Classifications

• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/362—Composites
  • H01M4/366—Composites as layered products
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
  • H01M4/134—Electrodes based on metals, Si or alloys
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/05—Accumulators with non-aqueous electrolyte
  • H01M10/052—Li-accumulators
  • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/05—Accumulators with non-aqueous electrolyte
  • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
  • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
  • H01M10/0566—Liquid materials
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
  • H01M4/139—Processes of manufacture
  • H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
  • H01M4/386—Silicon or alloys based on silicon
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
  • H01M4/621—Binders
  • H01M4/622—Binders being polymers
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M2004/021—Physical characteristics, e.g. porosity, surface area
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M2220/00—Batteries for particular applications
  • H01M2220/10—Batteries in stationary systems, e.g. emergency power source in plant
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M2220/00—Batteries for particular applications
  • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M2300/00—Electrolytes
  • H01M2300/0017—Non-aqueous electrolytes
  • H01M2300/0025—Organic electrolyte
  • H01M2300/0045—Room temperature molten salts comprising at least one organic ion
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
  • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
  • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
  • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
  • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
  • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
  • Y02E60/10—Energy storage using batteries
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
  • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

• the disclosure relates to energy storage devices. More particularly, the disclosure describes lithium-ion batteries.
• Silicon's volume expansion during lithiation make its use as a battery material problematical. While the commercialized graphite electrode expands roughly 10-13% during lithium intercalation, silicon's expansion amounts to nearly 300%, generating structural degradation and instability of the solid-electrolyte interphase. Such instabilities ultimately shorten the battery life to inadequate levels, cause breaking of conduction channels, active material isolation, continuous solid-electrolyte interphase reformation, and a mechanically unstable solid-electrolyte interface.
• the solid-electrolyte interphase layer forms on the anode surface through reductive decomposition of the electrolyte during charging of the battery.
• Silicon anodes suffer from a dynamic solid-electrolyte interphase that must reform each cycle as expansion during lithiation causes the layer to break. Formation of the solid-electrolyte interphase consumes Li + and depletes electrolyte during every cycle.
• full-cells In contrast to half- cells, which utilize a Li metal counterelectrode with an effectively unlimited supply of Li + , full-cells have a limited supply of Li + provided by the cathode. It follows that the continuous breaking and reforming of the solid- electrolyte interphase layer quickly destroys the cell's cycling performance.
• pyrrolidinium PYRi n+
• EMIM + l-ethyl-3-methyl-imidazolium
• TFSF bis(trifluoromethanesulfonyl)imide
• FSF fluorosulfonyl
• Fig. 1 (A) shows capacities and coulombic efficiencies of nSi-cPAN electrode in PYR )3 FSI (1.2 LiFSI) and EC/DEC (l LiPF 6 ).
• Fig. 1(B) shows capacities and coulombic efficiencies of nSi-cPAN electrode in PYR 13 TFSI (0.6 LiTFSI) and EMIMFSI (12M LiFSI) electrolyte systems.
• Figs. 2(A), 2(B), 2(C), 2(D), 2(E), 2(F), 2(G), and 2(H) show illustrations of a decomposition mechanism on a Li 13 Si 4 surface.
• Figs. 3(A), 3(B), 3(C), 3(D), 3(E), 3(F), and 3(G) show microimages of solid- electrolyte interphase compositions in a Si-PYR 13 FSI system.
• Figs. 4(A) and 4(B) show mass changes on an nSi-cPAN electrode during the first charge-discharge cycle.
• Fig. 6(B) shows results of a nSi-cPAN/PYRi 3 FSI/L333 full-cell rate study and long term cycling.
• Fig. 6(C) shows a mock-up of a commercial 18650 cell showing the opportunity for incorporating more electro- active material due to the relatively thin nSi-cPAN electrode.
• Fig. 7(B) shows a voltage profile of PYR 13 FSI (1.2 LiFSI) with nSi-cPAN.
• Fig. 7(C) shows a voltage profile of PYR 13 TFSI (O.6 L1TFSI) with nSi-cPAN.
• Fig. 7(D) shows a voltage profile of EMIMFSI (1.2 LiFSI) with nSi-cPAN.
• Figs. 8(A), 8(B), 8(C), and 8(D) show single-electron reductions of FSF and TFSF anions.
• Figs. 9(A), 9(B), 9(C), 9(D), and 9(E) images of a cross-section of solid- electrolyte interphase composition of a cycled conventional Si-based electrode.
• Figs. 10(A) and 10(B) show mass change per electron for different electrodes during the first charge-discharge cycle
• Fig. 1 1 shows half-cell electrochemical performance of a conventional Si-based electrode with PYR 13 FSI versus EC/DEC electrolyte systems.
• Fig. 12 shows high temperature electrochemical performance of a full-cell.
• Fig. 13(A) shows capacity and coulombic efficiency of an electrode.
• Fig. 13(B) shows capacity and coulombic efficiency of a full-cell.
• Fig. 14 shows an illustration of a composition of matter including a film formed on an electrode with the film including fluorine, oxygen, sulfur, carbon, and lithium.
• Fig. 15 shows an illustration of a substrate including an active material including nanosilicon, a polymer to bind the active material and to conduct electricity and an electrolyte to contact the polymer and the active material.
• Fig. 20 shows a flow diagram of a method including charging and discharging a cell having an electrode including nanosilicon, and forming a substantially mechanically stable solid-electrolyte interphase at the electrode.
• Fig. 21 shows a block diagram of a system including a plurality of electrically coupled cells including a first electrode including nanosilicon, a second electrode, and a room temperature ionic liquid electrolyte to contact the first electrode and the second electrode.
• a combinatorial approach one involving a mechanically resilient electrode architecture merged with an electrolyte capable of forming a favorable SEI, is one option to integrate structural integrity with stable interfacial chemistry in a bulk type Si anode.
• a nano-Si-RTIL system that exhibits a highly stable and resilient SEI, providing a solution to the drawbacks of the Si-anode and enabling the long-term operation of a lithium-ion full-cell with a bulk type nano-Si-based anode.
• a “nano-silicon based electrode” is an electrode which contains silicon active material with a particle size/diameter in the nanometer scale (1-500 nm).
• the cycling performances of the nano-Si-based electrode in RTIL solutions including PYR 13 FSI (1.2 LiFSI), PYR 13 TFSI (O.6 L1TFSI), and EMIMFSI (1.2 LiFSI), were directly compared to the electrode's performance in the commercial EC/DEC (l LiPF 6 ) electrolyte.
• the results of the preliminary cycling study are presented in Fig. 1 (A) and Fig. 1 (B), demonstrating the strong and unexpected cycling stability of the nSi-cPAN anodes in FSF-based ILs and their unexpected CE in the PYR 13 FSI system. Cycling was carried out at room temperature in 2032 coin-type half-cells operated between 0.05- 1 V (vs.
• Fig. 2 shows a decomposition mechanism of FSI-- and TFSI—based ILs on a Li 13 Si 4 surface ball and stick models of the A, FSF anion B, decomposed FSF radical di- anion, C, TFSF anion, and D,decomposed TFSF di-anion.
• the first type of theoretical study consists of cluster-based, localized basis
• FEC fluoroethylene carbonate
• Fig. 3 displays high-resolution transmission electron microscopy (HRTEM) images of the cycled/delithiated nSi-cPAN cross-section (Fig. 3(A)) with EELS mapping of silicon (Fig. 3(B)), carbon (Fig. 3(C)), sulfur (Fig. 3(D)), fluorine (Fig. 3(E)), lithium (Fig. 3(F)), and oxygen (Fig. 3(G)) , defining the elemental constitution and favored nucleation sites of the SEI formed.
• HRTEM transmission electron microscopy
• Fig. 4 shows mass changes on the nSi-cPAN electrode during the first charge- discharge cycle.
• EQCM massograms obtained during the initial SEI formation cycle for the nSi-cPAN electrodes cycled in A, conventional organic electrolyte and B, PYR13FSI (1.2 LiFSI) electrolyte, along with the voltage traces corresponding to each system.
• Fig. 4 conveys EQCM massograms for the nSi-cPAN initial formation cycle in both organic electrolyte (Fig. 4(A)) and FSF-based IL (Fig. 4(B)). Both systems reveal two very distinct behaviors during lithiation, as alluded to in our modeling study. The gradual rise in mass of about 43 ⁇ g cm "2 during the initial 20% of lithiation in both systems corresponds to the uptake of lithium by cPAN, other non-faradaic processes, and initial alloying of Li with Si.
• the electrodes undergo rapid mass changes, attributed mainly to the decomposition of electrolyte and deposition of decomposition products on the electrode- electrolyte interface.
• the onset of these rapid mass changes are visible in the voltage trace of each system through the "potential overshoot" phenomenon, a known artifact of electrolyte decomposition in EQCM experiments.
• the onset of this rapid mass change occurs earlier (20.5% lithiation) and at a significantly higher rate (reaching 73 g mol '1 of e at 46.1% lithiation) in conventional organic electrolyte.
• Mass change per mol of electrons (m.p.e., g mol '1 of e ) was extracted from data in Fig. 10.
• the mass of the Si-conventional organic electrolyte system crashes.
• the crash in mass could be caused by a number of factors, including the severe volume expansion known to occur in this system causing breakage of the electrode matrix, and the build-up and rupturing of an unstable interfacial layer.
• contraction of the nSi-cPAN composite leads to further breakage of the electrode matrix and material loss.
• the inability of this system to exhibit stable mass changes corresponds to the incompatibility of Si with conventional electrolyte.
• the nano-Si-RTIL system massogram exhibits more gradual mass growth and loss, with approximately 73% of the mass gained during initial lithiation remaining after delithiation.
• We attribute this behavior to the irreversible formation of a stable interfacial layer on the nano-Si electrode, manifesting stable cycling and high CEs throughout an impressive cycling life.
• Fig. 5 shows microstructure of nSi-cPAN and morphological effects of PYR) 3 FSI IL on anode.
• A EELS elemental mapping of carbon and silicon and
• B TEM micrograph of the pristine nSi-cPAN electrode reveal a thin, conformal coating of PAN on the nano-Si particles throughout the uncycled composite.
• C C
• D FESEM images of electrode cross-sections before (C) and after (D) initial lithiation showing an electrode volume expansion of only 17%.
• E-H TEM micrographs of fully lithiated (E, F) and 16th delithiated (G, H) nSi-cP AN electrodes showing no mechanical deficiencies or significant morphological changes.
• EELS and TEM reveal a thin, conformal coating of PAN on the nano-Si particles throughout the uncycled composite (Figs. 5(A) and 5(B)).
• the mechanical advantages of the cPAN coating are verified by analyzing electrode cross-sections at different stages of cycle life, finding an overall electrode volumetric expansion of only 40% after full initial lithiation with an EC/DEC (l LiPF 6 ) electrolyte.
• EC/DEC l LiPF 6
• TEM micrographs were taken upon initial lithiation (Figs. 5(E) and 5(F)) and after the 16 th delithiation (Figs. 5(G) and 5(H)).
• the TEM images of both the fully lithiated and cycled electrodes show no mechanical deficiencies or morphological changes within the Si particles or the composite structure.
• the Si- PYR] 3 FSI system exhibits no severance of connection between the Si particles and cPAN network with striking preservation of the nano- Si's spherical shape, contrasting the relatively poor nano-structural preservation of the same electrode in conventional electrolyte.
• the impressive structural integrity of the nano-Si-PYR] 3 FSI system is undoubtedly linked to the system's cycling stability, suggesting that the nano-Si-RTIL interface concurrently promotes favorable electrochemistry and structural resilience.
• Fig. 6(B) depicts the nSi-cPAN/PYR ]3 FSI (1.2 LiFSI)/L333 cell run for 1000 cycles delivering 107.33, 74.70, and 58.26 mAh g "1 at rates of 1C, 4C, and 6C, respectively.
• FIB FEI, NOVA200 dual beam system
• a mobile air-lock chamber was used for TEM sample preparation.
• TEM and EELS analysis were performed with a FEI Tecnai F20 operated at 200 keV.
• nSi-cPAN films were coated on 1 in. diameter Pt 5MHz resonating quartz crystals (Stanford Research Systems; SRS). The electrochemically active area in the cell was determined to be 1.359 cm 2 , based on the Pt pattern on the crystal. In order to mitigate error associated with frequency measurements using thick films on quartz crystals, all nSi-cPAN films were prepared with thicknesses under 10 ⁇ . The crystals were placed in a SRS QCM200 crystal holder. The holder was modified with PEEK insulation so that a standalone cell, with a volume of 2.5 mL, could be enclosed with a lid. The ceiling of the cell was lined with a Li foil counter electrode and connected to a copper wire. All current and potential parameters were consistent with the electrochemical characterizations of the coin-cells.
• Full-cells were fabricated from pre-conditioned electrodes selected based on deliverable capacity. Calculated from the active material mass, nSi-cPAN anodes were fabricated and matched with L333 cathodes such that the total anode capacity was approximately 160% of that of the cathode capacity. Both electrodes were then preconditioned: the anodes were allowed to run for 10 charge-discharge cycles in a half-cell configuration and were stopped after full lithiation, while the cathodes were allowed to run for 3 charge-discharge cycles in a half-cell configuration and were stopped after full delithiation.
• Fig. 8 shows Single-Electron Reductions of FSF and TFSF anions.
• Fig. (A) shows Li (TFSF) 2 .
• Fig. (B) shows adding an excess electron to (A) spontaneously decomposes a resulting FSF radical di-anion.
• Fig. (C) shows Li + (TFSF) 2 .
• Fig. (D) shows adding an electron to (C) decomposes the resulting TFSF di-anion.
• Fig. 9 shows solid-electrolyte interphase composition of a cycled conventional Si- based electrode.
• Cross-section of an electrode composed of active material (Si, 50 nm Alfa Aesar), conductive additive (acetylene black, AB), and binder (polyvinylidene difluoride, PVDF) in60:20:20 ratio, respectively, and cycled from 0.05 - 1 V (vs. Li/Li + ) with active material Si, 50 nm Alfa Aesar
• conductive additive acetylene black, AB
• binder polyvinylidene difluoride, PVDF
• AIMD Ab initio molecular dyamics
• Electrochemical Quartz Crystal Microbalance (EQCM): Potential Overshoot and Mass per
• m.p.e. values can be used to infer reaction products being adsorbed on the electrode.
• the following analysis offers a tentative explanation of the mechanistic aspects of our EQCM experiments and the m.p.e. data.
• the m.p.e. values are calculated by dividing the mass increase by the passed charge and multiplying by Faraday's constant.
• the m.p.e. values plotted in Fig. 10 are averages taken periodically over the course of the SEI formation steps. In the case of an already oxidized Si surface, reduction by Li wouldgive a m.p.e. of 6.9 g mol '1 e ⁇ (that of pure Li deposition or
• Fig. 11 shows half-cell electrochemical performance of a conventional Si-based electrode with PYR 1 3FSI versus EC/DEC electrolyte systems.
• Fig. 12 shows high Temperature electrochemical performance of a nSi-cPAN/L333 full-cell with PYR 13 FSI RTIL. Specific charge capacities of a nSi-PAN/L333 full-cell assembled with PYR 13 FSI (1.2 LiFSI) and cycled at 60°C. The cell was cycled
• Figs. 13 (A) and (B) provides the results for SiNW-cPAN in a half-cell configuration and in a full-cell configuration (L333 cathode) in PYR 13 FSI (1.2 LiFSI) and EC/DEC (l LiPF ) electrolyte systems similar to the data shown in Fig 1(A) and Fig. 6(A) above.
• Fig. 13(A) shows specific capacities and coulombic efficiencies of SiNW-cPAN electrode in PYR 13 FSI (1.2 LiFSI) and EC/DEC (l LiPF 6 ).
• Fig. 13(B) shows specific charge capacities and coulombic efficiencies of nSi-PAN/L333 full-cells assembled with PYR 13 FSI (1.2 LiFSI) and conventional EC/DEC (l LiPF 6 ) electrolytes.
• the full-cell assembled with PYR 13 FSI (1.2M LiFSI) has a capacity retention with respect to the 2nd cycle of 100% at 200 cycles and of 97.5% at 300 cycles.
• Fig. 14. shows an illustration of a composition of matter 100 including a film 102 formed on an electrode 104, the film 102 includes fluorine 106, oxygen 108, sulfur 110, carbon 112, and lithium 114.
• the film 102 is formed on the electrode 104, for example, during the charging and discharging of a lithium-ion battery.
• the film 102 is a solid-electrolyte interphase film.
• SEI solid-electrolyte interphase
• the electrode 104 includes a conductive material in which current may flow.
• An exemplary electrode 104 is an anode including nanosilicon and an electrochemically inactive polyacrylonitrile to bind the silicon.
• Another exemplary binder is polyvinylidene fluoride (PVDF).
• Fig. 15 shows an illustration of a substrate 200 including an active material 202 including nanosilicon 204, a polymer 206 to bind the active material 202 and to conduct electricity and an electrolyte 208 to contact the polymer 206 and the active material 202.
• the electrolyte 208 includes a salt 210 and an anion of the salt 212.
• the substrate 200 forms a base on which other materials may be deposited or formed.
• the substrate 200 is an electrode including the active material 202.
• the active material 202 includes material capable of conducting electricity.
• the active material 202 is a material that is electrochemically active. In operation, the active material 202 interacts with ions, such as Li ions, to store charge.
• the active material includes nano silicon.
• the active material 202 is not limited to a particular form.
• the active material 202 includes silicon nanowires.
• nanowires have a diameter of between about 5 nanometers and about 20 nanometers.
• nanowires have a diameter of between about 20 nanometers and about 50 nanometers.
• nanowires have a diameter of between about 50 nanometers and about 100 nanometers.
• Silicon suitable for use in connection with the formation of the active material 202 is commercially available from Alfa Aesar.
• the silicon 204 for example silicon particles, are coated in polyacrylonitrile during the electrode fabrication process. Thus, a "PAN coating" covers all silicon particles that make up the electrode.
• Fig. 16 shows an illustration of a substrate 300 including an active material
• the polyacrylonitrile is a conductive agent.
• electrodes contain an electronically conductive material whose purpose is to allow fast transport of electrons between a current collector and active material. After heat treatment, PAN becomes electronically conductive, thus it may be used both as a binder and conductive agent.
• Other exemplary conductive agents include acetylene black (AB) and "Super-P" (another type of carbon black), and SFG-6 (graphite).
• Fig. 17 shows a block diagram for an apparatus 400 including a first electrode including nanosilicon 402, a second electrode 404, and a room temperature ionic liquid electrolyte 406 to contact the first electrode 402 and the second electrode 404.
• the room temperature ionic liquid electrolyte 406 is not limited to a particular material. Ionic liquid electrolytes are a class of electrolyte materials based on room temperature ionic liquids (RTILs). A room temperature ionic liquid electrolyte includes a RTIL and a salt.
• the ionic liquid electrolyte 406 is not an organic solvent based electrolyte.
• the room temperature ionic liquid electrolyte 406 includes species selected from the group consisting of pyrrolidinium, 1-ethy 1-3 -methyl- imidazolium, bis(trifluoromethanesulfonyl)imide and bis(fluorosulfonyl)imide. In some embodiments the room temperature ionic liquid electrolyte 406 includes lithium bis(fluorosulfonyl)imide. In some embodiments, the room temperature ionic liquid electrolyte 406 has a 58.4 wt.% of the RTIL based on molecular weight of the ions.
• the salt is then added to this RTIL in a concentration of 1.2 M (or 1.2 mol/ L, with LiFSI salt weighing in at 187.09 g/mol... so there are 224.508 g/L of salt in the electrolyte).
• the first electrode including silicon 402 can be formed from various materials.
• the first electrode including nanosilicon 402 includes a cyclized- polyacrylonitrile silicon nanocomposite.
• the first electrode includes a nSi-cPAN and the electrolytic material or more specifically the room temperature ionic liquid electrolyte 406 includes a PYR 13 FSI (1.2 LiFSI) electrolyte.
• the electrode 402 including nanosilicon 404 has a weight ratio of 30 wt.% PAN,70 wt.% Silicon.
• the first electrode including nanosilicon 402 is not limited to a particular structure or thickness.
• the first electrode including nanosilicon 402 comprises a bulk electrode.
• the thickness of a bulk electrode exceeds the thickness of a thin film electrode.
• the bulk electrode has a thickness 408 of between about 10 micrometers and about 50 micrometers.
• the apparatus 400 in some embodiments including the bulk electrode maintains a half-cell coulombic efficiency of greater than about 99.994 percent over about 5000 cycles.
• the first electrode including nanosilicon 406 includes a substantially mechanically stable solid electrolyte interphase film.
• a substantially mechanically stable solid electrolyte interphase film exhibits a substantially constant conductivity over several thousand charging and discharging cycles.
• Fig. 18 shows a flow diagram 500 illustrating a method including charging and discharging a battery including an electrolyte (block 502), and forming a solid electrolyte interphase film including fluorine, oxygen, sulfur, carbon, and lithium on an electrode (block 504).
• Fig. 1 9 shows a flow diagram of a method 600 including charging and discharging a battery having an electrode including polyacrylonitrile coated n an o silicon (block 602), forming a solid electrolyte interphase film including fluorine, oxygen, sulfur, carbon, and lithium on the electrode (block 604), and covering the polyacrylonitrile coated nanosilicon conformally with fluorine, oxygen, and sulfur (block 606).
• a conformal coating or covering such as a polyacrylonitrile coating or covering
• the polyacrylonitrile coats or covers all active material, such as nanosilicon or silicon particles, substantially equally and substantially uniformly to a thickness of about 5 nanometers.
• Fig. 20 shows a flow diagram of a method 700 including charging and discharging a cell having an electrode including n a n o silicon (block 702), and forming a substantially mechanically stable solid-electrolyte interphase at the electrode (block 704).
• charging and discharging a cell including an electrode including nanosilicon includes charging and discharging the cell over at least about 5000 cycles.
• the method 700 further includes maintaining a half-cell coulombic efficiency of greater than about 99.994 percent over the at least about 5000 cycles.
• Fig. 21 shows a block diagram of a system 800 including a plurality of electrically coupled cells 802 including a first electrode 804 including nanosilicon 806, a second electrode 808, and a room temperature ionic liquid electrolyte 810 to contact the first electrode 804 and the second electrode 808, a film 812 formed on the first electrode 804, the film 812 including fluorine, oxygen, sulfur, carbon and lithium, and an electronic device 814 electrically coupled to the plurality of electrically coupled cells 802.
• the system 800 is not limited to use in connection with a particular electronic device 814.
• Exemplary electronic devices 814 suitable for use in connection with the system 800 include a processor 816, a motor 818, a turbine 820, a solar cell 822, and a transportation device 824.
• the transportation device 824 includes a truck 826.

Landscapes

• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Electrochemistry (AREA)
• General Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Manufacturing & Machinery (AREA)
• Condensed Matter Physics & Semiconductors (AREA)
• Physics & Mathematics (AREA)
• General Physics & Mathematics (AREA)
• Inorganic Chemistry (AREA)
• Composite Materials (AREA)
• Secondary Cells (AREA)
• Battery Electrode And Active Subsutance (AREA)
• Primary Cells (AREA)
• Electric Double-Layer Capacitors Or The Like (AREA)

Priority Applications (7)

Applications Claiming Priority (2)

Publications (1)

Family

ID=54540238

Family Applications (1)

Country Status (6)

Cited By (4)

Families Citing this family (50)

Citations (3)

Family Cites Families (20)

• 2015
  • 2015-10-30 US US15/522,256 patent/US10707481B2/en active Active
  • 2015-10-30 KR KR1020177014350A patent/KR102619076B1/ko active Active
  • 2015-10-30 CN CN202210859946.8A patent/CN115275320A/zh active Pending
  • 2015-10-30 KR KR1020237044416A patent/KR102838442B1/ko active Active
  • 2015-10-30 JP JP2017523915A patent/JP2017539051A/ja active Pending
  • 2015-10-30 WO PCT/US2015/058453 patent/WO2016070120A1/en not_active Ceased
  • 2015-10-30 EP EP15794013.1A patent/EP3213363B1/en active Active
  • 2015-10-30 CN CN201580071948.9A patent/CN107112507A/zh active Pending
• 2020
  • 2020-11-05 JP JP2020184856A patent/JP2021022580A/ja active Pending
• 2022
  • 2022-11-22 JP JP2022186597A patent/JP7611210B2/ja active Active
• 2024
  • 2024-12-23 JP JP2024226072A patent/JP2025038208A/ja active Pending

Patent Citations (3)

Non-Patent Citations (3)

Also Published As

Similar Documents

Legal Events