WO2016086532A1 - 柔性oled衬底及柔性oled封装方法 - Google Patents
柔性oled衬底及柔性oled封装方法 Download PDFInfo
- Publication number
- WO2016086532A1 WO2016086532A1 PCT/CN2015/072471 CN2015072471W WO2016086532A1 WO 2016086532 A1 WO2016086532 A1 WO 2016086532A1 CN 2015072471 W CN2015072471 W CN 2015072471W WO 2016086532 A1 WO2016086532 A1 WO 2016086532A1
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- WIPO (PCT)
- Prior art keywords
- metal foil
- polymer layer
- flexible oled
- layer
- flexible
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 53
- 238000000034 method Methods 0.000 title claims abstract description 15
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 14
- 239000011888 foil Substances 0.000 claims abstract description 77
- 229920000642 polymer Polymers 0.000 claims abstract description 76
- 229910052751 metal Inorganic materials 0.000 claims abstract description 72
- 239000002184 metal Substances 0.000 claims abstract description 72
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 16
- 239000001301 oxygen Substances 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000004642 Polyimide Substances 0.000 claims description 10
- 229920001721 polyimide Polymers 0.000 claims description 10
- 239000002243 precursor Substances 0.000 claims description 9
- 239000003292 glue Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 238000005452 bending Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 230000008093 supporting effect Effects 0.000 claims description 3
- 238000010073 coating (rubber) Methods 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 238000012858 packaging process Methods 0.000 abstract description 13
- 238000009413 insulation Methods 0.000 abstract description 4
- 230000035699 permeability Effects 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract 3
- 230000001070 adhesive effect Effects 0.000 abstract 3
- 230000000694 effects Effects 0.000 description 3
- 229920000307 polymer substrate Polymers 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 238000009459 flexible packaging Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K77/00—Constructional details of devices covered by this subclass and not covered by groups H10K10/80, H10K30/80, H10K50/80 or H10K59/80
- H10K77/10—Substrates, e.g. flexible substrates
- H10K77/111—Flexible substrates
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
- H10K2102/311—Flexible OLED
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Definitions
- the present invention relates to the field of display technologies, and in particular, to a flexible OLED substrate and a flexible OLED packaging method.
- the flat display device has many advantages such as thin body, power saving, no radiation, and has been widely used.
- the existing flat display devices mainly include a liquid crystal display (LCD) and an organic light emitting display (OLED).
- OLED display devices have become the most promising new display devices in recent years due to their advantages of self-luminescence, all solid state, and high contrast.
- the biggest feature of OLED display devices is that flexible display can be realized.
- Flexible display devices made of flexible substrates and which are light, flexible and portable are important development directions of OLED display devices.
- the conventional OLED display device uses a rigid glass substrate with low permeability to oxygen and water vapor, which can better protect the device.
- the flexible substrate applied to the flexible organic electroluminescent device is mainly a polymer substrate, and the polymer substrate is light, thin, strong and flexible, but the free volume fraction of the polymer substrate itself is small and the average segment is free. The greater the degree, it is easy to be penetrated by water and oxygen, shortening the life of organic light-emitting devices.
- the metal foil When the thickness of the metal foil is less than 100 ⁇ m, the metal foil can exhibit excellent flexibility, and is excellent in heat resistance and low in thermal expansion coefficient compared with the polymer, and in particular, there is no problem of water and oxygen permeation. It is used as a substrate material for a flexible organic electroluminescent device, but the metal foil as a substrate material of a flexible display device also has a problem of large conductivity and surface roughness.
- a polymer-metal foil composite flexible package substrate comprising: a first polymer layer 10, a metal foil 20 disposed on the first polymer layer 10, and disposed on the metal foil A second polymer layer 30 over the sheet 20.
- the surface size of the metal foil 20 is larger than the surface dimensions of the first polymer layer 10 and the second polymer layer 30, and the metal foil is excellent in flexibility and water and oxygen barrier properties. Overcome the problems of electrical conductivity and surface roughness.
- an organic electroluminescent device 50 is formed over the second polymer layer 30 of the flexible package substrate; then, the metal foil 20 on the flexible package substrate is not first
- the organic rubber 40 is coated over the portion covered by the polymer layer 10 and the second polymer layer 30, and the portion is adhered to the side of the organic electroluminescent device 50.
- the package structure It is still possible for water and oxygen to penetrate through the joint or the side of the polymer. And because it is a flexible device, when the device is deformed, stress occurs between the device and the substrate, and the stress is concentrated on the joint of the encapsulant, which is prone to cracking.
- the object of the present invention is to provide a flexible OLED substrate which has good flexibility and waterproof and oxygen permeability.
- the packaging process can be simplified, the reliability of the flexible packaging process can be improved, and water can be prevented.
- the leakage of oxygen through the package junction and the stress concentration when the flexible device is deformed causes the device to rupture.
- the present invention first provides a flexible OLED substrate comprising: a polymer layer, a metal foil disposed on the polymer layer, and an insulating rubber layer disposed on the metal foil;
- the surface size of the metal foil is larger than the surface size of the polymer layer, and the surface size of the polymer layer is larger than the surface size of the insulating rubber layer.
- the metal foil is a metal foil having water, oxygen, and flexibility bending capabilities.
- the metal foil is an aluminum foil.
- the metal foil has a thickness of between 3 ⁇ m and 100 ⁇ m.
- the polymer layer is a polymer layer that supports and protects the metal foil.
- the polymer layer is a polyimide layer.
- the polymer layer has a thickness of between 10 ⁇ m and 300 ⁇ m.
- the invention also provides a flexible OLED packaging method, comprising:
- Step 1 providing a metal foil, coating a polymer precursor solution on one side of the metal foil and then heating and solidifying to form a polymer layer;
- Step 2 Apply an insulating rubber material uniformly on the other side surface of the metal foil to form an insulating rubber layer with a rubber coating machine, thereby preparing a flexible OLED lining comprising a polymer layer, a metal foil and an insulating rubber layer. bottom;
- Step 3 Align the prepared OLED device with the flexible OLED substrate, and adhere the OLED device to the flexible OLED substrate through an insulating glue layer.
- the polymer precursor solution in the step 1 is a polyimide precursor solution, and the prepared polymer layer is a polyimide layer, and the polymer layer has a thickness of between 10 ⁇ m and 300 ⁇ m.
- the area of the insulating rubber layer in the step 2 is smaller than the area of the metal foil and the polymer layer, and is large.
- the area to be packaged for the OLED device and is located at the location covered by the metal foil and polymer layer.
- the OLED device in the step 3 is a bottom emission type OLED device.
- the present invention also provides a flexible OLED substrate comprising: a polymer layer, a metal foil disposed on the polymer layer, and an insulating rubber layer disposed on the metal foil; a surface size of the metal foil Greater than the surface size of the polymer layer, the surface size of the polymer layer is larger than the surface size of the insulating rubber layer;
- the metal foil is a metal foil having the ability to block water, oxygen and flexible bending;
- the thickness of the metal foil is between 3 ⁇ m and 100 ⁇ m;
- the polymer layer is a polymer layer having a supporting and protective effect on the metal foil;
- the thickness of the polymer layer is between 10 ⁇ m and 300 ⁇ m.
- the present invention prepares a flexible OLED substrate by using an insulating rubber material, which has good flexibility and water repellency and oxygen permeability.
- the prepared OLED flexible device is directly adhered to the substrate by using an insulating rubber material, and the substrate preparation and packaging process are combined to simplify the packaging process, and the stress generated between the device and the substrate when bent is caused by the entire device. Sharing, improving the reliability of the packaging process.
- Figure 1 is a prior art flexible OLED substrate
- FIG. 2 is an OLED display device packaged with the flexible OLED substrate of FIG. 1;
- Figure 3 is a flexible OLED substrate of the present invention.
- Figure 5 is an OLED display device incorporating a flexible OLED substrate package of the present invention.
- the present invention provides a flexible OLED substrate comprising: a polymer layer 1, a metal foil 2 disposed on the polymer layer 1 and an insulating rubber layer 3 disposed on the metal foil 2; the surface size of the metal foil 2 is larger than the surface size of the polymer layer 1, the polymer The surface size of the layer 1 is larger than the surface size of the insulating rubber layer 3.
- the metal foil 2 may be any metal foil having an ability to isolate water, oxygen, and flexible bending, such as aluminum foil; preferably, the metal foil 2 has a thickness of between 3 ⁇ m and 100 ⁇ m.
- the polymer layer 1 may be any polymer layer having a supporting and protective effect on the metal foil 2, such as a polyimide layer; preferably, the polymer layer 1 has a thickness of 10 ⁇ m to 300 ⁇ m. between.
- the material of the insulating glue layer 3 may be an insulating solid glue, and the insulating glue layer 3 is responsible for adhering the OLED device to the OLED flexible substrate during packaging, and has a certain insulation water, The action of oxygen, and because of its insulating properties, can avoid contact of the conductive metal foil with the device electrodes.
- the present invention further provides a flexible OLED packaging method, including:
- Step 1 A metal foil 2 is provided, and a polymer precursor solution is coated on the side of the metal foil 2 and then cured by heating to form a polymer layer 1.
- the metal foil 2 may be selected from an aluminum foil having a thickness of between 3 ⁇ m and 100 ⁇ m; the polymer precursor solution may be selected from a polyimide precursor solution, and the prepared polymer layer 1 is a polyimide.
- the layer, the polymer layer 1 has a thickness of between 10 ⁇ m and 300 ⁇ m.
- Step 2 uniformly coating the insulating rubber material on the other side surface of the metal foil sheet with a glue coater to form the insulating rubber material layer 3, thereby preparing the polymer layer 1, the metal foil sheet 2 and the insulating rubber material layer 3 Flexible OLED substrate.
- the area of the metal foil 2 in the step 1 should be larger than the area of the polymer layer 1; the area of the insulating rubber layer 3 coated in the step 2 should be smaller than that of the metal foil 2 and the polymer layer 1
- the area is larger than the area to be packaged by the OLED device 5, and is located at a position covered by the metal foil 2 and the polymer layer 1.
- Step 3 The prepared OLED device 5 is paired with the flexible OLED substrate, and the OLED device 5 is adhered to the flexible OLED substrate through the insulating rubber layer 3.
- the OLED device 5 in the step 3 is a bottom emission type OLED device.
- the insulating rubber layer 3 is adhered to the bottom and side edges of the OLED device 5.
- the OLED packaging method of the present invention simplifies the packaging process, and the insulating rubber material layer 3 in the obtained package structure is integrated, not spliced, thereby avoiding water and oxygen infiltration at the joint. Leakage, the stress generated between the device and the substrate when bent, will be shared by the entire device, improving the reliability of the packaging process.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Electroluminescent Light Sources (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
Abstract
Description
Claims (14)
- 一种柔性OLED衬底,包括:聚合物层,设于所述聚合物层上的金属箔片,及设于金属箔片上的绝缘胶材层;所述金属箔片的表面尺寸大于聚合物层的表面尺寸,聚合物层的表面尺寸大于绝缘胶材层的表面尺寸。
- 如权利要求1所述的柔性OLED衬底,其特征在于,所述金属箔片为具有隔绝水、氧能力和柔性弯曲能力的金属箔片。
- 如权利要求2所述的柔性OLED衬底,其中,所述金属箔片为铝箔。
- 如权利要求1所述的柔性OLED衬底,其中,所述金属箔片的厚度在3μm到100μm之间。
- 如权利要求1所述的柔性OLED衬底,其中,所述聚合物层为对金属箔片具有支撑和保护作用的聚合物层。
- 如权利要求5所述的柔性OLED衬底,其中,所述聚合物层为聚酰亚胺层。
- 如权利要求1所述的柔性OLED衬底,其中,所述聚合物层的厚度在10μm到300μm之间。
- 一种柔性OLED封装方法,包括:步骤1、提供一金属箔片,在金属箔片一侧涂布聚合物前体溶液然后加热固化形成聚合物层。步骤2、用胶材涂布机将绝缘胶材均匀涂覆于金属箔片另一侧表面形成绝缘胶材层,从而制备出包含聚合物层、金属箔片和绝缘胶材层的柔性OLED衬底;步骤3、将制备好的OLED器件与该柔性OLED衬底对组,通过绝缘胶材层将OLED器件粘附于该柔性OLED衬底上。
- 如权利要求8所述的柔性OLED封装方法,其中,所述步骤1中的聚合物前体溶液为聚酰亚胺前驱体溶液,制备出来的聚合物层为聚酰亚胺层,所述聚合物层的厚度在10μm到300μm之间。
- 如权利要求8所述的柔性OLED封装方法,其中,所述步骤2中的绝缘胶材层面积小于金属箔片和聚合物层的面积,大于OLED器件需封装的面积,并位于金属箔片和聚合物层所覆盖的位置。
- 如权利要求8所述的柔性OLED封装方法,其中,所述步骤3中的OLED器件为底发光型OLED器件。
- 一种柔性OLED衬底,包括:聚合物层,设于所述聚合物层上的 金属箔片,及设于金属箔片上的绝缘胶材层;所述金属箔片的表面尺寸大于聚合物层的表面尺寸,聚合物层的表面尺寸大于绝缘胶材层的表面尺寸;其中,所述金属箔片为具有隔绝水、氧能力和柔性弯曲能力的金属箔片;其中,所述金属箔片的厚度在3μm到100μm之间;其中,所述聚合物层为对金属箔片具有支撑和保护作用的聚合物层;其中,所述聚合物层的厚度在10μm到300μm之间。
- 如权利要求12所述的柔性OLED衬底,其中,所述金属箔片为铝箔。
- 如权利要求12所述的柔性OLED衬底,其中,所述聚合物层为聚酰亚胺层。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1706761.2A GB2546681B (en) | 2014-12-03 | 2015-02-08 | Flexible OLED susbtrate and flexible OLED package method |
US14/424,019 US20160372689A1 (en) | 2014-12-03 | 2015-02-08 | Flexible oled substrate and flexible oled package method |
JP2017528875A JP6637502B2 (ja) | 2014-12-03 | 2015-02-08 | フレキシブルoled実装方法 |
KR1020177012279A KR20170066572A (ko) | 2014-12-03 | 2015-02-08 | 플렉시블 oled 기판 및 플렉시블 oled 패키징 방법 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410727845.0 | 2014-12-03 | ||
CN201410727845.0A CN104538556B (zh) | 2014-12-03 | 2014-12-03 | 柔性oled衬底及柔性oled封装方法 |
Publications (1)
Publication Number | Publication Date |
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WO2016086532A1 true WO2016086532A1 (zh) | 2016-06-09 |
Family
ID=52854053
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2015/072471 WO2016086532A1 (zh) | 2014-12-03 | 2015-02-08 | 柔性oled衬底及柔性oled封装方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20160372689A1 (zh) |
JP (1) | JP6637502B2 (zh) |
KR (1) | KR20170066572A (zh) |
CN (1) | CN104538556B (zh) |
GB (1) | GB2546681B (zh) |
WO (1) | WO2016086532A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106711356A (zh) * | 2016-12-23 | 2017-05-24 | 成都新柯力化工科技有限公司 | 一种降低oled器件水、氧渗透率的方法 |
CN111915990A (zh) * | 2020-08-07 | 2020-11-10 | 武汉华星光电半导体显示技术有限公司 | 一种显示面板和显示装置 |
Families Citing this family (5)
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FR3056283B1 (fr) * | 2016-09-21 | 2021-05-14 | Valeo Vision | Dispositif lumineux comportant une source lumineuse surfacique |
CN107742628A (zh) * | 2017-09-12 | 2018-02-27 | 奕瑞影像科技(太仓)有限公司 | 柔性闪烁屏、放射线图像传感器及其制备方法 |
CN108597376B (zh) | 2018-04-25 | 2020-12-01 | 京东方科技集团股份有限公司 | 预拉伸基底及其制作方法、电子器件及其制作方法 |
CN109859627A (zh) * | 2018-12-19 | 2019-06-07 | 武汉华星光电半导体显示技术有限公司 | 柔性衬底及其制备方法 |
CN112510167B (zh) * | 2020-12-18 | 2023-08-15 | 重庆莱宝科技有限公司 | 显示面板及其制备方法 |
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2014
- 2014-12-03 CN CN201410727845.0A patent/CN104538556B/zh not_active Expired - Fee Related
-
2015
- 2015-02-08 JP JP2017528875A patent/JP6637502B2/ja not_active Expired - Fee Related
- 2015-02-08 KR KR1020177012279A patent/KR20170066572A/ko not_active Application Discontinuation
- 2015-02-08 WO PCT/CN2015/072471 patent/WO2016086532A1/zh active Application Filing
- 2015-02-08 GB GB1706761.2A patent/GB2546681B/en not_active Expired - Fee Related
- 2015-02-08 US US14/424,019 patent/US20160372689A1/en not_active Abandoned
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JP2018500731A (ja) | 2018-01-11 |
US20160372689A1 (en) | 2016-12-22 |
CN104538556B (zh) | 2017-01-25 |
GB201706761D0 (en) | 2017-06-14 |
KR20170066572A (ko) | 2017-06-14 |
CN104538556A (zh) | 2015-04-22 |
GB2546681A (en) | 2017-07-26 |
GB2546681B (en) | 2020-04-22 |
JP6637502B2 (ja) | 2020-01-29 |
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