WO2015162877A1 - リチウムイオン二次電池システム及びリチウム二次電池システムの運転方法 - Google Patents
リチウムイオン二次電池システム及びリチウム二次電池システムの運転方法 Download PDFInfo
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- WO2015162877A1 WO2015162877A1 PCT/JP2015/002081 JP2015002081W WO2015162877A1 WO 2015162877 A1 WO2015162877 A1 WO 2015162877A1 JP 2015002081 W JP2015002081 W JP 2015002081W WO 2015162877 A1 WO2015162877 A1 WO 2015162877A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/44—Methods for charging or discharging
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/46—Accumulators structurally combined with charging apparatus
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/48—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
- H02J7/0068—Battery or charger load switching, e.g. concurrent charging and load supply
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
- H02J7/007—Regulation of charging or discharging current or voltage
- H02J7/00711—Regulation of charging or discharging current or voltage with introduction of pulses during the charging process
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a lithium ion secondary battery system and a method for operating the lithium secondary battery system.
- the lithium ion secondary battery has a problem that the effective capacity that can be discharged decreases as the current with respect to the nominal capacity increases (see Patent Document 1).
- Patent Document 2 proposes to make the lithium ion distribution uniform. This proposal is a technique for intermittently discharging or charging a lithium ion secondary battery.
- Patent Document 3 discloses a technique for reducing internal resistance by performing pulse charge / discharge when the internal resistance of a lithium ion secondary battery exceeds a predetermined value.
- a main object of the present invention is to provide a lithium ion secondary battery system and a method for operating the lithium secondary battery system that can achieve high power efficiency and a large effective capacity.
- Continuous discharge mode for supplying electric power and pulsed power supply to the load from the lithium ion secondary battery and the lithium ion secondary from the external power source during the pulse discharge low level period when the power is not supplied to the load
- the invention relating to the operation method of the lithium ion secondary battery system that supplies power from the lithium ion secondary battery to the load includes a step of detecting the voltage of the lithium ion secondary battery and a criterion for switching the output mode. Obtaining the switching upper limit voltage, determining whether the voltage of the lithium ion secondary battery is lower than the switching upper limit voltage, and when the voltage of the lithium ion secondary battery is lower than the switching upper limit voltage, From the continuous discharge mode in which power is continuously supplied from the ion secondary battery to the load, in the pulse discharge low level period in which the power is supplied from the lithium ion secondary battery to the load in a pulsed manner and the power is not supplied to the load. Switching the output mode to a pulse charge / discharge mode in which a lithium ion secondary battery is charged in a pulse manner from an external power source; No, characterized in that.
- the discharge capacity can be improved while suppressing power loss.
- FIG. 1 is a block diagram of a lithium ion secondary battery system 2 according to the present embodiment.
- the lithium ion secondary battery system 2 includes a lithium ion secondary battery (hereinafter abbreviated as a battery) 10, a control unit 11, a current detection unit 13, a voltage detection unit 12, an input terminal T in , and an output terminal T out .
- the input terminal T in is connected an external power source 4 provided with a charging function, the load 6 is connected to the output terminal T out.
- the external power supply 4 and the load 6 are also shown.
- the load 6 may be a heater, a compressor, a motor, a cooler, or other equipment that uses a lot of current.
- the current detector 13 detects the discharge current and the charging current of the battery 10, and the voltage detector 12 detects the voltage of the battery 10.
- the output mode when power is supplied from the battery 10 to the load 6 includes a continuous discharge mode (continuous discharge mode) and a pulse discharge mode (pulse mode).
- the pulse mode includes a mode in which the battery 10 is charged by the external power source 4 when the pulse is at a low level (pulse charge / discharge mode) and a mode in which the battery 10 is not charged (pulse discharge mode). Note that the time when the pulse is at a low level is the T OFF period in FIG. 2, and this period is referred to as a pulse discharge low level period.
- FIG. 2 is a diagram illustrating a discharge current waveform to the load 6 and a charge current waveform to the battery 10.
- ID_1 is an average discharge current supplied to the load 6 in the continuous discharge mode
- ID_2 is a peak value of the pulse current supplied to the load 6 in the pulse charge / discharge mode
- IC is the peak value of the pulse current supplied to the battery 10 in the pulse charge / discharge mode.
- ID_1 is described as continuous discharge current
- ID_2 is described as pulse discharge current
- IC is described as pulse charge current.
- Equation 1 is the time of one cycle of pulse discharge, and the power supplied to the load 6 by pulse discharge (ID_2 * T ON ) and the power supplied to the load 6 by continuous discharge (ID_1 * (T ON + T OFF ) ) Is equal.
- the pulse charge / discharge mode is performed when the voltage V B of the battery 10 is a value between the switching upper limit voltage V U and the switching lower limit voltage V L.
- the output mode is switched from the continuous discharge mode to the pulse charge / discharge mode.
- the voltage V B becomes lower than the switching lower limit voltage V L , so that the pulse charge / discharge mode is switched to the continuous discharge mode.
- FIG. 3 shows the result of simulating the discharge capacity depending on the output mode (continuous discharge mode, pulse discharge mode, pulse charge / discharge mode).
- the horizontal axis represents the discharge capacity, and the vertical axis represents the closed circuit voltage of the battery.
- the simulation conditions are as follows: discharge capacity when battery 10 having a capacity of 32.5 Ah is set to 3.0 V, discharge capacity when continuously discharging at 6.25 C (curve C_10), discharge capacity when performing pulse discharge (Curve (C_11), the discharge capacity (curve C_12) at the time of pulse charge / discharge.
- the discharge capacity in the continuous discharge mode was 12.94 Ah
- the discharge capacity in the pulse discharge mode was 22.73 Ah
- the discharge capacity is improved by 1.23 times compared to the case of the pulse discharge mode. From the above, it was confirmed that the discharge capacity can be greatly improved by changing the mode from the continuous discharge mode to the pulse charge mode.
- the timing for changing the mode is important from the viewpoint of suppressing switching loss (improvement of power efficiency).
- the switching upper limit voltage V U and the switching lower limit voltage V L are set, the pulse charge / discharge mode is set when the voltage of the battery 10 is within the range, and the continuous discharge mode is set otherwise. To do.
- FIG. 4 is a diagram illustrating the open circuit voltage V O or the closed circuit voltage V C , the reference voltage V R , the switching upper limit voltage V U , the switching lower limit voltage V L , and the discharge end voltage V T with respect to the discharge capacity. .
- the shaded area in FIG. 4 indicates a range where the switching lower limit voltage V L ⁇ V B ⁇ switching upper limit voltage V U is satisfied. That is, the pulse charge / discharge mode is performed when the voltage V B of the battery 10 is within this range.
- V U V U * ⁇ (2)
- V R is the output current flowing between T out terminals as I
- V R V x ⁇ (I ⁇ I x ) * R O (3)
- Is a reference voltage defined by This reference voltage is a voltage obtained by subtracting the voltage drop due to the internal resistance from the electromotive force of the battery 10 and corresponds to the terminal voltage of the battery 10.
- V x is the open circuit voltage V O of the battery 10 or the closed circuit voltage V C of the battery 10 during low rate (1C or less) discharge.
- V x V O
- I x is the current I O when V O is detected
- V x V C
- I x is the current I C when V C is detected.
- alpha is allowable value indicating the permitted deviation of the degree of the voltage from the reference voltage V R at (ratio) is preferably alpha ⁇ 0.9 Simulation results described below.
- FIG. 5 is a diagram illustrating a result when the discharge capacity is simulated by changing the allowable value ⁇ .
- curve C_2 is a characteristic curve of the reference voltage V R at the time of 3C discharge capacity 32.30Ah.
- curve C_6 is 2 and the discharge capacity characteristic at the time of 3C continuous discharge at a discharge capacity of 5.91 Ah.
- the allowable value ⁇ when the allowable value ⁇ is set to a value larger than 0.9000 and the pulse charge / discharge mode is changed, the discharge capacities of the curves C_3 to C_5 are 2% of the discharge capacity of the curve C_1. It can be seen that it fits within.
- the allowable value ⁇ is preferably set to a value larger than 0.9000 in order to improve the discharge capacity.
- the allowable value ⁇ when a semiconductor switch is used as a switching means for performing the pulse charge / discharge mode, the allowable value ⁇ is set to ⁇ 0.9000 in order to minimize the power loss in the semiconductor switch. It is good to do.
- the switching lower limit voltage V L is a value obtained by adding a voltage drop ⁇ V due to pulse discharge to the discharge end voltage V T of the battery 10.
- V L V T + ⁇ V (4)
- the pulse discharge current is controlled so that the average value (average current) of the pulse discharge current over one cycle matches the continuous discharge current (when the relationship of Equation 1 is satisfied)
- the peak value in the pulse discharge mode is continuous. It becomes higher than the discharge current (ID_2> ID_1).
- a large current from Ohm's law means that the voltage drops. Therefore, when the continuous discharge current ID_1 and the pulse discharge current ID_2 are set so that the expression 1 is satisfied, the discharge end voltage is hit with a high discharge capacity. Therefore, when the voltage V B of the battery 10 becomes lower than the switching lower limit voltage V L (V B ⁇ V L ), the control unit 11 switches from the pulse charge / discharge mode to the continuous discharge mode, suppresses the peak current, and reaches the discharge end voltage. And thereby increase the discharge capacity.
- FIG. 6 is a flowchart showing the mode control procedure.
- Steps S1 and S2 First, the control unit 11 obtains the voltage V B of the battery 10 from the voltage detection unit 12. Then, it is determined whether or not voltage V B is higher than end-of-discharge voltage V T. When the voltage V B is equal to or lower than the end-of-discharge voltage V T (V B ⁇ V T ), it means that the battery 10 has no available capacity, and the process ends abnormally. Of course, at this time, the control unit 11 can also output a message indicating that the capacity is insufficient.
- Steps S3 and S4 When the discharge capacity of the battery 10 is sufficient (V B > V T ), the control unit 11 performs discharge in the continuous discharge mode, and acquires the current I at that time from the current detection unit 13. .
- Step S5 Next, a switching upper limit voltage value V U and a switching lower limit voltage value V L are calculated.
- the switching upper limit voltage value V U and the switching lower limit voltage value V L are described as being calculated when the processing is started, but are calculated in advance and stored in a memory or the like. Is also possible. A method for calculating the switching upper limit voltage value V U and the switching lower limit voltage value V L will be described later.
- Steps S6 and S7 The controller 11 sets the output mode to the continuous discharge mode and starts discharging. At the same time as the start of discharge, the current voltage V B of the battery 10 is acquired.
- Step S8 Thereafter, the control unit 11 determines whether or not the acquired voltage V B is between the switching upper limit voltage value V U and the switching lower limit voltage value V L.
- Step S9 When the voltage V B is between the switching upper limit voltage value V U and the switching lower limit voltage value V L (V L ⁇ V B ⁇ V U ), the output mode is changed to the pulse charge / discharge mode. Return to step S7.
- Step S10 On the other hand, when the voltage V B is not between the switching upper limit voltage value V U and the switching lower limit voltage value V L (V B ⁇ V T , V B > V U ), the voltage V B is determining whether the discharge cutoff voltage greater than V T being set. At this time, when the voltage V B is higher than the end-of-discharge voltage V T (V B > V T ), the process returns to step S6 to set the continuous discharge mode. On the other hand, when the voltage V B is equal to or lower than the end-of-discharge voltage V T (V B ⁇ V T ), the discharge ends.
- pulse charge from the external power supply 4 was performed in all pulse discharge low level periods.
- the present invention is not limited to this, and for example, pulse charging as shown in FIGS. 7 and 8 is also possible.
- pulse charging is performed only during a part of the period T 1 instead of the entire period of the pulse discharge low level period T 0 (T 0 > T 1 ).
- pulse charging is performed in at least one pulse discharge low level period among a plurality of pulse discharge low level periods.
- Which method is to be used may be appropriately set according to the capacity of the external power supply 4 or a desired discharge current.
- the switching upper limit voltage VU is calculated by Equation 2.
- the present invention is not limited to this method.
- the slope of the discharge capacity characteristic during continuous discharge may be set as a value when it reaches a predetermined value.
- An example of the slope m is a range in which diffusion resistance due to non-uniformity of lithium ions does not occur, and ⁇ 0.1 ⁇ m ⁇ ⁇ 0.02.
- the continuous discharge mode is switched to the pulse charge / discharge mode, and when the switching lower limit voltage V L is reached, the pulse charge / discharge mode is continuously discharged. Switch to mode. Thereby, it becomes possible to obtain the same operation effect as 1st Embodiment.
- Lithium ion secondary battery system Lithium ion secondary battery system 4 External power supply 6 Load 10 Battery 11 Control unit 12 Voltage detection unit 13 Current detection unit
Abstract
Description
<第1実施形態>
図1は、本実施形態にかかるリチウムイオン二次電池システム2のブロック図である。リチウムイオン二次電池システム2は、リチウムイオン二次電池(以下、電池と略記する)10、制御部11、電流検出部13、電圧検出部12、入力端子Tin、出力端子Toutを含む。
ID_2=ID_1*(TON+TOFF)/TON … (1)
の式1を満たすように設定する。式1は、パルス放電の1サイクルの時間で、パルス放電により負荷6に供給される電力(ID_2*TON)と、連続放電により負荷6に供給される電力(ID_1*(TON+TOFF))とを等しくすることを意味している。
VU=VR*α … (2)
の式2で定義する。
VRは、Tout端子間を流れる出力電流をIとして、
VR=Vx-(I-Ix)*RO … (3)
で定義される基準電圧である。この基準電圧は、電池10の起電力から内部抵抗による電圧降下分を差し引いた電圧で、電池10の端子電圧に相当する。
VL=VT+ΔV … (4)
の式4で定義する。このとき、降下電圧ΔVは、
ΔV=(ID_2-ID_1)*RO*β … (5)
で定義する。但し、βは比例係数で、β=1.0~1.2が望ましい。
<第2実施形態>
次に、第2実施形態を説明する。なお、上述した第1実施形態と同一構成に関しては、同一符号を用いて説明を適宜省略する。
この出願は、2014年4月24日に出願された日本出願特願2014-089704を基礎とする優先権を主張し、その開示の全てをここに取り込む。
4 外部電源
6 負荷
10 電池
11 制御部
12 電圧検出部
13 電流検出部
Claims (16)
- リチウムイオン二次電池から負荷に電力供給するリチウムイオン二次電池システムであって、
前記リチウムイオン二次電池を充電する外部電源と、
前記リチウムイオン二次電池から前記負荷に連続的に電力供給する連続放電モード、及び、前記リチウムイオン二次電池から前記負荷にパルス的に電力供給し、かつ、前記負荷に電力供給されていないパルス放電ローレベル期間のときに前記外部電源から前記リチウムイオン二次電池にパルス的に充電するパルス充放電モードの出力モード切り替えを行う制御手段と、を備え、
前記制御手段は、
前記リチウムイオン二次電池の電圧が、所定の切替上限電圧より低い場合には、前記出力モードを前記パルス充放電モードに設定する、
ことを特徴とするリチウムイオン二次電池システム。 - 請求項1に記載のリチウムイオン二次電池システムであって、
前記電圧が前記切替上限電圧より高い場合、及び、所定の切替下限電圧より低い場合には、前記出力モードを前記連続放電モードに設定する、
ことを特徴とするリチウムイオン二次電池システム。 - 請求項1又は2に記載のリチウムイオン二次電池システムであって、
前記パルス充放電モードでは、前記パルス放電ローレベル期間の少なくとも1つの期間内で、前記外部電源から前記リチウムイオン二次電池に充電が行われる、
ことを特徴とするリチウムイオン二次電池システム。 - 請求項1乃至3のいずれか1項に記載のリチウムイオン二次電池システムであって、
前記パルス放電ローレベル期間で行われる前記外部電源から前記リチウムイオン二次電池システムへの充電時間は、前記パルス放電ローレベル期間より短い、
ことを特徴とするリチウムイオン二次電池システム。 - 請求項1乃至4のいずれか1項に記載のリチウムイオン二次電池システムであって、
前記パルス充放電モードにおける1サイクルにわたるパルス放電電流の平均値と前記連続放電モードにおける連続放電電流とが、同じ値になるように、前記平均値を設定した、
ことを特徴とするリチウムイオン二次電池システム。 - 請求項1乃至5のいずれか1項に記載のリチウムイオン二次電池システムであって、
前記切替上限電圧は、前記リチウムイオン二次電池から電力を取り出す際の最大の電圧である基準電圧の0.90~0.98倍の値に設定されている、
ことを特徴とするリチウムイオン二次電池システム。 - 請求項1乃至5のいずれか1項に記載のリチウムイオン二次電池システムであって、
前記切替上限電圧は、放電容量に対する前記リチウムイオン二次電池の電圧の変化率mが、-0.1≦m≦-0.02の範囲になるときの前記リチウムイオン二次電池の電圧に設定した、
ことを特徴とするリチウムイオン二次電池システム。 - 請求項2乃至7のいずれか1項に記載のリチウムイオン二次電池システムであって、
前記切替下限電圧は、前記リチウムイオン二次電池の放電終止電圧とパルス放電を行った際の降下電圧との和の値に設定した、
ことを特徴とするリチウムイオン二次電池システム。 - リチウムイオン二次電池から負荷に電力供給するリチウムイオン二次電池システムの運転方法であって、
前記リチウムイオン二次電池の電圧を検出し、
出力モードの切替を行う際の判断基準をなす切替上限電圧を取得し、
前記リチウムイオン二次電池の電圧が切替上限電圧より低いか否かを判断し、
前記リチウムイオン二次電池の電圧が切替上限電圧より低い場合に、前記リチウムイオン二次電池から前記負荷に連続的に電力供給する連続放電モードから、前記リチウムイオン二次電池から前記負荷にパルス的に電力供給し、かつ、前記負荷に電力供給されていないパルス放電ローレベル期間のときに前記外部電源から前記リチウムイオン二次電池にパルス的に充電するパルス充放電モードに出力モード切替を行う、
ことを特徴とするリチウムイオン二次電池システムの運転方法。 - 請求項9に記載のリチウムイオン二次電池システムの運転方法であって、
前記運転方法は、さらに、
出力モードの切替を行う際の判断基準をなす切替下限電圧を取得し、
前記リチウムイオン二次電池の電圧が前記切替上限電圧より高い場合、及び、所定の切替下限電圧より低い場合には、前記出力モードを前記連続放電モードに設定する
ことを特徴とするリチウムイオン二次電池システムの運転方法。 - 請求項9又は10に記載のリチウムイオン二次電池システムの運転方法であって、
前記パルス充放電モードでは、前記パルス放電ローレベル期間の少なくとも1つの期間内で、前記外部電源から前記リチウムイオン二次電池に充電が行なわれる、
ことを特徴とするリチウムイオン二次電池システムの運転方法。 - 請求項9乃至11のいずれか1項に記載のリチウムイオン二次電池システムの運転方法であって、
前記パルス放電ローレベル期間で行われる前記外部電源から前記リチウムイオン二次電池システムの運転方法への充電時間は、前記パルス放電ローレベル期間より短い、
ことを特徴とするリチウムイオン二次電池システムの運転方法。 - 請求項9乃至12のいずれか1項に記載のリチウムイオン二次電池システムの運転方法であって、
前記パルス充放電モードにおける1サイクルにわたるパルス放電電流の平均値と前記連続放電モードにおける連続放電電流とが、同じ値になるように、前記平均値が設定されている、
ことを特徴とするリチウムイオン二次電池システムの運転方法。 - 請求項9乃至13のいずれか1項に記載のリチウムイオン二次電池システムの運転方法であって、
前記切替上限電圧は、前記リチウムイオン二次電池から電力を取り出す際の最大の電圧である基準電圧の0.90~0.98倍の値に設定されている、
ことを特徴とするリチウムイオン二次電池システムの運転方法。 - 請求項9乃至13のいずれか1項に記載のリチウムイオン二次電池システムの運転方法であって、
放電容量に対する前記リチウムイオン二次電池の電圧の変化率mが、-0.1≦m≦-0.02の範囲になるときの前記リチウムイオン二次電池の電圧を前記切替上限電圧に設定した、
ことを特徴とするリチウムイオン二次電池システムの運転方法。 - 請求項10乃至15のいずれか1項に記載のリチウムイオン二次電池システムの運転方法であって、
前記切替下限電圧は、前記リチウムイオン二次電池の放電終止電圧とパルス放電を行った際の降下電圧との和の値に設定した、
ことを特徴とするリチウムイオン二次電池システムの運転方法。
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US15/305,730 US20170054184A1 (en) | 2014-04-24 | 2015-04-15 | Lithium ion secondary battery system and lithium secondary battery system operation method |
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US10756557B2 (en) | 2015-12-01 | 2020-08-25 | Fuji Electric Co., Ltd. | Charge apparatus to repeatedly apply a pulsed high voltage and a low voltage to charge a battery |
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US10594150B2 (en) | 2015-04-24 | 2020-03-17 | Manodya Limited | Pulse discharge system |
KR102441469B1 (ko) | 2017-11-13 | 2022-09-06 | 주식회사 엘지에너지솔루션 | 배터리 충전 방법 및 배터리 충전 장치 |
GB2570356B (en) * | 2018-05-29 | 2020-01-15 | Manodya Ltd | A pulse discharge system |
DE102018211264A1 (de) * | 2018-07-09 | 2020-01-09 | Volkswagen Aktiengesellschaft | Verfahren zum Laden einer Batterie und Steuereinheit |
US20230018424A1 (en) * | 2021-07-14 | 2023-01-19 | Sk On Co., Ltd. | Method for charging and discharging battery |
CN114301114A (zh) * | 2021-12-10 | 2022-04-08 | 华为数字能源技术有限公司 | 锂电池、锂电系统及控制方法 |
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JP2004236381A (ja) * | 2003-01-28 | 2004-08-19 | Honda Motor Co Ltd | 蓄電池の充放電制御装置および車両用蓄電池の充放電制御装置 |
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US5595839A (en) * | 1994-10-13 | 1997-01-21 | Yardney Technical Products, Inc. | Bipolar lithium-ion rechargeable battery |
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JP2001102093A (ja) * | 1999-09-30 | 2001-04-13 | Fujitsu Ltd | 二次電池の劣化防止方法、並びにこの方法を実施するための充電器および電子機器 |
JP2004236381A (ja) * | 2003-01-28 | 2004-08-19 | Honda Motor Co Ltd | 蓄電池の充放電制御装置および車両用蓄電池の充放電制御装置 |
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US10756557B2 (en) | 2015-12-01 | 2020-08-25 | Fuji Electric Co., Ltd. | Charge apparatus to repeatedly apply a pulsed high voltage and a low voltage to charge a battery |
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