WO2016076078A1 - セル構造体、その製造方法、および、燃料電池 - Google Patents
セル構造体、その製造方法、および、燃料電池 Download PDFInfo
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- WO2016076078A1 WO2016076078A1 PCT/JP2015/079495 JP2015079495W WO2016076078A1 WO 2016076078 A1 WO2016076078 A1 WO 2016076078A1 JP 2015079495 W JP2015079495 W JP 2015079495W WO 2016076078 A1 WO2016076078 A1 WO 2016076078A1
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
- H01M8/1253—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides the electrolyte containing zirconium oxide
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- H—ELECTRICITY
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- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
- H01M8/126—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides the electrolyte containing cerium oxide
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
- H01M2300/0074—Ion conductive at high temperature
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
- H01M2300/0074—Ion conductive at high temperature
- H01M2300/0077—Ion conductive at high temperature based on zirconium oxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a cell structure and a fuel cell including a solid electrolyte having proton conductivity.
- a fuel cell is a device that generates electricity by an electrochemical reaction between a fuel such as hydrogen and air (oxygen), and has high power generation efficiency because it can directly convert chemical energy into electricity.
- a solid oxide fuel cell hereinafter referred to as SOFC
- SOFC solid oxide fuel cell
- an operating temperature 700 ° C. or higher, particularly about 800 to 1000 ° C.
- the operating temperature is very high, the use is limited to large power generation facilities and household power generation.
- SOFC solid oxide fuel cell
- solid electrolytes having proton conductivity examples include compounds having a perovskite structure, such as barium zirconate doped with yttrium (hereinafter referred to as BZY), barium cerate doped with yttrium (hereinafter referred to as BCY), and the like.
- BZY barium zirconate doped with yttrium
- BCY barium cerate doped with yttrium
- a metal oxide is known (Patent Document 1).
- Metal oxides are susceptible to moisture.
- metal oxides containing cerium are more susceptible to moisture than metal oxides containing zirconium (Non-Patent Document 1).
- BZY is used as the solid electrolyte layer of the fuel cell
- the durability is excellent, but the power generation performance is inferior. This is because BZY is relatively stable against moisture, but has poor grain sinterability and high resistance due to poor sinterability.
- Patent Document 1 a perovskite oxide (BZCY) containing zirconium and cerium has also been proposed, but its power generation performance is low because of its higher resistance than when BCY is used.
- BZCY perovskite oxide
- One aspect of the present invention includes a cathode, an anode, and a solid electrolyte layer interposed between the cathode and the anode and having proton conductivity, the solid electrolyte layer having a perovskite structure, zirconium , Cerium and a compound containing a rare earth element other than cerium, and when the thickness of the solid electrolyte layer is T, the zirconium and the cerium at a position of 0.25 T from the cathode side surface of the solid electrolyte layer Element ratio: Zr C / Ce C and element ratio of Zr A / Ce A at the position of 0.25 T from the anode side surface of the solid electrolyte layer: Zr A / Ce A are Zr C / Ce C It relates to a cell structure satisfying> Zr A / Ce A and satisfying Zr C / Ce C > 1.
- Another aspect of the present invention is that, as a cathode material, an anode material, and a solid electrolyte, the following formula (2): A2Zr x Ce y B2 1-xy O 3- ⁇ (where A2 is alkaline earth) B2 is a rare earth element other than cerium, x1 / y1> 1, 0.4 ⁇ x1 ⁇ 1, 0 ⁇ y1 ⁇ 0.5, and ⁇ is the amount of oxygen deficiency) Z and the following formula (3): A3Zr x2 Ce y2 B3 1-x2-y2 O 3- ⁇ (where A3 is an alkaline earth metal element, B3 is a rare earth element other than cerium, and x1 / y1> x2 / y2, 0 ⁇ x2 ⁇ 0.5, 0.4 ⁇ y2 ⁇ 1, and ⁇ is the amount of oxygen deficiency), and a first step of preparing the anode material for the anode A second step of forming into
- Still another aspect of the present invention is a fuel comprising the above cell structure, and having an oxidant flow path for supplying an oxidant to the cathode and a fuel flow path for supplying fuel to the anode. It relates to batteries.
- a cell structure that exhibits excellent power generation performance and durability can be provided.
- FIG. 1 is a cross-sectional view schematically showing a fuel cell according to an embodiment of the present invention. It is a graph which shows the output density of the fuel cell which concerns on an Example and a comparative example. It is a graph which shows the voltage change of the fuel cell which concerns on an Example and a comparative example.
- a cell structure according to a first aspect of the present invention includes (1) a cathode, an anode, and a solid electrolyte layer interposed between the cathode and the anode and having proton conductivity, and the solid electrolyte.
- the layer has a perovskite structure, contains a compound containing rare earth elements other than zirconium, cerium, and cerium, and when the thickness of the solid electrolyte layer is T, 0.25 T from the surface on the cathode side of the solid electrolyte layer Element ratio of zirconium to cerium at the position of: Zr C / Ce C, and element ratio of zirconium to cerium at a position of 0.25 T from the surface on the anode side of the solid electrolyte layer: Zr A / Ce A satisfies Zr C / Ce C > Zr A / Ce A and Zr C / Ce C > 1. When this cell structure is applied to a fuel cell, excellent power generation efficiency and durability can be exhibited.
- the compound has an average composition of the entire solid electrolyte represented by the following formula (1): A1Zr x Ce y B1 1-xy O 3- ⁇ (where A1 is an alkaline earth metal element, B1 is a rare earth element other than cerium, and is preferably represented by 0.4 ⁇ x ⁇ 0.6, 0 ⁇ y ⁇ 0.4, and ⁇ is the amount of oxygen deficiency. This is because the proton conductivity is excellent.
- the method for producing a cell structure according to the second aspect of the present invention includes the following formula (2): A2Zr x1 Ce y1 B2 1-x1-y1 as a cathode material, an anode material, and a solid electrolyte.
- A2 is an alkaline earth metal element
- B2 is a rare earth element other than cerium
- formula (3) A3Zr x2 Ce y2 B3 1-x2-y2 O 3- ⁇ (where A3 is an alkaline earth metal element and B3 is cerium And a compound C represented by x1 / y1> x2 / y2, 0 ⁇ x2 ⁇ 0.5, 0.4 ⁇ y2 ⁇ 1, and ⁇ is an oxygen deficiency amount).
- a fuel cell according to a third aspect of the present invention includes (5) an oxidant flow path for supplying an oxidant to the cathode, and a fuel for supplying fuel to the anode. It has a flow path. This fuel cell exhibits excellent power generation efficiency and durability.
- the cell structure 1 of the present embodiment includes a cathode 2, an anode 4, a solid electrolyte layer 3 interposed between the cathode 2 and the anode 4 and having proton conductivity, Is provided.
- the cathode 2, the solid electrolyte layer 3, and the anode 4 are integrated by sintering.
- FIG. 1A shows a stacked cell structure, the shape of the cell structure is not limited to this. For example, it may have a cylindrical shape rounded with the anode 4 inside so as to have a hollow.
- Solid electrolyte layer In the cathode 2, water is generated by the reaction between the proton conducted from the solid electrolyte layer 3 and the oxidizing agent. Therefore, it is desirable that at least the cathode side of the solid electrolyte layer 3 contains a large amount of zirconium having low reactivity with water. However, a fuel cell using a metal oxide containing a large amount of zirconium as a solid electrolyte has low output and poor power generation performance.
- the element ratio of zirconium and cerium is changed between the cathode side and the anode side of the solid electrolyte layer 3 in order to improve the power generation performance while suppressing the reaction with water and improving the durability.
- the cathode side of the solid electrolyte layer 3 refers to the side of the solid electrolyte layer 3 facing the cathode 2
- the anode side refers to the side of the solid electrolyte layer 3 facing the anode 4.
- the solid electrolyte layer includes a compound having a perovskite structure (ABO 3 ).
- the B site of the above compound contains zirconium (Zr) and cerium (Ce). Further, a part of the B site is substituted with a rare earth element other than cerium, and the above compound exhibits proton conductivity by such a dopant.
- the metal element entering the A site is not particularly limited, but may be an alkaline earth metal such as barium (Ba), calcium (Ca), or strontium (Sr). These can be used alone or in combination of two or more.
- Ba is preferably contained in the A site from the viewpoint of proton conductivity. In this case, the ratio of Ba occupying the A site is preferably 50 atomic% or more with respect to the total of Ba and other elements.
- rare earth elements other than cerium, yttrium (Y), scandium (Sc), neodymium (Nd), samarium (Sm), gadolinium (Gd), ytterbium (Yb), holmium (Ho), erbium (Er) , Thulium (Tm) and the like.
- Y occupies a part of B site from a viewpoint of proton conductivity.
- the ratio of Y to the total dopant is preferably 50 atomic% or more with respect to the total of Y and other dopants.
- the solid electrolyte layer may contain components other than the above compounds, but its content is preferably small. For example, 99% by mass or more of the solid electrolyte layer is preferably the above compound.
- Components other than the above compounds are not particularly limited, and examples of the solid electrolyte include known compounds (including compounds having no proton conductivity).
- the solid electrolyte layer has a low Zr reactivity with water at a position of 0.25 T with respect to the thickness T from the surface 3C on the cathode side (see FIG. 1B. Hereinafter, it may be simply referred to as the vicinity of the surface 3C). Contains a lot of elements.
- the element of Zr in the surface 3C near (Zr C) is an element of susceptible Ce moisture (Ce C) greater than (element ratio: Zr C / Ce C> 1 ) for resistance to water improves.
- the element ratio in the vicinity of the surface 3C: Zr C / Ce C is preferably 2 or more (Zr C / Ce C ⁇ 2). When the element ratio in the vicinity of the surface 3C: Zr C / Ce C is within this range, resistance to water is further improved. Element ratio: Zr C / Ce C is more preferably 3 or more (Zr C / Ce C ⁇ 3 ).
- the element ratio in the vicinity of the surface 3A: Zr A / Ce A is preferably less than 2 (Zr A / Ce A ⁇ 2). When the element ratio near the surface 3A: Zr A / Ce A is within this range, the resistance at the interface is further reduced.
- the element ratio: Zr A / Ce A is more preferably 1.7 or less (Zr A / Ce A ⁇ 1.7).
- the element ratio in the solid electrolyte layer can be determined by evaluating the element distribution state (depth profile) using energy dispersive X-ray spectroscopy (EDX). For example, when a normal line to the main surface of the solid electrolyte layer passing through a certain point of the solid electrolyte layer is drawn, the boundary between the cathode and the solid electrolyte layer on the normal line to the boundary between the solid electrolyte layer and the anode is Let it be the thickness (T) of the solid electrolyte layer. The thickness T is divided into four equal parts, and the profile of the position inside the surface 0.25T from the surface 3C and the position inside the surface 3A to 0.25T is evaluated.
- EDX energy dispersive X-ray spectroscopy
- the same evaluation is performed for another certain point of the solid electrolyte layer.
- the element ratio can be obtained by performing averaging for a plurality of arbitrary points (for example, 5 points) and averaging. Also, evaluate the distribution of Zr and Ce in the thickness direction by using X-ray photoelectron spectroscopy (also called XPS (X-ray Photoelectron Spectroscopy) or ESCA (Electron Spectroscopy for Chemical Analysis)) and ion etching in combination.
- X-ray photoelectron spectroscopy also called XPS (X-ray Photoelectron Spectroscopy) or ESCA (Electron Spectroscopy for Chemical Analysis)
- the compound having a perovskite structure contained in the solid electrolyte layer is represented, for example, by the following formula (1).
- Formula (1) A1Zr x Ce y B1 1-xy O 3- ⁇
- A1 is an alkaline earth metal element
- B1 is a rare earth element other than cerium, and preferably satisfies 0.4 ⁇ x ⁇ 0.6 and 0 ⁇ y ⁇ 0.4.
- ⁇ is the amount of oxygen deficiency.
- Formula (1) has shown the average composition of the whole solid electrolyte. In terms of water resistance, the element amounts x and y more preferably satisfy x> y.
- the soot element A1 is an alkaline earth metal element that occupies the A site of the perovskite structure, and specific examples thereof include the same elements as described above. Especially, it is preferable that element A1 is Ba.
- the element B1 is a dopant that occupies a part of the B site of the perovskite structure, and specific examples thereof include the same elements as described above. Especially, it is preferable that the element B1 is Y.
- the average composition represented by the formula (1) can be determined by EDX, for example. Specifically, a normal line passing through a certain point is drawn in the same manner as described above, and element distribution states (depth profiles) at a plurality of locations (for example, five locations) at different distances from the surface 3C on the normal are evaluated. By averaging the obtained profiles, an average composition can be obtained.
- the element ratio of Zr to Ce in the first region Zr R1 / Ce R1 is The element ratio between Zr and Ce is preferably larger than Zr R2 / Ce R2 . This is because the amount of Zr element on the cathode side increases and the resistance to water is further improved. Furthermore, by relatively increasing the proportion of the Ce element in other portions, not only the interface but also the resistance of the grain boundary inside the solid electrolyte layer is reduced, and the output is easily improved.
- the element ratio in the region from the surface 3C to 0.3T: Zr 0.3 / Ce 0.3 and the element ratio in the other region: Zr 0.7 / Ce 0.7 are Zr 0. More preferably, 3 / Ce 0.3 > Zr 0.7 / Ce 0.7 is satisfied. This is because if the region with a high Ce ratio is wide, the output characteristics are easily improved.
- the element ratio in the first region and the second region is an average value in each region and can be obtained in the same manner as described above. Specifically, a normal line is drawn in the same manner as described above, and in a range (first region) from the surface 3C to 0.5T at a plurality of locations (for example, three locations) at different distances from the surface 3C on the normal line. The profile is evaluated by EDX and averaged to obtain the element ratio of Zr and Ce in the first region. The element ratio of Zr and Ce can be similarly determined for the second region.
- the element ratio in the first region: Zr R1 / Ce R1 is preferably 2 or more (Zr R1 / Ce R1 ⁇ 2).
- the element ratio in the second region: Zr R2 / Ce R2 is preferably less than 2 (Zr R2 / Ce R2 ⁇ 2).
- the thickness of the solid electrolyte layer 3 is not particularly limited, but is preferably about 5 ⁇ m to 25 ⁇ m from the viewpoint of further reducing the resistance.
- Zr / Ce may change so as to decrease from the cathode side toward the anode side. This change may be continuous or stepwise as long as it can be grasped as an overall trend.
- a normal passing through one point is drawn, and the depth profiles at a plurality of locations (for example, 5 locations) at different distances from the surface 3C on the normal are evaluated by EDX, and the element ratio at each location is evaluated. : Zr / Ce is calculated.
- the element ratio thus calculated: Zr / Ce is plotted on a graph in which the horizontal axis is the distance from the surface 3C and the vertical axis is the element ratio: Zr / Ce. From this graph, when the approximate straight line or approximate curve obtained by the least square method is downward-sloping, the overall tendency is that the element ratio: Zr / Ce decreases from the cathode side toward the anode side. It can be determined that
- the respective element ratios: Zr 0.2 / Ce 0.2 and Zr 0.4 / Ce 0.4 are the same, or Zr 0.2 / Even when Ce 0.2 ⁇ Zr 0.4 / Ce 0.4 is satisfied, the relationship with the element ratio at the points of 0.2T, 0.5T, and 0.7T is Zr 0.2 / Ce 0. .2 > Zr 0.5 / Ce 0.5 and Zr 0.5 / Ce 0.5 > Zr 0.7 / Ce 0.7 , the element ratio: Zr / Ce is on the cathode side It can be considered that it becomes small continuously as it goes to the anode side.
- the element ratio in the first region occupying the range from the surface 3C to 0.5T for example, the change rate of the element ratio is 20% or less
- the element ratio in the second region occupying the remaining range There is almost no change (for example, the change rate of the element ratio is 20% or less)
- the average element ratio Zr L1 / Ce L1 in the first region and the average element ratio Zr L2 / in the second region When Ce L2 satisfies Zr L1 / Ce L1 > Zr L2 / Ce L2 , the element ratio: Zr / Ce can be considered to decrease stepwise from the cathode side toward the anode side. it can.
- the cathode 2 can adsorb oxygen molecules, dissociate them and ionize them, and has a porous structure.
- a reaction oxygen reduction reaction
- Oxide ions are generated by dissociation of an oxidant (oxygen) introduced from an oxide flow path, which will be described later.
- a known material used as a cathode of a fuel cell or a gas decomposition apparatus can be used.
- a compound having a perovskite structure is preferable.
- LSCF lanthanum strontium cobalt ferrite
- LSM Lanthanum strontium manganite
- LSC Lanthanum strontium manganite
- LSC La 1-d Sr d CoO 3- ⁇ , 0 ⁇ d ⁇ 1, ⁇ is the oxygen deficiency amount
- SSC samarium strontium cobaltite
- SSC Sm 1-e Sr e CoO 3- ⁇ , 0 ⁇ e
- the cathode 2 may contain a catalyst such as Ag. This is because the reaction between the proton and the oxidizing agent is promoted.
- the cathode 2 can be formed by mixing the catalyst and the above materials and sintering.
- the thickness of the cathode 2 is not particularly limited, but may be about 10 ⁇ m to 30 ⁇ m.
- the anode 4 has a porous structure.
- a reaction fuel oxidation reaction
- a fuel such as hydrogen introduced from a flow path to be described later is oxidized to release protons and electrons.
- the material of the anode for example, a known material used as an anode of a fuel cell can be used. Specifically, nickel oxide (NiO) which is a catalyst component, yttrium oxide (Y 2 O 3 ), BCY, BZY, or a solid electrolyte represented by the above formula (1) (hereinafter sometimes referred to as BZCY) And the like.
- NiO nickel oxide
- Y 2 O 3 yttrium oxide
- BCY yttrium oxide
- BZY solid electrolyte represented by the above formula (1)
- BZCY solid electrolyte represented by the above formula (1)
- the anode 4 containing such a composite oxide can be formed by mixing and sintering NiO powder and BZCY powder, for example. Further, the thickness of the anode 4 may be about 30 ⁇ m to 800 ⁇ m, for example. The anode 4 may be increased in thickness to function as a support for the cell structure 1.
- FIG. 1 shows the case where the anode 4 is thicker than the cathode 2 and the anode 4 functions as a support for the cell structure 1.
- the size of the anode 4 is not limited to this, and may be smaller than the cathode 2, for example.
- the cell structure has gas decomposition performance, and this cell structure can be used in a gas decomposition apparatus.
- a catalyst having a function of decomposing the gas may be included in the anode.
- the catalyst having a function of decomposing gas such as ammonia include compounds containing at least one catalyst component selected from the group consisting of Fe, Co, Ti, Mo, W, Mn, Ru, and Cu.
- a buffer layer may be interposed between the cathode 2 and the solid electrolyte layer 3.
- the buffer layer has a function of suppressing peeling and cracking between the cathode 2 and the solid electrolyte layer 3.
- the soot buffer layer has proton conductivity and has low reactivity with the cathode 2 and the solid electrolyte layer 3.
- the coefficient of thermal expansion of the material used for the buffer layer is preferably a value between the coefficients of thermal expansion of the cathode 2 and the solid electrolyte layer 3. Examples of such a material include lanthanum zirconate doped with yttrium having a pyrochlore structure.
- the thickness of the buffer layer is not particularly limited, but may be about 1 ⁇ m to 5 ⁇ m.
- a cell structure including solid electrolyte layers having different element ratios: Zr / Ce on the cathode side and the anode side can be produced, for example, as follows.
- a cathode material, an anode material (both will be described later), and two types of solid electrolytes having different element ratios of Zr and Ce: Zr / Ce are prepared (first step).
- a compound having a relatively large Zr / Ce is referred to as Compound Z
- a compound having a relatively small Zr / Ce is referred to as Compound C.
- Compound Z is represented by the following formula (2), for example.
- Formula (2) A2Zr x1 Ce y1 B2 1-x1-y1 O 3- ⁇
- x1 / y1> 1 is satisfied.
- the element A2 is preferably an alkaline earth metal element
- the element B2 is preferably a rare earth element other than cerium, and preferably satisfies 0.4 ⁇ x1 ⁇ 1 and 0 ⁇ y1 ⁇ 0.5.
- ⁇ is the amount of oxygen deficiency.
- Compound C is represented, for example, by the following formula (3).
- Formula (3) A3Zr x2 Ce y2 B3 1-x2-y2 O 3- ⁇
- x1 / y1> x2 / y2 is satisfied.
- the element A3 is preferably an alkaline earth metal element
- the element B3 is preferably a rare earth element other than cerium, and preferably satisfies 0 ⁇ x2 ⁇ 0.5 and 0.4 ⁇ y2 ⁇ 1.
- ⁇ is the amount of oxygen deficiency.
- Examples of the soot element A2 and the element A3 include the same elements as exemplified as the element A1.
- Examples of the element B2 and the element B3 include the same elements as exemplified as the element B1.
- the element A2 and the element A3 may be the same or different.
- the element B2 and the element B3 may be the same or different.
- a paste obtained by mixing the powder of compound C and the binder resin on the surface of the molded anode material so as to have a predetermined thickness Laminate by screen printing, spray coating, spin coating, dip coating, etc. (third step).
- a paste prepared by mixing the compound Z powder and the binder resin on the surface of the compound C is laminated in the same manner so as to have a predetermined thickness, and is sintered at a temperature of 1300 to 1500 ° C., for example.
- a solid electrolyte layer is formed (fourth step).
- a cathode material is laminated on the surface of the solid electrolyte layer by the same method, and then sintered in an oxygen atmosphere at, for example, 800 to 1100 ° C. (fifth step).
- the preliminary sintering may be performed at a temperature lower than the temperature at which the anode material is sintered (for example, 900 to 1100 ° C.). By pre-sintering, the compound C is easily laminated in the third step.
- the binder resin may be removed by heating to a relatively low temperature of about 600 to 800 ° C., and then the temperature may be raised to 1300 to 1500 ° C. for sintering.
- the material for the buffer layer may be laminated on the surface of the solid electrolyte layer, and then the cathode material may be laminated. Thereby, a buffer layer is formed between the solid electrolyte layer and the cathode. Examples of the method for laminating the buffer layer material include the same method as in the case of the solid electrolyte.
- the anode material and the compound C are co-sintered, and the compound C and the compound Z are co-sintered.
- compound C and compound Z are co-sintered, mutual diffusion of Zr and Ce occurs. Therefore, in the solid electrolyte layer to be formed, the element ratio of Zr and Ce changes so as to continuously decrease from the cathode side toward the anode side.
- the solid electrolyte to be used is not limited to two types, and may be three or more types.
- a step of stacking a compound having an intermediate element ratio: Zr / Ce between the compound C and the compound Z may be added between the stacking steps of the compound C and the compound Z.
- the element ratio of Zr and Ce increases as it goes from the cathode side to the anode side.
- a solid electrolyte layer that is significantly smaller can be formed.
- the layer containing the compound Z is laminated and sintered to suppress the mutual diffusion of Zr and Ce between the compound C and the compound Z. Because. It should be noted that the interface of each layer may include a very thin region where Zr and Ce are interdiffused.
- a method in which compound Z is laminated after compound C in the third step and then co-sintered with compound C and compound Z in the fourth step is preferable.
- the solid electrolyte used is not limited to two types, and may be three or more types.
- a step of laminating and sintering a compound having an intermediate element ratio: Zr / Ce between the compound C and the compound Z may be added between the sintering step of the compound C and the laminating step of the compound Z.
- element ratio: Zr / Ce can be changed in 3 steps or more.
- a solid electrolyte in which Ba occupies A site and Y occupies part of B site can be synthesized by the following method. Powders of barium carbonate, zirconium oxide, cerium oxide and yttrium oxide are mixed at a predetermined ratio, and pulverized and kneaded for 24 hours using a ball mill. The obtained mixture is uniaxially compressed at 20 to 50 MPa and formed into pellets, and then fired at 1200 to 1600 ° C. for 10 to 24 hours in an air atmosphere. By changing the blending of zirconium oxide and cerium oxide, the element ratio of Zr and Ce can be changed. The obtained solid electrolyte is pulverized and kneaded again for 10 to 100 hours using a ball mill to obtain a solid electrolyte powder.
- FIG. 2 schematically shows a cross section of the structure of the fuel cell 10.
- the fuel cell 10 includes a cell structure 1, an oxidant flow path 23 for supplying an oxidant to the cathode, and a fuel flow path 43 for supplying fuel to the anode.
- the oxidant flow path 23 has an oxidant inlet into which the oxidant flows and an oxidant discharge port through which water generated by the reaction, unused oxidant, and the like are discharged (both not shown).
- a gas containing oxygen is exemplified.
- the fuel flow path 43 has a fuel gas inlet through which fuel gas flows, and a fuel gas outlet through which unused fuel, N 2 or CO 2 generated by the reaction, and the like are discharged (both not shown).
- the fuel cell 10 includes a proton conductive solid electrolyte layer, the fuel cell 10 can be operated at an intermediate temperature range of less than 700 ° C., preferably about 400 to 600 ° C.
- the oxidant channel 23 may be formed in, for example, the cathode side separator 22 disposed outside the cathode.
- the fuel flow path 43 may be formed in the anode side separator 42 arrange
- the fuel cell 10 is configured by stacking a plurality of cell structures, for example, the cell structure 1, the cathode separator 22, and the anode separator 42 are stacked as a unit.
- the plurality of cell structures 1 may be connected in series by, for example, a separator having gas channels (oxidant channels and fuel channels) on both surfaces.
- the material of the heel separator examples include heat-resistant alloys such as stainless steel, nickel-base alloy, and chromium-base alloy in terms of conductivity and heat resistance. Of these, stainless steel is preferable because it is inexpensive. Since PCFC has an operating temperature of about 400 to 600 ° C., stainless steel can be used as a separator material.
- the fuel cell 10 may further include a current collector.
- the fuel cell 10 includes a cathode-side current collector 21 disposed between the cathode and the cathode-side separator 22, and an anode-side current collector 41 disposed between the anode and the anode-side separator 52. You may have.
- the cathode current collector 21 functions to supply the cathode while diffusing the oxidant gas introduced from the oxidant flow path 23.
- the anode-side current collector 41 functions to supply fuel to the anode while diffusing the fuel gas introduced from the fuel flow path 43. Therefore, each current collector is preferably a breathable structure.
- Examples of structures used for each current collector include metal porous bodies including platinum, silver, silver alloys, nickel, nickel alloys, metal meshes, punching metals, expanded metals, and the like.
- a metal porous body is preferable at the point of lightweight property or air permeability.
- a porous metal body having a three-dimensional network structure is preferable.
- the three-dimensional network structure refers to a structure in which rod-like or fibrous metals constituting a metal porous body are three-dimensionally connected to form a network.
- a sponge-like structure or a nonwoven fabric-like structure can be mentioned.
- the metal porous body can be formed, for example, by coating a resin porous body having continuous voids with the metal as described above. When the internal resin is removed after the metal coating process, a cavity is formed inside the skeleton of the metal porous body, and the metal becomes hollow.
- nickel “Celmet” registered trademark manufactured by Sumitomo Electric Industries, Ltd. can be used.
- Example 1 Production of cell structure A cell structure was produced by the following procedure. NiO is mixed with BZY (BaZr 0.8 Y 0.2 O 2.9 ) powder and BCY (BaCe 0.8 Y 0.2 O 2.9 ) powder so as to contain 70% by volume of Ni (catalyst component). And pulverized and kneaded by a ball mill. The BZY powder and the BCY powder were mixed so that the volume ratio was 1: 1.
- the circular sheet-like molded object which comprises an anode was formed by press molding, and it pre-sintered at 1000 degreeC for 10 hours.
- a paste obtained by mixing BCY (BaCe 0.8 Y 0.2 O 2.9 ) powder, an organic solvent (butyl acetate carbitol) and a binder resin (ethyl cellulose) on one surface of the molded body was screened. Applied by printing.
- a paste obtained by mixing BZY (BaZr 0.8 Y 0.2 O 2.9 ) powder, the same organic solvent as described above, and a binder resin is applied by screen printing, and then water-soluble at 750 ° C.
- the functional binder resin was removed.
- an LSCF paste was prepared by mixing LSCF (La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3- ⁇ ) powder and the same organic solvent as described above.
- the LSCF paste was applied to the surface of the solid electrolyte layer by spraying. Subsequently, heat treatment was performed at 1000 ° C. for 2 hours to sinter LSCF to form a cathode (thickness 20 ⁇ m).
- Comparative Example 1 A fuel cell a was produced and evaluated 1 and 2 in the same manner as in Example 1 except that only BCY (BaCe 0.8 Y 0.2 O 2.9 ) powder was used as the solid electrolyte.
- Comparative Example 2 A fuel cell b was prepared and evaluated 1 in the same manner as in Example 1 except that only BZY (BaZr 0.8 Y 0.2 O 2.9 ) powder was used as the solid electrolyte.
- Comparative Example 3 A fuel cell c was prepared and evaluated 1 in the same manner as in Example 1 except that only BZCY (BaZr 0.6 Ce 0.2 Y 0.2 O 2.9 ) powder was used as the solid electrolyte. It was. Element ratio: Zr / Ce was 3.0 at any of point 1, point 2, and point 3, and no change in element ratio was observed between the anode side and the cathode side.
- BZCY BaZr 0.6 Ce 0.2 Y 0.2 O 2.9
- Battery A in which the element ratio of the solid electrolyte layer on the cathode side and the anode side: Zr / Ce is changed has a much higher output than the battery b using only BZY as the solid electrolyte and the battery c using BZCY. Indicated.
- the battery a using BCY as a solid electrolyte was excellent in initial output, but the voltage decreased with time and was inferior in durability.
- the battery A does not show a decrease in voltage over time and is excellent in durability.
- the cell structure of the present invention is excellent in power density and durability, and can be applied to various solid oxide fuel cells.
Abstract
Description
最初に本発明の実施形態の内容を列記して説明する。
本発明の第1の局面に係るセル構造体は、(1)カソードと、アノードと、前記カソードおよび前記アノードの間に介在し、プロトン伝導性を有する固体電解質層と、を備え、前記固体電解質層は、ペロブスカイト構造を有し、ジルコニウム、セリウムおよびセリウム以外の希土類元素を含む化合物を含み、前記固体電解質層の厚みをTとするとき、前記固体電解質層の前記カソード側の表面から0.25Tの位置における前記ジルコニウムと前記セリウムとの元素比:ZrC/CeCと、前記固体電解質層の前記アノード側の表面から0.25Tの位置における前記ジルコニウムと前記セリウムとの元素比:ZrA/CeAとが、ZrC/CeC>ZrA/CeAを満たし、かつ、ZrC/CeC>1である。このセル構造体を、燃料電池に適用すると、優れた発電効率および耐久性を発揮することができる。
本発明の実施形態を具体的に以下に説明する。なお、本発明は、以下の内容に限定されるものではなく、請求の範囲によって示され、請求の範囲と均等の意味および範囲内でのすべての変更が含まれることが意図される。
カソード2では、固体電解質層3から伝導されたプロトンと酸化剤との反応により、水が生成する。そのため、固体電解質層3の少なくともカソード側は、水との反応性の低いジルコニウムを多く含むことが望ましい。しかし、ジルコニウムを多く含む金属酸化物を固体電解質として用いる燃料電池は、出力が低く発電性能に劣る。本実施形態では、水との反応を抑制して耐久性を向上させながら、発電性能をより向上させるため、固体電解質層3のカソード側とアノード側とで、ジルコニウムとセリウムとの元素比を変化させる。
固体電解質層3のカソード側とは、固体電解質層3のカソード2と対向する側をいい、アノード側とは、固体電解質層3のアノード4と対向する側をいう。
式(1):A1ZrxCeyB11-x-yO3-δ
式(1)において、A1はアルカリ土類金属元素、B1はセリウム以外の希土類元素であって、0.4<x≦0.6、0<y≦0.4を満たすことが好ましい。δは酸素欠損量である。また、式(1)は、固体電解質全体の平均的な組成を示している。耐水性の点で、元素量xおよびyは、x>yを満たすことがより好ましい。
カソード2は、酸素分子を吸着し、解離させてイオン化することができ、かつ、多孔質の構造を有している。カソード2では、固体電解質層3を介して伝導されてきたプロトンと、酸化物イオンとの反応(酸素の還元反応)が生じている。酸化物イオンは、後述する酸化物流路から導入された酸化剤(酸素)が解離することにより生成する。
アノード4は、多孔質の構造を有している。アノード4では、後述する流路から導入される水素などの燃料を酸化して、プロトンと電子とを放出する反応(燃料の酸化反応)が行われる。
一方、アンモニアの分解により同時に生成したN2は、排気ガスとして後述する燃料ガス出口から排出される。アノードには、上記ガスを分解する機能を有する触媒を含ませてもよい。アンモニア等のガスを分解する機能を有する触媒としては、Fe、Co、Ti、Mo、W、Mn、RuおよびCuよりなる群から選択される少なくとも1種の触媒成分を含む化合物が挙げられる。
カソード2と固体電解質層3との間に、バッファ層を介在させても良い。バッファ層は、カソード2と固体電解質層3との間の剥離やクラックを抑制する機能を有する。
カソード側とアノード側とで元素比:Zr/Ceが異なる固体電解質層を含むセル構造体は、例えば、以下のようにして作製することができる。
式(2):A2Zrx1Cey1B21-x1-y1O3-δ
式(2)において、x1/y1>1を満たす。元素A2はアルカリ土類金属元素、元素B2はセリウム以外の希土類元素であることが好ましく、0.4≦x1≦1、0≦y1≦0.5を満たすことが好ましい。δは酸素欠損量である。
式(3):A3Zrx2Cey2B31-x2-y2O3-δ
式(3)において、x1/y1>x2/y2を満たす。元素A3はアルカリ土類金属元素、元素B3はセリウム以外の希土類元素であることが好ましく、0≦x2<0.5、0.4≦y2≦1を満たすことが好ましい。δは酸素欠損量である。
炭酸バリウム、酸化ジルコニウム、酸化セリウムおよび酸化イットリウムの粉末を所定の割合で混合し、ボールミルを用いて24時間、粉砕混練を行う。得られた混合物を、20~50MPaで一軸圧縮成形してペレット状に成形した後、大気雰囲気下で1200~1600℃で10~24時間焼成する。酸化ジルコニウムおよび酸化セリウムの配合を変化させることにより、ZrとCeとの元素比を変化させることができる。得られた固体電解質を再び、ボールミルを用いて10~100時間の粉砕混練を行うことにより、固体電解質の粉末を得ることができる。
図2に燃料電池10の構造の断面を、模式的に示す。
燃料電池10は、セル構造体1と、カソードに酸化剤を供給するための酸化剤流路23、および、アノードに燃料を供給するための燃料流路43を有する。
酸化剤流路23は、例えば、カソードの外側に配置されるカソード側セパレータ22に形成されていても良い。同様に、燃料流路43は、例えば、アノードの外側に配置されるアノード側セパレータ42に形成されていても良い。
燃料電池10は、さらに集電体を備えていてもよい。例えば、燃料電池10は、カソードとカソード側セパレータ22との間に配置されるカソード側集電体21と、アノードとアノード側セパレータ52との間に配置されるアノード側集電体41とを、備えていてもよい。カソード側集電体21は、集電機能に加え、酸化剤流路23から導入される酸化剤ガスを拡散させながら、カソードに供給する機能を果たす。アノード側集電体41は、集電機能に加え、燃料流路43から導入される燃料ガスを拡散させながら、アノードに供給する機能を果たす。そのため、各集電体は、通気性を有する構造体であることが好ましい。
(1)セル構造体の作製
下記の手順でセル構造体を作製した。
BZY(BaZr0.8Y0.2O2.9)粉末およびBCY(BaCe0.8Y0.2O2.9)粉末に、Ni(触媒成分)を70体積%含むようにNiOを混合し、ボールミルによって粉砕混練した。BZY粉末とBCY粉末とは、体積比で1:1となるように混合した。
上記で得られたセル構造体(直径90mm)のカソードおよびアノードのそれぞれの表面に、ニッケル多孔質体(住友電気工業株式会社製、セルメット、厚み1mm、気孔率95体積%)で構成された集電体を積層した。さらに、カソード側の集電体の上に、酸化剤流路を有するステンレス鋼製のカソード側セパレータを積層し、アノード側集電体の上に、燃料流路を有するステンレス鋼製のアノード側セパレータを積層して、図2に示す燃料電池Aを製作した。各集電体には、リード線の一方の端部を接合した。上記リード線の他方の端部は、燃料電池の外部に引き出し、各リード線の間の電流値および電圧値を計測できるように、計測器に接続した。
動作温度を600℃として、作製された燃料電池のアノードに燃料ガスとして水素を100cm3/分で流し、カソードに空気を200cm3/分で流した時の初期の出力密度を求めた。結果を図3に示す。
(評価2)電圧変化
(1)と同様の条件で、定電流(120mA/cm2)で発電させたときの電圧の変化を測定した。結果を図4に示す。
固体電解質としてBCY(BaCe0.8Y0.2O2.9)粉末のみを使用したこと以外は、実施例1と同様にして、燃料電池aを作製し、評価1および2を行った。
固体電解質としてBZY(BaZr0.8Y0.2O2.9)粉末のみを使用したこと以外は、実施例1と同様にして、燃料電池bを作製し、評価1を行った。
固体電解質としてBZCY(BaZr0.6Ce0.2Y0.2O2.9)粉末のみを使用したこと以外は、実施例1と同様にして、燃料電池cを作製し、評価1を行った。元素比:Zr/Ceは、地点1、地点2、地点3のいずれにおいても3.0であり、アノード側とカソード側とで、元素比の変化は見られなかった。
Claims (5)
- カソードと、
アノードと、
前記カソードおよび前記アノードの間に介在し、プロトン伝導性を有する固体電解質層と、を備え、
前記固体電解質層は、ペロブスカイト構造を有し、ジルコニウム、セリウムおよびセリウム以外の希土類元素を含む化合物を含み、
前記固体電解質層の厚みをTとするとき、
前記固体電解質層の前記カソード側の表面から0.25Tの位置における前記ジルコニウムと前記セリウムとの元素比:ZrC/CeCと、
前記固体電解質層の前記アノード側の表面から0.25Tの位置における前記ジルコニウムと前記セリウムとの元素比:ZrA/CeAとが、
ZrC/CeC>ZrA/CeAを満たし、かつ、ZrC/CeC>1である、セル構造体。 - 前記元素比:ZrC/CeC≧2であり、
前記元素比:ZrA/CeA<2である、請求項1に記載のセル構造体。 - 前記化合物が、下記式(1):
A1ZrxCeyB11-x-yO3-δ
(ただし、A1はアルカリ土類金属元素であり、B1はセリウム以外の希土類元素であり、0.4<x≦0.6、0<y≦0.4、δは酸素欠損量である)
で表わされる、請求項1または2に記載のセル構造体。 - カソード用材料、アノード用材料、および、固体電解質として、下記式(2):
A2Zrx1Cey1B21-x1-y1O3-δ
(ただし、A2はアルカリ土類金属元素であり、B2はセリウム以外の希土類元素であり、x1/y1>1、0.4≦x1≦1、0≦y1≦0.5、δは酸素欠損量である)
で表わされる化合物Zと、下記式(3):
A3Zrx2Cey2B31-x2-y2O3-δ
(ただし、A3はアルカリ土類金属元素であり、B3はセリウム以外の希土類元素であり、x1/y1>x2/y2、0≦x2<0.5、0.4≦y2≦1、δは酸素欠損量である)
で表わされる化合物Cと、を準備する第1工程と、
前記アノード用材料をアノードの形状に成形する第2工程と、
成形された前記アノード用材料の表面に前記化合物Cを積層する第3工程と、
積層された前記化合物Cの表面に前記化合物Zを積層し、焼結して、固体電解質層を形成する第4工程と、
前記固体電解質層の表面に、前記カソード用材料を積層し、焼結する第5工程と、を備える、セル構造体の製造方法。 - 請求項1に記載のセル構造体を備え、
前記カソードに酸化剤を供給するための酸化剤流路、および、前記アノードに燃料を供給するための燃料流路を有する、燃料電池。
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JP2016105375A (ja) * | 2014-12-01 | 2016-06-09 | 住友電気工業株式会社 | セル構造体、電解質膜−電極接合体、および、燃料電池 |
WO2018230248A1 (ja) * | 2017-06-15 | 2018-12-20 | 住友電気工業株式会社 | 固体電解質部材、固体酸化物型燃料電池、水電解装置、水素ポンプ及び固体電解質部材の製造方法 |
JP2019197692A (ja) * | 2018-05-11 | 2019-11-14 | 日本碍子株式会社 | 燃料電池セル |
JPWO2019171905A1 (ja) * | 2018-03-06 | 2021-02-12 | 住友電気工業株式会社 | セル構造体 |
US20210057763A1 (en) * | 2018-05-01 | 2021-02-25 | Sumitomo Electric Industries, Ltd. | Fuel cell |
WO2021140817A1 (ja) * | 2020-01-07 | 2021-07-15 | パナソニックIpマネジメント株式会社 | 電解質膜、膜電極接合体、電気化学セル、電解質膜の製造方法 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3748033A4 (en) * | 2018-01-29 | 2021-07-07 | Mitsui Mining & Smelting Co., Ltd. | OXYGEN PERMEABLE ELEMENT AND TARGET SPRAY MATERIAL |
JP6773240B2 (ja) | 2018-08-30 | 2020-10-21 | 堺化学工業株式会社 | 固体酸化物形燃料電池用電解質材料とその前駆体の製造方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004303712A (ja) * | 2002-09-13 | 2004-10-28 | Toto Ltd | 固体酸化物形燃料電池 |
JP2006302602A (ja) * | 2005-04-19 | 2006-11-02 | Mitsubishi Heavy Ind Ltd | 固体酸化物形燃料電池及び固体酸化物形燃料電池の製造方法 |
WO2007060925A1 (ja) * | 2005-11-24 | 2007-05-31 | Japan Science & Technology Agency | 電気化学セル及び電気化学セルの製造方法 |
JP2012023017A (ja) * | 2010-06-15 | 2012-02-02 | Ngk Insulators Ltd | 燃料電池セル |
JP2013105718A (ja) * | 2011-11-16 | 2013-05-30 | Toyota Motor Corp | 電解質膜の製造方法 |
JP2014207215A (ja) * | 2013-03-21 | 2014-10-30 | 株式会社日本触媒 | 固体酸化物形燃料電池ハーフセル、及び固体酸化物形燃料電池 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3733030B2 (ja) | 2000-02-14 | 2006-01-11 | 松下電器産業株式会社 | イオン伝導体 |
US7632596B2 (en) * | 2003-11-05 | 2009-12-15 | Illinois Institute Of Technology | Distributed feed fuel cell stack |
JP5443325B2 (ja) | 2010-12-02 | 2014-03-19 | 日本電信電話株式会社 | 固体酸化物形燃料電池および固体酸化物形燃料電池用単セル |
DE112012001206T5 (de) | 2011-11-30 | 2014-07-03 | Panasonic Corporation | Brennstoffzellen-System |
CN103613105B (zh) * | 2013-11-25 | 2016-01-06 | 中国科学院宁波材料技术与工程研究所 | 单电池、其制备方法及应用 |
-
2015
- 2015-10-20 KR KR1020177009856A patent/KR20170082511A/ko unknown
- 2015-10-20 EP EP15859401.0A patent/EP3220464B1/en active Active
- 2015-10-20 CN CN201580061586.5A patent/CN107112564B/zh active Active
- 2015-10-20 US US15/525,104 patent/US10424801B2/en active Active
- 2015-10-20 JP JP2016558945A patent/JP6642446B2/ja active Active
- 2015-10-20 WO PCT/JP2015/079495 patent/WO2016076078A1/ja active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004303712A (ja) * | 2002-09-13 | 2004-10-28 | Toto Ltd | 固体酸化物形燃料電池 |
JP2006302602A (ja) * | 2005-04-19 | 2006-11-02 | Mitsubishi Heavy Ind Ltd | 固体酸化物形燃料電池及び固体酸化物形燃料電池の製造方法 |
WO2007060925A1 (ja) * | 2005-11-24 | 2007-05-31 | Japan Science & Technology Agency | 電気化学セル及び電気化学セルの製造方法 |
JP2012023017A (ja) * | 2010-06-15 | 2012-02-02 | Ngk Insulators Ltd | 燃料電池セル |
JP2013105718A (ja) * | 2011-11-16 | 2013-05-30 | Toyota Motor Corp | 電解質膜の製造方法 |
JP2014207215A (ja) * | 2013-03-21 | 2014-10-30 | 株式会社日本触媒 | 固体酸化物形燃料電池ハーフセル、及び固体酸化物形燃料電池 |
Non-Patent Citations (1)
Title |
---|
See also references of EP3220464A4 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016105375A (ja) * | 2014-12-01 | 2016-06-09 | 住友電気工業株式会社 | セル構造体、電解質膜−電極接合体、および、燃料電池 |
WO2018230248A1 (ja) * | 2017-06-15 | 2018-12-20 | 住友電気工業株式会社 | 固体電解質部材、固体酸化物型燃料電池、水電解装置、水素ポンプ及び固体電解質部材の製造方法 |
JPWO2019171905A1 (ja) * | 2018-03-06 | 2021-02-12 | 住友電気工業株式会社 | セル構造体 |
JP7136185B2 (ja) | 2018-03-06 | 2022-09-13 | 住友電気工業株式会社 | セル構造体 |
US20210057763A1 (en) * | 2018-05-01 | 2021-02-25 | Sumitomo Electric Industries, Ltd. | Fuel cell |
US11888185B2 (en) * | 2018-05-01 | 2024-01-30 | Sumitomo Electric Industries, Ltd. | Fuel cell |
JP2019197692A (ja) * | 2018-05-11 | 2019-11-14 | 日本碍子株式会社 | 燃料電池セル |
WO2021140817A1 (ja) * | 2020-01-07 | 2021-07-15 | パナソニックIpマネジメント株式会社 | 電解質膜、膜電極接合体、電気化学セル、電解質膜の製造方法 |
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CN107112564B (zh) | 2020-07-14 |
US10424801B2 (en) | 2019-09-24 |
EP3220464B1 (en) | 2018-11-28 |
EP3220464A4 (en) | 2017-09-20 |
JP6642446B2 (ja) | 2020-02-05 |
KR20170082511A (ko) | 2017-07-14 |
US20170317371A1 (en) | 2017-11-02 |
EP3220464A1 (en) | 2017-09-20 |
JPWO2016076078A1 (ja) | 2017-08-17 |
CN107112564A (zh) | 2017-08-29 |
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