WO2015068393A1 - 加熱調理器 - Google Patents
加熱調理器 Download PDFInfo
- Publication number
- WO2015068393A1 WO2015068393A1 PCT/JP2014/005588 JP2014005588W WO2015068393A1 WO 2015068393 A1 WO2015068393 A1 WO 2015068393A1 JP 2014005588 W JP2014005588 W JP 2014005588W WO 2015068393 A1 WO2015068393 A1 WO 2015068393A1
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- WO
- WIPO (PCT)
- Prior art keywords
- light
- top plate
- heating
- diffusion region
- black
- Prior art date
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C7/00—Stoves or ranges heated by electric energy
- F24C7/08—Arrangement or mounting of control or safety devices
- F24C7/082—Arrangement or mounting of control or safety devices on ranges, e.g. control panels, illumination
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0018—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents
- C03C10/0027—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents containing SiO2, Al2O3, Li2O as main constituents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3684—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used for decoration purposes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/44—Lustring
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/10—Tops, e.g. hot plates; Rings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/10—Tops, e.g. hot plates; Rings
- F24C15/102—Tops, e.g. hot plates; Rings electrically heated
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/10—Tops, e.g. hot plates; Rings
- F24C15/102—Tops, e.g. hot plates; Rings electrically heated
- F24C15/106—Tops, e.g. hot plates; Rings electrically heated electric circuits
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C7/00—Stoves or ranges heated by electric energy
- F24C7/08—Arrangement or mounting of control or safety devices
- F24C7/082—Arrangement or mounting of control or safety devices on ranges, e.g. control panels, illumination
- F24C7/083—Arrangement or mounting of control or safety devices on ranges, e.g. control panels, illumination on tops, hot plates
Definitions
- the present disclosure relates to a cooking device that is used in a commercial kitchen such as a general household dining table, a cooking table, a sink, and the like and includes a top plate on which a heated cooking container is placed.
- a heating cooker that heats a cooking container to be heated by a heating body disposed below the top plate, performs cooking, and displays a heating state on the top plate.
- this type of cooker is popular with IH cookers using an induction heating method for heating, and is highly regarded as having high safety and excellent care. This does not limit the heating method of the present invention to induction heating. Moreover, the top plate used for this cooking-by-heating machine is a shape near flat, is excellent in design property, and is excellent in care property.
- this type of cooking device has a problem that the state of heating is difficult to understand unlike a gas type cooking device, etc., using a light emitting element such as an LED or a liquid crystal display such as an LCD below the operation unit or the top plate.
- a light emitting element such as an LED or a liquid crystal display such as an LCD below the operation unit or the top plate.
- Various displays are used for display.
- the top plate placed on the upper surface of the heating cooker transmits the light of a display device that displays the heating state using a light emitting element such as an LED during heating, while the internal structure is not seen through when not heated.
- a light emitting element such as an LED
- a top plate for a cooker disposed on the top of the cooker, the top plate being formed on a transparent glass layer, a pearl tone layer disposed on the lower surface of the glass layer, and a lower surface of the pearl tone layer
- the top plate has a structure having a viewing window not provided with the light shielding layer above the light source provided in the cooking device (for example, a patent) See Document 1.
- the names of each part are the same as those in Patent Document 1.
- FIG. 10 is a cross-sectional view of the top plate disposed on the top of the cooking device described in Patent Document 1.
- FIG. 11 is a top view of the top plate disposed on the top of the cooking device described in Patent Document 1.
- the present invention solves the above-mentioned conventional problems, and in particular, in a display device using a top plate of a heating cooker using a black top plate and a light emitting element such as an LED, display is performed according to an angle viewed from the top surface of the top plate.
- a display device using a top plate of a heating cooker using a black top plate and a light emitting element such as an LED display is performed according to an angle viewed from the top surface of the top plate.
- the heating cooker of the present invention includes a top plate on which the cooked cooking container is placed, An outer case that forms the main body with the top plate disposed on the upper surface; A heating body for heating the heated cooking container above the top plate; A light emitting means provided in the outer case for displaying a heating state by the heating body; A cooking device comprising:
- the top plate is A crystallized glass mainly composed of Li 2 O—Al 2 O 3 —SiO 2 and having a ⁇ -quartz solid solution as a main crystal, the crystal size of which is smaller than the wavelength of visible light and has a low translucency.
- the display position varies depending on the angle viewed from the top surface of the top plate by providing a diffusion region (In particular, a reduction in visibility such as that it appears to be depressed) and a restriction on a structure disposed near the display device (becomes a shadow of light emission) are improved. That is, normally, even if a shadow is always visible from above due to the positional relationship with the structure, the user sees the diffusion region, so that the shadow due to the structure is suppressed.
- the display device can be kept away from the top plate, it is possible to reduce the thermal influence from the cooking container to be heated, so that light emitting elements such as LEDs used in this display device, light guides, and display device cases Or the like can be formed of an inexpensive material having low heat resistance. In particular, it is effective in the case of a device in which a cooking container is assumed to be placed above the light emitting means.
- a black top plate when not heated (when not emitting light), the internal structure such as the display device and the heating body is not seen through, and has both light shielding properties and light transmitting properties. When viewed from the top surface of the top plate, it is possible to provide a low-cost and easy-to-use cooking device with a high flat design and a uniform color on the entire top plate.
- the black top plate has both light shielding properties and translucency, realizes a high design top plate that does not impair the flat feeling, and is excellent in visibility to the display of the heating state. Can realize a cooking device.
- the cooking device includes a top plate on which the heated cooking container is placed, An outer case that forms the main body with the top plate disposed on the upper surface; A heating body for heating the heated cooking container above the top plate; A light emitting means provided in the outer case for displaying a heating state by the heating body; A cooking device comprising:
- the top plate is A crystallized glass mainly composed of Li 2 O—Al 2 O 3 —SiO 2 and having a ⁇ -quartz solid solution as a main crystal, the crystal size of which is smaller than the wavelength of visible light and has a low translucency.
- the light emitting means can be arranged at a position away from the top plate, light emitting elements such as LEDs, light guides, and light emitting elements, which are light emitting means, can be reduced by reducing the thermal influence from the cooked container.
- a structure such as a case to be stored can be formed of an inexpensive material having low heat resistance. In particular, it is effective in the case of a device in which a cooking container is assumed to be placed above the light emitting means.
- a black top plate when not heated (when not emitting light), the internal structure such as the light emitting means and the heating body is not seen through, and has both light shielding properties and light transmitting properties. When viewed from the top surface of the top plate, it is possible to provide a low-cost and easy-to-use cooking device with a high flat design and a uniform color on the entire top plate.
- the heating cooker which concerns on a 2nd aspect has the top plate which mounts a to-be-heated cooking container, An outer case that forms the main body with the top plate disposed on the upper surface; A heating body for heating the heated cooking container above the top plate; A light emitting means provided in the outer case for displaying a heating state by the heating body; A cooking device comprising:
- the top plate is Black composed of black colored low-expansion crystallized glass mainly composed of Li 2 O—Al 2 O 3 —SiO 2 , black colorant as an additive, and ⁇ -quartz solid solution as a main crystal.
- a system glass substrate A diffusing region that is provided on a part of the lower surface of the black glass substrate, includes a pearl pigment formed by coating an inorganic pigment with a metal oxide, and diffuses and emits light from the light emitting means;
- the light emitting means can be arranged at a position away from the top plate, light emitting elements such as LEDs, light guides, and light emitting elements, which are light emitting means, can be reduced by reducing the thermal influence from the cooked container.
- a structure such as a case to be stored can be formed of an inexpensive material having low heat resistance. In particular, it is effective in the case of a device in which a cooking container is assumed to be placed above the light emitting means.
- a black top plate when not heated (when not emitting light), the internal structure such as the light emitting means and the heating body is not seen through, and has both light shielding properties and light transmitting properties. When viewed from the top surface of the top plate, it is possible to provide a low-cost and easy-to-use cooking device with a high flat design and a uniform color on the entire top plate.
- the heating cooker which concerns on a 3rd aspect WHEREIN:
- permeability above a top plate is 60% or more, and the visible light transmittance
- permeability is 60. % Or less.
- the amount of visible light necessary for visibility can be obtained, and the infrared transmittance can be increased. It is possible to provide a heating cooker with high added value.
- the cooking device which concerns on a 4th aspect WHEREIN In the said 2nd aspect, as for the black type
- the cooking device according to the fifth aspect is the glass substrate and the design layer and the diffusion region, or the black glass base material and the diffusion region part according to any one of the first to fourth aspects.
- the amount of light transmitted through a display device using a light emitting element such as an LED above may be 35 cd / m 2 or more.
- the amount of light transmitted through a display device using a light emitting element such as an LED above the top plate is JIS-Z-8513 (ergonomics—office work using a visual display device—requirements for a visual display device: It is preferably 35 cd / m 2 or more as a requirement for ensuring good visibility as shown in the international standard ISO 9241-3).
- a light cooker that can be adjusted and provides an adjustable heating cooker is provided.
- a cooking device capable of simplifying and rationalizing the configuration such that the number of light emitting elements such as LEDs can be reduced by the diffusion effect, and it is not necessary to arrange a light guide.
- the diffusion region may include an inorganic pigment for adjusting a color tone.
- the pearl pigment may have a particle size larger than the wavelength of visible light and in the range of 1 to 500 ⁇ m. .
- the pearl pigment is 200 nm or less in which the particle size of the metal oxide covering the inorganic pigment is smaller than the wavelength of visible light.
- the thickness of the metal oxide coating may be 1 to 500 nm.
- Embodiment 1 to 5 are schematic diagrams showing a schematic configuration and the like of a heating cooker according to Embodiment 1 of the present invention. However, components that are not necessary for the description of the embodiment are omitted even if they are main components. Hereinafter, it demonstrates using drawing.
- FIG. 1 is a schematic diagram showing details of the cooking device according to Embodiment 1 of the present invention.
- the cooking device includes a top plate 2 on which the cooked container 1 is placed, an outer case 3 that forms the main body with the top plate 2 disposed on the upper surface, and a lower portion of the top plate 2.
- a heating body 4 that induction heats the heated cooking container 1 and a display device 5 that is disposed in the outer case 3 and that uses a light emitting element such as an LED that displays the heating state of the heating body 4, and the like.
- a light emitting element such as an LED that displays the heating state of the heating body 4, and the like.
- the top plate 2 includes at least one of a translucent low expansion crystallized glass 9, a design layer 6 having a black color provided on a lower surface of the translucent low expansion crystallized glass 9, and a lower surface of the design layer 6.
- a diffusion region 7 that diffuses and emits light in response to light emission of the display device 5, and a light shielding layer 8 that is provided on a lower surface of the design layer 6 other than the diffusion region 7 and shields light from below.
- the light-transmitting low-expansion crystallized glass 9 is a transparent crystallized glass (glass base material 9) mainly composed of Li 2 O—Al 2 O 3 —SiO 2 and ⁇ -quartz solid solution as a main crystal. The size of the crystal is smaller than the wavelength of visible light.
- the design layer 6 represents a black color when viewed from the top surface of the top plate 2 substantially uniformly on the entire surface of the top plate 2.
- the design layer 6 is obtained by applying and baking a raster paint using a diluted solution of an organometallic compound having a black color on the lower surface of the top plate 2 as the first lower layer.
- the diffusion region 7 diffuses and emits light substantially uniformly according to a pattern such as a figure, a symbol, or a character formed by the light transmission property of the pearl pigment or the diffusion effect due to the reflection of light according to the light emission of the display device 5.
- the diffusion region 7 is made of a pearl-like paint containing a pearl pigment formed by coating an inorganic pigment with a metal oxide on the lower surface of the design layer 6 and a silicon resin or a siliceous sol. It is obtained by applying and baking as the second lower surface layer.
- the light shielding layer 8 shields light other than the display portion.
- the light-shielding layer 8 is obtained by applying and baking a heat-resistant paint made of a heat-resistant resin and an inorganic pigment on the lower surface of the design layer 6 other than the diffusion region 7 and becoming opaque after baking as a third layer on the lower surface. It is done.
- the light shielding layer 8 should just be provided in parts other than the diffusion area
- the heating system of the to-be-heated cooking container 1 such as a pan in the present embodiment is induction heating as an example.
- the cooking device of the present invention is not limited to the induction heating method, and may be a sheathed heater, a radiant heater, a miraclon heater, a halogen heater, a gas, or the like.
- a high-frequency power supply device that supplies a high-frequency output to the heating body 4, a control device that controls them, a cooling device that suppresses heat generation, an operation unit that operates heating on and off, and a cooking container to be heated You may provide the temperature sensor etc. which detect temperature.
- the form of the display unit is arbitrary such as a figure, a character, a pattern, etc., and may be, for example, a substantially annular shape or a substantially semicircular shape arranged so as to surround the periphery of the heating body 4 or the display device 5.
- the transparent translucent low expansion crystallized glass 9 is mainly composed of Li 2 O—Al 2 O 3 —SiO 2 .
- the crystallized glass 9 is transparent because the crystal size is smaller than the wavelength of visible light, and the refractive index of the crystal layer and the glass layer are approximately the same.
- the crystallized glass 9 cancels out the ⁇ -quartz solid solution crystal exhibiting negative expansion characteristics and the remaining glass layer exhibiting positive expansion characteristics, so that the crystallized glass 9 as a whole has substantially zero thermal expansion.
- the coefficient generally indicates that the absolute value of the thermal expansion coefficient is 30 ⁇ 10 ⁇ 7 / ° C. or less.
- the heating cooker in which the top plate 2 on which the cooked cooking container 1 is placed is arranged on the upper surface, the bottom surface of the cooked cooking container 1 that is in contact with the top plate 2 is heated locally, particularly immediately above the heating body 4 of the top plate 2.
- the temperature difference from ⁇ 100 °C is large.
- the crystallized glass 9 is suitable for a cooking device having a large temperature difference between the bottom surface and the periphery of the top plate heated as described above.
- the manufacturing method of this translucent low expansion crystallized glass 9 is demonstrated.
- an antifoaming agent is added to a batch raw material such as SiO 2 , A 1 2 O 3 , Li 2 O, TiO 2 , ZrO 2 , P 2 O 5 , BaO, Na 2 O + K 2 O, As 2 O 3 and mixed. Then, after melting at about 1700 ° C. and forming the glass melt, it is gradually cooled to room temperature.
- the design layer 6 has a black color.
- the design layer 6 is obtained by applying a raster paint to the first layer on the lower surface of the translucent low expansion crystallized glass 9.
- the raster paint is Au, Pt, Pd, Rh, Ru, Bi, Sn, Ni, Fe, Cu, Cr, Ti, Ca, Si, Ba, Sr, Mg, Ag, Zr, In, Mn, etc. It can be obtained as a dilute solution of organometallic oxide containing a resin such as colophonium, balsam, asphalt, or a mixture of metals alone or in an arbitrary ratio.
- this raster-colored paint is made by adding an ethylcellulose-based or nitrocellulose-based resin to a binder and mixing it into a paste, and changing the color according to the choice of the metal to change the lower surface of the transparent translucent low expansion crystallized glass 9 It can apply
- the diluted solution of the organometallic oxide may contain, in mass%, 1 to 30% Au, 0.5 to 20% Si, and 0.1 to 10% Bi. Good.
- the binder may be composed of 20% ethyl cellulose, 40% ethyl cellosolve, and 40% butyl cellosolve. This raster-colored paint shows a black color tone.
- the raster-colored paint is preferably applied by screen printing, and can selectively correspond to various characteristics as a design layer by changing the thickness of the film thickness by arranging different meshes.
- the film thickness is selected in the range of 0.1 to 10 ⁇ m according to the characteristics as the design layer, and is fired at a temperature of 700 to 900 ° C.
- the film thickness of the raster color paint is too thin, the color tone of the design layer 6 cannot be developed. Also, if the film thickness of the raster-colored paint is too thick, the performance as a coating film such as peeling and cracking will deteriorate and the performance such as strength and thermal shock resistance of transparent translucent low expansion crystallized glass to be applied will be affected. Effect.
- This raster coloring paint can be applied very thinly and uniformly, and can be formed without affecting the properties such as strength and thermal shock resistance of the transparent translucent low expansion crystallized glass 9.
- it has a moderate metallic luster as a coating film, and with its excellent design and reflection due to this metallic luster, the inside of the heating cooker can be seen through when viewed from the top surface. Can be prevented.
- the top plate 2 having both a suitable light-shielding property and translucency that can transmit the light emitted from the display device 5.
- the diffusion region 7 is obtained by applying a pearl tone paint as a second lower layer of the translucent low expansion crystallized glass 9 to at least a part of the lower surface of the design layer.
- the pearl-tone paint includes a pearl pigment, a silicone resin or siliceous sol, and an organic binder.
- Pearl pigments include inorganic pigments such as kaolin, talc, sericite, pyroferrite, natural mica, synthetic mica, aluminum oxide, silicon oxide, borosilicate glass, titanium oxide, zirconium oxide, iron oxide, chromium oxide, tin oxide, oxidation
- a metal oxide such as zinc, cobalt oxide, boron oxide or the like is used alone or in combination at an arbitrary ratio and coated.
- the silicon resin is a polymer of an organosilicon compound having a siloxane bond as a main skeleton, and is obtained by dissolving a straight silicon varnish, a modified silicon varnish, a silicon alkyd varnish, a silicon epoxy varnish, etc. in an organic solvent as necessary.
- a siliceous sol a silica sol obtained by hydrolyzing ethyl silicate, a colloidal silica sol, or the like can be used.
- the organic binder acrylic resin, amide resin, alkyd resin, cellulose resin, or the like can be used.
- the pearl pigment for example, suspends mica powder in dilute titanic acid aqueous solution, heats it to 70-100 ° C, hydrolyzes the titanium salt, and precipitates hydrated titanium oxide particles on the mica powder surface. Then, it may be fired at a high temperature of 700 to 1000 ° C., and the mica as the inorganic pigment may be coated with titanium oxide as the metal oxide.
- the pearl paint may be composed of, for example, 1 to 30% by weight of pearl pigment, 1 to 30% silicone resin or siliceous sol, and 40 to 98% organic binder.
- the application of the pearl-like paint is preferably screen printing, and the diffusion region 7 can be obtained by applying a pattern such as a figure, a symbol, or a character on the lower surface of the design layer 6 as the second lower layer and baking it.
- the diffusion region 7 allows the light emission of the display device 5 to diffuse and emit light substantially uniformly according to the pattern of figures, symbols, characters, etc. formed by the light transmission of the pearl pigment and the diffusion effect due to the reflection of light. it can.
- the thickness of the film can be changed to cope with various characteristics as the diffusion region 7.
- the film thickness is selected in the range of 1 to 20 ⁇ m according to the characteristics of the diffusion region 7 and is fired at a temperature of 700 to 900 ° C. If the film thickness is too thin, the diffusion effect as the diffusion region 7 cannot be exhibited. On the other hand, if it is too thick, the transmission effect is lost and the visibility of the display is lowered. Moreover, the performance as a coating film such as peeling or cracking is also reduced.
- the content of silicon resin or siliceous sol is 1% or less, the adhesion of the pearl paint may be reduced. On the other hand, if it exceeds 30%, the silicon resin or the siliceous sol covers the pearl pigment, the reduction of the diffusion effect and the transmission effect is lost, and the display visibility is lowered.
- the light shielding layer 8 shields light other than the display portion.
- the light-shielding layer 8 is obtained by applying a heat-resistant paint as a third layer on the lower surface of the translucent low expansion crystallized glass 9 on a portion other than the diffusion region 7 on the lower surface of the design layer 6.
- the light shielding layer 8 should just be provided in parts other than the diffusion area
- a heat-resistant resin containing a silicon resin, a polyamide resin, a fluororesin, or a composite thereof and a mixture of an inorganic pigment for coloring can be used.
- the inorganic pigment for coloring include TiO 2 , ZrO 2 , ZrSiO 4 , Al 2 O 3 , 3Al 2 O 3 -2SiO 2 , and Al 2 TiO 5 as white inorganic pigments.
- Black inorganic pigments include Cr-Fe oxides, Co-Mn-Cr-Fe oxides, Co-Ni-Cr-Fe oxides, Co-Ni-Cr-Fe-Mn oxides, etc. Is mentioned.
- examples of the gray inorganic pigment include Sn—Sb-based oxides and Sn—Sb—V-based oxides.
- examples of the yellow inorganic pigment include Sn—V oxides, Zr—V oxides, Zr—Si—Pr oxides, Ti—Cr—Sb oxides, and the like.
- brown inorganic pigment examples include Zn-Al-Cr-Fe-based oxides and Zn-Mn-Al-Cr-Fe-based oxides.
- examples of the green inorganic pigment include Ca—Cr—Si oxide, Cr—Al oxide, Co—Zn—Al—Cr oxide, Zr—Si—Pr—V oxide, and the like.
- examples of the blue inorganic pigment include Co—Al—Zn oxides, Co—Al oxides, and Zr—Si oxides.
- examples of the pink inorganic pigment include Mn—Al oxide, Ca—Sn—Si—Cr oxide, Sn—Cr oxide, Zr—Si—Fe oxide, and the like.
- inorganic pigments for coloring can be mixed at an arbitrary ratio so as to obtain a desired color tone.
- the inorganic pigment is not limited to those listed here.
- inorganic pigments of other colors such as red pigments not listed above may be used.
- heat-resistant paints are mass% and include 50% heat-resistant resin and 50% inorganic pigment.
- the proportion of the inorganic pigment is preferably 50% or less, and if the content exceeds 50%, the adhesiveness of the heat-resistant resin may be lowered.
- the heat-resistant paint is preferably applied by screen printing, and can selectively correspond to various characteristics as the light-shielding layer 8 by changing the thickness of the film thickness by arranging different meshes.
- the film thickness is selected in the range of 1 to 30 ⁇ m according to the characteristics as the light shielding layer, and is fired at a temperature of 200 to 450 ° C. If the film thickness is too thin, the shielding property as the light shielding layer cannot be exhibited, and if it is too thick, the performance as a coating film such as peeling or cracking deteriorates.
- FIG. 2 is a diagram showing the spectral transmittance of the transparent translucent low-expansion crystallized glass (glass substrate 9) of the cooking device according to Embodiment 1 of the present invention.
- the top plate 2 is a crystallized glass mainly composed of Li 2 O—Al 2 O 3 —SiO 2 and having a ⁇ -quartz solid solution as a main crystal, and the size of the crystal is smaller than the wavelength of visible light. Shows transparency. For example, a thickness of about 4 mm was used.
- the manufacturing method is as described above.
- the result of measuring the transmission spectrum of this transparent translucent low expansion crystallized glass using a spectrophotometer is as shown in FIG.
- the MIN. Value is in the entire visible light range (380 to 760 nm). About 60% or more, MAX. A transmittance of about 80% on average is exhibited at about 90% or more. Further, it exhibits a transmittance of about 80% or more in the infrared region (1000 to 2500 nm).
- This infrared transmittance is effective when a heating body that exhibits a radiation effect, such as a halogen heater or a radiant heater, is used as the heating body of the heating cooker, and it is desirable that the infrared transmittance be as high as possible.
- infrared detection type non-contact type temperature sensor or the like is used as a temperature sensor in the cooking device of the present invention, and higher infrared transmittance is more effective for detection accuracy, resolution, and the like.
- the infrared transmittance is preferably 80% or more.
- the visible light transmittance is effective for the amount of light transmitted through the display device of the cooking device of the present invention, and JIS-Z-8513 (ergonomics—office work using a visual display device—requirements for a visual display device:
- the requirement for ensuring good visibility shown in the corresponding international standard ISO 9241-3) is preferably 35 cd / m 2 or more.
- the visible light transmittance is too high, structures such as a display device and a heating element arranged inside the cooking device of the present invention can be seen through the top plate when not heated (when not emitting light) Since the impression of the diffusion region used on the lower surface of the layer can be seen through, it is necessary to optimize the visible light transmittance.
- the adjustment of the infrared transmittance and the visible light transmittance can be adjusted by the component, ratio, film thickness, and concentration of the raster coloring paint using the diluted solution of the organometallic compound used in the design layer.
- the components of the raster paint forming the design layer 6 Au, Pt, Pd, Rh, Ru, Bi, Sn, Ni, Fe, Cu, Cr, Ti, Ca, Si, Ba, Sr, Mg, Ag
- the metal used for the organometallic compound such as Zr, In, and Mn can be used alone or in combination at any ratio, and the transparency and reflectivity can be adjusted depending on the color tone and gloss.
- the film thickness of the raster coloring paint can be adjusted in the range of 0.1 to 10 ⁇ m to adjust the translucency and reflectivity.
- the transparency and reflectivity can be adjusted by arbitrarily adjusting the mesh size by screen printing in the range of # 60 to # 500.
- the film thickness of the raster paint is preferably in the range of 0.1 to 5 ⁇ m, and the mesh size is preferably in the range of # 150 to # 350.
- the visible light here means a light wavelength in the range of 380 to 780 nm
- the infrared light means a light wavelength in the range of 1000 to 2500 nm.
- FIG. 3 shows the spectral transmittance of the crystallized glass obtained by applying a raster-colored paint as the first layer to the transparent translucent low-expansion crystallized glass of the heating cooker in Embodiment 1 of the present invention.
- the design layer 6 is a first layer on the lower surface of a transparent translucent low-expansion crystallized glass obtained by mixing a black raster-colored paint in which a diluted solution of an organometallic compound containing Au and a binder using ethyl cellulose is mixed.
- a black raster-colored paint in which a diluted solution of an organometallic compound containing Au and a binder using ethyl cellulose is mixed.
- Tetron mesh # 200 was screen printed with Tetron mesh # 200 and fired at about 850 ° C.
- FIG. 3 shows the result of measuring the transmission spectrum using a spectrophotometer for the crystallized glass obtained by applying and firing the raster-colored paint as the first lower layer of the transparent translucent low expansion crystallized glass. is there.
- the transmittance is 60% or less over the entire visible light range (380 to 760 nm). Further, in the infrared region (1000 to 2500 nm), the transmittance is 60% or more and an average of about 80%.
- top plate 2 when the top plate 2 is viewed from the top surface of the top plate 2 in a room dimmed to a brightness of about 300 Lx using an illuminance meter, internal structures such as the display device 5 and the heating body 4 are seen through.
- the entire surface of the top plate 2 is black and substantially uniform and shows a flat feeling without being seen.
- FIGS. 4 and 5 are a schematic view and a cross-sectional view showing details of the top plate of the heating cooker according to Embodiment 1 of the present invention.
- the top plate 2 is provided on a transparent translucent low-expansion crystallized glass 9, a lower surface thereof, a design layer 6 that is substantially uniformly expressed on the entire surface of the top plate 2, and a part of the lower surface of the design layer 6. And a diffusion region 7 provided.
- the design layer 6 is obtained by applying and baking a raster-colored paint using a diluted solution of an organometallic compound having a black color on the lower surface of a transparent translucent low expansion crystallized glass as the first lower layer. It is done.
- the diffusion region 7 has a pearl pigment formed by coating an inorganic pigment with a metal oxide on the lower surface of the design layer 6 and a pearl-tone paint using silicon resin or siliceous sol on the top plate 2 with figures, symbols, characters, etc. Is applied as a second layer on the lower surface and fired.
- the diffusion region 7 emits light in a substantially uniform manner according to a pattern such as a figure, a symbol, or a character formed by a diffusion effect caused by light transmission or light reflection of the pearl pigment according to light emission of the display device 5.
- a pearl pigment having a particle diameter of 10 to 60 ⁇ m and a coating thickness of 200 nm or more obtained by coating natural mica that develops white pearl tone with titanium oxide was used.
- the pearl pigment was mixed with 30% by mass, silicon resin (containing 50% organic solvent) 30%, and the balance with an organic binder, a thickening resin, etc. to obtain a pearl paint.
- this pearl paint is applied as a second lower layer on the lower surface of the design layer 6 and has a width of about 3 mm as shown in (a) section AA and (b) section BB in FIG.
- a linear figure was screen printed with a stainless mesh # 250 and fired at about 850 ° C. to obtain a diffusion region 7.
- the film thickness of the diffusion region 7 is about 5 ⁇ m.
- the top plate 2 configured as described above is an internal structure such as the display device 5 or the heating body 4 when viewed from the top surface of the top plate 2 in a room dimmed to a brightness of about 300 Lx using an illuminometer. Is not seen through, and the imprint of the diffusion region 7 is not seen through, and the entire surface of the top plate 2 is black and substantially uniform and shows a flat feeling.
- the amount of light can be adjusted according to the composition, ratio, film thickness, and concentration of the pearl paint used in the diffusion region 7.
- the properties and particle shape of inorganic pigments such as kaolin, talc, sericite, pyroferrite, natural mica, synthetic mica, aluminum oxide, silicon oxide, borosilicate glass, etc.
- the translucency and reflectivity can be adjusted.
- titanium oxide, zirconium oxide, iron oxide, chromium oxide, tin oxide, zinc oxide, cobalt oxide, boron oxide, and other metal oxides that coat this inorganic pigment may be used alone or in combination at any ratio to form a coating layer.
- Translucency, reflectivity, selectivity of reflected color, and the like can be adjusted by properties and film thickness.
- the film thickness of the pearl paint can be adjusted within the range of 1 to 20 ⁇ m to adjust the translucency and reflectivity.
- the translucency and reflectivity can be adjusted by arbitrarily adjusting the mesh size by screen printing in the range of # 60 to # 500.
- the film thickness of the pearl tone paint is preferably in the range of 2 to 15 ⁇ m, and the mesh size is preferably in the range of # 150 to # 350.
- an inorganic pigment is added to the diffusion region 7 and the color tone can be adjusted with the inorganic pigment so that the imprint is not seen through the top surface.
- the inorganic pigment for coloring used as the pearl tone paint specifically includes TiO 2 , ZrO 2 , ZrSiO 4 , Al 2 O 3 , 3Al 2 O 3 -2SiO 2 , Al 2 TiO 5 as the white inorganic pigment. Etc.
- Black inorganic pigments include Cr-Fe oxides, Co-Mn-Cr-Fe oxides, Co-Ni-Cr-Fe oxides, Co-Ni-Cr-Fe-Mn oxides, etc. Is mentioned.
- examples of the gray inorganic pigment include Sn—Sb-based oxides and Sn—Sb—V-based oxides.
- examples of the yellow inorganic pigment include Sn—V oxides, Zr—V oxides, Zr—Si—Pr oxides, Ti—Cr—Sb oxides, and the like.
- brown inorganic pigment examples include Zn-Al-Cr-Fe-based oxides and Zn-Mn-Al-Cr-Fe-based oxides.
- examples of the green inorganic pigment include Ca—Cr—Si oxide, Cr—Al oxide, Co—Zn—Al—Cr oxide, Zr—Si—Pr—V oxide, and the like.
- examples of the blue inorganic pigment include Co—Al—Zn oxides, Co—Al oxides, and Zr—Si oxides.
- examples of the pink inorganic pigment include Mn—Al oxide, Ca—Sn—Si—Cr oxide, Sn—Cr oxide, Zr—Si—Fe oxide, and the like.
- These inorganic pigments for coloring can be mixed in an arbitrary ratio to obtain a desired color tone.
- This inorganic pigment for coloring is added in a weight of 50% or less with respect to the weight of the pearl pigment as a pearl tone paint used in the diffusion region. Further, the total of the pearl pigment and the inorganic pigment for coloring does not exceed 30% by mass.
- the inorganic pigment for coloring is 5% or less
- the total of the powder of the pearl pigment and the inorganic pigment for coloring is 30% by mass
- the content is 10% or less.
- the pearl pigment used in the diffusion region 7 has a particle size larger than the wavelength of visible light to 1 to 500 ⁇ m, and adjusts the light transmission and diffusion effect due to light reflection.
- the particle size of the pearl pigment is relatively small, such as 1 to 60 ⁇ m, a gentle pearly luster is produced, the reflected light increases in a certain range, the repetition of transmission and reflection increases, and the light diffusion effect is exerted. high.
- the particle size is medium, such as 60 to 200 ⁇ m, strong pearl luster is produced, and in a certain range, the reflected light beam is smaller than when the particle size is relatively small, and the repetition of transmission and reflection is also reduced.
- the diffusion effect is reduced, but on the contrary, strong reflectivity is exhibited.
- the particle size exceeds 200 ⁇ m and is relatively large, it gives a bright and shiny luster.
- the reflected light beam is smaller than when the particle size is medium, and the repetition of transmission and reflection is further reduced. Although the diffusion effect is further reduced, it shows a stronger reflectivity.
- This property varies depending on the type of inorganic pigment used in the pearl pigment described above and the type of metal oxide covering this inorganic pigment, and is optimally selected along with the particle size according to the visibility seen from the top surface of the top plate. Is done.
- This pearl pigment reflects about 5% of light and repeatedly transmits about 95% of light, thereby expressing pearly luster.
- the pearl pigment used in the diffusion region has a natural mica formed with a titanium oxide coating
- the natural mica itself is a material having translucency and reflectivity. By setting it to 200 nm or less, which is smaller than the wavelength, it has both translucency and reflectivity.
- the transmitted light is partially reflected and partially transmitted by the surface of natural mica (between the titanium oxide coating). Further, the transmitted light is partially reflected and partially transmitted between the titanium oxide coating and the natural mica layer. Further, the transmitted light repeats reflection and transmission such that a part of the light is reflected inside the surface of the titanium oxide coating and a part of the light is transmitted.
- a metal oxide coating when a metal oxide coating is formed to a thickness of 60 to 80 nm and irradiated with light, blue light having a short wavelength is transmitted and yellow light is reflected.
- blue light having a short wavelength when the light is applied to form a thickness of 80 to 100 nm, green light is transmitted and red light is reflected.
- yellow light when the thickness is formed to 100 to 140 nm and light is applied, yellow light is transmitted and blue light is reflected.
- the thickness of 120 to 160 nm and exhibits properties such that when light is applied, red light is transmitted and green light is reflected.
- the color and wavelength here are visible light rays of purple 380 to 420 nm, blue 420 to 490 nm, green 490 to 550 nm, yellow 550 to 580 nm, and red 600 to 760 nm.
- FIG. 6 is a schematic view and a cross-sectional view showing details of the top plate of the heating cooker according to Embodiment 1 of the present invention.
- a heat-resistant paint made of a heat-resistant resin and an inorganic pigment on the lower surface of the design layer 6 on the lower surface of the design layer 6 and becoming opaque after baking as a third layer on the lower surface.
- a light shielding layer 8 for light shielding other than the display portion is formed.
- the light shielding layer 8 may be formed so as to partially overlap the periphery of the diffusion region 7.
- the light-shielding layer 8 is a heat-resistant paint in which mass%, silicon resin 70% (containing 50% organic solvent), and Fe—Cr—Co black inorganic pigment 30% are mixed, as shown in FIGS. As shown in the figure, it is obtained by screen printing on the lower surface of the design layer 6 on the portion other than the diffusion region 7 with a stainless mesh # 200 as the third lower surface layer and firing at about 350 ° C.
- the film thickness is about 10 ⁇ m.
- the top plate 2 configured as described above is an internal structure such as the display device 5 or the heating body 4 when viewed from the top surface of the top plate 2 in a room dimmed to a brightness of about 300 Lx using an illuminometer. Is not seen through, and the imprint of the light shielding layer 8 is not seen through, and the entire surface of the top plate 2 is black and substantially uniform and shows a flat feeling.
- FIG. 7 is a schematic diagram showing details of the method of measuring the luminance of the cooking device in the first embodiment of the present invention.
- a red LED is disposed as a light source at a position 20 mm below the top plate in Embodiment 1 of the present invention, and a luminance measuring device (color luminance meter: BM-7 stock) is positioned 500 mm above the top plate. Company Topcon Techno House).
- measurement is performed in a room dimmed to a brightness of about 300 Lx using an illuminometer so that the luminance measurement angle is 0.2 ° and the luminance of the red LED is 5000 cd / m 2. The current value was adjusted.
- the pearl pigment blending ratio in the diffusion region 7 described above was prepared as 100%, and the ratio was reduced to 50%, 25%, 10%, and 5%.
- Table 1 is a table showing the luminance measurement results.
- the transparent light-transmitting low-expansion crystallized glass had a transmittance of 94.5% and showed good transparency.
- the crystallized glass in which the design layer 6 and the diffusion region 7 are printed on the lower surface of the transparent translucent low expansion crystallized glass has a luminance of 31 cd / m 2 and JIS-Z-8513 (ergonomics-visual display device). Office work to be used-Requirements for visual display device: It was confirmed that it was lower than 35 cd / m 2 which is a requirement for ensuring good visibility as shown in the corresponding international standard ISO 9241-3).
- the current value was adjusted so that the luminance of the red LED was 5000 cd / m 2 under the measurement conditions this time, but this is a value equal to or less than 1 ⁇ 4 of the allowable current value of the red LED, and the appropriate light amount. In order to obtain the above, it is possible to increase the luminance of the red LED, and increase the number of red LEDs.
- the composition, film thickness, etc. so as to increase the visible light transmittance of the design layer 6.
- the crystallized glass having the design layer 6 and the light shielding layer 8 printed on the lower surface of the transparent translucent low expansion crystallized glass has a luminance of 2 cd / m 2 and is sufficiently shielded from light. .
- the current value of the red LED is adjusted so that the luminance at the center of the light source of each sample is 5000 cd / m 2 , and the other conditions are the positions 5 mm and 10 mm away from the center of the light source under the measurement conditions described above.
- Table 2 The results of measuring the luminance are summarized in Table 2.
- Table 2 is a table showing the luminance measurement results.
- the diffusion region 7 that there is no represents the luminance of 13 cd / m 2 at a position of 5mm from the light source center, some diffusion region 7 represents the luminance of 973cd / m 2, diffusion of at least about 70 times the luminance It was confirmed that an effect could be obtained.
- the diffusion effect was reduced when the blending ratio of the pearl pigment in the diffusion region 7 was decreased. However, even if this pearl pigment is reduced to 5%, it shows a luminance of 88 cd / m 2 at a position 5 mm from the center of the light source, and a diffusion effect of about 6 times or more can be obtained compared to the case where the pearl pigment is not present. It was confirmed that a sufficient diffusion effect can be obtained by providing.
- the luminance decreases as the distance from the light source center increases. This can improve unevenness in the amount of light by changing the screen printing mesh in the diffusion region 7 and adjusting the density of the printing. It is also possible to arrange the red LEDs at a predetermined interval, and to improve the unevenness of the light amount by taking into account the effect of increasing the brightness at the overlapping portion of the light. Further, it can be improved by adjusting the partial visible light transmittance of the design layer 6.
- the same effect can be obtained even if the blending ratio of the pearl pigment is decreased.
- the same or more effects can be obtained by setting the thickness of the metal oxide coating of the pearl pigment used in the diffusion region 7 to 1 to 500 nm and selectively adjusting the color tone of the transmitted light or interference light.
- the LED color is red
- the same effect can be obtained even though fine adjustment is necessary due to the difference in wavelength depending on the LED of each color such as blue, white, yellow and green.
- the display position varies depending on the angle viewed from the top surface of the top plate (particularly Visibility deterioration such as (looks deep inside) is improved.
- the restriction on the structure disposed in the vicinity of the display device is improved.
- the structure of light emitting elements such as LEDs and light guides used in this display device, the case of the display device, etc.
- the body can be formed of an inexpensive material with low heat resistance.
- the internal structure such as the display device and heating element does not show through, and it has both light-shielding and light-transmitting properties.
- the color of the entire top is uniform and flat. It is possible to provide an inexpensive and easy-to-use heating cooker with a sense of design and high design.
- an adjustable cooking device that can obtain the light amount necessary for visibility.
- a cooking device capable of simplifying and rationalizing the configuration such that the number of light emitting elements such as LEDs is reduced by the diffusion effect, and it is not necessary to arrange a light guide.
- (Embodiment 2) 8 and 9 show a schematic configuration and the like of the heating cooker according to the second embodiment of the present invention.
- the glass substrate 9 in the first embodiment is a black glass substrate 10.
- FIG. 8 is a schematic diagram showing details of the heating cooker according to the second embodiment of the present invention.
- the cooking device includes a top plate 2 on which the cooked container 1 is placed, an outer case 3 that forms the main body with the top plate 2 disposed on the upper surface, and a lower portion of the top plate 2.
- a heating body 4 that heats the cooking container 1 to be heated, and a display device 5 that is disposed in the outer case 3 and uses a light emitting element such as an LED that displays the heating state of the heating body 4. .
- the top plate 2 is provided on at least a part of the lower surface of the colored low-expansion crystallized glass (black glass substrate 10) and the black glass substrate 10, and diffuses and emits light in response to light emitted from the display device 5.
- 7 and a light shielding layer 8 which is provided on a lower surface of the black system glass base material 10 except the diffusion region 7 and shields light from below.
- the black system glass substrate 10 is mainly composed of Li 2 O—Al 2 O 3 —SiO 2 , contains a black system colorant as an additive, and has a black system coloration and low expansion using ⁇ -quartz solid solution as a main crystal. It is crystallized glass (black system glass substrate 10).
- the diffusion region 7 diffuses and emits light substantially uniformly according to a pattern such as a figure, a symbol, or a character formed by the light transmission property of the pearl pigment or the diffusion effect due to the reflection of light according to the light emission of the display device 5.
- the diffusion region 7 is made of a pearl-like paint containing a pearl pigment formed by coating an inorganic pigment with a metal oxide on the lower surface of the black glass base material 10 and a silicon resin or siliceous sol. It is obtained by applying and baking as the lower first layer so as to represent a pattern such as.
- the light shielding layer 8 shields light other than the display portion.
- the light-shielding layer 8 is formed by applying a heat-resistant paint, which is made of a heat-resistant resin and an inorganic pigment, on the lower surface of the black glass base material 10 other than the diffusion region 7 and becomes opaque after firing as a second lower layer, and is fired. Can be obtained.
- the light shielding layer 8 should just be provided in parts other than the diffusion area
- the heating system of the to-be-heated cooking container 1 such as a pan in the present embodiment is induction heating as an example.
- the cooking device of the present invention is not limited to the induction heating method, and may be a sheathed heater, a radiant heater, a miraclon heater, a halogen heater, a gas, or the like.
- a high-frequency power supply device that supplies a high-frequency output to the heating body 4, a control device that controls them, a cooling device that suppresses heat generation, an operation unit that operates heating on and off, and a cooking container to be heated You may provide the temperature sensor etc. which detect temperature.
- the form of the display unit is arbitrary such as a figure, a character, and a pattern, and may be, for example, a substantially annular shape or a substantially semicircular shape arranged so as to surround the periphery of the heating body or the display device.
- This colored low expansion crystallized glass is mainly composed of Li 2 O—Al 2 O 3 —SiO 2 , for example, about 5% of nucleating agent TIO 2 and about 0.1% of coloring agent V 2 O 5.
- % Composition A batch raw material having this composition is melted at about 1700 ° C., the glass melt is molded, and then gradually cooled to room temperature. When the glass after annealing is heat-treated at a nucleation temperature of 750 to 800 ° C., about 5 nm of ZrTiO 4 crystal nuclei are precipitated.
- transition metal oxides such as Cr 2 O 3 , MnO 2 , Fe 2 O 3 , CoO, NiO, CuO, V 2 O 5 , and Bi 2 O 3 are used alone or in combination at an arbitrary ratio. To obtain a desired color tone.
- ⁇ -quartz solid solution crystal exhibits a negative expansion characteristic, and the remaining glass layer exhibiting a positive expansion characteristic cancels out and exhibits a substantially zero thermal expansion coefficient.
- Low thermal expansion generally indicates that the absolute value of the thermal expansion coefficient is 30 ⁇ 10 ⁇ 7 / ° C. or less.
- the bottom surface where the cooked cooking container 1 comes into contact with the top plate 2 is heated locally directly above the heating body 4 of the top plate 2.
- ambient temperature room temperature to about 100 ° C
- this crystallized glass is suitable for a cooking device having a large temperature difference between the bottom surface and the periphery of the top plate heated as described above.
- the diffusion region 7 is obtained by applying a pearl paint to at least a part of the first lower layer of the colorable low expansion crystallized glass 10.
- the pearl-tone paint includes a pearl pigment, a silicone resin or siliceous sol, and an organic binder.
- Pearl pigments include inorganic pigments such as kaolin, talc, sericite, pyroferrite, natural mica, synthetic mica, aluminum oxide, silicon oxide, borosilicate glass, titanium oxide, zirconium oxide, iron oxide, chromium oxide, tin oxide, oxidation
- a metal oxide such as zinc, cobalt oxide, boron oxide or the like is used alone or in combination at an arbitrary ratio and coated.
- the silicon resin is a polymer of an organosilicon compound having a siloxane bond as a main skeleton, and is obtained by dissolving a straight silicon varnish, a modified silicon varnish, a silicon alkyd varnish, a silicon epoxy varnish, etc. in an organic solvent as necessary.
- a siliceous sol a silica sol obtained by hydrolyzing ethyl silicate, a colloidal silica sol, or the like can be used.
- the organic binder acrylic resin, amide resin, alkyd resin, cellulose resin, or the like can be used.
- the pearl pigment for example, suspends mica powder in dilute titanic acid aqueous solution, heats it to 70-100 ° C, hydrolyzes the titanium salt, and precipitates hydrated titanium oxide particles on the mica powder surface. Then, it may be fired at a high temperature of 700 to 1000 ° C., and the mica as the inorganic pigment may be coated with titanium oxide as the metal oxide.
- the pearl paint may be composed of, for example, 1 to 30% by weight of pearl pigment, 1 to 30% silicone resin or siliceous sol, and 40 to 98% organic binder.
- the application of the pearl-like paint is preferably screen printing, and the diffusion region 7 can be obtained by applying and baking a pattern such as a figure, a symbol, or a character as the first lower layer of the colorable low expansion crystallized glass 10. it can.
- the diffusion region 7 diffuses and emits light substantially uniformly according to a pattern such as a figure, a symbol, or a character formed by the light transmission of the pearl pigment or the diffusion effect due to the reflection of light according to the light emission of the display device 5.
- a pattern such as a figure, a symbol, or a character formed by the light transmission of the pearl pigment or the diffusion effect due to the reflection of light according to the light emission of the display device 5.
- a pattern such as a figure, a symbol, or a character formed by the light transmission of the pearl pigment or the diffusion effect due to the reflection of light according to the light emission of the display device 5.
- by selectively arranging different meshes and changing the thickness of the film thickness it is possible to deal with various characteristics as diffusion regions.
- the film thickness is selected in the range of 1 to 20 ⁇ m according to the characteristics of the diffusion region 7 and is fired at a temperature of 700 to 900 ° C. If the film thickness is too thin, the diffusion effect as the diffusion region 7 cannot be exhibited. On the other hand, if it is too thick, the transmission effect is lost and the visibility of the display is lowered. Moreover, the performance as a coating film such as peeling or cracking is also reduced.
- the content of the silicon resin or the siliceous sol is 1% or less, the adhesion of the pearl paint may be lowered.
- the silicon resin or the siliceous sol covers the pearl pigment, the reduction of the diffusion effect and the transmission effect is lost, and the display visibility is lowered.
- the viscosity as a coating material deteriorates as the content of the organic binder decreases, problems such as unevenness and blurring occur in coating film formation.
- the light shielding layer 8 shields light other than the display portion.
- the light shielding layer 8 is obtained by applying a heat-resistant paint as a second lower layer on the lower surface of the colored low expansion crystallized glass 10 and other than the diffusion region.
- the light shielding layer 8 should just be provided in parts other than the diffusion area
- a heat-resistant resin containing a silicon resin, a polyamide resin, a fluororesin, or a composite thereof and a mixture of an inorganic pigment for coloring can be used.
- the inorganic pigment for coloring include TiO 2 , ZrO 2 , ZrSiO 4 , Al 2 O 3 , 3Al 2 O 3 -2SiO 2 , and Al 2 TiO 5 as white inorganic pigments.
- Black inorganic pigments include Cr-Fe oxides, Co-Mn-Cr-Fe oxides, Co-Ni-Cr-Fe oxides, Co-Ni-Cr-Fe-Mn oxides, etc. Is mentioned.
- examples of the gray inorganic pigment include Sn—Sb-based oxides and Sn—Sb—V-based oxides.
- examples of the yellow inorganic pigment include Sn—V oxides, Zr—V oxides, Zr—Si—Pr oxides, Ti—Cr—Sb oxides, and the like.
- brown inorganic pigment examples include Zn-Al-Cr-Fe-based oxides and Zn-Mn-Al-Cr-Fe-based oxides.
- examples of the green inorganic pigment include Ca—Cr—Si oxide, Cr—Al oxide, Co—Zn—Al—Cr oxide, Zr—Si—Pr—V oxide, and the like.
- examples of the blue inorganic pigment include Co—Al—Zn oxides, Co—Al oxides, and Zr—Si oxides.
- examples of the pink inorganic pigment include Mn—Al oxide, Ca—Sn—Si—Cr oxide, Sn—Cr oxide, Zr—Si—Fe oxide, and the like.
- These inorganic pigments for coloring can be mixed at an arbitrary ratio so as to obtain a desired color tone.
- heat-resistant paints are mass% and include 50% heat-resistant resin and 50% inorganic pigment.
- the proportion of the inorganic pigment is preferably 50% or less, and if the content exceeds 50%, the adhesiveness of the heat-resistant resin may be lowered.
- the heat-resistant paint is preferably applied by screen printing, and can selectively correspond to the characteristics of the light shielding layer 8 by changing the thickness of the film thickness by arranging different meshes.
- the film thickness of the heat-resistant paint is selected in the range of 1 to 30 ⁇ m according to the characteristics as the light shielding layer, and is fired at a temperature of 200 to 450 ° C. If the film thickness is too thin, the shielding property cannot be exhibited as a light shielding layer. On the other hand, if the film thickness is too thick, the performance as a coating film such as peeling or cracking deteriorates.
- FIG. 9 is a diagram showing the spectral transmittance of the black colored low-expansion crystallized glass (black glass substrate 10) of the heating cooker in the second embodiment of the present invention.
- the top plate 2 is a black colored low expansion crystallized glass mainly composed of Li 2 O—Al 2 O 3 —SiO 2 , containing a black colorant as an additive, and ⁇ -quartz solid solution as a main crystal. It is. For example, a thickness of about 4 mm was used.
- the manufacturing method is as described above.
- FIG. 9 shows the result of measuring the transmission spectrum of this black colored low-expansion crystallized glass glass using a spectrophotometer.
- the transmittance is 60% or less over the entire visible light range (380 to 760 nm). Further, in the infrared region (1000 to 2500 nm), the transmittance is 60% or more and an average of about 80%.
- This infrared transmittance is effective when a heating body exhibiting a radiation effect such as a halogen heater or a radiant heater is used as the heating body of the heating cooker of the present invention, and it is desirable that the infrared transmittance is as high as possible.
- infrared detection type non-contact type temperature sensor or the like is used as a temperature sensor in the cooking device of the present invention, and higher infrared transmittance is more effective for detection accuracy, resolution, and the like.
- the infrared transmittance is preferably 80% or more.
- the visible light transmittance is effective for the amount of light transmitted through the display device of the cooking device of the present invention, and JIS-Z-8513 (ergonomics—office work using a visual display device—requirements for a visual display device:
- the requirement for ensuring good visibility shown in the corresponding international standard ISO 9241-3) is preferably 35 cd / m 2 or more.
- the visible light transmittance is too high, a structure such as a display device or a heating body arranged inside the heating cooker of the present invention can be seen through the top plate when not heated, or diffusion used for the bottom surface of the top plate Since the imprint of the region can be seen through, it is necessary to optimize the visible light transmittance.
- the infrared transmittance and visible light transmittance are adjusted by using Cr 2 O 3 , MnO 2 , Fe 2 O 3 , CoO, NiO, CuO, V 2 O 5 , used as a coloring agent for the colored low expansion crystallized glass.
- a transition metal oxide such as Bi 2 O 3 may be added alone or in a mixture of a plurality at an arbitrary ratio to adjust light absorption, translucency, and reflectivity.
- the visible light here means a light wavelength in the range of 380 to 780 nm
- the infrared light means a light wavelength in the range of 1000 to 2500 nm.
- top plate 2 when the top plate 2 is viewed from the top surface of the top plate 2 in a room dimmed to a brightness of about 300 Lx using an illuminance meter, internal structures such as the display device 5 and the heating body 4 are seen through.
- the entire surface of the top plate 2 is black and substantially uniform and shows a flat feeling without being seen.
- a pearl-like paint using an inorganic pigment coated with a metal oxide on at least a part of the lower surface of a black colored low-expansion crystallized glass, and a pearl-tone paint using a silicon resin or siliceous sol are displayed in figures and symbols.
- the diffusion region 7 can be obtained by applying and baking as the first lower layer so as to express patterns such as letters.
- the diffusion region 7 emits light in a substantially uniform manner according to a pattern such as a figure, a symbol, or a character formed by a diffusion effect caused by light transmission or light reflection of the pearl pigment according to light emission of the display device 5.
- a pearl pigment having a particle diameter of 10 to 60 ⁇ m and a coating thickness of 200 nm or more obtained by coating natural mica that develops white pearl tone with titanium oxide was used.
- the pearl pigment was mixed with 30% by mass, silicon resin (containing 50% organic solvent) 30%, and the balance with an organic binder, a thickening resin, etc. to obtain a pearl paint.
- this pearl paint is applied as a first lower layer on the lower surface of a black colored low expansion crystallized glass as shown in FIG.
- the screen-shaped figure was screen-printed with a stainless mesh # 250 and fired at about 850 ° C. to obtain a diffusion region 7.
- the film thickness of the diffusion region 7 is about 5 ⁇ m.
- the top plate 2 configured as described above is an internal structure such as the display device 5 or the heating body 4 when viewed from the top surface of the top plate 2 in a room dimmed to a brightness of about 300 Lx using an illuminometer. Is not seen through, and the imprint of the diffusion region 7 is not seen through, and the entire surface of the top plate 2 is black and substantially uniform and shows a flat feeling.
- the top plate 2 is made of a heat resistant resin and an inorganic pigment on the lower surface of the black glass base material 10 on the lower surface of the black glass base material 10, and is coated with a heat resistant paint that becomes opaque after firing, and then fired.
- a light shielding layer 8 is formed for the purpose of light shielding.
- the light shielding layer 8 should just be provided in parts other than the diffusion area
- the light-shielding layer 8 is a heat-resistant paint mixed with 70% silicon resin (containing 50% organic solvent) and 30% Fe—Cr—Co black inorganic pigment in a mass%, as shown in FIGS. 5 (a) and 5 (b).
- screen printing was performed on the lower surface of the black colored low-expansion crystallized glass with a stainless mesh # 200 as a second lower layer on the portion other than the diffusion region 7 and fired at about 350 ° C.
- the film thickness is about 10 ⁇ m.
- the top plate 2 configured as described above is an internal structure such as the display device 5 or the heating body 4 when viewed from the top surface of the top plate 2 in a room dimmed to a brightness of about 300 Lx using an illuminometer. Is not seen through, and the imprint of the light shielding layer 8 is not seen through, and the entire surface of the top plate 2 is black and substantially uniform and shows a flat feeling.
- the design layer 6 of the first embodiment is formed without having the characteristics. It was confirmed that the top plate 2 can be formed.
- the display position varies depending on the angle viewed from the top surface of the top plate (particularly Visibility deterioration such as (looks deep inside) is improved.
- the restriction on the structure disposed in the vicinity of the display device is improved.
- the structure of light emitting elements such as LEDs and light guides used in this display device, the case of the display device, etc.
- the body can be formed of an inexpensive material with low heat resistance.
- the internal structure of the display device, heating element, etc. is not seen through, and it has both light shielding properties and translucency, and the color of the entire top plate is uniform when viewed from the top surface of the top plate. It is possible to provide an inexpensive and easy-to-use heating cooker with a flat design and high design.
- an adjustable heating cooker that can obtain the amount of light necessary for visibility, reduce the number of light emitting elements such as LEDs by a diffusion effect, and arrange a light guide. It is possible to provide a cooking device that can be simplified and rationalized such that it becomes unnecessary.
- black colored low expansion crystallized glass black glass substrate 10
- the present invention particularly has a light-shielding property and a light-transmitting property in a display device using a top plate of a heating cooker using a black top plate and a light emitting element such as an LED, and from the top surface of the top plate.
- a table type, stationary type, or built-in type induction heating cooker used in a general household dining table, cooking table, sink, etc. It can also be applied to cooking devices other than the built-in type.
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Abstract
Description
前記天板を上面に配して本体を構成する外郭ケースと、
前記天板の上方の被加熱調理容器を加熱する加熱体と、
前記外郭ケースの中に設けられ、前記加熱体による加熱状態等を表示するための発光手段と、
を備えた加熱調理器であって、
前記天板は、
Li2O-Al2O3-SiO2を主成分とし、β-石英固溶体を主結晶とする結晶化ガラスであって、結晶の大きさが可視光の波長よりも小さい透明な透光性低膨張結晶化ガラスで構成されたガラス基材と、
前記ガラス基材の下面に設けられ、黒系統の色彩を有する意匠層と、
前記意匠層の下面の一部に設けられ、無機顔料を金属酸化物により被覆してなるパール顔料を含み、前記発光手段からの光を拡散発光する拡散領域と、
前記意匠層の下面であって、少なくとも前記拡散領域以外の部分に設けられ、無機顔料を有し、下方からの光を遮光する遮光層と、
を有する。
前記天板を上面に配して本体を構成する外郭ケースと、
前記天板の上方の被加熱調理容器を加熱する加熱体と、
前記外郭ケースの中に設けられ、前記加熱体による加熱状態等を表示するための発光手段と、
を備えた加熱調理器であって、
前記天板は、
Li2O-Al2O3-SiO2を主成分とし、β-石英固溶体を主結晶とする結晶化ガラスであって、結晶の大きさが可視光の波長よりも小さい透明な透光性低膨張結晶化ガラスで構成されたガラス基材と、
前記ガラス基材の下面に設けられ、黒系統の色彩を有する意匠層と、
前記意匠層の下面の一部に設けられ、無機顔料を金属酸化物により被覆してなるパール顔料を含み、前記発光手段からの光を拡散発光する拡散領域と、
前記意匠層の下面であって、少なくとも前記拡散領域以外の部分に設けられ、無機顔料を有し、下方からの光を遮光する遮光層と、
を有する。
前記天板を上面に配して本体を構成する外郭ケースと、
前記天板の上方の被加熱調理容器を加熱する加熱体と、
前記外郭ケースの中に設けられ、前記加熱体による加熱状態等を表示するための発光手段と、
を備えた加熱調理器であって、
前記天板は、
Li2O-Al2O3-SiO2を主成分とし、黒系統の着色剤を添加物として含み、β-石英固溶体を主結晶とする黒系統の着色低膨張結晶化ガラスで構成された黒系統ガラス基材と、
前記黒系統ガラス基材の下面の一部に設けられ、無機顔料を金属酸化物により被覆してなるパール顔料を含み、前記発光手段からの光を拡散発光する拡散領域と、
前記黒系統ガラス基材の下面であって、少なくとも前記拡散領域以外の部分に設けられ、無機顔料を有し、下方からの光を遮光する遮光層と、
を有する。
この構成により、特に黒系統の天板を用いた加熱調理器の天板およびLED等の発光素子を用いた表示装置において、視認性に必要な可視光の光量を得られるとともに、赤外線透過率を高め、付加価値の高い加熱調理器を提供できる。
この構成により、特に黒系統の天板を用いた加熱調理器の天板およびLED等の発光素子を用いた表示装置において、視認性に必要な可視光の光量を得られるとともに、赤外線透過率を高め、付加価値の高い加熱調理器を提供できる。
以下、本発明の実施の形態について、図面を参照しながら説明する。なお、この実施の形態によって本発明が限定されるものではない。ここで、実施の形態の説明順序は上記に記載の発明の順序とは異なる場合がある。また、複数の発明を包括して説明している場合もある。
図1~図5は、本発明における実施の形態1における加熱調理器の概略構成等を示す概略図である。但し、実施の形態の説明に不要な構成部分については主要構成であっても省略している。以下、図面を用いて説明する。
天板2は、透光性低膨張結晶化ガラス9と、透光性低膨張結晶化ガラス9の下面に設けられた黒系統の色彩を有する意匠層6と、意匠層6の下面の少なくとも一部に設けられ、表示装置5の発光に応じて拡散発光する拡散領域7と、意匠層6の下面であって、拡散領域7以外の部分に設けられ下方からの光を遮光する遮光層8と、を有する。
透光性低膨張結晶化ガラス9は、Li2O-Al2O3-SiO2を主成分とし、β-石英固溶体を主結晶とする透明な結晶化ガラス(ガラス基材9)で、その結晶の大きさが可視光の波長よりも小さい。
意匠層6は、天板2上面から見たときの黒系統の色彩を天板2の全面に略均一に表現する。この意匠層6は、天板2の下面に黒系統の色彩を有する有機金属化合物の希釈溶液を用いたラスター彩塗料を下面第一層目として塗布し焼成することによって得られる。
拡散領域7は、表示装置5の発光に応じてパール顔料の光の透過性や光の反射による拡散効果によって形成した図形や記号、文字等の模様に応じて略均一に拡散発光する。この拡散領域7は、意匠層6の下面に、無機顔料を金属酸化物により被覆してなるパール顔料と、シリコンレジン又はシリカ質ゾルと、を含むパール調塗料を図形や記号、文字等の模様を表すように下面第二層目として塗布し焼成することによって得られる。
遮光層8は、表示部以外の光を遮光する。この遮光層8は、意匠層6の下面に拡散領域7以外の部分に、耐熱樹脂と無機顔料等からなり、焼成後に不透明になる耐熱塗料を下面第三層目として塗布し焼成することによって得られる。なお、遮光層8は、少なくとも拡散領域7以外の部分に設けられ、拡散領域7の少なくとも一部が露出していればよい。すなわち、遮光層8は、少なくとも拡散領域7の周囲に設けられていれば良く、さらに、遮光層8は、拡散領域7の周縁と一部重なるように形成してもよい。
<透光性低膨張結晶化ガラス>
透明な透光性低膨張結晶化ガラス9は、Li2O-Al2O3-SiO2を主成分とする。
この透光性低膨張結晶化ガラス9の製造方法について説明する。たとえば、SiO2,A12O3,Li2O,TiO2,ZrO2,P2O5,BaO,Na2O+K2O,As2O3等のバッチ原料に消泡剤などを加えて混合し、約1700℃で溶融し,そのガラス融液を成形した後、常温まで徐冷する。
意匠層6は、黒系統の色彩を有する。この意匠層6は、ラスター彩塗料を透光性低膨張結晶化ガラス9の下面第一層目に塗布して得られる。
また、ラスター彩塗料は、Au,Pt,Pd,Rh,Ru,Bi,Sn,Ni,Fe,Cu,Cr,Ti,Ca,Si,Ba,Sr,Mg,Ag,Zr,In,Mn等の金属を単独もしくは任意の割合で複数混合し、コロホニウム、バルサム、アスファルト等の樹脂を含有した有機金属酸化物の希釈溶液として得られる。
拡散領域7は、パール調塗料を意匠層の下面の少なくとも一部に透光性低膨張結晶化ガラス9の下面第二層目として塗布して得られる。
パール調塗料としては、パール顔料と、シリコンレジン又はシリカ質ゾルと、有機バインダーと、を含む。
パール顔料は、カオリン、タルク、セリサイト、パイロフェライト、天然雲母、合成雲母、酸化アルミニウム、酸化ケイ素、ホウ珪酸ガラス等の無機顔料を酸化チタン、酸化ジルコニウム、酸化鉄、酸化クロム、酸化スズ、酸化亜鉛、酸化コバルト、酸化ホウ素等の金属酸化物を単独もしくは任意の割合で複数混合し、被覆してなる。
シリコンレジンは、シロキサン結合を主骨格とする有機珪素化合物の重合体で、ストレートシリコンワニス、変性シリコンワニス、シリコンアルキッドワニス、シリコンエポキシワニス等を必要に応じて有機溶剤にて溶解して得られる。
シリカ質ゾルは、エチルシリケートを加水分解して得られるシリカゾル、コロイド状シリカゾルなどを用いることができる。
有機バインダーは、アクリル系樹脂、アミド系樹脂、アルキッド系樹脂、セルロース系樹脂などを用いることができる。
遮光層8は、表示部以外の光を遮光する。この遮光層8は、耐熱塗料を意匠層6の下面の拡散領域7以外の部分に透光性低膨張結晶化ガラス9の下面第三層目として塗布して得られる。なお、遮光層8は、少なくとも拡散領域7以外の部分に設けられ、拡散領域7の少なくとも一部が露出していればよい。すなわち、遮光層8は、少なくとも拡散領域7の周囲に設けられていれば良く、さらに、遮光層8は、拡散領域7の周縁と一部重なるように形成してもよい。
耐熱塗料としては、シリコン樹脂、ポリアミド樹脂、フッ素樹脂もしくはこれらの複合体を含む耐熱樹脂に、着色用の無機顔料を加えて混合したものを用いることができる。
意匠層6を構成するラスター彩塗料の成分については、Au,Pt,Pd,Rh,Ru,Bi,Sn,Ni,Fe,Cu,Cr,Ti,Ca,Si,Ba,Sr,Mg,Ag,Zr,In,Mn等の有機金属化合物に用いる金属を単独もしくは任意の割合で複数混合し、色調や光沢感によって透過性、反射性を調整できる。ラスター彩塗料の膜厚については0.1~10μmの範囲で任意に調整することで透光性、反射性を調整できる。ラスター彩塗料の濃度についてはスクリーン印刷によるメッシュの大きさを#60~#500の範囲で任意に調整することで透過性、反射性を調整できる。なお、特にラスター彩塗料の膜厚は0.1~5μm範囲、メッシュの大きさは#150~#350の範囲が好ましい。
図8及び図9は、本発明における実施の形態2における加熱調理器の概略構成等を示す。本実施の形態2では、実施の形態1におけるガラス基材9を、黒系統ガラス基材10とした。また、実施の形態の説明に不要な構成部分については一部省略している。以下、図面を用いて説明する。
天板2は、着色低膨張結晶化ガラス(黒系統ガラス基材10)と、黒系統ガラス基材10の下面の少なくとも一部に設けられ、表示装置5の発光に応じて拡散発光する拡散領域7と、黒系統ガラス基材10の下面であって、拡散領域7以外の部分に設けられ下方からの光を遮光する遮光層8と、を有する。
黒系統ガラス基材10は、Li2O-Al2O3-SiO2を主成分とし、黒系統の着色剤を添加剤として含み、β-石英固溶体を主結晶とする黒系統の着色低膨張結晶化ガラス(黒系統ガラス基材10)である。
拡散領域7は、表示装置5の発光に応じてパール顔料の光の透過性や光の反射による拡散効果によって形成した図形や記号、文字等の模様に応じて略均一に拡散発光する。この拡散領域7は、黒系統ガラス基材10の下面に、無機顔料を金属酸化物により被覆してなるパール顔料と、シリコンレジンまたはシリカ質ゾルと、を含むパール調塗料を図形や記号、文字等の模様を表すように下面第一層目として塗布し焼成することによって得られる。
遮光層8は、表示部以外の光を遮光する。この遮光層8は、黒系統ガラス基材10の下面の拡散領域7以外の部分に、耐熱樹脂と無機顔料等からなり、焼成後に不透明になる耐熱塗料を下面第二層目として塗布し焼成することによって得られる。なお、遮光層8は、少なくとも拡散領域7以外の部分に設けられ、拡散領域7の少なくとも一部が露出していればよい。すなわち、遮光層8は、少なくとも拡散領域7の周囲に設けられていれば良く、さらに、遮光層8は、拡散領域7の周縁と一部重なるように形成してもよい。
<着色低膨張結晶化ガラス(黒系統ガラス基材10)>
この着色低膨張結晶化ガラスは、Li2O-Al2O3-SiO2を主成分とし、たとえば核形成剤のTIO2を約5%と、着色剤のV2O5を約0.1%含有した組成である。
この組成のバッチ原料を約1700℃で溶融し、そのガラス融液を成形した後、常温まで徐冷する。徐冷後のガラスを750~800℃の核形成温度で熱処理すると、約5nmのZrTiO4結晶核が析出する。続いて850~950℃の温度域で熱処理すると、結晶核の上にβ-石英固溶体結晶(Li2O・Al2O3・nSiO2,n≧2)が約50nmの大きさに成長して、約70質量%の結晶相と約30質量%の残存するガラス相が複合化し、VとTiによる黒系統の着色低膨張結晶化ガラスになる。
この結晶化ガラスは、結晶の大きさが可視光の波長よりも小さく、ある程度の可視光線は透過するとともに、約30質量%の残存するガラス相にTi(核形成剤の一部)とVが濃縮されて可視光を吸収し、反射光で黒色に見える。
拡散領域7は、パール調塗料を着色性低膨張結晶化ガラス10の下面第一層目の少なくとも一部に塗布して得られる。
パール調塗料としては、パール顔料と、シリコンレジン又はシリカ質ゾルと、有機バインダーと、を含む。
パール顔料は、カオリン、タルク、セリサイト、パイロフェライト、天然雲母、合成雲母、酸化アルミニウム、酸化ケイ素、ホウ珪酸ガラス等の無機顔料を酸化チタン、酸化ジルコニウム、酸化鉄、酸化クロム、酸化スズ、酸化亜鉛、酸化コバルト、酸化ホウ素等の金属酸化物を単独もしくは任意の割合で複数混合し、被覆してなる。
シリコンレジンは、シロキサン結合を主骨格とする有機珪素化合物の重合体で、ストレートシリコンワニス、変性シリコンワニス、シリコンアルキッドワニス、シリコンエポキシワニスなどを必要に応じて有機溶剤にて溶解して得られる。
シリカ質ゾルは、エチルシリケートを加水分解して得られるシリカゾル、コロイド状シリカゾルなどを用いることができる。
有機バインダーは、アクリル系樹脂、アミド系樹脂、アルキッド系樹脂、セルロース系樹脂などを用いることができる。
また、選択的に異なるメッシュを配置して膜厚の濃淡を変えて各種の拡散領域としての特性に対応することができる。膜厚は1~20μmの範囲で拡散領域7としての特性に応じて選択し、700~900℃の温度で焼成する。膜厚は薄すぎると拡散領域7としての拡散効果を発揮することができない。また、厚すぎると透過効果がなくなり表示の視認性が低下する。また、剥離やクラック等の塗膜としての性能も低下する。
また、有機バインダーの含有量の低下にともない塗料としての粘調性が悪化するため、塗膜形成においてムラやかすれ等の不具合が発生する。
遮光層8は、表示部以外の光を遮光する。この遮光層8は、耐熱塗料を着色性低膨張結晶化ガラス10の下面であって、拡散領域以外の部分に下面第二層目として塗布して得られる。なお、遮光層8は、少なくとも拡散領域7以外の部分に設けられ、拡散領域7の少なくとも一部が露出していればよい。すなわち、遮光層8は、少なくとも拡散領域7の周囲に設けられていれば良く、さらに、遮光層8は、拡散領域7の周縁と一部重なるように形成してもよい。
耐熱塗料としては、シリコン樹脂、ポリアミド樹脂、フッ素樹脂もしくはこれらの複合体を含む耐熱樹脂に、着色用の無機顔料を加えて混合したものを用いることができる。
2 天板
3 外郭ケース
4 加熱体
5 表示装置
6 意匠層
7 拡散領域
8 遮光層
9 ガラス基材
10 黒系統ガラス基材
Claims (8)
- 被加熱調理容器を載置する天板と、
前記天板を上面に配して本体を構成する外郭ケースと、
前記天板の上方の被加熱調理容器を加熱する加熱体と、
前記外郭ケースの中に設けられ、前記加熱体による加熱状態等を表示するための発光手段と、
を備えた加熱調理器であって、
前記天板は、
Li2O-Al2O3-SiO2を主成分とし、β-石英固溶体を主結晶とする結晶化ガラスであって、結晶の大きさが可視光の波長よりも小さい透明な透光性低膨張結晶化ガラスで構成されたガラス基材と、
前記ガラス基材の下面に設けられ、黒系統の色彩を有する意匠層と、
前記意匠層の下面の一部に設けられ、無機顔料を金属酸化物により被覆してなるパール顔料を含み、前記発光手段からの光を拡散発光する拡散領域と、
前記意匠層の下面であって、少なくとも前記拡散領域以外の部分に設けられ、無機顔料を有し、下方からの光を遮光する遮光層と、
を有する、加熱調理器。 - 被加熱調理容器を載置する天板と、
前記天板を上面に配して本体を構成する外郭ケースと、
前記天板の上方の被加熱調理容器を加熱する加熱体と、
前記外郭ケースの中に設けられ、前記加熱体による加熱状態等を表示するための発光手段と、
を備えた加熱調理器であって、
前記天板は、
Li2O-Al2O3-SiO2を主成分とし、黒系統の着色剤を添加物として含み、β-石英固溶体を主結晶とする黒系統の着色低膨張結晶化ガラスで構成された黒系統ガラス基材と、
前記黒系統ガラス基材の下面の一部に設けられ、無機顔料を金属酸化物により被覆してなるパール顔料を含み、前記発光手段からの光を拡散発光する拡散領域と、
前記黒系統ガラス基材の下面であって、少なくとも前記拡散領域以外の部分に設けられ、無機顔料を有し、下方からの光を遮光する遮光層と、
を有する、加熱調理器。 - 前記天板は、前記ガラス基材及び前記意匠層の部分の、前記天板の上方への赤外線透過率が60%以上で、かつ可視光線透過率が60%以下である、請求項1に記載の加熱調理器。
- 前記天板は、前記黒系統ガラス基材の部分の、前記天板の上方への赤外線透過率が60%以上で、かつ可視光線透過率が60%以下である、請求項2に記載の加熱調理器。
- 前記天板は、前記ガラス基材及び前記意匠層及び前記拡散領域、もしくは前記黒系統ガラス基材及び前記拡散領域の部分の、前記発光手段からの光の透過する光量が35cd/m2以上である、請求項1から4のいずれか一項に記載の加熱調理器。
- 前記拡散領域は、色調を調整する無機顔料を含む、請求項1から5のいずれか一項に記載の加熱調理器。
- 前記パール顔料は、粒径が可視光線の波長より大きく、1~500μmの範囲である、請求項1から6のいずれか一項に記載の加熱調理器。
- 前記パール顔料は、無機顔料を被覆する金属酸化物の粒径が可視光線の波長より小さい200nm以下であって、前記金属酸化物の被覆の厚みが1~500nmである、請求項1~7のいずれか1項に記載の加熱調理器。
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CN201480052094.5A CN105580494B (zh) | 2013-11-06 | 2014-11-06 | 加热烹调器 |
US15/031,508 US9863643B2 (en) | 2013-11-06 | 2014-11-06 | Heating cooker |
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US20160258631A1 (en) | 2016-09-08 |
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EP3068192B1 (en) | 2018-04-11 |
ES2671729T3 (es) | 2018-06-08 |
JP6260836B2 (ja) | 2018-01-17 |
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