WO2016114348A1 - 重合性組成物及び光学異方体 - Google Patents
重合性組成物及び光学異方体 Download PDFInfo
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- WO2016114348A1 WO2016114348A1 PCT/JP2016/050986 JP2016050986W WO2016114348A1 WO 2016114348 A1 WO2016114348 A1 WO 2016114348A1 JP 2016050986 W JP2016050986 W JP 2016050986W WO 2016114348 A1 WO2016114348 A1 WO 2016114348A1
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Images
Classifications
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- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
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- B29D11/00644—Production of filters polarizing
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
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- G02B5/3016—Polarising elements involving passive liquid crystal elements
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/141—Organic polymers or oligomers comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/731—Liquid crystalline materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
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- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
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- G02F2202/02—Materials and properties organic material
- G02F2202/022—Materials and properties organic material polymeric
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/86—Arrangements for improving contrast, e.g. preventing reflection of ambient light
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/8791—Arrangements for improving contrast, e.g. preventing reflection of ambient light
Definitions
- the present invention relates to a polymer having optical anisotropy that requires various optical properties, a polymerizable composition useful as a component of a film, an optical anisotropic body comprising the polymerizable composition, a retardation film, and optical compensation.
- the present invention relates to a film, an antireflection film, a lens, a lens sheet, a liquid crystal display element using the polymerizable composition, an organic light emitting display element, an illumination element, an optical component, a colorant, a security marking, a laser light emitting member, a printed matter, and the like.
- a compound having a polymerizable group is used in various optical materials.
- a polymer having a uniform orientation by aligning a polymerizable composition containing a polymerizable compound in a liquid crystal state and then polymerizing it.
- Such a polymer can be used for polarizing plates, retardation plates and the like necessary for displays.
- two or more types of polymerization are used to satisfy the required optical properties, polymerization rate, solubility, melting point, glass transition temperature, polymer transparency, mechanical strength, surface hardness, heat resistance and light resistance.
- a polymerizable composition containing a functional compound is used. In that case, the polymerizable compound to be used is required to bring good physical properties to the polymerizable composition without adversely affecting other properties.
- the problem to be solved by the present invention is to provide a polymerizable composition that does not cause precipitation of crystals and has high storage stability, and produced a film-like polymer obtained by polymerizing the composition. It is to provide a polymerizable composition that is less likely to cause unevenness. Further, an optical anisotropic body, retardation film, optical compensation film, antireflection film, lens, lens sheet, liquid crystal display device, organic light emitting display device, and lighting device using the polymerizable composition, comprising the polymerizable composition It is to provide an optical component, a colorant, a security marking, a laser emission member, a printed matter, and the like.
- the present invention provides the present invention as a result of intensive studies focusing on a polymerizable composition using a liquid crystal compound having a specific structure having one polymerizable group. It came. That is, the present invention a) General formula (1)
- S 11 represents a spacer group or a single bond, and when there are a plurality of S 11, they may be the same or different, and X 11 represents —O —, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, — CO—NH—, —NH—CO—, —SCH 2 —, —CH 2 S—, —CF 2 O—, —OCF 2 —, —CF 2 S—, —SCF 2 —, —CH ⁇ CH—COO —, —CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, —OCO—CH ⁇ CH—, —COO—CH 2 CH 2 —, —OCO—CH 2 CH 2 —, —CH 2 CH 2 — COO -,
- R 11 is a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a penta
- a fluorosulfuranyl group, a cyano group, a nitro group, an isocyano group, a thioisocyano group, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, — S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO— or —C ⁇ .
- a linear or branched alkyl group having 1 to 20 carbon atoms which may be substituted by C- represents an arbitrary hydrogen atom in the alkyl group may be substituted with a fluorine atom
- G represents the following Formula (G-1) or Formula (G-2)
- R 12 is a hydrogen atom, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, — May be substituted by COO-, -OCO-, -CO-S-, -S-CO-, -O-CO-O-, -CO-NH-, -NH-CO- or -C ⁇ C-
- a linear or branched alkyl group having 1 to 20 carbon atoms is represented, and any hydrogen atom in the alkyl group may be substituted with a fluorine atom, and W 11 has at least one aromatic group.
- W 12 may represent the same meaning as the W 11, also, W 11 and W 12 may be taken together to form a ring structure, or W 82 may be
- a hydrogen atom in the alkyl group may be substituted with a fluorine atom, and L 1 represents a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a pentafluorosulfuranyl group, a nitro group.
- alkyl group having 1 to 20 carbon atoms
- the alkyl group may be linear or branched, and any hydrogen atom may be substituted with a fluorine atom, and one —CH 2 — or nonadjacent two or more -CH 2 - are each independently -O -, - S -, - CO -, - COO -, - OCO -, - CO-S-, S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, — It may be substituted by
- an optical anisotropic body, a retardation film, an optical compensation film, an antireflection film, a lens, a lens sheet, a liquid crystal display device using the polymerizable composition, and an organic light emitting display device comprising the polymerizable composition Provide lighting elements, optical components, colorants, security markings, laser emission members, printed materials, and the like.
- the polymerizable composition of the present invention comprises a specific structure having one polymerizable group, a liquid crystal compound having reverse wavelength dispersion or low wavelength dispersion, and a polymerizable having at least two polymerizable groups.
- a polymerizable composition excellent in solubility and storage stability can be obtained, and by using the polymerizable composition, a polymer, an optical anisotropic body, and a phase difference excellent in productivity can be obtained.
- a film or the like can be obtained.
- liquid crystalline compound is intended to indicate a compound having a mesogenic skeleton, and the compound alone, It does not have to exhibit liquid crystallinity.
- the polymerizable composition can be polymerized (formed into a film) by performing a polymerization treatment by irradiation with light such as ultraviolet rays or heating.
- the film has a “reverse wavelength” It is commonly referred to by those skilled in the art as “dispersible” or “inversely dispersible”.
- the compounds constituting the retardation film exhibiting reverse wavelength dispersion are referred to as reverse wavelength dispersion compounds and low wavelength dispersion compounds.
- P 11 represents a polymerizable group
- P-20 the following formulas (P-1) to (P-20)
- these polymerizable groups are polymerized by radical polymerization, radical addition polymerization, cationic polymerization and anionic polymerization.
- the formula (P-1), formula (P-2), formula (P-3), formula (P-4), formula (P-5), formula (P ⁇ 7), formula (P-11), formula (P-13), formula (P-15) or formula (P-18) are preferred, and formula (P-1), formula (P-2), formula (P-18) P-7), formula (P-11) or formula (P-13) is more preferred, formula (P-1), formula (P-2) or formula (P-3) is more preferred, and formula (P- Particular preference is given to 1) or formula (P-2).
- S 11 represents a spacer group or a single bond, and when a plurality of S 11 are present, they may be the same or different.
- the spacer group one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —COO—, —OCO—, —OCO—O—, It preferably represents an alkylene group having 1 to 20 carbon atoms which may be replaced by —CO—NH—, —NH—CO—, —CH ⁇ CH— or —C ⁇ C—.
- a plurality of S are present from the viewpoint of availability of raw materials and synthesis, they may be the same or different, and each independently represents one —CH 2 — or not adjacent 2 It is more preferable that two or more —CH 2 — each independently represents an alkylene group having 1 to 10 carbon atoms or a single bond that may be independently replaced by —O—, —COO—, or —OCO—, each independently And more preferably an alkylene group having 1 to 10 carbon atoms or a single bond, and when there are a plurality of alkylene groups, they may be the same or different and each independently an alkylene group having 1 to 8 carbon atoms. Is particularly preferred.
- X 11 represents —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO.
- a 11 and A 12 are each independently 1,4-phenylene group, 1,4-cyclohexylene group, pyridine-2,5-diyl group, pyrimidine-2,5-diyl group, naphthalene-2,6-diyl.
- the group may be unsubstituted or substituted by one or more L 1 s , but when a plurality of A 11 and / or A 12 appear, they may be the same or different.
- a 11 and A 12 are each independently an unsubstituted or 1,4-phenylene group which may be substituted with one or more L, or 1,4-cyclo, from the viewpoint of availability of raw materials and ease of synthesis. It preferably represents a xylene group or naphthalene-2,6-diyl, each independently of the following formulas (A-1) to (A-11)
- each group independently represents a group selected from formula (A-1) to formula (A-8), and each independently represents a group selected from formula (A-1). It is particularly preferable to represent a group selected from the formula (A-4).
- Z 11 and Z 12 are each independently —O—, —S—, —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —CO—, —COO—, —OCO—, —CO.
- Z 11 and Z 12 are each independently a single bond, —OCH 2 —, —CH 2 O—, —COO—, —OCO— from the viewpoint of liquid crystallinity of the compound, availability of raw materials, and ease of synthesis.
- k represents an integer of 0 to 8, but preferably represents an integer of 0 to 4, more preferably represents an integer of 0 to 2, from the viewpoints of liquid crystallinity, availability of raw materials and ease of synthesis. It is more preferable to represent 0 or 1, and it is particularly preferable to represent 1.
- M1 and m2 each independently represents an integer of 0 to 5, but m1 + m2 represents an integer of 1 to 5.
- m1 and m2 each independently preferably represents an integer of 1 to 4, more preferably an integer of 1 to 3, more preferably 1 or 2. It is particularly preferred to represent.
- m1 + m2 preferably represents an integer of 1 to 4, particularly preferably 2 or 3.
- M is the following formula (M-1) to formula (M-8)
- M is each independently unsubstituted or substituted by one or more L 1 from the viewpoints of availability of raw materials and ease of synthesis, and the formula (M-1) or the formula (M-2) Alternatively, it preferably represents a group selected from unsubstituted formula (M-3) to formula (M-6), and may be unsubstituted or substituted by one or more Ls (M-1) or ( It is more preferable to represent a group selected from M-2), and it is particularly preferable to represent a group selected from unsubstituted formula (M-1) or formula (M-2).
- R 11 is a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a pentafluorosulfuranyl group, a cyano group, a nitro group, an isocyano group, a thioisocyano group, or one —CH 2 — or adjacent. Two or more —CH 2 — are each independently —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO.
- R 11 is easy from the viewpoint of hydrogen atoms of the liquid crystal and synthetic, fluorine atom, chlorine, cyano group, or one -CH 2 - or nonadjacent two or more -CH 2 - are each independently It preferably represents a linear or branched alkyl group having 1 to 12 carbon atoms which may be substituted by —O—, —COO—, —OCO—, —O—CO—O—, a hydrogen atom, fluorine It is more preferable to represent an atom, a chlorine atom, a cyano group, or a linear alkyl group or linear alkoxy group having 1 to 12 carbon atoms, and a linear alkyl group or linear alkoxy group having 1 to 12 carbon atoms. It is particularly preferred to represent.
- G is the following formula (G-1) or formula (G-2)
- R 12 is a hydrogen atom, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, — May be substituted by COO-, -OCO-, -CO-S-, -S-CO-, -O-CO-O-, -CO-NH-, -NH-CO- or -C ⁇ C-
- a linear or branched alkyl group having 1 to 20 carbon atoms is represented, and any hydrogen atom in the alkyl group may be substituted with a fluorine atom, and W 11 has at least one aromatic group.
- W 12 may represent the same meaning as the W 11, also, W 11 and W 12 may be taken together to form a ring structure, or W 12 may be
- R 12 is a hydrogen atom, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, —COO—, — 1 carbon atom which may be substituted by OCO-, -CO-S-, -S-CO-, -O-CO-O-, -CO-NH-, -NH-CO- or -C ⁇ C- To 20 straight-chain or branched alkyl groups, and any hydrogen atom in the alkyl group may be substituted with a fluorine atom.
- R 12 may be substituted with any hydrogen atom by a fluorine atom, and each of —12 — represents one —CH 2 — or two or more —CH 2 — not adjacent to each other. It preferably represents a linear or branched alkyl group having 1 to 12 carbon atoms which may be independently substituted by —O—, —COO— or —OCO—, and any hydrogen atom is substituted with a fluorine atom It is more preferable to represent a linear or branched alkyl group having 1 to 12 carbon atoms, and it is particularly preferable to represent a linear alkyl group having 1 to 12 carbon atoms.
- W 11 represents a group having 5 to 30 carbon atoms having at least one aromatic group, and the group may be unsubstituted or substituted by one or more L 1 groups.
- the aromatic group contained in W 11 may be an aromatic hydrocarbon group or an aromatic hetero group, or may contain both. These aromatic groups may be bonded via a single bond or a linking group, and may form a condensed ring.
- W 11 may contain an acyclic structure and / or a cyclic structure other than the aromatic group in addition to the aromatic group. From the viewpoints of availability of raw materials and ease of synthesis, the aromatic group contained in W 11 is unsubstituted or may be substituted with one or more L 1 from the following formula (W-1) Formula (W-19)
- Q 1 Represents —O—, —S—, —NR 4 — (wherein R 4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms) or —CO—.
- Each —CH ⁇ may be independently replaced by —N ⁇ , and each —CH 2 — independently represents —O—, —S—, —NR 4 — (wherein R 4 represents a hydrogen atom or carbon Represents an alkyl group having 1 to 8 atoms.) Or may be replaced by —CO—, but does not include an —O—O— bond, and the group represented by the formula (W-1) is unsubstituted. Or the following formula (W-1-1) to formula (W-1-8) which may be substituted by one or more L 1
- these groups may have a bond at an arbitrary position), preferably a group selected from the group represented by the formula (W-7) is unsubstituted. Or the following formula (W-7-1) to formula (W-7-7) which may be substituted by one or more L 1
- these groups may have a bond at an arbitrary position), preferably a group selected from the group represented by formula (W-10) is unsubstituted. Or one or more of L 1 may be substituted by the following formulas (W-10-1) to (W-10-8)
- these groups may have a bond at an arbitrary position, and R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- these groups may have a bond at an arbitrary position, and R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- Examples of the group represented by the formula (W-12) include the following formula (W-12-1) to formula (W-12-19) which may be unsubstituted or substituted with one or more L 1 groups. )
- these groups may have a bond at an arbitrary position, and R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- these groups may have a bond at an arbitrary position, and R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- the group represented by the formula (W-14) may be unsubstituted or substituted with one or more L 1 from the following formulas (W-14-1) to (W-14-4) )
- these groups may have a bond at an arbitrary position, and R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- the group represented by the formula (W-15) may be unsubstituted or substituted with one or more L 1 from the following formulas (W-15-1) to (W-15-18) )
- these groups may have a bond at an arbitrary position, and R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- these groups may have a bond at an arbitrary position, and R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- these groups may have a bond at an arbitrary position, and R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- Examples of the group represented by the formula (W-18) include the following formulas (W-18-1) to (W-18-6) which may be unsubstituted or substituted with one or more L 1 groups.
- these groups may have a bond at an arbitrary position, and R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- W 1 may be unsubstituted or substituted with one or more L 1 in formula (W-1-1), formula (W-7-1), formula (W— 7-2), Formula (W-7-7), Formula (W-8), Formula (W-10-6), Formula (W-10-7), Formula (W-10-8), Formula ( W-11-8), Formula (W-11-9), Formula (W-11-10), Formula (W-11-11), Formula (W-11-12), or Formula (W-11-13) More preferably a group selected from formula (W-1-1), formula (W-7-1), formula (W) which may be unsubstituted or substituted by one or more L 1 W-7-2), a group selected from formula (W-7-7), formula (W-10-6), formula (W-10-7) or formula (W-10-8) Particularly preferred. Further, W 1 is expressed by the following formulas (Wa-1) to (Wa-6)
- r represents an integer of 0 to 5
- s represents an integer of 0 to 4
- t represents an integer of 0 to 3.
- W 12 is a hydrogen atom, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, —COO—, — OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—.
- W 12 may represent the same meaning as the W 11, also, W 11 and W 12 may be taken together to form a ring structure, or W 12 may be
- W 12 is a hydrogen atom, or an arbitrary hydrogen atom may be substituted with a fluorine atom from the viewpoint of easy availability of raw materials and synthesis, and one —CH 2 — or two not adjacent to each other
- the above —CH 2 — is independently —O—, —CO—, —COO—, —OCO—, —CH ⁇ CH—COO—, —OCO—CH ⁇ CH—, —CH ⁇ CH—, — It preferably represents a linear or branched alkyl group having 1 to 20 carbon atoms which may be substituted by CF ⁇ CF— or —C ⁇ C—, and represents a hydrogen atom or one —CH 2 — or It is more preferable that two or more non-adjacent —CH 2 — each independently represent a
- Two or more -CH 2 - is particularly preferably each independently from a good 1 -C be replaced by -O- represents a linear alkyl group of 12. Also, if W 12 represents the same meaning as W 11, W 12 may be different even identical to W 11, the preferred group is the same as described for W 11. In the case where W 11 and W 12 together form a ring structure, the cyclic group represented by —NW 11 W 12 may be unsubstituted or substituted by one or more L 1 Formula (Wb-1) to Formula (Wb-42)
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- Wb-20 Formula (Wb-21), Formula (Wb-22), Formula (Wb-23), Formula (Wb) that may be substituted by one or more L 1
- CW 11 W 12 may be unsubstituted or may be substituted with one or more L 1.
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R 3 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- Wc-11 Formula (Wc-12), Formula (Wc-13), Formula (Wc-14), Formula (W) that may be substituted by one or more L 1 Wc-53), formula (Wc-54), formula (Wc-55), formula (Wc-56), formula (Wc-57) or formula (Wc-78) It is particularly preferred to represent a group selected from
- W 12 is the following group
- preferred P W82 is the same as described for P 11
- preferred S W82 is the same as described for S 11
- preferred X W82 is the same as described for X 11
- preferred n W82 is The same as described for k.
- the total number of ⁇ electrons contained in W 11 and W 12 is preferably 4 to 24 from the viewpoints of wavelength dispersion characteristics, storage stability, liquid crystallinity, and ease of synthesis.
- L 1 is a fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino.
- L 1 represents a fluorine atom, a chlorine atom, a pentafluorosulfuranyl group, a nitro group, a methylamino group, a dimethylamino group, a diethylamino group, a diisopropylamino group, or an arbitrary hydrogen.
- the atom may be substituted with a fluorine atom, and one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, —COO.
- L 1 when a plurality of L 1 are present in the compound, they may be the same or different.
- the polymerizable liquid crystal compound represented by the general formula (1) is preferably a compound represented by the following formula (1-1) to formula (1-130).
- the total content of the polymerizable compound represented by the general formula (1) is preferably 2 to 99% by mass, preferably 10 to 85% by mass, out of the total amount of the polymerizable compound used in the polymerizable composition.
- the content is more preferably 20 to 80% by mass.
- the lower limit value is preferably 5% by mass or more, more preferably 10% by mass or more, and the curability of the resulting coating film is emphasized.
- the upper limit value is preferably 80% by mass or less, and more preferably 70% by mass or less.
- the polymerizable compound having at least two polymerizable groups of the present invention may be a polymerizable compound having a mesogenic skeleton, and the compound alone may not exhibit liquid crystallinity.
- a rod-like polymerizable liquid crystal compound having two or more polymerizable functional groups such as a vinyl group, an acrylic group, and a (meth) acryl group, or JP-A Nos. 2004-2373 and 2004-99446.
- examples thereof include a rod-like polymerizable liquid crystal compound having two or more polymerizable groups having a maleimide group.
- a rod-like liquid crystal compound having two or more polymerizable groups is preferable because it can easily produce a liquid crystal having a temperature range around room temperature.
- polymerizable liquid crystal compound having at least two polymerizable groups include compounds represented by the following general formulas (2) to (7). Note that the compounds represented by the general formulas (2) to (7) do not contain an —O—O— bond.
- P 21 to P 74 each independently represents a polymerizable group
- S 21 to S 72 each independently represent a spacer group or a single bond, and when a plurality of S 21 to S 72 are present, they may be the same or different
- X 21 to X 72 are each independently —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—.
- MG 21 to MG 71 each independently represent a mesogenic group
- R 31 represents a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a pentafluorosulfuranyl group, a cyano group, a nitro group, an isocyano group, a thioisocyano group, or an alkyl group having 1 to 20 carbon atoms.
- the alkyl group may be linear or branched, and any hydrogen atom in the alkyl group may be substituted with a fluorine atom, and one —CH in the alkyl group may be substituted.
- the spacer group represented by S 21 to S 72 represents an alkylene group having 1 to 18 carbon atoms (the alkylene group is one or more halogen atoms, a CN group, an alkyl group having 1 to 8 carbon atoms, Alternatively, it may be substituted by an alkyl group having 1 to 8 carbon atoms having a polymerizable functional group, and one CH 2 group present in this group or two or more CH 2 groups which are not adjacent to each other are mutually bonded.
- a carbon atom A linear alkylene group of 2 to 8 and a fluorine atom Conversion alkylene group having 2 to 6 carbon atoms, alkylene group part number 5-14 carbon atoms which is substituted with -O- alkylene groups are preferred.
- the polymerizable groups represented by P 21 to P 74 are represented by the following formulas (P-1) to (P-20).
- the mesogenic group represented by MG 21 to MG 71 has the following formula (8-a)
- a 81 and A 82 are each independently 1,4-phenylene group, 1,4-cyclohexylene group, pyridine-2,5-diyl group, pyrimidine-2,5-diyl group, naphthalene-2,6-diyl.
- the groups may be unsubstituted or substituted with one or more L 2 s , but when a plurality of A 81 and / or A 82 appear, they may be the same or different, Z 81 and Z 82 are each independently —O—, —S—, —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —CO—, —COO—, —OCO—, —CO.
- G is the following formula (G-1) to formula (G-6)
- R 3 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and the alkyl group may be linear or branched, and any of the alkyl groups the hydrogen atoms may be substituted by a fluorine atom, one -CH 2 in the alkyl group - or nonadjacent two or more -CH 2 - are each independently -O -, - S- , —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO— or —C ⁇ C—.
- W 81 represents a group having 5 to 30 carbon atoms having at least one aromatic group, and the group may be unsubstituted or substituted by one or more L 2
- W 82 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and the alkyl group may be linear or branched, and any hydrogen atom in the alkyl group may be It may be substituted by a fluorine atom, one -CH 2 in the alkyl group - or nonadjacent two or more -CH 2 - are each independently -O -, - S -, - CO- , —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO—, — May be substituted by CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, —OCO—CH ⁇ CH——,
- W 83 and W 84 each independently has 5 to 30 carbon atoms having a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, a carbamoyloxy group, an amino group, a sulfamoyl group, or at least one aromatic group.
- alkyl groups having 1 to 20 carbon atoms alkyl groups having 1 to 20 carbon atoms, cycloalkyl groups having 3 to 20 carbon atoms, alkenyl groups having 2 to 20 carbon atoms, cycloalkenyl groups having 3 to 20 carbon atoms, and 1 to 20 carbon atoms.
- M is selected from Formula (M-1) to Formula (M-10)
- G is selected from Formula (G-1) to Formula (G-5)
- M is Formula (M-11).
- G represents the formula (G-6), L 2 is fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino.
- a 83 and A 84 are each independently 1,4-phenylene group, 1,4-cyclohexylene group, pyridine-2,5-diyl group, pyrimidine-2,5-diyl group, naphthalene-2,6-diyl.
- the groups may be unsubstituted or substituted by one or more of the above L 2 s , but when a plurality of A 83 and / or A 84 appear, they may be the same or different, Z 83 and Z 84 are each independently —O—, —S—, —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —CO—, —COO—, —OCO—, —CO.
- L 2 is fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino.
- any hydrogen atom in the alkyl group may be substituted by a fluorine atom, j83 and j84 each independently represents an integer of 0 to 5, while j83 + j84 represents an integer
- general formulas (2) to (7) are represented by the following general formula (2-a), general formula (2-b), general formula (3-a), general formula (3-b), General formula (4-a), general formula (4-b), general formula (5-a), general formula (5-b), general formula (6-a), general formula (6-b), general formula (7-a), represented by the general formula (7-b).
- the formula (P-1), the formula (P-2), the formula (P-7), Formula (P-12) or formula (P-13) is preferable, and formula (P-1), formula (P-7), and formula (P-12) are more preferable.
- S 21 to S 72 each independently represents a spacer group or a single bond, and when a plurality of S 21 to S 72 are present, they may be the same or different.
- the spacer group represented by S 21 to S 72 represents an alkylene group having 1 to 18 carbon atoms, and the alkylene group is one or more halogen atoms, a CN group, or an alkyl group having 1 to 8 carbon atoms.
- alkyl group having 1 to 8 carbon atoms having a respective one CH 2 group or not adjoining two or more CH 2 groups present in this group Independently of each other, in a form in which oxygen atoms are not directly bonded to each other, —O—, —S—, —NH—, —N (CH 3 ) —, —CO—, —CH (OH) —, CH ( COOH), —COO—, —OCO—, —OCOO—, —SCO—, —COS——C ⁇ C—, formula (S-1), or formula (S-2)
- a linear alkylene group having 2 to 8 carbon atoms an alkylene group having 2 to 6 carbon atoms substituted with a fluorine atom, and a part of the alkylene groups are —O—.
- a substituted alkylene group having 5 to 14 carbon atoms is preferred.
- X 21 ⁇ X 72 each independently represents —O—, —S—, —OCH 2 —, —CH 2 O—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —SCH 2 —, —CH 2 S—, —CF 2 O—, —OCF 2 —, —CF 2 S—, —SCF 2 —, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, —OCO—CH ⁇ CH—, —COO—CH 2
- each P— (SX) — does not contain an —O—O— bond).
- they may be the same or different, and each independently represents —O—, —S—, —OCH 2 —, —CH 2 O—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —COO—CH 2 CH 2 -, - OCO- CH 2 CH 2 -, - CH 2 CH 2 -COO -, - it is preferable to represent a CH 2 CH 2 -OCO- or a single bond, each independently -O -, - OCH 2 —, —CH 2 O—, —COO—, —OCO—, —COO—CH 2 CH 2 —, —OCO—CH 2
- a 21 to A 72 each independently represents 1,4-phenylene group, 1,4-cyclohexylene group, pyridine-2,5-diyl group, pyrimidine-2,5-diyl group, naphthalene-2,6-diyl group, naphthalene Represents a 1,4-diyl group, a tetrahydronaphthalene-2,6-diyl group, a decahydronaphthalene-2,6-diyl group, or a 1,3-dioxane-2,5-diyl group.
- a 21 to A 72 are each independently an unsubstituted or 1,4-phenylene group that may be substituted with one or more L 2 from the viewpoint of availability of raw materials and ease of synthesis;
- each group independently represents a group selected from formula (A-1) to formula (A-8), and each independently represents a group selected from formula (A-1). It is particularly preferable to represent a group selected from the formula (A-4).
- Z 21 ⁇ Z 72 each independently represents —O—, —S—, —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —CO—, —COO—, —OCO—, —CO—S—.
- Z 21 to Z 72 are each independently a single bond, —OCH 2 —, —CH 2 O—, —COO—, —OCO— from the viewpoint of liquid crystallinity of the compound, availability of raw materials, and ease of synthesis.
- Z 21 to Z 72 are each independently —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —COO.
- Z 21 ⁇ Z 72 are each independently , - - -CH 2 CH 2 Te COO -, - OCO -, - COO-CH 2 CH 2 -, - OCO-CH 2 CH 2 -, - CH 2 CH 2 -COO -, - CH 2 CH 2 -OCO It is more preferable to represent — or a single bond, and it is particularly preferable that each independently represents —CH 2 CH 2 —, —COO—, —OCO— or a single bond.
- R 31 represents a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a pentafluorosulfuranyl group, a cyano group, a nitro group, or an isocyano group.
- a thioisocyano group, or one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, —COO—, —OCO—.
- R 31 is a hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, or one —CH 2 — or two or more non-adjacent —CH 2 — independent from the viewpoint of liquid crystallinity and ease of synthesis.
- It preferably represents a linear or branched alkyl group having 1 to 12 carbon atoms which may be substituted by —O—, —COO—, —OCO—, —O—CO—O—, a hydrogen atom, fluorine It is more preferable to represent an atom, a chlorine atom, a cyano group, or a linear alkyl group or linear alkoxy group having 1 to 12 carbon atoms, and a linear alkyl group or linear alkoxy group having 1 to 12 carbon atoms. It is particularly preferred to represent.
- M is each independently unsubstituted or substituted with one or more L 2 from the viewpoints of availability of raw materials and ease of synthesis, and the formula (M-1) or (M-2) Or preferably represents a group selected from unsubstituted formula (M-3) to (M-6), and may be unsubstituted or substituted by one or more L 2 It is more preferable to represent a group selected from (M-2), and it is particularly preferable to represent a group selected from unsubstituted formula (M-1) or (M-2).
- G represents a group selected from formula (G-1) to formula (G-6).
- R 3 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and the alkyl group may be linear or branched.
- hydrogen atom may be substituted by a fluorine atom, one -CH 2 in the alkyl group - or nonadjacent two or more -CH 2 - are each independently -O -, - S-, By —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO— or —C ⁇ C—.
- W 81 represents a group having 5 to 30 carbon atoms having at least one aromatic group, and the group may be unsubstituted or substituted by one or more L 2
- W 82 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and the alkyl group may be linear or branched, and any hydrogen atom in the alkyl group may be substituted by fluorine atoms, one -CH 2 in the alkyl group - or nonadjacent two or more -CH 2 - are each independently -O -, - S -, - CO —, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO—, May be substituted by —CH ⁇ CH—OCO—, —COO—CH ⁇ CH—, —OCO—CH ⁇ CH—, —CH
- W 83 and W 84 each independently has 5 to 30 carbon atoms having a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, a carbamoyloxy group, an amino group, a sulfamoyl group, or at least one aromatic group.
- alkyl groups having 1 to 20 carbon atoms alkyl groups having 1 to 20 carbon atoms, cycloalkyl groups having 3 to 20 carbon atoms, alkenyl groups having 2 to 20 carbon atoms, cycloalkenyl groups having 3 to 20 carbon atoms, and 1 to 20 carbon atoms.
- the aromatic group contained in W 81 may be an aromatic hydrocarbon group or aromatic heterocyclic group may contain both. These aromatic groups may be bonded via a single bond or a linking group (—OCO—, —COO—, —CO—, —O—), and may form a condensed ring. W 81 may contain an acyclic structure and / or a cyclic structure other than the aromatic group in addition to the aromatic group. From the viewpoint of availability of raw materials and ease of synthesis, the aromatic group contained in W 81 is unsubstituted or may be substituted with one or more L 2 from the following formula (W-1) Formula (W-19)
- Q 1 Represents —O—, —S—, —NR 5 — (wherein R 5 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms) or —CO—.
- Each —CH ⁇ may be independently replaced by —N ⁇ , and each —CH 2 — independently represents —O—, —S—, —NR 4 — (wherein R 4 represents a hydrogen atom or carbon Represents an alkyl group having 1 to 8 atoms) or a group represented by the formula: -CO-, which may be substituted with -CO-, but does not contain an -O-O- bond.
- R 4 represents a hydrogen atom or carbon Represents an alkyl group having 1 to 8 atoms
- -CO- which may be substituted with -CO-, but does not contain an -O-O- bond.
- W-1 the following formula (W-1-1) to the formula (W-1-8) which may be unsubstituted or substituted by one or more L 2 groups. )
- these groups may have a bond at an arbitrary position), preferably a group selected from the group represented by the formula (W-7) is unsubstituted. Or the following formula (W-7-1) to formula (W-7-7) which may be substituted by one or more L 2
- these groups may have a bond at an arbitrary position), preferably a group selected from the group represented by formula (W-10) is unsubstituted. Or the following formula (W-10-1) to formula (W-10-8) which may be substituted by one or more L 2
- these groups may have a bond at an arbitrary position, and R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- these groups may have a bond at an arbitrary position, and R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, each identical if R 6 there are a plurality of It is preferable that the group represented by the formula (W-13) is unsubstituted or substituted by one or more L 2 groups.
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, each identical if R 6 there are a plurality of It is preferable that the group represented by the formula (W-14) is unsubstituted or substituted by one or more Ls.
- these groups may have a bond at an arbitrary position, and R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, each identical if R 6 there are a plurality of
- the group represented by formula (W-16) may be unsubstituted or substituted by one or more L 2 groups.
- these groups may have a bond at an arbitrary position, and R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- these groups may have a bond at an arbitrary position, and R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms).
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms.
- Examples of the group represented by the formula (W-18) include the following formulas (W-18-1) to (W-18-6) which may be unsubstituted or substituted with one or more Ls.
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, each identical if R 6 there are a plurality of
- the group represented by formula (W-19) may be unsubstituted or substituted by one or more L 2 groups.
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, each identical if R 6 there are a plurality of Or may be different. It is preferable to represent a group selected from:
- the aromatic group contained in W 81 is unsubstituted or may be substituted by one or more L 2.
- r represents an integer of 0 to 5
- s represents an integer of 0 to 4
- t represents an integer of 0 to 3.
- W 82 represents a hydrogen atom, or one -CH 2 - or nonadjacent two or more -CH 2 - are each independently -O -, - S -, - CO -, - COO -, - OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —CH ⁇ CH—COO—, —CH ⁇ CH—OCO—.
- W 82 may represent the same meaning as the W 81, also, W 81 and W 82 may form a ring structure together, or W 82 may be
- P W82 represents the same meaning as P 11
- S W82 represents the same meaning as S 11
- X W82 represents the same meaning as X 11
- n W82 represents the same meaning as k).
- W 82 is a hydrogen atom, or an arbitrary hydrogen atom may be substituted with a fluorine atom from the viewpoint of easy availability of raw materials and synthesis, and one —CH 2 — or two not adjacent to each other
- the above —CH 2 — is independently —O—, —CO—, —COO—, —OCO—, —CH ⁇ CH—COO—, —OCO—CH ⁇ CH—, —CH ⁇ CH—, —
- a linear or branched alkyl group having 1 to 20 carbon atoms, which may be substituted by CF ⁇ CF— or —C ⁇ C—, or W 82 is the following group:
- a hydrogen atom, or one —CH 2 — or two or more non-adjacent —CH 2 — each independently has 1 to 20 carbon atoms which may be substituted by —O—.
- Linear or branched alkyl group, or W82 is the following group
- n W82 represents the same meaning as k. More preferably, a hydrogen atom, or one —CH 2 — or two or more non-adjacent —CH 2 — may each independently be substituted with —O— from 1 to 20 carbon atoms.
- a linear or branched alkyl group, or W82 is the following group:
- P W82 represents the same meaning as P 11
- S W82 represents the same meaning as S 11
- X W82 represents the same meaning as X 11
- n W82 represents the same meaning as k). It is particularly preferred.
- W 82 represents the same meaning as W 81, W 82 may be different even identical to W 81, the preferred group is the same as described for W 81.
- the cyclic group represented by —NW 81 W 82 may be unsubstituted or substituted by one or more L 2 Formula (Wb-1) to Formula (Wb-42)
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms
- CW 81 W 82 may be unsubstituted or may be substituted with one or more L 2.
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and when there are a plurality of R 6 s , they may be the same or different from each other).
- R 6 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and when there are a plurality of R 6 s , they may be the same or different from each other.
- Formula (Wc-11), Formula (Wc-12), which may be unsubstituted or substituted by one or more L, Formula (Wc-13), Formula (Wc-14), Formula (Wc-53), Formula (Wc-54), Formula (Wc-55), Formula (Wc -56), a group selected from formula (Wc-57) or formula (Wc-78) is particularly preferred.
- W 82 is the following group
- preferred P W82 is the same as described for P 11
- preferred S W82 is the same as described for S 11
- preferred X W82 is the same as described for X 11
- preferred n W82 is The same as described for k.
- the total number of ⁇ electrons contained in W 81 and W 82 is preferably 4 to 24 from the viewpoint of wavelength dispersion characteristics, storage stability, liquid crystallinity, and ease of synthesis.
- W 83 and W 84 each independently has 5 to 30 carbon atoms having a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, a carbamoyloxy group, an amino group, a sulfamoyl group, or at least one aromatic group.
- a cyano group, a carboxyl group, one —CH 2 — or two or more non-adjacent —C H 2 — is each independently substituted by —CO—, —COO—, —OCO—, —O—CO—O—, —CO—NH—, —NH—CO— or —C ⁇ C—
- W84 is a cyano group, a nitro group, a carboxyl group, one —CH 2 — or adjacent group.
- Two or more —CH 2 — that are not present are each independently —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O.
- L 2 is fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino.
- L 2 is fluorine atom, chlorine atom, pentafluorosulfuranyl group, nitro group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino group, or any hydrogen
- the atom may be substituted with a fluorine atom, and one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, —COO.
- 21 to M 71 are 1,4-phenylene group, 1,4-cyclohexylene group, 1,4-cyclohexenyl group, tetrahydropyran-2,5-diyl group, and 1,3-dioxane-2,5-diyl group.
- L 2 is fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, nitro group, isocyano group, amino group, hydroxyl group, mercapto group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino.
- L 2 is fluorine atom, chlorine atom, pentafluorosulfuranyl group, nitro group, methylamino group, dimethylamino group, diethylamino group, diisopropylamino group, or any hydrogen
- the atom may be substituted with a fluorine atom, and one —CH 2 — or two or more non-adjacent —CH 2 — are each independently —O—, —S—, —CO—, —COO.
- j21, j22, j31, j32, j41, j42, j51, j52, j61, j62, j71 and j72 each independently represents an integer from 0 to 5, j21 + j22 represents an integer from 1 to 5, and j31 + j32 represents 1 J41 + j42 represents an integer from 1 to 5, j51 + j52 represents an integer from 1 to 5, j61 + j62 represents an integer from 1 to 5, and j71 + j72 represents an integer from 1 to 5.
- j21, j22, j31, j32, j41, j42, j51, j52, j61, j62, j71 and j72 each independently represents an integer of 1 to 4.
- it represents an integer of 1 to 3, more preferably 1 or 2.
- j21 + j22, j31 + j32, j41 + j42, j51 + j52, j61 + j62, and j71 + j72 each preferably represent an integer of 1 to 4, particularly preferably 2 or 3.
- the compound represented by the general formula (2-a) is preferably a compound represented by the following formula (2-a-1) to formula (2-a-64).
- n represents an integer of 1 to 10.
- compounds represented by general formula (2-b) are preferably compounds represented by the following formulas (2-b-1) to (2-b-33).
- n and n each independently represents an integer of 1 to 18, and R represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a cyano group.
- R represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a cyano group.
- these groups are alkyl groups having 1 to 6 carbon atoms or alkoxy groups having 1 to 6 carbon atoms, they may be all unsubstituted or substituted with one or more halogen atoms.
- These liquid crystal compounds can be used alone or in combination of two or more.
- liquid crystalline compounds can be used alone or in combination of two or more.
- liquid crystalline compounds can be used alone or in combination of two or more.
- the compounds represented by the general formula (4-a) are preferably compounds represented by the following formulas (4-a-1) to (4-a-26).
- liquid crystalline compounds can be used alone or in combination of two or more.
- R represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a cyano group.
- these groups are alkyl groups having 1 to 6 carbon atoms or alkoxy groups having 1 to 6 carbon atoms, they may be all unsubstituted or substituted with one or more halogen atoms.
- These liquid crystalline compounds can be used alone or in combination of two or more.
- n 1 to 10 carbon atoms.
- each n independently represents an integer of 1 to 10.
- R represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a cyano group.
- the group is an alkyl group having 1 to 6 carbon atoms or an alkoxy group having 1 to 6 carbon atoms, all of them may be unsubstituted or may be substituted with one or more halogen atoms.
- These liquid crystalline compounds can be used alone or in combination of two or more.
- the compounds represented by the general formula (6-a) are preferably compounds represented by the following formulas (6-a-1) to (6-a-25)
- liquid crystalline compounds can be used alone or in combination of two or more. You can also
- R represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, In the case where these groups are alkyl groups having 1 to 6 carbon atoms or alkoxy groups having 1 to 6 carbon atoms, they are all unsubstituted or substituted by one or more halogen atoms.
- These liquid crystalline compounds can be used alone or in combination of two or more.
- liquid crystalline compounds can be used alone or in combination of two or more.
- the compound represented by the general formula (7-b) is preferably a compound represented by the following formula (7-b-1) to (7-b-25).
- R represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or a cyano group. These groups are alkyl groups having 1 to 6 carbon atoms, or carbon atoms. In the case of the alkoxy groups of 1 to 6, all may be unsubstituted, or may be substituted by one or more halogen atoms.) These liquid crystalline compounds may be used alone. It can also be used in combination of two or more.
- the polymerizable compounds represented by the above formulas (2-a) to (7-a) are represented by the formula (I) Re (450 nm) / Re (550 nm) ⁇ 1.0 (I)
- Re (450 nm) is a wavelength of 450 nm when the compound having at least two polymerizable groups is oriented on the substrate so that the major axis direction of the molecule is substantially horizontal to the substrate.
- Re (550 nm) is a wavelength of 550 nm when the compound having at least two polymerizable groups is oriented on the substrate so that the major axis direction of the molecule is substantially horizontal to the substrate. It is preferable to satisfy the in-plane retardation at.
- the total content of the compound having at least two or more polymerizable groups is the total amount of the polymerizable compound used in the polymerizable composition (that is, the total content of the compound represented by the general formula (1) and 2 2 to 99% by mass, more preferably 10 to 85% by mass, and particularly preferably 20 to 80% by mass in the total content of the compounds having two or more polymerizable groups). preferable.
- the above formulas (2-a) to (7-) it is preferable to use one or more compounds selected from a), preferably 2 to 99% by mass, preferably 5 to 90% by mass, of the total amount of polymerizable compounds used in the polymerizable composition. It is more preferable to contain 20 to 80% by mass.
- one or more compounds selected from the above formulas (2-b) to (7-b) are used. It is preferably used, preferably 2 to 80% by mass, more preferably 10 to 90% by mass, and more preferably 20 to 99% by mass of the total amount of the polymerizable compound used in the polymerizable composition. Is particularly preferred.
- one or more compounds selected from the above formulas (2-a) to (7-a) are used.
- the total amount of compounds selected from (2-a) to formula (7-a) is preferably 25 to 95% by mass, more preferably 35 to 95% by mass, and 50 to 95% by mass.
- the total amount of the compounds selected from the formulas (2-b) to (7-b) is 25 to 95% by mass, and preferably 35 to 90% by mass. More preferably, the content is particularly preferably 50 to 80% by mass.
- the polymerizable composition of the present invention may contain an initiator as necessary.
- the polymerization initiator used in the polymerizable composition of the present invention is used for polymerizing the polymerizable composition of the present invention.
- the photopolymerization initiator used when the polymerization is carried out by light irradiation is not particularly limited, and has a polymerizable liquid crystalline compound represented by the general formula (1) and at least two polymerizable groups. A well-known and usual thing can be used in the grade which does not inhibit the orientation state of a polymeric liquid crystalline compound.
- a photoacid generator can be used as the photocationic initiator.
- the photoacid generator include diazodisulfone compounds, triphenylsulfonium compounds, phenylsulfone compounds, sulfonylpyridine compounds, triazine compounds, and diphenyliodonium compounds.
- the content of the photopolymerization initiator is the total content of the compounds represented by the general formula (1) and the total content of the compounds having two or more polymerizable groups used in the polymerizable composition of the present invention.
- the amount is preferably 0.1 to 10% by mass, particularly preferably 1 to 6% by mass, based on the total amount. These can be used alone or in combination of two or more.
- thermal polymerization initiator used in the thermal polymerization known ones can be used.
- methyl acetoacetate peroxide cumene hydroperoxide, benzoyl peroxide, bis (4-t-butylcyclohexyl) Peroxydicarbonate, t-butylperoxybenzoate, methyl ethyl ketone peroxide, 1,1-bis (t-hexylperoxy) 3,3,5-trimethylcyclohexane, p-pentahydroperoxide, t-butylhydro
- Organic peroxides such as peroxide, dicumyl peroxide, isobutyl peroxide, di (3-methyl-3-methoxybutyl) peroxydicarbonate, 1,1-bis (t-butylperoxy) cyclohexane, 2'-azobisisobutyronitrile, Azonitrile compounds such as 2,2′-azobis (2,4-dimethylvaleronitrile),
- the content of the thermal polymerization initiator is the total content of the compounds represented by the general formula (1) and the total content of the compounds having two or more polymerizable groups used in the polymerizable composition of the present invention.
- the amount is preferably from 0.1 to 10% by weight, particularly preferably from 1 to 6% by weight based on the total amount. These can be used alone or in combination of two or more.
- Organic solvent may contain an organic solvent as necessary. Although there is no limitation in particular as an organic solvent to be used, the organic solvent in which the said polymeric compound shows favorable solubility is preferable, and it is preferable that it is an organic solvent which can be dried at the temperature of 100 degrees C or less.
- solvents examples include aromatic hydrocarbons such as toluene, xylene, cumene, and mesitylene, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, cyclohexyl acetate, 3-butoxymethyl acetate, and ethyl lactate.
- aromatic hydrocarbons such as toluene, xylene, cumene, and mesitylene, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, cyclohexyl acetate, 3-butoxymethyl acetate, and ethyl lactate.
- Ester solvents such as methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, cyclopentanone, ether solvents such as tetrahydrofuran, 1,2-dimethoxyethane, anisole, N, N-dimethylformamide, N-methyl-2- Amido solvents such as pyrrolidone, ethylene glycol monomethyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monomethyl ether, propylene glycol diacetate, propylene glycol monomethyl Propyl ether, diethylene glycol monomethyl ether acetate, .gamma.-butyrolactone and chlorobenzene, and the like.
- ketone solvents such as methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, cyclopentanone
- ether solvents such as tetrahydrofuran,
- the ratio of the organic solvent to be used is not particularly limited as long as the applied state is not significantly impaired, since the polymerizable composition used in the present invention is usually applied by coating, but used in the polymerizable composition of the present invention.
- the content ratio of the total amount of the compound represented by the general formula (1) and the compound having two or more polymerizable groups is preferably 0.1 to 99% by mass, and 5 to 60% by mass. More preferably, the content is 10 to 50% by mass.
- the heating temperature at the time of heating and stirring may be appropriately adjusted in consideration of the solubility of the polymerizable liquid crystal compound to be used in the organic solvent, but is preferably 15 ° C. to 130 ° C., more preferably 30 ° C. to 110 ° C. from the viewpoint of productivity. 50 ° C. to 100 ° C. is particularly preferable.
- Additives The polymerizable composition of the present invention can be applied uniformly, or a general-purpose additive can be used according to each purpose.
- polymerization inhibitors for example, polymerization inhibitors, antioxidants, UV absorbers, leveling agents, alignment control agents, chain transfer agents, infrared absorbers, thixotropic agents, antistatic agents, dyes, fillers, chiral compounds, non-liquid crystals having polymerizable groups
- Additives such as liquid crystalline compounds, other liquid crystal compounds, and alignment materials can be added to the extent that the alignment of the liquid crystal is not significantly reduced.
- the polymeric composition of this invention can contain a polymerization inhibitor as needed. There is no limitation in particular as a polymerization inhibitor to be used, A well-known usual thing can be used.
- N'-diphenyl-p-phenylenediamine Ni-propyl-N'-phenyl-p-phenylenediamine, N- (1.3-dimethylbutyl) -N'-phenyl-p-phenylenediamine, N.I.
- Amine compounds such as N′-di-2-naphthyl-p-phenylenediamine, diphenylamine, N-phenyl- ⁇ -naphthylamine, 4.4′-dicumyl-diphenylamine, 4.4′-dioctyl-diphenylamine, phenothiazine, Thioether compounds such as distearyl thiodipropionate, N-nitrosodiphenylamine, N-nitrosophenylnaphthylamine, N-nitrosodinaphthylamine, p-nitrosophenol, nitrosobenzene, p-nitrosodiphenylamine, ⁇ -nitroso- ⁇ -naphthol N, N-dimethyl p-nitrosoaniline, p-nitrosodiphenylamine, p-nitronedimethylamine, p-nitrone-N, N-diethylamine, N
- the addition amount of the polymerization inhibitor is the total content of the compound represented by the general formula (1) used in the polymerizable composition of the present invention and the total content of the compound having two or more polymerizable groups.
- the content is preferably 0.01 to 2.0 mass%, more preferably 0.05 to 1.0 mass%, based on the total amount.
- Antioxidant The polymerizable composition of the present invention may contain an antioxidant or the like as necessary. Examples of such compounds include hydroquinone derivatives, nitrosamine polymerization inhibitors, hindered phenol antioxidants, and more specifically, tert-butyl hydroquinone, “Q-1300” manufactured by Wako Pure Chemical Industries, Ltd.
- the addition amount of the antioxidant is the total content of the compound represented by the general formula (1) used in the polymerizable composition of the present invention and the total content of the compound having two or more polymerizable groups.
- the content is preferably 0.01 to 2.0 mass%, more preferably 0.05 to 1.0 mass%, based on the total amount.
- Ultraviolet Absorber The polymerizable composition of the present invention can contain an ultraviolet absorber and a light stabilizer as necessary. Although the ultraviolet absorber and light stabilizer to be used are not particularly limited, those which improve light resistance such as an optical anisotropic body and an optical film are preferable.
- UV absorber examples include 2- (2-hydroxy-5-t-butylphenyl) -2H-benzotriazole “Tinuvin PS”, “Tinuvin 99-2”, “Tinuvin 109”, “TINUVIN 213”, “TINUVIN 234”, “TINUVIN 326”, “TINUVIN 328”, “TINUVIN 329”, “TINUVIN 384-2”, “TINUVIN 571”, 2- (2H-benzotriazol-2-yl) -4,6-bis (1-Methyl-1-phenylethyl) phenol “TINUVIN 900”, 2- (2H-benzotriazol-2-yl) -6- (1-methyl-1-phenylethyl) -4- (1,1,3 , 3-tetramethylbutyl) phenol “TINUVIN 928”, TINUVIN 1130, TINUVIN 400, TINUVIN 405, 2,4-bis [2-hydroxy-4-butoxyphenyl] -6- (2,4-dibutoxyphenyl) -1
- Examples of the light stabilizer include “TINUVIN 111FDL”, “TINUVIN 123”, “TINUVIN 144”, “TINUVIN 152”, “TINUVIN 292”, “TINUVIN 622”, “TINUVIN 770”, “TINUVIN 765”, “TINUVIN 780”.
- the polymerizable composition of the present invention may contain a leveling agent as required.
- the leveling agent to be used is not particularly limited, but a leveling agent is preferably used in order to reduce film thickness unevenness when forming a thin film such as an optical anisotropic body or an optical film.
- leveling agent examples include alkyl carboxylates, alkyl phosphates, alkyl sulfonates, fluoroalkyl carboxylates, fluoroalkyl phosphates, fluoroalkyl sulfonates, polyoxyethylene derivatives, fluoroalkylethylene oxide derivatives, polyethylene Examples include glycol derivatives, alkyl ammonium salts, and fluoroalkyl ammonium salts.
- the addition amount of the leveling agent is the total amount of the total content of the compound represented by the general formula (1) and the compound having two or more polymerizable groups used in the polymerizable composition of the present invention.
- the content is preferably 0.01 to 2% by mass, more preferably 0.05 to 0.5% by mass.
- the polymerizable composition of the present invention can contain an alignment control agent in order to control the alignment state of the liquid crystal compound.
- the alignment control agent to be used include those in which the liquid crystalline compound is substantially horizontally aligned, substantially vertically aligned, or substantially hybridly aligned with respect to the substrate.
- a chiral compound when a chiral compound is added, those which are substantially planarly oriented can be mentioned. As described above, horizontal alignment and planar alignment may be induced by the surfactant, but there is no particular limitation as long as each alignment state is induced, and a known and conventional one should be used. Can do.
- a weight average molecular weight having a repeating unit represented by the following general formula (8) having an effect of effectively reducing the tilt angle of the air interface when an optical anisotropic body is used Is a compound having a molecular weight of 100 or more and 1000000 or less.
- R 11 , R 12 , R 13 and R 14 each independently represents a hydrogen atom, a halogen atom or a hydrocarbon group having 1 to 20 carbon atoms, and one hydrocarbon atom in the hydrocarbon group
- R 11 , R 12 , R 13 and R 14 each independently represents a hydrogen atom, a halogen atom or a hydrocarbon group having 1 to 20 carbon atoms, and one hydrocarbon atom in the hydrocarbon group
- R 11 , R 12 , R 13 and R 14 each independently represents a hydrogen atom, a halogen atom or a hydrocarbon group having 1 to 20 carbon atoms, and one hydrocarbon atom in the hydrocarbon group
- a rod-like liquid crystal compound modified with a fluoroalkyl group a discotic liquid crystal compound, a polymerizable compound containing a long-chain aliphatic alkyl group which may have a branched structure, and the like are also included.
- the polymerizable composition of the present invention can contain a chain transfer agent in order to further improve the adhesion between the polymer or optical anisotropic body and the substrate.
- Chain transfer agents include aromatic hydrocarbons, halogenated hydrocarbons such as chloroform, carbon tetrachloride, carbon tetrabromide, bromotrichloromethane, Mercaptan compounds such as octyl mercaptan, n-butyl mercaptan, n-pentyl mercaptan, n-hexadecyl mercaptan, n-tetradecyl merc, n-dodecyl mercaptan, t-tetradecyl mercaptan, t-dodecyl mercaptan, hexanedithiol, decandithiol 1,4-butanediol bisthiopropionate, 1,4-butanediol bisthioglycolate, ethylene glycol bisthioglycolate, ethylene glycol bisthiopropionate, trimethylolpropane tristhiogly
- R 95 represents an alkyl group having 2 to 18 carbon atoms, and the alkyl group may be linear or branched, and one or more methylene groups in the alkyl group are oxygen atoms.
- a sulfur atom that is not directly bonded to each other may be substituted with an oxygen atom, a sulfur atom, —CO—, —OCO—, —COO—, or —CH ⁇ CH—
- R 96 is a carbon atom Represents an alkylene group of 2 to 18, and one or more methylene groups in the alkylene group are oxygen atoms, sulfur atoms, —CO—, —OCO—, wherein oxygen atoms and sulfur atoms are not directly bonded to each other.
- —COO—, or —CH ⁇ CH— may be substituted.
- the chain transfer agent is preferably added in the step of mixing the polymerizable liquid crystal compound in an organic solvent and heating and stirring to prepare a polymerizable solution, but is added in the subsequent step of mixing the polymerization initiator in the polymerizable solution. It may be added in both steps.
- the addition amount of the chain transfer agent is the total content of the compound represented by the general formula (1) used in the polymerizable composition of the present invention and the total content of the compound having two or more polymerizable groups.
- the content is preferably from 0.1 to 10% by mass, more preferably from 1.0 to 5.0% by mass, based on the total amount.
- liquid crystal compounds that are not polymerizable can be added as necessary to adjust the physical properties.
- a polymerizable compound having no liquid crystallinity is preferably added in the step of preparing a polymerizable solution by mixing the polymerizable compound with an organic solvent and stirring under heating. You may add in the process of mixing a polymerization initiator with a solution, and may add in both processes.
- the addition amount of these compounds is the total content of the compound represented by the general formula (1) and the total content of the compounds having two or more polymerizable groups used in the polymerizable composition of the present invention. 20 mass% or less is preferable with respect to the total amount, 10 mass% or less is more preferable, and 5 mass% or less is still more preferable.
- the polymerizable composition of the present invention can contain an infrared absorber as necessary.
- the infrared absorber to be used is not particularly limited, and any known and conventional one can be contained within a range not disturbing the orientation.
- Examples of the infrared absorber include cyanine compounds, phthalocyanine compounds, naphthoquinone compounds, dithiol compounds, diimmonium compounds, azo compounds, and aluminum salts.
- the polymerizable composition of the present invention can contain an antistatic agent as necessary.
- the antistatic agent to be used is not particularly limited, and a known and commonly used antistatic agent can be contained as long as the orientation is not disturbed.
- an antistatic agent examples include a polymer compound having at least one sulfonate group or phosphate group in the molecule, a compound having a quaternary ammonium salt, a surfactant having a polymerizable group, and the like.
- surfactants having a polymerizable group are preferred.
- anionic surfactants such as “Antox SAD” and “Antox MS-2N” Made by company), “AQUALON KH-05”, “AQUALON KH-10”, “AQUALON KH-20”, “AQUALON KH-0530”, “AQUALON KH-1025” (above, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.), Alkyl ethers such as “ADEKA rear soap SR-10N”, “ADEKA rear soap SR-20N” (manufactured by ADEKA Corporation), “Latemul PD-104” (manufactured by Kao Corporation), etc., “Latemuru S-120” “Latemul S-120A”, “Latemul S-180P”, “Latemul S-180A” (manufactured by Kao Corporation), “Eleminor” S-2 "(manufactureured by Kao Corporation), “Eleminor” S-2 "(
- nonionic surfactants having a polymerizable group include, for example, “Antox LMA-20”, “Antox LMA-27”, “Antox EMH-20”, “Antox LMH— 20, “Antox SMH-20” (manufactured by Nippon Emulsifier Co., Ltd.), “Adekalia Soap ER-10”, “Adekalia Soap ER-20”, “Adekalia Soap ER-30”, “Adekalia Soap” ER-40 "(above, manufactured by ADEKA Corporation),” Latemul PD-420 “,” Latemuru PD-430 “,” Latemuru PD-450 “(above, manufactured by Kao Corporation), etc.
- RN-10 Aqualon RN-20, Aqualon RN-30, Aqualon RN-50, Aqualon RN-2025 ( (Daiichi Kogyo Seiyaku Co., Ltd.), “Adekalia Soap NE-10”, “Adekalia Soap NE-20”, “Adekalia Soap NE-30”, “Adekalia Soap NE-40” (Meth) acrylate sulfuric acid such as alkylphenyl ether type or alkylphenyl ester type such as “RMA-564”, “RMA-568”, “RMA-1114” (above, manufactured by Nippon Emulsifier Co., Ltd.) An ester type is mentioned.
- antistatic agents examples include polyethylene glycol (meth) acrylate, methoxypolyethylene glycol (meth) acrylate, ethoxypolyethylene glycol (meth) acrylate, propoxypolyethylene glycol (meth) acrylate, and n-butoxypolyethylene glycol (meth) acrylate.
- the antistatic agent can be used alone or in combination of two or more.
- the addition amount of the antistatic agent is the total content of the compound represented by the general formula (1) and the compound having two or more polymerizable groups used in the polymerizable composition of the present invention. Is preferably 0.001 to 10% by weight, more preferably 0.01 to 5% by weight, based on the total amount of the polymerizable composition.
- the polymerizable composition of the present invention may contain a dye as necessary.
- the dye to be used is not particularly limited, and may include known and commonly used dyes as long as the orientation is not disturbed.
- the dye examples include dichroic dyes and fluorescent dyes.
- examples of such dyes include polyazo dyes, anthraquinone dyes, cyanine dyes, phthalocyanine dyes, perylene dyes, perinone dyes, squarylium dyes and the like.
- the dye is preferably a liquid crystal dye. .
- dichroic dye examples include the following formulas (d-1) to (d-8)
- the added amount of the dye such as the dichroic dye is a compound having the total content of the compound represented by the general formula (1) and the two or more polymerizable groups used in the polymerizable composition of the present invention. Is preferably 0.001 to 20% by weight, more preferably 0.01 to 10% by weight, based on the total amount of the above.
- the polymerizable composition of the present invention may contain a filler as necessary.
- the filler to be used is not particularly limited, and may contain known and commonly used fillers as long as the thermal conductivity of the obtained polymer is not lowered.
- the filler examples include inorganic fillers such as alumina, titanium white, aluminum hydroxide, talc, clay, mica, barium titanate, zinc oxide, and glass fiber, metal powder such as silver powder and copper powder, aluminum nitride, and nitride.
- thermally conductive fillers such as boron, silicon nitride, gallium nitride, silicon carbide, magnesia (aluminum oxide), silica, crystalline silica (silicon oxide), fused silica (silicon oxide), graphite, carbon fibers including carbon nanofibers, etc. Silver nanoparticles and the like.
- DAM-70, DAM-45, DAM-07, DAM-05, DAW-45, DAW-05, DAW-03, ASFP-20 (above, manufactured by Denki Kagaku Kogyo Co., Ltd.), AL -43-KT, AL-47-H, AL-47-1, AL-160SG-3, AL-43-BE, AS-30, AS-40, AS-50, AS-400, CB-P02, CB -P05 (above, Showa Denko KK), A31, A31B, A32, A33F, A41A, A43A, MM-22, MM-26, MM-P, MM-23B, LS-110F, LS-130, LS- 210, LS-242C, LS-250, AHP300 (manufactured by Nippon Light Metal Co., Ltd.), AA-03, AA-04, AA-05, AA-07, AA-2, AA-5, AA-1
- the filler can be used alone or in combination of two or more.
- the added amount of the filler is the total amount of the total content of the compound represented by the general formula (1) and the compound having two or more polymerizable groups, which is used in the polymerizable composition of the present invention. On the other hand, it is preferably 0.01 to 80% by weight, more preferably 0.1 to 50% by weight.
- p) Chiral Compound The polymerizable composition of the present invention may contain a chiral compound for the purpose of obtaining a chiral nematic phase. The chiral compound itself does not need to exhibit liquid crystallinity, and may or may not have a polymerizable group. Moreover, the direction of the spiral of the chiral compound can be appropriately selected depending on the intended use of the polymer.
- the chiral compound having a polymerizable group is not particularly limited and known and conventional compounds can be used, but a chiral compound having a large helical twisting power (HTP) is preferred.
- the polymerizable group is preferably a vinyl group, a vinyloxy group, an allyl group, an allyloxy group, an acryloyloxy group, a methacryloyloxy group, a glycidyl group, or an oxetanyl group, and particularly preferably an acryloyloxy group, a glycidyl group, or an oxetanyl group.
- the compounding amount of the chiral compound needs to be appropriately adjusted depending on the helical induction force of the compound, but it should be contained in an amount of 0.5 to 80% by mass based on the total amount of the liquid crystalline compound having a polymerizable group and the chiral compound.
- the content is preferably 3 to 50% by mass, more preferably 5 to 30% by mass.
- chiral compound examples include compounds represented by the following general formulas (10-1) to (10-4), but are not limited to the following general formulas.
- Sp 5a and Sp 5b each independently represent an alkylene group having 0 to 18 carbon atoms, and the alkylene group is a carbon atom having one or more halogen atoms, CN groups, or polymerizable functional groups.
- A5 and A6 are each independently 1,4-phenylene group, 1,4-cyclohexylene group, 1,4-cyclohexenyl group, tetrahydropyran-2,5-diyl group, 1,3-dioxane-2,5-diyl group, tetrahydrothiopyran-2,5-diyl group, 1,4-bicyclo (2,2,2) octylene group, decahydronaphthalene-2,6-diyl
- R 5a and R 5b represent a hydrogen atom, a halogen atom, a cyano group, or an alkyl group having 1 to 18 carbon atoms, and the alkyl group may be substituted with one or more halogen atoms or CN.
- R 5a and R 5b are represented by the general formula (10-a)
- P 5a represents a polymerizable functional group
- Sp 5a represents the same meaning as Sp 1
- P 5a represents a substituent selected from the polymerizable groups represented by the following formulas (P-1) to (P-20).
- chiral compound examples include compounds represented by the following general formulas (10-5) to (10-38).
- n and n each independently represents an integer of 1 to 10
- R represents a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, or a fluorine atom. These may be the same or different.
- chiral compound having no polymerizable group examples include, for example, pelargonic acid cholesterol having a cholesteryl group as a chiral group, cholesterol stearate, and a product of BDH having a 2-methylbutyl group as a chiral group.
- the value obtained by dividing the thickness (d) of the obtained polymer by the helical pitch (P) in the polymer (d / P) is preferably added in an amount ranging from 0.1 to 100, more preferably from 0.1 to 20.
- q) Non-Liquid Crystalline Compound Having a Polymerizable Group The polymerizable composition of the present invention can be added with a compound having a polymerizable group but not a liquid crystal compound. Such a compound can be used without particular limitation as long as it is generally recognized as a polymerizable monomer or polymerizable oligomer in this technical field. When added, the total content of the compound represented by the general formula (1) and the total content of the compounds having two or more polymerizable groups used in the polymerizable composition of the present invention is used. 15 mass% or less, preferably 10 mass% or less.
- the polymerizable composition of the present invention is polymerizable having one polymerizable group in addition to the polymerizable liquid crystalline compound having one polymerizable group represented by the general formula (1).
- Compounds can be included. However, if the addition amount is too large, the optical properties of the obtained optical anisotropic body may be deteriorated.
- it is represented by the general formula (1) used for the polymerizable composition of the present invention. Is preferably 30% by mass or less, more preferably 10% by mass or less, and further preferably 5% by mass or less, based on the total content of the compounds and the total content of the compounds having two or more polymerizable groups. Particularly preferred.
- liquid crystalline compounds examples include the following formulas (11-1) to (11-43).
- m11 and n11 each independently represent an integer of 1 to 10
- R 111 and R 112 each independently represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, or a fluorine atom.
- R 113 is a hydrogen atom, fluorine atom, chlorine atom, bromine atom, iodine atom, pentafluorosulfuranyl group, cyano group, nitro group, isocyano group, thioisocyano group, or one —CH 2 — or adjacent Two or more —CH 2 — are each independently —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—.
- the polymerizable composition of the present invention can contain an alignment material whose orientation is improved in order to improve the orientation.
- the alignment material to be used may be a known and usual one as long as it is soluble in a solvent capable of dissolving the liquid crystalline compound having a polymerizable group used in the polymerizable composition of the present invention. It can be added as long as the orientation is not significantly deteriorated.
- the total content of the compound represented by the general formula (1) and the total content of the compound having two or more polymerizable groups used in the polymerizable composition of the present invention 0.05 to 30% by weight, preferably 0.5 to 15% by weight, more preferably 1 to 10% by weight.
- the alignment material is polyimide, polyamide, BCB (Penzocyclobutene Polymer), polyvinyl alcohol, polycarbonate, polystyrene, polyphenylene ether, polyarylate, polyethylene terephthalate, polyether sulfone, epoxy resin, epoxy acrylate resin, acrylic Resin, coumarin compound, chalcone compound, cinnamate compound, fulgide compound, anthraquinone compound, azo compound, arylethene compound, and other compounds that can be photoisomerized or photodimerized, but materials that are oriented by UV irradiation or visible light irradiation (Photo-alignment material) is preferable.
- photo-alignment material examples include polyimide having a cyclic cycloalkane, wholly aromatic polyarylate, polyvinyl cinnamate as disclosed in JP-A-5-232473, polyvinyl ester of paramethoxycinnamic acid, and JP-A-6-6. 287453, cinnamate derivatives as shown in JP-A-6-289374, maleimide derivatives as shown in JP-A-2002-265541, and the like. Specifically, compounds represented by the following formulas (12-1) to (12-9) are preferable.
- R 5 represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 3 carbon atoms, an alkoxy group or a nitro group
- R 6 represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.
- the group may be linear or branched, and any hydrogen atom in the alkyl group may be substituted with a fluorine atom, and one —CH 2 — or adjacent group in the alkyl group may be substituted.
- Two or more —CH 2 — that are not present are each independently —O—, —S—, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O.
- n 4 to 100,000
- m represents an integer of 1 to 12.
- R 7 represents a hydrogen atom, a halogen atom, a halogenated alkyl group, an allyloxy group, a cyano group, a nitro group, an alkyl group, a hydroxyalkyl group, an alkoxy group, a carboxy group or an alkali metal salt thereof, an alkoxycarbonyl group, a halogenated methoxy group.
- the polymer of the present invention is obtained by polymerizing the polymerizable composition of the present invention in a state containing an initiator.
- the polymer of the present invention is used for optical anisotropic bodies, retardation films, lenses, colorants, printed materials and the like.
- optical anisotropic body manufacturing method (Optical anisotropic)
- the polymerizable composition of the present invention is applied to a substrate or a substrate having an alignment function, and the liquid crystalline compound molecules in the polymerizable composition of the present invention are retained in a nematic phase or a smectic phase. By uniformly aligning and polymerizing, the optical anisotropic body of the present invention is obtained.
- the polymerizable composition of the present invention containing a material having a photo-alignment function such as an azo derivative, a chalcone derivative, a coumarin derivative, a cinnamate derivative, or a cycloalkane derivative, is applied to a base material.
- a material having a photo-alignment function such as an azo derivative, a chalcone derivative, a coumarin derivative, a cinnamate derivative, or a cycloalkane derivative.
- the optically anisotropic body of the present invention can also be obtained by uniformly aligning and polymerizing the liquid crystalline compound molecules in the state in which the nematic phase or smectic phase is maintained.
- the base material used for the optical anisotropic body of the present invention is a base material usually used for liquid crystal display elements, organic light emitting display elements, other display elements, optical components, colorants, markings, printed matter and optical films, If it is the material which has heat resistance which can endure the heating at the time of drying after application
- base materials include glass base materials, metal base materials, ceramic base materials, plastic base materials, and organic materials such as paper.
- the substrate when the substrate is an organic material, examples thereof include cellulose derivatives, polyolefins, polyesters, polyolefins, polycarbonates, polyacrylates, polyarylates, polyether sulfones, polyimides, polyphenylene sulfides, polyphenylene ethers, nylons, and polystyrenes.
- plastic substrates such as polyester, polystyrene, polyolefin, cellulose derivatives, polyarylate, and polycarbonate are preferable.
- a shape of a base material you may have a curved surface other than a flat plate. These base materials may have an electrode layer, an antireflection function, and a reflection function as needed.
- surface treatment of these substrates may be performed.
- the surface treatment include ozone treatment, plasma treatment, corona treatment, silane coupling treatment, and the like.
- an organic thin film, an inorganic oxide thin film, a metal thin film, etc. are provided on the surface of the substrate by a method such as vapor deposition, or in order to add optical added value.
- the material may be a pickup lens, a rod lens, an optical disk, a retardation film, a light diffusion film, a color filter, or the like.
- a pickup lens, a retardation film, a light diffusion film, and a color filter that have higher added value are preferable.
- Orientation treatment Moreover, even if the said base material is normally orientated or the orientation film
- the alignment treatment include stretching treatment, rubbing treatment, polarized ultraviolet visible light irradiation treatment, ion beam treatment, oblique deposition treatment of SiO 2 on the substrate, and the like.
- the alignment film is used, a known and conventional alignment film is used.
- Such alignment films include polyimide, polysiloxane, polyamide, polyvinyl alcohol, polycarbonate, polystyrene, polyphenylene ether, polyarylate, polyethylene terephthalate, polyethersulfone, epoxy resin, epoxy acrylate resin, acrylic resin, azo compound, coumarin.
- Examples thereof include compounds such as compounds, chalcone compounds, cinnamate compounds, fulgide compounds, anthraquinone compounds, azo compounds and arylethene compounds, and polymers and copolymers of the above compounds.
- the compound subjected to the alignment treatment by rubbing is preferably an alignment treatment or a compound in which crystallization of the material is promoted by inserting a heating step after the alignment treatment.
- liquid crystal molecules when a liquid crystal composition is brought into contact with a substrate having an alignment function, the liquid crystal molecules are aligned along the direction in which the substrate is aligned in the vicinity of the substrate. Whether the liquid crystal molecules are aligned horizontally with respect to the substrate or inclined or perpendicular to the substrate is greatly influenced by the alignment treatment method for the substrate. For example, when an alignment film having a very small pretilt angle as used in an in-plane switching (IPS) type liquid crystal display element is provided on a substrate, a polymerizable liquid crystal layer aligned substantially horizontally can be obtained.
- IPS in-plane switching
- Application methods for obtaining the optical anisotropic body of the present invention include applicator method, bar coating method, spin coating method, roll coating method, direct gravure coating method, reverse gravure coating method, flexo coating method, ink jet method, and die coating. Methods, cap coating methods, dip coating methods, slit coating methods, spray coating methods, and the like can be used. After applying the polymerizable composition, it is dried.
- the liquid crystal molecules in the polymerizable composition of the present invention are preferably uniformly aligned while maintaining the smectic phase or nematic phase.
- One of the methods is a heat treatment method. Specifically, after coating the polymerizable composition of the present invention on a substrate, the N (nematic phase) -I (isotropic liquid phase) transition temperature (hereinafter abbreviated as the NI transition temperature) of the liquid crystal composition. ) By heating to the above, the liquid crystal composition is brought into an isotropic liquid state. From there, it is gradually cooled as necessary to develop a nematic phase.
- a heat treatment may be performed such that the temperature is maintained for a certain time within a temperature range in which the nematic phase of the polymerizable composition of the present invention is expressed.
- the heating temperature is too high, the polymerizable liquid crystal compound may deteriorate due to an undesirable polymerization reaction. Moreover, when it cools too much, a polymeric composition raise
- the liquid crystal phase is cooled to a minimum temperature at which phase separation does not occur, that is, is supercooled, and polymerization is performed in a state where the liquid crystal phase is aligned at the temperature.
- the polymerization treatment of the dried polymerizable composition is generally performed by light irradiation such as visible ultraviolet rays or heating in a uniformly oriented state.
- the polymerization is performed by light irradiation, specifically, it is preferable to irradiate visible ultraviolet light having a wavelength of 420 nm or less, and most preferable to irradiate ultraviolet light having a wavelength of 250 to 370 nm.
- the polymerizable composition causes decomposition or the like due to visible ultraviolet light of 420 nm or less, it may be preferable to perform polymerization treatment with visible ultraviolet light of 420 nm or more.
- Examples of the method for polymerizing the polymerizable composition of the present invention include a method of irradiating active energy rays and a thermal polymerization method.
- the reaction proceeds at room temperature without requiring heating, and the active energy rays are irradiated.
- a method of irradiating light such as ultraviolet rays is preferable because the operation is simple.
- the temperature at the time of irradiation is preferably set to 30 ° C. or less as much as possible in order to avoid the induction of thermal polymerization of the polymerizable composition by setting the temperature at which the polymerizable composition of the present invention can maintain the liquid crystal phase.
- the polymerizable liquid crystal composition usually has a temperature within the range from the C (solid phase) -N (nematic) transition temperature (hereinafter abbreviated as the CN transition temperature) to the NI transition temperature range during the temperature rising process. Shows liquid crystal phase.
- the liquid crystal composition in a supercooled state is also included in the state in which the liquid crystal phase is retained. Specifically, irradiation with ultraviolet light of 390 nm or less is preferable, and irradiation with light having a wavelength of 250 to 370 nm is most preferable.
- the polymerizable composition causes decomposition or the like due to ultraviolet light of 390 nm or less
- This light is preferably diffused light and unpolarized light.
- the ultraviolet irradiation intensity is preferably in the range of 0.05 mW / cm 2 to 10 W / cm 2 . In particular, the range of 0.2 mW / cm 2 to 2 W / cm 2 is preferable. When the ultraviolet intensity is less than 0.05 mW / cm 2 , it takes a lot of time to complete the polymerization.
- the ultraviolet irradiation amount is preferably in the range of 10mJ / cm 2 ⁇ 20J / cm 2, more preferably 50mJ / cm 2 ⁇ 10J / cm 2, 100mJ / cm 2 ⁇ 5J / cm 2 is particularly preferred.
- the orientation state of the unpolymerized part is changed by applying an electric field, a magnetic field or temperature, and then the unpolymerized part is polymerized.
- An optical anisotropic body having a plurality of regions having orientation directions can also be obtained.
- the alignment was regulated in advance by applying an electric field, magnetic field or temperature to the unpolymerized polymerizable liquid crystal composition, and the state was maintained.
- An optical anisotropic body having a plurality of regions having different orientation directions can also be obtained by irradiating light from above the mask and polymerizing it.
- optical anisotropic body obtained by polymerizing the polymerizable composition of the present invention can be peeled off from the substrate and used alone as an optical anisotropic body, or can be used as an optical anisotropic body as it is without peeling from the substrate. You can also In particular, since it is difficult to contaminate other members, it is useful when used as a laminated substrate or by being attached to another substrate.
- the optical anisotropic body can be subjected to a heat aging treatment. In this case, it is preferable to heat above the glass transition point of the prepolymerizable liquid crystal film. Usually, 50 to 300 ° C. is preferable, 80 to 240 ° C. is more preferable, and 100 to 220 ° C. is more preferable.
- the retardation film of the present invention contains the optical anisotropic body, and the liquid crystalline compound forms a uniform continuous alignment state with respect to the substrate, and is in-plane with respect to the substrate. It is only necessary to have biaxiality outside, in-plane and out-of-plane, or in-plane.
- an adhesive, an adhesive layer, an adhesive, an adhesive layer, a protective film, a polarizing film, or the like may be laminated.
- a retardation film for example, a positive A plate in which a rod-like liquid crystalline compound is substantially horizontally aligned with respect to a base material, and a negative A plate in which a disk-like liquid crystalline compound is vertically uniaxially oriented with respect to a base material
- a positive C plate in which rod-like liquid crystalline compounds are aligned substantially vertically with respect to the substrate, a rod-like liquid crystalline compound is cholesteric aligned with respect to the substrate, or a negative C in which disc-like liquid crystalline compounds are horizontally aligned uniaxially.
- An orientation mode of a plate, a biaxial plate, a positive O plate in which a rod-like liquid crystalline compound is hybrid-aligned with respect to a substrate, and a negative O plate in which a disc-like liquid crystalline compound is hybrid-aligned with respect to a substrate can be applied.
- various orientation modes can be applied without particular limitation as long as the viewing angle dependency is improved.
- orientation modes of positive A plate, negative A plate, positive C plate, negative C plate, biaxial plate, positive O plate, and negative O plate can be applied.
- the liquid crystal medium of the liquid crystal display element is in the vertical alignment (VA) mode
- VA vertical alignment
- a positive A plate as the first retardation layer in order to compensate the viewing angle dependence of polarization axis orthogonality and widen the viewing angle.
- the positive A plate has a refractive index in the in-plane slow axis direction of the film as nx, a refractive index in the in-plane fast axis direction of the film as ny, and a refractive index in the thickness direction of the film as nz.
- the positive A plate preferably has an in-plane retardation value in the range of 30 to 500 nm at a wavelength of 550 nm.
- the thickness direction retardation value is not particularly limited.
- the Nz coefficient is preferably in the range of 0.5 to 1.5.
- a so-called negative C plate having negative refractive index anisotropy as the second retardation layer.
- a negative C plate may be laminated on a positive A plate.
- the negative C plate has a refractive index nx in the in-plane slow axis direction of the retardation layer, ny in the in-plane fast axis direction of the retardation layer, and a refractive index in the thickness direction of the retardation layer.
- the thickness direction retardation value of the negative C plate is preferably in the range of 20 to 400 nm.
- the refractive index anisotropy in the thickness direction is represented by a thickness direction retardation value Rth defined by the following formula (2).
- a thickness direction retardation value Rth an in-plane retardation value R 0 , a retardation value R 50 measured with a slow axis as an inclination axis and an inclination of 50 °, a film thickness d, and an average refractive index n 0 of the film are used.
- nx, ny, and nz can be obtained by numerical calculation from the equation (1) and the following equations (4) to (7), and these can be substituted into the equation (2).
- R 0 (nx ⁇ ny) ⁇ d (1)
- Rth [(nx + ny) / 2 ⁇ nz] ⁇ d (2)
- Nz coefficient (nx ⁇ nz) / (nx ⁇ ny) (3)
- R 50 (nx ⁇ ny ′) ⁇ d / cos ( ⁇ ) (4)
- ny ′ ny ⁇ nz / [ny 2 ⁇ sin 2 ( ⁇ ) + nz 2 ⁇ cos 2 ( ⁇ )] 1/2 (7)
- the numerical calculation shown here is automatically performed in the device, and the in-plane retardation value R0 , the thickness direction retardation value Rth, etc. are automatically displayed. There are many.
- An example of such a measuring apparatus is RETS-100 (manufactured by Ots, etc
- the liquid crystal medium of the liquid crystal display element is in an in-plane switching (IPS) mode or a fringe field switching (FFS) mode
- IPS in-plane switching
- FFS fringe field switching
- a positive A plate and / or a positive C plate it is more preferable to use a positive A plate and / or a positive C plate, and it is particularly preferable to stack a positive A plate and a positive C plate.
- a positive A plate as the first retardation layer.
- the positive A plate has a refractive index in the in-plane slow axis direction of the film as nx, a refractive index in the in-plane fast axis direction of the film as ny, and a refractive index in the thickness direction of the film as nz,
- the positive A plate preferably has an in-plane retardation value in the range of 10 to 300 nm at a wavelength of 550 nm.
- the thickness direction retardation value is not particularly limited.
- the Nz coefficient is preferably in the range of 0.9 to 1.1.
- a so-called positive C plate having positive refractive index anisotropy as the second retardation layer.
- a positive C plate may be laminated on the positive A plate.
- the thickness direction retardation value of the positive C plate is preferably in the range of 10 to 300 nm.
- the refractive index anisotropy in the thickness direction is represented by a thickness direction retardation value Rth defined by the equation (2).
- the thickness direction retardation value Rth is an in-plane retardation value R 0 , and is 50 with the slow axis as the tilt axis.
- the Nz coefficient can be calculated from the equation (3). The same applies to other descriptions in the present specification.
- R 0 (nx ⁇ ny) ⁇ d (1)
- Rth [(nx + ny) / 2 ⁇ nz] ⁇ d (2)
- Nz coefficient (nx ⁇ nz) / (nx ⁇ ny) (3)
- R 50 (nx ⁇ ny ′) ⁇ d / cos ( ⁇ ) (4)
- ny ′ ny ⁇ nz / [ny 2 ⁇ sin 2 ( ⁇ ) + nz 2 ⁇ cos 2 ( ⁇ )] 1/2 (7)
- the retardation film of the present invention can also be used as a circularly polarizing plate by combining with a linearly polarizing plate.
- the retardation film of the present invention is a positive A plate in which the polymerizable liquid crystalline compound is substantially horizontally aligned with respect to the substrate, and the polarizing axis of the linearly polarizing plate and the retardation film
- the angle formed by the slow axis is preferably substantially 45 °.
- the retardation film of the present invention can also be used as a wave plate.
- the retardation film of the present invention is a positive A plate in which a polymerizable liquid crystalline compound is substantially horizontally aligned with respect to a substrate, and is used as a half wave plate or a quarter wave plate. It is preferred to use.
- the retardation film of the present invention can also be used as a polarizing reflection film or an infrared reflection film.
- the rod-like liquid crystalline compound in the retardation film of the present invention, is substantially cholesterically oriented in the horizontal direction with respect to the base material.
- the pitch is preferably in the infrared region.
- the polymerizable composition of the present invention is coated on a base material or a base material having an orientation function, or injected into a lens-shaped mold, and uniformly oriented while maintaining a nematic phase or a smectic phase. By polymerizing, it can be used for the lens of the present invention.
- Examples of the shape of the lens include a simple cell type, a prism type, and a lenticular type.
- the polymerizable composition of the present invention is coated on a substrate or a substrate having an alignment function, and is uniformly aligned and polymerized while maintaining a nematic phase or a smectic phase. It can be used for an element.
- Examples of usage forms include optical compensation films, patterned retardation films for liquid crystal stereoscopic display elements, retardation correction layers for color filters, overcoat layers, alignment films for liquid crystal media, and the like.
- the liquid crystal display element has a liquid crystal medium layer, a TFT drive circuit, a black matrix layer, a color filter layer, a spacer, and a liquid crystal medium layer at least sandwiched by corresponding electrode circuits on at least two base materials.
- the layer, the polarizing plate layer, and the touch panel layer are arranged outside the two substrates, but in some cases, the optical compensation layer, the overcoat layer, the polarizing plate layer, and the electrode layer for the touch panel are narrowed in the two substrates. May be held.
- Alignment modes of liquid crystal display elements include TN mode, VA mode, IPS mode, FFS mode, OCB mode, etc.
- a phase difference corresponding to the orientation mode is used.
- the liquid crystalline compound in the polymerizable composition may be substantially horizontally aligned with the substrate.
- a liquid crystalline compound having more polymerizable groups in one molecule may be thermally polymerized.
- the organic light emitting display of the present invention can be used for an element.
- it can be used as an antireflection film of an organic light emitting display element by combining the retardation film obtained by the polymerization and a polarizing plate.
- the angle formed by the polarizing axis of the polarizing plate and the slow axis of the retardation film is preferably about 45 °.
- the polarizing plate and the retardation film may be bonded together with an adhesive or a pressure-sensitive adhesive. Moreover, you may laminate
- the polarizing plate used at this time may be a film having a polarizing function, for example, a film obtained by stretching a polyvinyl alcohol film by adsorbing iodine or a dichroic dye, or a film obtained by stretching a polyvinyl alcohol film.
- Examples thereof include a film on which a dichroic dye or a dichroic dye is adsorbed, a film in which an aqueous solution containing a dichroic dye is coated on a substrate to form a polarizing layer, and a wire grid polarizer.
- polyvinyl alcohol resin a saponified polyvinyl acetate resin
- polyvinyl acetate resin in addition to polyvinyl acetate which is a homopolymer of vinyl acetate, polyvinyl acetate and Examples thereof include copolymers with other copolymerizable monomers. Examples of other monomers copolymerizable with vinyl acetate include unsaturated carboxylic acids, olefins, vinyl ethers, unsaturated sulfonic acids, and acrylamides having an ammonium group.
- the method for forming a polyvinyl alcohol-based resin is not particularly limited, and can be formed by a known method.
- the thickness of the polyvinyl alcohol-based raw film is not particularly limited, but is, for example, about 10 to 150 ⁇ m.
- iodine When iodine is used as the dichroic dye, a method of dyeing a polyvinyl alcohol-based resin film in an aqueous solution containing iodine and potassium iodide is usually employed.
- a dichroic dye When a dichroic dye is used as the dichroic dye, a method of immersing and dyeing a polyvinyl alcohol-based resin film in an aqueous solution containing a water-soluble dichroic dye is usually employed.
- examples of the dichroic dye to be applied are direct dyes, acid dyes, etc., depending on the type of substrate used Water-soluble dyes and their salt salts and disperse dyes, and water-insoluble pigments such as oil-soluble additives. These dyes are usually dissolved in water and an organic solvent, and in some cases, a surfactant is added to the base material which has been subjected to rubbing and corona treatment.
- the organic solvent varies depending on the solvent resistance of the substrate, but in general, alcohols such as methanol, ethanol and isopropyl alcohol, cellosolves such as methyl cellosolve and ethyl cellosolve, ketone cheeks such as acetone and methyl ethyl ketone, dimethylforma And amides such as N-methylpyrrolidone, and aromatic organic solvents such as benzene and toluene.
- the coating amount of the dye varies depending on the polarization performance of the dye, but is generally 0.05 to 1.0 g / po, preferably 0.1 to 0.8 g / rrf. Examples of the method for applying the color PfJ solution to the substrate include various coating methods such as bar coder coating spray coating, roll coating, and gravure coater.
- a material formed of a conductive material such as Al, Cu, Ag, Cu, Ni, Cr, and Si.
- a polymer obtained by polymerizing the polymerizable composition of the present invention in a nematic phase, a smectic phase, or in a state of being oriented on a substrate having an orientation function should be used as a heat dissipation material for an illumination element, particularly a light emitting diode element. You can also.
- the form of the heat dissipation material is preferably a prepreg, a polymer sheet, an adhesive, a sheet with metal foil, or the like.
- the polymerizable composition of the present invention can be used as the optical component of the present invention by polymerizing the polymerizable composition while maintaining a nematic phase or a smectic phase, or in combination with an alignment material.
- the polymerizable composition of the present invention can be used as a colorant by adding a colorant such as a dye or an organic pigment.
- the polymerizable composition of the present invention can be combined with or added to a dichroic dye, a lyotropic liquid crystal, a chromonic liquid crystal, or the like to be used as a polarizing film.
- Irgacure 907 (Irg907: manufactured by BASF Japan Ltd.), MegaFac F- 0.2 part of 554 (F-554: manufactured by DIC Corporation) and 0.1 part of p-methoxyphenol (MEHQ) were added and further stirred to obtain a solution.
- the solution was clear and uniform.
- the obtained solution was filtered through a 0.20 ⁇ m membrane filter to obtain a polymerizable composition (1) used in Example 1 and the like.
- the following table shows specific compositions of the polymerizable liquid crystal compositions (1) to (29) and comparative polymerizable liquid crystal compositions (C1) to (C2) of the present invention.
- ⁇ A transparent and uniform state can be visually confirmed when heated and expanded, but precipitation of the compound is confirmed when the temperature is returned to room temperature.
- X Even if it heats and stirs, a compound cannot melt
- Storage stability The state after allowing the polymerizable composition (1) of the present invention to stand at room temperature for 1 week was visually observed. The polymerizable composition of the present invention maintained a transparent and uniform state even after 3 days. The storage stability was evaluated as follows: ⁇ : A transparent and uniform state is maintained even after standing at room temperature for 3 days. ⁇ : A transparent and uniform state is maintained even after standing at room temperature for 1 day. X: Precipitation of the compound is confirmed after standing at room temperature for 1 hour. The results obtained are shown in the table below.
- Example 55 Optical anisotropic body A polyimide solution for alignment film is applied to a glass substrate having a thickness of 0.7 mm using a spin coating method, dried at 100 ° C for 10 minutes, and then baked at 200 ° C for 60 minutes. A coating film was obtained. The obtained coating film was rubbed. The rubbing treatment was performed using a commercially available rubbing apparatus.
- the polymerizable composition (1) of the present invention was applied to the rubbed substrate by a spin coating method and dried at 100 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature, and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp, to obtain the optical anisotropic body of Example 55.
- the obtained optical anisotropic body was evaluated according to the following criteria, there were no defects visually, and there were no defects even when observed with a polarizing microscope. In the following criteria, “ ⁇ ” is the most excellent in orientation, and “x” is intended to indicate no orientation at all.
- Examples 56 to 83 Optical anisotropic bodies of Examples 56 to 83 were obtained under the same conditions as in Example 55 except that the polymerizable compositions used were changed to the polymerizable compositions (2) to (29) of the present invention, respectively. .
- the results obtained are shown in the table above.
- Adjustment of polymerizable composition (30) 40 parts of the compound represented by formula (1-6), 40 parts of the compound represented by formula (1-7), 10 parts of the compound represented by formula (2-a-1-a), a-28) After adding 10 parts to 400 parts of methyl ethyl ketone (MEK), the mixture was heated to 60 ° C. and dissolved by stirring.
- MEK methyl ethyl ketone
- Example 30 3 parts, 0.2 part of MEGAFACE F-554 (manufactured by DIC Corporation) and 0.1 part of p-methoxyphenol were added and further stirred to obtain a solution. The solution was clear and uniform. The obtained solution was filtered with a 0.20 ⁇ m membrane filter to obtain a polymerizable composition (30) used in Example 30 and the like.
- the polymerizable composition of the present invention maintained a transparent and uniform state even after one week.
- Example 52 In the same manner as in Example 51, a polymerizable composition (52) used in Example 52 and the like was obtained.
- the polymerizable composition of the present invention maintained a transparent and uniform state even after one week.
- 40 parts of the compound represented by formula (1-7), 20 parts of the compound represented by formula (1-2), 20 parts of the compound represented by formula (2-a-1-a), 10 parts of the compound represented by a-28) and 10 parts of the compound represented by the formula (2-b-1-a) were added to 300 parts of methyl ethyl ketone (MEK) and 100 parts of methyl isobutyl ketone (MIBK). Thereafter, the mixture was heated to 60 ° C.
- MEK methyl ethyl ketone
- MIBK methyl isobutyl ketone
- Example 53 In the same manner as in Example 53, a polymerizable composition (54) used in Example 54 and the like was obtained.
- the polymerizable composition of the present invention maintained a transparent and uniform state even after one week.
- the polymerizable compositions (53) and (54) of the present invention had no defects visually, had no defects even when observed with a polarizing microscope, and were excellent in orientation.
- the following table shows specific compositions of the polymerizable liquid crystal compositions (30) to (54) and comparative polymerizable liquid crystal compositions (C3) to (C4) of the present invention.
- Example 30 Solubility
- the solubility of the polymerizable composition (30) of the present invention was evaluated as follows. ⁇ : After adjustment, a transparent and uniform state can be visually confirmed. ⁇ : A transparent and uniform state can be visually confirmed when heated and expanded, but precipitation of the compound is confirmed when the temperature is returned to room temperature. X: Even if it heats and stirs, a compound cannot melt
- Storage stability The state after allowing the polymerizable composition (30) of the present invention to stand at room temperature for 1 week was visually observed. The polymerizable composition of the present invention maintained a transparent and uniform state even after 3 days. The storage stability was evaluated as follows: ⁇ : A transparent and uniform state is maintained even after standing at room temperature for 3 days. ⁇ : A transparent and uniform state is maintained even after standing at room temperature for 1 day. X: Precipitation of the compound is confirmed after standing at room temperature for 1 hour. The results obtained are shown in the table below.
- Example 31 to 52 Comparative Examples 3 to 4
- solubility, storage stability and orientation were measured.
- the results are shown in the above table as Examples 31 to 52 and Comparative Examples 3 to 4, respectively.
- Example 84 Optically anisotropic body A uniaxially stretched PET film having a thickness of 50 ⁇ m was rubbed using a commercially available rubbing apparatus, and then the polymerizable composition (30) of the present invention was applied by a bar coating method at 80 ° C. And dried for 2 minutes.
- the obtained coating film was cooled to room temperature, and then irradiated with ultraviolet rays at a conveyor speed of 6 m / min using a UV conveyor device (manufactured by GS Yuasa Co., Ltd.) to obtain an optical anisotropic body of Example 84.
- a UV conveyor device manufactured by GS Yuasa Co., Ltd.
- ⁇ There are no defects by visual observation, and there are no defects even by observation with a polarizing microscope.
- ⁇ There are no defects visually, but there are non-oriented portions as a whole by observation with a polarizing microscope.
- X Defects are visually observed as a whole.
- the retardation (retardation) of the obtained optical anisotropic body was measured by a retardation film / optical material inspection apparatus RETS-100 (manufactured by Otsuka Electronics Co., Ltd.). )) was 130 nm.
- the ratio Re (450) / Re (550) between the in-plane retardation (Re (450)) and Re (550) at a wavelength of 450 nm was 0.851, and a retardation film with good uniformity was obtained.
- the polymerizable composition (C3) of Comparative Example 3 and the polymerizable composition (C4) of Comparative Example 4 have poor solubility in methyl ethyl ketone and methyl isobutyl ketone, and an optically anisotropic substance cannot be obtained.
- chloroform was used instead of methyl ethyl ketone and methyl isobutyl ketone, and each optical anisotropic body was obtained in the same manner as in Example 55.
- Table 1 shows the orientation and retardation ratio of the obtained optical anisotropic body.
- Example 85 to 104 Optical anisotropic bodies of Examples 85 to 104 were obtained under the same conditions as in Example 84, except that the polymerizable compositions used were changed to the polymerizable compositions (31) to (50) of the present invention, respectively. .
- Example 105 A 40 ⁇ m thick unstretched cycloolefin polymer film “ZEONOR” (manufactured by Nippon Zeon Co., Ltd.) was rubbed using a commercially available rubbing apparatus, and then the polymerizable composition (51) of the present invention was applied by a bar coating method. And dried at 80 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature, and then irradiated with ultraviolet rays at a conveyor speed of 6 m / min using a UV conveyor device (manufactured by GS Yuasa Co., Ltd.) to obtain an optical anisotropic body of Example 105.
- a UV conveyor device manufactured by GS Yuasa Co., Ltd.
- (Re (550) is 121 nm
- the ratio of in-plane retardation (Re (450)) to Re (550) at a wavelength of 450 nm, Re (450) / Re (550) is 0.
- Example 106 An optical anisotropic body of Example 106 was obtained under the same conditions as Example 105 except that the polymerizable composition used was changed to the polymerizable composition (52) of the present invention. The results obtained are shown in the table above.
- Example 107 5 parts of a photoalignment material (weight average molecular weight: 250,000) represented by the formula (12-4) was dissolved in 95 parts of cyclopentanone to obtain a solution. The obtained solution was filtered with a 0.45 ⁇ m membrane filter to obtain a photo-alignment solution (1).
- a photoalignment material weight average molecular weight: 250,000
- Example 107 After it was applied to a glass substrate having a thickness of 0.7 mm by using a spin coating method, dried at 80 ° C. for 2 minutes, and then immediately irradiated with 313 nm linearly polarized light at an intensity of 10 mW / cm 2 for 20 seconds. A membrane (1) was obtained.
- the polymerizable composition (53) was applied on the obtained photo-alignment film by a spin coating method and dried at 100 ° C. for 2 minutes. The obtained coating film was cooled to room temperature, and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp, to obtain an optical anisotropic body of Example 107.
- the obtained optical anisotropic body was evaluated according to the following criteria, there were no defects visually, and there were no defects even when observed with a polarizing microscope. Further, when the retardation of the obtained optical anisotropic body was measured with RETS-100 (manufactured by Otsuka Electronics Co., Ltd.), the in-plane retardation (Re (550)) at a wavelength of 550 nm was 125 nm, and the uniformity was good. A phase difference film was obtained.
- Example 108 5 parts of the photo-alignment material (weight average molecular weight: 200,000) represented by the above formula (12-1) was dissolved in 95 parts of N-methyl-2-pyrrolidone, and the resulting solution was passed through a 0.45 ⁇ m membrane filter. Filtration yielded a photoalignment solution (2). Next, it was applied to a glass substrate having a thickness of 0.7 mm using a spin coating method, dried at 100 ° C. for 5 minutes, further dried at 130 ° C. for 10 minutes, and then immediately applied 313 nm linearly polarized light to 10 mW / cm 2. The photo-alignment film (2) was obtained by irradiating at an intensity of 1 minute.
- the polymerizable composition (53) was applied on the obtained photo-alignment film by a spin coating method and dried at 100 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp to obtain the optical anisotropic body of Example 108.
- the obtained optical anisotropic body was evaluated according to the following criteria, there were no defects visually, and there were no defects even when observed with a polarizing microscope.
- the retardation of the obtained optical anisotropic body was measured with RETS-100 (manufactured by Otsuka Electronics Co., Ltd.).
- the in-plane retardation (Re (550)) at a wavelength of 550 nm was 120 nm, and the uniformity was good.
- a phase difference film was obtained.
- 1 part of the photo-alignment material represented by the above formula (12-9) is dissolved in 50 parts of (2-ethoxyethoxy) ethanol and 49 parts of 2-butoxyethanol, and the resulting solution is filtered through a 0.45 ⁇ m membrane filter. As a result, a photo-alignment solution (3) was obtained. Next, it was applied to a polymethyl methacrylate (PMMA) film having a thickness of 80 ⁇ m using a bar coating method, dried at 80 ° C.
- PMMA polymethyl methacrylate
- a photo-alignment film (3) was obtained.
- the polymerizable composition (53) was applied on the obtained photo-alignment film by a spin coating method and dried at 100 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp to obtain the optical anisotropic body of Example 109.
- the orientation of the obtained optical anisotropic body was evaluated, there was no defect by visual observation, and there was no defect even by observation with a polarizing microscope.
- Example 110 The retardation of the obtained optical anisotropic body was measured with RETS-100 (manufactured by Otsuka Electronics Co., Ltd.). As a result, the in-plane retardation (Re (550)) at a wavelength of 550 nm was 137 nm, and the uniformity was good. A phase difference film was obtained.
- Examples 110 to 112 Except for using the polymerizable composition (54), an optical anisotropic body of Example 110 was obtained under the same conditions as in Example 107, and an optical anisotropic body of Example 111 was obtained under the same conditions as in Example 108. The optical anisotropic body of Example 112 was obtained under the same conditions as Example 109.
- Example 113 10 parts of a compound represented by formula (1-6), 55 parts of a compound represented by formula (1-7), 10 parts of a compound represented by formula (1-2), 7 parts of a compound represented by a), 10 parts of a compound represented by formula (2-b-1-a), 8 parts of a compound represented by formula (2-b-1-b), The compound represented by ⁇ 10) is added to 200 parts of methyl ethyl ketone and 200 parts of methyl isobutyl ketone, heated to 60 ° C. and dissolved by stirring.
- a uniaxially stretched PET film having a thickness of 180 ⁇ m was rubbed using a commercially available rubbing apparatus, and then the polymerizable composition (113) of the present invention was applied by a bar coating method and dried at 80 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature, and then irradiated with ultraviolet rays at a conveyor speed of 4 m / min using a UV conveyor device (GS Yuasa Co., Ltd.) having a lamp output of 2 kW (80 W / cm).
- An optical anisotropic body was obtained. When the orientation of the obtained optical anisotropic body was evaluated, there was no defect by visual observation, and there was no defect even by observation with a polarizing microscope. Moreover, the obtained optical anisotropic body was exhibiting green, and it turned out that it is a reflective film.
- Example 114 An optical anisotropic body of Example 114 was obtained under the same conditions as Example 113, except that 6 parts of Formula (10-10) was replaced with 3 parts of Formula (10-33).
- 6 parts of Formula (10-10) was replaced with 3 parts of Formula (10-33).
- the obtained optical anisotropic body is transparent, and when the transmittance is measured with a spectrophotometer (manufactured by Hitachi High-Tech Science Co., Ltd.), a region where the transmittance decreases in the infrared region is observed, and an infrared reflecting film is formed. I found out.
- Example 115 An optical anisotropic body of Example 115 was obtained in the same manner as Example 113 except that 6 parts of Formula (10-10) was replaced with 8.5 parts of Formula (10-38). When the orientation of the obtained optical anisotropic body was evaluated, there was no defect by visual observation, and there was no defect even by observation with a polarizing microscope.
- the obtained optical anisotropic body is transparent, and when the transmittance is measured with a spectrophotometer (manufactured by Hitachi High-Tech Science Co., Ltd.), a region where the transmittance decreases in the ultraviolet region is observed, and an ultraviolet reflecting film is formed. I found out. Further, using RETS-100, the angle of incident light was changed from ⁇ 50 ° to 50 ° in units of 10 °, the phase difference was measured, and the out-of-plane phase difference (Rth) at a wavelength of 550 nm was calculated from the obtained phase difference. However, it was 132 nm, and it was found that it was a negative C plate.
- Example 116 30 parts of a compound represented by formula (1-6), 30 parts of a compound represented by formula (1-7), 40 parts of a compound represented by formula (2-a-28), and formula (12-10) After adding 1 part of a compound represented by the formula (weight average molecular weight: 50,000) to 400 parts of cyclopentanone, heating and stirring at 40 ° C. to dissolve, confirming dissolution, then returning to room temperature, Irgacure 3 parts of 907 (manufactured by BASF Japan Ltd.), 0.1 part of MegaFac F-554 (manufactured by DIC Corporation) and 0.1 part of p-methoxyphenol were added and further stirred to obtain a solution. The solution was clear and uniform.
- the resulting solution was filtered through a 0.20 ⁇ m membrane filter to obtain a polymerizable composition (116) of the present invention.
- the obtained polymerizable composition (116) was applied to a glass substrate having a thickness of 0.7 mm using a spin coating method, dried at 70 ° C. for 2 minutes, further dried at 100 ° C. for 2 minutes, and 313 nm in thickness.
- Linearly polarized light was irradiated at an intensity of 10 mW / cm 2 for 30 seconds. Thereafter, the coating film was returned to room temperature, and irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp, to obtain an optical anisotropic body of Example 116.
- Example 117 30 parts of a compound represented by formula (1-6), 30 parts of a compound represented by formula (1-7), 40 parts of a compound represented by formula (2-a-28), formula (12-4) After adding 0.6 parts of the compound represented by the formula (weight average molecular weight: 100,000) to 400 parts of cyclopentanone, heating to 40 ° C. and stirring to dissolve, the dissolution was confirmed, and then returned to room temperature. , 3 parts of Irgacure 907 (BASF Japan Ltd.), 0.2 part of Megafak F-554 (DIC Inc.) and 0.1 part of p-methoxyphenol were added and further stirred to obtain a solution. . The solution was clear and uniform.
- the obtained solution was filtered through a 0.20 ⁇ m membrane filter to obtain a polymerizable composition (117) of the present invention.
- the obtained polymerizable composition (117) was applied to a 0.7 mm-thick glass substrate using a spin coating method, dried at 60 ° C. for 2 minutes, and further dried at 110 ° C. for 2 minutes. Then, 313 nm linearly polarized light was irradiated at an intensity of 10 mW / cm 2 for 50 seconds. Thereafter, the coating film was returned to room temperature and irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp to obtain the optical anisotropic body of Example 117.
- the retardation of the obtained optical anisotropic body was measured with RETS-100 (manufactured by Otsuka Electronics Co., Ltd.).
- the in-plane retardation (Re (550)) at a wavelength of 550 nm was 130 nm, and the uniformity was good.
- a phase difference film was obtained.
- Example 118 30 parts of a compound represented by formula (1-6), 30 parts of a compound represented by formula (1-7), 40 parts of a compound represented by formula (2-a-28), and formula (12-8) After adding 20 parts of a compound represented by the formula (weight average molecular weight: 10,000) to 400 parts of cyclopentanone, heating to 40 ° C. and stirring to dissolve, confirm dissolution, return to room temperature, Irgacure 3 parts of 907 (manufactured by BASF Japan Ltd.), 0.2 part of MegaFac F-554 (manufactured by DIC Corporation) and 0.1 part of p-methoxyphenol were added and further stirred to obtain a solution. The solution was clear and uniform.
- the resulting solution was filtered through a 0.45 ⁇ m membrane filter to obtain a polymerizable composition (118) of the present invention.
- the obtained polymerizable composition (118) was applied to a glass substrate having a thickness of 0.7 mm by using a spin coating method, dried at 60 ° C. for 2 minutes, and further dried at 110 ° C. for 2 minutes. Then, 313 nm linearly polarized light was irradiated at an intensity of 10 mW / cm 2 for 100 seconds. Thereafter, the coating film was returned to room temperature, and irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp, to obtain an optical anisotropic body of Example 118.
- Example 119 50 parts of a compound represented by formula (1-7), 10 parts of a compound represented by formula (2-a-1-a), 20 parts of a compound represented by formula (2-b-1-a), After adding 20 parts of a compound represented by the formula (2-b-1-b) and 6 parts of a compound represented by the following formula (d-7) to 400 parts of cyclopentanone, the mixture was heated to 60 ° C. and stirred.
- the polyimide solution for alignment film was applied to a glass substrate having a thickness of 0.7 mm using a spin coating method, dried at 100 ° C. for 10 minutes, and then baked at 200 ° C. for 60 minutes to obtain a coating film. .
- the obtained coating film was rubbed. The rubbing treatment was performed using a commercially available rubbing apparatus.
- the polymerizable composition (119) of the present invention was applied to the rubbed substrate by a spin coating method and dried at 90 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature over 2 minutes, and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp, to obtain the optical anisotropic body of Example 119.
- the polarization degree, transmittance, and contrast of the obtained optical anisotropic body were measured with RETS-100 (manufactured by Otsuka Electronics Co., Ltd.), the polarization degree was 99.0%, the transmittance was 44.5%, and the contrast was It was 93 and it turned out that it functions as a polarizing film.
- Example 120 An optical anisotropic body of Example 120 was obtained under the same conditions as Example 119, except that formula (d-7) was changed to formula (d-9).
- the polarization degree, transmittance, and contrast of the obtained optical anisotropic body were measured with RETS-100 (manufactured by Otsuka Electronics Co., Ltd.). The polarization degree was 98.5%, the transmittance was 44.3%, and the contrast was It was 91 and it turned out that it functions as a polarizing film.
- Example 121 40 parts of the compound represented by formula (1-7), 40 parts of the compound represented by formula (1-2), 10 parts of the compound represented by formula (2-a-1-a), After adding 10 parts of the compound represented by b-1-a) to 100 parts of methyl ethyl ketone and 300 parts of methyl isobutyl ketone, the mixture was heated to 60 ° C. with stirring and dissolved, and dissolution was confirmed.
- a protective film is applied to one side of a 30 ⁇ m thick triacetyl cellulose (TAC) film, the opposite side is rubbed using a commercially available rubbing apparatus, and then the polymerizable composition (121) of the present invention is applied by a bar coating method. And dried at 70 ° C. for 2 minutes. The obtained coating film was cooled to room temperature, and then irradiated with ultraviolet rays at a conveyor speed of 5 m / min using a UV conveyor device (manufactured by GS Yuasa Co., Ltd.) having a lamp output of 2 kW (80 W / cm). An optical anisotropic body was obtained.
- TAC triacetyl cellulose
- Example 122 The optically anisotropic body of Example 122 was obtained on the same conditions as Example 121 except having replaced 3 parts of light ester HOA (N) with 3 parts of light ester HOB-A (made by Kyoei Chemical Co., Ltd.). Similarly, an optically anisotropic body of Example 123 was obtained under the same conditions as Example 121 except that 3 parts of light ester HOA (N) was replaced with 3 parts of A-SA (manufactured by Shin-Nakamura Chemical Co., Ltd.).
- Example 124 the optically anisotropic body of Example 124 was obtained under the same conditions as Example 121, except that 3 parts of light ester HOA (N) was replaced with 2 parts of A-9300 (manufactured by Shin-Nakamura Chemical Co., Ltd.).
- the orientation properties of the optically anisotropic bodies obtained in Examples 122 to 124 were evaluated. As a result, there were no defects visually, and there were no defects observed with a polarizing microscope. Moreover, each of the obtained optical anisotropic bodies has a retardation, and a retardation film with good uniformity was obtained.
- Example 125 to 126 40 parts of the compound represented by formula (1-7), 40 parts of the compound represented by formula (1-2), 10 parts of the compound represented by formula (2-a-1-a), After adding 10 parts of the compound represented by b-1-a) to 100 parts of methyl ethyl ketone and 300 parts of methyl isobutyl ketone, the mixture was heated to 60 ° C. with stirring and dissolved, and dissolution was confirmed. Return to room temperature, 3 parts Irgacure 907 (BASF Japan Ltd.), 0.2 part Megafak F-554 (DIC Inc.), 0.1 part p-methoxyphenol, 0.1 part Tinuvin 765, TMMP 4 parts of SC Organic Chemical Co., Ltd.
- Example 125 was obtained on the same conditions as Example 121 using polymeric composition (125).
- Example 126 3 parts Irgacure 907 (BASF Japan Ltd.), 0.2 part Megafak F-554 (DIC Inc.), 0.1 part p-methoxyphenol, 0.1 part Tinuvin 765, tetraethylene glycol 4 parts of bis (3-mercaptopropionate) and 0.05 part of Sanconol A600-50R (manufactured by Sanko Chemical Co., Ltd.) were added and further stirred to obtain a solution. The solution was homogeneous. The obtained solution was filtered through a 0.20 ⁇ m membrane filter to obtain a polymerizable composition (126) of the present invention. The optical anisotropic body of Example 126 was obtained on the same conditions as Example 121 using polymeric composition (126).
- Example 12-7 3 parts of a compound represented by formula (1-6), 3 parts of a compound represented by formula (1-7), 3 parts of a compound represented by formula (2-b-1-a), 1 part of the compound represented by b-1-b) was added to 40 parts of cyclopentanone, heated to 60 ° C. and dissolved by stirring.
- the obtained polymerizable composition was applied to a PET film having a thickness of 180 ⁇ m using an applicator method, and dried at 40 ° C. for 5 minutes and further at 110 ° C. for 5 minutes.
- the obtained coating film was irradiated with ultraviolet rays at a conveyor speed of 3 m / min using a UV conveyor device (GS Yuasa Co., Ltd.) having a lamp output of 2 kW (80 W / cm) to obtain a polymer.
- the obtained polymer is peeled from the PET film, and sandwiched between two copper foils so that the mat surface of the copper foil faces the semi-cured epoxy resin composition.
- the vacuum thermocompression bonding was performed at a pressure of 1 kPa, a press pressure of 4 MPa, and a pressurization time of 5 minutes. Heat cured. Then, it heated at normal pressure 230 degreeC for 1 hour, and obtained the polymer of Example 127.
- the thermal conductivity of the polymer film was determined by measuring the thermal diffusivity by xenon flash method (LFA447 nanoflash made by NETZSCH) after blackening with graphite spray, and the density measured by Archimedes method.
- the thermal conductivity was determined from the product with the specific heat measured by DSC (DSC Pyris 1 manufactured by Perkin Elmer) and found to be 20.1 W / mK.
- the thermal conductivity of the polymerizable composition portion in the polymer film was calculated using the following formula and found to be 0.53 W / mK.
- the heat conductivity of the resin part in a polymer film has shown the value which remove
- a polymerizable composition was prepared.
- the obtained polymerizable composition was applied to a PET film having a thickness of 180 ⁇ m using an applicator method, and dried at 40 ° C. for 5 minutes and further at 110 ° C. for 5 minutes.
- the obtained coating film was irradiated with ultraviolet rays at a conveyor speed of 3 m / min using a UV conveyor device (GS Yuasa Co., Ltd.) having a lamp output of 2 kW (80 W / cm) to obtain a polymer.
- the obtained polymer is peeled from the PET film, the obtained polymer is peeled from the PET film, and sandwiched between two copper foils so that the mat surface of the copper foil faces the semi-cured epoxy resin composition.
- thermocompression bonding was performed at a press temperature of 200 ° C., a degree of vacuum of 1 kPa, a press pressure of 4 MPa, and a pressurization time of 5 minutes. Heat cured. Then, it heated at normal pressure 230 degreeC for 1 hour, and obtained the polymer. Next, the polymer copper foil obtained was removed by etching to obtain a polymer film having a thickness of 50 ⁇ m. The obtained polymer film was subjected to a temperature wave thermal analyzer (ai-Phase manufactured by ai-Phase). The thermal diffusivity was measured using mobile 1u). From the product of this value and the density and specific heat obtained by the above-mentioned method, the thermal conductivity of the polymer film without filler was determined to be 0.43 W / mK.
- the polymer sheet is used as a heat dissipation adhesive layer between the metal plate and the heat dissipation base substrate in a semiconductor module in which the heat dissipation base substrate, the adhesive layer, the metal plate, the solder layer, and the semiconductor chip are laminated in this order. Is possible.
- Example 128 Liquid Crystal Display Element 30 parts of a compound represented by formula (1-6), 30 parts of a compound represented by formula (1-7), 10 parts of a compound represented by formula (1-109), After adding 20 parts of the compound represented by the formula (2-a-1-a) and 10 parts of the compound represented by the formula (2-b-1-b) to 400 parts of cyclopentanone, the mixture was heated to 60 ° C. Warm, stir to disperse and dissolve.
- a polyimide solution for an alignment film was applied to a base material on which a color filter layer was formed on a glass base material RAGLE-XG (manufactured by Corning Co., Ltd.) having a thickness of 0.7 mm using a spin coating method at 100 ° C. After drying for 10 minutes, a coating film was obtained by baking at 200 ° C. for 60 minutes. The obtained coating film was rubbed. The rubbing treatment was performed using a commercially available rubbing apparatus. Next, the polymerizable composition (128) of the present invention was applied by spin coating and dried at 80 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature over 2 minutes and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high pressure mercury lamp to obtain a positive A plate.
- the polymerizable composition () of the present invention was applied on the positive A plate by a spin coating method and dried at 80 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature over 2 minutes and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp to obtain a negative C plate.
- a transparent electrode layer having a thickness of 100 nm was formed on the obtained color filter layer retardation layer using a sputtering apparatus. Further, an alignment film was formed on the transparent electrode layer. The polyimide solution for vertical alignment was applied and dried using a spin coat method, and baked at 220 ° C. for 1 hour. A polyimide film having a thickness of 100 nm was obtained.
- a transparent electrode layer was formed on another glass substrate RAGLE-XG (manufactured by Corning Co., Ltd.) using a sputtering apparatus in the same manner as described above.
- a vertical alignment film made of a polyimide film was formed on the transparent electrode layer under the above conditions.
- an ultraviolet curable sealant containing 0.5% by mass of a spacer having a particle diameter of 4 ⁇ m is surrounded by a dispenser (manufactured by Musashi Engineering Co., Ltd.) around the edge of the alignment film substrate having only the transparent electrode layer.
- a dispenser manufactured by Musashi Engineering Co., Ltd.
- An appropriate amount of a liquid crystal composition having a negative dielectric characteristic was dropped inside the enclosure and bonded to a substrate with a color filter layer. Thereafter, only the sealant portion was irradiated with ultraviolet rays at an intensity of 10 mWcm 2 for 60 seconds using a high-pressure mercury lamp to obtain a liquid crystal display element of the present invention.
- Example 129 A polyimide solution for an alignment film is applied to a base material on which a color filter layer is formed on a glass base material RAGLE-XG (manufactured by Corning Co., Ltd.) having a thickness of 0.7 mm by using a spin coating method, and is performed at 100 ° C. for 10 minutes. After drying, a coating film was obtained by baking at 200 ° C. for 60 minutes. The obtained coating film was rubbed.
- the rubbing treatment was performed using a commercially available rubbing apparatus.
- the polymerizable composition (128) of the present invention was applied by spin coating and dried at 80 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature over 2 minutes and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high pressure mercury lamp to obtain a positive A plate.
- a transparent electrode layer was formed on another glass substrate RAGLE-XG (manufactured by Corning Co., Ltd.) using a sputtering apparatus in the same manner as described above.
- a horizontal alignment film made of a polyimide film was formed on the transparent electrode layer under the above conditions.
- an ultraviolet curable sealant containing 0.5% by mass of a spacer having a particle size of 4 ⁇ m is surrounded by a dispenser (manufactured by Musashi Engineering Co., Ltd.) around the edge of the alignment film substrate having only the transparent electrode layer.
- a dispenser manufactured by Musashi Engineering Co., Ltd.
- An appropriate amount of a liquid crystal composition having a positive dielectric property was dropped inside the enclosure and bonded to a substrate with a color filter layer. Thereafter, only the sealant part was irradiated with ultraviolet rays at an intensity of 10 mWcm 2 for 60 seconds using a high-pressure mercury lamp to obtain a liquid crystal cell of the present invention.
- UCL-018-030 (manufactured by DIC Corporation) was applied to the glass surface of the obtained liquid crystal cell on the color filter layer side by a spin coating method, dried at 60 ° C. for 3 minutes, and then kept at room temperature for 3 minutes to increase the pressure. Using a mercury lamp, ultraviolet rays were irradiated for 30 seconds at an intensity of 30 mW / cm 2 to obtain a positive C plate.
- the obtained liquid crystal display element is placed between polarizing plates arranged under crossed Nicols conditions, and even when observed from the front and oblique 45 ° to the liquid crystal display element, there is no light leakage and a uniform display is obtained. Was confirmed.
- Antireflection film organic light-emitting device 10 parts of a compound represented by formula (1-6), 50 parts of a compound represented by formula (1-7), represented by formula (1-109) 10 parts of the compound, 20 parts of the compound represented by the formula (2-a-1-a), 200 parts of the compound represented by the formula (2-b-1-b), and 200 parts of methyl ethyl ketone and 200 parts of methyl isobutyl ketone Then, the mixture was heated to 60 ° C. and stirred to disperse and dissolve.
- the polymerizable composition (130) of the present invention was applied by a bar coating method and dried at 80 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature, and then irradiated with ultraviolet rays at a conveyor speed of 5 m / min using a UV conveyor device (GS Yuasa Co., Ltd.) having a lamp output of 2 kW to obtain an optical anisotropic body.
- a UV conveyor device GS Yuasa Co., Ltd.
- the obtained optical anisotropic body has a phase difference Re (550) of 137 nm and an in-plane phase difference (Re (450)) / Re (550) ratio Re (450) / Re (550) of 0.821 at a wavelength of 450 nm.
- a retardation film with good uniformity was obtained.
- a polyvinyl alcohol film having an average degree of polymerization of about 2400 and a saponification degree of 99.9 mol% or more and a thickness of 75 ⁇ m was uniaxially stretched about 5.5 times in a dry manner, and further kept at 60 ° C.
- After being immersed in pure water for 60 seconds it was immersed in an aqueous solution having a weight ratio of iodine / potassium iodide / water of 0.05 / 5/100 at 28 ° C. for 20 seconds. Then, it was immersed in an aqueous solution having a weight ratio of potassium iodide / boric acid / water of 8.5 / 8.5 / 100 at 72 ° C. for 300 seconds.
- the film was washed with pure water at 26 ° C. for 20 seconds and then dried at 65 ° C. to obtain a polarizing film in which iodine was adsorbed and oriented on a polyvinyl alcohol resin.
- the antireflection film of the present invention was obtained by pasting together through an adhesive so that the angle between the polarization axis of the obtained polarizing film and the slow axis of the retardation film was 45 °. Furthermore, when the obtained antireflection film and an aluminum plate used as an alternative to the organic light-emitting element were bonded together with an adhesive, the reflection visibility coming from the aluminum plate was visually confirmed from the front and oblique 45 °. No plate-derived transfer was observed.
- Example 131 A stretched cycloolefin polymer film “ZEONOR” (manufactured by Zeon Corporation) having a thickness of 40 ⁇ m was rubbed using a commercially available rubbing apparatus, and then the polymerizable composition (119) of the present invention was applied by a bar coating method. After drying at ° C. for 2 minutes, ultraviolet rays were irradiated at a conveyor speed of 5 m / min using a UV conveyor device (manufactured by GS Yuasa Co., Ltd.) having a lamp output of 2 kW to obtain a polarizing film.
- a UV conveyor device manufactured by GS Yuasa Co., Ltd.
- the photo-alignment solution (1) was applied to the obtained polarizing film by a bar coating method and dried at 80 ° C., and then the angle formed by the polarizing axis of the polarizing film and the polarizing axis of 313 nm linearly polarized light was 45 °. In this way, a photo-alignment film was formed by irradiation with an intensity of 10 mW / cm 2 for 30 seconds.
- the polymerizable composition (130) of the present invention was applied onto the photo-alignment film by a bar coating method, dried at 80 ° C. for 2 minutes, and then the obtained coating film was cooled to room temperature, and a UV conveyor having a lamp output of 2 kW.
- An antireflection film of the present invention was obtained by irradiating ultraviolet rays at a conveyor speed of 5 m / min using an apparatus (manufactured by GS Yuasa Co., Ltd.). Furthermore, when the obtained antireflection film and an aluminum plate used as an alternative to the organic light-emitting element were bonded together with an adhesive, the reflection visibility coming from the aluminum plate was visually confirmed, and the transfer from the aluminum plate was observed. Was not.
- Re (450 nm) / Re (550 nm) of the compounds represented by the above formulas (1-117), (1-124), and (1-126) are 0.664, 0.769, 0. 749.
- Storage stability The state after the polymerizable compositions (132) to (141) of the present invention were allowed to stand at room temperature for 3 days was visually observed. The polymerizable composition of the present invention maintained a transparent and uniform state even after 3 days. In addition, evaluation of storage stability is ⁇ : A transparent and uniform state is maintained even after standing at room temperature for 3 days. ⁇ : A transparent and uniform state is maintained even after standing at room temperature for 1 day. X: Precipitation of the compound is confirmed after standing at room temperature for 1 hour.
- Example 142 The polyimide solution for alignment film was applied to a glass substrate having a thickness of 0.7 mm using a spin coating method, dried at 100 ° C. for 10 minutes, and then baked at 200 ° C. for 60 minutes to obtain a coating film. The obtained coating film was rubbed. The rubbing treatment was performed using a commercially available rubbing apparatus.
- the polymerizable composition (132) of the present invention was applied to the rubbed substrate by a spin coating method and dried at 90 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature, and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high-pressure mercury lamp, to obtain the optical anisotropic body of Example 142.
- the obtained optical anisotropic body was evaluated according to the following criteria, there were no defects visually, and there were no defects even when observed with a polarizing microscope. In the following criteria, “ ⁇ ” is the most excellent in orientation, and “x” is intended to indicate no orientation at all.
- Example 143 to 144 Optical anisotropic bodies of Examples 143 to 144 were obtained under the same conditions as Example 142, except that the polymerizable compositions used were changed to the polymerizable compositions (133) to (134) of the present invention, respectively. .
- Example 145) The polyimide solution for vertical alignment was applied to a glass substrate having a thickness of 0.7 mm using a spin coating method, dried at 100 ° C. for 10 minutes, and then baked at 200 ° C. for 60 minutes to obtain a coating film.
- the polymerizable composition (135) of the present invention was applied to the substrate by a spin coating method and dried at 90 ° C. for 2 minutes.
- the obtained coating film was cooled to room temperature, and then irradiated with ultraviolet rays at an intensity of 30 mW / cm 2 for 30 seconds using a high pressure mercury lamp, to obtain an optical anisotropic body of Example 145.
- the obtained optical anisotropic body was evaluated in the same manner as in Example 142. As a result, there was no defect visually, and there was no defect even when observed with a polarizing microscope.
- the retardation (retardation) of the obtained optical anisotropic body and the incident angle dependence of the retardation were measured with a retardation film / optical material inspection apparatus RETS-100 (manufactured by Otsuka Electronics Co., Ltd.).
- the out-of-plane retardation (Rth (550)) at a wavelength of 550 nm was 160 nm.
- the ratio Rth (450) / Rth (550) between the out-of-plane retardation (Rth (450)) and Rth (550) at a wavelength of 450 nm is 0.861, and a vertically aligned retardation film with good uniformity (positive) C plate) was obtained.
- Example 146 to 147 Optical anisotropic bodies of Examples 146 to 147 were obtained under the same conditions as Example 145 except that the polymerizable compositions used were changed to the polymerizable compositions (136) to (137) of the present invention, respectively. .
- Example 148 to 149) Optical anisotropic bodies of Examples 148 to 149 were obtained under the same conditions as Example 142, except that the polymerizable compositions used were changed to the polymerizable compositions (138) to (139) of the present invention, respectively. .
- the obtained optical anisotropic body was evaluated according to the following criteria, there were no defects visually, and there were no defects even when observed with a polarizing microscope. (Phase difference ratio) Further, the retardation (retardation) of the obtained optical anisotropic body and the incident angle dependence of the retardation were measured with a retardation film / optical material inspection apparatus RETS-100 (manufactured by Otsuka Electronics Co., Ltd.). The in-plane retardation (Re (550)) at 44 was 44 nm in Example 148 and 60 nm in Example 149 (FIG. 2).
- Example 150 to 151 Optical anisotropic bodies of Examples 150 to 151 were obtained under the same conditions as Example 142, except that the polymerizable compositions used were changed to the polymerizable compositions (140) to (141) of the present invention, respectively. .
- the obtained optical anisotropic body was evaluated according to the following criteria, there were no defects visually, and there were no defects even when observed with a polarizing microscope. Moreover, the obtained optical anisotropic body was exhibiting green, and it turned out that it is a reflective film.
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Abstract
Description
即ち本発明は、
a)一般式(1)
b)少なくとも2つ以上の重合性基を有する重合性化合物、
c)必要に応じて開始剤、
及びd)必要に応じて溶剤、を含有する重合性組成物を提供する。
a)一般式(1)で表される化合物
本発明の重合性組成物には、下記一般式(1)で表される化合物を必須成分として含有する。なお、一般式(1)で表される化合物には-O-O-結合を含まない。
b)少なくとも2つ以上の重合性基を有する化合物
本発明の重合性組成物には、少なくとも2つ以上の重合性基を有する化合物を必須成分として含有する。
S21~S72は各々独立してスペーサー基を又は単結合を表すが、S21~S72が複数存在する場合それらは各々同一であっても異なっていても良く、
X21~X72は各々独立して-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、X21~X72が複数存在する場合それらは各々同一であっても異なっていても良く(ただし、各P-(S-X)-結合には-O-O-を含まない。)、
MG21~MG71は各々独立してメソゲン性基を表し、
R31は水素原子、フッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、シアノ基、ニトロ基、イソシアノ基、チオイソシアノ基、又は、炭素原子数1から20のアルキル基を表すが、当該アルキル基は直鎖状であっても分岐状であっても良く、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、当該アルキル基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-又は-C≡C-によって置換されても良く、
m2~m7、n2~n7、l4~l6、k6は各々独立して0から5の整数を表す。
MG21~MG71で表されるメソゲン性基は、下記式(8-a)
A81、A82は各々独立して1,4-フェニレン基、1,4-シクロヘキシレン基、ピリジン-2,5-ジイル基、ピリミジン-2,5-ジイル基、ナフタレン-2,6-ジイル基、ナフタレン-1,4-ジイル基、テトラヒドロナフタレン-2,6-ジイル基、デカヒドロナフタレン-2,6-ジイル基又は1,3-ジオキサン-2,5-ジイル基を表すが、これらの基は無置換又は1つ以上のL2によって置換されても良いが、A81及び/又はA82が複数現れる場合は各々同一であっても異なっていても良く、
Z81及びZ82は各々独立して-O-、-S-、-OCH2-、-CH2O-、-CH2CH2-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-、-N=CH-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、Z81及び/又はZ82が複数現れる場合は各々同一であっても異なっていても良く、
Mは下記の式(M-1)から式(M-11)
Gは下記の式(G-1)~式(G-6)
W81は少なくとも1つの芳香族基を有する、炭素原子数5から30の基を表すが、当該基は無置換又は1つ以上のL2によって置換されても良く、
W82は水素原子、又は、炭素原子数1から20のアルキル基を表すが、当該アルキル基は直鎖状であっても分岐状であっても良く、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、当該アルキル基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良く、若しくは、W82はW81と同様の意味を表しても良く、また、W81及びW82は互いに連結し同一の環構造を形成しても良く、或いはW82は下記の基
W83、W84はそれぞれ独立してハロゲン原子、シアノ基、ヒドロキシ基、ニトロ基、カルボキシル基、カルバモイルオキシ基、アミノ基、スルファモイル基、少なくとも1つの芳香族基を有する炭素原子数5から30の基、炭素原子数1から20のアルキル基、炭素原子数3から20のシクロアルキル基、炭素原子数2から20のアルケニル基、炭素原子数3から20のシクロアルケニル基、炭素原子数1から20のアルコキシ基、炭素原子数2から20のアシルオキシ基、炭素原子数2から20の又は、アルキルカルボニルオキシ基を表すが、前記アルキル基、シクロアルキル基、アルケニル基、シクロアルケニル基、アルコキシ基、アシルオキシ基、アルキルカルボニルオキシ基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-又は-C≡C-によって置換されても良く、
但し、上記Mが式(M-1)~式(M-10)から選択される場合Gは式(G-1)~式(G-5)から選択され、Mが式(M-11)である場合Gは式(G-6)を表し、
L2はフッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基、又は、炭素原子数1から20のアルキル基を表すが、当該アルキル基は直鎖状であっても分岐状であっても良く、任意の水素原子はフッ素原子に置換されても良く、当該アルキル基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-から選択される基によって置換されても良く、j81及びj82は各々独立して0から5の整数を表すが、j81+j82は1から5の整数を表す。)で表される基、あるいは式(8-b)
A83、A84は各々独立して1,4-フェニレン基、1,4-シクロヘキシレン基、ピリジン-2,5-ジイル基、ピリミジン-2,5-ジイル基、ナフタレン-2,6-ジイル基、ナフタレン-1,4-ジイル基、テトラヒドロナフタレン-2,6-ジイル基、デカヒドロナフタレン-2,6-ジイル基又は1,3-ジオキサン-2,5-ジイル基を表すが、これらの基は無置換又は1つ以上の上記L2によって置換されても良いが、A83及び/又はA84が複数現れる場合は各々同一であっても異なっていても良く、
Z83及びZ84は各々独立して-O-、-S-、-OCH2-、-CH2O-、-CH2CH2-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-、-N=CH-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、Z83及び/又はZ84が複数現れる場合は各々同一であっても異なっていても良く、
M81は1,4-フェニレン基、1,4-シクロヘキシレン基、1,4-シクロヘキセニル基、テトラヒドロピラン-2,5-ジイル基、1,3-ジオキサン-2,5-ジイル基、テトラヒドロチオピラン-2,5-ジイル基、1,4-ビシクロ(2,2,2)オクチレン基、デカヒドロナフタレン-2,6-ジイル基、ピリジン-2,5-ジイル基、ピリミジン-2,5-ジイル基、ピラジン-2,5-ジイル基、チオフェン-2,5-ジイル基-、1,2,3,4-テトラヒドロナフタレン-2,6-ジイル基、ナフチレン-1,4-ジイル基、ナフチレン-1,5-ジイル基、ナフチレン-1,6-ジイル基、ナフチレン-2,6-ジイル基、フェナントレン-2,7-ジイル基、9,10-ジヒドロフェナントレン-2,7-ジイル基、1,2,3,4,4a,9,10a-オクタヒドロフェナントレン-2,7-ジイル基、ベンゾ[1,2-b:4,5-b‘]ジチオフェン-2,6-ジイル基、ベンゾ[1,2-b:4,5-b‘]ジセレノフェン-2,6-ジイル基、[1]ベンゾチエノ[3,2-b]チオフェン-2,7-ジイル基、[1]ベンゾセレノフェノ[3,2-b]セレノフェン-2,7-ジイル基、又はフルオレン-2,7-ジイル基から選ばれる基を表すが、これらの基は無置換又は1つ以上のL2によって置換されても良く、
L2はフッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基、又は、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良い炭素原子数1から20の直鎖状又は分岐状アルキル基を表すが、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、
j83及びj84は各々独立して0から5の整数を表すが、j83+j84は1から5の整数を表す。)で表される基を表す。
W81は少なくとも1つの芳香族基を有する、炭素原子数5から30の基を表すが、当該基は無置換であるか又は1つ以上のL2によって置換されても良く、
W82は、水素原子、又は、炭素原子数1から20のアルキル基を表すが、当該アルキル基は直鎖状であっても分岐状であっても良く、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、当該アルキル基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良く、若しくは、W82はW81と同様の意味を表しても良く、また、W81及びW82は一緒になって環構造を形成しても良く、或いはW82は下記の基
W83、W84はそれぞれ独立してハロゲン原子、シアノ基、ヒドロキシ基、ニトロ基、カルボキシル基、カルバモイルオキシ基、アミノ基、スルファモイル基、少なくとも1つの芳香族基を有する炭素原子数5から30の基、炭素原子数1から20のアルキル基、炭素原子数3から20のシクロアルキル基、炭素原子数2から20のアルケニル基、炭素原子数3から20のシクロアルケニル基、炭素原子数1から20のアルコキシ基、炭素原子数2から20のアシルオキシ基、炭素原子数2から20の又は、アルキルカルボニルオキシ基を表すが、前記アルキル基、シクロアルキル基、アルケニル基、シクロアルケニル基、アルコキシ基、アシルオキシ基、アルキルカルボニルオキシ基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-又は-C≡C-によって置換されても良い。
W82が下記の基
一般式(2-b)で表される化合物として具体的には、下記の式(2-b-1)から式(2-b-33)で表される化合物が好ましい。
Re(450nm)/Re(550nm)<1.0 (I)
(式中、Re(450nm)は、前記少なくとも2つ以上の重合性基を有する化合物を基板上に分子の長軸方向が実質的に基板に対して水平に配向させたときの450nmの波長における面内位相差、Re(550nm)は、前記少なくとも2つ以上の重合性基を有する化合物を基板上に分子の長軸方向が実質的に基板に対して水平に配向させたときの550nmの波長における面内位相差を表す。)を満たすことが好ましい。また、重合性組成物を重合して得られる光学異方体の逆分散性を高めるためには、Re(450nm)/Re(550nm)<0.98であることがより好ましく、Re(450nm)/Re(550nm)<0.95であることがさらに好ましい。
c)開始剤
本発明の重合性組成物は、必要に応じて開始剤を含有することができる。本発明の重合性組成物で用いられる重合開始剤は、本発明の重合性組成物を重合させるために用いる。重合を光照射によって行う場合に使用する光重合開始剤としては、特に限定はないが、前記一般式(1)で表される重合性液晶性化合物、前記少なくとも2つ以上の重合性基を有する重合性液晶性化合物の配向状態を阻害しない程度で公知慣用のものが使用できる。
LAMBSON社の「スピードキュアBMS」、「スピードキュアPBZ」、「ベンゾフェノン」等が挙げられる。さらに、光カチオン開始剤としては、光酸発生剤を用いることができる。光酸発生剤としてはジアゾジスルホン系化合物、トリフェニルスルホニウム系化合物、フェニルスルホン系化合物、スルフォニルピリジン系化合物、トリアジン系化合物及びジフェニルヨードニウム化合物などが挙げられる。
d)有機溶剤
本発明の重合性組成物は、必要に応じて有機溶剤を含有することができる。用いる有機溶剤としては特に限定はないが、前記重合性化合物が良好な溶解性を示す有機溶剤が好ましく、100℃以下の温度で乾燥できる有機溶剤であることが好ましい。そのような溶剤としては、例えば、トルエン、キシレン、クメン、メシチレン、等の芳香族系炭化水素、酢酸メチル、酢酸エチル、酢酸プロピル、酢酸ブチル、酢酸シクロヘキシル、酢酸3-ブトキシメチル、乳酸エチル等のエステル系溶剤、メチルエチルケトン、メチルイソブチルケトン、シクロヘキサノン、シクロペンタノン等のケトン系溶剤、テトラヒドロフラン、1,2-ジメトキシエタン、アニソール等のエーテル系溶剤、N,N-ジメチルホルムアミド、N-メチル-2-ピロリドン、等のアミド系溶剤、エチレングリコールモノメチルエーテルアセテート、プロピレングリコールモノメチルエーテルアセテート、プロピレングリコールモノメチルエーテル、プロピレングリコールジアセテート、プロピレングリコールモノメチルプロピルエーテル、ジエチレングリコールモノメチルエーテルアセテート、γ-ブチロラクトン及びクロロベンゼン等が挙げられる。これらは、単独で使用することもできるし、2種類以上混合して使用することもできるが、ケトン系溶剤、エーテル系溶剤、エステル系溶剤及び芳香族炭化水素系溶剤のうちのいずれか1種類以上を用いることが溶液安定性の点から好ましい。
e)添加剤
本発明の重合性組成物は、均一に塗布するため、あるいは、各々の目的に応じて汎用の添加剤を使用することもできる。例えば、重合禁止剤、酸化防止剤、紫外線吸収剤、レベリング剤、配向制御剤、連鎖移動剤、赤外線吸収剤、チキソ剤、帯電防止剤、色素、フィラー、キラル化合物、重合性基を有する非液晶性化合物、その他液晶化合物、配向材料等の添加剤を液晶の配向性を著しく低下させない程度添加することができる。
f)重合禁止剤
本発明の重合性組成物は、必要に応じて重合禁止剤を含有することができる。用いる重合禁止剤としては、特に限定はなく、公知慣例のものが使用できる。
g)酸化防止剤
本発明の重合性組成物は、必要に応じて酸化防止剤等を含有することができる。そのような化合物として、ヒドロキノン誘導体、ニトロソアミン系重合禁止剤、ヒンダードフェノール系酸化防止剤等が挙げられ、より具体的には、tert-ブチルハイドロキノン、和光純薬工業社の「Q-1300」、「Q-1301」、ペンタエリスリトールテトラキス[3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)プロピオネート「IRGANOX1010」、チオジエチレンビス[3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)プロピオネート「IRGANOX1035」、オクタデシル-3-(3,5-ジ-tert-ブチル-4-ヒドロキシフェニル)プロピオネート「IRGANOX1076」、「IRGANOX1135」、「IRGANOX1330」、4,6-ビス(オクチルチオメチル)-o-クレゾール「IRGANOX1520L」、「IRGANOX1726」、「IRGANOX245」、「IRGANOX259」、「IRGANOX3114」、「IRGANOX3790」、「IRGANOX5057」、「IRGANOX565」(以上、BASF株式会社製)、株式会社ADEKA製のアデカスタブAO-20、AO-30、AO-40、AO-50、AO-60、AO-80、住友化学株式会社のスミライザーBHT、スミライザーBBM-S、およびスミライザーGA-80等々があげられる。
h)紫外線吸収剤
本発明の重合性組成物は、必要に応じて紫外線吸収剤や光安定剤を含有することができる。用いる紫外線吸収剤や光安定剤は特に限定はないが、光学異方体や光学フィルム等の耐光性を向上させるものが好ましい。
i)レベリング剤
本発明の重合性組成物は、必要に応じてレベリング剤を含有することができる。用いるレベリング剤は特に限定はないが、光学異方体や光学フィルム等の薄膜を形成する場合に膜厚むらを低減させるためものが好ましい。 前記レベリング剤としては、アルキルカルボン酸塩、アルキルリン酸塩、アルキルスルホン酸塩、フルオロアルキルカルボン酸塩、フルオロアルキルリン酸塩、フルオロアルキルスルホン酸塩、ポリオキシエチレン誘導体、フルオロアルキルエチレンオキシド誘導体、ポリエチレングリコール誘導体、アルキルアンモニウム塩、フルオロアルキルアンモニウム塩類等が挙げられる。
「フタージェント100」、「フタージェント100C」、「フタージェント110」、「フタージェント150」、「フタージェント150CH」、「フタージェント100A-K」、「フタージェント300」、「フタージェント310」、「フタージェント320」、「フタージェント400SW」、「フタージェント251」、「フタージェント215M」、「フタージェント212M」、「フタージェント215M」、「フタージェント250」、「フタージェント222F」、「フタージェント212D」、「FTX-218」、「フタージェント209F」、「フタージェント245F」、「フタージェント208G」、「フタージェント240G」、「フタージェント212P」、「フタージェント220P」、「フタージェント228P」、「DFX-18」、「フタージェント601AD」、「フタージェント602A」、「フタージェント650A」、「フタージェント750FM」、「FTX-730FM」、「フタージェント730FL」、「フタージェント710FS」、「フタージェント710FM」、「フタージェント710FL」、「フタージェント750LL」、「FTX-730LS」、「フタージェント730LM」、(以上、株式会社ネオス製)、
「BYK-300」、「BYK-302」、「BYK-306」、「BYK-307」、「BYK-310」、「BYK-315」、「BYK-320」、「BYK-322」、「BYK-323」、「BYK-325」、「BYK-330」、「BYK-331」、「BYK-333」、「BYK-337」、「BYK-340」、「BYK-344」、「BYK-370」、「BYK-375」、「BYK-377」、「BYK-350」、「BYK-352」、「BYK-354」、「BYK-355」、「BYK-356」、「BYK-358N」、「BYK-361N」、「BYK-357」、「BYK-390」、「BYK-392」、「BYK-UV3500」、「BYK-UV3510」、「BYK-UV3570」、「BYK-Silclean3700」(以上、BYK株式会社製)、
「TEGO Rad2100」、「TEGO Rad2011」、「TEGO Rad2200N」、「TEGO Rad2250」、「TEGO Rad2300」、「TEGO Rad2500」、「TEGO Rad2600」、「TEGO Rad2650」、「TEGO Rad2700」、「TEGO Flow300」、「TEGO Flow370」、「TEGO Flow425」、「TEGO Flow ATF2」、「TEGO Flow ZFS460」、「TEGO Glide100」、「TEGO Glide110」、「TEGO Glide130」、「TEGO Glide410」、「TEGO Glide411」、「TEGO Glide415」、「TEGO Glide432」、「TEGO Glide440」、「TEGO Glide450」、「TEGO Glide482」、「TEGO Glide A115」、「TEGO Glide B1484」、「TEGO Glide ZG400」、「TEGO Twin4000」、「TEGO Twin4100」、「TEGO Twin4200」、「TEGO Wet240」、「TEGO Wet250」、「TEGO Wet260」、「TEGO Wet265」、「TEGO Wet270」、「TEGO Wet280」、「TEGO Wet500」、「TEGO Wet505」、「TEGO Wet510」、「TEGO Wet520」、「TEGO Wet KL245」、(以上、エボニック・インダストリーズ株式会社製)、「FC-4430」、「FC-4432」(以上、スリーエムジャパン株式会社製)、「ユニダインNS」(以上、ダイキン工業株式会社製)、「サーフロンS-241」、「サーフロンS-242」、「サーフロンS-243」、「サーフロンS-420」、「サーフロンS-611」、「サーフロンS-651」、「サーフロンS-386」(以上、AGCセイミケミカル株式会社製)、「DISPARLON OX-880EF」、「DISPARLON OX-881」、「DISPARLON OX-883」、「DISPARLON OX-77EF」、「DISPARLON OX-710」、「DISPARLON 1922」、「DISPARLON 1927」、「DISPARLON 1958」、「DISPARLON P-410EF」、「DISPARLON P-420」、「DISPARLON P-425」、「DISPARLON PD-7」、「DISPARLON 1970」、「DISPARLON 230」、「DISPARLON LF-1980」、「DISPARLON LF-1982」、「DISPARLON LF-1983」、「DISPARLON LF-1084」、「DISPARLON LF-1985」、「DISPARLON LHP-90」、「DISPARLON LHP-91」、「DISPARLON LHP-95」、「DISPARLON LHP-96」、「DISPARLON OX-715」、「DISPARLON 1930N」、「DISPARLON 1931」、「DISPARLON 1933」、「DISPARLON 1934」、「DISPARLON 1711EF」、「DISPARLON 1751N」、「DISPARLON 1761」、「DISPARLON LS-009」、「DISPARLON LS-001」、「DISPARLON LS-050」(以上、楠本化成株式会社製)、「PF-151N」、「PF-636」、「PF-6320」、「PF-656」、「PF-6520」、「PF-652-NF」、「PF-3320」(以上、OMNOVA SOLUTIONS社製)、「ポリフローNo.7」、「ポリフローNo.50E」、「ポリフローNo.50EHF」、「ポリフローNo.54N」、「ポリフローNo.75」、「ポリフローNo.77」、「ポリフローNo.85」、「ポリフローNo.85HF」、「ポリフローNo.90」、「ポリフローNo.90D-50」、「ポリフローNo.95」、「ポリフローNo.99C」、「ポリフローKL-400K」、「ポリフローKL-400HF」、「ポリフローKL-401」、「ポリフローKL-402」、「ポリフローKL-403」、「ポリフローKL-404」、「ポリフローKL-100」、「ポリフローLE-604」、「ポリフローKL-700」、「フローレンAC-300」、「フローレンAC-303」、「フローレンAC-324」、「フローレンAC-326F」、「フローレンAC-530」、「フローレンAC-903」、「フローレンAC-903HF」、「フローレンAC-1160」、「フローレンAC-1190」、「フローレンAC-2000」、「フローレンAC-2300C」、「フローレンAO-82」、「フローレンAO-98」、「フローレンAO-108」(以上、共栄社化学株式会社製)、「L-7001」、「L-7002」、「8032ADDITIVE」、「57ADDTIVE」、「L-7064」、「FZ-2110」、「FZ-2105」、「67ADDTIVE」、「8616ADDTIVE」(以上、東レ・ダウシリコーン株式会社製)等の例を挙げることができる。
j)配向制御剤
本発明の重合性組成物は、液晶性化合物の配向状態を制御するために、配向制御剤を含有することができる。用いる配向制御剤としては、液晶性化合物が、基材に対して実質的に水平配向、実質的に垂直配向、実質的にハイブリッド配向するものが挙げられる。また、キラル化合物を添加した場合には実質的に平面配向するものが挙げられる。前述したように、界面活性剤によって、水平配向、平面配向が誘起される場合もあるが、各々の配向状態が誘起されるものであれば、特に限定はなく、公知慣用のものを使用することができる。
また、フルオロアルキル基で変性された棒状液晶性化合物、円盤状液晶性化合物、分岐構造を有してもよい長鎖脂肪族アルキル基を含有した重合性化合物、等も挙げられる。
k)連鎖移動剤
本発明の重合性組成物は、重合体や光学異方体と基材との密着性をより向上させるため、連鎖移動剤を含有することができる。連鎖移動剤としては、芳香族炭化水素類、クロロホルム、四塩化炭素、四臭化炭素、ブロモトリクロロメタン等のハロゲン化炭化水素類、
オクチルメルカプタン、n―ブチルメルカプタン、n―ペンチルメルカプタン、n-ヘキサデシルメルカプタン、n-テトラデシルメル、n―ドデシルメルカプタン、t-テトラデシルメルカプタン、t―ドデシルメルカプタン等のメルカプタン化合物、ヘキサンジチオール、デカンジチオール、1,4-ブタンジオールビスチオプロピオネート、1,4-ブタンジオールビスチオグリコレート、エチレングリコールビスチオグリコレート、エチレングリコールビスチオプロピオネート、トリメチロールプロパントリスチオグリコレート、トリメチロールプロパントリスチオプロピオネート、トリメチロールプロパントリス(3-メルカプトブチレート)、ペンタエリスリトールテトラキスチオグリコレート、ペンタエリスリトールテトラキスチオプロピオネート、トリメルカプトプロピオン酸トリス(2-ヒドロキシエチル)イソシアヌレート、1,4-ジメチルメルカプトベンゼン、2、4、6-トリメルカプト-s-トリアジン、2-(N,N-ジブチルアミノ)-4,6-ジメルカプト-s-トリアジン等のチオール化合物、ジメチルキサントゲンジスルフィド、ジエチルキサントゲンジスルフィド、ジイソプロピルキサントゲンジスルフィド、テトラメチルチウラムジスルフィド、テトラエチルチウラムジスルフィド、テトラブチルチウラムジスルフィド等のスルフィド化合物、N,N-ジメチルアニリン、N,N-ジビニルアニリン、ペンタフェニルエタン、α-メチルスチレンダイマー、アクロレイン、アリルアルコール、ターピノーレン、α-テルピネン、γ-テルビネン、ジペンテン、等が挙げられるが、2,4-ジフェニル-4-メチル-1-ペンテン、チオール化合物がより好ましい。
l)赤外線吸収剤
本発明の重合性組成物は、必要に応じて赤外線吸収剤を含有することができる。用いる赤外線吸収剤は、特に限定はなく、配向性を乱さない範囲で公知慣用のものを含有することができる。
m)帯電防止剤
本発明の重合性組成物は、必要に応じて帯電防止剤を含有することができる。用いる帯電防止剤は、特に限定はなく、配向性を乱さない範囲で公知慣用のものを含有することができる。
n)色素
本発明の重合性組成物は、必要に応じて色素を含有することができる。用いる色素は、特に限定はなく、配向性を乱さない範囲で公知慣用のものを含有することができる。
CRC Press、1994年、および「機能性色素市場の新展開」、第一章、1頁、1994年、CMC株式会社発光、等に記載の色素を使用することができる。
o)フィラー
本発明の重合性組成物は、必要に応じてフィラーを含有することができる。用いるフィラーは、特に限定はなく、得られた重合物の熱伝導性が低下しない範囲で公知慣用のものを含有することができる。
窒化アルミニウムとしてHグレード、Eグレード、H-Tグレード(以上、トクヤマ株式会社製)、TOYAL TecFiller TFS-A05P、TOYAL TecFiller TFZ-A02P(以上、東洋アルミニウム株式会社製)、ALN020BF、ALN050BF、ALN020AF、ALN050AF、ALN020SF(以上、巴工業株式会社製)、FAN-f05、FAN-f30(以上、古河電子株式会社製)、窒化ホウ素としてデンカボロンナイトライドSGP、デンカボロンナイトライドMGP、デンカボロンナイトライドGP、デンカボロンナイトライドHGP、デンカボロンナイトライドSP-2、デンカボロンナイトライドSGPS(以上、電気化学工業株式会社製)、UHP-S1、UHP-1K、UHP-2、UHP-EX(以上、昭和電工株式会社製)窒化ケイ素としてSN-9、SN-9S、SN-9FWS、SN-F1、SN-F2(以上、電気化学工業株式会社製)、CF0027、CF0093、CF0018、CF0033(以上、日本フリット株式会社製)、炭化ケイ素として、GMF-Hタイプ、GMF-H2タイプ、GMF-LCタイプ(以上、太平洋ランダム株式会社)、HSC1200、HSC1000、HSC059、HSC059I、HSC007(以上、巴工業株式会社製)、シリカとしてサイシリア(富士シリシア化学株式会社)、AEROSIL R972、AEROSIL R104、AEROSIL R202、AEROSIL 805、AEROSIL R812、AEROSIL R7200(以上、日本エアロジル株式会社製)、レオシールシリーズ(トクヤマ株式会社製)、結晶性シリカ(酸化ケイ素)としてCMC-12、VX-S、VX-SR(以上、株式会社龍森社製)、溶融シリカ(酸化ケイ素)としてFB-3SDC、FB-3SDX、SFP-30M、SFP-20M、SFP-30MHE、SFP-130MC、UFP-30(以上、電気化学工業株式会社製)、エクセリカシリーズ(トクヤマ株式会社製)、酸化アルミニウムとしてAEROXIDE Alu C、AEROXIDE Alu 65(以上、日本エアロジル株式会社製)、炭素繊維やグラファイトとしてトレカミルドファイバーMLD-30、トレカミルドファイバーMLD-300(以上、東レ株式会社製)、CFMP-30X、CFMP-150X(以上、日本ポリマー産業株式会社製)、XN-100、HC-600(以上、日本グラファイトファイバー株式会社製)、SWeNT SG65、SWeNT SGi、IsoNanoTubes-M、IsoNanoTubes-S、PureTubes、Pyrograf PR-25-XT-PS、PR-25XT-LHT(以上、シグマアルドリッチ株式会社製)、等が挙げられる。
p)キラル化合物
本発明の重合性組成物には、キラルネマチック相を得ることを目的としてキラル化合物を含有してもよい。前記キラル化合物は、それ自体が液晶性を示す必要はなく、また、重合性基を有していても、有していなくてもよい。また、キラル化合物の螺旋の向きは、重合体の使用用途によって適宜選択することができる。
A1、A2、A3、A4、A5及びA6はそれぞれ独立して、1,4-フェニレン基、1,4-シクロヘキシレン基、1,4-シクロヘキセニル基、テトラヒドロピラン-2,5-ジイル基、1,3-ジオキサン-2,5-ジイル基、テトラヒドロチオピラン-2,5-ジイル基、1,4-ビシクロ(2,2,2)オクチレン基、デカヒドロナフタレン-2,6-ジイル基、ピリジン-2,5-ジイル基、ピリミジン-2,5-ジイル基、ピラジン-2,5-ジイル基、チオフェン-2,5-ジイル基-、1,2,3,4-テトラヒドロナフタレン-2,6-ジイル基、2,6-ナフチレン基、フェナントレン-2,7-ジイル基、9,10-ジヒドロフェナントレン-2,7-ジイル基、1,2,3,4,4a,9,10a-オクタヒドロフェナントレン-2,7-ジイル基、1,4-ナフチレン基、ベンゾ[1,2-b:4,5-b‘]ジチオフェン-2,6-ジイル基、ベンゾ[1,2-b:4,5-b‘]ジセレノフェン-2,6-ジイル基、[1]ベンゾチエノ[3,2-b]チオフェン-2,7-ジイル基、[1]ベンゾセレノフェノ[3,2-b]セレノフェン-2,7-ジイル基、又はフルオレン-2,7-ジイル基を表し、n、l及びkはそれぞれ独立して、0又は1を表し、0≦n+l+k≦3となり、
m5は0又は1を表し、
Z0、Z1、Z2、Z3、Z4、Z5及びZ6はそれぞれ独立して、-COO-、-OCO-、-CH2 CH2-、-OCH2-、-CH2O-、-CH=CH-、-C≡C-、-CH=CHCOO-、-OCOCH=CH-、-CH2CH2COO-、-CH2CH2OCO-、-COOCH2CH2-、-OCOCH2CH2-、-CONH-、-NHCO-、炭素数2~10のハロゲン原子を有してもよいアルキル基又は単結合を表し、
R5a及びR5bは、水素原子、ハロゲン原子、シアノ基又は炭素原子数1~18のアルキル基を表すが、該アルキル基は1つ以上のハロゲン原子又はCNにより置換されていても良く、この基中に存在する1つのCH2基又は隣接していない2つ以上のCH2基はそれぞれ相互に独立して、酸素原子が相互に直接結合しない形で、-O-、-S-、-NH-、-N(CH3)-、-CO-、-COO-、-OCO-、-OCOO-、-SCO-、-COS-又は-C≡C-により置き換えられていても良く、あるいはR5a及びR5bは一般式(10-a)
P5aは、下記の式(P-1)から式(P-20)で表される重合性基から選ばれる置換基を表す。
q)重合性基を有する非液晶性化合物
本発明の重合性組成物は、重合性基を有するが液晶化合物ではない化合物を添加することもできる。このような化合物としては、通常、この技術分野で重合性モノマーあるいは重合性オリゴマーとして認識されるものであれば特に制限なく使用することができる。添加する場合は、本発明の重合性組成物に用いる、上記一般式(1)で表される化合物の合計含有量及び上記2つ以上の重合性基を有する化合物の合計含有量の総量に対し、15質量%以下であることが好ましく、10質量%以下が更に好ましい。
r)その他液晶性化合物
本発明の重合性組成物は、前記一般式(1)で表される重合性基を1つ有する重合性液晶性化合物以外にも、重合性基を1つ有する重合性化合物を含有することができる。しかし、添加量が多すぎると、得られた光学異方体の光学特性が低下する恐れがあり、添加する場合は、本発明の重合性組成物に用いる、上記一般式(1)で表される化合物の合計含有量及び上記2つ以上の重合性基を有する化合物の合計含有量の総量に対し、30質量%以下とすることが好ましく、10質量%以下がさらに好ましく、5質量%以下が特に好ましい。
s)配向材料
本発明の重合性組成物は、配向性を向上させるために配向性が向上する配向材料を含有することができる。用いる配向材料は、本発明の重合性組成物に用いられる、重合性基を有する液晶性化合物を溶解させることができる溶剤に可溶であれば、公知慣用のものでよいが、添加することにより配向性を著しく劣化させない範囲で添加することができる。具体的には、本発明の重合性組成物に用いる、上記一般式(1)で表される化合物の合計含有量及び上記2つ以上の重合性基を有する化合物の合計含有量の総量に対し、0.05~30重量%が好ましく、0.5~15重量%がさらに好ましく、1~10重量%が特に好ましい。
R7は、水素原子、ハロゲン原子、ハロゲン化アルキル基、アリルオキシ基、シアノ基、ニトロ基、アルキル基、ヒドロキシアルキル基、アルコキシ基、カルボキシ基若しくはそのアルカリ金属塩、アルコキシカルボニル基、ハロゲン化メトキシ基、ヒドロキシ基、スルホニルオキシ基若しくはそのアルカリ金属塩、アミノ基、カルバモイル基、スルファモイル基又は(メタ)アクリロイル基、(メタ)アクリロイルオキシ基、(メタ)アクリロイルアミノ基、ビニル基、ビニルオキシ基及びマレイミド基からなる群から選ばれる重合性官能基を表す。
(重合体)
本発明の重合性組成物に開始剤を含有した状態で重合させることにより、本発明の重合体が得られる。本発明の重合体は、光学異方体、位相差フィルム、レンズ、着色剤、印刷物等に利用される。
(光学異方体の製造方法)
(光学異方体)
本発明の重合性組成物を、基材、あるいは、配向機能を有する基材上に塗布し、本発明の重合性組成物中の液晶性化合物分子を、ネマチック相やスメクチック相を保持した状態で均一に配向させ、重合させることによって、本発明の光学異方体が得られる。
(基材)
本発明の光学異方体に用いられる基材は、液晶表示素子、有機発光表示素子、その他表示素子、光学部品、着色剤、マーキング、印刷物や光学フィルムに通常使用する基材であって、本発明の重合性組成物溶液の塗布後の乾燥時における加熱に耐えうる耐熱性を有する材料であれば、特に制限はない。そのような基材としては、ガラス基材、金属基材、セラミックス基材、プラスチック基材や紙等の有機材料が挙げられる。特に基材が有機材料の場合、セルロース誘導体、ポリオレフィン、ポリエステル、ポリオレフィン、ポリカーボネート、ポリアクリレート、ポリアリレート、ポリエーテルサルホン、ポリイミド、ポリフェニレンスルフィド、ポリフェニレンエーテル、ナイロン又はポリスチレン等が挙げられる。中でもポリエステル、ポリスチレン、ポリオレフィン、セルロース誘導体、ポリアリレート、ポリカーボネート等のプラスチック基材が好ましい。基材の形状としては、平板の他、曲面を有するものであっても良い。これらの基材は、必要に応じて、電極層、反射防止機能、反射機能を有していてもよい。
(配向処理)
また、上記基材には、本発明の重合性組成物溶液を塗布乾燥した際に重合性組成物が配向するように、通常配向処理が施されている、あるいは配向膜が設けられていても良い。配向処理としては、延伸処理、ラビング処理、偏光紫外可視光照射処理、イオンビーム処理、基材へのSiO2の斜方蒸着処理、等が挙げられる。配向膜を用いる場合、配向膜は公知慣用のものが用いられる。そのような配向膜としては、ポリイミド、ポリシロキサン、ポリアミド、ポリビニルアルコール、ポリカーボネート、ポリスチレン、ポリフェニレンエーテル、ポリアリレート、ポリエチレンテレフタレート、ポリエーテルサルホン、エポキシ樹脂、エポキシアクリレート樹脂、アクリル樹脂、アゾ化合物、クマリン化合物、カルコン化合物、シンナメート化合物、フルギド化合物、アントラキノン化合物、アゾ化合物、アリールエテン化合物等の化合物、もしくは、前記化合物の重合体や共重合体が挙げられる。ラビングにより配向処理する化合物は、配向処理、もしくは配向処理の後に加熱工程を入れることで材料の結晶化が促進されるものが好ましい。ラビング以外の配向処理を行う化合物の中では光配向材料を用いることが好ましい。
(塗布)
本発明の光学異方体を得るための塗布法としては、アプリケーター法、バーコーティング法、スピンコーティング法、ロールコーティング法、ダイレクトグラビアコーティング法、リバースグラビアコーティング法、フレキソコーティング法、インクジェット法、ダイコーティング法、キャップコーティング法、ディップコーティング法、スリットコーティング法、スプレーコーティング法等、公知慣用の方法を行うことができる。重合性組成物を塗布後、乾燥させる。
(重合工程)
乾燥した重合性組成物の重合処理は、一様に配向した状態で一般に可視紫外線等の光照射、あるいは加熱によって行われる。重合を光照射で行う場合は、具体的には420nm以下の可視紫外光を照射することが好ましく、250~370nmの波長の紫外光を照射することが最も好ましい。但し、420nm以下の可視紫外光により重合性組成物が分解などを引き起こす場合は、420nm以上の可視紫外光で重合処理を行ったほうが好ましい場合もある。
(重合方法)
本発明の重合性組成物を重合させる方法としては、活性エネルギー線を照射する方法や熱重合法等が挙げられるが、加熱を必要とせず、室温で反応が進行することから活性エネルギー線を照射する方法が好ましく、中でも、操作が簡便なことから、紫外線等の光を照射する方法が好ましい。照射時の温度は、本発明の重合性組成物が液晶相を保持できる温度とし、重合性組成物の熱重合の誘起を避けるため、可能な限り30℃以下とすることが好ましい。尚、重合性液晶組成物は、通常、昇温過程において、C(固相)-N(ネマチック)転移温度(以下、C-N転移温度と略す。)から、N-I転移温度範囲内で液晶相を示す。一方、降温過程においては、熱力学的に非平衡状態を取るため、C-N転移温度以下でも凝固せず液晶状態を保つ場合がある。この状態を過冷却状態という。本発明においては、過冷却状態にある液晶組成物も液晶相を保持している状態に含めるものとする。具体的には390nm以下の紫外光を照射することが好ましく、250~370nmの波長の光を照射することが最も好ましい。但し、390nm以下の紫外光により重合性組成物が分解などを引き起こす場合は、390nm以上の紫外光で重合処理を行ったほうが好ましい場合もある。この光は、拡散光で、かつ偏光していない光であることが好ましい。紫外線照射強度は、0.05mW/cm2~10W/cm2の範囲が好ましい。特に、0.2mW/cm2~2W/cm2の範囲が好ましい。紫外線強度が0.05mW/cm2未満の場合、重合を完了させるのに多大な時間がかかる。一方、2W/cm2を超える強度では、重合性組成物中の液晶分子が光分解する傾向にあることや、重合熱が多く発生して重合中の温度が上昇し、重合性液晶のオーダーパラメーターが変化して、重合後のフィルムのリタデーションに狂いが生じる可能性がある。
(位相差フィルム)
本発明の位相差フィルムは、前記光学異方体を含有しており、液晶性化合物が基材に対して一様に連続的な配向状態を形成して、基材に対して面内、面外、面内と面外の両方、あるいは面内において2軸性を有していればよい。また、接着剤や接着層、粘着剤や粘着層、保護フィルムや偏光フィルム等が積層されていてもよい。
することができる。以下、本明細書の他の記載において同様である。
Rth=[(nx+ny)/2-nz]×d (2)
Nz係数=(nx-nz)/(nx-ny) (3)
R50=(nx-ny’)×d/cos(φ) (4)
(nx+ny+nz)/3=n0 (5)
ここで、
φ=sin-1[sin(50°)/n0] (6)
ny’=ny×nz/[ny2×sin2(φ)+nz2×cos2(φ)]1/2 (7)
市販の位相差測定装置では、ここに示した数値計算を装置内で自動的に行い、面内位相差値R0や厚み方向位相差値Rthなどを自動的に表示するようになっているものが多い。このような測定装置としては、例えば、RETS-100(大塚化学(株)製)を挙げることができる。
液晶セルでは、第1の位相差層として、ポジティブAプレートを使用することが好ましい。ここで、ポジティブAプレートは、フィルムの面内遅相軸方向の屈折率をnx、フィルムの面内進相軸方向の屈折率をny、フィルムの厚み方向の屈折率をnzとしたときに、「nx>ny=nz」の関係となる。ポジティブAプレートとしては、波長550nmにおける面内位相差値が10~300nmの範囲にあるものが好ましい。また、厚み方向位相差値は特に限定されない。Nz係数は、0.9~1.1の範囲が好ましい。
°傾斜して測定した位相差値R50、フィルムの厚みd、フィルムの平均屈折率n0を用
いて、式(1)と次式(4)~(7)から数値計算によりnx、ny、nzを求め、これ
らを式(2)に代入して算出することができる。また、Nz係数=は、式(3)から算出
することができる。以下、本明細書の他の記載において同様である。
Rth=[(nx+ny)/2-nz]×d (2)
Nz係数=(nx-nz)/(nx-ny) (3)
R50=(nx-ny’)×d/cos(φ) (4)
(nx+ny+nz)/3=n0 (5)
ここで、
φ=sin-1[sin(50°)/n0] (6)
ny’=ny×nz/[ny2×sin2(φ)+nz2×cos2(φ)]1/2 (7)
さらに本発明の位相差フィルムは、直線偏光板と組み合わせることで円偏光板として使用することもできる。円偏光板として使用する場合、本発明の位相差フィルムは、基材に対して重合性液晶性化合物が実質的に水平配向したポジティブAプレートであり、直線偏光板の偏光軸と位相差フィルムの遅相軸のなす角度は実質的に45°にするのが好ましい。
(レンズ)
本発明の重合性組成物を、基材、あるいは、配向機能を有する基材上に塗布し、もしくは、レンズ形状の金型に注入し、ネマチック相やスメクチック相を保持した状態で均一に配向させ、重合させることによって、本発明のレンズに使用することができる。レンズの形状は単純セル型、プリズム型、レンチキュラー型、等が挙げられる。
(液晶表示素子)
本発明の重合性組成物を、基材、あるいは、配向機能を有する基材上に塗布し、ネマチック相やスメクチック相を保持した状態で均一に配向させ、重合させることにより、本発明の液晶表示素子に使用することができる。使用形態としては、光学補償フィルム、液晶立体表示素子のパターン化された位相差フィルム、カラーフィルターの位相差補正層、オーバーコート層、液晶媒体用の配向膜、等が挙げられる。液晶表示素子は、少なくとも二つの基材に液晶媒体層、TFT駆動回路、ブラックマトリックス層、カラーフィルター層、スペーサー、液晶媒体層に相応の電極回路が最低限狭持されており、通常、光学補償層、偏光板層、タッチパネル層は二つの基材の外側に配置されるが、場合によっては、光学補償層、オーバーコート層、偏光板層、タッチパネル用の電極層が二つの基材内に狭持されてもよい。
(有機発光表示素子)
本発明の重合性組成物を、基材、あるいは、配向機能を有する基材に塗布し、ネマチック相やスメクチック相を保持した状態で均一に配向させ、重合させることにより、本発明の有機発光表示素子に使用することができる。使用形態としては、前記重合により得られた位相差フィルムと偏光板と組み合わせることにより、有機発光表示素子の反射防止フィルムとして使用することができる。反射防止フィルムとして使用する場合、偏光板の偏光軸と位相差フィルムの遅相軸のなす角度は45°程度が好ましい。偏光板と前記位相差フィルムは、接着剤や粘着剤等で貼り合わせてもよい。また、偏光板上にラビング処理や光配向膜を積層した配向処理等により、直接積層してもよい。このとき使用する前記偏光板は、偏光機能を有するフィルムであればよく、例えば、ポリビニルアルコール系フィルムにヨウ素や二色性色素を吸着させて延伸したフィルム、ポリビニルアルコール系フィルムを延伸してヨウ素や二色性染料あるいは、二色性色素を吸着させたフィルム、二色性染料を含有する水溶液を基板上に塗布して偏光層を形成したフィルム、ワイヤーグリッド偏光子等が挙げられる。
(照明素子)
本発明の重合性組成物を、ネマチック相やスメクチック相、あるいは、配向機能を有する基材上に配向させた状態で重合させた重合体は照明素子、特に発光ダイオード素子の放熱材料として使用することもできる。放熱材料の形態としては、プリプレグ、重合体シート、接着剤、金属箔付きシート、等が好ましい。
(光学部品)
本発明の重合性組成物を、ネマチック相やスメクチック相を保持した状態、あるいは、配向材料と組み合わせた状態で重合させることにより、本発明の光学部品として使用することができる。
(着色剤)
本発明の重合性組成物は、染料や有機顔料等の着色剤を添加して、着色剤として使用することもできる。
(偏光フィルム)
本発明の重合性組成物は、2色性色素、リオトロピック液晶やクロモニック液晶等と組み合わせる、あるいは添加して、偏光フィルムとして使用することもできる。
(重合性組成物(1)の調製)
式(1-6)で表される化合物55部、式(1-7)で表される化合物25部、式(2-a-1-a)で表される化合物20部をシクロペンタノン(CPN)400部に加えた後、60℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(Irg907:BASFジャパン株式会社製)3部、メガファックF-554(F-554:DIC株式会社製)0.2部、p-メトキシフェノール(MEHQ)0.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、透明で均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、実施例1等に用いる重合性組成物(1)を得た。
(重合性組成物(2)~(29)、比較用重合性組成物(C1)~(C2)の調製)
下記表に示す各化合物をそれぞれ下記表に示す割合に変更した以外は実施例1の重合性組成物(1)の調整と同一条件で、実施例2~29等に用いる重合性組成物(2)~(29)及び比較例1~2の重合性組成物(C1)~(C2)を得た。
(実施例1)
(溶解性)
本発明の重合性組成物(1)の溶解性は以下のようにして評価した。
○:調整後、透明で均一な状態が目視で確認できる。
△:加温、拡販したときには透明で均一な状態が目視で確認できるが、室温に戻したときに化合物の析出が確認される。
×:加温、撹拌しても化合物が均一溶解できない。
(保存安定性)
本発明の重合性組成物(1)を室温で1週間放置した後の状態を目視で観察した。本発明の重合性組成物は、3日後も透明で均一な状態を保持していた。なお、保存安定性の評価は
○:室温で3日放置後も透明で均一な状態が保持される。
△:室温で1日放置後も透明で均一な状態が保持される。
×:室温で1時間放置後に化合物の析出が確認される。
得られた結果を以下の表に示す。
重合性組成物(2)~(29)及び比較用重合性組成物(C1)~(C2)を用いて、溶解性、保存性を測定した。結果を、それぞれ、実施例2~29、比較例1~2とし、上記表に示す。
(実施例55)光学異方体
配向膜用ポリイミド溶液を厚さ0.7mmのガラス基材にスピンコート法を用いて塗布し、100℃で10分乾燥した後、200℃で60分焼成することにより塗膜を得た。得られた塗膜をラビング処理した。ラビング処理は、市販のラビング装置を用いて行った。
(配向性)
○:目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くない。
△:目視では欠陥はないが、偏光顕微鏡観察で全体的に無配向部分が存在している。
×:目視で全体的に欠陥がみられる。
(位相差比)
また、得られた光学異方体のリタデーション(位相差)を位相差フィルム・光学材料検査装置RETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は130nmであった。また、波長450nmにおける面内位相差(Re(450))とRe(550)の比Re(450)/Re(550)は0.851であり、均一性良好な位相差フィルムが得られた。
(実施例56~83)
用いる重合性組成物をそれぞれ、本発明の重合性組成物(2)~(29)に変更した以外は、実施例55と同一条件にて、実施例56~83の光学異方体を得た。
得られた結果を上記表に示す。
(重合性組成物(30)の調整)
式(1-6)で表される化合物40部、式(1-7)で表される化合物40部、式(2-a-1-a)で表される化合物10部、式(2-a-28)10部をメチルエチルケトン(MEK)400部に加えた後、60℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、透明で均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、実施例30等に用いる重合性組成物(30)を得た。
(重合性組成物(31)~(50)、比較用重合性組成物(C3)~(C4)の調製)
下記表に示す各化合物をそれぞれ下記表に示す割合に変更した以外は重合性組成物(30)の調整と同一条件で、実施例31~50等に用いる重合性組成物(31)~(50)及び比較例3~4等に用いる重合性組成物(C3)~(C4)を得た。
(重合性組成物(51)~(52)の調製)
式(1-7)で表される化合物50部、式(1-2)で表される化合物25部、式(2-a-1-a)で表される化合物25部をメチルエチルケトン(MEK)200部、及び、メチルイソブチルケトン(MIBK)200部に加えた後、60℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、透明で均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、実施例51等に用いる重合性組成物(51)を得た。
(重合性組成物(53)~(54)の調製)
式(1-7)で表される化合物40部、式(1-2)で表される化合物20部、式(2-a-1-a)で表される化合物20部、式(2-a-28)で表される化合物10部、式(2-b-1-a)で表される化合物10部をメチルエチルケトン(MEK)300部、及び、メチルイソブチルケトン(MIBK)100部に加えた後、60℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、透明で均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、実施例53等に用いる重合性組成物(53)を得た。
(溶解性)
本発明の重合性組成物(30)の溶解性は以下のようにして評価した。
○:調整後、透明で均一な状態が目視で確認できる。
△:加温、拡販したときには透明で均一な状態が目視で確認できるが、室温に戻したときに化合物の析出が確認される。
×:加温、撹拌しても化合物が均一溶解できない。
(保存安定性)
本発明の重合性組成物(30)を室温で1週間放置した後の状態を目視で観察した。本発明の重合性組成物は、3日後も透明で均一な状態を保持していた。なお、保存安定性の評価は
○:室温で3日放置後も透明で均一な状態が保持される。
△:室温で1日放置後も透明で均一な状態が保持される。
×:室温で1時間放置後に化合物の析出が確認される。
得られた結果を以下の表に示す。
重合性組成物(31)~(52)及び比較用重合性組成物(C3)~(C4)を用いて、溶解性、保存性、配向性を測定した。結果を、それぞれ、実施例31~52、比較例3~4とし、上記表に示す。
(実施例84)光学異方体
厚さ50μmの一軸延伸PETフィルムを市販のラビング装置を用いてラビング処理した後、本発明の重合性組成物(30)をバーコート法で塗布し、80℃で2分乾燥した。得られた塗布膜を室温まで冷却した後、UVコンベア装置(GSユアサ株式会社製)を用いてコンベア速度6m/minで紫外線を照射して、実施例84の光学異方体を得た。得られた光学異方体を以下の基準に従って評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。
(配向性)
○:目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くない。
△:目視では欠陥はないが、偏光顕微鏡観察で全体的に無配向部分が存在している。
×:目視で全体的に欠陥がみられる。
(位相差比)
また、得られた光学異方体のリタデーション(位相差)を位相差フィルム・光学材料検査装置RETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は130nmであった。また、波長450nmにおける面内位相差(Re(450))とRe(550)の比Re(450)/Re(550)は0.851であり、均一性良好な位相差フィルムが得られた。
(実施例85~104)
用いる重合性組成物をそれぞれ、本発明の重合性組成物(31)~(50)に変更した以外は、実施例84と同一条件にて、実施例85~104の光学異方体を得た。
(実施例105)
厚さ40μmの無延伸シクロオレフィンポリマーフィルム「ゼオノア」(日本ゼオン株式会社製)を市販のラビング装置を用いてラビング処理した後、本発明の重合性組成物(51)をバーコート法で塗布し、80℃で2分乾燥した。得られた塗布膜を室温まで冷却した後、UVコンベア装置(GSユアサ株式会社製)を用いてコンベア速度6m/minで紫外線を照射して、実施例105の光学異方体を得た。得られた光学異方体を上記の基準に従って評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また、得られた光学異方体の(Re(550)は121nm、波長450nmにおける面内位相差(Re(450))とRe(550)の比Re(450)/Re(550)は0.806であり、均一性良好な位相差フィルムが得られた。
(実施例106)
用いる重合性組成物をそれぞれ、本発明の重合性組成物(52)に変更した以外は、実施例105と同一条件にて、実施例106の光学異方体を得た。
得られた結果を上記表に示す。
(実施例107)
式(12-4)で表される光配向材料(重量平均分子量:25万)5部をシクロペンタノン95部に溶解させ、溶液を得た。得られた溶液を0.45μmのメンブランフィルターでろ過し、光配向溶液(1)を得た。次に厚さ0.7mmのガラス基材にスピンコート法を用いて塗布し、80℃で2分乾燥した後、直ぐに313nmの直線偏光を10mW/cm2の強度で20秒間照射して光配向膜(1)得た。得られた光配向膜上に重合性組成物(53)をスピンコート法で塗布し、100℃で2分乾燥した。得られた塗布膜を室温まで冷却した後、高圧水銀ランプを用いて、30mW/cm2の強度で30秒間紫外線を照射して実施例107の光学異方体を得た。得られた光学異方体を以下の基準に従って評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また、得られた光学異方体のリタデーションをRETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は125nmであり、均一性良好な位相差フィルムが得られた。
上記式(12-1)で表される光配向材料(重量平均分子量:20万)5部をN-メチル-2-ピロリドン95部に溶解させ、得られた溶液を0.45μmのメンブランフィルターでろ過し、光配向溶液(2)を得た。次に厚さ0.7mmのガラス基材にスピンコート法を用いて塗布し、100℃で5分乾燥した後、さらに130℃で10分乾燥した後、直ぐに313nmの直線偏光を10mW/cm2の強度で1分間照射して光配向膜(2)得た。得られた光配向膜上に重合性組成物(53)をスピンコート法で塗布し、100℃で2分乾燥した。得られた塗布膜を室温まで冷却した後、高圧水銀ランプを用いて、30mW/cm2の強度で30秒間紫外線を照射して実施例108の光学異方体を得た。得られた光学異方体を以下の基準に従って評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また、得られた光学異方体のリタデーションをRETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は120nmであり、均一性良好な位相差フィルムが得られた。
(実施例109)
上記式(12-9)で表される光配向材料1部を(2-エトキシエトキシ)エタノール50部、2-ブトキシエタノール49部に溶解させ、得られた溶液を0.45μmのメンブランフィルターでろ過し、光配向溶液(3)を得た。次に厚さ80μmのポリメタクリル酸メチル(PMMA)フィルムにバーコート法を用いて塗布し、80℃で2分乾燥した後、365nmの直線偏光を10mW/cm2の強度で50秒間照射して光配向膜(3)得た。得られた光配向膜上に重合性組成物(53)をスピンコート法で塗布し、100℃で2分乾燥した。得られた塗布膜を室温まで冷却した後、高圧水銀ランプを用いて、30mW/cm2の強度で30秒間紫外線を照射して実施例109の光学異方体を得た。得られた光学異方体の配向性を評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また、得られた光学異方体のリタデーションをRETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は137nmであり、均一性良好な位相差フィルムが得られた。
(実施例110~112)
重合性組成物(54)を使用した以外は、実施例107と同一条件で実施例110の光学異方体を得て、実施例108と同一条件で実施例111の光学異方体を得て、実施例109と同一条件で実施例112の光学異方体を得た。得られた光学異方体の配向性を評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全く、均一性良好な位相差フィルムが得られた。
(実施例113)
式(1-6)で表される化合物10部、式(1-7)で表される化合物55部、式(1-2)で表される化合物10部、式(2-a-1-a)で表される化合物7部、式(2-b-1-a)で表される化合物10部、式(2-b-1-b)で表される化合物8部、下記式(10-10)で表される化合物6部をメチルエチルケトン200部、及び、メチルイソブチルケトン200部に加えた後、60℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.05部、重量平均分子量1200のポリプロピレン0.2部、p-メトキシフェノール0.1部、イルガノックス10760.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、透明で均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、本発明の重合性組成物(113)を得た。
式(10-10)6部を上記式(10-33)3部に代えた以外は実施例113と同一条件にて、実施例114の光学異方体を得た。得られた光学異方体の配向性を評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また得られた光学異方体は透明であり、分光光度計(日立ハイテクサイエンス株式会社製)で透過率を測定したところ、赤外線領域に透過率が減少する領域が観測され、赤外線反射フィルムになっていることがわかった。さらにRETS-100を用いて入射光の角度を-50°から50°まで10°単位で変え、位相差を測定し、得られた位相差から波長550nmにおける面外位相差(Rth)を計算したところ、130nmであり、ネガCプレートになっていることがわかった。
(実施例115)
式(10-10)6部を上記式(10-38)8.5部に代えた以外は実施例113と同様にして、実施例115の光学異方体を得た。得られた光学異方体の配向性を評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また得られた光学異方体は透明であり、分光光度計(日立ハイテクサイエンス株式会社製)で透過率を測定したところ、紫外線領域に透過率が減少する領域が観測され、紫外線反射フィルムになっていることがわかった。さらにRETS-100を用いて入射光の角度を-50°から50°まで10°単位で変え、位相差を測定し、得られた位相差から波長550nmにおける面外位相差(Rth)を計算したところ、132nmであり、ネガCプレートになっていることがわかった。
(実施例116)
式(1-6)で表される化合物30部、式(1-7)で表される化合物30部、式(2-a-28)で表される化合物40部、式(12-10)で表される化合物(重量平均分子量:5万)1部をシクロペンタノン400部に加えた後、40℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.1部、p-メトキシフェノール0.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、透明で均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、本発明の重合性組成物(116)を得た。得られた重合性組成物(116)を厚さ0.7mmのガラス基材にスピンコート法を用いて塗布し、70℃で2分乾燥した後、さらに100℃で2分乾燥し、313nmの直線偏光を10mW/cm2の強度で30秒間照射した。その後、塗布膜を室温まで戻し、高圧水銀ランプを用いて、30mW/cm2の強度で30秒間紫外線を照射して実施例116の光学異方体を得た。得られた光学異方体の配向性を評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また、得られた光学異方体のリタデーションをRETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は137nmであり、均一性良好な位相差フィルムが得られた。
式(1-6)で表される化合物30部、式(1-7)で表される化合物30部、式(2-a-28)で表される化合物40部、式(12-4)で表される化合物(重量平均分子量:10万)0.6部をシクロペンタノン400部に加えた後、40℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、透明で均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、本発明の重合性組成物(117)を得た。得られた重合性組成物(117)を厚さ0.7mmのガラス基材にスピンコート法を用いて塗布し、60℃で2分乾燥した後、さらに110℃で2分乾燥し、60℃に戻して313nmの直線偏光を10mW/cm2の強度で50秒間照射した。その後、塗布膜を室温まで戻し、高圧水銀ランプを用いて、30mW/cm2の強度で30秒間紫外線を照射して実施例117の光学異方体を得た。得られた光学異方体の配向性を評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また、得られた光学異方体のリタデーションをRETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は130nmであり、均一性良好な位相差フィルムが得られた。
(実施例118)
式(1-6)で表される化合物30部、式(1-7)で表される化合物30部、式(2-a-28)で表される化合物40部、式(12-8)で表される化合物(重量平均分子量:1万)20部をシクロペンタノン400部に加えた後、40℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、透明で均一であった。得られた溶液を0.45μmのメンブランフィルターでろ過し、本発明の重合性組成物(118)を得た。得られた重合性組成物(118)を厚さ0.7mmのガラス基材にスピンコート法を用いて塗布し、60℃で2分乾燥した後、さらに110℃で2分乾燥し、60℃に戻して313nmの直線偏光を10mW/cm2の強度で100秒間照射した。その後、塗布膜を室温まで戻し、高圧水銀ランプを用いて、30mW/cm2の強度で30秒間紫外線を照射して実施例118の光学異方体を得た。得られた光学異方体の配向性を評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また、得られた光学異方体のリタデーションをRETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は108nmであり、均一性良好な位相差フィルムが得られた。
式(1-7)で表される化合物50部、式(2-a-1-a)で表される化合物10部、式(2-b-1-a)で表される化合物20部、式(2-b-1-b)で表される化合物20部、下記式(d-7)で表される化合物6部をシクロペンタノン400部に加えた後、60℃に加温、撹拌して分散溶解させ、分散溶解が確認された後、室温に戻し、イルガキュアOXE01(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部、イルガノックス1076(BASFジャパン株式会社製)0.1部、トリメチロールプロパン トリス(3-メルカプトプロピオネート)TMMP(SC有機化学株式会社製)2部を加えて、さらに撹拌を行い、溶液を得た。溶液は、均一であった。得られた溶液を0.5μmのメンブランフィルターでろ過し、本発明の重合性組成物(119)を得た。
式(d-7)を式(d-9)に代えた以外は、実施例119と同一条件にて実施例120の光学異方体を得た。得られた光学異方体の偏光度、透過率、及びコントラストをRETS-100(大塚電子株式会社製)で測定したところ、偏光度は98.5%、透過率は44.3%、コントラストは91であり、偏光フィルムとして機能することがわかった。
(実施例121)
式(1-7)で表される化合物40部、式(1-2)で表される化合物40部、式(2-a-1-a)で表される化合物10部、式(2-b-1-a)で表される化合物10部、をメチルエチルケトン100部、及び、メチルイソブチルケトン300部に加えた後、60℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、ライトエステルHOA(N)(共栄化学社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部、イルガノックス1035(BASFジャパン株式会社製)0.1部加えて、さらに撹拌を行い、溶液を得た。溶液は、均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、本発明の重合性組成物(121)を得た。
(実施例122~124)
ライトエステルHOA(N)3部をライトエステルHOB-A(共栄化学社製)3部に代えた以外は、実施例121と同一条件にて実施例122の光学異方体を得た。同様に、ライトエステルHOA(N)3部をA-SA(新中村化学社製)3部に代えた以外は、実施例121と同一条件にて実施例123の光学異方体を得た。同様に、ライトエステルHOA(N)3部をA-9300(新中村化学社製)2部に代えた以外は、実施例121と同一条件にて実施例124の光学異方体を得た。得られた実施例122~実施例124の光学異方体の配向性を評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また、得られた光学異方体は各々位相差を有しており、均一性良好な位相差フィルムが得られた。
(実施例125~126)
式(1-7)で表される化合物40部、式(1-2)で表される化合物40部、式(2-a-1-a)で表される化合物10部、式(2-b-1-a)で表される化合物10部、をメチルエチルケトン100部、及び、メチルイソブチルケトン300部に加えた後、60℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部、チヌビン765を0.1部、TMMP(SC有機化学株式会社製)を4部、サンコノールA600-50R(三光化学工業社製)を0.05部加えて、さらに撹拌を行い、溶液を得た。溶液は、均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、本発明の重合性組成物(125)を得た。重合性組成物(125)を用いて実施例121と同一条件にて実施例125の光学異方体を得た。
(実施例127)
式(1-6)で表される化合物3部、式(1-7)で表される化合物3部、式(2-b-1-a)で表される化合物3部、式(2-b-1-b)で表される化合物1部をシクロペンタノン40部に加えた後、60℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュアOXE01(BASFジャパン株式会社製)0.5部、p-メトキシフェノール0.01部、メガファック554(DIC株式会社製)0.02部、イルガノックス1076(BASFジャパン株式会社製)0.01部、TMMP(SC有機化学株式会社製)0.4部、チヌビン765(BASFジャパン株式会社製)0.01部、アルミナ粒子AA-04(住友化学株式会社製)8部、窒化ホウ素粒子HP-40(水島合金株式会社製)38部を加えて、撹拌混合し、本発明の重合性組成物(127)を得た。得られた重合性組成物を厚み180μmのPETフィルムにアプリケーター法を用いて塗布し、40℃で5分、さらに110℃で5分乾燥させた。得られた塗布膜をランプ出力2kW(80W/cm)のUVコンベア装置(GSユアサ株式会社製)を用いてコンベア速度3m/minで紫外線を照射して、重合体を得た。得られた重合体をPETフィルムから剥がし、2枚の銅箔で、前記銅箔のマット面がそれぞれ半硬化エポキシ樹脂組成物に対向するようにして挟み、真空プレスにてプレス温度200℃、真空度1kPa、プレス圧4MPa、加圧時間5分で真空熱圧着させた。熱硬化させた。その後、常圧230℃で1時間加熱し、実施例127の重合体を得た。
(ただし、x=1/(1+χ))
λmix:樹脂シートの熱伝導率(W/mK)
λres:樹脂シートにおける樹脂部分の熱伝導率(W/mK)
λfil:樹脂シートにおけるフィラー部分の熱伝導率(W/mK)(アルミナは30、窒化ホウ素は60とした。)
ν:フィラーの体積分率(体積%)
χ:フィラーの形状パラメーター(アルミナは2.2、窒化アルミニウムは2.2とした。)
本発明の比較のために、本発明の重合性組成物(127)からアルミナ粒子AA-04(住友化学株式会社製)8部、窒化ホウ素粒子HP-40(水島合金株式会社製)38部を除いて重合性組成物を作成した。得られた重合性組成物を厚み180μmのPETフィルムにアプリケーター法を用いて塗布し、40℃で5分、さらに110℃で5分乾燥させた。得られた塗布膜をランプ出力2kW(80W/cm)のUVコンベア装置(GSユアサ株式会社製)を用いてコンベア速度3m/minで紫外線を照射して、重合体を得た。得られた重合体をPETフィルムから剥がし、得られた重合体をPETフィルムから剥がし、2枚の銅箔で、前記銅箔のマット面がそれぞれ半硬化エポキシ樹脂組成物に対向するようにして挟み、真空プレスにてプレス温度200℃、真空度1kPa、プレス圧4MPa、加圧時間5分で真空熱圧着させた。熱硬化させた。その後、常圧230℃で1時間加熱し、重合体を得た。次に得られた重合体の銅箔をエッチングにて取り除き、厚み50μmの重合体フィルムを得た。得られた重合体フィルムを温度波熱分析装置(ai-Phase社製ai-Phase
mobile 1u)を用いて熱拡散率を測定した。この値と、前述の方法にて求めた密度と比熱との積から、フィラー無し重合体フィルムの熱伝導率を求めたところ、0.43W/mKであった。
式(1-6)で表される化合物30部、式(1-7)で表される化合物30部、式(1-109)で表される化合物10部、式(2-a-1-a)で表される化合物20部、式(2-b-1-b)で表される化合物10部をシクロペンタノン400部に加えた後、60℃に加温、撹拌して分散溶解させ、分散溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部、イルガノックス1076(BASFジャパン株式会社製)0.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、本発明の重合性組成物(128)を得た。
(実施例129)
厚さ0.7mmのガラス基材RAGLE-XG(コーニング株式会社製)にカラーフィルター層が形成された基材に配向膜用のポリイミド溶液をスピンコート法を用いて塗布し、100℃で10分乾燥した後、200℃で60分焼成することにより塗膜を得た。得られた塗膜をラビング処理した。ラビング処理は、市販のラビング装置を用いて行った。次に本発明の重合性組成物(128)をスピンコート法で塗布し、80℃で2分乾燥した。得られた塗布膜を室温まで2分かけて冷却した後、高圧水銀ランプを用いて、30mW/cm2の強度で30秒間紫外線を照射してポジティブAプレートを得た。
(実施例130)反射防止フィルム:有機発光素子
式(1-6)で表される化合物10部、式(1-7)で表される化合物50部、式(1-109)で表される化合物10部、式(2-a-1-a)で表される化合物20部、式(2-b-1-b)で表される化合物10部をメチルエチルケトン200部、及び、メチルイソブチルケトン200部に加えた後、60℃に加温、撹拌して分散溶解させ、分散溶解が確認された後、室温に戻し、イルガキュア907(BASFジャパン株式会社製)3部、メガファックF-554(DIC株式会社製)0.2部、p-メトキシフェノール0.1部、イルガノックス1076(BASFジャパン株式会社製)0.1部を加えて、さらに撹拌を行い、溶液を得た。溶液は、均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、本発明の重合性組成物(130)を得た。
(実施例131)
厚み40μmの延伸シクロオレフィンポリマーフィルム「ゼオノア」(日本ゼオン株式会社製)を市販のラビング装置を用いてラビング処理した後、本発明の重合性組成物(119)をバーコート法で塗布し、80℃で2分乾燥した後、ランプ出力2kWのUVコンベア装置(GSユアサ株式会社製)を用いてコンベア速度5m/minで紫外線を照射して、偏光フィルムを得た。
(重合性組成物(132)の調製)
式(1-6)で表される化合物20部、式(1-117)で表される化合物30部、式(2-a-43)で表される化合物50部をトルエン(TOL)300部、メチルエチルケトン(MEK)100部に加えた後、70℃に加温、撹拌して溶解させ、溶解が確認された後、室温に戻し、イルガキュア907(Irg907:BASFジャパン株式会社製)5部、メガファックF-554(F-554:DIC株式会社製)0.2部、p-メトキシフェノール(MEHQ)0.1部、を加えて、さらに撹拌を行い、溶液を得た。溶液は、透明で均一であった。得られた溶液を0.20μmのメンブランフィルターでろ過し、実施例1等に用いる重合性組成物(132)を得た。
(重合性組成物(133)~(141)の調製)
下記表に示す各化合物をそれぞれ下記表に示す割合に変更した以外は実施例132等に用いる重合性組成物(132)の調整と同一条件で、実施例133~151等に用いる重合性組成物(133)~(141)を得た。
(実施例132~141)
(溶解性)
本発明の重合性組成物(132)~(141)の溶解性、保存安定性(保存性)は以下のようにして評価した。
(溶解性)
○:調整後、透明で均一な状態が目視で確認できる。
△:加温、拡販したときには透明で均一な状態が目視で確認できるが、室温に戻したときに化合物の析出が確認される。
×:加温、撹拌しても化合物が均一溶解できない。
(保存安定性)
本発明の重合性組成物(132)~(141)を室温で3日間放置した後の状態を目視で観察した。本発明の重合性組成物は、3日後も透明で均一な状態を保持していた。なお、保存安定性の評価は、
○:室温で3日放置後も透明で均一な状態が保持される。
△:室温で1日放置後も透明で均一な状態が保持される。
×:室温で1時間放置後に化合物の析出が確認される。
配向膜用ポリイミド溶液を厚さ0.7mmのガラス基材にスピンコート法を用いて塗布し、100℃で10分乾燥した後、200℃で60分焼成することにより塗膜を得た。得られた塗膜をラビング処理した。ラビング処理は、市販のラビング装置を用いて行った。
(配向性)
○:目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くない。
△:目視では欠陥はないが、偏光顕微鏡観察で全体的に無配向部分が存在している。
×:目視で全体的に欠陥がみられる。
得られた結果を上記表に示す。
(位相差比)
また、得られた光学異方体のリタデーション(位相差)を位相差フィルム・光学材料検査装置RETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は130nmであった。また、波長450nmにおける面内位相差(Re(450))とRe(550)の比Re(450)/Re(550)は0.848であり、均一性良好な位相差フィルムが得られた。
(実施例143~144)
用いる重合性組成物をそれぞれ、本発明の重合性組成物(133)~(134)に変更した以外は、実施例142と同一条件にて、実施例143~144の光学異方体を得た。
(実施例145)
垂直配向用ポリイミド溶液を厚さ0.7mmのガラス基材にスピンコート法を用いて塗布し、100℃で10分乾燥した後、200℃で60分焼成することにより塗膜を得た。
(位相差比)
また、得られた光学異方体のリタデーション(位相差)、及び、リタデーションの入射角依存性を位相差フィルム・光学材料検査装置RETS-100(大塚電子株式会社製)で測定したところ、下記のとおり、波長550nmにおける面外位相差(Rth(550))は160nmであった。また、波長450nmにおける面外位相差(Rth(450))とRth(550)の比Rth(450)/Rth(550)は0.861であり、均一性良好な垂直配向した位相差フィルム(ポジティブCプレート)が得られた。なお、面内位相差は(Re(550))0nmであった(図1)。
(実施例146~147)
用いる重合性組成物をそれぞれ、本発明の重合性組成物(136)~(137)に変更した以外は、実施例145と同一条件にて、実施例146~147の光学異方体を得た。
(実施例148~149)
用いる重合性組成物をそれぞれ、本発明の重合性組成物(138)~(139)に変更した以外は、実施例142と同一条件にて、実施例148~149の光学異方体を得た。得られた光学異方体を以下の基準に従って評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。
(位相差比)
また、得られた光学異方体のリタデーション(位相差)、及び、リタデーションの入射角依存性を位相差フィルム・光学材料検査装置RETS-100(大塚電子株式会社製)で測定したところ、波長550nmにおける面内位相差(Re(550))は、実施例148が44nm、実施例149が60nmであった(図2)。また、波長450nmにおける面内位相差(Re(450))とRe(550)の比Re(450)/Re(550)は0.826であり、均一性良好なハイブリッド配向した位相差フィルム(ポジディブOプレート)が得られた。
(実施例150~151)
用いる重合性組成物をそれぞれ、本発明の重合性組成物(140)~(141)に変更した以外は、実施例142と同一条件にて、実施例150~151の光学異方体を得た。得られた光学異方体を以下の基準に従って評価したところ、目視では欠陥が全くなく、偏光顕微鏡観察でも欠陥が全くなかった。また、得られた光学異方体は緑色を呈しており、反射フィルムになっていることがわかった。
Claims (24)
- a)一般式(1)
b)少なくとも2つ以上の重合性基を有する重合性化合物、
c)必要に応じて開始剤、
及びd)必要に応じて溶剤、を含有する重合性組成物。 - 一般式(1)において、kが1であり、S11が、1個の-CH2-又は隣接していない2個以上の-CH2-が各々独立して-O-、-COO-、-OCO-、-OCO-O-、-CO-NH-、-NH-CO-、-CH=CH-又は-C≡C-に置き換えられても良い炭素原子数1から20のアルキレン基を表す、請求項1又は請求項2のいずれか一項に記載の重合性組成物。
- 一般式(1)において、W11及びW12に含まれるπ電子の総数が4から24である、請求項1から請求項3のいずれか一項に記載の重合性組成物。
- 一般式(1)において、W11に含まれる芳香族基が下記の式(W-1)から式(W-19)
- 前記少なくとも2つ以上の重合性基を有する重合性化合物が、下記一般式(2)~一般式(7)
S21~S72は各々独立してスペーサー基を又は単結合を表すが、S21~S72が複数存在する場合それらは各々同一であっても異なっていても良く、
X21~X72は各々独立して-O-、-S-、-OCH2-、-CH2O-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、X21~X72が複数存在する場合それらは各々同一であっても異なっていても良く(ただし、各P-(S-X)-結合には-O-O-を含まない。)、
MG21~MG71は各々独立してメソゲン性基を表し、
R31は水素原子、フッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、シアノ基、ニトロ基、イソシアノ基、チオイソシアノ基、又は、炭素原子数1から20のアルキル基を表すが、当該アルキル基は直鎖状であっても分岐状であっても良く、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、当該アルキル基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-又は-C≡C-によって置換されても良く、
m2~m7、n2~n7、l4~l6、k6は各々独立して0から5の整数を表す。)のいずれかで表される化合物である、請求項1から請求項5のいずれか1項に記載の重合性組成物。 - 前記メソゲン性基MG21~MG71が式(8-a)
A81、A82は各々独立して1,4-フェニレン基、1,4-シクロヘキシレン基、ピリジン-2,5-ジイル基、ピリミジン-2,5-ジイル基、ナフタレン-2,6-ジイル基、ナフタレン-1,4-ジイル基、テトラヒドロナフタレン-2,6-ジイル基、デカヒドロナフタレン-2,6-ジイル基又は1,3-ジオキサン-2,5-ジイル基を表すが、これらの基は無置換又は1つ以上のL2によって置換されても良いが、A81及び/又はA82が複数現れる場合は各々同一であっても異なっていても良く、
Z81及びZ82は各々独立して-O-、-S-、-OCH2-、-CH2O-、-CH2CH2-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-、-N=CH-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、Z81及び/又はZ82が複数現れる場合は各々同一であっても異なっていても良く、
Mは下記の式(M-1)から式(M-11)
Gは下記の式(G-1)から式(G-6)
W81は少なくとも1つの芳香族基を有する、炭素原子数5から30の基を表すが、当該基は無置換又は1つ以上のL2によって置換されても良く、
W82は水素原子、又は、炭素原子数1から20のアルキル基を表すが、当該アルキル基は直鎖状であっても分岐状であっても良く、当該アルキル基中の任意の水素原子はフッ素原子に置換されても良く、当該アルキル基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-によって置換されても良く、若しくは、W82はW81と同様の意味を表しても良く、また、W81及びW82は互いに連結し同一の環構造を形成しても良く、或いはW82は下記の基
W83、W84はそれぞれ独立してハロゲン原子、シアノ基、ヒドロキシ基、ニトロ基、カルボキシル基、カルバモイルオキシ基、アミノ基、スルファモイル基、少なくとも1つの芳香族基を有する炭素原子数5から30の基、炭素原子数1から20のアルキル基、炭素原子数3から20のシクロアルキル基、炭素原子数2から20のアルケニル基、炭素原子数3から20のシクロアルケニル基、炭素原子数1から20のアルコキシ基、炭素原子数2から20のアシルオキシ基、炭素原子数2から20の又は、アルキルカルボニルオキシ基を表すが、前記アルキル基、シクロアルキル基、アルケニル基、シクロアルケニル基、アルコキシ基、アシルオキシ基、アルキルカルボニルオキシ基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-又は-C≡C-によって置換されても良く、
但し、上記Mが式(M-1)~式(M-10)から選択される場合Gは式(G-1)~式(G-5)から選択され、Mが式(M-11)である場合Gは式(G-6)を表し、
L2はフッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基、又は、炭素原子数1から20のアルキル基を表すが、当該アルキル基は直鎖状であっても分岐状であっても良く、任意の水素原子はフッ素原子に置換されても良く、当該アルキル基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-から選択される基によって置換されても良いが、化合物内にL2が複数存在する場合それらは同一であっても異なっていても良く、j81及びj82は各々独立して0から5の整数を表すが、j81+j82は1から5の整数を表す。)で表される基、あるいは式(8-b)
A83、A84は各々独立して1,4-フェニレン基、1,4-シクロヘキシレン基、ピリジン-2,5-ジイル基、ピリミジン-2,5-ジイル基、ナフタレン-2,6-ジイル基、ナフタレン-1,4-ジイル基、テトラヒドロナフタレン-2,6-ジイル基、デカヒドロナフタレン-2,6-ジイル基又は1,3-ジオキサン-2,5-ジイル基を表すが、これらの基は無置換又は1つ以上のL2によって置換されても良いが、A83及び/又はA84が複数現れる場合は各々同一であっても異なっていても良く、
Z83及びZ84は各々独立して-O-、-S-、-OCH2-、-CH2O-、-CH2CH2-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-SCH2-、-CH2S-、-CF2O-、-OCF2-、-CF2S-、-SCF2-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-COO-CH2CH2-、-OCO-CH2CH2-、-CH2CH2-COO-、-CH2CH2-OCO-、-COO-CH2-、-OCO-CH2-、-CH2-COO-、-CH2-OCO-、-CH=CH-、-N=N-、-CH=N-、-N=CH-、-CH=N-N=CH-、-CF=CF-、-C≡C-又は単結合を表すが、Z83及び/又はZ84が複数現れる場合は各々同一であっても異なっていても良く、
M81は1,4-フェニレン基、1,4-シクロヘキシレン基、1,4-シクロヘキセニル基、テトラヒドロピラン-2,5-ジイル基、1,3-ジオキサン-2,5-ジイル基、テトラヒドロチオピラン-2,5-ジイル基、1,4-ビシクロ(2,2,2)オクチレン基、デカヒドロナフタレン-2,6-ジイル基、ピリジン-2,5-ジイル基、ピリミジン-2,5-ジイル基、ピラジン-2,5-ジイル基、チオフェン-2,5-ジイル基-、1,2,3,4-テトラヒドロナフタレン-2,6-ジイル基、ナフチレン-1,4-ジイル基、ナフチレン-1,5-ジイル基、ナフチレン-1,6-ジイル基、ナフチレン-2,6-ジイル基、フェナントレン-2,7-ジイル基、9,10-ジヒドロフェナントレン-2,7-ジイル基、1,2,3,4,4a,9,10a-オクタヒドロフェナントレン-2,7-ジイル基、ベンゾ[1,2-b:4,5-b‘]ジチオフェン-2,6-ジイル基、ベンゾ[1,2-b:4,5-b‘]ジセレノフェン-2,6-ジイル基、[1]ベンゾチエノ[3,2-b]チオフェン-2,7-ジイル基、[1]ベンゾセレノフェノ[3,2-b]セレノフェン-2,7-ジイル基、又はフルオレン-2,7-ジイル基から選ばれる基を表すが、これらの基は無置換又は1つ以上のL2によって置換されても良く、
L2はフッ素原子、塩素原子、臭素原子、ヨウ素原子、ペンタフルオロスルフラニル基、ニトロ基、イソシアノ基、アミノ基、ヒドロキシル基、メルカプト基、メチルアミノ基、ジメチルアミノ基、ジエチルアミノ基、ジイソプロピルアミノ基、トリメチルシリル基、ジメチルシリル基、チオイソシアノ基、又は、炭素原子数1から20のアルキル基を表すが、当該アルキル基は直鎖状であっても分岐状であっても良く、任意の水素原子はフッ素原子に置換されても良く、当該アルキル基中の1個の-CH2-又は隣接していない2個以上の-CH2-は各々独立して-O-、-S-、-CO-、-COO-、-OCO-、-CO-S-、-S-CO-、-O-CO-O-、-CO-NH-、-NH-CO-、-CH=CH-COO-、-CH=CH-OCO-、-COO-CH=CH-、-OCO-CH=CH-、-CH=CH-、-CF=CF-又は-C≡C-から選択される基によって置換されても良いが、化合物内にL2が複数存在する場合それらは同一であっても異なっていても良く、mは0から8の整数を表し、j83及びj84は各々独立して0から5の整数を表すが、j83+j84は1から5の整数を表す。)で表される基から選択される、請求項6に記載の重合性組成物。 - 前記少なくとも2つ以上の重合性基を有する重合性化合物が、式(I)
Re(450nm)/Re(550nm)<1.0 (I)
(式中、Re(450nm)は、前記少なくとも2つ以上の重合性基を有する化合物を基板上に分子の長軸方向が実質的に基板に対して水平に配向させたときの450nmの波長における面内位相差、Re(550nm)は、前記少なくとも2つ以上の重合性基を有する化合物を基板上に分子の長軸方向が実質的に基板に対して水平に配向させたときの550nmの波長における面内位相差を表す。)を満たす、請求項1から請求項8のいずれか一項に記載の重合性組成物。 - 請求項1から請求項9のいずれか一項に記載の重合性組成物を用いた重合体。
- 請求項1から請求項9のいずれか一項に記載の重合性組成物を用いた光学異方体。
- 請求項1から請求項9のいずれか一項に記載の重合性組成物を用いた位相差フィルム。
- 請求項11に記載の光学異方体、又は、請求項12に記載の位相差フィルムを含有する表示素子。
- 請求項11に記載の光学異方体、又は、請求項12に記載の位相差フィルムを含有する発光素子。
- 請求項10に記載の重合体を含有する発光ダイオード照明装置。
- 請求項12に記載の位相差フィルムを含有する反射フィルム。
- 請求項10に記載の重合体を含有するレンズシート。
- 請求項1から請求項9のいずれか一項に記載の重合性組成物、及び、2色性色素を含有する重合性組成物。
- 請求項18の重合性組成物を用いた偏光フィルム。
- 請求項1から請求項9のいずれか一項に記載の重合性組成物、及び、アゾ誘導体、カルコン誘導体、クマリン誘導体、シンナメート誘導体、シクロアルカン誘導体のうちのいずれか一種類の誘導体を含有する重合性組成物。
- 請求項20に記載の重合性組成物を用いた光学異方体。
- 請求項20に記載の重合性組成物を用いた位相差フィルム。
- 請求項12、あるいは20に記載の位相差フィルム、及び/または、請求項19に記載の偏光フィルムを含有する表示素子。
- 請求項12、あるいは22に記載の位相差フィルム、及び/または、請求項19に記載の偏光フィルムを含有する発光素子。
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