WO2014203839A1 - 光源装置および発光装置 - Google Patents
光源装置および発光装置 Download PDFInfo
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- WO2014203839A1 WO2014203839A1 PCT/JP2014/065844 JP2014065844W WO2014203839A1 WO 2014203839 A1 WO2014203839 A1 WO 2014203839A1 JP 2014065844 W JP2014065844 W JP 2014065844W WO 2014203839 A1 WO2014203839 A1 WO 2014203839A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/85—Packages
- H10H20/851—Wavelength conversion means
- H10H20/8511—Wavelength conversion means characterised by their material, e.g. binder
- H10H20/8512—Wavelength conversion materials
- H10H20/8513—Wavelength conversion materials having two or more wavelength conversion materials
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/85—Packages
- H10H20/852—Encapsulations
- H10H20/854—Encapsulations characterised by their material, e.g. epoxy or silicone resins
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W90/00—Package configurations
Definitions
- the present invention relates to a light source device and a light emitting device using LEDs (Light Emitting Diode).
- LEDs Light Emitting Diode
- an LED illumination module configured to emit white light.
- a method of generating white light using an LED a method of generating three types of LEDs, a red LED, a blue LED, and a green LED, by combining three primary colors of light, or a blue LED as a light source of a yellow phosphor And a method of generating by mixing blue light and yellow light.
- Patent Document 1 discloses an illumination light source that emits white light by exciting a yellow phosphor, a green phosphor, and a red phosphor using two types of blue LEDs having different peak wavelengths.
- a plurality of different LED packages are arranged to form a lighting device.
- Patent Document 2 discloses a blue light emitting LED element sealed with a translucent resin containing a phosphor and a red light emitting LED element sealed with a translucent resin not containing a phosphor. A light-emitting device that emits white light by use is disclosed.
- Japanese Laid-Open Patent Publication No. 2008-258356 (released on October 23, 2008) Japanese Unexamined Patent Publication No. 2011-192703 (released on September 29, 2011)
- the light having a wavelength of 415 to 460 nm has a large influence (degree of injury) on the retina of the human eye.
- the wavelength 440 nm is set to 1 (maximum degree of injury). In this case, 0.80 at 415 nm, 0.95 at 425 nm, 0.94 at 450 nm, 0.80 at 460 nm, and 0.62 at 470 nm. It can be said that the smaller this value is, the easier it is to the eyes.
- the conventional light sources and light-emitting devices using LEDs are all intended to improve the luminous efficiency, and are not particularly considered for the effect on the retina of the human eye.
- a blue component in the vicinity of 450 nm having a large photodamage function value is included in white light.
- the present invention has been made in view of the above problems, and an object of the present invention is to provide a light source device that emits white light that is friendly to human eyes and light emission by using blue light having a small blue light injury function value. To provide an apparatus.
- a light source device is a light source device that emits white light using a light emitting diode, and has an integrated emission intensity of 415 nm to 460 nm in the emission spectrum of the white light. Is characterized in that the integrated emission intensity from 460 nm to 500 nm is large.
- the main blue component of white light is light having a wavelength of 460 nm to 500 nm, so that it is possible to provide a light source device that emits white light that is gentle to human eyes. Play.
- (A) is a top view which shows the structural example of the light emission surface of the light source device which concerns on Embodiment 1 of this invention, (b) is AA arrow sectional drawing shown to (a).
- (A) is a top view which shows the structural example of the light emission surface of the light source device which concerns on Embodiment 2 of this invention, (b) is BB arrow sectional drawing shown to (a).
- (A) is a top view which shows the structural example of the light emission surface of the light source device which concerns on Embodiment 3 of this invention, (b) is CC line arrow directional cross-sectional view shown to (a).
- FIG. 4 It is a top view which shows the formation position of the sealing resin on a board
- substrate shown in FIG. 4 is shown, (a) is a top view, (b) is DD sectional view taken on the line of (a). 4 shows another light source device in which a sealing resin is formed on the substrate shown in FIG. 4, (a) is a plan view, and (b) is a cross-sectional view taken along line EE of (a). It is a top view which shows the structural example of the light emission surface of the light source device which concerns on Embodiment 5 of this invention.
- Embodiment 1 An embodiment of the present invention will be described as follows.
- FIG. 1A is a plan view showing a configuration example of the light source device 10 according to the present embodiment
- FIG. 1B is a cross-sectional view taken along line AA in FIG.
- the light source device 10 includes a substrate 101, a first LED chip 102 (first light emitting diode), a phosphor-containing resin layer (phosphor-containing sealing resin) 104, and a dam ring 105 (resin). Sex frame).
- the substrate 101 is a substrate made of ceramic.
- the substrate 101 has a rectangular shape in plan view.
- the first LED chip 102 (first light emitting diode), the phosphor-containing resin layer 104, and the dam ring 105 (resinous frame) described above are provided on one surface (hereinafter, referred to as an upper surface) of the substrate 101.
- electrode lands 106 and 107 for external connection are formed.
- the electrode land 106 functions as an anode electrode
- the electrode land 107 functions as a cathode electrode.
- the electrode lands 106 and 107 are arranged on the upper surface of the substrate 101 outside the region surrounded by the dam ring 105 and in the vicinity of two corners on the upper surface. The surfaces of the electrode lands 106 and 107 are exposed and can be connected to external terminals.
- the first LED chip 102 is made of a blue light emitting diode, and is electrically connected to a wiring (not shown).
- the wiring is connected to the electrode lands 106 and 107.
- the electrode lands 106 and 107 are connected via the first LED chip 102 so that the first LED chip 102 can emit light. Details of the first LED chip 102 will be described later.
- the phosphor-containing resin layer 104 includes a green phosphor 104a (a divalent europium-activated ⁇ -type SiAlON) and a red phosphor 104b (Sr x Ca 1-x AlSiN 3 : Eu 2+ ) is a sealing resin layer made of a resin.
- the phosphor-containing resin layer 104 is formed so as to fill the region surrounded by the dam ring 105 and bury the first LED chip 102 disposed in the region. That is, the phosphor-containing resin layer 104 collectively seals the first LED chip 102.
- the green phosphor 104a and the red phosphor 104b are not limited to the above-described phosphors, and may be the following phosphors, which are optimum conditions in view of the excitation characteristics of the phosphors. Thus, it is preferable to select a combination of an LED chip and a phosphor used in the light source device. In addition, one of the green phosphor and the red phosphor may not be used, or a plurality of each phosphor may be used simultaneously.
- Green phosphor 104a (1) A divalent europium-activated oxynitride phosphor that is ⁇ -type SiAlON substantially represented by Eu a Si b Al c O d N e . (2) Expressed as MI 3-x Ce x MII 5 O 12 , MI is at least one element selected from Lu, Y, La and Gd, and MII is selected from Al and Ga A garnet-type trivalent cerium-activated oxide phosphor that is at least one element. (3) A divalent europium activated silicate phosphor represented by MIII 2-x Eu x SiO 4 , wherein MIII is at least one element selected from Mg, Ca, Sr, and Ba.
- MIII 3-x Ce x MIV 2 Si 3 O 12 is substantially represented, MIII is at least one element selected from Mg, Ca, Sr, and Ba, and MIV is Trivalent cerium activated silicate which is at least one element selected from Li, Na, K, Cs, Rb, Mg, Ca, Ba, Al, Ga, In, Sc, Y, La, Gd, and Lu Phosphor.
- a trivalent cerium-activated nitride phosphor represented by MI 3-x Ce x Si 6 N 11 and having at least one element selected from Lu, Y, La, and Gd.
- MIII 1-x Eu x MVSiN 3 represented by MIII is at least one element selected from Mg, Ca, Sr, and Ba, and MV is Al, Ga, In, Sc Bivalent europium activated nitride phosphor which is at least one element selected from Y, La, Gd and Lu.
- Eu f MVI g Si h Al i O j N k is substantially represented, and MVI is Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, and Gd.
- a divalent europium activated oxynitride phosphor which is ⁇ -type SiAlON which is at least one element selected from (4) MVII 2 (MVIII 1-x Mn x ) F 6 , where MVII is at least one element selected from Li, Na, K, Rb, and Cs, and MVIII is Ge, Si, Sn, Ti, And a tetravalent manganese-activated metal fluoride metal salt phosphor that is at least one element selected from Zr.
- the dam ring 105 is a member that defines the phosphor-containing resin layer 104 described above. That is, the dam ring 105 functions as a dam (blocking member) for preventing resin leakage when the phosphor-containing resin layer 104 is formed.
- the first LED chip 102 is a blue light emitting diode (470 nm chip) having a peak wavelength in the range of 460 nm to 500 nm.
- a blue light emitting diode (450 nm chip) having a peak wavelength in the range of 415 nm to 460 nm is not used.
- the first LED chip 102 has a peak wavelength in the range of 460 nm to 500 nm. And the blue light obtained by light emission of this 1st LED chip 102 is used for formation of white light. That is, the blue light obtained by the first LED chip 102 emitting light becomes the blue component of the white light emitted from the light source device 10.
- the blue light obtained by the light emission of the first LED chip 102 excites the green phosphor 104a and the red phosphor 104b included in the phosphor-containing resin layer 104 to become green light and red light, respectively. That is, the blue light obtained by emitting light from the first LED chip 102 also becomes a red component and a green component of white light emitted from the light source device 10 due to excitation and emission of the phosphor.
- the lower limit (critical value) of the peak wavelength range of the first LED chip 102 has a damage degree of 80% with respect to the wavelength 440 nm which is the maximum damage degree. If the degree of injury is greater than 80%, there is a high possibility that the retina of the human eye will be adversely affected. Therefore, the lower limit of the peak wavelength range of the first LED chip 102 is preferably 460 nm.
- 500 nm which is the upper limit of the peak wavelength range of the first LED chip 102 is the upper limit as a blue component of white light.
- the first LED chips 102 are arranged at regular intervals in the dam ring 105 as shown in FIG. As a result, the color mixture due to the light emission of each first LED chip 102 is easily made uniform, and it is possible to reduce luminance unevenness.
- the arrangement of the first LED chip 102 is not limited to the arrangement as shown in FIG.
- the light source device 10 As described above, according to the light source device 10 according to the present embodiment, white light emitted without using a blue light emitting diode having a high degree of injury to human eyes and having a peak wavelength in the range of 415 nm to 460 nm.
- the blue component is realized by the first LED chip 102 having a low degree of injury and a peak wavelength range (460 nm to 500 nm) that is gentle to the human eye, and can therefore emit white light that is gentle to the human eye.
- each color component is obtained by light emission of LED chips of each color (three colors) regardless of phosphor excitation.
- FIG. 2A is a plan view showing a configuration example of the light source device 20 according to the present embodiment
- FIG. 2B is a cross-sectional view taken along line BB in FIG.
- a dam ring 105, an electrode land 106, and an electrode land 107 are formed on a substrate 101.
- the first LED chip 102 and the second LED chip 103 of the first embodiment are used.
- a blue chip 131, a red chip (red light emitting diode) 132, and a green chip (green light emitting diode) 133 are provided.
- a translucent sealing resin layer is provided.
- 134 is formed. That is, the green chip 133 is a green light emitting diode that emits green light used when white light is emitted, and the red chip 132 is a red light emitting diode that emits red light used when white light is emitted.
- the transparent sealing resin layer 134 is filled in a region surrounded by the dam ring 105 on the substrate 101, and the blue chip 131 and the red chip 132 disposed in the region.
- the green chip 133 is embedded.
- a light emitting diode having the same peak wavelength as that of the first LED chip 102 of 460 nm to 500 nm is used.
- red chip 132 a light emitting diode having a peak wavelength of 580 nm to 680 nm is used.
- a light emitting diode having a peak wavelength of 500 nm to 580 nm is used.
- the blue light emitting diode having a peak wavelength of 415 nm to 460 nm that adversely affects the retina of the human eye is not used. There is no wavelength component with a high degree of damage.
- the light source device can be easily manufactured.
- the blue light emitting diode (470 nm chip) having a peak wavelength in the range of 460 nm to 500 nm is considered in consideration of increasing the white light emission efficiency.
- An example of a light source device to which a blue light emitting diode (450 nm chip) having a peak wavelength in the range of 415 nm to 460 nm is added will be described.
- a 470 nm chip and a 450 nm chip are used, and both of them have an integral emission intensity of 460 nm to 500 nm rather than an integrated emission intensity of 415 to 460 nm in the emission spectrum of white light emitted from the light source device.
- a 470 nm chip and a 450 nm chip are used so as to increase the emission intensity. In this way, it is possible to minimize the adverse effects of the 450 nm chip on the human eye.
- the integrated emission intensity of 460 nm to 500 nm is larger than the integrated emission intensity of 415 to 460 nm in the emission spectrum of white light emitted from the light source device.
- a blue LED chip having emission wavelengths at 450 nm and 470 nm is shown, but the wavelength of the chip is not limited to this.
- Lu 3 Al 5 O 12 : Ce 3+ is shown as a green phosphor and Sr x Ca 1-x AlSiN 3 : Eu 2+ is shown as a red phosphor, but the phosphor is also limited to these. It is not something.
- FIG. 3A is a plan view showing a configuration example of the light source device 30 according to the present embodiment
- FIG. 3B is a cross-sectional view taken along the CC line in FIG.
- the light source device 30 includes a substrate 101, a first LED chip 102 (first light emitting diode), a second LED chip 103 (second light emitting diode), a phosphor-containing resin layer 104, a dam ring. 105 (resinous frame).
- the substrate 101 is a substrate made of ceramic.
- the substrate 101 has a rectangular shape in plan view.
- the first LED chip 102 first light emitting diode
- the second LED chip 103 second light emitting diode
- the phosphor-containing resin layer 104 described above.
- electrode lands 106 and 107 for external connection are formed.
- the electrode land 106 functions as an anode electrode
- the electrode land 107 functions as a cathode electrode.
- the electrode lands 106 and 107 are arranged on the upper surface of the substrate 101 outside the region surrounded by the dam ring 105 and in the vicinity of two corners on the upper surface. The surfaces of the electrode lands 106 and 107 are exposed and can be connected to external terminals.
- the first LED chip 102 and the second LED chip 103 are each made of a blue light emitting diode, and are electrically connected to a wiring (not shown), and the wiring is connected to the electrode lands 106 and 107. Thereby, the electrode lands 106 and 107 are connected via the first LED chip 102 and the second LED chip 103 so that the first LED chip 102 and the second LED chip 103 can emit light. Details of the first LED chip 102 and the second LED chip 103 will be described later.
- the phosphor-containing resin layer 104 includes a green phosphor 104a (Lu 3 Al 5 O 12 : Ce 3+ ) and a red phosphor 104b (Sr x Ca 1-x AlSiN 3 : Eu. 2+ ) is a sealing resin layer made of a resin.
- the phosphor-containing resin layer 104 is formed so as to fill a region surrounded by the dam ring 105 and bury the first LED chip 102 and the second LED chip 103 disposed in the region. That is, the phosphor-containing resin layer 104 collectively seals the first LED chip 102 and the second LED chip 103.
- the green phosphor 104a and the red phosphor 104b are not limited to the above-described phosphors, and may be the following phosphors, which are optimum conditions in view of the excitation characteristics of the phosphors. Thus, it is preferable to select a combination of an LED chip and a phosphor used in the light source device. In addition, one of the green phosphor and the red phosphor may not be used, or a plurality of each phosphor may be used simultaneously.
- Green phosphor 104a (1) A divalent europium-activated oxynitride phosphor that is ⁇ -type SiAlON substantially represented by Eu a Si b Al c O d N e . (2) Expressed as MI 3-x Ce x MII 5 O 12 , MI is at least one element selected from Lu, Y, La and Gd, and MII is selected from Al and Ga A garnet-type trivalent cerium-activated oxide phosphor that is at least one element. (3) A divalent europium activated silicate phosphor represented by MIII 2-x Eu x SiO 4 , wherein MIII is at least one element selected from Mg, Ca, Sr, and Ba.
- MIII 3-x Ce x MIV 2 Si 3 O 12 is substantially represented, MIII is at least one element selected from Mg, Ca, Sr, and Ba, and MIV is Trivalent cerium activated silicate which is at least one element selected from Li, Na, K, Cs, Rb, Mg, Ca, Ba, Al, Ga, In, Sc, Y, La, Gd, and Lu Phosphor.
- a trivalent cerium-activated nitride phosphor represented by MI 3-x Ce x Si 6 N 11 and having at least one element selected from Lu, Y, La, and Gd.
- MIII 1-x Eu x MVSiN 3 is substantially represented, and MIII is at least one element selected from Mg, Ca, Sr, and Ba, and MV is Al, Ga, A divalent europium activated nitride phosphor that is at least one element selected from In, Sc, Y, La, Gd, and Lu.
- Eu f MVI g Si h Al i O j N k is substantially represented, and MVI is Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, and Gd.
- a divalent europium activated oxynitride phosphor which is ⁇ -type SiAlON which is at least one element selected from (4) MVII 2 (MVIII 1-x Mn x ) F 6 , where MVII is at least one alkali metal element selected from Li, Na, K, Rb, and Cs, and MVIII is Ge, Si
- a tetravalent manganese-activated metal fluoride metal salt phosphor that is at least one element selected from Sn, Ti, and Zr.
- the dam ring 105 is a member that defines the phosphor-containing resin layer 104. That is, the dam ring 105 functions as a dam (blocking member) for preventing resin leakage when the phosphor-containing resin layer 104 is formed.
- the first LED chip 102 and the second LED chip 103 are both blue light emitting diodes, but their peak wavelengths are different and the emitted blue light is used differently.
- the first LED chip 102 is a blue light emitting diode (470 nm chip) having a peak wavelength in the range of 460 nm to 500 nm. And the blue light obtained by light emission of this 1st LED chip 102 is used for formation of white light. That is, the blue light obtained by emitting light from the first LED chip 102 becomes a blue component of white light emitted from the light source device 30.
- the second LED chip 103 is a blue light emitting diode (450 nm chip) having a peak wavelength in the range of 415 nm to 460 nm. Then, the blue light obtained by emitting light from the second LED chip 103 excites a green phosphor 104a and a red phosphor 104b included in a phosphor-containing resin layer 104, which will be described later, to become green light and red light, respectively. . That is, the blue light obtained by the light emitted from the second LED chip 103 becomes the red component and the green component of the white light emitted from the light source device 10.
- a part of blue light obtained by the first LED chip 102 emitting light is used as excitation light for exciting the green phosphor 104a and the red phosphor 104b.
- the lower limit (critical value) of the peak wavelength range of the first LED chip 102 has a damage degree of 80% with respect to the wavelength 440 nm which is the maximum damage degree. If the degree of injury is greater than 80%, there is a high possibility that the retina of the human eye will be adversely affected. Therefore, the lower limit of the peak wavelength range of the first LED chip 102 is preferably 460 nm.
- 500 nm which is the upper limit of the peak wavelength range of the first LED chip 102 is the upper limit as a blue component of white light.
- the range of the peak wavelength of the second LED chip 103 is set according to the type of phosphor to be excited.
- the first LED chips 102 and the second LED chips 103 are alternately arranged in a row.
- the arrangement positions of the first LED chip 102 and the second LED chip 103 are not particularly limited as long as they are inside the dam ring 105 formed on the substrate 101.
- the first LED chip 102 and the second LED chip 103 are not particularly limited as described above, but at least the integrated emission intensity of 460 nm to 500 nm is larger than the integrated emission intensity of 415 nm to 460 nm in the emission spectrum of the light source device 30. It is necessary to arrange so that it becomes.
- the blue component of the emitted white light is realized by the first LED chip 102 having a low degree of injury and a peak wavelength range that is kind to human eyes. Therefore, it is possible to emit white light that is kind to human eyes.
- the second LED chip 103 having a peak wavelength range in which the excitation efficiency of the phosphor is good is used, a red component and a green component other than the blue component forming white light can be efficiently obtained. Light can be emitted with high efficiency.
- the first LED chip 102 and the second LED chip 103 are collectively sealed with a phosphor-containing resin obtained by kneading a red phosphor and a green phosphor. That is, the first LED chip 102 and the second LED chip 103 are sealed with the same resin.
- the first LED chip 102 and the second LED chip 103 may be sealed with different types of resins.
- Embodiment 4 below shows an example in which the first LED chip 102 and the second LED chip 103 are sealed with different types of resins.
- the light source device according to the present embodiment has the same basic configuration as the light source device 30 of the third embodiment, and is different in that the type of resin for sealing each LED chip is different.
- FIG. 4 is a plan view showing a state before resin sealing in the light source device according to the present embodiment.
- the first LED chip 102, the second LED chip 103, the electrode land 106, and the electrode land 107 are provided on the substrate 101 before resin sealing.
- a donut-shaped dam ring forming position 101a for forming the dam ring 105 and a first sealing resin forming position 101b around the first LED chip 102 are set.
- a second sealing resin forming position 101c is set around the second LED chip 103 in a region other than the region where the first sealing resin forming position 101b is set.
- the first LED chip 102 as shown in the light source device 40 shown in FIGS. 5 (a) and 5 (b) and the light source device 50 shown in FIGS. 6 (a) and 6 (b).
- the second LED chip 103 is sealed with a different type of resin.
- the first sealing resin layer 111 is formed using a transparent high thixotropic resin as the resin for sealing the first LED chip 102, and the second LED chip 103.
- the second sealing resin device 112 is formed by using a resin in which a red phosphor and a green phosphor are kneaded as a resin for sealing.
- the first sealing resin layer 111 made of a highly thixotropic resin is formed so as to cover the first LED chip, and then the second sealing resin layer 112 is attached to the second LED chip 103. Form to cover.
- the upper portion of the first LED chip 102 is covered with the transparent first sealing resin layer 111, and the green phosphor 112 a and the red portion are directly above the second LED chip 103.
- the second sealing resin layer 112 including the phosphor 112b is covered.
- the resin that does not include the phosphor is used as the resin that seals the first LED chip 102.
- the resin is not limited to this, and the phosphor that seals the first LED chip 102 is not limited thereto. You may use resin containing.
- the first sealing resin layer 121 is formed using a highly thixotropic resin kneaded with a red phosphor as a resin for sealing the first LED chip 102.
- the second sealing resin device 122 is formed using a resin in which a green phosphor is kneaded as a resin for sealing the second LED chip 103.
- the top of the first LED chip 102 is covered with a first sealing resin layer 121 including a red phosphor 121a, and the green phosphor 122a is directly over the second LED chip 103. It is covered with a second sealing resin layer 122 containing
- the red phosphor 112b, 121a are all Sr x Ca 1-x AlSiN 3 : is Eu 2+, green phosphor 112a, 122a are, Lu 3 Al 5 O 12: the Ce 3+
- the phosphor materials are not particularly limited, and the phosphor materials are determined so that the excitation efficiency is higher depending on the peak wavelength ranges of the first LED chip 102 and the second LED chip 103. That's fine.
- the green phosphor Lu 3 Al 5 O 12 : Ce 3+ has lower excitation efficiency at 470 nm than 450 nm
- the red phosphor Sr x Ca 1-x AlSiN 3 : Eu 2+ has excitation efficiency at 450 nm or 470 nm.
- the phosphor and resin for sealing the first LED chip 102 and the phosphor and resin for sealing the second LED chip 103 are determined. In other words, whether the green phosphor and the red phosphor are sealed with 111, 112, or 121, 122 is determined by the wavelength of the LED chip used in the light source device and the excitation characteristics of the phosphor.
- the green phosphor is MI.
- sealing is preferably performed as shown in this example.
- the green phosphors 112a and 122a and the red phosphors 112b and 121a are not limited to the above-described phosphors, and may be the following phosphors in view of excitation characteristics of the phosphors. It is preferable to select a combination of an LED chip and a phosphor used in the light source device so as to obtain the optimum conditions. In addition, one of the green phosphor and the red phosphor may not be used, or a plurality of each phosphor may be used simultaneously.
- Green phosphor 112a, 122a A divalent europium-activated oxynitride phosphor that is ⁇ -type SiAlON substantially represented by Eu a Si b Al c O d N e .
- MI 3-x Ce x MII 5 O 12 MI is at least one element selected from Lu, Y, La and Gd, and MII is selected from Al and Ga
- MIII 2-x Eu x SiO 4 A divalent europium activated silicate phosphor represented by MIII 2-x Eu x SiO 4 , wherein MIII is at least one element selected from Mg, Ca, Sr, and Ba.
- MIII 3-x Ce x MIV 2 Si 3 O 12 is substantially represented, MIII is at least one element selected from Mg, Ca, Sr, and Ba, and MIV is Trivalent cerium activated silicate which is at least one element selected from Li, Na, K, Cs, Rb, Mg, Ca, Ba, Al, Ga, In, Sc, Y, La, Gd, and Lu Phosphor.
- a trivalent cerium-activated nitride phosphor represented by MI 3-x Ce x Si 6 N 11 and having at least one element selected from Lu, Y, La, and Gd.
- MIII 1-x Eu x MVSiN 3 is substantially represented, and MIII is at least one element selected from Mg, Ca, Sr, and Ba, and MV is Al, Ga, A divalent europium activated nitride phosphor that is at least one element selected from In, Sc, Y, La, Gd, and Lu.
- Eu f MVI g Si h Al i O j N k is substantially represented, and MVI is Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, and Gd.
- a divalent europium activated oxynitride phosphor which is ⁇ -type SiAlON which is at least one element selected from (4) MVII 2 (MVIII 1-x Mn x ) F 6 , where MVII is at least one alkali metal element selected from Li, Na, K, Rb, and Cs, and MVIII is Ge, Si
- a tetravalent manganese-activated metal fluoride metal salt phosphor that is at least one element selected from Sn, Ti, and Zr.
- the light source devices 40 and 50 according to the present embodiment each include the first LED chip 102 (with a peak wavelength range of 460 nm to 500 nm), as in the first to third embodiments, the white light is gentle to human eyes. Can emit light.
- the resin for sealing the first LED chip 102 since a high thixotropic resin is used as the resin for sealing the first LED chip 102, the following effects can be obtained. In other words, if one LED chip (either the first LED chip 102 or the second LED chip 103) is sealed with a high thixotropic resin, the other LED chip is sealed by drawing using an air dispenser or the like. It is possible to stop. As described above, after sealing and pre-curing only a specific portion with the high thixotropic resin (the high thixotropic resin functions as a new dam ring at the time of sealing the second LED chip 103), the thixo kneaded with the phosphor The inside of the ring of the dam ring may be sealed with a resin having low properties.
- the high thixotropic resin is used only for the resin that seals the first LED chip 102.
- the present invention is not limited to this, and the high thixotropic resin is used for the resin that seals the second LED chip 103. May be used.
- a high thixotropic resin is used only for the resin that seals the second LED chip 103, and a resin that is less thixotropic than the resin that seals the second LED chip 103 is used as the resin that seals the first LED chip 102. Also good.
- all LED chips formed on the substrate 101 are driven using one system of inputs, that is, the electrode land 106 that functions as an anode electrode and the electrode land 107 that functions as a cathode electrode.
- the present invention is not limited to this and may be driven by two systems of inputs. An example of two-system input is shown in the fifth embodiment below.
- FIG. 7 is a plan view showing a configuration example of the light source device 60 according to the present embodiment.
- the light source device 60 has substantially the same configuration as the light source device 40 shown in FIG. 5A of the third embodiment, and further includes an electrode land 108 that functions as an anode electrode and an electrode land 109 that functions as a cathode electrode. It has been. Thereby, the light source device 50 is configured to realize two systems of input.
- the configuration of the light source device 60 other than the electrode lands 108 and 109 is the same as that of the light source device 40 shown in FIG. 5A of the second embodiment, detailed description thereof is omitted.
- the input signal can be adjusted according to the characteristics of the diodes, so that the performance of each diode is maximized. This can improve the life and efficiency.
- the 415 to 460 nm component is smaller in the case of (2) than in the case of (1) even at the same color temperature. That is, in the case of (2), since there are few 415 to 460 nm components that adversely affect the eyes, it can be said that it is gentler to human eyes.
- the light source devices 10 and 20 of Embodiments 1 and 2 do not use the second LED chip 103 having a peak wavelength of 415 nm to 460 nm, and are therefore friendly to human eyes.
- the graph of FIG. 9 shows the emission spectrum of LEDs (450 nm or 470 nm LED chips) having different peak wavelengths in which the resin is kneaded with the same blending ratio at almost the same amount for each color temperature.
- both devices were produced with a phosphor sealing amount of 3000K or 5000K in white using an LED using a 450 nm LED chip.
- Sr x Ca 1-x AlSiN 3 : Eu 2+ is used as the red phosphor kneaded in the resin
- Lu 3 Al 5 O 12 : Ce 3+ is used as the green phosphor.
- the four types of devices created in this way are shown as a 470 nm chip (1), a 450 nm chip (1), a 470 nm chip (2), and a 450 nm chip (2) in the graph shown in FIG.
- the 470 nm chip (1) is obtained by encapsulating a 470 nm chip with a phosphor sealing amount of 5000 K white in an LED using a 450 nm LED chip.
- the 450 nm chip (1) is obtained by encapsulating a 450 nm chip with a phosphor encapsulating amount of 5000 K white in an LED using a 450 nm LED chip.
- the 470 nm chip (2) is obtained by encapsulating a 470 nm chip with an LED using a 450 nm LED chip with a phosphor sealing amount of 3000 K white.
- the 450 nm chip (2) is obtained by sealing a 450 nm chip with a phosphor sealing amount of 3000 K white in an LED using a 450 nm LED chip.
- the green component 500 to 580 nm, especially around 530 to 560 nm
- the excitation efficiency of Lu 3 Al 5 O 12 : Ce 3+ is poor. Therefore, in Embodiments 3 to 5 described above, in order to compensate for the excitation efficiency of Lu 3 Al 5 O 12 : Ce 3+ , the excitation efficiency of Lu 3 Al 5 O 12 : Ce 3+ is 460 nm to 500 nm, which is the peak wavelength where the excitation efficiency is poor.
- the combinations are not limited to those shown here.
- One of the green phosphor and the red phosphor may not be used, or a plurality of each phosphor may be used simultaneously.
- the manufacturing process of the light source device is roughly divided into three steps, that is, a light emitting element mounting step, a second light reflecting resin layer (dam ring) forming step, and a sealing resin forming step.
- Light emitting elements (first LED chip 102, second LED chip 103, blue chip 131, green chip 133, red chip 132, etc.) are mounted on a substrate (substrate 101). Specifically, first, the light emitting element is die-bonded using an adhesive resin such as a silicone resin. In this description, 20 light emitting elements are arranged in a region surrounded by conductor wiring.
- the light emitting element is an LED chip having a rectangular outer shape when viewed from above, and has a thickness of 100 to 180 ⁇ m, for example.
- two tip electrodes (electrode lands 106 and 107) for anode and cathode are provided so as to face each other in the longitudinal direction.
- the light emitting elements are arranged substantially in a row, and four light emitting elements are arranged in five rows per row.
- wire bonding is performed using a wire.
- wire bonding is performed between the conductor wiring and the chip electrode for the light emitting element disposed adjacent to the conductor wiring.
- Adjacent light emitting elements that do not sandwich the conductor wiring directly connect both chip electrodes by wire bonding. Thereby, between the anode electrode and the cathode electrode, five series circuit portions in which four light emitting elements are connected in series are connected in parallel.
- ⁇ Second light reflecting resin layer forming step Dam ring forming step>
- a light reflecting resin frame is formed so as to cover the conductor wiring. Specifically, for example, using a resin discharge device, a liquid alumina filler-containing silicone resin is drawn at a predetermined position while being discharged from a nozzle having a round opening. And the light reflection resin frame (dam ring 105) is formed by performing a heat curing process on the conditions of curing temperature: 120 degreeC and curing time: 1 hour.
- the curing temperature and the curing time are examples, and are not limited thereto.
- the light reflecting resin frame has a width of 0.9 mm, for example.
- the height of the uppermost portion of the light reflecting resin frame is set to be higher than the height of the upper surface of the light emitting elements and higher than the wire (wire loop) connecting the light emitting elements.
- the sealing resin can be formed so as not to expose the light emitting element and the wire, and these can be protected.
- At least a part of the wire connected to the conductor wiring is covered with the light reflecting resin frame. Therefore, it is possible to reduce wire peeling and to prevent wire peeling.
- a nozzle having a round opening is used for the resin discharge device.
- the present invention is not limited to this.
- a nozzle having an opening that matches the drawing shape of the light reflecting resin frame here, an annular shape
- the resin is discharged from the opening at a time, so that an annular light-reflecting resin frame without a joint can be produced in a short time. That is, it is possible to form a light-reflecting resin frame capable of suppressing the swelling of the joint portion and reducing the leakage of the sealing resin.
- a sealing resin (phosphor-containing resin or translucent resin not containing a phosphor) is formed on the substrate. Specifically, a phosphor-containing resin obtained by dispersing a phosphor in a liquid translucent resin is injected so as to fill the region surrounded by the light reflecting resin frame. After injecting the phosphor-containing resin, it is cured at a predetermined temperature and time. Thereby, the light emitting element and the wire are covered and protected by the sealing resin.
- a translucent resin that does not contain a phosphor is also formed in the same process as the phosphor-containing resin, and only the presence or absence of the phosphor in the resin is different.
- the light source devices 10 to 60 of the first to fifth embodiments are manufactured by the above-described steps. However, since each light source device has a slightly different configuration, differences in the manufacturing process will be described below.
- the first LED chips 102 are mounted in a row on the substrate 101 as shown in FIG.
- the first LED chip 102 is sealed with a phosphor-containing resin.
- the first LED chip 102 and the second LED chip 103 are mounted on the substrate 101 in a row as shown in FIG.
- the first LED chip 102 and the second LED chip 103 are sealed with the same type of phosphor-containing resin.
- the first LED chip 102 and the second LED chip 103 are mounted on the substrate 101 in a row as shown in FIGS.
- the first LED chip 102 is sealed with a highly thixotropic resin in which the phosphor is not kneaded in the same drawing as the dam ring 105, and temporarily cured at 100 ° C. for 10 minutes.
- the second LED chip 103 is sealed with a resin in which a green phosphor and a red phosphor are kneaded (potting each region divided by the second LED chip 103). Thereafter, the sealing resin is cured under the original conditions.
- the first LED chip 102 and the second LED chip 103 are mounted in a row on the substrate 101, and the first LED chip 102 and the second LED chip 103 are Connect to a different input system.
- the first LED chip 102 is sealed with a highly thixotropic resin in which the phosphor is not kneaded in the same drawing as the dam ring 105, and temporarily cured at 100 ° C. for 10 minutes.
- the second LED chip 103 is sealed with a resin in which a green phosphor and a red phosphor are kneaded (potting each region divided by a 470 nm chip). Thereafter, the sealing resin is cured under the original conditions.
- the temporary curing temperature and the temporary curing time are examples, and are not limited thereto.
- any of the light source devices 10 to 60 of the first to fifth embodiments can be suitably used as a light source of a light emitting device, for example, a lighting device.
- the light source device of each embodiment according to the present invention is an LED package having a configuration in which LEDs of different wavelengths are mounted on one substrate, white light is emitted by arranging a plurality of LED packages in terms of color mixing. There is an advantage over the device to do.
- a light source device (10, 20, 30, 40, 50, 60) according to aspect 1 of the present invention is a light source device that emits white light using a light emitting diode, and has a wavelength of 415 to 460 nm in the emission spectrum of the white light.
- the integrated light emission intensity of 460 nm to 500 nm is larger than the integrated light emission intensity.
- the main blue component of the white light is light of 460 nm to 500 nm because the integrated light emission intensity of 460 nm to 500 nm is larger than the integrated light emission intensity of 415 to 460 nm in the light emission spectrum of the light source device. It becomes.
- the main blue component of the white light emitted by the light source device does not include a component having a wavelength (415 nm to 460 nm) that has a large influence (degree of injury) on the retina of the human eye.
- the white light emitted from the light becomes white light that is kind to human eyes.
- the light source device (10, 20, 30, 40, 50, 60) according to aspect 2 of the present invention is the first light emitting diode (first LED chip 102) that emits blue light necessary for forming white light in the above aspect 1. , Blue chip 131), and the peak wavelength of the first light emitting diode is in the range of 460 nm to 500 nm.
- the blue light injury function (JIS T7330) is about 0.1 because the peak wavelength of the first light emitting diode that emits the blue light necessary for the formation of white light is in the range of 460 nm to 500 nm. It can be as small as 62.
- the blue component of the white light does not include a component having a wavelength (415 nm to 460 nm) having a large influence (degree of injury) on the retina of the human eye, the white light emitted from the light source device having the above configuration is It becomes white light that is kind to human eyes.
- the light source device (30, 40, 50, 60) according to Aspect 3 of the present invention is lower than the peak wavelength of the first light-emitting diode in Aspect 2, and has phosphors (green phosphor 112a (122a), red fluorescence).
- the second light emitting diode (second LED chip 103) for exciting the body 112b (121a)) is further included.
- the excitation efficiency is obtained when the peak wavelength is in the range of 460 nm to 500 nm.
- the peak wavelength of the second light emitting diode is in the range of 415 nm to 460 nm. It is a feature.
- the excitation efficiency of the green phosphor having poor excitation efficiency when the peak wavelength is in the range of 460 nm to 500 nm by the second LED chip. can be improved.
- the light emission efficiency as the whole light source device can be improved.
- the first light emitting diode (first LED chip 102) and the second light emitting diode (second LED chip 103) are The second light emitting diode is sealed with a phosphor-containing sealing resin (phosphor sealing resin layer 104) containing a phosphor excited by light emitted.
- the first light-emitting diode and the second light-emitting diode can be collectively sealed, so that the manufacturing process can be simplified.
- the first light emitting diode (first LED chip 102) and the second light emitting diode (second LED chip 103) are respectively It is characterized by being sealed with different types of sealing resins (first sealing resin layers 111 and 121, second sealing resin layers 112 and 122).
- the sealing resin can be changed in accordance with the light emitting diode having high phosphor excitation efficiency, a light source device having higher phosphor excitation efficiency can be realized.
- the light source device (20) includes a green light emitting diode (green chip 133) that emits green light that is used when white light is emitted and red light that is used when white light is emitted. Further, a red light emitting diode (red chip 132) that emits light is further included.
- green chip 133 green light emitting diode
- red chip 132 red light emitting diode
- the sealing resin since all the colors (blue, red, green) used when emitting white light are performed by the light emitting diodes, the sealing resin does not need to contain a phosphor. This eliminates the need to use a blue light emitting diode having a peak wavelength of 415 nm to 460 nm, which is used to excite the green phosphor, and can emit white light that is friendly to human eyes.
- the light source device (60) according to aspect 8 of the present invention is the light source device (60) according to any one of aspects 2 to 7, wherein a signal input system to the first light emitting diode (first LED chip 102) is another light emitting diode (first light emitting diode). 2LED chip 103) is different from the signal input system.
- the input signal can be adjusted according to the characteristics of the diodes, so that the performance of each diode is maximized. This can improve the life and efficiency.
- a light-emitting device is characterized by including the light source device according to any one of Aspects 1 to 8 as a light source.
- the present invention can be suitably used as various light sources, particularly illumination light sources and backlight light sources for displays that require light that is gentle on the human eye.
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Abstract
Description
本発明の一実施の形態について説明すれば、以下の通りである。
図1の(a)は、本実施形態に係る光源装置10の一構成例を示す平面図であり、図1の(b)は、図1の(a)のAA線矢視断面である。
(1)EuaSibAlcOdNeで実質的に表されるβ型SiAlONである2価のユーロピウム賦活酸窒化物蛍光体。
(2)MI3―xCexMII5O12で表され、MIはLu、Y、La、およびGdの中から選択される少なくとも1種の元素、MIIはAl、Gaの中から選択される少なくとも1種の元素であるガーネット型の3価のセリウム賦活酸化物蛍光体。
(3)MIII2―xEuxSiO4で表され、MIIIはMg、Ca、Sr、およびBaから選ばれる少なくとも1種の元素である2価のユーロピウム賦活珪酸塩蛍光体。
(4)MIII3-xCexMIV2Si3O12で実質的に表され、MIIIは、Mg、Ca、Sr、およびBaの中から選択される少なくとも1種の元素であり、MIVは、Li、Na、K、Cs、Rb、Mg、Ca、Ba、Al、Ga、In、Sc、Y、La、Gd、およびLuから選択される少なくとも1種の元素である3価のセリウム賦活珪酸塩蛍光体。(5)MI3-xCexSi6N11で表され、Lu、Y、La、およびGdの中から選択される少なくとも1種の元素ある3価のセリウム賦活窒化物蛍光体。
(1)MIII1-xEuxMVSiN3で表され、MIIIは、Mg、Ca、Sr、およびBaの中から選択される少なくとも1種の元素であり、MVは、Al、Ga、In、Sc、Y、La、Gd及びLuから選択される少なくとも1種の元素である2価のユーロピウム賦活窒化物蛍光体。
(2)MIII2-xEuxSi5N8で表され、MIIIは、Mg、Ca、Sr、およびBaの中から選択される少なくとも1種の元素である2価のユーロピウム賦活窒化物蛍光体。
(3)EufMVIgSihAliOjNkで実質的に表され、MVIはLi、Na、K、Rb、Cs、Mg、Ca、Sr、Ba、Sc、Y、La、およびGdから選択される少なくとも1種の元素であるα型SiAlONである2価のユーロピウム賦活酸窒化物蛍光体。
(4)MVII2(MVIII1-xMnx)F6で表され、MVIIはLi、Na、K、Rb、およびCsから選ばれる少なくとも1種の元素、MVIIIはGe、Si、Sn、Ti、およびZrから選ばれる少なくとも1種の元素である4価のマンガン賦活フッ化金属塩蛍光体。
第1LEDチップ102は、ピーク波長が460nm~500nmの範囲の青色発光ダイオード(470nmチップ)である。本実施形態では、ピーク波長が415nm~460nmの範囲の青色発光ダイオード(450nmチップ)は使用しない。
第1LEDチップ102は、図1の(a)に示すように、ダムリング105内で、等間隔で配置されている。これにより、各第1LEDチップ102の発光による色の混ざり具合が均一化されやすくなり、輝度ムラを低減することが可能となる。ただし、第1LEDチップ102の配置は、図1の(a)のような配置に限定されるものではない。
以上のように、本実施形態に係る光源装置10によれば、人の眼に対して傷害度の高い、ピーク波長が415nm~460nmの範囲の青色発光ダイオードを使用せず、発光される白色光の青色成分が、傷害度の低い、人の眼に優しいピーク波長の範囲(460nm~500nm)を有する第1LEDチップ102によって実現されるので、人の眼に優しい白色光を発光することができる。
本発明の他の実施の形態について説明すれば、以下の通りである。なお、本実施の形態では、前記実施形態1と機能が同じ部材には、同一番号を付記し、その詳細な説明は省略する。
図2の(a)は、本実施形態に係る光源装置20の一構成例を示す平面図であり、図2の(b)は、図2の(a)のBB線矢視断面である。
以上のように、本実施形態では、前記実施形態1と同様に、人の眼の網膜に悪影響を及ぼすピーク波長415nm~460nmの青色発光ダイオードが用いられていないため、発光する白色光には、傷害度の高い波長成分が存在しないことになる。
本発明のさらに他の実施の形態について説明すれば、以下の通りである。なお、本実施の形態では、前記実施形態1と機能が同じ部材には、同一番号を付記し、その詳細な説明は省略する。
図3の(a)は、本実施形態に係る光源装置30の一構成例を示す平面図であり、図3の(b)は、図3の(a)のCC線矢視断面である。
(1)EuaSibAlcOdNeで実質的に表されるβ型SiAlONである2価のユーロピウム賦活酸窒化物蛍光体。
(2)MI3―xCexMII5O12で表され、MIはLu、Y、La、およびGdの中から選択される少なくとも1種の元素、MIIはAl、Gaの中から選択される少なくとも1種の元素であるガーネット型の3価のセリウム賦活酸化物蛍光体。
(3)MIII2―xEuxSiO4で表され、MIIIはMg、Ca、Sr、およびBaから選ばれる少なくとも1種の元素である2価のユーロピウム賦活珪酸塩蛍光体。
(4)MIII3-xCexMIV2Si3O12で実質的に表され、MIIIは、Mg、Ca、Sr、およびBaの中から選択される少なくとも1種の元素であり、MIVは、Li、Na、K、Cs、Rb、Mg、Ca、Ba、Al、Ga、In、Sc、Y、La、Gd、およびLuから選択される少なくとも1種の元素である3価のセリウム賦活珪酸塩蛍光体。
(5)MI3-xCexSi6N11で表され、Lu、Y、La、およびGdの中から選択される少なくとも1種の元素ある3価のセリウム賦活窒化物蛍光体。
(1)MIII1-xEuxMVSiN3で実質的に表され、MIIIは、Mg、Ca、Sr、およびBaの中から選択される少なくとも1種の元素であり、MVは、Al、Ga、In、Sc、Y、La、Gd及びLuから選択される少なくとも1種の元素である2価のユーロピウム賦活窒化物蛍光体。
(2)MIII2-xEuxSi5N8で実質的に表され、MIIIは、Mg、Ca、Sr、およびBaの中から選択される少なくとも1種の元素である2価のユーロピウム賦活窒化物蛍光体。
(3)EufMVIgSihAliOjNkで実質的に表され、MVIはLi、Na、K、Rb、Cs、Mg、Ca、Sr、Ba、Sc、Y、La、およびGdから選択される少なくとも1種の元素であるα型SiAlONである2価のユーロピウム賦活酸窒化物蛍光体。
(4)MVII2(MVIII1-xMnx)F6で実質的に表され、MVIIはLi、Na、K、Rb、およびCsから選ばれる少なくとも1種のアルカリ金属元素、MVIIIはGe、Si、Sn、Ti、およびZrから選ばれる少なくとも1種の元素である4価のマンガン賦活フッ化金属塩蛍光体。
第1LEDチップ102及び第2LEDチップ103は、何れも青色発光ダイオードであるが、それぞれのピーク波長は異なり、出射される青色光の用いられ方も異なる。
第1LEDチップ102及び第2LEDチップ103は、図3の(a)に示すように、列で交互に配置されている。しかしながら、第1LEDチップ102及び第2LEDチップ103は、基板101上に形成されたダムリング105の内側であれば、配置位置について特に限定しない。しかしながら、色の混ざり具合から、第1LEDチップ102及び第2LEDチップ103は、なるべく交互かつ均等な間隔で配置されることが望ましく、また、第1LEDチップ102および103の配置(数および配列)は、図3の(a)で示したものに限定されるものではない。
以上のように、本実施形態に係る光源装置30によれば、発光される白色光の青色成分が、傷害度の低い、人の眼に優しいピーク波長の範囲を有する第1LEDチップ102によって実現されるので、人の眼に優しい白色光を発光することができる。しかも、蛍光体の励起効率がよいピーク波長の範囲を有する第2LEDチップ103が用いられているので、白色光を形成する青色成分以外の赤色成分、緑色成分を効率よく得ることができるため、白色光を高効率で発光させることができる。
本発明のさらに他の実施の形態について説明すれば、以下の通りである。なお、本実施形態に係る光源装置は、前記実施形態3の光源装置30と基本的な構成は同じで、各LEDチップを封止する樹脂の種類が異なる点で異なる。
図4は、本実施形態に係る光源装置における樹脂封止前の状態を示す平面図である。
図5の(a)に示す光源装置40では、第1LEDチップ102を封止する樹脂として、透明な高チクソ性の樹脂を用いて、第1封止樹脂層111が形成され、第2LEDチップ103を封止する樹脂として、赤色蛍光体及び緑色蛍光体を混錬した樹脂を用いて、第2封止樹脂装置112が形成されている。
(1)EuaSibAlcOdNeで実質的に表されるβ型SiAlONである2価のユーロピウム賦活酸窒化物蛍光体。
(2)MI3―xCexMII5O12で表され、MIはLu、Y、La、およびGdの中から選択される少なくとも1種の元素、MIIはAl、Gaの中から選択される少なくとも1種の元素であるガーネット型の3価のセリウム賦活酸化物蛍光体。
(3)MIII2―xEuxSiO4で表され、MIIIはMg、Ca、Sr、およびBaから選ばれる少なくとも1種の元素である2価のユーロピウム賦活珪酸塩蛍光体。
(4)MIII3-xCexMIV2Si3O12で実質的に表され、MIIIは、Mg、Ca、Sr、およびBaの中から選択される少なくとも1種の元素であり、MIVは、Li、Na、K、Cs、Rb、Mg、Ca、Ba、Al、Ga、In、Sc、Y、La、Gd、およびLuから選択される少なくとも1種の元素である3価のセリウム賦活珪酸塩蛍光体。
(5)MI3-xCexSi6N11で表され、Lu、Y、La、およびGdの中から選択される少なくとも1種の元素ある3価のセリウム賦活窒化物蛍光体。
(1)MIII1-xEuxMVSiN3で実質的に表され、MIIIは、Mg、Ca、Sr、およびBaの中から選択される少なくとも1種の元素であり、MVは、Al、Ga、In、Sc、Y、La、Gd及びLuから選択される少なくとも1種の元素である2価のユーロピウム賦活窒化物蛍光体。
(2)MIII2-xEuxSi5N8で実質的に表され、MIIIは、Mg、Ca、Sr、およびBaの中から選択される少なくとも1種の元素である2価のユーロピウム賦活窒化物蛍光体。
(3)EufMVIgSihAliOjNkで実質的に表され、MVIはLi、Na、K、Rb、Cs、Mg、Ca、Sr、Ba、Sc、Y、La、およびGdから選択される少なくとも1種の元素であるα型SiAlONである2価のユーロピウム賦活酸窒化物蛍光体。
(4)MVII2(MVIII1-xMnx)F6で実質的に表され、MVIIはLi、Na、K、Rb、およびCsから選ばれる少なくとも1種のアルカリ金属元素、MVIIIはGe、Si、Sn、Ti、およびZrから選ばれる少なくとも1種の元素である4価のマンガン賦活フッ化金属塩蛍光体。
本実施形態に係る光源装置40,50は、前記実施形態1~3と同様に、いずれも第1LEDチップ102(ピーク波長の範囲が460nm~500nm)を備えているため、人の眼に優しい白色光を発光することができる。
本発明のさらに他の実施形態について説明すれば、以下の通りである。
本実施形態では、二系統入力の一系統(電極ランド106,107)を第1LEDチップ102に割り当て、もう一系統(電極ランド108,109)を第2LEDチップ103に割り当てる。このように、信号の入力系統(信号入力系統)を分けることで、チップ特性が異なる場合に柔軟に対応することができる。
上記の各実施形態の光源装置10~60による効果の一つである、人の眼に優しい点について、図8のグラフを参照しながら以下に説明する。
前記実施形態1~5の光源装置の製造方法について以下に説明する。
発光素子(第1LEDチップ102、第2LEDチップ103、青色チップ131、緑色チップ133、赤色チップ132等)を基板(基板101)に実装する。具体的には、まず、発光素子を、例えばシリコーン樹脂などの接着樹脂を用いてダイボンディングする。本説明では、発光素子は、導電体配線で囲まれる領域に20個配置される。
光反射樹脂枠を、導電体配線を覆うように形成する。具体的には、例えば樹脂吐出装置を用いて、液状のアルミナフィラー含有シリコーン樹脂を、丸形状の開口部を持つノズルから吐出しながら、所定の位置に描画する。そして、硬化温度:120℃、硬化時間:1時間の条件で加熱硬化処理を施すことにより、光反射樹脂枠(ダムリング105)を形成する。なお、硬化温度および硬化時間は一例であり、これに限定されない。
続いて、封止樹脂(蛍光体含有樹脂または蛍光体を含有しない透光性樹脂)を基板上に形成する。具体的には、液状の透光性樹脂に蛍光体を分散させたものである蛍光体含有樹脂を、光反射樹脂枠により囲まれた領域を満たすよう注入する。蛍光体含有樹脂を注入した後は、所定の温度および時間で硬化させる。これによって、発光素子およびワイヤが封止樹脂によって覆われて保護される。蛍光体を含有しない透光性樹脂の場合も蛍光体含有樹脂と同じ工程にて形成され、樹脂中の蛍光体の有無のみが異なる。
本発明の態様1に係る光源装置(10,20,30,40,50,60)は、発光ダイオードを用いて白色光を発光する光源装置において、上記白色光の発光スペクトルのうち415~460nmの積分発光強度よりも460nm~500nmの積分発光強度が大であることを特徴としている。
101 基板
102 第1LEDチップ(第1発光ダイオード)
103 第2LEDチップ(第2発光ダイオード)
104 蛍光体含有樹脂層
105 ダムリング
106~109 電極ランド
111,121 第1封止樹脂層
112,122 第2封止樹脂層
112a、122a 緑色蛍光体
112b、121a 赤色蛍光体
131 青色チップ(第1発光ダイオード)
132 赤色チップ(赤色発光ダイオード)
133 緑色チップ(緑色発光ダイオード)
134 透光性封止樹脂層
Claims (9)
- 発光ダイオードを用いて白色光を発光する光源装置において、
上記白色光の発光スペクトルのうち415nm~460nmの積分発光強度よりも460nm~500nmの積分発光強度が大であることを特徴とする光源装置。 - 白色光の形成に必要な青色光を出射する第1発光ダイオードを含み、
上記第1発光ダイオードのピーク波長は、460nm~500nmの範囲であることを特徴とする請求項1に記載の光源装置。 - 上記第1発光ダイオードのピーク波長よりも短く、蛍光体を励起する第2発光ダイオードをさらに含んでいることを特徴とする請求項2に記載の光源装置。
- 上記第2発光ダイオードのピーク波長は、415nm~460nmの範囲であることを特徴とする請求項3に記載の光源装置。
- 上記第1発光ダイオード及び第2発光ダイオードは、蛍光体含有封止樹脂により封止されていることを特徴とする請求項3または4に記載の光源装置。
- 上記第1発光ダイオード及び第2発光ダイオードは、それぞれ異なる蛍光体含有封止樹脂により封止されていることを特徴とする請求項3または4に記載の光源装置。
- 白色光の発光時に用いられる緑色光を出射する緑色発光ダイオードと、
白色光の発光時に用いられる赤色光を出射する赤色発光ダイオードをさらに含んでいることを特徴とする請求項2に記載の光源装置。 - 上記第1発光ダイオードに対する信号の入力系統は、他の発光ダイオードに対する信号入力系統と異なることを特徴とする請求項2~7の何れか1項に記載の光源装置。
- 請求項1~8の何れか1項に記載の光源装置を備えていることを特徴とする発光装置。
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| CN201480034605.0A CN105324859B (zh) | 2013-06-18 | 2014-06-16 | 光源装置以及发光装置 |
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| Publication number | Publication date |
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| JP6396295B2 (ja) | 2018-09-26 |
| JP2017118130A (ja) | 2017-06-29 |
| US20160149094A1 (en) | 2016-05-26 |
| CN105324859A (zh) | 2016-02-10 |
| JPWO2014203839A1 (ja) | 2017-02-23 |
| JP6549165B2 (ja) | 2019-07-24 |
| US10026875B2 (en) | 2018-07-17 |
| CN105324859B (zh) | 2019-06-04 |
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