WO2015180326A1 - 光配向膜及其制作方法、液晶显示器 - Google Patents
光配向膜及其制作方法、液晶显示器 Download PDFInfo
- Publication number
- WO2015180326A1 WO2015180326A1 PCT/CN2014/087314 CN2014087314W WO2015180326A1 WO 2015180326 A1 WO2015180326 A1 WO 2015180326A1 CN 2014087314 W CN2014087314 W CN 2014087314W WO 2015180326 A1 WO2015180326 A1 WO 2015180326A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- alignment film
- photo
- light
- manufacturing
- polarized light
- Prior art date
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Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
- G02F1/133711—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by organic films, e.g. polymeric films
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
- G02F1/13378—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
- G02F1/133788—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by light irradiation, e.g. linearly polarised light photo-polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
- B32B2457/202—LCD, i.e. liquid crystal displays
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/02—Alignment layer characterised by chemical composition
Definitions
- the present disclosure relates to the field of liquid crystal display technology, and in particular, to a photo alignment film, a method for fabricating the same, and a liquid crystal display.
- a polyimide (PI) film is a functional film layer for ensuring that liquid crystal molecules are oriented as desired and form a certain pretilt angle, which is also called an alignment film.
- the alignment film manufacturing process includes a patterning process.
- the patterning of the alignment film is usually completed by using a pattern coating method, specifically:
- the transfer plate having the alignment film orientation pattern is designed according to the size and structure of the product, and the alignment film material is bonded to the transfer plate to form an alignment film, so that the alignment film has a certain orientation, and then the transfer plate is printed.
- the patterned alignment film is printed onto the substrate of the liquid crystal display such that the alignment film is only located in the display area of the liquid crystal display.
- the existing graphical coating has the following disadvantages:
- the transfer plate has a certain service life, there are maintenance and replacement costs;
- the graphical coating has a bottleneck in the accuracy of the graphical boundary, and cannot correspond to the refined graphics
- the graphic coating includes two processes of coating and transfer, and the production efficiency is low.
- the present disclosure provides a photo alignment film, a method for fabricating the same, and a liquid crystal display to reduce the cost of producing a patterned alignment film and improve the production efficiency and the accuracy of the pattern boundary.
- the present disclosure provides a method for fabricating a photo alignment film, comprising:
- the polarized light is irradiated to the photo-alignment film through a mask plate, and the mask plate includes a light-transmitting region and an opaque region outside the light-transmitting region, and the polarized light passes through the light-transmitting region to illuminate Orienting the light alignment film;
- the photo-alignment film corresponding to the opaque region is removed to form a patterned photo-alignment film.
- the polarized light passes through the light-transmitting region to photopolymerize the irradiated photo-alignment film.
- the polarized light is ultraviolet polarized light
- the irradiation amount is 500 to 2000 mJ/cm 2 .
- the substrate is washed with water, acetone or iso-acetone to remove the photo-alignment film corresponding to the opaque region.
- the method further includes:
- the substrate is subjected to a first heat treatment.
- the temperature of the first heat treatment is 70° C. to 150° C.
- the time of the first heat treatment is 60 s to 120 s.
- the method further includes:
- the substrate is subjected to a second heat treatment.
- the second heat treatment process The temperature is from 220 ° C to 250 ° C.
- the time of the second heat treatment is greater than 40 min.
- the present disclosure also provides a photo-alignment film which is produced by the above-described production method.
- the photo-alignment film is a photopolymerizable alignment film material.
- the photopolymerizable alignment film material is a cinnamate compound.
- the present disclosure also provides a liquid crystal display employing the photoalignment film as described above.
- the polarized light is irradiated to the light-aligning film through a mask, and the photo-alignment film corresponding to the display region is oriented by the polarized light of the anisotropic energy, and the photo-alignment film corresponding to the non-display region other than the display region is not. Orientation occurs and the unoriented photo-alignment film is removed such that the photo-alignment film only corresponds to the display area to form a patterned photo-alignment film.
- the technical solution of the present disclosure improves the precision of the photo-alignment film boundary, and the production efficiency is high.
- the manufacturing cost and maintenance cost of the mask are lower than those of the transfer coating used for pattern coating, which reduces the production cost.
- 1 to 3 are views showing a process of fabricating a photo alignment film in an embodiment of the present disclosure.
- Figure 4a shows a photoalignment film prepared by a conventional pattern coating method
- Figure 4b shows a photoalignment film prepared in an embodiment of the present disclosure.
- the liquid crystal display realizes the liquid crystal molecules to be oriented as required by the alignment film and forms a certain pretilt angle.
- the alignment film manufacturing process includes a patterning process.
- the patterning of the alignment film is usually performed by means of pattern coating, but the formation of the alignment film has low boundary precision, low production efficiency, and high production cost and maintenance cost of the transfer sheet.
- the present disclosure provides a method for fabricating a photo-alignment film by irradiating a light-aligning film through a mask through polarized light, and aligning the light-aligning film corresponding to the display region with polarized light of anisotropic energy.
- the photo-alignment film corresponding to the non-display region other than the display region is not oriented, and the unoriented photo-alignment film is removed, so that the photo-alignment film only corresponds to the display region to form a patterned photo-alignment film.
- the technical solution of the present disclosure improves the precision of the alignment film boundary and has high production efficiency.
- the manufacturing cost and maintenance cost of the mask are lower than those of the transfer coating used for pattern coating, which reduces the production cost.
- the orientation principle of the photo-alignment film is:
- the polarized light of anisotropic energy is irradiated onto the photo-alignment film to cause photopolymerization of the molecular structure on the surface of the film
- optical alignment film is a photopolymerizable alignment film material
- conversion The photo-alignment film is a configuration conversion type alignment film material) or photodecomposition (the photo-alignment film is a photo-decomposition type alignment film material) reacts, resulting in an anisotropic distribution of the van der Waals force on the surface of the film, thereby inducing alignment of the liquid crystal molecules.
- a method for fabricating a photo-alignment film which specifically includes:
- the polarized light is irradiated to the photo-alignment film through a mask plate, and the mask plate includes a light-transmitting region and an opaque region outside the light-transmitting region, and the polarized light passes through the light-transmitting region to illuminate Orienting the light alignment film;
- the photo-alignment film of the opaque region is removed to form a patterned photo-alignment film.
- the photo-alignment film can be patterned by the mask plate, and the orientation of the photo-alignment film can be realized to form a patterned photo-alignment film, which has high production efficiency and is obtained.
- the light alignment film boundary has high precision. Since the production cost and maintenance cost of the mask sheet relative to the transfer sheet used for the pattern coating are low, the production cost is lowered.
- the photo-alignment film according to the present disclosure is produced by orienting a photo-alignment film.
- the light alignment film 101 covering the entire substrate 100 may be formed on the substrate 100 by an inkjet or spin coating process.
- the substrate 100 may be an array substrate or a color filter substrate of a liquid crystal display.
- the temperature of the first heat treatment is 70 ° C to 150 ° C, and may be 80 ° C.
- the time is 60s to 120s, and the time is 100s.
- the substrate 100 is sent to a polarized light irradiation device to perform an alignment process.
- the polarized light is irradiated to the light-aligning film 101 through the mask 20, and the direction of the arrow in FIGS. 1 and 2 is the incident direction of the polarized light, wherein the mask 20 includes the light-transmitting region 200 (corresponding to the display of the liquid crystal display) The area) and the opaque area 201 (corresponding to the non-display area of the liquid crystal display) outside the light-transmitting area 200.
- the polarized light passes through the light-transmitting region 200 to align the irradiated light-aligning film 101 to form the photo-alignment film 10.
- the photo-alignment film 101 corresponding to the opaque region 201 is not irradiated with polarized light, and is an unoriented photo-alignment film pattern 11, as shown in FIGS. 1 and 2.
- the photo-alignment film is a photopolymerizable alignment film material (such as a cinnamate compound such as vinyl cinnamate or vinyl methoxycinnamate), and the polarized light is transmitted through the light-transmitting region 200 of the mask 20
- the photoalignment film is photopolymerized.
- the polarized light is usually ultraviolet polarized light, and the irradiation amount is 500 to 2000 mJ/cm 2 .
- the photo-alignment film corresponding to the opaque region 201 is removed, that is, the unoriented photo-alignment film pattern 11 is removed to form a patterned photo-alignment film 10, as shown in FIGS. 2 and 3.
- the substrate 100 may be washed with water, acetone or iso-acetone to remove the photo-alignment film corresponding to the opaque region 201.
- the substrate 100 may be subjected to a second heat treatment to remove the cleaning agent and increase the degree of polymerization of the photo-alignment film 10.
- the temperature of the second heat treatment is 220 ° C to 250 ° C, and may be 230 ° C.
- the time is greater than 40 min, which can be 60 min.
- a photo-alignment film is provided, which is prepared by the manufacturing method in the first embodiment.
- the polarized light is irradiated through the mask plate to illuminate the light alignment film, and the mask plate includes a light-transmitting region and a location.
- An opaque region other than the light-transmitting region the polarized light is transmitted through the light-transmitting region to orient the irradiated light-aligning film, and the light-aligning film corresponding to the opaque region is removed, thereby forming a patterned light alignment membrane.
- the optical alignment film obtained by the above-mentioned production method has high boundary precision and improves product quality. At the same time, it also improves production efficiency and reduces production costs.
- a liquid crystal display which includes an array substrate and a color filter substrate disposed on the cartridge, and a light alignment film is formed on the array substrate and the color filter substrate.
- the photo-alignment film adopts the photo-alignment film in the second embodiment, and the photo-alignment film corresponds to the display region of the liquid crystal display.
- the technical solution of the present disclosure adopts the "all-print coating + patterning process" to form a patterned photo-alignment film without using pattern coating, which saves the graphic design of the transfer plate design, material and maintenance. Cost; and the speed of full-print coating is faster than the speed of pattern coating, which reduces the production time of a single substrate and high production efficiency; the patterning boundary of the photo-alignment film is significantly improved by the etching process in the patterning process. The degree of fineness of the boundary of the light alignment film.
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- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Liquid Crystal (AREA)
- Polarising Elements (AREA)
Abstract
Description
Claims (14)
- 一种光配向膜的制作方法,包括:在一基板上形成光配向薄膜;使偏振光通过一掩膜板照射所述光配向薄膜,所述掩膜板包括透光区域和位于所述透光区域以外的不透光区域,偏振光透过所述透光区域对照射的光配向薄膜进行取向;去除所述不透光区域对应的光配向薄膜,形成图形化的光配向膜。
- 根据权利要求1所述的制作方法,其中,所述偏振光透过所述透光区域对照射的光配向薄膜进行光聚合取向。
- 根据权利要求2所述的制作方法,其中,所述偏振光为紫外偏振光,照射量为500~2000mJ/cm2。
- 根据权利要求1所述的制作方法,其中,采用水、丙酮或异丙酮清洗基板,来去除所述不透光区域对应的光配向薄膜。
- 根据权利要求1所述的制作方法,其中,在所述基板上形成光配向薄膜的步骤之后,在使偏振光通过一掩膜板照射所述光配向薄膜的步骤之前还包括:对所述基板进行第一加热处理。
- 根据权利要求5所述的制作方法,其中,所述第一加热处理的温度为70℃~150℃。
- 根据权利要求5所述的制作方法,其中,所述第一加热处理的时间为60s~120s。
- 根据权利要求1所述的制作方法,其中,在使偏振光通过一掩膜板照射所述光配向薄膜的步骤之后还包括:对所述基板进行第二加热处理。
- 根据权利要求8所述的制作方法,其中,所述第二加热处理的温度为220℃~250℃。
- 根据权利要求8所述的制作方法,其中,所述第二加热处理的时间大于40min。
- 一种光配向膜,采用权利要求1-10中任一项所述的制作方法制得。
- 根据权利要求11所述的光配向膜,其中,所述光配向膜为光聚合型配向膜材料。
- 根据权利要求12所述的光配向膜,其中,所述光聚合型配向膜材料为肉桂酸酯类化合物。
- 一种液晶显示器,采用了权利要求11至13中任一项所述的光配向膜。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US14/436,793 US20160252779A1 (en) | 2014-05-30 | 2014-09-24 | Optical alignment film, its manufacturing method, and liquid crystal display device |
Applications Claiming Priority (2)
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CN201410241216.7A CN104035237B (zh) | 2014-05-30 | 2014-05-30 | 光配向膜及其制作方法、液晶显示器 |
CN201410241216.7 | 2014-05-30 |
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WO2015180326A1 true WO2015180326A1 (zh) | 2015-12-03 |
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PCT/CN2014/087314 WO2015180326A1 (zh) | 2014-05-30 | 2014-09-24 | 光配向膜及其制作方法、液晶显示器 |
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US (1) | US20160252779A1 (zh) |
CN (1) | CN104035237B (zh) |
WO (1) | WO2015180326A1 (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104035237B (zh) * | 2014-05-30 | 2017-03-01 | 京东方科技集团股份有限公司 | 光配向膜及其制作方法、液晶显示器 |
CN104280940B (zh) * | 2014-09-26 | 2017-02-08 | 京东方科技集团股份有限公司 | 一种掩膜板及取向膜摩擦方法 |
CN104808396A (zh) * | 2015-05-13 | 2015-07-29 | 京东方科技集团股份有限公司 | 一种液晶盒及其制备方法、显示装置 |
CN105511166A (zh) * | 2016-01-27 | 2016-04-20 | 京东方科技集团股份有限公司 | 一种取向设备及取向膜的制备方法、显示基板 |
CN105607349B (zh) * | 2016-03-14 | 2019-01-11 | 深圳市华星光电技术有限公司 | Pi液涂布方法 |
JP2018173541A (ja) * | 2017-03-31 | 2018-11-08 | 株式会社ジャパンディスプレイ | 配向膜の製造方法および液晶表示装置 |
JP2019184827A (ja) * | 2018-04-10 | 2019-10-24 | シャープ株式会社 | 液晶表示装置及びその製造方法 |
CN113467131B (zh) * | 2021-06-28 | 2022-05-24 | 北海惠科光电技术有限公司 | 配向膜制作方法 |
CN113552749A (zh) * | 2021-07-26 | 2021-10-26 | 信利(仁寿)高端显示科技有限公司 | 一种高精度配向膜印刷方法、掩膜板及液晶面板 |
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2014
- 2014-05-30 CN CN201410241216.7A patent/CN104035237B/zh not_active Expired - Fee Related
- 2014-09-24 US US14/436,793 patent/US20160252779A1/en not_active Abandoned
- 2014-09-24 WO PCT/CN2014/087314 patent/WO2015180326A1/zh active Application Filing
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Publication number | Publication date |
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CN104035237A (zh) | 2014-09-10 |
US20160252779A1 (en) | 2016-09-01 |
CN104035237B (zh) | 2017-03-01 |
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