WO2016116705A1 - Procédé d'amélioration de l'uniformité de dimension critique de films ordonnés de copolymères à blocs - Google Patents
Procédé d'amélioration de l'uniformité de dimension critique de films ordonnés de copolymères à blocs Download PDFInfo
- Publication number
- WO2016116705A1 WO2016116705A1 PCT/FR2016/050113 FR2016050113W WO2016116705A1 WO 2016116705 A1 WO2016116705 A1 WO 2016116705A1 FR 2016050113 W FR2016050113 W FR 2016050113W WO 2016116705 A1 WO2016116705 A1 WO 2016116705A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- todt
- block copolymer
- block
- mixture
- copolymer
- Prior art date
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Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0002—Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/002—Processes for applying liquids or other fluent materials the substrate being rotated
- B05D1/005—Spin coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/68—Preparation processes not covered by groups G03F1/20 - G03F1/50
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/16—Coating processes; Apparatus therefor
- G03F7/162—Coating on a rotating support, e.g. using a whirler or a spinner
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/16—Coating processes; Apparatus therefor
- G03F7/168—Finishing the coated layer, e.g. drying, baking, soaking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/545,068 US20180203348A1 (en) | 2015-01-21 | 2016-01-21 | Process for improving the critical dimension uniformity of ordered films of block copolymers |
SG11201705896UA SG11201705896UA (en) | 2015-01-21 | 2016-01-21 | Method for improving the critical dimension uniformity of ordered films of block copolymers |
JP2017537908A JP2018506183A (ja) | 2015-01-21 | 2016-01-21 | ブロックコポリマーの秩序膜(ordered film)の限界寸法均一性を向上させるための方法 |
CN201680017108.9A CN107406660A (zh) | 2015-01-21 | 2016-01-21 | 用于改善嵌段共聚物的有序膜的关键尺寸均匀性的方法 |
EP16703591.4A EP3247747A1 (fr) | 2015-01-21 | 2016-01-21 | Procédé d'amélioration de l'uniformité de dimension critique de films ordonnés de copolymères à blocs |
KR1020177023124A KR20170118744A (ko) | 2015-01-21 | 2016-01-21 | 블록 공중합체의 질서화된 필름의 임계 치수 균일성 개선 방법 |
US16/656,103 US20200057368A1 (en) | 2015-01-21 | 2019-10-17 | Process for improving the critical dimension uniformity of ordered films of block copolymers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1550466A FR3031749B1 (fr) | 2015-01-21 | 2015-01-21 | Procede d'amelioration de l'uniformite de dimension critique de films ordonnes de copolymeres a blocs |
FR1550466 | 2015-01-21 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/545,068 A-371-Of-International US20180203348A1 (en) | 2015-01-21 | 2016-01-21 | Process for improving the critical dimension uniformity of ordered films of block copolymers |
US16/656,103 Continuation US20200057368A1 (en) | 2015-01-21 | 2019-10-17 | Process for improving the critical dimension uniformity of ordered films of block copolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2016116705A1 true WO2016116705A1 (fr) | 2016-07-28 |
Family
ID=52779889
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2016/050113 WO2016116705A1 (fr) | 2015-01-21 | 2016-01-21 | Procédé d'amélioration de l'uniformité de dimension critique de films ordonnés de copolymères à blocs |
Country Status (9)
Country | Link |
---|---|
US (2) | US20180203348A1 (fr) |
EP (1) | EP3247747A1 (fr) |
JP (1) | JP2018506183A (fr) |
KR (1) | KR20170118744A (fr) |
CN (1) | CN107406660A (fr) |
FR (1) | FR3031749B1 (fr) |
SG (1) | SG11201705896UA (fr) |
TW (1) | TWI598395B (fr) |
WO (1) | WO2016116705A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111492308A (zh) * | 2017-12-21 | 2020-08-04 | 阿科玛法国公司 | 转移印刷方法 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3031748B1 (fr) * | 2015-01-21 | 2018-09-28 | Arkema France | Procede de reduction du temps d'assemblage des films ordones de copolymere a blocs |
US20220236639A1 (en) * | 2021-01-22 | 2022-07-28 | Tokyo Electron Limited | Directed self-assembly |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005029779A (ja) * | 1999-06-07 | 2005-02-03 | Toshiba Corp | パターン形成材料、パターン形成方法、多孔質構造体の製造方法、電気化学セル、多孔質カーボン構造体の製造方法、および多孔質カーボン構造体 |
WO2009145204A1 (fr) * | 2008-05-30 | 2009-12-03 | Canon Kabushiki Kaisha | Film de copolymère séquencé et son procédé de fabrication |
US20120164392A1 (en) * | 2004-11-22 | 2012-06-28 | Wisconsin Alumni Research Foundation | Methods and compositions for forming patterns with isolated or discrete features using block copolymer materials |
WO2013083919A1 (fr) | 2011-12-09 | 2013-06-13 | Arkema France | Procede de preparation de surfaces |
US20130209696A1 (en) * | 2012-02-10 | 2013-08-15 | Rohm And Haas Electronic Materials Llc | Diblock copolymer blend composition |
US20140061155A1 (en) * | 2012-08-31 | 2014-03-06 | Dow Global Technologies Llc. | Composition and method for preparing pattern on a substrate |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8821978B2 (en) * | 2009-12-18 | 2014-09-02 | International Business Machines Corporation | Methods of directed self-assembly and layered structures formed therefrom |
JP5802740B2 (ja) * | 2010-04-14 | 2015-11-04 | エーエスエムエル ネザーランズ ビー.ブイ. | リソグラフィで使用される自己組織化可能な重合体の秩序化された層を提供する方法 |
JP5300799B2 (ja) * | 2010-07-28 | 2013-09-25 | 株式会社東芝 | パターン形成方法及びポリマーアロイ下地材料 |
JP5694109B2 (ja) * | 2011-09-26 | 2015-04-01 | 株式会社東芝 | パターン形成方法 |
-
2015
- 2015-01-21 FR FR1550466A patent/FR3031749B1/fr active Active
-
2016
- 2016-01-21 WO PCT/FR2016/050113 patent/WO2016116705A1/fr active Application Filing
- 2016-01-21 TW TW105101872A patent/TWI598395B/zh active
- 2016-01-21 KR KR1020177023124A patent/KR20170118744A/ko not_active Application Discontinuation
- 2016-01-21 SG SG11201705896UA patent/SG11201705896UA/en unknown
- 2016-01-21 EP EP16703591.4A patent/EP3247747A1/fr not_active Withdrawn
- 2016-01-21 US US15/545,068 patent/US20180203348A1/en not_active Abandoned
- 2016-01-21 CN CN201680017108.9A patent/CN107406660A/zh active Pending
- 2016-01-21 JP JP2017537908A patent/JP2018506183A/ja active Pending
-
2019
- 2019-10-17 US US16/656,103 patent/US20200057368A1/en not_active Abandoned
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005029779A (ja) * | 1999-06-07 | 2005-02-03 | Toshiba Corp | パターン形成材料、パターン形成方法、多孔質構造体の製造方法、電気化学セル、多孔質カーボン構造体の製造方法、および多孔質カーボン構造体 |
US20120164392A1 (en) * | 2004-11-22 | 2012-06-28 | Wisconsin Alumni Research Foundation | Methods and compositions for forming patterns with isolated or discrete features using block copolymer materials |
WO2009145204A1 (fr) * | 2008-05-30 | 2009-12-03 | Canon Kabushiki Kaisha | Film de copolymère séquencé et son procédé de fabrication |
WO2013083919A1 (fr) | 2011-12-09 | 2013-06-13 | Arkema France | Procede de preparation de surfaces |
US20130209696A1 (en) * | 2012-02-10 | 2013-08-15 | Rohm And Haas Electronic Materials Llc | Diblock copolymer blend composition |
US20140061155A1 (en) * | 2012-08-31 | 2014-03-06 | Dow Global Technologies Llc. | Composition and method for preparing pattern on a substrate |
Non-Patent Citations (7)
Title |
---|
CHEVALIER X ET AL: "Improvements of self-assembly properties via homopolymer addition or block-copolymer blends", PROCEEDINGS OF SPIE, S P I E - INTERNATIONAL SOCIETY FOR OPTICAL ENGINEERING, US, vol. 9049, 27 March 2014 (2014-03-27), pages 90490T - 90490T, XP060030887, ISSN: 0277-786X, DOI: 10.1117/12.2046329 * |
HIROFUMI KITANO ET AL: "Control of the Microdomain Orientation in Block Copolymer Thin Films with Homopolymers for Lithographic Application", LANGMUIR, vol. 23, no. 11, 1 May 2007 (2007-05-01), pages 6404 - 6410, XP055110353, ISSN: 0743-7463, DOI: 10.1021/la0637014 * |
J.K.KIM ET AL., MACROMOLECULES, vol. 31, 1998, pages 4045 - 4048 |
MACROMOLECULE, vol. 30, 1997, pages 1621 - 1632 |
MANSKY ET AL., SCIENCE, vol. 275, 1997, pages 1458 - 1460 |
N.P. BALSARA ET AL., MACROMOLECULES, vol. 25, 1992, pages 3896 - 3901 |
N.SAKAMOTO ET AL., MACROMOLECULES, vol. 30, 1997, pages 5321 - 5330 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111492308A (zh) * | 2017-12-21 | 2020-08-04 | 阿科玛法国公司 | 转移印刷方法 |
CN111492308B (zh) * | 2017-12-21 | 2023-10-31 | 阿科玛法国公司 | 转移印刷方法 |
Also Published As
Publication number | Publication date |
---|---|
FR3031749A1 (fr) | 2016-07-22 |
KR20170118744A (ko) | 2017-10-25 |
US20180203348A1 (en) | 2018-07-19 |
TW201700593A (zh) | 2017-01-01 |
TWI598395B (zh) | 2017-09-11 |
SG11201705896UA (en) | 2017-08-30 |
US20200057368A1 (en) | 2020-02-20 |
FR3031749B1 (fr) | 2018-09-28 |
JP2018506183A (ja) | 2018-03-01 |
CN107406660A (zh) | 2017-11-28 |
EP3247747A1 (fr) | 2017-11-29 |
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