WO2015018813A1 - Compositions réfractaires à mouler et leur utilisation dans la formation et la réparation de revêtements réfractaires monolithiques - Google Patents

Compositions réfractaires à mouler et leur utilisation dans la formation et la réparation de revêtements réfractaires monolithiques Download PDF

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Publication number
WO2015018813A1
WO2015018813A1 PCT/EP2014/066778 EP2014066778W WO2015018813A1 WO 2015018813 A1 WO2015018813 A1 WO 2015018813A1 EP 2014066778 W EP2014066778 W EP 2014066778W WO 2015018813 A1 WO2015018813 A1 WO 2015018813A1
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Prior art keywords
castable refractory
refractory composition
castable
homogenised
mixture
Prior art date
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PCT/EP2014/066778
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English (en)
Inventor
Indra Nath CHAKRABORTY
Saumen SINHA
Rajesh Tilakchand BISEN
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Calderys France
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Priority to EP20172148.7A priority Critical patent/EP3705463A1/fr
Priority to DK14758304.1T priority patent/DK3030535T3/da
Priority to EP14758304.1A priority patent/EP3030535B1/fr
Priority to EA201690338A priority patent/EA036340B1/ru
Priority to JP2016532659A priority patent/JP6670748B2/ja
Publication of WO2015018813A1 publication Critical patent/WO2015018813A1/fr

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    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/422—Carbon
    • C04B2235/425—Graphite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/428—Silicon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5427—Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5463—Particle size distributions
    • C04B2235/5472—Bimodal, multi-modal or multi-fraction
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/72—Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
    • C04B2235/721—Carbon content
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Definitions

  • the present invention concerns magnesia-based castable refractory compositions.
  • the invention further concerns the use of the magnesia-based castable refractory compositions, as well as methods for producing monolithic refractory linings using said magnesia-based castable refractory compositions.
  • Refractories are materials having properties that make them suitable for use as heat-resistant barriers in high temperature applications.
  • Magnesia (magnesium oxide, MgO) refractory materials have been used extensively in the ferrous and non- ferrous industries as linings for metallurgical vessels, ladles, furnaces, crucibles and other equipment, to protect against the chemical and mechanical strains caused by liquidised metal and/or slag.
  • Magnesia refractories often contain substantial amounts of elemental carbon or carbonaceous compounds to improve performance.
  • magnesia linings have been produced by assembling magnesia or magnesia-carbon bricks against an interior wall of the vessel or equipment to be protected.
  • unshaped refractory materials have the ability to form joint-less linings and are often referred to as monolithics.
  • Monolithics are particularly useful as linings for cupola hearths and siphons, blast furnaces, main, secondary and tilting runners, and more generally vessels or vessel spouts, ladles, tundishes, reaction chambers and troughs that contain, direct the flow of, or are suitable for facilitating industrial treatment of liquid metals and slags, or of any other high temperature liquids, solids or gases.
  • Magnesium oxide (monolithic) refractories are preferably used in areas where slags and atmospheres are basic, since they are stable to alkaline materials.
  • Magnesia has a strong affinity to water, in liquid or gaseous form, and reacts with water to form brucite.
  • the formation or presence of hydrated magnesia in a refractory composition has a strong detrimental impact on the final performance of a monolithic refractory lining.
  • the flaky structure of brucite crystals formed around magnesia particles can form lumps in a particulate refractory composition, which inhibits the casting process after formation of a castable (wet) mixture. If hydration of magnesia occurs after installation of a lining, this can result in cracking of the lining, since the transformation of magnesia into brucite takes place with a high volume expansion.
  • additives have been used that are intended to inhibit MgO hydration, such as for example tartaric acid, citric acid, boric acid, magnesium fluoride and microsilica.
  • MgO hydration such as for example tartaric acid, citric acid, boric acid, magnesium fluoride and microsilica.
  • the presence of such additives however has detrimental effects on flow properties, mechanical resistance, refractoriness (stability at elevated temperature), cost, among others.
  • magnesia-carbon monolithic formulations are not generally available.
  • Castable magnesia compositions may be used as gunning materials for repairing magnesia-carbon brick linings.
  • the provision of castable magnesia-carbon compositions would on the one hand allow the installation of monolithic magnesia- carbon linings, and on the other hand the use of these composition as a gunning material for repairing magnesia-carbon brick linings having improved compatibility with the brick linings.
  • MOR modulus of rupture
  • CCS cold crushing strength
  • the present invention is embodied by a castable refractory composition consisting dry and wet fractions (liquid constituents), each fraction comprising a plurality of dry or wet components, as the case may be.
  • the castable refractory composition according to the present invention comprises, based on the total weight of the castable refractory composition, between 50 wt.-% and 99 wt.-% of a magnesia aggregate material, and between 0.1 wt.-% and 10 wt.-% carbonaceous material, and between 0.1 wt.-% and 5 wt.-% antioxidant, and a non-aqueous binder.
  • the water content of the castable refractory composition is 2 wt.-% or less, and the fixed carbon in the composition is no more than about 10 wt.-%.
  • the antioxidant may be selected from one or more carbide materials, or from one or more nitride materials, or from one or more boride materials, or from one or more metals or metal alloys, or from combinations thereof.
  • the carbonaceous material of the composition is at least partially present in a coating on the surface of the magnesia aggregate material of the composition.
  • a coating on the surface of the magnesia aggregate material further comprises one or more non-aqueous binders, or one or more solid hydrocarbons, or one or more antioxidants, or a combination thereof.
  • the carbonaceous material present in the castable refractory composition is selected from natural graphite, synthetic graphite, petcoke, carbon black, fusible carbon, pitch, and combinations thereof.
  • the antioxidant present in the castable refractory composition is selected from boron carbide, silicon carbide, silicon nitride, calcium boride, zirconium boride, aluminium metal, zinc metal, silicon metal, one or more aluminium-magnesium alloys, one or more zinc-magnesium alloys, one or more zinc-aluminium-magnesium alloys, or combinations thereof, such as for example aluminium metal and/or boron carbide.
  • the non-aqueous binder present in the castable refractory composition comprises one or more phenolic resins or one or more epoxy-compounds, or a combination thereof.
  • the non-aqueous binder present in the castable refractory composition comprises one or more esterified fatty acids, such as esterified vegetable oils or biodiesels, or combinations thereof.
  • the esterified fatty acid may have a molecular weight ranging in the range of 1 ,000 to 10,000 and/or a viscosity in the range of 20 to 150 cps.
  • the castable refractory composition may further comprise one or more additives, such as, for example, dispersants, viscosity modifiers, hardeners, accelerators, surfactants, and/or cross-linking catalysts.
  • additives such as, for example, dispersants, viscosity modifiers, hardeners, accelerators, surfactants, and/or cross-linking catalysts.
  • Also part of the present invention is the use of a castable refractory composition in the formation or repair of a monolithic refractory composition by a casting, spray-casting, gunning, self-flowing, ramming, shotcrete or patching process, for example in the formation of a monolithic refractory lining.
  • Also part of the present invention is a method of making a monolithic refractory lining comprising the steps of providing a mixture of at least a portion of said plurality of dry components to obtain a dry mix, providing a mixture of one or more liquid components, excluding hardeners, to obtain a liquid mixture, mixing the provided dry mix with the provided liquid mixture and optionally adding one or more nonaqueous binders to obtain a homogenised castable refractory composition, installing the obtained homogenised castable refractory composition using a casting, vibration casting, spray-casting, gunning, self-flowing, ramming, or shotcrete process, and curing the installed homogenised castable refractory composition to obtain a monolithic refractory lining.
  • one or more hardeners are added to the homogenised castable refractory composition prior to the installation step.
  • At least a portion of the carbonaceous material is included in the mixture of one or more of the liquid components when providing the mixture of one or more liquid components.
  • the method is used to provide monolithic refractory linings having a modulus of rupture (MOR) in the range of 50 kg/cm 2 or more, such as from 50 to 200 kg/cm 2 , and/or a cold crushing strength (CCS) in the range of 100 kg/cm 2 such as form 100 to 400 kg/cm 2 , and/or a porosity in the range of 5 to 12%.
  • MOR modulus of rupture
  • CCS cold crushing strength
  • the curing in the final step of the method may be carried out at a temperature of 150°C to 250°C, such as at a temperature of 180°C to 220°C, for example at about 200°C, for 12 to 36 h, for example for about 24 h.
  • Also part of the present invention is a method of repairing a monolithic refractory lining comprising the steps of providing a mixture of at least a portion of said plurality of dry components to obtain a dry mix, providing a mixture of one or more liquid components, excluding hardeners, to obtain a liquid mixture, mixing the provided dry mix with the provided liquid mixture and optionally adding one or more nonaqueous binders to obtain a homogenised castable refractory composition, applying the said homogenised castable refractory composition obtained at the end of step (c) to the monolithic refractory lining to be repaired, using a patching process; and curing said applied homegenised castable refractory composition obtained at the end of step (e) to obtain a repaired monolithic refractory lining.
  • one or more hardeners are added to the homogenised castable refractory composition prior to the installation step.
  • the present invention provides an essentially water-free magnesia-based composition for use as a castable refractory material. It has been found that a combination of non-aqueous binders, anti-oxidants and carbonaceous materials with magnesia aggregate material provides castable refractory compositions that may be used either for the production of monolithic refractory linings, or as gunnable compositions for repairing damaged refractory (brick) structures.
  • the castable refractory composition comprises 50 wt.-% to 99 wt.-% MgO, such as aggregate MgO.
  • the magnesia content of the castable refractory composition may be above about 60 wt.-%, such as for example above about 70 wt.-%, such as for example from about 80 wt.-% to 98 wt.-%, or from about 85 wt.-% to 95 wt.-%.
  • the magnesia comprised in the castable refractory composition according to the present invention may be commercially available fused magnesia, which normally has a purity of about 97 %.
  • the magnesia comprised in the castable refractory composition according to the present invention may have a broad particle size distribution below 5 mm, such that it comprises substantial amounts of particles having a particle diameter of 2 to 5 mm, and of particles having a diameter of 1 to 2 mm, and of particles having a diameter of 0.5 to 1 mm, and of particles having a diameter below 0.5 mm, and of particles having a size of 170 mesh (88 ⁇ ) or below.
  • the particle size distribution of the magnesia used in the castable refractory composition according to the present invention is a multimodal distribution, such as for example a bimodal distribution.
  • a bimodal particle size distribution the representing curve of which exhibits two distinct peaks, in and a multimodal the representing curve of which exhibits two or more distinct peaks.
  • the curve representing the particle size distribution of the magnesia comprised in the castable refractory composition according to the present invention may have a first maximum peak at a particle size between 2 and 5 mm, and a second maximum peak at a particle size smaller than 88 ⁇ .
  • the curve representing the particle size distribution of the magnesia comprised in the castable refractory composition according to the present invention may have a first maximum peak at a particle size between 2 and 5 mm, and three further maximum peaks at particle sizes of about 40 ⁇ , about 18 ⁇ and at about 4 ⁇ .
  • the magnesia comprised in the composition according to the present invention may comprise an ultrafine component, consisting of (a) ground magnesia (fused magnesia or sea water dead burned magnesia or earth dead burned magnesia) with a d 50 between 1 .5 and 4 ⁇ , or close to crystal size; or (b) a precipitated (caustic) magnesia having a d 5 o below 1 .5 ⁇ and a BET specific surface area in the range of 5 to 500 m 2 -g "1 ; or (c) magnesia resulting from chemical disintegration of magnesium silicates and having a BET specific surface area in the range of 1 to 10 m 2 -g "1 .
  • an ultrafine component consisting of (a) ground magnesia (fused magnesia or sea water dead burned magnesia or earth dead burned magnesia) with a d 50 between 1 .5 and 4 ⁇ , or close to crystal size; or (b) a precipit
  • the carbonaceous material comprised in the castable refractory composition according to the present invention may be selected from a broad variety of carbonaceous compounds, including natural graphite, synthetic graphite, petcoke, carbon black, fusible carbon, pitch and combinations thereof.
  • the carbonaceous material may be selected such that the total castable refractory composition according to the present invention does not comprise more than 10 wt.-% fixed carbon .
  • the skilled person in the art will appreciate that the liquid components of the composition according to the invention will not provide any fixed carbon to the composition. The fixed carbon in the product will thus only originate from the solid carbonaceous materials. In one embodiment, it is not preferred that the carbonaceous material is selected from tar, wood or charcoal.
  • the carbonaceous material is present as medium thermal carbon black. In one embodiment, the carbonaceous material is at least partially present as graphite flakes having an average particle size smaller than 72 mesh (below 200 m).
  • the carbonaceous material is at least partially present in the castable refractory composition according to the invention as graphite in a coating on the surface of the magnesia particles.
  • Coated magnesia particles are obtained by mixing graphite particles with an organic binder, followed by treatment of the magnesia particles with said graphite/binder combination.
  • the use of graphite in coatings on magnesia particles according to the present invention has the advantage that commonly occurring surface chemistry problem of graphite, such as reduced wettability and high shape factor leading to poor mixing properties in the castable and reduced fluidity thereof, are avoided.
  • Antioxidant is at least partially present in the castable refractory composition according to the invention as graphite in a coating on the surface of the magnesia particles.
  • the antioxidant comprised in the castable refractory composition according to the present invention is selected from one or more carbide materials, or from one or more nitride materials, or from one or more boride materials, or from one or more metals or metal alloys, or from combinations thereof. More specifically, it may be selected from a variety of species, including boron carbide, silicon carbide, silicon nitride, calcium boride, zirconium boride, aluminium metal, zinc metal, silicon metal, barium metal, titanium metal, aluminium-magnesium alloys, zinc-magnesium alloys, zinc-aluminium-magnesium alloys, and combinations thereof.
  • the antioxidant is aluminium metal and/or boron carbide, such as for example a mixture of aluminium metal and boron carbide.
  • aluminium metal may be present in the castable refractory composition according to the present invention in an amount of 0.1 wt.-% to 5 wt.-%, such as for example in an amount of 1 wt.-% to 3 wt.-%, such as for example about 2 wt.-%.
  • boron carbide may be present in the castable refractory composition according to the present invention in an amount of 0.1 wt.-% to 5 wt.-%, such as for example in an amount of 0.5 wt.-% to 2 wt.-%, such as for example about 1 wt.-%.
  • the antioxidant is selected from ferrosilicon nitride, from SiAION (oxinitrides), or from alkali metals.
  • the non-aqueous binder comprised in the castable refractory composition according to the present invention may be selected from (a) polyhydric compounds, (b) epoxy compounds, optionally in combination with amine hardeners, (c) isocyanates, (d) reaction rate modifying agents or cross-linking agents, (e) polyester resins, (g) diluents, (h) surface active agents, and combinations thereof.
  • polyhydric compounds for use as non-aqueous binders comprised in the castable refractory composition according to the present invention may be selected from phenolic resole resins, polyether polyols including polyethylene glycol, polypropylene glycol, polytetramethlyene glycol; polyester polyols from aliphatic and/or aromatic polycarbonates, polycaprolactones, adipates, terephthalates and mixtures thereof.
  • polyhydroxylated natural oils and/or their derivatives such as linseed oil, and castor oil.
  • the inherent water content of the hydroxide bearing component does not exceed 2.0 wt.-%.
  • the polyfunctional hydric compounds utilised in the present invention may have a molecular weight of 600 or above and a functionality of 2 or more.
  • specific polyhydric compounds further include but are not limited to Valires RO 100.02, Valires RO 100.42, Valires RD 300.25, Corrosol 433264, such compounds as described in "Chemistry and Technology of Polyols for Polyurethanes", as published by Smithers Information Limited (January 2005) on pages 400 to 407, 424 to 431 and 439 to 455.
  • the polyhydric component or mixture of components should be comprised in the castable refractory composition according to the invention in an amount in the range from 1 .0 to 6.0 wt.-%, based upon total mass of the composition.
  • epoxy-compounds for use as non-aqueous binders comprised in the castable refractory composition according to the present invention may be a liquid having an equivalent epoxy weight in the range 150 to 250 (g/eq).
  • the viscosity of the epoxy resin may be in the range of from 500 to 20000 mPa.s, such as in the range of from 500 to 15000mPa.s.
  • the functionality of the epoxy resin may be 2 or more glycidyl groups per molecule.
  • a suitable epoxy staring material may be an epichlorohydrin-functionalised novolac resin (available under the trade name D.E.N.
  • the epoxy-compounds or mixture thereof may be comprised in the castable refractory composition according to the invention in an amount in the range from 1.0 to 6.0 wt.-%, based upon total mass of the composition.
  • the epoxy compounds are optionally used in combination with amine hardeners.
  • isocyanates for use as non-aqueous binders comprised in the castable refractory composition according to the present invention may be selected from aromatic isocyanates, aliphatic isocyanates or a combination of aromatic and aliphatic isocyanates.
  • the isocyanates may have an isocyanate(-NCO) functionality of 2 or higher.
  • Specific isocyanates may be polyisocyanates such as 4,4'- dicyclohexylmethane diisocyanate (H12MDI), 1 ,4-cyclohexane diisocyanate (CHDI), 3- isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate, i.e.
  • IPDI isophoronediisocyanate
  • TDI 2,4- and 2,6-toluene diisocyanate
  • MDI toluidine diisocyanate
  • MDI 2,2'-, 2,4'- and/or 4,4'-diphenylmethlyene diisocyanates
  • MDI 1,2-naphthylene diisocyanate
  • xylene diisocyanate tetramethyl- xylenediisocyanate
  • TXDI tetramethyl- xylenediisocyanate
  • isocyanates for use in the present invention are commercially available, for example from BAYER (Lupranat), BASF (Desmodur), Huntsman (Suprasec), or other providers.
  • Linked polyisocyanates, and those containing heteroatoms are also suitable for use in the present invention and include polyisocyanates containing urea, urethane, biuret, allophonate, uretidinedione, isocyanurate, imide, carbodimide, uretonimine groups and the like.
  • One suitable isocyanate for use in the present invention is the polymeric form of MDI, with a viscosity in the range of 100 to 5000 mPa.s, such as from 100 to 2000 mPa.s.
  • isocyanate-based pre- polymers synthesised from polyisocyanates, polyhydric compounds, pre-polymers of isocyanate. All of the above polyhydric compounds are suitable as starting materials for the synthesis of polyisocyanateprepolymers with an -NCO value of 2 or more.
  • the isocyanate content may be in the range 10 to 50 wt.-% of the total binder in the composition, and may constitute from 0.5 to 5.0 wt.-% the of castable refractory composition according to the invention.
  • reaction rate modifying agents or cross-linking agents for use as non-aqueous binders comprised in the castable refractory composition according to the present invention may be selected from divalent metal catalysts, such as metals capable of forming suitable redox pairs selected from compounds containing cobalt, lead, manganese, cerium, calcium, zinc, zirconium, or mixtures thereof. In one embodiment, these may be selected from lead 2- ethylhexonate, 2-ethylhexonate, and cerium 2-ethylhexonate. These agents have a dual function as a polyurethane catalyst or an initiator for radical polymerisation in polyester resins.
  • the reaction rate modifying agents or cross- linking agents should be comprised in the castable refractory composition according to the invention in combination with a polyhydric component in amount in the range from 0.1 to 5.0 wt.-%, based upon total mass of the polyhydric component.
  • the epoxy compounds are optionally used in combination with DPA (N-(3-Dimethylaminopropyl-)- N,N-Diisopropanolamine) and/or amine accelerators.
  • a polyester resin for use as non-aqueous binders comprised in the castable refractory composition according to the present invention may be a styrene free vinyl polyester (e.g. dissolved in methacrylates), which is crosslinkable with peroxide and redox metal pair (commercially known as Alcotac Premium 100). This may be used in combination with other binders and act as a reactive diluent in the composition according to the present invention.
  • diluents for use as non-aqueous binders comprised in the castable refractory composition according to the present invention may be selected from organic and inorganic esters, aliphatic and aromatic hydrocarbons.
  • Suitable organic esters include but are not limited to phthalic acid, adipic acid, sebacic acid, fumaric acid, maleic acid, itaconic acid and citric acid.
  • Suitable inorganic esters include but are not limited to triethylphosphate and tris-(1 -chloro-2- propyl)phosphateare.
  • Suitable aromatic hydrocarbons include xylenes, toluene, naphthalene, solvent naptha heavy aromatics, hydro treated heavy naphthenic distillates, and kerosene (fractional distillate from 90°C to 152.5°C).
  • Suitable oleochemicals include polymerised cashew nut oil and castor oil. Suitable commercial diluents are available under the trade names Sovermol 1058, Durez 37033, Nytex 4700, Nyprint 863 and Nyflex 223.
  • a diluent or diluents mixture may be comprised in the castable refractory composition according to the invention in an amount in the range from 0.1 to 1 .0 wt.-%, based upon total mass of the composition.
  • a surface active agent for use as a non-aqueous binder comprised in the castable refractory composition according to the present invention may be Solsperse® 3000 (polymeric dispersant provided by Lubrizol, Ltd., Blackley, United Kingdom; CAS No. 86753-77-7), and act to enhance the installation characteristics of the castable refractory composition according to the present invention.
  • a surface active agent be comprised in the castable refractory composition according to the present invention in an amount in the range from 0.1 to 1.0 wt.-%, based upon total mass of the composition.
  • the binder present in the castable refractory composition according to the invention is one or more esterified fatty acids (EFA), such as esterified vegetable oils and/or esterified biodiesels, present in the composition as part of a coating of graphite and EFA on the aggregated magnesia particles.
  • EFA esterified fatty acids
  • the esterified fatty acid has a molecular weight ranging in the range of 1 ,000 to 10,000 and/or a viscosity in the range of 20 to 150 cps.
  • the binder is a thermoplastic resin or a natural resin.
  • the castable refractory compositions according to present invention are specific in that they contain no more than 2 wt.-% water, for example no more than 1 wt.-% water, or even no more than 0.5 wt.-% water.
  • There is no technical lower limit for the amount of water present in the compositions since water is not required in the composition according to the invention to perform well. As described in the introductory part of this application, water is often detrimental to the performance of magnesia-containing refractories due to the formation of brucite in the composition, resulting from hydration of magnesia.
  • the lower limit of water content in the composition is determined by external factors, such as moisture in the atmosphere, cost and ease of drying components and equipment, etc.
  • the castable refractory composition has solid and (non-aqueous) liquid components, which render the mixture castable and/or gunnable. It has been shown that the non-aqueous liquid components provide sufficient flowability to the composition for it to be practical to install, e.g. in metallurgical ladles, to form monolithic refractory linings after curing.
  • the castable refractory composition comprises no more than 10 wt.-% fixed carbon.
  • the castable refractory composition comprises no more than 8 wt.-% and no less than 3 wt.-% fixed carbon, such as no more than 6 wt.-% fixed carbon, such as, for example from 3.5 to 5.5 wt.-% fixed carbon.
  • the fixed carbon derives from the solid hydrocarbons present in the composition. The inclusion of solid hydrocarbons allows to obtain improved thermal conductivity, thermal shock resistance, and/or corrosion resistance in the final product.
  • the amount of fixed carbon in the composition is determined according to Indian Standard Procedure IS 1350 (Part 1 , 1984). According to this Standard, 1 g of material is dried at 108°C for one hour. The weight loss is reported as moisture percentage (A). Then, 1 g of material is treated at 800°C for one hour, and the retained material is reported as ash (B). Then, 1 g of material is treated at 900°C for 7 minutes under air exclusion conditions. The weight loss, minus (A), is reported as volatile matter (C). The fixed carbon is determined as a percentage 100 - A - B - C.
  • the castable refractory compositions are suitable for use in forming monolithic refractory linings for metallurgical vessels, by casting, spray-casting, gunning, self-flowing, ramming, or shotcrete. They are also suitable as gunning or patching solutions for repairing magnesia-carbon brick linings. Methods for forming monolithic refractory linings and for repairing magnesia-carbon brick linings are known in the art.
  • castable refractory compositions can be obtained by (a) providing a mixture of at least a portion of said plurality of dry components of a castable refractory compositions of the present invention, to obtain a dry mix; (b) providing a mixture of one or more of the liquid components of any one of the castable refractory compositions of the present invention, with the exception of any hardener used, to obtain a liquid mixture; (c) mixing the dry mix with the liquid mixture and optionally adding one or more non-aqueous binders, to obtain a homogenised castable refractory composition; (d) optionally adding one or more hardeners to said homogenised castable refractory composition; (e) installing the said homogenised castable refractory composition obtained at the end of step (c) or (d), using a casting, vibration casting, spray-casting, self-flowing, ramming or shotcrete process; and (f) curing said installed homogenised castable refractory
  • step (e) the composition is left to set to provide a ceramic green body for curing in step (f).
  • the composition is simply left at room temperature.
  • bond formation for development of strength and stability of the set monolithic lining occurs, and the composition may be heated to a temperature of 150°C to 250°C, or to a temperature of about 200°C, for a period of 12 h to 36 h, such as for about 24 h during the curing step (f).
  • steps (b) and (d) are carried out simultaneously in a step (b').
  • any hardener used in the formulation is first mixed with the one or more further liquid components (steps (b) and (d)), and next the dry mix and the liquid mixture (including any hardener) are mixed with optional addition of one or more non-aqueous binders to obtain a homogenised castable refractory composition.
  • the said homogenised castable refractory composition may then be used on a further step (e') in a gunning process, followed by (f) curing to obtain a monolithic refractory lining.
  • At least a portion of the carbonaceous material in the castable refractory composition is not included in the solid mix provided, but included or dissolved in the liquid mixture of step (b).
  • modulus of rupture MOR
  • CCS cold crushing strength
  • magnesia-based castable refractory compositions comprising non-aqueous binders according to the present invention were compared to compositions comprising aqueous systems.
  • the compositions were compared for (a) flow value after mixing and (b) their resistance to hydration, using a visual observation of cracks after the compositions were allowed to set for 24 hours at a temperature of 80°C at 90% relative humidity.
  • the compositions are listed in table 1 , with the total liquid amounts indicated:
  • the diluent used in Example 1 is an esterified fatty ester.
  • compositions according to the invention were prepared, along with a composition with a magnesia silicate hydrate binder (fumed silica and water included in the composition).
  • the compositions are shown in Table 3:
  • the composition according to Example 2 is similar to Example 1.
  • the composition according to Example 3 comprises graphite-coated magnesia.
  • the composition according to Example 4 comprises graphite coated with esterified fatty acids and fusible carbon derived from pitch.
  • the composition according to Example 5 comprises graphite flakes having a particle diameter of in the range of 106 to 250 ⁇ and fusible carbon derived from pitch.
  • the slag used had the following composition: Al 2 0 3 : 8.10 wt.-%; CaO: 44.39 wt.-%; Cr 2 0 3 : 0.14 wt-%; FeO: 15.44 wt-%; K 2 0: 0.18 wt-%; MgO: 5.58 wt.-%; MnO: 1 .82 wt-%; Na 2 0: 0.1 1 wt.-%; P 2 0 5 : 0.97 wt-%; S0 3 : 0.70 wt.-%; Si0 2 : 21 .72 wt.-%; Ti0 2 : 0.66 wt.-%; Zr0 2 : 0.05 wt.-%; V 2 0 5 : 0.14 wt-%.
  • the real temperature measured using a pyrometer measured using a pyrometer to be 1654°C (average) and 1743°C(maximum).
  • the commercially obtained brick was obtained from Tata refractories and comprised 97.4-% pure MgO, and an apparent porosity of 3.7%, a bulk density of 2.98 g/cm 3 , a CCS of 342 kg/cm 2 , and a carbon content by elemental analysis of 10.9 wt.-% (as indicated by the manufacturer). The results of the corrosion tests are shown in Table 8. Table 8
  • compositions according to Examples 2 to 5 have vastly improved corrosion resistance than Comparative Example 2, although not as high as that of the MgO-C bricks according to the state of the art. For this reason, the compositions according to Examples 2 to 5 are suitable both as castable refractory compositions for formation of monolithic linings, and as gunning compositions for repairing and/or replacing damaged bricks in refractory brick linings.
  • Setting time was measured using the following test method: The composition was wet mixed for 3 minutes and then placed into a mould, and vibrated for 2 x 30s. The compacted composition was then stored at 20°C and the setting tested every 15 minutes using a metallic nail pressed firmly at the top surface of the castable. The setting time is reached when the nail path is no more than 2 mm depth. The wet out time was assessed by a change in sound during wet sample preparation of the castable mix, and the data serves as comparison between the tested samples. Softness of mixture was assessed by feeling the material by hand after wet mixing of the castable material.
  • Surfactant 1 is Solsperse® 3000, a polymeric dispersant provided by Lubrizol, Ltd., Blackley, United Kingdom; CAS No. 86753-77-7.
  • Surfactant 2 is DISPERBYK-108, a hydroxyl-functional carboxylic acid ester with a pigment affinic group, provided by BYK Asia Pacific Private Limited (BYK-Chemie GmbH, Wesel, Germany).
  • Surfactant 3 is DISPERBYK-103, a copolymer solution having a filler affinic group, also provided by BYK Asia Pacific Private Limited.
  • Example 8 Example 9 Example 10 Example 1 1
  • Castable refractory compositions according to the present invention were prepared wherein various grades and amounts of carbonaceous material were used. They will be compared to Example 1 1 , and the components of the compositions are shown in Table 13.
  • Example 14 repair composition
  • a MgO-C lining after use will also require repair to extend the performance. Repair can be done by trowelling /casting over the virgin MgO-C lining which has to be cleaned and moistened before patching. In this case a non-aqueous slurry, the composition and selected properties of which are presented in Tables 15 and 16 is used for moistening prior to the application of MgO-C patching material (Example 15, 16) presented in Table 17, 18 and 19.

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  • Ceramic Engineering (AREA)
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  • Physics & Mathematics (AREA)
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Abstract

L'invention concerne des compositions réfractaires à mouler à base d'agrégats d'oxyde de magnésium. Les compositions de l'invention comportent plusieurs composants secs et plusieurs composants humides, ladite composition réfractaire à mouler comprenant, par rapport au poids total de la composition réfractaire à mouler, entre 50 % en poids et 99 % en poids d'un agrégat d'oxyde de magnésium; entre 0,1 % en poids et 10 % en poids d'une matière carbonée; entre 0,1 % en poids et 5 % en poids d'un antioxydant; et un liant non aqueux. Les compositions selon l'invention ne renferment pas plus de 2 % en poids d'eau; le carbone fixe dans la composition ne dépasse pas environ 10 % en poids, et l'antioxydant est choisi parmi un ou plusieurs carbures, nitrures, borures, métaux ou alliages métalliques, ou associations de ceux-ci. L'invention concerne également l'utilisation des compositions dans les procédés de moulage, de moulage par vibration, de moulage par pulvérisation, de moulage par projection, d'écoulement automatique, de damage, d'application de béton projeté ou de colmatage, et leur procédé de formation.
PCT/EP2014/066778 2013-08-05 2014-08-05 Compositions réfractaires à mouler et leur utilisation dans la formation et la réparation de revêtements réfractaires monolithiques WO2015018813A1 (fr)

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EP20172148.7A EP3705463A1 (fr) 2013-08-05 2014-08-05 Compositions réfractaires coulables, leur utilisation dans la formation de garnitures réfractaires et procédés de production de ces compositions
DK14758304.1T DK3030535T3 (da) 2013-08-05 2014-08-05 Støbebare ildfaste sammensætninger og deres anvendelse til dannelse og reparation af monolitiske ildfaste foringer
EP14758304.1A EP3030535B1 (fr) 2013-08-05 2014-08-05 Bétons refractaires et leur utilisation pour la formation et la réparation des revêtements réfractaires monolithiques
EA201690338A EA036340B1 (ru) 2013-08-05 2014-08-05 Литьевые огнеупорные составы и их использование в формировании и восстановлении монолитных огнеупорных футеровок
JP2016532659A JP6670748B2 (ja) 2013-08-05 2014-08-05 キャスタブル耐火性組成物並びにモノリシック耐火性ライニングの形成及び補修におけるその使用

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KR20180088658A (ko) * 2015-12-01 2018-08-06 케르네오스 내화성 마그네시아 시멘트
US10207955B2 (en) 2014-12-22 2019-02-19 Refratechnik Holding Gmbh Refractories and use thereof

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KR101865571B1 (ko) * 2016-12-13 2018-06-11 (주)포스코켐텍 카본 함유 블록 수리용 세라믹 조이닝재
JP2022133052A (ja) * 2021-03-01 2022-09-13 明智セラミックス株式会社 高熱伝導性断熱材

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WO2016102149A1 (fr) * 2014-12-22 2016-06-30 Refratechnik Holding Gmbh Produits réfractaires et leur utilisation
US10207955B2 (en) 2014-12-22 2019-02-19 Refratechnik Holding Gmbh Refractories and use thereof
US10227260B2 (en) 2014-12-22 2019-03-12 Refratechnik Holding Gmbh Refractories and use thereof
KR20180088658A (ko) * 2015-12-01 2018-08-06 케르네오스 내화성 마그네시아 시멘트
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EP3030535A1 (fr) 2016-06-15
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DK3030535T3 (da) 2021-04-26

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