WO2014148245A1 - シャンプー組成物 - Google Patents
シャンプー組成物 Download PDFInfo
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- WO2014148245A1 WO2014148245A1 PCT/JP2014/055451 JP2014055451W WO2014148245A1 WO 2014148245 A1 WO2014148245 A1 WO 2014148245A1 JP 2014055451 W JP2014055451 W JP 2014055451W WO 2014148245 A1 WO2014148245 A1 WO 2014148245A1
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- Prior art keywords
- component
- mass
- hair
- shampoo composition
- smoothness
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Definitions
- the present invention relates to a shampoo composition.
- the hair does not spread and is easy to style, the hair does not stick together, it is finished lightly, and it has both smoothness and softness. It is desired to provide a shampoo composition having excellent properties.
- the present invention makes it a subject to solve the said various problems in the past and to achieve the following objectives. That is, the present invention is easy to style without hair spreading even in areas where the environment changes between high temperature and high humidity and low humidity where the air conditioner is effective, and the hair does not stick together, finishes lightly, and is smooth and soft. Another object of the present invention is to provide a shampoo composition that has both the same properties and excellent usability.
- the shampoo composition of the present invention as a means for solving the above problems, (A) an anionic surfactant having a sulfuric acid residue; (B) a gallic acid glycoside, (C) a gloss imparting agent; (D) a cationic polymer; (E) 0.15% by mass to 5.0% by mass of a silicone compound; Containing The mass ratio (B + C) / (A + D) of the component (B) and the component (C) to the component (A) and the component (D) is 0.05 to 0.6,
- the component (A) contains polyoxyethylene alkyl ether sulfate (A1) and alkyl sulfate (A2),
- the component (D) comprises a cationized guar gum (D1) and a cationized cellulose (D2), and a mass ratio D1 / D2 between the component (D1) and the component (D2) is 2 to 20,
- the component (E) is composed of dimethylpolysiloxane (E
- the above-described problems can be solved and the above-mentioned object can be achieved, and the hair does not spread even in a region where the environmental change is severe between high temperature and high humidity and low humidity where the air conditioner is effective.
- a shampoo composition that is easy to style, does not stick to each other, is lightly finished, has both smoothness and softness, and has excellent usability.
- the shampoo composition of the present invention comprises an anionic surfactant having a sulfate residue (hereinafter sometimes referred to as “component (A)”), a gallic acid glycoside (hereinafter referred to as “component (B)”)
- component (C) A gloss imparting agent
- component (D) a cationic polymer
- component (E) component a silicone compound
- anionic surfactant having sulfuric acid residue is a component that forms a suitable foam and serves as a cleaning base that removes dirt attached to the hair.
- the component (A) is not particularly limited as long as it has a sulfate residue, and can be appropriately selected according to the purpose.
- the salt is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include alkali metals such as sodium and potassium; ammonium; alkanolamine and the like.
- component (A) polyoxyalkylene alkyl ether sulfates, polyoxyalkylene alkenyl ether sulfates, and alkyl sulfates are preferable, and anionic surfactants represented by the following general formula (A1) ( Hereinafter, an anionic surfactant represented by the following general formula (A2) (hereinafter may be referred to as “component (A2)”) is more preferred.
- R 1 represents an alkyl or alkenyl group having 10 to 18 carbon atoms
- M 1 represents any one of an alkali metal, ammonium, and an alkanolamine
- m represents The number of added moles is an average number of 1 to 5.
- A2) [In the general formula (A2), R 2 represents an alkyl group having 10 to 18 carbon atoms, and M 2 represents any one of an alkali metal, ammonium, and alkanolamine. ]
- R 1 in the general formula (A1) and / or R 2 in the general formula (A2) from the viewpoint of achieving both the dissolution stability in the shampoo composition and the goodness of fingering of the hair during hair washing, Alkyl groups having 12 to 16 carbon atoms are preferred.
- m in the general formula (A1) is preferably 2 to 3 from the viewpoint that smoothness can be imparted to the hair during rinsing.
- M 1 in the general formula (A1) or M 2 in the general formula (A2) is the smoothness of the hair at the time of rinsing, quick drying of the hair after washing, and ease of hair styling. Ammonium is particularly preferred.
- Texapon ALES 70 POE (3) ammonium lauryl ether sulfate, manufactured by BASF
- Sinoline SPE-1250 POE (2) sodium lauryl ether sulfate, manufactured by Shin Nippon Chemical Co., Ltd.
- (A1) component such as Texapon ALS 70 (ammonium lauryl sulfate, manufactured by BASF)
- (A2) component such as Texapon K12 (sodium lauryl sulfate, manufactured by BASF), and the like.
- Texapon ALES 70 POE (3) ammonium lauryl ether sulfate, as the component (A2), Texapon ALS 70 (ammonium lauryl sulfate, BASF) Product.
- the component (A) it is particularly preferable to use the component (A1) and the component (A2) in combination.
- the component (A) is only the component (A1), the styling of the hair under high humidity and the smoothness of the hair at the time of rinsing are reduced or sufficient foaming cannot be obtained. Sometimes.
- the styling of the hair under high humidity and the smoothness of the hair during rinsing are reduced, or the smoothness of the hair during rinsing is performed. May be insufficient.
- the content of the component (A1) is not particularly limited and may be appropriately selected depending on the intended purpose. It is preferably 3% by mass to 24% by mass, and preferably 5% by mass to the total amount of the shampoo composition. 22% by mass is more preferable, and 7% by mass to 15% by mass is particularly preferable.
- the content of the component (A1) is less than 3% by mass, the smoothness of the hair at the time of rinsing may be reduced, and when it exceeds 24% by mass, foaming at the time of rinsing is deteriorated, viscosity May increase and usability may deteriorate.
- the content of the component (A2) is not particularly limited and may be appropriately selected depending on the intended purpose. It is preferably 1% by mass to 15% by mass, and preferably 2% by mass to the total amount of the shampoo composition. 12% by mass is more preferable, and 3% by mass to 10% by mass is particularly preferable.
- the content of the component (A2) is less than 1% by mass, the foaming at the time of rinsing may deteriorate, and when it exceeds 15% by mass, the smoothness of the hair at the time of rinsing may be reduced. .
- the content of the component (A) (the total content of the component (A1) and the component (A2)) is not particularly limited and may be appropriately selected depending on the intended purpose. From the viewpoint of good foaming at the time and smoothness of the hair at the time of rinsing, 5% by mass to 30% by mass is preferable, 10% by mass to 25% by mass is more preferable, and 12% by mass with respect to the total amount of the shampoo composition % To 20% by mass is particularly preferable.
- the content of the component (A) is less than 5% by mass, foaming may deteriorate, and the smoothness of the hair during rinsing may decrease.
- the content exceeds 30% by mass the viscosity is high and usability is high. May cause poor foaming, poor foaming during rinsing, and reduced smoothness of hair during rinsing.
- the mass ratio A1 / A2 between the component (A1) and the component (A2) is not particularly limited and may be appropriately selected depending on the intended purpose.
- foam performance, smoothness of hair during rinsing, high temperature and high humidity 1 to 7 is preferable and 1.3 to 4 is more preferable from the viewpoint of preventing stickiness of hair after drying at a temperature of 27 ° C. and a humidity of 70% RH.
- the smoothness of the hair at the time of rinsing may be reduced, and when it exceeds 7, after drying at high temperature and high humidity (temperature 27 ° C., humidity 70% RH) May cause stickiness of the hair, making it difficult to style, reducing the lightness of the hair, and the smoothness of the hair after drying.
- high temperature and high humidity temperature 27 ° C., humidity 70% RH
- gallic acid glycoside which is the component (B) is soft to the hair after drying, and the hair does not spread even under low humidity (temperature 25 ° C., humidity 40% RH), and is easy to style, And it is a component which can give the function that hair does not stick easily, hair becomes non-sticky, and hair is finished lightly.
- the gallic acid glycoside is not particularly limited and may be appropriately selected depending on the intended purpose.
- gallic acid-3,4-diglucoside and gallic acid-3,5-diglucoside are particularly preferable from the viewpoint of softness of the hair after drying.
- gallic acid glycoside of the component (B) a commercially available product may be used, or an appropriately synthesized product may be used.
- examples of the commercially available products include gallic acid-3,4-diglucoside (DGA, manufactured by Mitsui Chemicals), gallic acid-3,5-diglucoside (DGA, manufactured by Mitsui Chemicals), and the like.
- the content of the gallic acid glycoside as the component (B) is not particularly limited and may be appropriately selected depending on the intended purpose, but is 0.01% by mass to 7.% by mass relative to the total amount of the shampoo composition. 5 mass% is preferable, 0.05 mass% to 3 mass% is more preferable, and 0.1 mass% to 1 mass% is still more preferable.
- the content is less than 0.01% by mass, the softness of the hair cannot be obtained, and the hair becomes too wide at high temperature and high humidity (temperature 27 ° C., humidity 70% RH), making styling difficult. May end up.
- the amount of hair adsorbed becomes excessive, under high temperature and high humidity (temperature 27 ° C., humidity 70% RH), under low temperature and low humidity (temperature 25 ° C., humidity 40 % RH), the hairs stick to each other, making it difficult to style the hair, and the hair may become sticky and the lightness of the hair may decrease.
- gloss imparting agent The gloss imparting agent (also referred to as “gloss agent”, “pearling agent”, “pearl imparting agent”, etc.) as the component (C) imparts a pearl-like gloss to the shampoo composition. Can do. This is advantageous in that the commercial value can be increased.
- the component (C) not only imparts a pearly luster to the shampoo composition, but the hair does not spread under high temperature and high humidity (temperature 27 ° C., humidity 70% RH), and the hairs are difficult to stick together. Hair styling is easy and the hair is not sticky and light.
- the component (C) is not particularly limited and may be appropriately selected depending on the intended purpose.
- ethylene glycol, diethylene glycol or triethylene glycol stearates are preferred, and specifically, hydroxystearate.
- Examples include polyethylene glycol monostearate, polyethylene glycol distearate, ethylene glycol monostearate, ethylene glycol distearate, stearic acid monoethanolamide, and stearic acid monoethanol stearate. These may be used alone or in combination of two or more.
- Ethylene glycol distearate is particularly preferred.
- the component (C) can generally impart a pearly luster to the shampoo composition by being dispersed as a crystal in the shampoo composition.
- fusing point of this (C) component The method of cooling what mixed this (C) component in the surface-active-agent aqueous solution cooled, etc. are mentioned.
- a pearly luster is suitably imparted to the shampoo composition by adding a dispersion of the crystal of the component (C) to the shampoo composition so that the component (C) has a predetermined concentration. can do.
- the median particle diameter of the dispersion of the crystal of the component (C) is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 0.5 ⁇ m to 6 ⁇ m, and more preferably 1 ⁇ m to 3 ⁇ m. If the median particle size is less than 0.5 ⁇ m, the smoothness of the hair during rinsing may be reduced, and a pearly luster cannot be imparted, resulting in a loss of luxury. When the median particle diameter exceeds 6 ⁇ m, the lightness of the hair after drying and the dry feeling of the hair ends may be lowered, and the preferable washing feeling may be lowered.
- the dispersion shape of the crystal of the component (C) is preferably a needle crystal.
- the needle-like crystals By forming the needle-like crystals, the smoothness of the hair during rinsing is improved.
- the median particle diameter is generally expressed as D50, and refers to a diameter in which the large side and the small side are equivalent when the dispersion is divided into two from a certain particle diameter.
- D50 a laser diffraction particle size distribution analyzer
- LA-920 manufactured by HORIBA, Ltd.
- the median particle size can be calculated by measuring the particle size distribution of the dispersion of the crystal of the component (C).
- the content of the gloss imparting agent of the component (C) is not particularly limited and can be appropriately selected according to the purpose.
- 1% by mass with respect to the total amount of the shampoo composition. Is preferably 5% by mass, more preferably 1.2% by mass to 4.5% by mass.
- the content is less than 1% by mass, the pearl appearance becomes weak, the hair tends to stick together under high temperature and high humidity (temperature 27 ° C., humidity 70% RH), hair styling is difficult, and the hair is light.
- the amount exceeds 5% by mass the smoothness of the hair after drying may be lowered, and the usability (ease of taking out from the bottle) may be inferior.
- ⁇ (D) component cationic polymer>
- the cationic polymer that is the component (D) is from cationized guar gum (hereinafter sometimes referred to as “(D1) component”) and cationized cellulose (hereinafter sometimes referred to as “(D2) component”). Become.
- (D1) component cationized guar gum
- the cationized guar gum as the component (D1) is also called guar hydroxypropyltrimonium chloride, O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum and the like.
- the nitrogen content of the component (D1) is not particularly limited and may be appropriately selected depending on the intended purpose. However, from the viewpoint that smoothness can be imparted to the hair during rinsing, 1% by mass to 1.8%. Those having a mass% are preferred, and those having a mass% of 1.1 to 1.45% are more preferred.
- the nitrogen content can be measured by decomposing the component (D1) with sulfuric acid to give ammonium sulfate and quantifying the ammonia by the Kjeldahl method. For details, refer to “Quasi-drug raw material standard 2006 (Pharmaceutical Daily)” general test method. It can be measured by the method described with reference to the nitrogen determination method.
- a commercial item may be used and what was synthesize
- the commercially available products include, under the trade names, JAGUAR C14S (nitrogen content: 1.3% by mass to 1.7% by mass), JAGUAR Excel (nitrogen content: 1.0% by mass to 3.0% by mass). ), JAGUAR series (manufactured by Rhodia) such as Jaguar C-500 (nitrogen content: 1.15% to 1.45% by mass); N-Hance CG14 (nitrogen content: 1.25% to 1.55% by mass) %), N-Hance 3299 (nitrogen content: 1.15% to 1.45% by mass), N-Hance CCG45 (nitrogen content: 1.15% to 1.45% by mass), etc.
- N-Hance 3299, N-Hance CCG45, and Jaguar C-500 are particularly preferable in terms of the smoothness of the hair during rinsing and the smoothness of the hair after drying.
- the content of the component (D1) is not particularly limited and may be appropriately selected depending on the intended purpose. However, it is suitable for defoaming at the time of rinsing, smoothness of the hair at the time of rinsing, and smoothness of the hair after drying.
- the total amount of the shampoo composition is preferably 0.075% by mass to 4.5% by mass, more preferably 0.1% by mass to 1.1% by mass, and 0.2% by mass to 0% by mass. More preferably, 6% by mass.
- the content of the component (D1) is less than 0.075% by mass, the smoothness of the hair at the time of rinsing may be reduced, and when it exceeds 4.5% by mass, the hair is soft after drying. , Bubbles may be lost during rinsing, and usability may deteriorate.
- ⁇ (D2) component cationized cellulose
- the cationized cellulose as the component (D2) is a salt of hydroxyethyl cellulose reacted with a trimethylammonium substituted epoxide, which is also called polyquaternium-10, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose, or the like. It is.
- the nitrogen content of the component (D2) is not particularly limited and may be appropriately selected depending on the intended purpose. However, the foaming at the time of rinsing is good and the hair can be smoothened at the time of rinsing. From 1.5% by mass to 2.2% by mass is preferable, and from 1.6% by mass to 2.0% by mass is more preferable.
- the nitrogen content can be measured by decomposing the component (D2) with sulfuric acid to give ammonium sulfate and quantifying the ammonia by the Kjeldahl method. For details, refer to “Quasi-drug raw material standard 2006 (Pharmaceutical Daily)” general test method. It can be measured by the method described with reference to the nitrogen determination method.
- a commercially available product may be used, or an appropriately synthesized product may be used.
- the commercially available products include trade names of UCARE Polymer JR400 (nitrogen content: 1.5 mass% to 2.2 mass%), UCARE Polymer JR-30M (nitrogen content: 1.5 mass% to 2 mass%).
- UCARE Polymer JR series (manufactured by Dow Chemical Company), etc .; Katchinal HC 100, Katchinal HC 200, etc. Katchinal HC series (manufactured by Toho Chemical Co., Ltd.); Leo Guard GP, Leo Guard KGP, Leo Guard MGP, etc.
- MICONIUM® PQ10-J-400 nitrogen content: 1.5% to 2.2% by mass
- MIWON Manufactured by MIWON.
- MICONIUM registered trademark
- Leogard GP Leogard GP
- Leogard KGP are particularly preferable because they can be used to remove bubbles during rinsing and can impart smoothness to hair during rinsing.
- the content of the component (D2) is not particularly limited and may be appropriately selected depending on the purpose.
- the shampoo composition is preferable in terms of good foam loss during rinsing and smooth hair during rinsing. 0.01 mass% to 1 mass% is preferable with respect to the total amount, 0.03 mass% to 0.7 mass% is more preferable, and 0.09 mass% to 0.5 mass% is still more preferable.
- the content of the component (D2) is less than 0.01% by mass, the smoothness of the hair at the time of rinsing may be reduced, and when it exceeds 1% by mass, the softness of the hair after drying, and Bubbles may be lost during rinsing.
- the total content of the component (D1) and the component (D2) (hereinafter sometimes referred to as “content of the component (D)”) is not particularly limited and can be appropriately selected depending on the purpose. However, it is preferably 0.1% by mass to 5% by mass, more preferably 0.2% by mass to 1.5% by mass, and more preferably 0.3% by mass to 0.8% by mass with respect to the total amount of the shampoo composition. Further preferred. When the content of the component (D) is less than 0.1% by mass, the smoothness of the hair after drying may not be obtained. When the content exceeds 5% by mass, the softness of the hair after drying is not obtained.
- the shampoo composition may be gelled to increase the viscosity and deteriorate the usability.
- the mass ratio D1 / D2 between the component (D1) and the component (D2) is 2 to 20, preferably 3 to 15 in terms of the smoothness of the hair when rinsing and the smoothness of the hair after drying. 3 to 9 are more preferable.
- the mass ratio D1 / D2 is less than 2, the smoothness of the hair during rinsing may be reduced, and when it exceeds 20, the smoothness of the hair after drying may be reduced.
- the silicone compound as component (E) is composed of dimethylpolysiloxane (hereinafter sometimes referred to as “(E1) component”) and amino-modified silicone (hereinafter sometimes referred to as “(E2) component”). .
- the component (E1) is not particularly limited as long as it is dimethylpolysiloxane, and can be appropriately selected according to the purpose. Examples thereof include trimethylsilyl group-terminated dimethylpolysiloxane and silanol group-terminated dimethylpolysiloxane. . Among these, trimethylsilyl group-terminated dimethylpolysiloxane is preferable in terms of lightness of the hair after drying, smoothness of the hair after drying, and the point of being able to impart a smooth feeling to the hair tips.
- the kinematic viscosity of the dimethylpolysiloxane at 25 ° C. is 10,000 mm 2 / s from the point that the hair after drying, the smoothness of the hair after drying, and the hair tip can be given a dry feeling. preferably ⁇ 30,000,000mm 2 / s, more preferably 100,000mm 2 / s ⁇ 10,000,000mm 2 / s, 100,000mm 2 / s ⁇ 1,000,000mm 2 / s is particularly preferred.
- the kinematic viscosity at 25 ° C. of the dimethylpolysiloxane can be measured, for example, by the method shown below.
- a toluene solution of dimethylpolysiloxane having a concentration of 1 g / 100 mL is prepared, and the specific viscosity ⁇ sp (25 ° C.) is obtained by the following formula (1).
- the intrinsic viscosity [ ⁇ ] is obtained by substituting it into the Huggins relational expression shown in the following formula (2). As the Huggins constant, those described in Nakamuta, Nikka, 77, 588, 1956 are used.
- [ ⁇ ] is represented by the following formula (3). Substituting it into the Kololov equation to determine the molecular weight.
- the component (E1) is preferably pre-emulsified with an emulsifier from the viewpoint of production efficiency and dispersion stability of the shampoo composition.
- an emulsifier and the emulsification method at the time of emulsifying the said (E1) component According to the objective, it can select suitably.
- the number average particle diameter of the component (E1) in the emulsion is not particularly limited and may be appropriately selected depending on the intended purpose. However, it is easy to follow the hair during hair washing, and the hair is dried after washing. Is preferably 0.5 ⁇ m to 60 ⁇ m, more preferably 10 ⁇ m to 50 ⁇ m, and particularly preferably 15 ⁇ m to 40 ⁇ m.
- the number average particle size is less than 0.5 ⁇ m, the hairs tend to stick together under high temperature and high humidity (temperature 27 ° C., humidity 70% RH), styling is difficult, stickiness occurs, and the hair is light. If it exceeds 60 ⁇ m, the smoothness of the hair during rinsing may be reduced.
- the number average particle diameter is obtained by arbitrarily capturing images of particles observed with an optical microscope into 100 computers and setting the same magnification, and then performing image processing (for example, two-dimensional image analysis software WinROOF).
- (E1) component a commercial item may be used and what was synthesize
- the trade name BY22-029 [kinematic viscosity: 100,000 mm 2 / s, number average particle size: 0.5 ⁇ m] (Toray Dow Corning Co., Ltd.) DC-7137 (kinematic viscosity: 600,000 mm 2 / s, number average particle size: 35 ⁇ m) (manufactured by Dow Corning); KM-902 (kinematic viscosity: 500,000 mm 2 / s, number average particle size) : 0.5 ⁇ m] (manufactured by Shin-Etsu Chemical Co., Ltd.); Rheoflow DMS-55 [kinematic viscosity: 100,000 mm 2 / s, number average particle size: 0.5 ⁇ m], Rheoflow DMS-60 [kinematic viscosity: 10 , 000,
- DC-7137 and EMU120 are preferable from the viewpoint of smoothness of hair after drying, lightness of hair under high temperature and high humidity (temperature 27 ° C., humidity 70% RH), and ease of styling.
- the content of the component (E1) is preferably 0.1% by mass to 4.8% by mass and preferably 0.5% by mass with respect to the total amount of the shampoo composition from the viewpoint of obtaining smooth hair after drying. More preferred is 3% by mass.
- the content of the component (E1) is less than 0.1% by mass, the smoothness of the hair during rinsing and the smoothness of the hair after drying may not be obtained. Exceeding this makes it easy for the hairs to stick together under high temperature and high humidity (temperature 27 ° C., humidity 70% RH), reducing the styling of the hair, causing stickiness to the hair, and reducing the lightness of the hair. Sometimes.
- ⁇ (E2) component amino-modified silicone>
- the amino-modified silicone as the component (E2) is not particularly limited and may be appropriately selected depending on the intended purpose.
- an aminoethylaminopropylsiloxane / dimethylsiloxane copolymer hereinafter referred to as “amodimethicone”.
- Aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer hereinafter sometimes referred to as “aminoethylaminopropylmethicone / dimethicone copolymer”
- amino-modified organopolysiloxane chain and polyoxyalkylene examples thereof include a copolymer having a chain with a chain (hereinafter sometimes referred to as “linear amino polyether-modified silicone”), aminopropyl dimethicone, and the like. These may be used alone or in combination of two or more.
- amodimethicone and linear amino polyether-modified silicone are preferable from the viewpoint that the smoothness of the hair at the time of rinsing can be imparted.
- the component (E2) component a commercial item may be used and what was synthesize
- Specific examples of commercially available products of the component (E2) include SM8904CE, BY22-079, FZ-4671 (Amodimethicone emulsion, manufactured by Toray Dow Corning Co., Ltd.), DC2-8194 (produced by Dow Corning).
- Amodimethicone such as KF-8004, KF-867S, KF-880 (manufactured by Shin-Etsu Chemical Co., Ltd.); Aminoethylaminopropyl methicone-dimethicone copolymer such as KF-8005 (manufactured by Shin-Etsu Chemical Co., Ltd.) SILSTYLE 104 (bisisobutyl PEG-14 / amodimethicone) copolymer, SILSTYLE 201 (bisisobutyl PEG-14 / amodimethicone) copolymer, SILSTLE 401 (bisbutoxyoxydimethicone / PEG-60) copolymer (above, Toray Dowconi) Linear amino polyether-modified silicone such as KF-8015, KF-865, KF-8017, KF-8018, KF-8020 (manufactured by Shin-Etsu Chemical Co., Ltd.
- the content of the component (E2) is not particularly limited and may be appropriately selected depending on the purpose. It is preferably 0.01% by mass to 1.5% by mass with respect to the total amount of the shampoo composition, More preferably, the content is 0.1% by mass to 1% by mass.
- the content of the component (E2) is less than 0.01% by mass, smoothness of the hair after drying may not be obtained.
- the content exceeds 1.5% by mass, under high temperature and high humidity (temperature At 27 ° C., humidity 70% RH), the hairs tend to stick together, the styling ease decreases, the hair becomes sticky, and the hair lightness may decrease.
- the total content of the component (E1) and the component (E2) (hereinafter sometimes referred to as “content of the component (E)”) is high temperature and high humidity (temperature 27 ° C., humidity 70% RH). From the standpoint of preventing the styling of hair from spreading, it is 0.15% by mass to 5.0% by mass, and 0.8% by mass to 3.8% by mass with respect to the total amount of the shampoo composition. preferable. When the content of the component (E) is less than 0.15% by mass, the smoothness of the hair at the time of rinsing and the smoothness of the hair after drying may not be obtained.
- the mass ratio E1 / E2 between the component (E1) and the component (E2) is 2 to 30, preferably 5 to 27.
- the mass ratio E1 / E2 is less than 2, after drying under high temperature and high humidity (temperature 27 ° C., humidity 70% RH), the hairs tend to stick to each other, and the styling ease decreases. It may become sticky, the lightness of the hair may decrease, and may result in a shampoo composition with poor cleaning feeling.
- the mass ratio E1 / E2 exceeds 30, the smoothness and usability of the hair after drying may decrease.
- the mass ratio (B + C) / (A + D) of the component (B) and the component (C) to the component (A) and the component (D) is high temperature and high humidity (temperature 27 ° C., humidity 70% RH).
- the mass ratio (B + C) / (A + D) is less than 0.05, the hairs tend to stick together under high temperature and high humidity (temperature 27 ° C., humidity 70% RH), and the styling of the hair is easy.
- the hair may become sticky and the lightness of the hair may decrease, and if it exceeds 0.6, the hair tends to stick together under high temperature and high humidity (temperature 27 ° C, humidity 70% RH), and hair styling
- high temperature and high humidity temperature 27 ° C, humidity 70% RH
- hair styling The ease of care may decrease, the hair may become sticky, the lightness of the hair may decrease, and the smoothness of the hair after drying may deteriorate.
- the mass ratio (B + C) / (A + D) is within the above numerical range, the hair does not spread both under high temperature and high humidity (temperature 27 ° C., humidity 70% RH) and under low humidity where the air conditioner works. It is advantageous in terms of lightness of the hair because it is easy to style hair, it is difficult for the hairs to stick together, the hair is not sticky.
- An inhibitor, a chelating agent, a pH adjuster, an ultraviolet absorption / scattering agent, vitamins, amino acids, a fragrance, a pigment, water, and the like can be appropriately blended as necessary. These may be used alone or in combination of two or more.
- oils examples include castor oil, olive oil, cacao oil, hydrogenated palm oil, coconut oil, coconut oil, tree wax, jojoba oil, grape seed oil, avocado oil and the like, or ester compounds thereof, mink oil, Animal fats such as egg yolk oil, waxes such as beeswax, whale wax, lanolin, hydrogenated lanolin, carnauba wax, candelilla wax, hydrocarbons such as liquid paraffin, squalane, microcrystalline wax, ceresin wax, paraffin wax, petrolatum Natural and synthetic fatty acids such as lauric acid, myristic acid, stearic acid, oleic acid, isostearic acid, behenic acid, glycerol tri-2-ethylhexanoate, 2-ethylhexyl stearate, butyl stearate, isopropyl myristate, Isopro palmitate Le, octyldodecyl myristate, esters of oct
- alcohols examples include natural and synthetic higher alcohols such as cetyl alcohol, oleyl alcohol, stearyl alcohol, hexyl decanol, octyl decanol, and lauryl alcohol.
- humectant examples include 1,3-butanediol, isoprene glycol, 1,2-pentanediol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, diethylene glycol monoalkyl ether, polyethylene glycol (average molecular weight is 200, 300, 400, 600, 1,000, or 1,500), polypropylene glycol, polyethylene glycol / polypropylene glycol, hydrogenated castor oil (30EO), glycerin, diglycerin, triglycerin, polyglycerin, sorbitol, etc. Can be mentioned.
- the thickener examples include natural polymers such as sodium alginate, xanthan gum, aluminum oxalate, quince seed extract, tragacanth gum, starch, and semisynthetic compounds such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, and soluble starch.
- natural polymers such as sodium alginate, xanthan gum, aluminum oxalate, quince seed extract, tragacanth gum, starch
- semisynthetic compounds such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, and soluble starch.
- synthetic polymers such as polymers, carboxyvinyl polymers, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, and methacryloylethylbetaine / methacrylic acid ester copolymers.
- preservative examples include benzoate, sorbate, dehydroacetate, p-hydroxybenzoate, 2,4,4′-trichloro-2′-hydroxydiphenyl ether, 3,4,4′-trichlorocarbani Lido, benzalkonium chloride, hinokitiol, resorcin, methylchloroisothiazolinone / methylisothiazolinone solution (trade name Caisson CG; manufactured by Rohm and Haas Japan), salicylic acid, pentanediol, phenoxyethanol, ethanol, etc. Can be mentioned.
- antioxidants examples include dibutylhydroxytoluene, butylhydroxyanisole, ascorbic acid, and the like.
- chelating agent examples include edetate disodium, ethylenediaminetetraacetate, hexametaphosphate, gluconic acid, and the like.
- pH adjuster examples include sodium hydroxide, potassium hydroxide, citric acid, succinic acid, triethanolamine, aqueous ammonia, triisopropanolamine, phosphoric acid, glycolic acid, and the like.
- ultraviolet absorbing / scattering agent examples include 2-hydroxy-4-methoxybenzophenone, octyldimethylparaaminobenzoate, ethylhexylparamethoxycynamate, titanium oxide, kaolin, and talc.
- vitamins examples include vitamin A, vitamin B group, vitamin C, vitamin D, vitamin E, vitamin F, vitamin K, vitamin P, vitamin U, carnitine, ferulic acid, ⁇ -oryzanol, ⁇ -lipoic acid, Orotic acid or a derivative thereof.
- amino acids examples include glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, glutamic acid, arginine, histidine, lysine or a derivative thereof. It is done.
- fragrances examples include fragrance ingredients described in paragraphs [0021] to [0035] of JP-A No. 2003-300811, fragrance solvents described in paragraph [0050], and the like.
- the pH of the shampoo composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 5.0 to 6.0 at 25 ° C.
- the pH can be measured, for example, by measuring the shampoo composition at 25 ° C. using a pH meter (HM-30G, manufactured by Toa DKK Corporation).
- the pH of the shampoo composition can be adjusted using a desired pH adjuster.
- the pH adjuster is not particularly limited and may be appropriately selected depending on the intended purpose. For example, citric acid, succinic acid, sulfuric acid, 2-amino-2-methyl-1-propanol, monoethanolamine, or These salts are mentioned.
- the viscosity of the shampoo composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 1 Pa ⁇ s to 30 Pa ⁇ s at 25 ° C.
- the viscosities are measured using, for example, a viscometer (BM type viscometer, manufactured by TOKIMEC). The measurement can be performed under the condition of 25 ° C. after 30 seconds at 30 rpm with a 4-rotor.
- the container for the shampoo composition is not particularly limited and may be appropriately selected depending on the purpose. It can be filled into a dispenser container and a squeeze container, a laminate film container, a dropper container, a stick container, a bottle container, etc. by differential pressure.
- the laminate film usually has two or more layers, and the materials thereof are polyethylene resin, polyethylene terephthalate resin, polyester resin, biaxially stretched polypropylene resin, unstretched polypropylene resin, polyacrylonitrile resin, ethylene-vinyl acetate copolymer resin. It is comprised with synthetic resins, such as paper, aluminum vapor deposition plastics, etc.
- the material of the bottle is not particularly limited and may be appropriately selected depending on the purpose.
- polyethylene resin, polypropylene resin, polyethylene terephthalate resin, polystyrene resin, polyvinyl chloride resin, ethylene-vinyl alcohol copolymer resin polyethylene resin, polypropylene resin, polyethylene terephthalate resin, polystyrene resin, polyvinyl chloride resin, ethylene-vinyl alcohol copolymer resin
- a resin such as acrylonitrile-styrene copolymer resin, ABS resin, polyamide, or glass, or a single layer or a combination of two or more layers can be used.
- the shampoo composition is easy to style, since hair does not spread even in areas where the environment changes drastically between high temperature and high humidity (temperature 27 ° C, humidity 70% RH) and low humidity where the air conditioner is effective. It is lightly finished without sticking, has both smoothness and softness, and is excellent in usability. For example, it can be suitably used for skin cleansing shampoo, damage care shampoo, mild shampoo, rinse-in shampoo and the like. In addition to human hair, it can also be used for animal hair such as pets.
- Examples 1 to 50 and Comparative Examples 1 to 18 (A) component, (B) component, (C) component, (D) component, (E) component, and optional components described in the Examples and Comparative Examples shown in Tables 1 to 12 below were added, and 25 ° C. For 30 minutes.
- the gloss imparting agent ethylene glycol distearate
- component (C) a 4.5 mass% gloss imparting agent dispersion is prepared in advance by the following preparation method, and the gloss imparting agent in the shampoo composition is adjusted to a predetermined amount. Was added.
- 33.3% by mass of 4.5% by mass gloss imparting agent dispersion was added.
- polyoxyethylene lauryl sulfate and lauryl sulfate which are the components (A) are contained, and the blending amounts described in the examples are the addition amount from the gloss imparting agent dispersion liquid. It was described as the total amount of. After adding the gloss imparting agent dispersion, the mixture was sufficiently stirred, and the pH was adjusted to 5.8 with citric acid to obtain a shampoo composition.
- ethylene glycol distearate crystal dispersion as component (C) gloss imparting agent was prepared by the following method.
- the mixture was kept at 80 ° C. and stirred in a 2 L beaker.
- ethylene glycol distearate (Tegin EGS, manufactured by Evonik) melted at 80 ° C. was gradually added to the aqueous solution so as to have a final concentration of 4.5% by mass.
- Three-one motor (FBL1200, manufactured by HEIDEN Co.) was mixed uniformly at 100 rpm for 30 minutes using a 4-tilted paddle, and then dispersed and mixed at 4,500 rpm for 10 minutes using a homomixer (manufactured by Primics Co., Ltd.). Next, the dispersion mixture obtained was immersed in a water bath and the inside of the dispersion mixing tank was cooled to 35 ° C.
- Example 21 A 5 mass% ethylene glycol distearate crystal dispersion was prepared.
- Example 21 a 4.5 mass% ethylene glycol distearate crystal dispersion was prepared in the same manner as above using polyoxyethylene (2) sodium lauryl ether sulfate / sodium lauryl sulfate.
- the median particle size of the 4.5 mass% ethylene glycol distearate crystal dispersion was measured using a laser diffraction particle size distribution analyzer (LA-920, manufactured by Horiba, Ltd.), and the relative refractive index with respect to water was set to 1. .08 was measured.
- the median particle size was 2.0 ⁇ m. Further, the dispersed shape of the crystal was needle-like.
- ⁇ Evaluation method> Apply 6 mL of each shampoo composition to well-wetted hair, thoroughly foam it, wash it with hair, wash it off with a tap water temperature of 40 ° C. and a flow rate of 250 mL / 3 seconds, lightly towel dry, and then temperature 27 ° C. and humidity 70
- the process of resting in a room of% RH for 12 hours and resting in a room of temperature 25 ° C. and humidity 40% RH for 12 hours was repeated 7 times (the following cycle was repeated 7 times).
- the “smoothness of the hair when rinsing” was evaluated, and after drying the towel, it was allowed to rest in a room at a temperature of 27 ° C.
- Lightness of hair after drying at 27 ° C. and 70% RH was evaluated according to the following criteria. Based on the number of respondents who answered good, the following criteria were used. Here, “lightness of the hair” means that the hair is light and the hairs are scattered one by one. ⁇ Judgment criteria ⁇ ⁇ : 16 or more responded good ⁇ ⁇ ⁇ : 13 or more and 15 or less responded good ⁇ : 11 or more and 12 or less responded good ⁇ : 6 or more and 10 or less responded good ⁇ : 5 or less responded good
- Lightness of hair after drying at 25 ° C. and 40% RH was evaluated according to the following criteria. Based on the number of respondents who answered good, the following criteria were used. Here, “lightness of the hair” means that the hair is light and the hairs are scattered one by one. ⁇ Judgment criteria ⁇ ⁇ : 16 or more responded good ⁇ ⁇ ⁇ : 13 or more and 15 or less responded good ⁇ : 11 or more and 12 or less responded good ⁇ : 6 or more and 10 or less responded good ⁇ : 5 or less responded good
- Ease of hair styling after drying at 27 ° C. and 70% RH was evaluated according to the following criteria. Based on the number of respondents who answered good, the following criteria were used. Here, “ease of hair styling” means that the hair combs well and is easy to bundle. ⁇ Judgment criteria ⁇ ⁇ : 16 or more responded good ⁇ ⁇ ⁇ : 13 or more and 15 or less responded good ⁇ : 11 or more and 12 or less responded good ⁇ : 6 or more and 10 or less responded good ⁇ : 5 or less responded good
- Ease of hair styling after drying at 25 ° C. and 40% RH was evaluated according to the following criteria. Based on the number of respondents who answered good, the following criteria were used. Here, “ease of hair styling” means that the hair combs well and is easy to bundle. ⁇ Judgment criteria ⁇ ⁇ : 16 or more responded good ⁇ ⁇ ⁇ : 13 or more and 15 or less responded good ⁇ : 11 or more and 12 or less responded good ⁇ : 6 or more and 10 or less responded good ⁇ : 5 or less responded good
- Softness of hair after drying was evaluated according to the following criteria. The following evaluation criteria are shown according to the number of respondents who answered good. Here, the “softness of the hair after drying” means that the hair is supple when touched after drying. ⁇ Judgment criteria ⁇ ⁇ : 16 or more responded good ⁇ ⁇ ⁇ : 13 or more and 15 or less responded good ⁇ : 11 or more and 12 or less responded good ⁇ : 6 or more and 10 or less responded good ⁇ : 5 or less responded good
- the “usability” of the shampoo composition was evaluated according to the following criteria. The following evaluation criteria are shown according to the number of respondents who answered good. Here, “usability” indicates the ease of taking out the shampoo composition from the bottle. ⁇ Judgment criteria ⁇ ⁇ : 16 or more responded good ⁇ ⁇ ⁇ : 13 or more and 15 or less responded good ⁇ : 11 or more and 12 or less responded good ⁇ : 6 or more and 10 or less responded good ⁇ : 5 or less responded good
- Dimethylpolysiloxane B (emulsion) in Table 13 was prepared by the following method.
- Rheoflow DMS-60 manufactured by Yushi Co., Ltd.
- [Highly polymerized methylpolysiloxane with kinematic viscosity 10,000,000 mm 2 / s: Highly polymerized methylpolysiloxane with kinematic viscosity 4,000,000 mm 2 / s: Kinematic viscosity 1,000 mm 2 / s methylpolysiloxane 15: 15: 70 (mass ratio)]
- POE (15) cetyl ether (trade name: NPO-97, manufactured by Lion Chemical Co., Ltd.) was added as an emulsifier, Emulsified and dispersed.
- Examples of the aspect of the present invention include the following. ⁇ 1> (A) an anionic surfactant having a sulfuric acid residue; (B) a gallic acid glycoside, (C) a gloss imparting agent; (D) a cationic polymer; (E) 0.15% by mass to 5.0% by mass of a silicone compound; Containing The mass ratio (B + C) / (A + D) of the component (B) and the component (C) to the component (A) and the component (D) is 0.05 to 0.6,
- the component (A) contains polyoxyethylene alkyl ether sulfate (A1) and alkyl sulfate (A2),
- the component (D) comprises a cationized guar gum (D1) and a cationized cellulose (D2), and a mass ratio D1 / D2 between the component (D1) and the component (D2) is 2 to 20,
- the component (E) is composed of dimethylpolysiloxane (E1)
- a shampoo composition characterized. ⁇ 2> (A) 10% by mass to 25% by mass of an anionic surfactant having a sulfuric acid residue; (B) 0.05% by mass to 3% by mass of gallic acid glycoside, (C) The gloss-imparting agent is 1.2 mass% to 4.5 mass%, (D) 0.2% by mass to 1.5% by mass of the cationic polymer; It is a shampoo composition as described in said ⁇ 1> containing.
- the nitrogen content of the component (D1) is 1% by mass to 1.8% by mass, and the nitrogen content of the component (D2) is 1.5% by mass to 2.2% by mass.
- ⁇ 4> The shampoo composition according to any one of ⁇ 1> to ⁇ 3>, wherein a mass ratio A1 / A2 of the component (A1) to the component (A2) is 1 to 7.
- the shampoo composition of the present invention is easy to style without hair spreading even in areas where the environment changes severely between high temperature and high humidity and low humidity where the air conditioner is effective. Since it has both softness and softness, it can be suitably used for, for example, a skin cleansing shampoo, a damage care shampoo, a mild shampoo, and a rinse-in shampoo.
Abstract
Description
また、損傷毛及び毛髪のきしみ改善のために、没食子酸配糖体をシャンプー組成物に配合することが提案されている(例えば、特許文献5及び6参照)。
しかしながら、これらの提案の技術は、高温高湿度下において、コンディショニングシャンプーでは、毛髪がべたつき、毛髪同士がくっついて、スタイリングしにくく、毛髪の軽さ、なめらかさ及びやわらかさが損なわれしまうことがある。
(A)硫酸残基を有するアニオン性界面活性剤と、
(B)没食子酸配糖体と、
(C)光沢付与剤と、
(D)カチオン性ポリマーと、
(E)シリコーン化合物を0.15質量%~5.0質量%と、
を含有し、
前記(B)成分及び前記(C)成分と、前記(A)成分及び前記(D)成分との質量比(B+C)/(A+D)が、0.05~0.6であり、
前記(A)成分が、ポリオキシエチレンアルキルエーテル硫酸塩(A1)とアルキル硫酸塩(A2)とを含有し、
前記(D)成分が、カチオン化グアーガム(D1)及びカチオン化セルロース(D2)からなり、前記(D1)成分と前記(D2)成分との質量比D1/D2が、2~20であり、
前記(E)成分が、ジメチルポリシロキサン(E1)及びアミノ変性シリコーン(E2)からなり、前記(E1)成分と前記(E2)成分との質量比E1/E2が、2~30である。
本発明のシャンプー組成物は、硫酸残基を有するアニオン性界面活性剤(以下、「(A)成分」と称することがある)と、没食子酸配糖体(以下、「(B)成分」と称することがある)と、光沢付与剤(以下、「(C)成分」と称することがある)と、カチオン性ポリマー(以下、「(D)成分」と称することがある)と、シリコーン化合物(以下、「(E)成分」と称することがある)とを含有し、更に必要に応じて、その他の成分を含有する。
前記(A)成分であるアニオン性界面活性剤は、適度な泡を形成し、かつ毛髪に付着した汚れを除去する洗浄基剤となる成分である。
R1O(CH2CH2O)mSO3M1 ・・・ 一般式(A1)
〔ただし、前記一般式(A1)において、R1は、炭素数10~18のアルキル基又はアルケニル基を示し、M1は、アルカリ金属、アンモニウム、及びアルカノールアミンのいずれかを示し、mは、平均付加モル数で1~5の数を示す。〕
R2OSO3M2 ・・・ 一般式(A2)
〔ただし、前記一般式(A2)において、R2は、炭素数10~18のアルキル基を示し、M2は、アルカリ金属、アンモニウム、及びアルカノールアミンのいずれかを示す。〕
前記市販品の具体例としては、商品名で、Texapon ALES 70(POE(3)ラウリルエーテル硫酸アンモニウム、BASF社製)、シノリンSPE-1250(POE(2)ラウリルエーテル硫酸ナトリウム、新日本理化株式会社製)等の(A1)成分;Texapon ALS 70(ラウリル硫酸アンモニウム、BASF社製)、Texapon K12(ラウリル硫酸ナトリウム、BASF社製)等の(A2)成分、などが挙げられる。
これらの中でも、すすぎ時の毛髪のなめらかさの点から、前記(A1)成分として、Texapon ALES 70(POE(3)ラウリルエーテル硫酸アンモニウム、前記(A2)成分として、Texapon ALS 70(ラウリル硫酸アンモニウム、BASF社製)が好ましい。
前記(B)成分である没食子酸配糖体は、乾燥後の毛髪のやわらかさが得られ、低湿度下(温度25℃で湿度40%RH)においても毛髪が広がらずに、スタイリングしやすく、かつ毛髪同士がくっつきにくく、毛髪がべたつかなくなり、毛髪が軽く仕上がるという機能を付与することができる成分である。
前記没食子酸配糖体としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、没食子酸メチルエステル-3-グルコシド、没食子酸メチルエステル-4-グルコシド、没食子酸プロピルエステル-3-グルコシド、没食子酸メチルエステル-3-マルトシド、没食子酸-3-グルコシド、没食子酸-3-マルトシド、没食子酸オクチル-3-マルトシド、没食子酸-3-グルクロニド、没食子酸ガラクツロニド、没食子酸メチルエステル-3,5-ジグルコシド、没食子酸-3,4-ジグルコシド、没食子酸-3,5-ジグルコシドなどが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。これらの中でも、乾燥後の毛髪のやわらかさの点から、没食子酸-3,4-ジグルコシド、没食子酸-3,5-ジグルコシドが特に好ましい。
前記(C)成分としての光沢付与剤(「光沢剤」、「パール化剤」、「パール付与剤」などと称することもある。)は、前記シャンプー組成物にパール様の光沢を付与することができる。これにより、商品価値を高めることができる点で有利である。
また、前記(C)成分は、パール様の光沢をシャンプー組成物に付与するだけでなく、高温高湿度下(温度27℃で湿度70%RH)において毛髪が広がらず、毛髪同士がくっつきにくいため、毛髪のスタイリングがしやすく、毛髪がべたつかず軽く仕上がる。
前記結晶物の分散液を調製する方法としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、前記(C)成分を融解し、該(C)成分の融点以上に保持した界面活性剤水溶液中に該(C)成分を分散混合したものを、冷却する方法などが挙げられる。
前記(D)成分であるカチオン性ポリマーは、カチオン化グアーガム(以下、「(D1)成分」と称することがある)及びカチオン化セルロース(以下、「(D2)成分」と称することがある)からなる。
前記(D1)成分としてのカチオン化グアーガムは、グアーヒドロキシプロピルトリモニウムクロリド、塩化O-[2-ヒドロキシ-3-(トリメチルアンモニオ)プロピル]グアーガムなどとも呼ばれる。
前記窒素含量は、ケルダール法により、前記(D1)成分を硫酸で分解して硫酸アンモニウムとし、そのアンモニアを定量することにより測定できる。詳細には、「医薬部外品原料規格2006(薬事日報社)」一般試験法 44.窒素定量法を参考に記載された方法により測定できる。
前記(D2)成分としてのカチオン化セルロースは、ポリクオタニウム-10、塩化O-[2-ヒドロキシ-3-(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロースなどとも呼ばれるトリメチルアンモニウム置換エポキシドと反応させたヒドロキシエチルセルロースの塩である。
前記窒素含量は、ケルダール法により、前記(D2)成分を硫酸で分解して硫酸アンモニウムとし、そのアンモニアを定量することにより測定できる。詳細には、「医薬部外品原料規格2006(薬事日報社)」一般試験法 44.窒素定量法を参考に記載された方法により測定できる。
前記(E)成分であるシリコーン化合物は、ジメチルポリシロキサン(以下、「(E1)成分」と称することがある)及びアミノ変性シリコーン(以下、「(E2)成分」と称することがある)からなる。
前記(E1)成分は、ジメチルポリシロキサンであれば、特に制限はなく、目的に応じて適宜選択することができ、例えば、トリメチルシリル基末端ジメチルポリシロキサン、シラノール基末端ジメチルポリシロキサン、などが挙げられる。これらの中でも、乾燥後の毛髪の軽さ、乾燥後の毛髪のなめらかさ、及び毛先にさらさら感を付与することができる点で、トリメチルシリル基末端ジメチルポリシロキサンが好ましい。
1g/100mL濃度のジメチルポリシロキサンのトルエン溶液を調製し、下記式(1)により、比粘度ηsp(25℃)を求める。次に、下記式(2)に示すHugginsの関係式に代入し、固有粘度〔η〕を求める。Huggins定数は、中牟田,日化,77,588,1956に記載のものを用いる。次に、〔η〕を下記式(3)に示すA.Kolorlovの式に代入し、分子量を求める。最後に、Mを下記式(4)に示すA.J.Barryの式に代入し、ジメチルポリシロキサンの動粘度ηを求めることができる。
ηsp=(η/η0)-1・・・式(1)
ηsp=〔η〕+K’〔η〕2・・・式(2)
〔η〕=0.215×10-4M0.65・・・式(3)
logη=1.00+0.0123M0.5・・・式(4)
前記式(1)中、「η0」は、トルエンの粘度を示し、「η」は、溶液の粘度を示す。
前記η0及び前記ηは、化粧品原料基準一般試験法粘度測定法第1法に準拠して測定したものである。
前記数平均粒径は、光学顕微鏡で観察した粒子の像を任意に100ヶ所コンピューターに取り込み、同倍率とした上で、画像処理(例えば、二次元画像解析ソフトウェアWinROOFなど)することにより求められる。
前記(E2)成分としてのアミノ変性シリコーンとしては、特に制限はなく、目的に応じて適宜選択することができ、例えば、アミノエチルアミノプロピルシロキサン・ジメチルシロキサン共重合体(以下、「アモジメチコン」と称することがある)、アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体(以下、「アミノエチルアミノプロピルメチコン・ジメチコン共重合体」と称することがある)、アミノ変性オルガノポリシロキサン鎖とポリオキシアルキレン鎖とのブロック鎖を有する共重合体(以下、「直鎖アミノポリエーテル変性シリコーン」と称することがある)、アミノプロピルジメチコンなどが挙げられる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。これらの中でも、すすぎ時の毛髪のなめらかさを付与することができる点から、アモジメチコン、直鎖アミノポリエーテル変性シリコーンが好ましい。
前記(E2)成分の市販品の具体例としては、商品名で、SM8904CE、BY22-079、FZ-4671(アモジメチコンエマルション、東レ・ダウコーニング株式会社製)、DC2-8194(ダウコーニング社製)、KF-8004、KF-867S、KF-880(以上、信越化学工業株式会社製)等のアモジメチコン;KF-8005(信越化学工業株式会社製)等のアミノエチルアミノプロピルメチコン・ジメチコン共重合体;SILSTYLE 104(ビスイソブチルPEG-14/アモジメチコン)コポリマー、SILSTYLE 201(ビスイソブチルPEG-14/アモジメチコン)コポリマー、SILSTYLE 401(ビスブチロキシアモジメチコン/PEG-60)コポリマー(以上、東レ・ダウコーニング株式会社製)等の直鎖アミノポリエーテル変性シリコーン;KF-8015、KF-865、KF-8017、KF-8018、KF-8020(信越化学工業株式会社製)等のアミノプロピルジメチコン、などが挙げられる。これらの中でも、SILSTYLE 401が好ましい。
前記(B)成分及び前記(C)成分と、前記(A)成分及び前記(D)成分との質量比(B+C)/(A+D)は、高温高湿度下(温度27℃で湿度70%RH)で毛髪が広がるのを防ぎ、毛髪のスタイリングのしやすさ、及び毛髪の軽さの点から、0.05~0.6であり、0.06~0.5が好ましく、0.08~0.4がより好ましい。前記質量比(B+C)/(A+D)が、0.05未満であると、高温高湿度下(温度27℃で湿度70%RH)で毛髪同士がくっつきやすくなり、毛髪のスタイリングのしやすさが低下し、毛髪がべたつき、毛髪の軽さが低下することがあり、0.6を超えると、高温高湿度下(温度27℃で湿度70%RH)で毛髪同士がくっつきやすくなり、毛髪のスタイリングのしやすさが低下し、毛髪がべたつき、毛髪の軽さが低下し、乾燥後の毛髪のなめらかさが悪くなる場合がある。
前記質量比(B+C)/(A+D)が、前記数値範囲であると、高温高湿度下(温度27℃で湿度70%RH)とエアコンの効いた低湿度下のどちらにおいても毛髪が広がらずに毛髪のスタイリングがしやすく、毛髪同士がくっつきにくく、毛髪がべたつかず、毛髪の軽さの点で有利である。
前記その他の成分としては、本発明の効果を損なわない限り、特に制限はなく、目的に応じて適宜選択することができ、例えば、油分、アルコール類、保湿剤、増粘剤、防腐剤、酸化防止剤、キレート剤、pH調整剤、紫外線吸収・散乱剤、ビタミン類、アミノ酸類、香料、色素、水等を適宜必要に応じて配合することができる。これらは、1種単独で使用してもよく、2種以上を併用してもよい。
前記シャンプー組成物のpHとしては、特に制限はなく、目的に応じて適宜選択することができるが、25℃で、5.0~6.0が好ましい。
前記pHは、例えば、前記シャンプー組成物をpHメーター(HM-30G、東亜ディーケーケー株式会社製)を用いて25℃で測定することができる。
前記シャンプー組成物のpHは、所望のpH調整剤を用いて調整することができる。前記pH調整剤としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、クエン酸、コハク酸、硫酸、2-アミノ-2-メチル-1-プロパノール、モノエタノールアミン、又はこれらの塩、などが挙げられる。
前記シャンプー組成物の粘度としては、特に制限はなく、目的に応じて適宜選択することができるが、25℃で、1Pa・s~30Pa・sが好ましい。
前記粘度は、例えば、粘度計(BM型粘度計、TOKIMEC社製)を用い、No.4ローターにて、30rpm、20秒間後、25℃の条件で測定することができる。
前記シャンプー組成物の容器としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、アルミニウムラミネートチューブ、EVALチューブ、アルミチューブ、ガラス蒸着プラスチックチューブ等のチューブの他、機械的又は差圧によるディスペンサー容器及びスクイーズ容器、ラミネートフィルム容器、スポイト容器、スティック容器、ボトル容器等に充填することができる。
前記ラミネートフィルムは、通常2層以上の多層を有し、その材質はポリエチレン樹脂、ポリエチレンテレフタレート樹脂、ポリエステル樹脂、二軸延伸ポリプロピレン樹脂、無延伸ポリプロピレン樹脂、ポリアクリロニトリル樹脂、エチレン-酢酸ビニル共重合樹脂等の合成樹脂、紙、アルミニウム蒸着プラスチック等によって構成される。これらの中でも、強度、柔軟性、耐候性等を考慮して、一般的には2層~5層のものを用いることが好ましい。
前記ボトルの材質としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、ポリエチレン樹脂、ポリプロピレン樹脂、ポリエチレンテレフタレート樹脂、ポリスチレン樹脂、ポリ塩化ビニル樹脂、エチレン-ビニルアルコール共重合樹脂、アクリロニトリル-スチレン共重合樹脂、ABS樹脂、ポリアミド等の樹脂、あるいはガラス等を単層ないし2層以上組み合わせて用いることができる。
前記シャンプー組成物は、高温高湿度(温度27℃で湿度70%RH)下とエアコンの効いた低湿度下との環境変化が激しい地域においても毛髪が広がらずに、スタイリングしやすく、毛髪同士がくっつかないで、軽く仕上がり、なめらかさとやわらかさを併せ持ち、使用性に優れているため、例えば、地肌クレンジング用シャンプー、ダメージケア用シャンプー、マイルドシャンプー、リンスインシャンプーなどに好適に用いることができる。また、ヒトの毛髪の他、ペット等の動物の毛にも使用することができる。
下記表1~表12に示す実施例及び比較例に記載の(A)成分、(B)成分、(C)成分、(D)成分、(E)成分、及び任意成分を添加し、25℃で30分間攪拌した。(C)成分の光沢付与剤(エチレングリコールジステアレート)については、予め下記の調製方法により4.5質量%光沢付与剤分散液を調製し、シャンプー組成物中の光沢付与剤が所定量になるよう添加した。例えば、(C)成分の光沢付与剤1.5質量%配合の場合は、4.5質量%光沢付与剤分散液を33.3質量%添加した。光沢付与剤分散液中には、(A)成分であるポリオキシエチレンラウリル硫酸塩とラウリル硫酸塩を含有するが、実施例に記載の配合量は、光沢付与剤分散液中からの添加量との合算量として記載した。光沢付与剤分散液添加後、十分攪拌した後、クエン酸でpHを5.8に調整し、シャンプー組成物を得た。
-エチレングリコールジステアレート結晶物分散液の調製-
(C)成分の光沢付与剤としてのエチレングリコールジステアレート結晶物分散液は、以下の方法で調製した。
ポリオキシエチレン(3)ラウリルエーテル硫酸アンモニウム(Texapon ALES 70、BASF社製)が終濃度10質量%、ラウリル硫酸アンモニウム(Texapon ALS 70、BASF社製)が終濃度5質量%となるように溶解した水溶液を80℃に保ち、2Lビーカー中で攪拌した。前記水溶液を攪拌しながら、該水溶液に、80℃で融解したエチレングリコールジステアレート(Tegin EGS、Evonik社製)を終濃度4.5質量%となるように徐々に添加し、80℃にて、スリーワンモータ(FBL1200、HEIDEN社製)、4枚傾斜パドルを用いて100rpmで30分間均一混合後、ホモミキサー(プライミクス株式会社製)を使用して、4,500rpmで10分間分散混合させた。
次いで、得られた分散混合物をウォーターバス中に浸漬させて4枚傾斜パドルを用いて100rpmで攪拌しながら、分散混合槽内を35℃まで冷却(冷却速度1℃/分間)することにより、4.5質量%エチレングリコールジステアレート結晶物分散液を調製した。
なお、実施例21は、ポリオキシエチレン(2)ラウリルエーテル硫酸ナトリウム/ラウリル硫酸ナトリウムを使用して、上記と同様な操作で4.5質量%エチレングリコールジステアレート結晶物分散液を調製した。
前記4.5質量%エチレングリコールジステアレート結晶物分散液のメディアン粒径を、レーザー回析式粒度分布測定器(LA-920、株式会社堀場製作所製)を用い、水に対する相対屈折率を1.08として測定した。メディアン粒径は、2.0μmであった。また、結晶物の分散形状は、針状であった。
十分濡らした毛髪に、各シャンプー組成物6mLを塗布し、十分に泡立てて洗髪後、水道水温度40℃、流量250mL/3秒間のシャワーで洗い流し、軽くタオルドライした後に、温度27℃、湿度70%RHの部屋で12時間安静にし、温度25℃、湿度40%RHの部屋で12時間安静にする工程を7回繰り返した(下記サイクルを7回繰り返した。)
また、その後、温度25℃で湿度40%RHの部屋で12時間安静にし、「25℃、40%RHでの乾燥後の毛髪の軽さ」、及び「25℃、40%RHでの乾燥後の毛髪のスタイリングのしやすさ」を評価した。
「27℃、70%RHでの乾燥後の毛髪の軽さ」を以下の判断基準により評価した。良好と回答した人数により下記判断基準で示した。ここで「毛髪の軽さ」とは、毛髪が軽く、髪の毛一本一本がばらけて、さらさらすることを示す。
〔判断基準〕
◎:16名以上が良好と回答した
◎~○:13名以上15名以下が良好と回答した
○:11名以上12名以下が良好と回答した
△:6名以上10名以下が良好と回答した
×:5名以下が良好と回答した
「25℃、40%RHでの乾燥後の毛髪の軽さ」を以下の判断基準により評価した。良好と回答した人数により下記判断基準で示した。ここで「毛髪の軽さ」とは、毛髪が軽く、髪の毛一本一本がばらけて、さらさらすることを示す。
〔判断基準〕
◎:16名以上が良好と回答した
◎~○:13名以上15名以下が良好と回答した
○:11名以上12名以下が良好と回答した
△:6名以上10名以下が良好と回答した
×:5名以下が良好と回答した
「27℃、70%RHでの乾燥後の毛髪のスタイリングのしやすさ」を以下の判断基準により評価した。良好と回答した人数により下記判断基準で示した。ここで「毛髪のスタイリングのしやすさ」とは、毛髪の櫛通りが良く、まとまりやすいことを示す。
〔判断基準〕
◎:16名以上が良好と回答した
◎~○:13名以上15名以下が良好と回答した
○:11名以上12名以下が良好と回答した
△:6名以上10名以下が良好と回答した
×:5名以下が良好と回答した
「25℃、40%RHでの乾燥後の毛髪のスタイリングのしやすさ」を以下の判断基準により評価した。良好と回答した人数により下記判断基準で示した。ここで「毛髪のスタイリングのしやすさ」とは、毛髪の櫛通りが良く、まとまりやすいことを示す。
〔判断基準〕
◎:16名以上が良好と回答した
◎~○:13名以上15名以下が良好と回答した
○:11名以上12名以下が良好と回答した
△:6名以上10名以下が良好と回答した
×:5名以下が良好と回答した
「すすぎ時の毛髪のなめらかさ」を以下の判断基準により評価した。良好と回答した人数により下記判断基準で示した。ここで「すすぎ時の毛髪のなめらかさ」とは、シャンプーを洗い流している間、毛髪を触った時、抵抗なく指が滑ることを示す。
〔判断基準〕
◎:16名以上が良好と回答した
◎~○:13名以上15名以下が良好と回答した
○:11名以上12名以下が良好と回答した
△:6名以上10名以下が良好と回答した
×:5名以下が良好と回答した
「乾燥後の毛髪のなめらかさ」を以下の判断基準により評価した。良好と回答した人数により下記判断基準で示した。ここで「乾燥後の毛髪のなめらかさ」とは、乾燥後に毛髪を触ったとき、抵抗なく指が滑ることを示す。
〔判断基準〕
◎:16名以上が良好と回答した
◎~○:13名以上15名以下が良好と回答した
○:11名以上12名以下が良好と回答した
△:6名以上10名以下が良好と回答した
×:5名以下が良好と回答した
「乾燥後の毛髪のやわらかさ」を以下の判断基準により評価した。良好と回答した人数により下記評価基準で示した。ここで「乾燥後の毛髪のやわらかさ」とは、乾燥後に毛髪を触った時、しなやかであることを示す。
〔判断基準〕
◎:16名以上が良好と回答した
◎~○:13名以上15名以下が良好と回答した
○:11名以上12名以下が良好と回答した
△:6名以上10名以下が良好と回答した
×:5名以下が良好と回答した
シャンプー組成物の「使用性」を以下の判断基準により評価した。良好と回答した人数により下記評価基準で示した。ここで、「使用性」とは、ボトルからのシャンプー組成物の出しやすさを示す。
〔判断基準〕
◎:16名以上が良好と回答した
◎~○:13名以上15名以下が良好と回答した
○:11名以上12名以下が良好と回答した
△:6名以上10名以下が良好と回答した
×:5名以下が良好と回答した
レオフローDMS-60(一方社油脂工業株式会社製)〔動粘度10,000,000mm2/sの高重合メチルポリシロキサン:動粘度4,000,000mm2/sの高重合メチルポリシロキサン:動粘度1,000mm2/sのメチルポリシロキサン=15:15:70(質量比)〕に、POE(15)セチルエーテル(商品名:NPO-97、ライオンケミカル株式会社製)を乳化剤として添加し、水に乳化分散した。
<1> (A)硫酸残基を有するアニオン性界面活性剤と、
(B)没食子酸配糖体と、
(C)光沢付与剤と、
(D)カチオン性ポリマーと、
(E)シリコーン化合物を0.15質量%~5.0質量%と、
を含有し、
前記(B)成分及び前記(C)成分と、前記(A)成分及び前記(D)成分との質量比(B+C)/(A+D)が、0.05~0.6であり、
前記(A)成分が、ポリオキシエチレンアルキルエーテル硫酸塩(A1)とアルキル硫酸塩(A2)とを含有し、
前記(D)成分が、カチオン化グアーガム(D1)及びカチオン化セルロース(D2)からなり、前記(D1)成分と前記(D2)成分との質量比D1/D2が、2~20であり、
前記(E)成分が、ジメチルポリシロキサン(E1)及びアミノ変性シリコーン(E2)からなり、前記(E1)成分と前記(E2)成分との質量比E1/E2が、2~30であることを特徴とするシャンプー組成物である。
<2> (A)硫酸残基を有するアニオン性界面活性剤を10質量%~25質量%と、
(B)没食子酸配糖体を0.05質量%~3質量%と、
(C)光沢付与剤を1.2質量%~4.5質量%と、
(D)カチオン性ポリマーを0.2質量%~1.5質量%と、
を含有する前記<1>に記載のシャンプー組成物である。
<3> (D1)成分の窒素含量が1質量%~1.8質量%であり、(D2)成分の窒素含量が1.5質量%~2.2質量%である前記<1>から<2>のいずれかに記載のシャンプー組成物である。
<4> (A1)成分と(A2)成分との質量比A1/A2が、1~7である前記<1>から<3>のいずれかに記載のシャンプー組成物である。
Claims (4)
- (A)硫酸残基を有するアニオン性界面活性剤と、
(B)没食子酸配糖体と、
(C)光沢付与剤と、
(D)カチオン性ポリマーと、
(E)シリコーン化合物を0.15質量%~5.0質量%と、
を含有し、
前記(B)成分及び前記(C)成分と、前記(A)成分及び前記(D)成分との質量比(B+C)/(A+D)が、0.05~0.6であり、
前記(A)成分が、ポリオキシエチレンアルキルエーテル硫酸塩(A1)とアルキル硫酸塩(A2)とを含有し、
前記(D)成分が、カチオン化グアーガム(D1)及びカチオン化セルロース(D2)からなり、前記(D1)成分と前記(D2)成分との質量比D1/D2が、2~20であり、
前記(E)成分が、ジメチルポリシロキサン(E1)及びアミノ変性シリコーン(E2)からなり、前記(E1)成分と前記(E2)成分との質量比E1/E2が、2~30であることを特徴とするシャンプー組成物。 - (A)硫酸残基を有するアニオン性界面活性剤を10質量%~25質量%と、
(B)没食子酸配糖体を0.05質量%~3質量%と、
(C)光沢付与剤を1.2質量%~4.5質量%と、
(D)カチオン性ポリマーを0.2質量%~1.5質量%と、
を含有する請求項1に記載のシャンプー組成物。 - (D1)成分の窒素含量が1質量%~1.8質量%であり、(D2)成分の窒素含量が1.5質量%~2.2質量%である請求項1から2のいずれかに記載のシャンプー組成物。
- (A1)成分と(A2)成分との質量比A1/A2が、1~7である請求項1から3のいずれかに記載のシャンプー組成物。
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KR1020157023154A KR102164147B1 (ko) | 2013-03-21 | 2014-03-04 | 샴푸 조성물 |
PH12015502173A PH12015502173A1 (en) | 2013-03-21 | 2015-09-16 | Shampoo composition |
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JP (1) | JP6174118B2 (ja) |
KR (1) | KR102164147B1 (ja) |
CN (1) | CN105050578B (ja) |
MY (1) | MY170252A (ja) |
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US11607373B2 (en) | 2017-10-10 | 2023-03-21 | The Procter & Gamble Company | Sulfate free clear personal cleansing composition comprising low inorganic salt |
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US10912732B2 (en) | 2017-12-20 | 2021-02-09 | The Procter And Gamble Company | Clear shampoo composition containing silicone polymers |
US11318073B2 (en) | 2018-06-29 | 2022-05-03 | The Procter And Gamble Company | Low surfactant aerosol antidandruff composition |
US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
US11819474B2 (en) | 2020-12-04 | 2023-11-21 | The Procter & Gamble Company | Hair care compositions comprising malodor reduction materials |
US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
Also Published As
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MY170252A (en) | 2019-07-13 |
CN105050578A (zh) | 2015-11-11 |
CN105050578B (zh) | 2018-06-26 |
JP6174118B2 (ja) | 2017-08-02 |
KR102164147B1 (ko) | 2020-10-12 |
PH12015502173A1 (en) | 2016-01-25 |
JPWO2014148245A1 (ja) | 2017-02-16 |
KR20150132116A (ko) | 2015-11-25 |
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