WO2015131684A2 - 一种玻璃纤维组合物及其玻璃纤维和复合材料 - Google Patents
一种玻璃纤维组合物及其玻璃纤维和复合材料 Download PDFInfo
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- WO2015131684A2 WO2015131684A2 PCT/CN2015/071153 CN2015071153W WO2015131684A2 WO 2015131684 A2 WO2015131684 A2 WO 2015131684A2 CN 2015071153 W CN2015071153 W CN 2015071153W WO 2015131684 A2 WO2015131684 A2 WO 2015131684A2
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- Prior art keywords
- glass
- cao
- mgo
- glass fiber
- weight percentage
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
- B32B17/04—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments bonded with or embedded in a plastic substance
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/0092—Compositions for glass with special properties for glass with improved high visible transmittance, e.g. extra-clear glass
Definitions
- the present invention relates to a glass fiber composition, and more particularly to a high performance glass fiber composition capable of reinforcing a substrate as an advanced composite material, and glass fibers and composite materials thereof.
- Glass fiber is an inorganic fiber material, and it can be used to reinforce a resin to obtain a composite material with excellent properties.
- high-performance glass fiber was originally used in the defense, military and other fields of defense, military and other fields. With the advancement of technology and economic development, high-performance glass fiber has been widely used in civil and industrial fields such as motors, wind blades, pressure vessels, offshore oil pipelines, sports equipment, and the automotive industry.
- Performance glass typical solutions such as French R glass and American HiPer-tex glass, is a compromise strategy to sacrifice part of the glass performance in exchange for production scale, but because the design is too conservative, especially to maintain Al 2 O 3 content More than 20%, preferably 25%, the production difficulty is still very high, although the realization of small-scale pool kiln production, but the production efficiency is low, the product cost is not high.
- the conventional R glass is difficult to form, the molding temperature reaches about 1410 ° C, and the liquidus temperature reaches 1330 ° C, which also causes difficulty in drawing glass fiber, and it is also difficult to achieve large-scale industrial production.
- R glass fiber which has slightly lower mechanical properties than conventional R glass fiber, and has better melting and forming properties than conventional R glass fiber.
- the glass is analyzed. The crystal risk is large, and too much Li 2 O is introduced, which not only affects the chemical stability of the glass, but also increases the cost of raw materials, and is not conducive to large-scale industrial production.
- the main components of high-strength 2# glass fiber also include SiO 2 , Al 2 O 3 , MgO, and also introduce some parts of Li 2 O, B 2 O 3 , CeO 2 and Fe 2 O 3 , which also have high strength and Modulus, and its molding temperature is only about 1245 ° C, the liquidus temperature is 1320 ° C, the temperature of both is much lower than S glass fiber, but its molding temperature is lower than the liquidus temperature, but it is not good for glass fiber. Drawing, the drawing temperature must be increased, and a special form of the leaking nozzle is used to prevent the glass from devitrifying during the drawing process, which causes difficulty in temperature control and is difficult to achieve large-scale industrial production.
- the liquidus temperature of the glass is high and the risk of crystallization is large.
- the liquidus temperature of the mainstream E glass is generally lower than 1200 ° C
- the liquidus temperature of the above high performance glass is generally higher than 1300 ° C, which causes the glass crystallization phenomenon to occur easily in the production process, thereby greatly reducing the glass.
- the present invention is directed to solving the problems described above.
- the object of the present invention is to provide a high-performance glass fiber composition which overcomes the high liquidus temperature and the devitrification rate of the conventional high-performance glass on the basis of high mechanical properties and low molding temperature.
- Fast, prone to glass crystallization, difficult to carry out large-scale high-efficiency production significantly lower the liquidus temperature of high-performance glass, increase the crystallization peak temperature of glass, and reduce the crystallization degree of glass under the same conditions
- it has excellent refractive index of glass, which greatly improves the permeability of glass fiber products.
- a glass fiber composition comprising the following components, the content of each component being expressed by weight percentage as follows:
- the content of CaO is expressed by weight percentages of more than 10.5% and less than 11.8%.
- a glass fiber made of the above glass fiber composition.
- a composite material comprising the glass fibers described above.
- the glass fiber composition of the present invention by introducing appropriate amounts of SrO and Li 2 O, the content ranges of CaO, MgO and SrO, the ratio range of (MgO+SrO)/CaO and CaO/MgO, and the utilization of CaO, MgO and
- the SrO ternary mixed alkaline earth effect overcomes the high temperature of the liquidus in the traditional high performance glass and the crystallization rate is fast on the basis of ensuring the high mechanical properties and low molding temperature of the glass fiber, which is prone to glass crystallization and is difficult to be formed.
- the problem of large-scale high-efficiency production significantly reduces the liquidus temperature of high-performance glass, increases the crystallization peak temperature of glass, reduces the crystallization degree of glass under the same conditions, and has excellent refractive index of glass. Improve the permeability of glass fiber products.
- the glass fiber composition according to the present invention contains the following components, and the content of each component is expressed by weight percentage as follows:
- the functions and contents of the components in the glass fiber composition are as follows:
- SiO 2 is the main oxide forming the glass skeleton and functions to stabilize the components.
- the content of SiO 2 is limited to 58-64%, and if the content is too low, the mechanical properties of the glass are affected; if the content is too high, the viscosity of the glass is too high to cause melting, Clarify the difficulties.
- the content of SiO 2 may be limited to 59-62%. More preferably, the content of SiO 2 may be limited to 59-61.5%.
- Al 2 O 3 is also an oxide forming a glass skeleton. When combined with SiO 2 , it can play a substantial role in the mechanical properties of the glass and plays an important role in preventing phase separation and water resistance of the glass.
- the content of Al 2 O 3 is limited to 14-19%, and if it is low in content, high enough mechanical properties of the glass, especially modulus, cannot be obtained; if the content is too high, The viscosity of the glass is too high, which makes melting and clarification difficult.
- the content of Al 2 O 3 may be limited to 14.5-18%. More preferably, the content of Al 2 O 3 may be limited to 14.5-16.5%.
- CaO, MgO and SrO mainly function to control glass crystallization, adjust glass viscosity and material properties.
- the inventors obtained unexpected effects by controlling their introduction amount and proportional relationship.
- high-performance glass mainly composed of MgO-CaO-Al 2 O 3 -SiO 2 system
- the crystal phase contained in the glass after crystallization is mainly composed of diopside (CaMgSi 2 O 6 ) and anorthite ( CaAl 2 Si 2 O 8 ).
- the ratio of CaO/MgO can be reasonably controlled, and the molar ratio of Ca 2+ /Mg 2+ ions can be reduced.
- the apparent lack of Ca 2+ ions in the crystallization process of the two crystal phases can significantly reduce the crystallization rate and grain integrity of the two crystal phases, thereby simultaneously inhibiting the crystallization tendency of the two crystal phases and lowering the liquid phase.
- the purpose of the line temperature it is surprising to the inventor that when both techniques are used simultaneously, the overall technical effect produced is significantly greater than a simple superposition using a single technical means.
- the crystallization process of glass is actually the process of nucleation and continuous growth, which is the process of reorganization and reorganization of various atoms in glass.
- the ternary alkaline earth system designed in the invention is more likely to realize the close packing of the glass structure, and at the same time, due to the large ionic radius of Sr 2+ , it is not only difficult to move by itself, but also can effectively block Mg 2+ and Ca 2+ ions under the same conditions.
- the mobile recombination achieves the purpose of suppressing the tendency of crystallization and reducing the rate of crystallization. Therefore, the glass fiber composition of the present invention can obtain more excellent glass crystallization properties.
- the ternary mixed alkaline earth effect of CaO, MgO and SrO is comprehensively considered and the appropriate SrO content is selected to enable lower crystallization upper limit temperature and crystallization degree, higher mechanical properties and glass refractive index.
- the large molecular weight of cerium oxide due to the large molecular weight of cerium oxide, excessive introduction will increase the density of the glass, and have a certain negative impact on the specific strength and specific modulus of the glass fiber.
- the /CaO range is 0.75-1.1.
- the content of SrO ranges from 0.5 to 2%
- the content of CaO ranges from >10.5% and ⁇ 11.8%
- the content of MgO ranges from 8 to 10.5%
- the ratio of weight percentage C1 (MgO + SrO) / CaO
- the range is 0.8-1. More preferably, the content of CaO ranges from 10.6-11.7%, and the content of MgO ranges from 8 to 10%.
- the crystal phase contained in the high-performance glass mainly composed of MgO-CaO-Al 2 O 3 -SiO 2 system mainly includes diopside (CaMgSi 2 O 6 ) and anorthite (CaAl 2 Si 2 O 8 ). .
- the molecular formula Ca 2+ /Mg 2+ molar ratio of diopside is 1.
- anorthite is also An environment rich in Ca 2+ is needed to grow quickly.
- the approximate ratio of Ca 2+ /Mg 2+ molar ratio (2 points after the decimal point) is greater than 1.14. And 1.42. In this case, it is sufficient to ensure that the two crystal phases are completely and rapidly growing Ca 2+ and Mg 2+ ions. Therefore, although the ratio of the two crystal phases in the final crystallization product changes, it cannot be achieved. At the same time, the effect of growth of the two crystal phases is suppressed.
- the inventors have unexpectedly discovered that in the glass fiber composition of the present invention, when the CaO/MgO ratio is controlled to be less than 1.4, especially less than 1.3, the approximate ratio of Ca 2+ /Mg 2+ molar ratio is less than 1 respectively.
- the CaO/MgO ratio in conventional high performance glass is greater than 1.6 and 2
- its glass liquidus temperature and crystallization degree are significantly reduced.
- the significant decrease in the degree of crystallization of the crystal phase is manifested by the significant decrease in the intensity of the X-ray diffraction peak, and the grain morphology of the diopside in the SEM scan of the crystal phase changes from column to rod to slender needle.
- MgO can provide much more oxygen than CaO, which is beneficial to the formation of tetrahedral with more aluminum ions.
- the position, enhanced network structure of the glass system, can further reduce the crystallization tendency of the glass.
- the CaO/MgO ratio should not be too low, otherwise the magnesium ions will be excessively large, which will enhance the crystallization tendency of the new crystalline olivine (Mg 2 Si 2 O 6 ) to some extent, so the CaO/MgO ratio is preferred. It is preferably greater than 1 and less than 1.3.
- the content of SrO is controlled in the range of 0.5 to 2%
- the content of CaO is in the range of >10.5% and ⁇ 11.8%, MgO.
- the content ranges from 8 to 10.5%
- the ion deposition effect between the oxides is extremely tight, the glass structure is particularly stable, and the inhibition of Sr 2+ ions and the lack of Ca 2+ ions further suppress the crystallization tendency of the two crystal phases, thereby making the glass have a significantly reduced liquid. Phase temperature and crystallization degree. This technical effect is unexpected compared to traditional high performance glass.
- both K 2 O and Na 2 O reduce the viscosity of the glass and are good fluxing agents.
- replacing Na 2 O with K 2 O can reduce the crystallization tendency of the glass and improve the fiber forming property; and can also lower the surface tension of the glass liquid and improve the glass melting performance.
- the content of Na 2 O + K 2 O is limited to a range of from 0.1 to 2%.
- the content of Na 2 O+K 2 O ranges from 0.1 to 1%.
- Fe 2 O 3 is advantageous for the melting of glass and also for improving the crystallization properties of glass.
- the content of Fe 2 O 3 is limited to a range of 0.05 to 1%.
- the content of Fe 2 O 3 ranges from 0.05 to 0.7%
- TiO 2 not only reduces the viscosity of the glass at high temperatures, but also has a certain fluxing effect. However, since the titanium ion has a certain coloring effect, especially when the TiO 2 content exceeds 1.1%, the coloring effect becomes particularly remarkable, and the appearance of the glass fiber product is affected to some extent. Therefore, in the glass fiber composition of the present invention, the content of TiO 2 is limited to a range of 0.05 to 1.1%. Preferably, the content of TiO 2 ranges from 0.05 to 0.8%.
- Li 2 O Compared with Na 2 O and K 2 O, Li 2 O not only can significantly reduce the viscosity of the glass, thereby improving the glass melting performance, and is obviously helpful for improving the mechanical properties of the glass. At the same time, a small amount of Li 2 O can provide considerable free oxygen, which is beneficial to the formation of tetrahedral coordination of more aluminum ions, enhance the network structure of the glass system, and further reduce the crystallization ability of the glass. Considering the high cost of Li 2 O, it is not advisable to introduce too much. Therefore, in the glass fiber composition of the present invention, the content of Li 2 O is limited to a range of 0.05 to 0.9%. Preferably, the Li 2 O content ranges from 0.05 to 0.7%.
- the glass fiber composition of the present invention is also allowed to contain a small amount of fluorine (F 2 ), and the content of F 2 is limited to less than 0.5%.
- F 2 fluorine
- the content of F 2 is limited to less than 0.5%.
- the glass fiber composition according to the present invention contains the following components, and the content of each component is expressed by weight percentage as follows:
- the glass fiber composition according to the present invention contains the following components, and the content of each component is expressed by weight percentage as follows:
- the glass fiber composition according to the present invention contains the following components, and the content of each component is expressed by weight percentage as follows:
- the glass obtained according to the composition of the preferred example 3 has excellent mechanical properties, and generally has a Young's modulus of more than 84 GPa and less than 91.5 GPa.
- the glass density is estimated according to, in general, their specific Young's modulus greater than 32MPa / (kg / m 3) and less than 35.5MPa / (kg / m 3) .
- the glass fiber composition according to the invention can overcome the problem that the high-performance glass liquidus temperature is high, the crystallization rate is too fast, the glass crystallization phenomenon is easy to occur, the large-scale high-efficiency production is difficult to be performed, and the high-performance glass is remarkably lowered.
- the liquidus temperature increases the crystallization peak temperature of the glass, reduces the crystallization degree of the glass under the same conditions, and has an excellent refractive index of the glass, which greatly improves the permeability of the glass fiber product.
- the molding temperature corresponds to the temperature at which the glass melt has a viscosity of 10 3 poise.
- the liquidus temperature corresponds to the temperature at which the crystal nucleus begins to form when the glass melt is cooled, that is, the upper limit temperature of the glass crystallization.
- the temperature of the crystallization peak which corresponds to the temperature of the strongest peak of glass crystallization during the DTA test.
- the higher the temperature the more energy is required to grow the crystal nucleus, and the crystallization tendency of the glass is smaller.
- Refractive index the ratio of the speed of light in air to the speed of light in the glass.
- Young's modulus which is the elastic modulus along the longitudinal direction, characterizing the ability of the glass to resist elastic deformation.
- the above six parameters and their measurement methods are well known to those skilled in the art, and therefore the above parameters can strongly explain the properties of the glass fiber composition of the present invention.
- the inventors also observed the type, morphology and crystallization of the crystal phase by means of an X-ray diffractometer and an electron scanning electron microscope.
- each component can be obtained from a suitable raw material, and various raw materials are mixed in proportion to achieve the final expected weight percentage of each component, and the mixed batch material is melted and clarified, and then the glass liquid
- the glass fiber is formed by the leaking nozzle on the drain plate being pulled out, and the glass fiber is drawn around the rotating head of the wire drawing machine to form a raw silk cake or a yarn group.
- these glass fibers can be further processed in a conventional manner to meet the expected requirements.
- the content of the glass fiber composition is expressed by weight percentage. It should be noted that the total content of the components of the examples is slightly less than 100%, and it can be understood that the residual amount is a trace impurity or a small component which cannot be analyzed.
- the glass fiber composition of the present invention has the following advantages as compared with the conventional R glass and the modified R glass: (1) having a much lower liquidus temperature, which is advantageous for lowering the glass. Crystal risk, improve the drawing efficiency of the fiber; (2) have a higher crystallization peak temperature, which indicates that the formation and growth of the nucleus during the crystallization process requires more energy, that is, the invention under the same conditions The crystallization of glass is less risky. (3) The crystallinity of the crystal phase is low, the grain size is small, and the arrangement is irregular. This indicates that the crystallization of the glass of the present invention is weaker under the same conditions, further reducing the risk of crystallization of the glass.
- the effect of the embodiment which simultaneously satisfies the preferred ranges of the ratios C1 and C2 is more significant.
- the refractive index of the glass with a marked improvement.
- the glass fiber composition of the invention has a higher modulus than the modified R glass, which indicates that the close-packed structure obtained by the ternary alkaline earth effect designed by the invention also greatly promotes the mechanical properties of the glass.
- the glass fiber composition of the present invention has similar crystallization properties and molding properties, and meets the requirements for efficient production of large-scale pool kiln.
- the glass fiber composition of the present invention has made a breakthrough in the improvement of the crystallization property and the refractive index of the R-grade glass. Under the same conditions, the risk of crystallization of the glass is greatly reduced, the refractive index is significantly improved, and the overall technology
- the crystallization and molding properties of the solution are similar to those of the mainstream boron-free E-glass, making it easy to achieve efficient production of large-scale kiln.
- Glass fibers having the above-described excellent properties can be produced from the glass fiber composition according to the present invention.
- the glass fiber composition according to the present invention can be combined with one or more organic and/or inorganic materials to produce a composite material having excellent properties, for example, a glass fiber reinforced substrate.
- the glass fiber composition of the invention overcomes the high temperature of the liquidus of the traditional high performance glass, the crystallization rate is too fast, and the crystallization of the glass is easy to occur, which is difficult to achieve on the basis of ensuring high mechanical properties and low molding temperature of the glass fiber.
- the problem of large-scale high-efficiency production significantly reduces the liquidus temperature of high-performance glass, increases the crystallization peak temperature of glass, reduces the crystallization degree of glass under the same conditions, and has excellent refractive index of glass. Improve the permeability of glass fiber products.
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Abstract
Description
Claims (9)
- 根据权利要求1所述的玻璃纤维组合物,其特征在于,重量百分比的比值C2=CaO/MgO的范围为大于1且小于1.3。
- 根据权利要求1或2所述的玻璃纤维组合物,其特征在于,重量百分比的比值C1=(MgO+SrO)/CaO的范围为0.8-1。
- 根据权利要求1或2所述的玻璃纤维组合物,其特征在于,CaO的含量以重量百分比表示为大于10.5%且小于11.8%。
- 一种玻璃纤维,其特征在于,所述玻璃纤维由如权利要求1-8中任一项所述的玻璃纤维组合物制成。
- 一种复合材料,其特征在于,所述复合材料包括如权利要求9所述的玻璃纤维。
Priority Applications (19)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MA40158A MA40158A1 (fr) | 2015-01-20 | 2015-01-20 | Composition de fibre de verre, fibre de verre et matériau composite la contenant |
JP2017530177A JP6411657B2 (ja) | 2015-01-20 | 2015-01-20 | ガラス繊維組成物及びガラス繊維、並びに複合材料 |
PT15757761T PT3093276T (pt) | 2015-01-20 | 2015-01-20 | Composição de fibra de vidro, fibra de vidro e o seu material compósito |
SI201530504T SI3093276T1 (sl) | 2015-01-20 | 2015-01-20 | Sestavek steklenega vlakna in stekleno vlakno ter kompozitni material le-tega |
CA2942671A CA2942671C (en) | 2015-01-20 | 2015-01-20 | A glass fiber composition, glass fiber and composite material therefrom |
PCT/CN2015/071153 WO2015131684A2 (zh) | 2015-01-20 | 2015-01-20 | 一种玻璃纤维组合物及其玻璃纤维和复合材料 |
RU2017111504A RU2667170C1 (ru) | 2015-01-20 | 2015-01-20 | Композиция стекловолокна, стекловолокно и содержащий его композиционный материал |
BR112016019954-5A BR112016019954B1 (pt) | 2015-01-20 | 2015-01-20 | Composição de fibra de vidro, fibra de vidro e material compósito do mesmo |
MX2017007618A MX2017007618A (es) | 2015-01-20 | 2015-01-20 | Una composicion de fibra de vidrio, fibra de vidrio y material compuesto de la misma. |
EP15757761.0A EP3093276B1 (en) | 2015-01-20 | 2015-01-20 | Glass fiber composition and glass fiber and composite material thereof |
KR1020177010371A KR101987121B1 (ko) | 2015-01-20 | 2015-01-20 | 유리섬유 조성물, 유리섬유 및 그의 복합재료 |
PL15757761T PL3093276T3 (pl) | 2015-01-20 | 2015-01-20 | Kompozycja włókna szklanego, wykonane z niej włókno szklane i materiał kompozytowy |
CN201580000905.1A CN106488890B (zh) | 2015-01-20 | 2015-01-20 | 一种玻璃纤维组合物及其玻璃纤维和复合材料 |
DK15757761.0T DK3093276T3 (en) | 2015-01-20 | 2015-01-20 | GLASS FIBER COMPOSITION AND GLASS FIBER AND COMPOSITION MATERIALS THEREOF |
US15/122,127 US9758423B2 (en) | 2015-01-20 | 2015-01-20 | Glass fiber composition and glass fiber and composite material thereof |
ES15757761T ES2702720T3 (es) | 2015-01-20 | 2015-01-20 | Composición de fibra de vidrio y fibra de vidrio y materiales compuestos de la misma |
ZA2017/01507A ZA201701507B (en) | 2015-01-20 | 2017-02-28 | Glass fiber composition and glass fiber and composite material thereof |
SA517381900A SA517381900B1 (ar) | 2015-01-20 | 2017-07-11 | تركيبة ألياف زجاجية، ليف زجاجي ومادة مركبة منها |
HRP20181929TT HRP20181929T1 (hr) | 2015-01-20 | 2018-11-19 | Sastav staklenog vlakna i od njega dobiveno stakleno vlakno i kompozitni materijal |
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PCT/CN2015/071153 WO2015131684A2 (zh) | 2015-01-20 | 2015-01-20 | 一种玻璃纤维组合物及其玻璃纤维和复合材料 |
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US (1) | US9758423B2 (zh) |
EP (1) | EP3093276B1 (zh) |
JP (1) | JP6411657B2 (zh) |
KR (1) | KR101987121B1 (zh) |
CN (1) | CN106488890B (zh) |
BR (1) | BR112016019954B1 (zh) |
CA (1) | CA2942671C (zh) |
DK (1) | DK3093276T3 (zh) |
ES (1) | ES2702720T3 (zh) |
HR (1) | HRP20181929T1 (zh) |
MA (1) | MA40158A1 (zh) |
MX (1) | MX2017007618A (zh) |
PL (1) | PL3093276T3 (zh) |
PT (1) | PT3093276T (zh) |
RU (1) | RU2667170C1 (zh) |
SA (1) | SA517381900B1 (zh) |
SI (1) | SI3093276T1 (zh) |
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KR20190086588A (ko) * | 2017-08-30 | 2019-07-22 | 주시 그룹 코., 엘티디. | 유리섬유 조성물 및 그 유리섬유와 복합재료 |
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CN106938891A (zh) | 2015-04-21 | 2017-07-11 | 巨石集团有限公司 | 一种高性能玻璃纤维组合物及其玻璃纤维和复合材料 |
CN113800773B (zh) * | 2017-01-26 | 2023-03-14 | 巨石集团有限公司 | 一种高性能玻璃纤维组合物及其玻璃纤维和复合材料 |
MX2020006064A (es) | 2017-12-19 | 2020-08-24 | Ocv Intellectual Capital Llc | Composicion de fibra de vidrio de alto rendimiento. |
MX2021005461A (es) | 2018-11-26 | 2021-06-18 | Owens Corning Intellectual Capital Llc | Composicion de fibra de vidrio de alto rendimiento con modulo de elasticidad mejorado. |
US11524918B2 (en) | 2018-11-26 | 2022-12-13 | Owens Corning Intellectual Capital, Llc | High performance fiberglass composition with improved specific modulus |
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FR2879591B1 (fr) | 2004-12-16 | 2007-02-09 | Saint Gobain Vetrotex | Fils de verre aptes a renforcer des matieres organiques et/ou inorganiques |
EP2042474B1 (en) * | 2006-06-23 | 2013-03-20 | Nippon Sheet Glass Company, Limited | Glass flake |
FR2930543B1 (fr) | 2008-04-23 | 2010-11-19 | Saint Gobain Technical Fabrics | Fils de verre et composites a matrice organique et/ou inorganique contenant lesdits fils |
CN101580344B (zh) * | 2009-06-29 | 2012-10-17 | 巨石集团有限公司 | 一种高强度玻璃纤维组合物 |
CN101597140B (zh) * | 2009-07-02 | 2011-01-05 | 重庆国际复合材料有限公司 | 一种高强度高模量玻璃纤维 |
MX2012001466A (es) * | 2009-08-04 | 2012-02-22 | Ocv Intellectual Capital Llc | Vidrio libre de litio, con modulo mejorado. |
EP2581350B1 (en) * | 2010-06-08 | 2017-01-11 | Nitto Boseki Co., Ltd. | Glass fiber |
CN102390934B (zh) | 2011-08-10 | 2013-12-25 | 巨石集团有限公司 | 一种玻璃纤维组合物 |
CN103974811B (zh) * | 2011-12-06 | 2016-08-24 | 日东纺绩株式会社 | 长纤维强化热塑性树脂预制坯以及使用了该预制坯的纤维强化树脂成型体 |
US9499432B2 (en) * | 2012-04-18 | 2016-11-22 | 3B-Fibreglass Sprl | Glass fibre composition and composite material reinforced therewith |
CN103351102B (zh) | 2013-06-25 | 2016-03-30 | 巨石集团有限公司 | 一种玻璃纤维组合物及由其制成的具有低介电常数的玻璃纤维 |
WO2016040425A1 (en) * | 2014-09-09 | 2016-03-17 | Ppg Industries Ohio, Inc. | Glass compositions, fiberizable glass compositions, and glass fibers made therefrom |
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2015
- 2015-01-20 WO PCT/CN2015/071153 patent/WO2015131684A2/zh active Application Filing
- 2015-01-20 SI SI201530504T patent/SI3093276T1/sl unknown
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- 2015-01-20 CN CN201580000905.1A patent/CN106488890B/zh active Active
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Cited By (6)
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KR20190086588A (ko) * | 2017-08-30 | 2019-07-22 | 주시 그룹 코., 엘티디. | 유리섬유 조성물 및 그 유리섬유와 복합재료 |
JP2019533627A (ja) * | 2017-08-30 | 2019-11-21 | ジュシ グループ カンパニー リミテッド | ガラス繊維組成物及びそのガラス繊維と複合材料 |
KR102280662B1 (ko) * | 2017-08-30 | 2021-07-21 | 주시 그룹 코., 엘티디. | 유리섬유 조성물 및 그 유리섬유와 복합재료 |
US11339085B2 (en) * | 2017-08-30 | 2022-05-24 | Jushi Group Co., Ltd. | Glass fiber composition, glass fiber and composite material thereof |
US20220234945A1 (en) * | 2017-08-30 | 2022-07-28 | Jushi Group Co., Ltd. | Glass fiber composition, glass fiber and composite material thereof |
US11884575B2 (en) * | 2017-08-30 | 2024-01-30 | Jushi Group Co., Ltd. | Glass fiber composition, glass fiber and composite material thereof |
Also Published As
Publication number | Publication date |
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EP3093276A2 (en) | 2016-11-16 |
EP3093276A4 (en) | 2017-09-13 |
BR112016019954B1 (pt) | 2022-01-04 |
SI3093276T1 (sl) | 2019-01-31 |
PL3093276T3 (pl) | 2019-05-31 |
MX2017007618A (es) | 2017-09-18 |
PT3093276T (pt) | 2018-12-24 |
KR20170068484A (ko) | 2017-06-19 |
KR101987121B1 (ko) | 2019-06-10 |
HRP20181929T1 (hr) | 2019-03-22 |
WO2015131684A3 (zh) | 2015-12-10 |
CN106488890A (zh) | 2017-03-08 |
US9758423B2 (en) | 2017-09-12 |
ES2702720T3 (es) | 2019-03-05 |
JP2018502037A (ja) | 2018-01-25 |
SA517381900B1 (ar) | 2021-06-13 |
RU2667170C1 (ru) | 2018-09-17 |
CN106488890B (zh) | 2019-03-15 |
CA2942671C (en) | 2018-09-18 |
JP6411657B2 (ja) | 2018-10-24 |
CA2942671A1 (en) | 2015-09-11 |
ZA201701507B (en) | 2018-07-25 |
MA40158A1 (fr) | 2017-10-31 |
DK3093276T3 (en) | 2018-11-26 |
US20160362327A1 (en) | 2016-12-15 |
BR112016019954A2 (pt) | 2017-10-24 |
EP3093276B1 (en) | 2018-09-26 |
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