ester flame retardant, phosphate flame retardant as the flame retardant composition of the first invention
- the same phenol-based antioxidant, phosphorus-based antioxidant, thioether-based antioxidant, ultraviolet absorber, hindered amine as the flame retardant composition of the first invention You may mix
- the amount used is preferably 0.001 to 5% by mass, and 0.05 to 3% by mass in the synthetic resin composition when blended with the synthetic resin. It is more preferable that When the phosphorus-based antioxidant is used, the amount used is preferably 0.001 to 5% by mass, and 0.05 to 3% by mass in the synthetic resin composition when blended with the synthetic resin. It is more preferable that When the thioether-based antioxidant is used, the amount used is preferably 0.001 to 5% by mass, and 0.05 to 3% by mass in the synthetic resin composition when blended with the synthetic resin.
- the amount used is preferably 0.001 to 5% by mass, and 0.05 to 3% by mass in the synthetic resin composition when blended with the synthetic resin. It is more preferable.
- the amount used is preferably 0.001 to 5% by mass, and 0.05 to 3% by mass in the synthetic resin composition when blended with the synthetic resin. It is more preferable that When the anti-aging agent is used, the amount used is preferably 0.001 to 5% by mass, and 0.05 to 3% by mass in the synthetic resin composition when blended with the synthetic resin. It is more preferable.
- a reinforcing material, a crystal nucleating agent, and a plasticizer similar to those of the flame retardant composition of the first invention may be used as optional components as long as the effects of the invention are not impaired. These components may be added to the synthetic resin when the flame retardant composition of the second invention is added to the synthetic resin.
- additives that are usually used in synthetic resins as necessary, for example, crosslinking agents, antistatic agents, metal soaps, spotting agents, This includes fogging agents, plate-out prevention agents, surface treatment agents, fluorescent agents, antifungal agents, bactericides, foaming agents, metal deactivators, mold release agents, pigments, processing aids other than acrylic processing aids, etc. It can mix
- additives that are usually used in synthetic resins as necessary, for example, crosslinking agents, antistatic agents, metal soaps, spotting agents, This includes fogging agents, plate-out prevention agents, surface treatment agents, fluorescent agents, antifungal agents, bactericides, foaming agents, metal deactivators, mold release agents, pigments, processing aids other than acrylic processing aids, etc. It can mix
- These components may be added to the synthetic resin when the flame retardant composition of the present invention is added to the synthetic resin.
- Other arbitrary components may be mixed, and various mixers can be used for mixing. You may heat at the time of mixing. Examples of the mixer that can be used include a tumbler mixer, a Henschel mixer, a ribbon blender, a V-type mixer, a W-type mixer, a super mixer, and a Nauta mixer.
- the above-described flame retardant compositions of the first and second inventions are effective for making a synthetic resin flame retardant, and are blended with a synthetic resin to produce a flame retardant synthetic resin composition (a flame retardant synthetic of the third invention). It is also preferably used as a resin composition).
- a flame retardant synthetic resin composition a flame retardant synthetic of the third invention. It is also preferably used as a resin composition.
- the third invention relates to a flame retardant synthetic resin composition, which is a synthetic resin composition flame-retarded by the synthetic resin and the flame retardant composition of the first invention or the second invention described above.
- the molded product of the fourth invention is a molded product obtained by molding the flame-retardant synthetic resin composition of the third invention.
- the flame retardance in 3rd invention is synonymous with 1st invention or 2nd invention.
- specific examples of the synthetic resin flame-retarded by the flame retardant composition of the first invention or the second invention include polypropylene, high-density polyethylene, low-density polyethylene, ⁇ -olefin polymers such as linear low density polyethylene, crosslinked polyethylene, ultrahigh molecular weight polyethylene, polybutene-1, poly-3-methylpentene, etc., ethylene-vinyl acetate copolymers, ethylene-ethyl acrylate copolymers, ethylene- Polyolefins such as propylene copolymer and copolymers thereof, polyvinyl chloride, polyvinylidene chloride, chlorinated polyethylene, chlorinated polypropylene, polyvinylidene fluoride, chlorinated rubber, vinyl chloride-vinyl acetate copolymer, vinyl chloride-ethylene Copolymer, vinyl chloride-vinylidene chloride copolymer, vinyl chloride
- Aromatic polyester such as polyalkylene naphthalate and linear polyester such as polytetramethylene terephthalate; polyhydroxybutyrate, poly Degradable aliphatic polyesters such as caprolactone, polybutylene succinate, polyethylene succinate, polylactic acid resin, polymalic acid, polyglycolic acid, polydioxane, poly (2-oxetanone); polyphenylene oxide, polycaprolactam and polyhexamethylene adipa Polyamides such as amides, polycarbonates, branched polycarbonates, polyacetals, polyphenylene sulfides, polyurethanes, thermoplastic resins such as fiber-based resins and blends thereof, phenol resins, urea resins, melamine resins, epoxy resins, unsaturated polyester resins, etc.
- Polyamides such as amides, polycarbonates, branched polycarbonates, polyacetals, polyphenylene sulfides, polyurethanes, thermoplastic
- Thermosetting resin, fluorine resin, silicone resin, silicone rubber polyethersulfone, polysulfone, polyphenylene ether, polyether ketone, polyether Teruketon, is a liquid crystal polymer or the like. Further examples include isoprene rubber, butadiene rubber, acrylonitrile-butadiene copolymer rubber, styrene-butadiene copolymer rubber, fluorine rubber, and silicone rubber.
- the flame retardant synthetic resin examples include olefin thermoplastic elastomer, styrene thermoplastic elastomer, polyester thermoplastic elastomer, nitrile thermoplastic elastomer, nylon thermoplastic elastomer, vinyl chloride thermoplastic elastomer. , Polyamide-based thermoplastic elastomers, polyurethane-based thermoplastic elastomers, and the like.
- These synthetic resins may be used alone or in combination of two or more.
- the synthetic resin may be alloyed.
- the synthetic resin used in the third invention is molecular weight, degree of polymerization, density, softening point, ratio of insoluble matter in solvent, degree of stereoregularity, presence or absence of catalyst residue, type and blending ratio of monomer as raw material, polymerization Regardless of the type of catalyst (eg, Ziegler catalyst, metallocene catalyst, etc.), it can be used.
- polyolefin resins are preferable from the viewpoint that excellent flame retardancy can be imparted.
- polystyrene resins examples include, for example, polyethylene, low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, homopolypropylene, random copolymer polypropylene, block copolymer polypropylene, impact copolymer polypropylene, and high impact copolymer.
- Polypropylene isotactic polypropylene, syndiotactic polypropylene, hemiisotactic polypropylene, maleic anhydride modified polypropylene, polybutene, cycloolefin polymer, stereoblock polypropylene, poly-3-methyl-1-butene, poly-3-methyl- ⁇ -olefin polymers such as 1-pentene and poly-4-methyl-1-pentene, ethylene / propylene block or Random copolymer, ethylene - methyl methacrylate copolymer, ethylene - alpha-olefin copolymer such as vinyl acetate copolymer.
- the content of the synthetic resin is preferably 40% by mass or more and less than 90% by mass, preferably 50% by mass or more and less than 80% by mass, and 55% by mass. % Or more and less than 75% by mass.
- the content of the flame retardant composition of the first invention or the second invention is preferably 10% by mass or more and less than 60% by mass and preferably 20% by mass or more and less than 50% by mass from the viewpoint of flame retardancy. More preferably, it is more preferably 25% by mass or more and less than 45% by mass.
- the content of the synthetic resin is 90% by mass or more, or the content of the flame retardant composition of the first invention or the second invention is less than 10% by mass, sufficient flame retardancy may not be exhibited, and the synthetic resin If the content of is less than 40 mass or the content of the flame retardant composition of the first invention or the second invention is 60 mass% or more, the original physical properties of the resin may be impaired.
- the flame-retardant synthetic resin composition of the third invention can be molded to obtain a molded article excellent in flame retardancy (the molded article of the fourth invention).
- the molding method is not particularly limited, and examples thereof include extrusion processing, calendar processing, injection molding, roll, compression molding, blow molding, and the like, and molded products having various shapes such as resin plates, sheets, films, and irregular shaped products. Can be manufactured.
- the flame-retardant synthetic resin composition of the third invention can be used for housings (frames, housings, covers, exteriors) and parts of automobiles, machines, electrical / electronic devices, OA devices, automotive interior and exterior materials, Used for applications that require the UL-94V standard, preferably the UL94 5VA standard.
- the flame-retardant synthetic resin composition of the third invention and the molded product of the fourth invention obtained by molding the composition are electric / electronic / communication, agriculture, forestry and fisheries, mining, construction, food, textile, clothing, medical care, coal, It can be used in a wide range of industrial fields such as petroleum, rubber, leather, automobiles, precision equipment, wood, building materials, civil engineering, furniture, printing, and musical instruments. More specifically, printers, personal computers, word processors, keyboards, PDAs (small information terminals), telephones, copiers, facsimiles, ECRs (electronic cash registers), calculators, electronic notebooks, cards, holders, stationery, etc.
- AV equipment such as liquid crystal displays, connectors, relays, capacitors, switches, printed boards, coil bobbins, semiconductor sealing materials, LED sealing materials, electric wires, cables, transformers, deflection yokes, distribution boards, watches, etc.
- housings frames, housings, covers, exteriors
- the flame-retardant synthetic resin composition of the third invention, the flame-retardant synthetic resin composition of the fourth invention obtained by molding the composition, and the molded body thereof are a seat (filling, outer material, etc.), belt, ceiling covering , Compatible top, armrest, door trim, rear package tray, carpet, mat, sun visor, foil cover, mattress cover, airbag, insulation, suspension hand, suspension band, wire covering material, electrical insulation, paint, coating material , Upholstery materials, flooring materials, corner walls, carpets, wallpaper, wall covering materials, exterior materials, interior materials, roofing materials, deck materials, wall materials, pillar materials, slabs, eaves materials, frames and forms, windows and Materials for automobiles, hybrid cars, electric cars, vehicles, ships, airplanes, buildings, houses and construction, and earth and wood, such as door profiles, slabs, slabs, terraces, balconies, sound insulation boards, heat insulation boards, window materials, etc.
- Clothing curtains, sheets, plywood, synthetic fibers, carpets, doormats, sheets, buckets, hoses, containers, glasses, bags, cases, goggles, skis, rackets, tents, musical instruments, etc., sports equipment, etc. Used for various purposes.
- Examples 1 to 9 and Comparative Examples 1 to 7 are examples of the flame retardant composition of the first invention and comparative examples thereof, and Examples 10 to 20 and Comparative Example 8 are examples.
- -17 are examples of the flame retardant synthetic resin composition of the third invention using the flame retardant composition of the first invention and comparative examples thereof.
- Examples 21 to 29 and Comparative Examples 18 to 26 are examples of the flame retardant composition of the second invention and comparative examples thereof.
- Examples 30 to 40 and Comparative Examples 27 to 36 are difficult examples of the second invention. It is an Example of the flame-retardant synthetic resin composition of 3rd invention using a flame retardant composition, and its comparative example.
- Examples 1 to 9 and Comparative Examples 1 to 7 The components shown in Table 1 were mixed for 20 minutes using a Henschel mixer at a rotation speed of 1500 rpm / minute to prepare flame retardant composition powders of Examples 1 to 9.
- the aliphatic dicarboxylic acid ether ester compound represented by the general formula (1) as the component (D) is a compound No. 1 having the following structure. 1 was used.
- flame retardant composition powders of Comparative Examples 1 to 7 were prepared with the formulations shown in Table 2.
- the comparative example which used silicone oil, and the compound No. of (D) component of an Example in order to compare with the silane coupling agent of (C) component of an Example, the comparative example which used silicone oil, and the compound No. of (D) component of an Example.
- a comparative example using glycerin monostearate was performed to compare with 1.
- the dust property was measured using a powder physical property measuring instrument, trade name Multi Tester MT-1001, manufactured by Seishin Corporation.
- 10 g of the flame retardant composition powder obtained above was spontaneously dropped from the upper part of the cylinder of the measuring instrument onto a tray having a diameter of 10 cm, which is 60 cm below.
- the weight of the flame retardant composition powder on the saucer was measured, and the weight of the flame retardant composition powder scattered outside the saucer was calculated by subtracting the weight from 10 g. It can be said that the smaller the weight of the scattered powder, the less dusting and the better the handling property.
- the measurement was performed three times, and the average values are shown in Tables 1 and 2.
- ⁇ Storage stability test method First, the particle size distribution of the flame retardant composition powder obtained above was measured with a Microtrac particle size distribution meter (MT-3000II manufactured by Nikkiso Co., Ltd.). Next, 30g of the flame retardant composition powder is placed in an aluminum bag 13cm in length and 6cm in width, and left in an oven at 50 ° C for 30 days under a pressure of 58g / cm 2 from the top of the aluminum bag for stable storage. A sex test was performed. After 30 days, the flame retardant composition powder in the aluminum bag was taken out, and the particle size distribution was measured with a Microtrac particle size distribution meter.
- MT-3000II manufactured by Nikkiso Co., Ltd.
- Table 1 and Table 2 show the particle size (D 50 ) with an integrated value of 50% before and after the test, and the increase / decrease value of the particle size.
- D 50 particle size
- Table 1 and Table 2 show the particle size (D 50 ) with an integrated value of 50% before and after the test, and the increase / decrease value of the particle size.
- a larger value of the particle size indicates that the particles adhere to each other and are caking. It can be said that the smaller the change in particle size, the better the storage stability.
- the flame retardant composition obtained in Examples 1 to 9 was added at the blending ratio (mass%) shown in Table 3, and Example 10 was added.
- flame retardant synthetic resin compositions Up to 20 flame retardant synthetic resin compositions were obtained. Incidentally, in the flame retardant composition, the flame retardant composition obtained in Example 1 was designated as flame retardant composition-1, the flame retardant composition obtained in Example 2 was designated as flame retardant composition-2, and the same in the following manner. The flame retardant composition up to 9 obtained in Example 9 was used.
- Comparative Flame retardant Composition-1 the flame retardant composition obtained in Comparative Example 2 is referred to as Comparative Flame retardant Composition-2, and the following comparative flame retardant composition.
- the flame-retardant synthetic resin compositions of Comparative Examples 8 to 17 were obtained using the product No. 7 at the blending ratio (mass%) shown in Table 4.
- the obtained flame-retardant synthetic resin composition was extruded at 200 to 230 ° C. to produce pellets, which were used for injection molding at 200 ° C., having a length of 127 mm, a width of 12.7 mm, and a thickness of 1.6 mm. A specimen was obtained. Using this test piece, a UL-94V test was conducted as a flame retardancy test by the following test method. The results are shown in Tables 3 and 4.
- ⁇ Flame Retardant UL-94V Test Method> The test piece of 127mm in length, 12.7mm in width and 1.6mm in thickness is kept vertical, the flame of the burner is removed at the lower end after indirect flame for 10 seconds, and the time when the fire ignited on the test piece is extinguished. It was measured. Next, at the same time when the fire was extinguished, the second flame contact was performed for 10 seconds, and the time when the ignited fire was extinguished was measured in the same manner as the first time. Moreover, it was also evaluated at the same time whether or not the cotton under the test piece was ignited by the falling fire type.
- Combustion ranks were assigned according to the UL-94V standard from the first and second combustion times, the presence or absence of cotton ignition, and the like.
- the combustion rank is V-0, and the flame retardance decreases as V-1 and V-2 are reached.
- those not corresponding to any of the ranks V-0 to V-2 are NR.
- Example 21 to 29 and Comparative Examples 18 to 26 The ingredients shown in Table 5 were mixed using a Henschel mixer at a rotation speed of 1500 rpm for 20 minutes to prepare flame retardant composition powders of Examples 21 to 29.
- the aliphatic carboxylic acid ester compound represented by the general formula (2) as the component (E) is a compound No. 1 having the following structure. 23 was used.
- flame retardant composition powders of Comparative Examples 18 to 26 were prepared with the formulations shown in Table 6.
- a comparative example using glycerin monostearate was also performed in order to compare with the aliphatic carboxylic acid ester compound of the component (E) in the examples.
- the dust property was measured using a powder physical property measuring instrument, trade name Multi Tester MT-1001, manufactured by Seishin Corporation.
- 10 g of the flame retardant composition powder obtained above was spontaneously dropped from the upper part of the cylinder of the measuring instrument onto a tray having a diameter of 10 cm, which is 60 cm below.
- the weight of the flame retardant composition powder on the saucer was measured, and the weight of the flame retardant composition powder scattered outside the saucer was calculated by subtracting the weight from 10 g. It can be said that the smaller the weight of the scattered powder, the less dusting and the better the handling property.
- the measurement was performed three times, and the average values are shown in Tables 5 and 6.
- ⁇ Storage stability test method First, the particle size distribution of the flame retardant composition powder obtained above was measured with a Microtrac particle size distribution meter (MT-3000II manufactured by Nikkiso Co., Ltd.). Next, 30g of the flame retardant composition powder is placed in an aluminum bag 13cm in length and 6cm in width, and left in an oven at 50 ° C for 30 days under a pressure of 58g / cm 2 from the top of the aluminum bag for stable storage. A sex test was performed. After 30 days, the flame retardant composition powder in the aluminum bag was taken out, and the particle size distribution was measured with a Microtrac particle size distribution meter.
- MT-3000II manufactured by Nikkiso Co., Ltd.
- Table 1 and Table 2 show the particle size (D 50 ) with an integrated value of 50% before and after the test, and the increase / decrease value of the particle size.
- D 50 particle size
- Table 1 and Table 2 show the particle size (D 50 ) with an integrated value of 50% before and after the test, and the increase / decrease value of the particle size.
- a larger value of the particle size indicates that the particles adhere to each other and are caking. It can be said that the smaller the change in particle size, the better the storage stability.
- Example 30 was carried out by adding the flame retardant compositions obtained in Examples 21 to 29 in the proportions (mass%) shown in Table 7 to the polypropylene resin composition obtained by blending 3 parts by mass.
- flame retardant synthetic resin compositions Up to 40 flame retardant synthetic resin compositions were obtained. Incidentally, in the flame retardant composition, the flame retardant composition obtained in Example 21 was designated as flame retardant composition-10, the flame retardant composition obtained in Example 22 was designated as flame retardant composition-11, and so on. The flame retardant composition obtained in Example 29 was used as the flame retardant composition-18.
- Comparative Flame retardant Composition-8 the flame retardant composition obtained in Comparative Example 19 is referred to as Comparative Flame retardant Composition-9, and the following is similarly performed.
- flame retardant compositions-16 flame retardant synthetic resin compositions of Comparative Examples 27 to 36 were obtained at the blending ratios (mass%) shown in Table 8.
- the obtained flame-retardant synthetic resin composition was extruded at 200 to 230 ° C. to produce pellets, which were used for injection molding at 200 ° C., having a length of 127 mm, a width of 12.7 mm, and a thickness of 1.6 mm. A specimen was obtained. Using this test piece, a UL-94V test was conducted as a flame retardancy test by the following test method. The results are shown in Tables 7 and 8.
- ⁇ Flame Retardant UL-94V Test Method> The test piece of 127mm in length, 12.7mm in width and 1.6mm in thickness is kept vertical, the flame of the burner is removed at the lower end after indirect flame for 10 seconds, and the time when the fire ignited on the test piece is extinguished. It was measured. Next, at the same time when the fire was extinguished, the second flame contact was performed for 10 seconds, and the time when the ignited fire was extinguished was measured in the same manner as the first time. Moreover, it was also evaluated at the same time whether or not the cotton under the test piece was ignited by the falling fire type.
- Combustion ranks were assigned according to the UL-94V standard from the first and second combustion times, the presence or absence of cotton ignition, and the like.
- the combustion rank is V-0, and the flame retardance decreases as V-1 and V-2 are reached.
- those not corresponding to any of the ranks V-0 to V-2 are NR.
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Abstract
Description
さらに、このイントメッセント系難燃剤の、粉体特性や加工性、樹脂に配合した場合の樹脂物性を改良するために、高級脂肪族カルボン酸エステル等の添加や、シリコーンオイルやシランカップリング剤の添加等が提案されている。(特許文献2~4)
しかしながらこれら従来のイントメッセント系難燃剤は、使用時に粉立ちを発生する等、そのハンドリング性が充分に解決されておらず、また粉立ちを改善できても保存時にケーキング等が発生し保存安定性に問題が生じたり、さらには難燃性にも悪影響を及ぼす問題があった。そのため、粉立ち等が少なくハンドリング性に優れ、ケーキング等を生じず保存安定性に優れ、優れた難燃性を有する難燃剤が必要とされていた。
すなわち本発明は、第1発明として、下記(A)成分を20~50質量部、下記(B)成分を50~80質量部(但し(A)成分と(B)成分の合計は100質量部)、下記(C)成分を0.01~5.0質量部及び下記(D)成分を0.01~1.0質量部含有する難燃剤組成物を提供するものである。
(A)成分:オルトリン酸メラミン、ピロリン酸メラミン、ポリリン酸メラミンの群から、1種以上選択されるメラミン塩
(B)成分:オルトリン酸ピペラジン、ピロリン酸ピペラジン、ポリリン酸ピペラジンの群から、1種以上選択されるピペラジン塩
(C)成分:シランカップリング剤
(D)成分:下記一般式(1)で表される脂肪族ジカルボン酸エーテルエステル化合物
(A)成分:オルトリン酸メラミン、ピロリン酸メラミン、ポリリン酸メラミンの群から、1種以上選択されるメラミン塩
(B)成分:オルトリン酸ピペラジン、ピロリン酸ピペラジン、ポリリン酸ピペラジンの群から、1種以上選択されるピペラジン塩
(E)成分:下記一般式(2)で表される脂肪族カルボン酸エステル化合物
第1発明及び第2発明は、難燃剤組成物に係るものである。第1発明及び第2発明において、難燃性とは、物質が着火しにくく、また着火して燃焼が持続してもその速度が非常に遅かったり、その後、自己消火したりする性質であること、好ましくは実施例に記載されているUL-94V規格に従った燃焼ランクのうち、少なくともV-2のランクを有することを意味し、難燃剤組成物とは、難燃剤の1種以上を含有する組成物を意味する。
先ず、第1発明について説明する。
これらリン酸とメラミンとの塩は、それぞれ対応するリン酸又はリン酸塩とメラミンを反応させることによって得ることもできるが、(A)成分で使用されるメラミン塩は、オルトリン酸1メラミンを加熱縮合させて得られたピロリン酸メラミン又はポリリン酸メラミンが好ましく、特にピロリン酸メラミンが好ましい。
これらリン酸とピペラジンの塩は、それぞれ対応するリン酸又はリン酸塩とピペラジンを反応させることで得ることもできるが、(B)成分で使用されるピペラジン塩は、2オルトリン酸1ピペラジンを加熱縮合させて得られたピロリン酸ピペラジン又はポリリン酸ピペラジンが好ましく、特にピロリン酸ピペラジンが好ましい。
本発明では、(C)成分としてシランカップリング剤を使用する。
シランカップリング剤としては、例えば、アルケニル基を有するシランカップリング剤として、ビニルトリメトキシシラン、ビニルトリエトキシシラン、ビニルトリアセトキシシラン、ビニルトリス(2-メトキシエトキシ)シラン、ビニルメチルジメトキシシラン、オクテニルトリメトキシシラン、アリルトリメトキシシラン、p-スチリルトリメトキシシラン等が挙げられ、アクリル基を有するシランカップリング剤として、3-アクリロキシプロピルトリメトキシシラン、3-アクリロキシプロピルトリエトキシシラン等が挙げられ、メタクリル基を有するシランカップリング剤として、3-メタクリロキシプロピルメチルジメトキシシラン、3-メタクリロキシプロピルトリメトキシシラン、3-メタクリロキシプロピルメチルジエトキシシラン、3-メタクリロキシプロピルトリエトキシシラン、メタクリロキシオクチルトリメトキシシラン等が挙げられ、エポキシ基を有するシランカップリング剤として、2-(3,4-エポキシシクロヘキシル)エチルトリメトキシシラン、3-グリシドキシプロピルメチルジメトキシシラン、3-グリシドキシプロピルトリメトキシシラン、3-グリシドキシプロピルメチルジエトキシシラン、3-グリシドキシプロピルトリエトキシシラン、グリシドキシオクチルトリメトキシシラン等が挙げられ、アミノ基を有するシランカップリング剤として、N-2-(アミノエチル)-3-アミノプロピルメチルジメトキシシラン、N-2-(アミノエチル)-3-アミノプロピルトリメトキシシラン、3-アミノプロピルトリメトキシシラン、3-アミノプロピルトリエトキシシラン、3-トリエトキシシリル-N-(1,3-ジメチル-ブチリデン)プロピルアミン、N-フェニル-3-アミノプロピルトリメトキシシラン、N,N’-ビス[3-(トリメトキシシリル)プロピル]エチレンジアミン、N-(ビニルベンジル)-2-アミノエチル-3-アミノプロピルトリメトキシシランの塩酸塩等が挙げられ、イソシアヌレート基を有するシランカップリング剤として、トリス-(トリメトキシシリルプロピル)イソシアヌレートが挙げられ、メルカプト基を有するシランカップリング剤として、3-メルカプトプロピルメチルジメトキシシラン、3-メルカプトプロピルトリメトキシシラン、3-メルカプトプロピルトリエトキシシラン等が挙げられ、ウレイド基を有するシランカップリング剤として、3-ウレイドプロピルトリメトキシシラン、3-ウレイドプロピルトリエトキシシラン等が挙げられ、スルフィド基を有するシランカップリング剤として、ビス(トリエトキシシリルプロピル)テトラスルフィドが挙げられ、チオエステル基を有するシランカップリング剤として、3-オクタノイルチオ-1-プロピルトリエトキシシランが挙げられ、イソシアネート基を有するシランカップリング剤として、3-イソシアネートプロピルトリエトキシシラン、3-イソシアネートプロピルトリメトキシシラン等が挙げられる。
これらシランカップリング剤の中でも、難燃性、ハンドリング性、さらには難燃剤粉末の凝集を防止し、保存安定性向上の点から、エポキシ基を有するシランカップリング剤が好ましく、2-(3,4-エポキシシクロヘキシル)エチルトリメトキシシラン、3-グリシドキシプロピルメチルジメトキシシラン、3-グリシドキシプロピルトリメトキシシラン、3-グリシドキシプロピルメチルジエトキシシラン、3-グリシドキシプロピルトリエトキシシラン、グリシドキシオクチルトリメトキシシランがより好ましい。
第1発明の難燃剤組成物の(D)成分は、下記一般式(1)で表される脂肪族ジカルボン酸エーテルエステル化合物である。
上記一般式(1)において、難燃性と、特にハンドリング性と保存安定性の点から、nは4が好ましい。また上記一般式(1)において、難燃性と、特にハンドリング性と保存安定性の点から、mは2が好ましい。
その製造方法の例を挙げると、炭素原子数4~8の脂肪族ジカルボン酸と、アルキル基の炭素原子数1~6の、ジエチレングリコールモノアルキルエーテル又はエチレングリコールモノアルキルエーテル又はトリエチレングリコールモノアルキルエーテルとを、エステル化反応すればよい。エステル化反応には、通常使用される触媒を使用してもよい。
例えば、上記化合物No.1を製造する場合は、1molのアジピン酸と2molのジエチレングリコールモノブチルエーテルをエステル化反応させることで得ることができる。
上記無機リン系難燃剤としては、赤リンが挙げられる。
上記ジアルキルホスフィン酸塩としては、ジエチルホスフィン酸アルミニウム、ジエチルホスフィン酸亜鉛等が挙げられる。
次に、第2発明について説明する。尚、第2発明において特に説明しない点については、第1発明における説明が適宜適用される。
また、本発明の難燃剤組成物の(B)成分は、第1発明の難燃剤組成物で(B)成分として用いられるピペラジン塩と同様であり、第1発明の難燃剤組成物の(B)成分における説明がそのまま適用される。
第2発明の難燃剤組成物の(E)成分は、下記一般式(2)で表される脂肪族カルボン酸エステル化合物である。
上記一般式(2)において、難燃性と、特にハンドリング性と保存安定性の点から、oは14~20が好ましく、16がより好ましい。
その製造方法の例を挙げると、炭素原子数12~22の脂肪族カルボン酸と、炭素原子数1~8の脂肪族アルコールとを、エステル化反応すればよい。エステル化反応には、通常使用される触媒を使用してもよい。
第2発明の難燃剤組成物中の(G)成分の酸化亜鉛の含有量は、(A)成分と(B)成分の合計100質量部に対して、難燃性の点から、0.01~10質量部が好ましく、より好ましくは0.5~10質量部、さらにより好ましくは1.0~7.5質量部である。
上記ドリップ防止剤を含有させる場合のドリップ防止剤の含有量は、(A)成分と(B)成分の合計100質量部に対して、0.005~5質量部が好ましく、より好ましくは0.01~5質量部、より好ましくは0.05~3質量部、さらに好ましくは0.1~1質量部である。0.005質量部未満だとドリップ防止効果が十分ではなく、5質量部を超えると樹脂の特性を低下させる場合がある。
上記の多価アルコール化合物を含有させる場合の含有量は、(A)成分と(B)成分の合計100質量部に対して、好ましくは0.5~15質量部であり、より好ましくは2~12質量部であり、更に好ましくは5~10質量部である。
上記の滑剤を含有させる場合の含有量は、(A)成分と(B)成分の合計100質量部に対して、好ましくは0.05~10質量部であり、より好ましくは0.1~5質量である。
(式中、x1及びx2は各々下記式で表される条件を満たす数を示し、mは実数を示す。0≦x2/x1<10、2≦x1+x2<20)
上記リン系酸化防止剤を使用する場合、その使用量は、合成樹脂に配合したときに、合成樹脂組成物中、0.001~5質量%であることが好ましく、0.05~3質量%であることがより好ましい。
上記チオエーテル系酸化防止剤を使用する場合、その使用量は、合成樹脂に配合したときに、合成樹脂組成物中、0.001~5質量%であることが好ましく、0.05~3質量%であることがより好ましい。
上記紫外線吸収剤を使用する場合、その使用量は、合成樹脂に配合したときに、合成樹脂組成物中、0.001~5質量%であることが好ましく、0.05~3質量%であることがより好ましい。
上記ヒンダードアミン系光安定剤を使用する場合、その使用量は、合成樹脂に配合したときに、合成樹脂組成物中、0.001~5質量%であることが好ましく、0.05~3質量%であることがより好ましい。
上記老化防止剤を使用する場合、その使用量は、合成樹脂に配合したときに、合成樹脂組成物中、0.001~5質量%であることが好ましく、0.05~3質量%であることがより好ましい。
次に、第3発明及び第4発明について説明する。尚、第3発明及び第4発明において特に説明しない点については、第1発明又は第2発明における説明が適宜適用される。
第3発明で使用する合成樹脂は、分子量、重合度、密度、軟化点、溶媒への不溶分の割合、立体規則性の程度、触媒残渣の有無、原料となるモノマーの種類や配合比率、重合触媒の種類(例えば、チーグラー触媒、メタロセン触媒等)等に関わらず、使用することができる。これら合成樹脂の中でも、優れた難燃性を付与できる点から、ポリオレフィン系樹脂が好ましい。
また実施例21~29及び比較例18~26は、第2発明の難燃剤組成物の実施例及びその比較例であり、実施例30~40及び比較例27~36は、第2発明の難燃剤組成物を用いた第3発明の難燃性合成樹脂組成物の実施例及びその比較例である。
表1記載の配合で、ヘンシェルミキサーを用いて各成分を回転数1500rpm/分で、20分間混合し、実施例1~9の難燃剤組成物粉末を調製した。(D)成分の上記一般式(1)で表される脂肪族ジカルボン酸エーテルエステル化合物は、下記構造の化合物No.1を使用した。
また、上記で得られた難燃剤組成物の保存安定性を評価するために、下記保存安定性試験により、ケーキングの発生を評価した。結果を表1及び表2に示す。
粉塵性は、株式会社セイシン企業の粉体物性測定器、商品名マルチテスターMT-1001を用いて測定した。先ず、上記で得られた難燃性組成物粉末10gを測定器の円筒上部より、60cm下にある直径10cmの受け皿に自然落下させた。落下後、受け皿上の難燃剤組成物粉末の重量を測定し、10gからその重量を差し引いて、受け皿の外に飛散した難燃剤組成物粉末の重量を算出した。
飛散した粉末の重量が少ないほど、粉立ちが少なく、ハンドリング性に優れるといえる。測定は3回行い、その平均値を表1及び表2に記載した。
先ず、上記で得られた難燃剤組成物粉末の粒度分布を、マイクロトラック粒度分布計(日機装(株)製MT-3000II)により測定した。次に、縦13cm、横6cmのアルミ袋に、難燃剤組成物粉末30gを入れ、アルミ袋上から58g/cm2の圧力を加えた状態で50℃のオーブン中に30日間静置し保存安定性試験を行った。30日後、アルミ袋中の難燃剤組成物粉末を取り出し、マイクロトラック粒度分布計により、粒度分布を測定した。
試験前後における、積算値50%の粒径(D50)と、さらに粒径の増減値を、表1及び表2に記載した。粒径の増加した値が大きいほど、粒子同士がくっついてケーキングしていることを示す。粒径の変化が少ないほど保存安定性に優れるといえる。
ポリプロピレン(メルトフローレート=8g/10min)60質量部に、ステアリン酸カルシウム(滑剤)0.1質量部、テトラキス[3-(3,5-ジ第三ブチル-4-ヒドロキシフェニル)プロピオン酸メチル]メタン(フェノール系酸化防止剤)0.1質量部、トリス(2,4-ジ-第三ブチルフェニル)ホスファイト(リン系酸化防止剤)0.1質量部、グリセリンモノステアレート(滑剤)0.3質量部を配合して得られたポリプロピレン樹脂組成物に対して、実施例1~9で得られた難燃性組成物を表3記載の配合割合(質量%)で添加して実施例10~20の難燃性合成樹脂組成物を得た。ちなみに難燃剤組成物は、実施例1で得られた難燃剤組成物を難燃剤組成物-1、実施例2で得られた難燃剤組成物を難燃剤組成物-2とし、以下同様にして、実施例9で得られた難燃剤組成物-9までを用いた。
長さ127mm、幅12.7mm、厚さ1.6mmの試験片を垂直に保ち、下端にバーナーの火を10秒間接炎させた後で炎を取り除き、試験片に着火した火が消える時間を測定した。次に、火が消えると同時に2回目の接炎を10秒間行ない、1回目と同様にして着火した火が消える時間を測定した。また、落下する火種により試験片の下の綿が着火するか否かについても同時に評価した。
1回目と2回目の燃焼時間、綿着火の有無等からUL-94V規格にしたがって燃焼ランクをつけた。燃焼ランクはV-0が最高のものであり、V-1、V-2となるに従って難燃性は低下する。但し、V-0~V-2のランクの何れにも該当しないものはNRとする。
表5記載の配合で、ヘンシェルミキサーを用いて各成分を、回転数1500rpmで、 20分間混合し、実施例21~29の難燃剤組成物粉末を調製した。(E)成分の上記一般式(2)で表される脂肪族カルボン酸エステル化合物は、下記構造の化合物No.23を使用した。
また、上記で得られた難燃剤組成物の保存安定性を評価するために、下記保存安定性試験により、ケーキングの発生を評価した。結果を表5及び表6に示す。
粉塵性は、株式会社セイシン企業の粉体物性測定器、商品名マルチテスターMT-1001を用いて測定した。先ず、上記で得られた難燃性組成物粉末10gを測定器の円筒上部より、60cm下にある直径10cmの受け皿に自然落下させた。落下後、受け皿上の難燃剤組成物粉末の重量を測定し、10gからその重量を差し引いて、受け皿の外に飛散した難燃剤組成物粉末の重量を算出した。
飛散した粉末の重量が少ないほど、粉立ちが少なく、ハンドリング性に優れるといえる。測定は3回行い、その平均値を表5及び表6に記載した。
先ず、上記で得られた難燃剤組成物粉末の粒度分布を、マイクロトラック粒度分布計(日機装(株)製MT-3000II)により測定した。次に、縦13cm、横6cmのアルミ袋に、難燃剤組成物粉末30gを入れ、アルミ袋上から58g/cm2の圧力を加えた状態で50℃のオーブン中に30日間静置し保存安定性試験を行った。30日後、アルミ袋中の難燃剤組成物粉末を取り出し、マイクロトラック粒度分布計により、粒度分布を測定した。
試験前後における、積算値50%の粒径(D50)と、さらに粒径の増減値を、表1及び表2に記載した。粒径の増加した値が大きいほど、粒子同士がくっついてケーキングしていることを示す。粒径の変化が少ないほど保存安定性に優れるといえる。
ポリプロピレン(メルトフローレート=8g/10min)60質量部に、ステアリン酸カルシウム(滑剤)0.1質量部、テトラキス[3-(3,5-ジ第三ブチル-4-ヒドロキシフェニル)プロピオン酸メチル]メタン(フェノール系酸化防止剤)0.1質量部、トリス(2,4-ジ-第三ブチルフェニル)ホスファイト(リン系酸化防止剤)0.1質量部、グリセリンモノステアレート(滑剤)0.3質量部を配合して得られたポリプロピレン樹脂組成物に対して、実施例21~29で得られた難燃性組成物を表7記載の配合割合(質量%)で添加して実施例30~40の難燃性合成樹脂組成物を得た。ちなみに難燃剤組成物は、実施例21で得られた難燃剤組成物を難燃剤組成物-10、実施例22で得られた難燃剤組成物を難燃剤組成物-11とし、以下同様にして、実施例29で得られた難燃剤組成物を難燃剤組成物-18として用いた。
長さ127mm、幅12.7mm、厚さ1.6mmの試験片を垂直に保ち、下端にバーナーの火を10秒間接炎させた後で炎を取り除き、試験片に着火した火が消える時間を測定した。次に、火が消えると同時に2回目の接炎を10秒間行ない、1回目と同様にして着火した火が消える時間を測定した。また、落下する火種により試験片の下の綿が着火するか否かについても同時に評価した。
1回目と2回目の燃焼時間、綿着火の有無等からUL-94V規格にしたがって燃焼ランクをつけた。燃焼ランクはV-0が最高のものであり、V-1、V-2となるに従って難燃性は低下する。但し、V-0~V-2のランクの何れにも該当しないものはNRとする。
Claims (8)
- 下記(A)成分を20~50質量部、下記(B)成分を50~80質量部(但し(A)成分と(B)成分の合計は100質量部)、下記(C)成分を0.01~5.0質量部及び下記(D)成分を0.01~1.0質量部含有する難燃剤組成物。
(A)成分:オルトリン酸メラミン、ピロリン酸メラミン、ポリリン酸メラミンの群から、1種以上選択されるメラミン塩
(B)成分:オルトリン酸ピペラジン、ピロリン酸ピペラジン、ポリリン酸ピペラジンの群から、1種以上選択されるピペラジン塩
(C)成分:シランカップリング剤
(D)成分:下記一般式(1)で表される脂肪族ジカルボン酸エーテルエステル化合物
- 上記(C)成分が、エポキシ基を有するシランカップリング剤である請求項1に記載された難燃剤組成物。
- さらに(F)成分として、シリコーンオイルを0.01~10質量部含有する請求項3に記載された難燃剤組成物。
- さらに(G)成分として、酸化亜鉛を0.01~10質量部含有する請求項1~4の何れかに1項記載された難燃剤組成物。
- 合成樹脂及び請求項1から5の何れか1項に記載された難燃剤組成物を含有する難燃性合成樹脂組成物。
- 合成樹脂が、ポリオレフィン系樹脂である請求項6に記載された難燃性合成樹脂組成物。
- 請求項6又は7に記載された難燃性合成樹脂組成物の成形体。
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018042869A1 (ja) * | 2016-08-29 | 2018-03-08 | 株式会社Adeka | 難燃剤組成物及び難燃性合成樹脂組成物 |
WO2018073610A1 (en) * | 2016-10-21 | 2018-04-26 | Frangos Lambros Larry | Fire-resistant material having flame-retarding properties |
WO2019009340A1 (ja) * | 2017-07-07 | 2019-01-10 | 株式会社Adeka | 難燃剤組成物及びそれを含有する難燃性樹脂組成物 |
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Families Citing this family (7)
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KR102055569B1 (ko) * | 2018-04-26 | 2019-12-13 | (주) 이우티이씨 | 다결정 실리콘 절연체를 포함하는 애자 및 피뢰기 |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004000973A1 (ja) * | 2002-06-24 | 2003-12-31 | Asahi Denka Co., Ltd. | 難燃剤組成物及び該組成物を含有した難燃性樹脂組成物 |
JP2008208269A (ja) * | 2007-02-27 | 2008-09-11 | Adeka Corp | 難燃性樹脂組成物 |
JP2014012704A (ja) * | 2013-08-27 | 2014-01-23 | Adeka Corp | 難燃性合成樹脂組成物 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4753498B2 (ja) * | 2001-07-17 | 2011-08-24 | 株式会社Adeka | 難燃性合成樹脂組成物 |
JP4526255B2 (ja) * | 2003-10-16 | 2010-08-18 | 株式会社Adeka | 高純度ピロリン酸ピペラジンの製造方法 |
JP5191125B2 (ja) | 2004-02-24 | 2013-04-24 | 株式会社Adeka | シリコーンオイル被覆難燃剤、該難燃剤を用いた難燃性合成樹脂組成物及びその成形品 |
DE102007035417A1 (de) * | 2007-07-28 | 2009-01-29 | Chemische Fabrik Budenheim Kg | Halogenfreies Flammschutzmittel |
JP5414168B2 (ja) * | 2007-11-14 | 2014-02-12 | 株式会社Adeka | 加工性の改善された難燃剤組成物、難燃性合成樹脂組成物及びその成形品 |
DE102009055434A1 (de) * | 2009-12-31 | 2011-07-07 | Chemische Fabrik Budenheim KG, 55257 | Flammenschutzmittelzusammensetzung für thermoplastische Formmassen |
US20140155528A1 (en) * | 2011-06-29 | 2014-06-05 | Toray Industries, Inc. | Thermoplastic resin composition and molded product made thereof |
JP5793068B2 (ja) * | 2011-12-06 | 2015-10-14 | 株式会社Adeka | 難燃性ポリオレフィン系樹脂組成物 |
-
2016
- 2016-01-25 EP EP16746443.7A patent/EP3255121B1/en active Active
- 2016-01-25 JP JP2016573283A patent/JP6557685B2/ja active Active
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- 2016-01-25 KR KR1020177017835A patent/KR102512595B1/ko active IP Right Grant
- 2016-01-25 CN CN201680004956.6A patent/CN107109236B/zh active Active
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004000973A1 (ja) * | 2002-06-24 | 2003-12-31 | Asahi Denka Co., Ltd. | 難燃剤組成物及び該組成物を含有した難燃性樹脂組成物 |
JP2008208269A (ja) * | 2007-02-27 | 2008-09-11 | Adeka Corp | 難燃性樹脂組成物 |
JP2014012704A (ja) * | 2013-08-27 | 2014-01-23 | Adeka Corp | 難燃性合成樹脂組成物 |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2018042869A1 (ja) * | 2016-08-29 | 2019-06-24 | 株式会社Adeka | 難燃剤組成物及び難燃性合成樹脂組成物 |
KR102431906B1 (ko) | 2016-08-29 | 2022-08-12 | 가부시키가이샤 아데카 | 난연제 조성물 및 난연성 합성 수지 조성물 |
US10968336B2 (en) | 2016-08-29 | 2021-04-06 | Adeka Corporation | Flame retardant composition and flame retardant synthetic resin composition |
WO2018042869A1 (ja) * | 2016-08-29 | 2018-03-08 | 株式会社Adeka | 難燃剤組成物及び難燃性合成樹脂組成物 |
KR20190045155A (ko) * | 2016-08-29 | 2019-05-02 | 가부시키가이샤 아데카 | 난연제 조성물 및 난연성 합성 수지 조성물 |
US10882209B2 (en) | 2016-10-21 | 2021-01-05 | AML Technologies LLC | Non-flammable compositions |
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JPWO2019009340A1 (ja) * | 2017-07-07 | 2020-05-07 | 株式会社Adeka | 難燃剤組成物及びそれを含有する難燃性樹脂組成物 |
WO2019009340A1 (ja) * | 2017-07-07 | 2019-01-10 | 株式会社Adeka | 難燃剤組成物及びそれを含有する難燃性樹脂組成物 |
US11186777B2 (en) | 2017-07-07 | 2021-11-30 | Adeka Corporation | Flame retardant composition and flame-retardant resin composition containing same |
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CN109232836B (zh) * | 2018-08-28 | 2020-09-29 | 武汉轻工大学 | 一种无卤膨胀阻燃剂-苯乙烯共聚复合小球及其制备方法 |
CN109232836A (zh) * | 2018-08-28 | 2019-01-18 | 武汉轻工大学 | 一种无卤膨胀阻燃剂-苯乙烯共聚复合小球及其制备方法 |
WO2022131284A1 (ja) | 2020-12-16 | 2022-06-23 | 株式会社Adeka | 難燃剤組成物、難燃性樹脂組成物および成形体 |
KR20230121038A (ko) | 2020-12-16 | 2023-08-17 | 가부시키가이샤 아데카 | 난연제 조성물, 난연성 수지 조성물 및 성형체 |
CN115386142A (zh) * | 2021-05-25 | 2022-11-25 | 金发科技股份有限公司 | 一种良分散的无卤阻燃剂及其制备方法和应用 |
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CN107109236A (zh) | 2017-08-29 |
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