WO2016017655A1 - ゴム物品補強用スチールコード - Google Patents
ゴム物品補強用スチールコード Download PDFInfo
- Publication number
- WO2016017655A1 WO2016017655A1 PCT/JP2015/071407 JP2015071407W WO2016017655A1 WO 2016017655 A1 WO2016017655 A1 WO 2016017655A1 JP 2015071407 W JP2015071407 W JP 2015071407W WO 2016017655 A1 WO2016017655 A1 WO 2016017655A1
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- WIPO (PCT)
- Prior art keywords
- sheath
- cord
- core strand
- filaments
- steel
- Prior art date
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Classifications
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0606—Reinforcing cords for rubber or plastic articles
- D07B1/0613—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the rope configuration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/0007—Reinforcements made of metallic elements, e.g. cords, yarns, filaments or fibres made from metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0606—Reinforcing cords for rubber or plastic articles
- D07B1/062—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0606—Reinforcing cords for rubber or plastic articles
- D07B1/062—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration
- D07B1/0626—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration the reinforcing cords consisting of three core wires or filaments and at least one layer of outer wires or filaments, i.e. a 3+N configuration
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0606—Reinforcing cords for rubber or plastic articles
- D07B1/062—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration
- D07B1/0633—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration having a multiple-layer configuration
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/202—Strands characterised by a value or range of the dimension given
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2024—Strands twisted
- D07B2201/2029—Open winding
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2036—Strands characterised by the use of different wires or filaments
- D07B2201/2037—Strands characterised by the use of different wires or filaments regarding the dimension of the wires or filaments
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2038—Strands characterised by the number of wires or filaments
- D07B2201/204—Strands characterised by the number of wires or filaments nine or more wires or filaments respectively forming multiple layers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2047—Cores
- D07B2201/2051—Cores characterised by a value or range of the dimension given
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2047—Cores
- D07B2201/2052—Cores characterised by their structure
- D07B2201/2059—Cores characterised by their structure comprising wires
- D07B2201/2061—Cores characterised by their structure comprising wires resulting in a twisted structure
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2047—Cores
- D07B2201/2067—Cores characterised by the elongation or tension behaviour
- D07B2201/2068—Cores characterised by the elongation or tension behaviour having a load bearing function
Definitions
- the present invention relates to a steel cord for reinforcing rubber articles (hereinafter also simply referred to as “cord”), and more particularly to a steel cord for reinforcing rubber articles used for reinforcing rubber articles such as tires.
- steel cords formed by twisting a plurality of steel filaments are widely used as reinforcing materials.
- tires used for large vehicles such as construction vehicles are used under heavy load on rough terrain and the like, and therefore, steel cords used as reinforcing materials have particularly high strength and durability. Needed. Therefore, in such a large tire, a steel cord having a so-called double-twist structure in which a plurality of strands formed by twisting a plurality of steel filaments is further twisted is employed.
- Patent Document 1 discloses a rubber having a double twist structure in which a plurality of strands having a layer twist structure in which a plurality of steel filaments are twisted are twisted together.
- the ratio dc / ds between the diameter dc of the outermost layer sheath filament constituting the outermost layer sheath of the core strand and the diameter ds of the outermost layer sheath filament constituting the outermost layer sheath of the sheath strand is 1.
- a technology for improving the cord strength by preventing the occurrence of preceding breakage of the outermost layer filament by setting to 05 to 1.25 is disclosed.
- an object of the present invention is to provide a steel cord for reinforcing rubber articles that can further improve cut resistance when applied to a tire.
- the steel cord for reinforcing rubber articles of the present invention has one core strand having a layer twist structure formed by twisting a plurality of steel filaments and a layer twist structure formed by twisting a plurality of steel filaments.
- a steel cord for reinforcing rubber articles comprising a plurality of sheath strands, wherein the sheath strand is twisted around the core strand
- the ratio S1 / S of the sum S1 of the cross-sectional areas of the outermost sheath filaments constituting the outermost sheath of the core strand to the sum S of the cross-sectional areas of all the filaments constituting the core strand is 0.69-0. 74
- the ratio Ps / P between the total strength Ps of the sheath strands and the strength P of the entire cord is 0.81 to 0.85.
- the number of the sheath strands is preferably 7 to 9. In the cord of the present invention, it is preferable that all the filaments constituting the core strand have the same diameter. Furthermore, in the cord of the present invention, the cord diameter is preferably 5.00 mm or more.
- the pneumatic tire of the present invention is characterized by using the steel cord for reinforcing rubber articles of the present invention as a reinforcing material.
- FIG. 1 is a cross-sectional view in the width direction showing a structural example of a steel cord for reinforcing rubber articles according to the present invention.
- the cord of the present invention is formed by twisting a single core strand 11 having a two-layer twisted structure formed by twisting a plurality of steel filaments 1 and a plurality of steel filaments 2.
- the sheath strand 12 is composed of a plurality of layers having a layer twist structure of layers, in the illustrated example, and has a double twist structure in which the sheath strand 12 is twisted around the core strand 11.
- first sheath filaments 1b are twisted together to form a first sheath around a core composed of three core filaments 1a in which core strands 11 are twisted.
- the second sheath filament 1c is twisted together to form a second sheath, and the sheath strand 12 is surrounded by eight sheath filaments 2b around the core composed of the three core filaments 2a twisted together.
- the spiral filament 3 is spirally wound around the outer periphery of the sheath strand 12.
- the ratio S1 / S between the sum S1 of the cross-sectional areas of the outermost sheath filaments 1c constituting the outermost sheath of the core strand 11 and the sum S of the cross-sectional areas of all the filaments constituting the core strand 11 is It is important that the ratio Ps / P of the total strength Ps of the sheath strand 12 and the strength P of the entire cord is 0.81 to 0.85, which is 0.69 to 0.74. In order to prevent the occurrence of this pre-breaking, the fact that the outermost layer filament of the core strand is pre-ruptured due to the sheath strand tightening the core strand is a factor that reduces the shear resistance of the cord.
- the magnitude of the stress at which the sheath strand clamps the core strand is proportional to the strength of the sheath strand, and the shear resistance of the outermost filament of the core strand is the total cross-sectional area of the outermost filament of the core strand.
- the ratio of the total strength of the sheath strand 12 to the cord strength is set to a relatively low range of 0.81 to 0.85, and the tightening force of the sheath strand is reduced, and the outermost filament of the core strand is reduced.
- the ratio of the total cross-sectional area to the total cross-sectional area of the filament is set to a relatively high range of 0.69 to 0.74 to improve the shear resistance of the outermost filament of the core strand. As a result, the shear resistance of the entire cord can be improved as never before.
- the value of the ratio S1 / S needs to be 0.69 to 0.74, and is preferably in the range of 0.71 to 0.73. If the value of S1 / S is smaller than 0.69, it is impossible to prevent the preceding breakage of the outermost layer filament of the core strand. On the other hand, if the value of S1 / S is larger than 0.74, the filament inside the outermost layer sheath of the core strand becomes too thin, and there is a risk of preceding breakage. Further, the value of the ratio Ps / P needs to be 0.81 to 0.85, and preferably in the range of 0.81 to 0.83.
- the absolute value of the sum S1 of the cross-sectional areas of the outermost sheath filaments constituting the outermost layer sheath of the core strand is preferably 1.33 mm from the viewpoint of ensuring high shear resistance, although it depends on the cord diameter and the like. 2 or more, for example, be a 1.60 ⁇ 1.90 mm 2.
- the number of layers of the core strand layer twist structure is not particularly limited, and may be, for example, 2 to 3 layers. Therefore, when the first sheath and the second sheath are sequentially formed from the inner side of the layer twist structure, when the core strand 11 has a three-layer twist structure as shown in FIG. 1, the outermost layer sheath of the core strand 11 is It becomes the second sheath. Further, the number of layers of the layer twist structure of the sheath strand is not particularly limited, and may be, for example, 2 to 3 layers.
- the number of sheath strands 12 is preferably 7-9. If the core strand and the sheath strand are all the same diameter and the sheath strands are in the close-packed state so that there is no gap between them, six sheath strands can be arranged.
- the diameter of the sheath strand 12 is made smaller than the diameter of the core strand 11 so that 7 to 9 sheath strands 12 can be arranged. Therefore, by setting the number of sheath strands 12 to 9 to 9, sufficiently strong core strands that can withstand the tightening force of the sheath strands can be obtained, and the cut resistance of the cord can be further improved.
- the core strand when the core strand has a two-layer structure, it is preferable that all the filaments constituting the core strand have the same diameter.
- the core strand In the core strand, it is possible to improve the shear resistance by making the core filament smaller in diameter than the sheath filament, but in this case, it is difficult to ensure a gap amount between the sheath filaments. Therefore, when the core strand has a two-layer structure, it is preferable that all the filaments constituting the core strand have the same diameter.
- the core filament 1a and the first sheath filament 1b when the core strand has a three-layer structure, it is preferable that the core filament 1a and the first sheath filament 1b have the same diameter among the filaments constituting the core strand 11. .
- the core filament 1a has a smaller diameter than the first sheath filament 1b in the core strand 11, it becomes difficult to ensure a gap between the first sheath filaments. Therefore, when the core strand has a three-layer structure, it is preferable that the core filament 1a and the first sheath filament 1b have the same diameter.
- the cord diameter of the cord of the present invention is preferably 5.00 mm or more, for example, 5.00 to 6.00 mm.
- a cord having a large diameter of 5.00 mm or more it is possible to ensure both strength and cut resistance required for large tires used in large vehicles such as construction vehicles. .
- the wire diameter and tensile strength of the filament to be used and the twisting direction and twisting pitch of the filament and strand are not particularly limited, and are appropriately selected according to the usual method according to a desired method. It is possible.
- the filament a so-called high strength steel having a carbon content of 0.80% by mass or more can be used.
- the cord of the present invention may or may not have a spiral filament.
- the cord of the present invention is excellent in cut resistance, it is particularly used as a reinforcing material for large tires used in large vehicles such as construction vehicles, especially for ultra-large off-road radial tires having a tire size of about 40.00R57.
- a large tire usually has one or more carcass made of a steel cord ply extending in a radial direction between a pair of bead cores and at least four belts arranged on the outer side in the tire radial direction of the crown portion. And a tread disposed on the outer side in the tire radial direction.
- the cord of the present invention can be used, for example, as a reinforcing cord for a belt crossing layer in such a tire.
Abstract
Description
前記コアストランドの最外層シースを構成する最外層シースフィラメントの断面積の総和S1と、該コアストランドを構成するすべてのフィラメントの断面積の総和Sとの比S1/Sが0.69~0.74であって、かつ、前記シースストランドの強力の総和Psとコード全体の強力Pとの比Ps/Pが、0.81~0.85であることを特徴とするものである。
図1に、本発明のゴム物品補強用スチールコードの一構成例を示す幅方向断面図を示す。図示するように、本発明のコードは、複数本のスチールフィラメント1を撚り合わせてなる2層の層撚り構造を有する1本のコアストランド11と、複数本のスチールフィラメント2を撚り合わせてなる2層の層撚り構造を有する複数本、図示例では7本のシースストランド12とからなり、シースストランド12がコアストランド11の周囲に撚り合わせられてなる複撚り構造を有する。図示するコードにおいては、コアストランド11が、撚り合わされた3本のコアフィラメント1aからなるコアの周囲に、8本の第1シースフィラメント1bが撚り合わされて第1シースが形成され、さらに、10本の第2シースフィラメント1cが撚り合わされて第2シースが形成された3+8+10構造を有し、シースストランド12が、撚り合わされた3本のコアフィラメント2aからなるコアの周囲に、8本のシースフィラメント2bが撚り合わされてシースが形成された3+8構造を有している。また、図示するコードにおいては、シースストランド12の外周に、スパイラルフィラメント3が螺旋状に巻き付けられている。
下記の表中に示すように、コード構造の変更により、コアストランドの最外層シースを構成する最外層シースフィラメントの断面積の総和S1と、コアストランドを構成する全フィラメントの断面積の総和Sとの比S1/S、および、シースストランドの強力の総和Psとコード全体の強力Pの比Ps/Pを変えて、層撚り構造を有する1本のコアストランドの周囲に、層撚り構造を有する複数本のシースストランドが撚り合わせられてなる各実施例および比較例のゴム物品補強用スチールコードを作製した。得られた各コードについて下記の評価を行った結果を、下記の表中に併せて示す。
得られた各コードにつき、シャルピー衝撃試験機を用いて、耐せん断力を評価した。数値が大きいほど、耐せん断性に優れ、良好である。
1a,2a コアフィラメント
1b 第1シースフィラメント
1c 第2シースフィラメント(最外層シースフィラメント)
2b シースフィラメント
3 スパイラルフィラメント
11 コアストランド
12 シースストランド
Claims (5)
- 複数本のスチールフィラメントを撚り合わせてなる層撚り構造を有する1本のコアストランドと、複数本のスチールフィラメントを撚り合わせてなる層撚り構造を有する複数本のシースストランドとからなり、該シースストランドが該コアストランドの周囲に撚り合わせられているゴム物品補強用スチールコードにおいて、
前記コアストランドの最外層シースを構成する最外層シースフィラメントの断面積の総和S1と、該コアストランドを構成するすべてのフィラメントの断面積の総和Sとの比S1/Sが0.69~0.74であって、かつ、前記シースストランドの強力の総和Psとコード全体の強力Pとの比Ps/Pが、0.81~0.85であることを特徴とするゴム物品補強用スチールコード。 - 前記シースストランドの本数が7~9本である請求項1記載のゴム物品補強用スチールコード。
- 前記コアストランドを構成する各フィラメントがすべて同径である請求項1記載のゴム物品補強用スチールコード。
- コード径が5.00mm以上である請求項1記載のゴム物品補強用スチールコード。
- 請求項1記載のゴム物品補強用スチールコードを補強材として用いたことを特徴とする空気入りタイヤ。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/328,731 US20170210169A1 (en) | 2014-07-28 | 2015-07-28 | Steel cord for reinforcing rubber article |
CN201580040620.0A CN106536819B (zh) | 2014-07-28 | 2015-07-28 | 用于加固橡胶制品的钢帘线 |
ES15828190T ES2743486T5 (es) | 2014-07-28 | 2015-07-28 | Cable de acero para reforzar un artículo de caucho |
JP2016538374A JP6560677B2 (ja) | 2014-07-28 | 2015-07-28 | ゴム物品補強用スチールコード |
EP15828190.7A EP3196354B2 (en) | 2014-07-28 | 2015-07-28 | Steel cord for reinforcing rubber article |
US16/378,668 US10895037B2 (en) | 2014-07-28 | 2019-04-09 | Steel cord for reinforcing rubber article |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014-153033 | 2014-07-28 | ||
JP2014153033 | 2014-07-28 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/328,731 A-371-Of-International US20170210169A1 (en) | 2014-07-28 | 2015-07-28 | Steel cord for reinforcing rubber article |
US16/378,668 Continuation-In-Part US10895037B2 (en) | 2014-07-28 | 2019-04-09 | Steel cord for reinforcing rubber article |
Publications (1)
Publication Number | Publication Date |
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WO2016017655A1 true WO2016017655A1 (ja) | 2016-02-04 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2015/071407 WO2016017655A1 (ja) | 2014-07-28 | 2015-07-28 | ゴム物品補強用スチールコード |
Country Status (6)
Country | Link |
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US (1) | US20170210169A1 (ja) |
EP (1) | EP3196354B2 (ja) |
JP (1) | JP6560677B2 (ja) |
CN (1) | CN106536819B (ja) |
ES (1) | ES2743486T5 (ja) |
WO (1) | WO2016017655A1 (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10105991B2 (en) | 2014-10-01 | 2018-10-23 | Bridgestone Corporation | Steel cord for reinforcing rubber article, and pneumatic tire using same |
CN111566281A (zh) * | 2017-12-15 | 2020-08-21 | 株式会社普利司通 | 橡胶制品增强用钢丝帘线和轮胎 |
WO2021099712A1 (fr) | 2019-11-22 | 2021-05-27 | Compagnie Generale Des Etablissements Michelin | Câble multi-torons à deux couches à énergie de rupture surfacique améliorée |
WO2022234201A1 (fr) | 2021-05-07 | 2022-11-10 | Compagnie Generale Des Etablissements Michelin | Câble multi-torons à deux couches à énergie de rupture surfacique améliorée |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JP7330191B2 (ja) | 2017-12-19 | 2023-08-21 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 超低、低、及び中程度の弾性率を有する2層マルチストランドコード |
US11591750B2 (en) | 2017-12-19 | 2023-02-28 | Compagnie Generale Des Etablissements Michelin | Two-layer multi-strand cables having very low, low and medium modulus |
US11346049B2 (en) * | 2017-12-19 | 2022-05-31 | Compagnie Generale Des Etablissements Michelin | Two-layer multi-strand cords having very low, low and medium moduli |
EP3728728B1 (fr) | 2017-12-19 | 2022-07-20 | Compagnie Generale Des Etablissements Michelin | Câbles multi-torons à deux couches à très bas, bas et moyen modules |
JP7309715B2 (ja) | 2017-12-19 | 2023-07-18 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 超低、低、及び中程度の弾性率を有する2層マルチストランドコード |
CN109147989A (zh) * | 2018-09-10 | 2019-01-04 | 宁波容合电线有限公司 | 一种防内缩型绞合电缆 |
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- 2015-07-28 WO PCT/JP2015/071407 patent/WO2016017655A1/ja active Application Filing
- 2015-07-28 ES ES15828190T patent/ES2743486T5/es active Active
- 2015-07-28 JP JP2016538374A patent/JP6560677B2/ja active Active
- 2015-07-28 US US15/328,731 patent/US20170210169A1/en not_active Abandoned
- 2015-07-28 CN CN201580040620.0A patent/CN106536819B/zh active Active
- 2015-07-28 EP EP15828190.7A patent/EP3196354B2/en active Active
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WO2001034900A1 (fr) * | 1999-11-11 | 2001-05-17 | Bridgestone Corporation | Cable d'acier de renforcement d'un article en caoutchouc et pneumatique correspondant |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10105991B2 (en) | 2014-10-01 | 2018-10-23 | Bridgestone Corporation | Steel cord for reinforcing rubber article, and pneumatic tire using same |
CN111566281A (zh) * | 2017-12-15 | 2020-08-21 | 株式会社普利司通 | 橡胶制品增强用钢丝帘线和轮胎 |
US11591749B2 (en) | 2017-12-15 | 2023-02-28 | Bridgestone Corporation | Steel cord for rubber article reinforcement, and tire |
WO2021099712A1 (fr) | 2019-11-22 | 2021-05-27 | Compagnie Generale Des Etablissements Michelin | Câble multi-torons à deux couches à énergie de rupture surfacique améliorée |
FR3103500A1 (fr) | 2019-11-22 | 2021-05-28 | Compagnie Generale Des Etablissements Michelin | Câble multi-torons à deux couches à énergie de rupture surfacique améliorée |
WO2022234201A1 (fr) | 2021-05-07 | 2022-11-10 | Compagnie Generale Des Etablissements Michelin | Câble multi-torons à deux couches à énergie de rupture surfacique améliorée |
FR3122676A1 (fr) | 2021-05-07 | 2022-11-11 | Compagnie Generale Des Etablissements Michelin | Câble multi-torons à deux couches à énergie de rupture surfacique améliorée |
Also Published As
Publication number | Publication date |
---|---|
EP3196354B1 (en) | 2019-06-12 |
JP6560677B2 (ja) | 2019-08-14 |
EP3196354A1 (en) | 2017-07-26 |
ES2743486T5 (es) | 2023-04-10 |
CN106536819B (zh) | 2019-04-26 |
EP3196354B2 (en) | 2022-11-30 |
US20170210169A1 (en) | 2017-07-27 |
CN106536819A (zh) | 2017-03-22 |
ES2743486T3 (es) | 2020-02-19 |
EP3196354A4 (en) | 2017-08-16 |
JPWO2016017655A1 (ja) | 2017-04-27 |
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