WO2016043202A1 - 抗菌・抗かび加工製品の製法およびそれによって得られる抗菌・抗かび加工製品 - Google Patents
抗菌・抗かび加工製品の製法およびそれによって得られる抗菌・抗かび加工製品 Download PDFInfo
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- WO2016043202A1 WO2016043202A1 PCT/JP2015/076215 JP2015076215W WO2016043202A1 WO 2016043202 A1 WO2016043202 A1 WO 2016043202A1 JP 2015076215 W JP2015076215 W JP 2015076215W WO 2016043202 A1 WO2016043202 A1 WO 2016043202A1
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- antibacterial
- antifungal
- resin
- compound
- resin molded
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
- C08J7/065—Low-molecular-weight organic substances, e.g. absorption of additives in the surface of the article
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2400/00—Specific information on the treatment or the process itself not provided in D06M23/00-D06M23/18
- D06M2400/01—Creating covalent bondings between the treating agent and the fibre
Definitions
- the present invention relates to a method for producing an antibacterial / antifungal processed product having water resistance and washing durability, and an antibacterial / antifungal processed product obtained thereby.
- MRSA methicillin-resistant Staphylococcus aureus: Staphylococcus aureus resistant to methicillin antibiotics
- MRSA methicillin-resistant Staphylococcus aureus: Staphylococcus aureus resistant to methicillin antibiotics
- multidrug-resistant bacteria resistant to various antibiotics such as methicillin, macrolide, quinolone, and ⁇ -lactam have emerged, trembling medical personnel.
- mycosis caused by specific fungi intestinal cancer patients, AIDS virus infected people, internal organs and brain infections of immunocompromised people by administration of anticancer drugs and steroids, etc. is also seen as a problem by medical personnel Yes.
- antibacterial and antifungal compounds are added to various textile products such as bedding and clothing, household goods and various industrial materials. Researches have been made on methods for sustaining effects such as water resistance and washing resistance, and some of them have already been put into practical use.
- Patent Document 1 For example, a carpet laying structure in which a soluble glass containing silver ions is kneaded into a polyolefin resin to form a nonwoven fabric and this is overlapped with a carpet so as to exhibit an antibacterial, antifungal, deodorant and insect repellent function (see Patent Document 1). Have been proposed). However, this effect is not sufficient because it does not directly impart antibacterial and antifungal properties to the fibers constituting the carpet.
- an antibacterial / antifungal agent exhibiting excellent antibacterial / antifungal properties against a wide variety of fungi and fungi is applied to resin molded products including textiles with water resistance,
- the present invention has been made in view of such circumstances, and its antibacterial and antifungal performance has water resistance and washing durability.
- the purpose is to provide the resulting antibacterial and antifungal processed products.
- the present invention provides a method for obtaining an antibacterial / antifungal processed product to which antibacterial / antifungal properties are imparted, wherein the following antibacterial / antifungal compound (A) is added to a resin molded product.
- the antibacterial / antifungal compound (A) is fixed to at least the surface of the resin molded article by performing a heat treatment under normal pressure or under pressure in a state where the treatment liquid containing is contacted.
- the manufacturing method of the mold processed product is the first gist.
- An antibacterial / antifungal compound comprising a quaternary ammonium salt compound having a molecular weight of 1500 or less.
- the present invention also provides an antibacterial / antifungal material in which the resin molded article contains at least one resin selected from polyester resins, polyamide resins, acrylic resins and polyurethane resins.
- the manufacturing method of processed products is the second gist.
- the present invention in particular, after the treatment liquid is attached to the resin molded product by spraying, dipping, or coating, in a gas at 70 to 230 ° C. under normal pressure or pressure.
- Antibacterial and antifungal processed products with heat treatment are the third main point.
- the antibacterial and antifungal products are immersed in a treatment liquid and heated in a bath at 70 to 230 ° C under normal pressure or pressure.
- the manufacturing method of the anti-mold processed product is the fourth gist.
- the present invention also provides an antibacterial / antifungal processed product obtained by the production method according to any one of the first to fourth aspects, wherein the following antibacterial / antifungal compound (A) is fixed to at least the surface.
- the bactericidal activity value against at least three types of S. aureus, methicillin-resistant Staphylococcus aureus, Klebsiella pneumoniae, Bacillus subtilis, Bacillus cereus, Escherichia coli, Salmonella and Pseudomonas aeruginosa is 0 or more.
- a fifth aspect of the present invention is an antibacterial and antifungal processed product in which a resin molded product having an antifungal activity value of 2 or more among at least two types of fungi, black mold, ringworm, and Candida is used.
- An antibacterial / antifungal compound comprising a quaternary ammonium salt compound having a molecular weight of 1500 or less.
- the present invention also provides an antibacterial / antifungal material in which the resin molded article contains at least one resin selected from polyester resins, polyamide resins, acrylic resins and polyurethane resins.
- the processed product is the sixth gist.
- the present invention has a seventh gist of antibacterial and antifungal processed products in which the resin molded product is a fiber product among them, and the resin molded product is a resin sheet, a resin film, a predetermined shape.
- An eighth antibacterial and antifungal processed product that is any of the cured resin bodies having
- resin molded product refers to the product material in the stage before obtaining the final product, and this product material may be used as it is as the final product without any changes in shape. This is intended to be included in the “resin molded product”.
- fixing the antibacterial / antifungal compound (A) refers to bonding the resin molded product and the antibacterial / antifungal compound (A) by chemical bonding.
- the chemical bond includes various bonds such as an ionic bond, a hydrogen bond, and a coordination bond.
- the present inventors develop a method for imparting antibacterial and antifungal properties having water resistance and washing durability to resin molded products used for various industrial materials and household goods (including clothing). We studied as hard as possible.
- quaternary ammonium salt compounds conventionally known as antibacterial agents in particular, a quaternary ammonium salt compound (A) having a molecular weight of a predetermined size or less in a solvent such as water. If the treatment liquid is prepared by being dissolved or dispersed in the resin, and the treatment liquid is brought into contact with the resin molded product and subjected to heat treatment, the film-forming compound is not used to form the resin film.
- the compound (A) was directly bonded to the functional group of the resin and immobilized. And since the said compound (A) fix
- the present inventors have found that antibacterial and antifungal properties excellent in water resistance and washing durability can be imparted, and reached the present invention.
- antibacterial agents and antifungal agents there are many compounds known as antibacterial agents and antifungal agents, and among them, those that exhibit antibacterial performance only for specific fungi (for example, Gram-positive bacteria) and specific fungi (for example, It is known that the compound (A) of the present invention exerts strong antifungal performance against ringworms, but the compound (A) of the present invention has excellent antibacterial properties against both gram positive bacteria (including MRSA) and gram negative bacteria. It is a finding that the present inventors have obtained for the first time that it exhibits excellent antifungal properties against molds of many genera.
- the quaternary ammonium salt compound is a water-soluble compound, and as such, it has been difficult to fix to a hydrophobic resin surface as it is in a form having water resistance and washing resistance. is there.
- a water-soluble compound on the surface of a resin such as a synthetic fiber, it is common knowledge to confine and fix in a resin film using a film-forming compound as described above.
- a method of introducing a sulfone group into a hydrophobic polyester fiber and modifying it to dye a water-soluble cationic dye is known, but without such modification, There is no known method for directly immobilizing a water-soluble compound on a hydrophobic resin.
- the present inventors heated the resin component to be above the glass transition temperature of the resin molded product to which the quaternary ammonium salt-based compound is to be added, and formed pores in the amorphous region of the resin component.
- the idea is that if the quaternary ammonium salt compound having heat resistance can be infiltrated, unreacted functional groups remaining in the resin can be chemically bonded to this compound. .
- a relatively small one having a molecular weight of 1500 or less is incorporated into the amorphous region of the resin, and the functional group in the resin It was found that they were bound and fixed by hydrogen bonds or the like.
- a special antibacterial / antifungal compound (A) that exhibits antibacterial and antifungal performance against a wide range of bacteria and fungi can be used regardless of the resin coating or the like. Since it can be directly chemically bonded and fixed to a molded product, an antibacterial and antifungal processed product excellent in water resistance and washing durability can be provided. And in the production, there is no need to use a special device or the like, and the equipment (fiber product) that heat-treats the resin molded product in contact with the treatment liquid containing the antibacterial / antifungal compound (A). If there is a dyeing treatment facility for the above, etc., it can be used as it is, so that the manufacturing cost can be kept low. Further, since a film forming compound (so-called binder resin) for fixing the antibacterial / antifungal compound (A) is not required, there is an advantage that no extra material cost is required.
- the antibacterial and antifungal processed products of the present invention exhibit excellent antibacterial and antifungal properties against a wide variety of fungi and fungi, and the antibacterial and antifungal properties have water resistance and washing durability. It has the effect of lasting for a long time. Further, since it is possible to repeatedly wash, wipe and wash without losing antibacterial and antifungal properties, the antibacterial and antifungal processed product can be kept clean for a long time.
- the resin molded article contains at least one resin selected from a polyester resin, a polyamide resin, an acrylic resin, and a polyurethane resin, these Since a relatively large amount of unreacted functional groups remain in the resin, the antibacterial / antifungal compound (A) can be fixed in a stronger and more stable form, which is preferable.
- a treatment liquid is attached to a resin molded product by spraying, dipping, or coating, it is heated in a gas at 70 to 230 ° C. under normal pressure or pressure.
- a heat treatment in a bath at 70 to 230 ° C. at normal pressure or under pressure, particularly excellent water resistance and Since washing resistance is obtained, it is suitable.
- the processed product for which the present invention provides antibacterial and antifungal properties uses a resin molded product, and as described above, the resin molded product prepared before the processing remains as it is. It may be in the shape of the final product, or it may be a final product by modifying the resin molded product or changing the shape or configuration by combining other members .
- Examples of such processed products include various industrial materials and household products.
- the types of resins used in the resin molded products are polyester resins, polyamide resins, acrylic resins, polyurethane resins, polylactic acid.
- Synthetic resins such as resin, synthetic fibers, composites and mixtures thereof.
- synthetic resins mixed with components other than synthetic resins metal, inorganic substances, etc.
- fibers blends of synthetic fibers and natural fibers such as cotton, rayon, wool, silk, etc. Etc.
- polyester resins such as polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid resin, and the like, which are particularly in demand as antibacterial and antifungal processed products, and whose washing durability is a problem, and Mixtures of these with other resins (in the case of fibers, blended products) can be mentioned, and it is preferable to target these.
- examples of the form include yarn, string, rope, fabric (woven fabric, knitted fabric, non-woven fabric) and the like.
- household goods include bedding bedding (curtains, sheets, towels, futon mats, futon cotton, mats, carpets, pillow covers, etc.) and clothing (coats, suits, sweaters, blouses, shirts, underwear, hats) , Masks, socks, gloves, etc.), uniforms (white coats, work clothes, school uniforms, etc.).
- textiles not only textiles but also household goods and industrial materials made of various resin materials such as resin sheets and resin films can be mentioned.
- Examples of these include nursing care seats, shower curtains, car seats, seat covers, ceiling materials and other interior materials, tents, insect and bird nets, partition sheets, air conditioning filters, vacuum cleaner filters, masks, tablecloths, Desk laying, apron, wallpaper, wrapping paper, etc.
- medical supplies medical beds, wheelchairs, sterilized bags, etc.
- hygiene supplies toilet bowls, cleaning brushes, dust boxes, disposable gloves, disposable masks, etc.
- cooking utensils tables, trays, etc.
- antibacterial / antifungal treatment can be similarly applied and can be the subject of the present invention.
- the antibacterial / antifungal compound (A) used in the present invention is a quaternary ammonium salt compound having a molecular weight of 1500 or less.
- Such quaternary ammonium salt compounds include tetramethylammonium iodide, trimethyldecylammonium bromide, didecyldimethylammonium bromide (hereinafter abbreviated as “DDAB”), dodecyldimethyl-2-phenoxyethylammonium bromide, lauryltrimethyl.
- DDAC didecyldimethylammonium chloride
- trimethylammonium chloride trimethyldodecylammonium chloride, trimethyltetradecylammonium chloride, cetylpyridinium chloride, trimethylhexadecylammonium chloride, trimethyloctadecylammonium Chloride
- didecyl monomethyl Droxyethylammonium bromide alkyldimethylhydroxyethylammonium chloride, alkyltrimethylammonium bromide, dioctyldimethylammonium chloride, dioctyldimethylammonium bromide, octyldecyldimethylammonium chloride, octyldecyldimethylammonium bromide, methylbenzethonium chloride, alky
- DDAB Downlink Detection-Detection-Detection-Detection-Detection-Ard Generation
- DDAC digital to analog converter
- BAC BAC
- the antibacterial and antifungal compound (A) which consists of the said quaternary ammonium salt type compound is prepared as a process liquid containing this.
- the treatment liquid is generally an aqueous solution in which the antibacterial / antifungal compound (A) is dissolved in water, but in some cases, a solution using an organic solvent as a solvent, a dispersion, or the like is used.
- various adjuvants and additives can be mix
- ⁇ Auxiliaries and additives that can be used in the treatment liquid> when processing a blend of polyester fiber and natural fiber such as cotton, rayon, wool, silk, etc., or processing a blend of polyester fiber and polyamide, acrylic or urethane fiber Depending on the processing temperature and time, fibers other than the polyester fiber may cause abnormalities such as discoloration, curing, and shrinkage due to the action of the cation of the antibacterial / antifungal compound (A), or antibacterial / antifungal properties. Loss may occur. Therefore, in order to prevent such a situation, it is preferable to use a textile processing agent such as a fixing agent (fixing agent, Fixer), a slow dyeing agent, and a fluorescent brightening agent as an auxiliary agent. Similarly, when processing a resin molded product made of a resin material obtained by blending a polyester-based resin and a polyamide-based, acrylic-based, or urethane-based resin, it is preferable to use such a fiber processing agent.
- a fixing agent
- the fiber processing agent include alkali salt compounds typified by anhydrous sodium carbonate; neutral salt compounds typified by sodium sulfate (sodium sulfate); alkyl ether type, polycyclic phenyl ether type, sorbitan derivative , Nonionic surfactants typified by aliphatic polyether types, etc .; cationic surfactants typified by quaternary ammonium salts [quaternary ammonium salts used as antibacterial and antifungal compounds (A) Anionic surfactant represented by sodium dialkyl succinate sulfonate, naphthalene sulfonic acid formalin condensate, etc .; bis (triazinylamino) stilbene disulfonic acid derivative, bisstyryl biphenyl derivative, coumarin derivative, pyrazoline derivative, etc. And the like. These may be used alone or in combination of two or more.
- swelling agents such as a wrinkle agent and a texture processing agent can be blended.
- water-soluble organic substances such as ethanol, n-propanol, and ethylene glycol can be used with or in place of water.
- a solvent can be used.
- a non-aqueous solvent can also be used.
- a treatment liquid containing the antibacterial / antifungal compound (A) is brought into contact with a resin molded product of a target product, and a predetermined heat treatment is performed in that state.
- a preferred method can be appropriately selected according to the type and material of the target resin molded product. .
- a method in which a resin molded product is immersed in the treatment liquid and heat-treated at a predetermined temperature and a predetermined pressure in that state can be given.
- a method after the treatment liquid is attached to a resin molded product by dipping (impregnation), spraying, coating, or the like under normal pressure, and then squeezed at a predetermined squeezing rate by mangle or centrifugation.
- a method in which the resin molded product is heat-treated at normal pressure or under pressure.
- the content of the antibacterial and antifungal compound (A) contained in the treatment liquid is 0.005 to 20.0% owf (on weight of fiber) when the resin molded product is, for example, a fiber product.
- the weight is preferably set to be w / w), more preferably 0.01 to 10.0% owf.
- the bath ratio (the amount of solution relative to the target material, the weight ratio) is preferably 1: 5 to 1:30, and more preferably 1: 5 to 1:20.
- the resin molded product is immersed in the treatment liquid at normal pressure or under pressure, but the processing conditions such as the temperature, time, and pressure of the heat treatment in the immersed state depend on the material and form of the resin molded product. It is set accordingly. Usually, it is set within the range of 70 to 230 ° C. and 0.1 to 60 minutes, and the higher the temperature and pressure, the shorter the processing time. Therefore, when processing a resin material that is not preferred for high temperature and long time heating, it is preferable to relax the heating conditions by applying pressure. Moreover, when performing a process continuously, it is preferable to process by a normal pressure on an installation, and when processing by a batch type, it is preferable to aim at shortening of process time by a pressurization process. In addition, there is no restriction
- the antibacterial / antifungal compound (A) when the content ratio of the antibacterial / antifungal compound (A) is too low, the antibacterial / antifungal property of the obtained antibacterial / antifungal processed product may be poor. Conversely, when the content ratio is too high, There is a risk of causing abnormal physical properties (curing, shrinkage, discoloration, etc.) of the resin molded product, which is not preferable. In addition, the antibacterial / antifungal compound (A) may be insufficiently fixed to the resin molded product under insufficient processing temperature, processing time and high bath ratio condition, which may result in poor antibacterial / antifungal properties. .
- the antibacterial / antifungal compound (A) for the treatment liquid to be used is used.
- the ratio is 0.005 to 20.0% ows (on weight of solution, antibacterial / antifungal compound (A) concentration in the treatment liquid, w / w) when the resin molded product is, for example, a fiber product. Is preferable, and 0.01 to 10.0% ows is more preferable.
- the squeezing rate varies depending on the type of resin molded product, but it is usually preferably 30 to 200%.
- the heat treatment after the treatment liquid is attached to the resin molded product is performed under normal pressure or under pressure, for example, at a treatment temperature of 70 to 230 ° C. More specifically, for example, after drying at 100 to 130 ° C. for 1 to 3 minutes (preliminary drying may not be performed when the basis weight is small), curing is performed at 140 to 230 ° C.
- the curing treatment time is preferably about 30 seconds to 1 hour depending on the basis weight and physical properties of the resin molded product. Also in this method, when the content ratio of the antibacterial / antifungal compound (A) is low, the antibacterial / antifungal property of the obtained antibacterial / antifungal processed product may be poor.
- the antibacterial and antifungal properties may be poor, or the water resistance and washing durability may be insufficient.
- the content of the antibacterial / antifungal compound (A), the processing temperature, and the processing time have passed, abnormal physical properties of the resin molded product (curing, shrinkage, discoloration, etc.) There is a possibility of causing heat transpiration and decomposition, which is not preferable.
- the antibacterial and antifungal processed product of the present invention obtained by the above production method exhibits excellent antibacterial and antifungal properties against a wide range of bacteria and a wide range of fungi. And because this excellent antibacterial and antifungal property has water resistance and washing durability and lasts for a long time, this processed product can be used cleanly for a long time by repeatedly washing, wiping and washing. be able to.
- Gram-positive bacteria Staphylococcus aureus, MRSA (Methicillin-resistant Staphylococcus aureus), Bacillus subtilis, Bacillus cereus and the like.
- Gram-negative bacteria Esherichia coli, Klebsiella pneumoniae, Salmonella typhimurium, Pseudomonas aeruginosa, etc.
- yeast Aspergillus niger, Penicillium citrinum, Black mold (Cladosporium cladosporioides), Trichopyton mentagrophytes, Candida albicans, etc.
- the evaluation of antibacterial / antifungal properties in the present invention is at least three types of bacteria among Staphylococcus aureus, methicillin-resistant Staphylococcus aureus (MRSA), Klebsiella pneumoniae, Bacillus subtilis, Bacillus cereus, Escherichia coli, Salmonella and Pseudomonas aeruginosa. It is effective when the bactericidal activity value is 0 or more for all, and the antifungal activity value for at least two types of fungi is 2 or more among black mold, mold, black mold, ringworm, and Candida.
- MRSA methicillin-resistant Staphylococcus aureus
- bactericidal activity value is the standard (JIS L 1902) established by the Japan Textile Evaluation Technology Council (JTETC). It is for evaluating the antibacterial performance of whether or not it is possible.
- JIS L 1902 Japan Textile Evaluation Technology Council
- JTETC Japan Textile Evaluation Technology Council
- the “bactericidal activity value” can be determined by the following formula (1). When the “bactericidal activity value” after predetermined washing for S. aureus and K. pneumoniae is 0 (zero) or more, JTETC It means that it has antibacterial performance that is certified as “effective bactericidal processing”.
- Bactericidal activity value ⁇ log (3 average viable count immediately after inoculation of standard cloth) ⁇ log (3 average viable count after 18 hours of culturing of processed cloth) ⁇ (1)
- the “bactericidal activity value” after predetermined washing for MRSA is greater than 0, it means that the antibacterial performance certified by JTETC as “specific antibacterial processing is effective” is provided. To do.
- antifungal activity value is also a standard (ISO 13629-1) stipulated by JTETC, and to what extent a fiber product originally provided with antifungal processing can suppress mold growth. This is for evaluating the anti-fungal performance.
- the “antifungal activity value” is the same as the “bactericidal activity value”.
- the “cloth” in the “standard cloth” and the “processed cloth” It can be evaluated by replacing with a “sample made of a resin molded product”.
- the “antifungal activity value” can be obtained by the following formula (2).
- JTETC determines “ It means that it has anti-mold performance (performance against products other than products that are less prone to washing and prone to mold).
- Antifungal activity value ⁇ log (3 average mold ATP amount after 42 hours of incubation of standard cloth) ⁇ log (3 average mold ATP amount immediately after test mold inoculation of standard cloth) ⁇ ⁇ ⁇ log (42 of processed cloth) 3 average live mold ATP amount after time culture) -log (3 average live mold ATP amount immediately after test mold inoculation of processed cloth) ⁇ (2)
- the antifungal performance approved by JTETC as “antifungal processing is effective” (Performance for products with low frequency of washing and prone to mold).
- the antibacterial and antifungal processed products of the present invention are not limited to evaluation by JTETC, but are evaluated by JIS Z 2801 (antibacterial test for antibacterial plastic products etc.) comparable to JTETC evaluation, and JIS Z It is possible to impart antibacterial performance and antifungal performance that can sufficiently withstand evaluation by 2911 (antifungal test on anti-molded plastic products and the like).
- the quantitative analysis of the remaining amount was performed based on the above-mentioned [Test Method for Evaluation of Washing Resistance]. That is, first, after carrying out predetermined household or industrial washing on the target antibacterial and antifungal processed products, 5 g of that is put in a pressure resistant stainless steel container immersed in 100 g of ion-exchanged water. And extraction at 130 ° C. for 30 minutes. Each extract was subjected to a quantitative analysis of a control substance other than the antibacterial / antifungal compound (A) or (A).
- the evaluation criteria are as follows. ⁇ : The residual amount of the compound is 100 ppm or more. ⁇ : The residual amount of the compound is less than 100 ppm and 10 ppm or more. X: The residual amount of a compound is less than 10 ppm.
- DDAB Didecyldimethylammonium bromide
- PDIEC1 Polyoxyethylene (dimethylimino) ethylene (dimethylimino) ethylene dichloride (molecular weight 900)
- PDIEC2 Same as above (molecular weight 2000)
- DDAA Didecyldimethylammonium adipate
- DDAP N, N-didecyl-N-methyl-poly (oxyethyl) ammonium propionate (molecular weight: 2000)
- PHMB Polyhexamethylene biguanidine chloride (molecular weight: 2000)
- Examples 1 to 6 Polyester standard cloth (Teijin Tropical, the same shall apply hereinafter) is immersed in 0.32% and 0.16% by weight aqueous solutions of DDAC, BAC, and DDAA, respectively, drawn to 100% with mangle, and each is dried at 130 ° C for 1 minute. 170 ° C., 2 minutes / 180 ° C., 1 minute / 200 ° C., and 30 seconds of curing.
- the pressure at the time of processing is a normal pressure at any stage (a state where neither pressurization nor pressure reduction is performed) (in the following examples, it is a normal pressure unless otherwise specified).
- the residual amount of each compound was quantitatively analyzed after 10 home washings of 40 degreeC, and it evaluated in accordance with the above-mentioned reference
- the antibacterial / antifungal compound (A) remains on the fiber by performing heat treatment under predetermined conditions. It was confirmed that it was fixed.
- Example 7 to 11 A polyester standard cloth was dipped in 0.32% by weight aqueous solutions of DDAC, BAC, DDAB, PDIEC1 (molecular weight: 900) and DDAA, respectively, and then squeezed to 100% with mangle, and each was cured at 180 ° C. for 1 minute. . And about each sample, the residual amount of each compound was quantitatively analyzed 10 times after industrial washing of 80 degreeC, and it evaluated in accordance with the above-mentioned reference
- a polyester standard fabric was prepared by adding 0.36% by weight aqueous solution of PDIEC2 (molecular weight: 2000), 0.32% by weight aqueous solution of DDAP (counter ion is an organic carboxylic acid), and 0.40% by weight of PHMB (not ammonium salt). After dipping each in an aqueous solution, as in Examples 7 to 11, the squeezing rate was 100% with mangle and each was cured at 180 ° C. for 1 minute. And about each sample, the residual amount of each compound was quantitatively analyzed 10 times after industrial washing of 80 degreeC, and it evaluated in accordance with the above-mentioned reference
- the antibacterial / antifungal compound (A) is brought into contact with the polyester standard fabric, and then subjected to heat treatment under predetermined conditions, so that the antibacterial / antifungal compound is applied to the fiber even after 10 industrial washings. It was confirmed that it remained and fixed. Moreover, it was confirmed that the thing which contacted the compound different from an antibacterial and antifungal compound (A) becomes insufficient in a fiber even if it heat-processes on predetermined conditions.
- Example 12 and 13 A polyester / cotton blend (80% by weight polyester, 20% by weight cotton) was dyed with 0.5% ows diaminostilbene sulfonic acid fluorescent whitening agent and dried. The obtained dough was used as a sample, immersed in 0.32 and 0.60% by weight aqueous solutions of DDAC, drawn to 100% with mangle, dried at 130 ° C. for 1 minute, and cured at 170 ° C. for 2 minutes. About these samples, after carrying out 10 home washing
- Example 14 and 15 A sample fabric of polyamide fiber (nylon 6) (product name: nylon 6 jersey, manufactured by Color Dyeing Co., Ltd.) was immersed in a 0.32% by weight aqueous solution of DDAC and DDAA, respectively, and then cured at 85 ° C. for 45 minutes. . This sample was subjected to 10 home washings at 40 ° C., and then the remaining amount of the compound was quantitatively analyzed and evaluated according to the above-mentioned criteria. The results are shown in Table 4 below.
- the antibacterial / antifungal compound (A) is brought into contact with the polyamide fiber sample fabric and then cured under predetermined conditions, so that the antibacterial / antifungal compound can be obtained even after 10 home washings. It was confirmed that it remained on the fiber and was fixed.
- Example 16 to 21 A polyester standard fabric was immersed in 0.40, 0.20 and 0.10 wt% aqueous solutions of DDAC and 0.10 wt% aqueous solutions of DDAA, BAC and PDIEC1, respectively, and then cured at 180 ° C for 1 minute. About these samples, the bactericidal activity value was calculated
- the antibacterial / antifungal compound (A) is brought into contact with the polyester standard fabric and then subjected to heat treatment under predetermined conditions. It was confirmed that it remained and exhibited a sufficient bactericidal activity value. Moreover, it was confirmed that the thing which contacted the compound different from an antibacterial and antifungal compound (A) is inadequate in bactericidal activity value even if it heat-processes on predetermined conditions.
- Example 22 to 25 After immersing the polyester standard fabric in a 0.20% by weight aqueous solution of DDAC, a 0.20% by weight aqueous solution of DDAA, a 0.40% by weight aqueous solution of BAC, and a 1.0% by weight aqueous solution of PDIEC1, 1 Curing for a minute. About these samples, after carrying out 10 home washing
- the antibacterial / antifungal compound (A) is brought into contact with the polyester standard fabric and then heat-treated under predetermined conditions, so that the antibacterial / antifungal compound remains in the fiber even after 10 home washings. It was confirmed that the anti-fungal activity was sufficient. In addition, when a compound different from the antibacterial / antifungal compound (A) is contacted, the compound remains insufficient on the fiber even when heat-treated under predetermined conditions, and exhibits antifungal activity. Not confirmed.
- the antibacterial / antifungal compound (A) of the present invention was immersed in a fabric made of various synthetic fibers or a blend of synthetic fibers and natural fibers, followed by heat treatment.
- the antibacterial / antifungal compound (A) is fixed to the fabric, and the antibacterial / antifungal compound (A) remains after 10 home washings or 100 industrial washings, It can be seen that it exhibits sufficient antibacterial and antifungal properties.
- a compound different from the quaternary ammonium salt compound (DDAP, PHMB, or quaternary ammonium salt compound used in the antibacterial / antifungal compound (A) of the present invention has a molecular weight of 1500. It can be seen that all of the comparative products using PDIC (exceeding PIEC) have insufficient antibacterial and antifungal properties because the compound is not fixed to the fabric.
- the present invention can be used to provide antibacterial and antifungal processed products having a wide range of antibacterial and antifungal properties, and having excellent water resistance and washing resistance.
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Abstract
Description
(A)分子量1500以下の第四級アンモニウム塩系化合物からなる抗菌・抗かび性化合物。
(A)分子量1500以下の第四級アンモニウム塩系化合物からなる抗菌・抗かび性化合物。
まず、本発明が抗菌・抗かび性を付与することを対象とする加工製品は、樹脂成形品を用いたものであって、前述のとおり、その加工前に準備される樹脂成形品が、そのまま最終製品の形になっているものであってもよいし、樹脂成形品に変形を加えたり、他の部材を組み合わせて形状や構成を変えたりして、最終製品にするものであってもよい。
つぎに、本発明に用いられる抗菌・抗かび性化合物(A)は、分子量が1500以下の第四級アンモニウム塩系化合物である。
また、本発明の製法において、上記第四級アンモニウム塩系化合物からなる抗菌・抗かび性化合物(A)は、これを含有する処理液体として調製される。処理液体は、一般に、抗菌・抗かび性化合物(A)を、水で溶解した水溶液が用いられるが、場合によっては、有機溶剤を溶媒とした溶液や、分散液等が用いられる。そして、上記処理液体には、対象とする樹脂成形品の種類や処理条件等に応じて、各種の助剤、添加剤を配合することができる。
例えば、ポリエステル系繊維と綿、レーヨン、羊毛、絹等の天然繊維との混紡品を加工処理する際、またポリエステル系繊維とポリアミド系、アクリル系、ウレタン系の繊維との混紡品を加工処理する際、加工温度、時間によっては、ポリエステル系繊維以外の繊維が、抗菌・抗かび性化合物(A)のカチオンの作用によって変色、硬化、縮化等の異常を生じたり、抗菌・抗かび性の喪失が起きたりすることがある。そこで、このような事態を防止するために、助剤として、フィックス剤(固着剤、Fixer)、緩染剤、蛍光増白剤等の繊維加工用薬剤を用いることが好ましい。同様に、ポリエステル系樹脂とポリアミド系、アクリル系、ウレタン系の樹脂とをブレンドした樹脂材料からなる樹脂成形品に加工処理を施す場合も、このような繊維加工用薬剤を用いることが好ましい。
つぎに、本発明の、抗菌・抗かび加工製品の製法について説明する。本発明の製法は、上記抗菌・抗かび性化合物(A)を含有する処理液体を、目的とする製品の樹脂成形品に接触させ、その状態で所定の加熱処理を行うというものである。樹脂成形品と処理液体とを接触させる方法、および両者を接触させた状態で加熱処理する方法については、対象とする樹脂成形品の種類や材質に応じて、好ましい方法を適宜選択することができる。
上記製法によって得られる、本発明の抗菌・抗かび加工製品は、先にも述べたとおり、広範囲の細菌、広範囲のかびに対して、優れた抗菌・抗かび性を発揮する。そして、この優れた抗菌・抗かび性は、耐水性、洗濯耐久性を備え、長く持続するため、この加工製品に対し、繰り返し水洗いや水拭き、洗濯を施すことにより、長期にわたって清浄に使用することができる。
[細菌]
グラム陽性菌:黄色ブドウ球菌(Staphylococcus aureus)、MRSA(Methicillin-resistant Staphylococcus aureus)、枯草菌(Bacillus subtilis)、セレウス菌(Bacillus cereus)等。
グラム陰性菌:大腸菌(Esherichia coli)、肺炎桿菌(Klebsiella pneumoniae)、サルモネラ菌(Salmonella typhimurium)、緑膿菌(Pseudomonas aeruginosa)等。
[かび(酵母を含む)]
クロコウジカビ(Aspergillus niger)、アオカビ(Penicillium citrinum)、クロカビ(Cladosporium cladosporioides)、白癬菌(Trichopyton mentagrophytes)、カンジダ(Candida albicans)等。
[耐洗濯性評価のための試験方法]
まず、耐洗濯性については、下記の「一般家庭洗濯」における洗濯耐久性と、「工業洗濯」における洗濯耐久性のいずれかを、対象とする抗菌・抗かび加工製品の種類に応じて、適用することができる。
(1)一般家庭洗濯(40℃)
JIS L0217、103号に準拠した洗濯方法により40℃、10回の洗濯を実施する。
(2)工業洗濯(80℃)
JTETCが認証する特定制菌加工による洗濯方法により80℃、10回~100回の洗濯を実施する(厚労省令第13号に準拠した簡略法)。
殺菌活性値={log(標準布の接種直後の3平均生菌数)-log(加工布の18時間培養後の3平均生菌数)} …(1)
抗かび活性値={log(標準布の42時間培養後の3平均生かびATP量)-log(標準布の試験かび接種直後の3平均生かびATP量)}-{log(加工布の42時間培養後の3平均生かびATP量)-log(加工布の試験かび接種直後の3平均生かびATP量)} …(2)
○:化合物の残存量が、100ppm以上。
△:化合物の残存量が、100ppm未満10ppm以上。
×:化合物の残存量が、10ppm未満。
DDAC:ジデシルジメチルアンモニウムクロライド
BAC:アルキルジメチルベンジルアンモニウムクロライド
DDAB:ジデシルジメチルアンモニウムブロマイド
PDIEC1:ポリオキシエチレン(ジメチルイミノ)エチレン(ジメチルイミノ)エチレンジクロライド(分子量900)
PDIEC2:同上(分子量2000)
DDAA:ジデシルジメチルアンモニウムアジペ-ト
DDAP:N,N-ジデシル-N-メチル-ポリ(オキシエチル)アンモニウムプロピオネ-ト(分子量:2000)
PHMB:ポリヘキサメチレンビグアニジンクロライド(分子量:2000)
ポリエステル標準布(帝人製トロピカル、以下同じ)を、DDAC、BAC、DDAAのそれぞれ0.32および0.16重量%水溶液に浸漬後、マングルで100%絞りとし、各々を130℃で1分間乾燥後、170℃、2分間/180℃、1分間/200℃、30秒間のキュアリングを実施した。なお、加工時の圧力は、いずれの段階においても常圧(加圧も減圧もしていない状態)である(以下の例においても、特に記載がない場合は常圧である)。そして、各試料について、40℃の家庭洗濯10回後に各化合物の残存量を定量分析し、前述の基準にしたがって評価した。その結果を下記の表1に示す。
ポリエステル標準布を、DDAC、BAC、DDAB、PDIEC1(分子量:900)、DDAAのそれぞれ0.32重量%水溶液に浸漬後、マングルで100%の絞り率とし、各々を180℃で1分間キュアリングした。そして、各試料について、80℃の工業洗濯10回後に各化合物の残存量を定量分析し、前述の基準にしたがって評価した。その結果を後記の表2に示す。
ポリエステル標準布を、PDIEC2(分子量:2000)の0.36重量%水溶液、DDAP(対イオンが有機カルボン酸)の0.32重量%水溶液、およびPHMB(アンモニウム塩ではない)の0.40重量%水溶液にそれぞれ浸漬後、実施例7~11と同様、マングルで100%の絞り率とし、各々を180℃で1分間キュアリングした。そして、各試料について、80℃の工業洗濯10回後に各化合物の残存量を定量分析し、前述の基準にしたがって評価した。その結果を下記の表2に併せて示す。
ポリエステルと綿の混紡品(ポリエステル80重量%、綿20重量%)を、ジアミノスチルベンスルホン酸系蛍光増白剤0.5%owsで染色、乾燥を実施した。得られた生地を試料とし、DDACの0.32および0.60重量%水溶液に浸漬後、マングルで100%の絞り率とし、130℃で1分乾燥後、170℃で2分間キュアリングした。これらの試料について、40℃の家庭洗濯10回を実施後、上記化合物の残存量を定量分析し、前述の基準にしたがって評価した。その結果を後記の表3に示す。
ポリエステルと綿の混紡品(ポリエステル80重量%、綿20重量%)を、ジアミノスチルベンスルホン酸系増白剤0.5%owsで染色、乾燥を実施した。得られた生地を試料とし、DDAPの、0.60重量%水溶液、PHMBの0.60重量%水溶液のそれぞれに浸漬後、マングルで100%の絞り率とし、130℃で1分乾燥後、170℃で2分キュアリングした。これらの試料について、40℃の家庭洗濯10回を実施後、各化合物の残存量を定量分析し、前述の基準にしたがって評価した。その結果を下記の表3に併せて示す。
ポリアミド繊維(ナイロン6)のサンプル生地(色染社製、商品名:ナイロン6ジャージ)を、DDAC、DDAAのそれぞれ0.32重量%水溶液に浸漬後、85℃、45分間のキュアリングを行った。この試料について、40℃の家庭洗濯10回を実施後、上記化合物の残存量を定量分析し、前述の基準にしたがって評価した。その結果を下記の表4に示す。
ポリエステル標準布を、DDACの0.40、0.20および0.10重量%水溶液と、DDAA、BAC、PDIEC1のそれぞれ0.10重量%水溶液に浸漬後、180℃で1分間キュアリングした。これらの試料について、80℃の工業洗濯100回を実施後、JTETCの評価基準にしたがって、その殺菌活性値を求めた。これらの結果を後記の表5に示す。
ポリエステル標準布を、PHMB、PDIEC2、DDAPのそれぞれ1.0重量%水溶液に浸漬後、マングルで100%絞り率とし、180℃で1分間キュアリングした。これらの試料について、80℃の工業洗濯100回を実施後、実施例16~21と同様にして、JTETCの評価基準にしたがって、その殺菌活性値を求めた。その結果を下記の表5に併せて示す。
ポリエステル標準布を、DDACの0.20重量%水溶液、DDAAの0.20重量%水溶液、BACの0.40重量%水溶液、PDIEC1の1.0重量%水溶液のそれぞれに浸漬後、180℃で1分間キュアリングした。これらの試料について、40℃の家庭洗濯10回を実施後、JTETCの評価基準にしたがって、その抗かび活性値を求めた。これらの結果を後記の表6に示す。
ポリエステル標準布を、PHMB、PDIED2、DDAPの各1.0重量%水溶液に浸漬後、180℃で1分間キュアリングした。これらの試料について、40℃の家庭洗濯10回を実施後、JTETCの評価基準にしたがって、その抗かび活性値を求めた。これらの結果を下記の表6に示す。
Claims (8)
- 抗菌・抗かび性が付与された抗菌・抗かび加工製品を得る方法であって、樹脂成形品に、下記の抗菌・抗かび性化合物(A)を含有する処理液体を接触させた状態で、常圧または加圧下で加熱処理を行うことにより、上記抗菌・抗かび性化合物(A)を、上記樹脂成形品の少なくとも表面に固定させることを特徴とする抗菌・抗かび加工製品の製法。
(A)分子量1500以下の第四級アンモニウム塩系化合物からなる抗菌・抗かび性化合物。 - 上記樹脂成形品が、ポリエステル系樹脂、ポリアミド系樹脂、アクリル系樹脂およびポリウレタン系樹脂から選択される少なくとも一種の樹脂を含有するものである請求項1記載の抗菌・抗かび加工製品の製法。
- 上記樹脂成形品に対し、処理液体をスプレー、浸漬、塗布のいずれかによって付着させた後、常圧または加圧下、70~230℃の気体中で加熱処理を行う請求項1または2記載の抗菌・抗かび加工製品の製法。
- 上記樹脂成形品を処理液体中に浸漬し、常圧または加圧下、70~230℃の浴中で加熱処理を行う請求項1または2記載の抗菌・抗かび加工製品の製法。
- 請求項1~4のいずれか一項に記載の製法によって得られる抗菌・抗かび加工製品であって、少なくとも表面に下記の抗菌・抗かび性化合物(A)が固定されており、黄色ブドウ球菌、メチシリン耐性黄色ブドウ球菌、肺炎桿菌、枯草菌、セレウス菌、大腸菌、サルモネラ菌、緑膿菌のうち少なくとも3種類の菌に対する殺菌活性値がいずれも0以上、クロコウジカビ、アオカビ、クロカビ、白癬菌、カンジダのうち少なくとも2種類のかびに対する抗かび活性値がいずれも2以上である樹脂成形品が用いられていることを特徴とする抗菌・抗かび加工製品。
(A)分子量1500以下の第四級アンモニウム塩系化合物からなる抗菌・抗かび性化合物。 - 上記樹脂成形品が、ポリエステル系樹脂、ポリアミド系樹脂、アクリル系樹脂およびポリウレタン系樹脂から選択される少なくとも一種の樹脂を含有するものである請求項5記載の抗菌・抗かび加工製品。
- 上記樹脂成形品が、繊維品である請求項5または6記載の抗菌・抗かび加工製品。
- 上記樹脂成形品が、樹脂シート、樹脂フィルム、所定形状を有する樹脂硬化体のいずれかである請求項5または6記載の抗菌・抗かび加工製品。
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JPWO2016043202A1 (ja) | 2017-07-06 |
TW201614121A (en) | 2016-04-16 |
US20170260688A1 (en) | 2017-09-14 |
US10563347B2 (en) | 2020-02-18 |
JP6726100B2 (ja) | 2020-07-22 |
TWI676723B (zh) | 2019-11-11 |
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