WO2014129323A1 - インクジェット捺染用インク及び染色方法 - Google Patents
インクジェット捺染用インク及び染色方法 Download PDFInfo
- Publication number
- WO2014129323A1 WO2014129323A1 PCT/JP2014/052923 JP2014052923W WO2014129323A1 WO 2014129323 A1 WO2014129323 A1 WO 2014129323A1 JP 2014052923 W JP2014052923 W JP 2014052923W WO 2014129323 A1 WO2014129323 A1 WO 2014129323A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ink
- water
- parts
- mass
- soluble organic
- Prior art date
Links
- 238000007641 inkjet printing Methods 0.000 title claims abstract description 33
- 238000007447 staining method Methods 0.000 title 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000000986 disperse dye Substances 0.000 claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000002270 dispersing agent Substances 0.000 claims abstract description 29
- 239000004744 fabric Substances 0.000 claims abstract description 28
- 235000011187 glycerol Nutrition 0.000 claims abstract description 26
- 238000007639 printing Methods 0.000 claims abstract description 25
- -1 acetylene glycol Chemical compound 0.000 claims abstract description 23
- 239000002253 acid Substances 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000003960 organic solvent Substances 0.000 claims abstract description 21
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920006318 anionic polymer Polymers 0.000 claims abstract description 18
- 239000000126 substance Substances 0.000 claims abstract description 18
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 13
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 21
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 17
- 239000004753 textile Substances 0.000 claims description 12
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 239000002657 fibrous material Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 230000002209 hydrophobic effect Effects 0.000 claims description 5
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 4
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 230000035515 penetration Effects 0.000 abstract description 2
- 229920003122 (meth)acrylate-based copolymer Polymers 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 101
- 239000000975 dye Substances 0.000 description 51
- 239000006185 dispersion Substances 0.000 description 42
- 239000002245 particle Substances 0.000 description 22
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 14
- 239000000203 mixture Substances 0.000 description 12
- 239000002585 base Substances 0.000 description 11
- 238000004043 dyeing Methods 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 239000010419 fine particle Substances 0.000 description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 239000004576 sand Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- ALXCWDABTQQKAH-UHFFFAOYSA-N 4-(1-amino-4-hydroxy-9,10-dioxoanthracen-2-yl)oxy-n-(3-ethoxypropyl)benzenesulfonamide Chemical compound C1=CC(S(=O)(=O)NCCCOCC)=CC=C1OC1=CC(O)=C(C(=O)C=2C(=CC=CC=2)C2=O)C2=C1N ALXCWDABTQQKAH-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000011324 bead Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052845 zircon Inorganic materials 0.000 description 5
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- JOUDBUYBGJYFFP-NXVVXOECSA-N (2z)-2-(3-oxo-1-benzothiophen-2-ylidene)-1-benzothiophen-3-one Chemical compound S/1C2=CC=CC=C2C(=O)C\1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-NXVVXOECSA-N 0.000 description 2
- 229940015975 1,2-hexanediol Drugs 0.000 description 2
- IHJUECRFYCQBMW-UHFFFAOYSA-N 2,5-dimethylhex-3-yne-2,5-diol Chemical compound CC(C)(O)C#CC(C)(C)O IHJUECRFYCQBMW-UHFFFAOYSA-N 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 230000002457 bidirectional effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229930003836 cresol Natural products 0.000 description 2
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 2
- 229940105990 diglycerin Drugs 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 2
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002952 polymeric resin Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- QOSTVEDABRQTSU-UHFFFAOYSA-N 1,4-bis(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC)=CC=C2NC QOSTVEDABRQTSU-UHFFFAOYSA-N 0.000 description 1
- WSPPHHAIMCTKNN-UHFFFAOYSA-N 1-amino-4-hydroxy-2-methoxyanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(O)=C3C(=O)C2=C1 WSPPHHAIMCTKNN-UHFFFAOYSA-N 0.000 description 1
- URGSMJLDEFDWNX-UHFFFAOYSA-N 1-butylnaphthalene Chemical compound C1=CC=C2C(CCCC)=CC=CC2=C1 URGSMJLDEFDWNX-UHFFFAOYSA-N 0.000 description 1
- WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
- LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical compound CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 description 1
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 1
- JQXYBDVZAUEPDL-UHFFFAOYSA-N 2-methylidene-5-phenylpent-4-enoic acid Chemical compound OC(=O)C(=C)CC=CC1=CC=CC=C1 JQXYBDVZAUEPDL-UHFFFAOYSA-N 0.000 description 1
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- NUYADIDKTLPDGG-UHFFFAOYSA-N 3,6-dimethyloct-4-yne-3,6-diol Chemical compound CCC(C)(O)C#CC(C)(O)CC NUYADIDKTLPDGG-UHFFFAOYSA-N 0.000 description 1
- ZSPPPAFDNHYXNW-UHFFFAOYSA-N 3-[n-ethyl-4-[(4-nitrophenyl)diazenyl]anilino]propanenitrile Chemical compound C1=CC(N(CCC#N)CC)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1 ZSPPPAFDNHYXNW-UHFFFAOYSA-N 0.000 description 1
- BBFRYSKTTHYWQZ-UHFFFAOYSA-N 4-anilino-3-nitro-n-phenylbenzenesulfonamide Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)NC=2C=CC=CC=2)=CC=C1NC1=CC=CC=C1 BBFRYSKTTHYWQZ-UHFFFAOYSA-N 0.000 description 1
- QPQKUYVSJWQSDY-UHFFFAOYSA-N 4-phenyldiazenylaniline Chemical compound C1=CC(N)=CC=C1N=NC1=CC=CC=C1 QPQKUYVSJWQSDY-UHFFFAOYSA-N 0.000 description 1
- MKALOVJHPRAZRE-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=CC=CC1=CC=CC=C1 MKALOVJHPRAZRE-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- GBEULHWUGMFZDA-UHFFFAOYSA-N CC(CC)(C#CC(CC)(O)C)O.CC(C)CC(C#CC(CC(C)C)(O)C)(O)C Chemical compound CC(CC)(C#CC(CC)(O)C)O.CC(C)CC(C#CC(CC(C)C)(O)C)(O)C GBEULHWUGMFZDA-UHFFFAOYSA-N 0.000 description 1
- 235000006173 Larrea tridentata Nutrition 0.000 description 1
- 244000073231 Larrea tridentata Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- XREZMAAQVYVESP-UHFFFAOYSA-N acetyloxymethyl 2-[n-[2-(acetyloxymethoxy)-2-oxoethyl]-2-[2-[2-[bis[2-(acetyloxymethoxy)-2-oxoethyl]amino]-4-fluorophenoxy]ethoxy]-5-fluoroanilino]acetate Chemical compound CC(=O)OCOC(=O)CN(CC(=O)OCOC(C)=O)C1=CC(F)=CC=C1OCCOC1=CC=C(F)C=C1N(CC(=O)OCOC(C)=O)CC(=O)OCOC(C)=O XREZMAAQVYVESP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N aconitic acid Chemical compound OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 229960002126 creosote Drugs 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- LEGWLJGBFZBZSC-UHFFFAOYSA-N n-[2-[(2,6-dicyano-4-nitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide Chemical compound CC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=C(C#N)C=C([N+]([O-])=O)C=C1C#N LEGWLJGBFZBZSC-UHFFFAOYSA-N 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- XIQGQTYUPQAUBV-UHFFFAOYSA-N prop-2-enoic acid;prop-1-en-2-ylbenzene;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1.CC(=C)C1=CC=CC=C1 XIQGQTYUPQAUBV-UHFFFAOYSA-N 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- ZPWQALCOMQRMRK-UHFFFAOYSA-M sodium;6-hydroxynaphthalene-2-sulfonate Chemical compound [Na+].C1=C(S([O-])(=O)=O)C=CC2=CC(O)=CC=C21 ZPWQALCOMQRMRK-UHFFFAOYSA-M 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/324—Inkjet printing inks characterised by colouring agents containing carbon black
- C09D11/326—Inkjet printing inks characterised by colouring agents containing carbon black characterised by the pigment dispersant
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/36—Material containing ester groups using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2066—Thermic treatments of textile materials
- D06P5/2077—Thermic treatments of textile materials after dyeing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
Definitions
- the present invention relates to an ink for ink jet textile printing and an ink jet textile printing method using the same in an ink jet recording system.
- the water-based ink for inkjet recording is in the form of a solution in which a water-soluble dye is dissolved in water or an aqueous solution containing a water-soluble organic solvent, or a dispersion in which a water-insoluble colorant is dispersed in water or an aqueous solution containing a water-soluble organic solvent. It is common to take Ink-jet printing inks using disperse dyes are also used in methods such as performing inkjet printing on fabrics made of hydrophobic fiber materials and then dyeing them by heating.
- the on-demand system has a problem in that ejection failure occurs during continuous operation for a long time because ink ejection from the nozzles is temporarily stopped even during continuous operation.
- inks for inkjet printing in the form of dispersions using disperse dyes unlike the case of using water-soluble dyes, formation of precipitates (aggregates) due to dispersion deterioration, thickening due to evaporation of moisture at the nozzle, etc. Cause clogging.
- humectants include high-boiling water-soluble organic solvents and solid water-soluble compounds.
- high-boiling water-soluble organic solvents include polyhydric alcohol compounds such as glycerin and polyethylene glycol, pyrrolidone compounds such as 2-pyrrolidone and N-methyl-2-pyrrolidone, and solid water-soluble compounds include saccharides and urea compounds. Etc. are used.
- Patent Document 1 describes an ink for ink-jet recording comprising a water-insoluble colorant, a dispersant, and a polyoxyethylene alkyl ether compound having an alkyl group having 25 to 150 carbon atoms. .
- the inkjet recording ink of Patent Document 1 uses a dispersant and a polyoxyethylene alkyl ether compound having 25 to 150 carbon atoms in the alkyl group for the purpose of improving redispersibility, so that the surface tension is increased.
- ink jet printing is performed on a cloth made of a hydrophobic fiber material, excessive penetrability may be exhibited with respect to the cloth, and the concentration of the cloth surface tends to be low.
- the average dispersed particle size of the water-insoluble dye is 0.1 to 0.3 ⁇ m, and the acid value in the form of free acid of the styrene-acrylic acid copolymer is 150 mgKOH / g or more and 250 mgKOH / g.
- a water-based ink composition is described in which the ratio of the styrene-acrylic acid copolymer to the water-insoluble dye is 5% by mass or more and less than 20% by mass.
- Patent Document 2 describes that an extremely high recording density can be achieved by setting the average dispersed particle size of the water-insoluble dye within a relatively large specific range of 0.1 to 0.3 ⁇ m. However, since the ratio of the styrene-acrylic acid copolymer to the water-insoluble dye is 5% by mass or more and less than 20% by mass, the dispersion stability of the water-insoluble dye (ink storage stability) is not sufficient.
- Patent Document 3 describes an ink composition containing an acetylene glycol compound as a penetrant and a styrene- (meth) acrylic acid-based water-soluble resin as a water-soluble dispersant in an ink containing a specific pigment. It is described that an ink composition comprising a specific pigment together with a specific component realizes an image excellent in abrasion resistance and color reproducibility and has advantages as a super-penetrating ink composition.
- the weight-average molecular weight of the styrene- (meth) acrylic acid-based water-soluble resin described in each example of Patent Document 3 is only 7,000, the acid value is 70 to 150, and the acetylene glycol compound is Not specified. In the examples, only “Surfinol 465” is described as an acetylene glycol compound.
- Patent Document 4 in an inkjet ink containing a disperse dye, a polymer resin having a carboxyl group or a sulfonic acid group as an acidic group and having an acid value of 80 mgKOH / g or more and 300 mgKOH / g or less is 2% by mass in solid content. Above, 10% by mass or less, the polymer resin is used as a binder resin, not as a dispersant, and describes an inkjet ink that can create a high-quality and highly durable image simply by heating a fabric. Yes.
- the present invention solves the problems of inks for ink jet textile printing using the conventional disperse dyes as described above, has high-quality and stable recording performance, and maintains the storage stability of the ink while maintaining the ink surface.
- An ink for inkjet printing containing a disperse dye capable of increasing the printing density of the ink and an inkjet printing method using the same are provided.
- the ink for inkjet printing of the present invention is an ink for inkjet printing containing water, a disperse dye, a water-soluble organic solvent and an anionic polymer dispersant, and the water-soluble organic solvent is glycerin, diethylene glycol, triethylene glycol, At least one selected from polyethylene glycol (average molecular weight 200 to 600), dipropylene glycol and tripropylene glycol, and the content of the water-soluble organic solvent is 25 to 50% by mass relative to the total mass of the ink; Is a styrene- (meth) acrylic acid copolymer having an acid value of 160 to 250 mg KOH / g and a weight average molecular weight of 8,000 to 20,000. Further, as a penetrant, the following chemical formula (I) It contains an acetylene glycol compound represented by To.
- the ink-jet printing method of the present invention is characterized in that the ink-jet printing ink of the present invention is subjected to ink-jet printing on a fabric made of a hydrophobic fiber material and then heated.
- an ink for inkjet textile printing containing a disperse dye which has high quality and stable recording performance originally required, and can increase the printing density on the fabric surface while maintaining the storage stability of the ink.
- the dyeing method using the ink for ink jet textile printing of the present invention can also provide an ink jet textile printing method having a high dyeing density on the surface of the object to be dyed.
- the present inventors have used a dispersing agent and a penetrating agent for disperse dyes. As a result of investigating the agent, it was found that the object can be achieved by selecting a specific anionic polymer dispersant and a specific penetrant, and the present invention has been achieved.
- the anionic polymer dispersant used in the present invention is a styrene- (meth) acrylic acid copolymer having an acid value of 160 to 250 mgKOH / g and a weight average molecular weight of 8,000 to 20,000.
- One feature of the present invention is the use of the anionic polymer dispersant as a dispersant for the disperse dye.
- the anionic polymer dispersant is for dispersing a dispersed dye into fine particles and dispersing it in an aqueous medium, and also exhibits a function of maintaining the dispersion stability of the finely divided dispersed dye.
- styrene- (meth) acrylic acid copolymer examples include styrene-acrylic acid copolymer, styrene-methacrylic acid copolymer, styrene-acrylic acid-acrylic acid ester copolymer, and styrene-methacrylic acid- An acrylic ester copolymer, a styrene- ⁇ -methylstyrene-acrylic acid copolymer, a styrene- ⁇ -methylstyrene-methacrylic acid copolymer, and the like can be given.
- the styrene- (meth) acrylic acid copolymer used in the present invention has an acid value of 160 to 250, preferably in the range of 200 to 250. If the acid value is less than 160, the solubility of the resin in water tends to be poor, and the dispersion stabilization power to the disperse dye tends to be poor. If the acid value exceeds 250, the affinity with an aqueous medium becomes strong, This is not preferable because the image after printing tends to be blurred.
- the acid value of the resin represents the number of mg of KOH required to neutralize 1 g of the resin, and is measured according to JIS-K3054.
- the styrene- (meth) acrylic acid copolymer has a weight average molecular weight of 8,000 to 20,000, preferably 10,000 to 18,000. When the weight average molecular weight is less than 8,000, the dispersion stabilizing ability with respect to the disperse dye is lowered. When it is greater than 20,000, the ability to disperse the disperse dye is lowered, and the viscosity of the ink may be too high. There is not preferable.
- the weight average molecular weight of the styrene- (meth) acrylic acid copolymer is measured by GPC (gel permeation chromatography) method.
- the styrene- (meth) acrylic acid copolymer is commercially available in the form of a flake or an aqueous solution, and an aqueous solution is preferably used from the viewpoint of handling.
- the content of these anionic polymer dispersants is preferably 0.2 to 4% by mass with respect to the total mass of the ink for the purpose of maintaining good dispersion stability of the disperse dye.
- the content of these anionic polymer dispersants is preferably 20 to 40% by mass, more preferably 20 to 30% by mass with respect to the disperse dye for the purpose of maintaining good dispersion stability of the sublimable dye.
- Another feature of the present invention is that it contains an acetylene glycol compound represented by the chemical formula (I) as a penetrant.
- the chemical formula name of the compound of the above chemical formula (I) is 3,6-dimethyl-4-octyne-63,6-diol, and is commercially available as “Surfinol 82” from Nissin Chemical Industry Co., Ltd. Yes.
- acetylene glycol compounds include 2,5-dimethyl-3-hexyne-2,5-diol, 4, 7- dimethyl- 5-decin- 4, 7 -diol, 2,4,7,9 -Tetramethyl-5-decyne-4, 7-diol 3,6-dimethyl-4-octyne-3,6-diol, and the 2,5-dimethyl-3-hexyne-2,5-diol, , 7- dimethyl-5-decyne-4, 7 -diol, 2,4,7,9-tetramethyl-5-decyne- 4,7-diol and 3, 6-dimethyl-4- octyne-3, Mention may be made of the addition of ethyleneoxy groups and / or propyleneoxy groups to each of the 6-diols, including “Surfinol 82”, 104, 420, 440, 65, 485 (manufactured by
- an ink composition having a high printing density on the surface of the fabric made of the hydrophobic fiber material is obtained. be able to.
- the combination of the anionic polymer dispersant and the other acetylene glycol compound results in an ink composition having high penetrability, and thus the print density on the fabric surface cannot be increased.
- the compound of the formula (I) has a gradual penetration effect compared to the other acetylene glycol compounds, so that the permeability of the ink to the fabric is also slow, and the disperse dye stays near the surface, so the surface concentration of the fabric Will be higher.
- the storage stability of the ink is deteriorated, but in the case of the compound of the chemical formula (I), the storage stability of the ink is also good.
- the content of the compound of the formula (I) is preferably 0.1 to 2.0% by mass with respect to the total mass of the ink from the viewpoint of maintaining the solubility in the ink and the gentle permeability to the fabric. More preferably, it is 0.1 to 1.5% by mass, and still more preferably 0.2 to 1.0% by mass.
- Examples of the disperse dye used in the present invention include dyes such as azo, anthraquinone, quinophthalone, styryl, oxazine, xanthene, methine, and azomethine.
- examples of yellow disperse dyes include “C.I. Disperse Yellow 42”, 51, 54, 60, 64, 65, 71, 82, 98, 114, 119, 149, 160, 163, 201, 211 and the like.
- Examples of orange disperse dyes include "C.I. Disperse Orange 25", 29, 30, 31, 32, 33, 44, 61, 62, 73, 155, 288, and the like.
- Examples of red disperse dyes include “C.I.
- Disperse Red 4 22, 50, 55, 59, 60, 73, 86, 91, 92, 145, 146, 152, 153, 167, 167: 1, 177, 179, 191, 227, 258, 302, 343, and the like.
- blue disperse dyes include “C.I. Disperse Blue 14”, 27,56,60,72,73,77,79,79: 1,148,165,165: 1,183: 1,214,281,284,291,291: 1,301,334,359,360,366,367 and the like.
- examples of other disperse dyes include “C.I. Disperse Violet 26”, 27, 28, 57, 93, and the like.
- Other dyes other than the above include “C.I. Solvent Yellow 160”, 163, “C.I. Vat Red 41” and the like.
- the content of these disperse dyes is preferably 0.2 to 12% by mass with respect to the total mass of the ink because dispersion stability is maintained and a necessary printing density is obtained. More preferably, it is 0.5 to 10% by mass.
- the anionic polymer dispersant used in the present invention is a fine dispersion of a disperse dye that is dispersed in an aqueous medium, and also exhibits the function of maintaining the dispersion stability of the disperse dye formed into a fine particle. .
- an anionic surfactant a nonionic surfactant, and the like can be used during the preparation of the ink.
- the anionic surfactant is preferably contained in an amount of 0.1 to 3% by mass based on the total mass of the ink.
- Anionic surfactants include formalin condensates of naphthalene sulfonate, lignin sulfonates, and aromatic sulfonate formalin condensates (formalin condensation of sodium alkylnaphthalene sulfonate such as butyl naphthalene and sodium naphthalene sulfonate. , Formalin condensate of sodium cresol sulfonate and sodium 2-naphthol-6-sulfonate, formalin condensate of sodium cresol sulfonate, formalin condensate of sodium creosote oil sulfonate), polyoxyethylene alkyl ether sulfate, etc. Is mentioned. Among these, a formalin condensate of naphthalene sulfonate and a formalin condensate of aromatic sulfonate are preferable.
- water-soluble organic solvent examples include glycerin, diglycerin, polyglycerin, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, 1,3-propanediol, dipropylene glycol, and tripropylene.
- examples thereof include glycol, polypropylene glycol, 2-pyrrolidone, N-methylpyrrolidone, dimethyl sulfoxide, and sulfolane.
- glycerin diethylene glycol, triethylene glycol, polyethylene glycol (average molecular weight 200 to 600), dipropylene glycol, and tripropylene glycol are preferable from the viewpoint of moisture retention performance, and glycerin, diethylene glycol, and dipropylene glycol are further included. preferable. Among these, glycerin is particularly preferable. These may be used alone or in combination of two or more.
- the content of the water-soluble organic solvent is preferably 25 to 50% by mass with respect to the total mass of the ink from the viewpoint of adjusting the viscosity of the ink and preventing clogging due to the moisturizing effect. More preferably, it is 30 to 45% by mass, and particularly preferably 30 to 40% by mass.
- various other additives can be added as necessary within a range not impeding the achievement of the object of the present invention.
- surface tension adjusting agent hydrotrope agent, pH adjusting agent, viscosity adjusting agent, antiseptic agent, antifungal agent, rust inhibitor, antioxidant, reducing agent, light stabilizer, chelating agent, antifoaming agent, etc. It is.
- organic amines, alkali metal hydroxides, and the like can be used.
- antifoaming agent acetylene glycol compounds other than the compound of the chemical formula (I) (trade name “Surfinol 104E”, etc., manufactured by Nissin Chemical Industry Co., Ltd.) can be used. Since the concentration is low, 0.01 to 0.1% by mass is preferable.
- the method for preparing the ink for inkjet textile printing of the present invention is not particularly limited, but it is preferably prepared by the method described below.
- Disperse dye, styrene- (meth) acrylic acid copolymer, water and, if necessary, a water-soluble organic solvent and the above additives are mixed and stirred to prepare a preliminary dispersion
- the predispersed liquid is finely dispersed in a wet medium mill such as a sand mill and dispersed to obtain a dispersed dye dispersion.
- the styrene- (meth) acrylic acid copolymer may be further added at the time of adjusting the concentration in order to improve the dispersibility of the disperse dye.
- the average particle size of the disperse dye obtained by the above method is preferably 200 nm or less, more preferably 50 to 150 nm.
- the disperse dye, the water-soluble organic solvent, the styrene- (meth) acrylic acid copolymer, the compound represented by the chemical formula (I), and other components have been illustrated and described as specific examples. It is not limited to only those illustrated in the examples.
- the ink for ink-jet textile printing can be set in a piezo-type ink-jet printer and ejected onto a polyester cloth that has been subjected to pretreatment such as bleeding prevention to form a desired image. Further, this fabric is heat-treated at a temperature of, for example, 150 to 220 ° C. for 1 to 15 minutes to dye the disperse dye into polyester fibers. Thereafter, unfixed disperse dye, additives such as a dispersant, pretreatment agent and the like are removed by reduction washing and water washing, and dried to obtain a dyed product of the image.
- Example 2 to 4 Except for changing "Surfinol 82" to 0.2 parts, 1.5 parts and 1.8 parts, the dye concentration was adjusted to 8% in the same manner as in Example 1 to prepare inks of Examples 2 to 4. did.
- the average particle size of the dye was 100 nm.
- Example 5 In place of the red disperse dye base, 100 parts of yellow disperse dye base (CI Disperse Yellow 65) was used to obtain fine dispersion in the same manner as in Example 1. Ink was prepared by adding 35 parts of glycerin, 1 part of “Surfinol 82” and 44 parts of water to 20 parts of this dispersion to adjust the dye concentration to 4%. The average particle size of the dye was 90 nm.
- Example 6 instead of the red disperse dye base, 100 parts of a blue disperse dye base (CI Disperse Blue 60) was used to obtain a dispersion by finely dividing the same as in Example 1. Ink was prepared by adding 35 parts of glycerin, 1 part of “Surfinol 82” and 24 parts of water to 40 parts of this dispersion to adjust the dye concentration to 8%. The average particle size of the dye was 110 nm.
- Example 7 Instead of the red disperse dye base, 100 parts of a blue disperse dye base (CI Disperse Blue 165) was used to obtain fine particles in the same manner as in Example 1 to obtain a dispersion. Ink was prepared by adding 35 parts of glycerin, 1 part of “Surfinol 82” and 44 parts of water to 20 parts of this dispersion to adjust the dye concentration to 4%. The average particle size of the dye was 90 nm.
- CI Disperse Blue 165 CI Disperse Blue 165
- Example 8 An ink having a dye concentration adjusted to 8% was prepared in the same manner as in Example 1 except that 67 parts of “Johncrill 63” and 333 parts of water were used to make fine particles. The average particle size of the dye was 100 nm.
- Example 9 Ink was prepared by adjusting the dye concentration to 2% by adding 35 parts of glycerin, 1 part of “Surfinol 82” and 54 parts of water to 10 parts of the dispersion prepared by the same method as in Example 1.
- the average particle size of the dye was 100 nm.
- Example 10 Using a mixture of 100 parts of red disperse dye base (CI Disperse Red 92), 133 parts of "Joncrill 63", and 267 parts of water, 1500 parts of zircon beads having a diameter of 0.4 mm were used in a sand mill to obtain 35 parts. A dispersion was obtained by micronizing with time. An ink was prepared by adjusting the dye concentration to 10% by adding 35 parts of glycerin, 1 part of "Surfinol 82" and 14 parts of water to 50 parts of this dispersion. The average particle size of the dye was 100 nm.
- An ink was prepared by adding 35 parts of glycerin, 1 part of “Surfinol 82” and 24 parts of water to 40 parts of this dispersion to adjust the dye concentration to 8%.
- the average particle size of the dye was 100 nm.
- Example 13 40 parts of a dispersion prepared in the same manner as in Example 1, 35 parts of glycerin, 1 part of “Surfinol 82”, “Demol N” as an anionic surfactant (produced by Kao Corporation, ⁇ -naphthalenesulfonic acid) A formalin condensate (sodium salt) (1.5 parts) and water (22.5 parts) were added to prepare an ink having a dye concentration adjusted to 8%. The average particle size of the dye was 100 nm.
- Example 14 In 40 parts of the dispersion prepared in the same manner as in Example 1, 35 parts of glycerin, 1 part of “Surfinol 82”, “Demol SNB” as an anionic surfactant (manufactured by Kao Corporation, sodium aromatic sulfonate) The ink was prepared by adding 1.5 parts of the formalin condensate and 22.5 parts of water and adjusting the dye concentration to 8%. The average particle size of the dye was 100 nm.
- Example 15 Ink was prepared by adding 25 parts of glycerin, 1 part of “Surfinol 82” and 34 parts of water to 40 parts of the dispersion prepared by the same method as in Example 1, and adjusting the dye concentration to 8%.
- the average particle size of the dye was 100 nm.
- Example 16 Ink was prepared by adjusting the dye concentration to 8% by adding 40 parts of glycerin, 1 part of “Surfinol 82” and 9 parts of water to 40 parts of the dispersion prepared by the same method as in Example 1.
- the average particle size of the dye was 100 nm.
- An ink was prepared by adding 35 parts of glycerin, 1 part of “Surfinol 82” and 24 parts of water to 40 parts of this dispersion to adjust the dye concentration to 8%.
- the average particle size of the dye was 120 nm.
- Tables 1-3 The test results are shown in Tables 1-3.
- the numerical values of each substance in Tables 1 to 3 indicate parts by mass.
- the ink containing “John Krill 63” and “Surfinol 82” of Examples 1 to 22 of the present invention has stable recording performance, storage stability of the ink, and the surface of the dyed cloth. It had a high printing density.
- the inks of Comparative Examples 1 to 5 in which “Surfynol 82” is replaced with “Surfinol 104E”, “Surfinol 465”, “BYK-348”, diethylene glycol monobutyl ether, and 1,2-hexanediol have stable recording performance.
- the print density was low and the storage stability of the ink was poor.
- the ink of Comparative Example 6 in which “Johncrill 63” was replaced with “Johncrill 57” having a low molecular weight did not have sufficient ink storage stability.
- the ink of Comparative Example 7 in which “Joncrill 63” was replaced with “Demol N” had low print density as a result of permeation into the dyed cloth, and the storage stability of the ink was poor.
- the ink of Comparative Example 8 in which “Joncrill 63” was replaced with “Demol N” and “Unitox 480” was further added had a low print density as a result of permeation into the dyed fabric.
- the ink for inkjet printing using the disperse dye of the present invention as a color material component increases the printing density on the fabric surface while maintaining the originally required high quality and stable recording performance and ink storage stability.
- the present invention provides an inkjet printing ink containing a disperse dye and an inkjet printing method using the same. Therefore, it is suitable for an ink for inkjet printing using a disperse dye as a color material component and a dyeing method using the same.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Coloring (AREA)
Abstract
Description
(1)ノズルの目詰まり防止、吐出安定性
(2)インク吐出時の方向性、吐出量及びドットの形状が一定した高品位な記録画像
(3)インクの保存安定性
(4)高印字濃度、高品位な画質
(5)インクの乾燥性、定着性
などが挙げられる。
(1)分散染料、スチレン-(メタ)アクリル酸系共重合体、水、並びに、必要に応じて水溶性有機溶剤や前記添加剤を混合して撹拌し、予備分散液を調整し、次いで、
(2)該予備分散液をサンドミル等の湿式媒体ミルで分散染料を微粒子化し、分散させ、分散染料分散液を得る。
(3)該分散染料分散液に、水、前記化学式(I)の化合物、必要に応じて水溶性有機溶剤や前記添加剤を加え濃度調整した後、濾紙等でろ過してからインクジェット捺染用インクとして使用する。
レッド分散染料原体(C.I.Disperse Red 92)100部、アニオン性高分子分散剤として"ジョンクリル63"( スチレン-(メタ)アクリル酸系共重合体アンモニア中和物の30%樹脂水溶液、重量平均分子量=12,500、酸価=213)100部、水300部からなる混合物に直径0.4mmのジルコンビーズ1500部を使用して、サンドミルにて35時間微粒子化して分散液を得た。
"サーフィノール82"を0.2部、1.5部及び1.8部に変更する以外は実施例1と同様にして染料濃度を8%に調整し、実施例2~4のインクを作成した。染料の平均粒径は100nmであった。
レッド分散染料原体に代えて、イエロー分散染料原体(C.I.Disperse Yellow 65)100部を使用する以外は実施例1と同様に微粒子化して分散液を得た。この分散液20部に、グリセリン35部、"サーフィノール82"1部、さらに水を44部加え染料濃度を4%に調整したインクを作製した。染料の平均粒径は90nmであった。
レッド分散染料原体に代えて、ブルー分散染料原体(C.I.Disperse Blue 60)100部を使用する以外は実施例1と同様に微粒子化して分散液を得た。この分散液40部に、 グリセリン35部、"サーフィノール82"1部、さらに水を24部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は110nmであった。
レッド分散染料原体に代えて、ブルー分散染料原体(C.I.DisperseBlue 165)100部を使用する以外は実施例1と同様に微粒子化して分散液を得た。この分散液20部に、グリセリン35部、"サーフィノール82"1部、さらに水を44部加え染料濃度を4%に調整したインクを作製した。染料の平均粒径は90nmであった。
"ジョンクリル63"67部、水333部を使用して微粒子化する以外は実施例1と同様にして、染料濃度を8%に調整したインクを作製した。染料の平均粒径は100nmであった。
実施例1と同一の方法で作製した分散液10部に、グリセリン35部、"サーフィノール82"1部、さらに水を54部加え染料濃度を2%に調整したインクを作成した。染料の平均粒径は100nmであった。
レッド分散染料原体(C.I.Disperse Red 92)100部、"ジョンクリル63"133部、水267部からなる混合物に直径0.4mmのジルコンビーズ1500部を使用して、サンドミルにて35時間微粒子化して分散液を得た。この分散液50部に、グリセリン35部、"サーフィノール82"1部、さらに水を14部加え染料濃度を10%に調整したインクを作成した。染料の平均粒径は100nmであった。
アニオン性高分子分散剤として"ジョンクリル61"( スチレン-(メタ)アクリル酸系共重合体アンモニア中和物の30.5%樹脂水溶液、重量平均分子量=12,000、酸価=195)98部、水302部を使用する以外は実施例1と同様に微粒子化して分散液を得た。この分散液40部に、グリセリン35部、"サーフィノール82"1部、さらに水を24部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は100nmであった。
アニオン性高分子分散剤として"ジョンクリル70"( スチレン-(メタ)アクリル酸系共重合体アンモニア中和物の30%樹脂水溶液、重量平均分子量=16,500、酸価=240)100部を使用する以外は実施例1と同様に微粒子化して分散液を得た。この分散液40部に、グリセリン35部、"サーフィノール82"1部、さらに水を24部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は100nmであった。
実施例1と同一の方法で作製した分散液40部に、グリセリン35部、"サーフィノール82"1部、アニオン性界面活性剤として“デモールN”(花王(株)製、β-ナフタレンスルホン酸ホルマリン縮合物のナトリウム塩)1.5部、さらに水を22.5部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は100nmであった。
実施例1と同一の方法で作製した分散液40部に、グリセリン35部、"サーフィノール82"1部、アニオン性界面活性剤として"デモール SNB"(花王(株)製、芳香族スルホン酸ナトリウムのホルマリン縮合物)1.5部、さらに水を22.5部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は100nmであった。
実施例1と同一の方法で作製した分散液40部に、グリセリン25部、"サーフィノール82"1部、さらに水を34部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は100nmであった。
実施例1と同一の方法で作製した分散液40部に、グリセリン50部、"サーフィノール82"1部、さらに水を9部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は100nmであった。
実施例1と同一の方法で作製した分散液40部に、表2に記載のグリセリン、ジグリセリン、エチレングリコール、プロピレングリコール、ジエチレングリコール、ポリエチレングリコール(平均分子量300)、ジプロピレングリコールを所定量、"サーフィノール82"1部、さらに水を24部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は100nmであった。なお参考例1~3は技術情報として開示する。
実施例1の"サーフィノール 82"を、それぞれ"サーフィノール104E"(日信化学工業(株)製、アセチレングリコール系化合物)、"サーフィノール465"(日信化学工業(株)製、“サーフィノール104”のエチレンオキサイド付加体)、"BYK-348"(ビックケミー・ジャパン(株)製、シリコン系界面活性剤)、ジエチレングリコールモノブチルエーテル及び1,2-ヘキサンジオールに変更した以外は、実施例1と同様にして比較例1~5のインクを作製した。各比較例の染料の平均粒径は100nmであった。
レッド分散染料原体(C.I.Disperse Red 92)100部、アニオン性高分子分散剤として"ジョンクリル57"( スチレン-(メタ)アクリル酸系共重合体アンモニア中和物の37%樹脂水溶液、重量平均分子量=4,900、酸価=215)81部、水319部からなる混合物に直径0.4mmのジルコンビーズ1500部を使用して、サンドミルにて35時間微粒子化して分散液を得た。この分散液40部に、グリセリン35部、"サーフィノール82"1部、さらに水を24部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は120nmであった。
レッド分散染料原体(C.I.Disperse Red 92)100部、分散剤として“デモールN”100部、水300部からなる混合物に直径0.4mmのジルコンビーズ1500部を使用して、サンドミルにて35時間微粒子化して分散液を得た。この分散液40部に、グリセリン35部、"サーフィノール82"1部、さらに水を24部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は120nmであった。
レッド分散染料原体(C.I.Disperse Red 92)100部、分散剤として “デモールN”70部、"ユニトックス480" (平均炭素数30直鎖アルコールのエチレンオキサイド付加物、米国ペトロライト社製)30部、水300部からなる混合物に直径0.4mmのジルコンビーズ1500部を使用して、サンドミルにて35時間微粒子化して分散液を得た。この分散液40部に、グリセリン35部、"サーフィノール82"1部、さらに水を24部加え染料濃度を8%に調整したインクを作製した。染料の平均粒径は100nmであった。
(1)出射試験
上記実施例および比較例で作製したインクを市販の大判インクジェット用プロッター((株)ミマキエンジニアリング製"JV4-130")を使用して、360×540dpi、3パス、双方向、印字幅1200mmの条件下で、単色・塗りつぶし印刷を10時間行った。印刷後ノズルチェックを行い、全180ノズルのうちの正常出射していないノズルの数を確認した。
評価基準:
A 正常出射していないノズルの数が0~2。
B 正常出射していないノズルの数が3~9。
C 正常出射していないノズルの数が10以上。
上記実施例および比較例で作製したインクを市販のインクジェット印刷用前処理済みポリエステル布(株式会社大力製、“大力スーパーポンジ”)に、大判インクジェット用プロッター(ピエゾ方式、(株)ミマキエンジニアリング製"TX2-160")により、360×540dpi、3パス、双方向の条件で、縦300mm、横400mmの単色・塗りつぶし印刷を行い、H.T.スチーマーにて175℃にて8分間加熱して染色を行い、次いで還元洗浄、水洗を施し、染色布を得た。得られた染色布の濃度感を目視にて確認した。
評価基準:
A 染色布の染色濃度が高い。
B 少し、染色布の染色濃度が低い。
C かなり、染色布の染色濃度が低い。
実施例および比較例で作成した昇華転写用インクジェット記録用インクを40℃で1ヶ月間保管して、凝集物(沈降物)の発生状況を目視で確認した。
評価基準:
A 凝集物の発生なし。
B 少し、凝集物が発生している。
C 多量の凝集物が発生している。
Claims (9)
- 水、分散染料、水溶性有機溶剤及びアニオン性高分子分散剤を含有するインクジェット捺染用インクであって、
前記水溶性有機溶剤はグリセリン、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール(平均分子量200~600)、ジプロピレングリコール及びトリプロピレングリコールから選ばれる少なくとも1種であり、
前記水溶性有機溶剤の含有量はインク全質量に対し25~50質量%であり、
前記アニオン性高分子分散剤は、酸価160~250mgKOH/g、重量平均分子量8,000~20,000のスチレン-(メタ)アクリル酸系共重合体であり、
さらに、浸透剤として下記化学式(I)
- 前記分散剤の重量平均分子量は、10,000~18,000である請求項1に記載のインクジェット捺染用インク。
- 前記スチレン-(メタ)アクリル酸系共重合体の含有量は、インク全質量に対して0.2~4質量%である請求項1または2に記載のインクジェット捺染用インク。
- 前記アセチレングリコール系化合物は、インク全質量に対して0.1~2.0質量%含む請求項1~3のいずれか1項に記載のインクジェット捺染用インク。
- 前記インクにはさらに、アニオン性界面活性剤をインク全質量に対して0.1~3質量%含有する請求項1~4のいずれか1項に記載のインクジェット捺染用インク。
- 前記水溶性有機溶剤は、グリセリン、ジエチレングリコール及びジプロピレングリコールから選ばれる少なくとも1種である請求項1~5のいずれか1項に記載のインクジェット捺染用インク。
- 前記水溶性有機溶剤はグリセリンである請求項6に記載のインクジェット捺染用インク。
- 請求項1~7のいずれか1項に記載のインクジェット捺染用インクを使用して、疎水性繊維材料からなる布帛にインクジェット印刷を行った後、加熱するインクジェット捺染方法。
- 前記加熱の温度が150~220℃の範囲であり、加熱時間は1~15分間である請求項8に記載のインクジェット捺染方法。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201480001144.7A CN104271688B (zh) | 2013-02-21 | 2014-02-07 | 喷墨印染用油墨及染色方法 |
EP14754474.6A EP2960305B1 (en) | 2013-02-21 | 2014-02-07 | Ink for ink jet printing and staining method |
JP2014524976A JP6010123B2 (ja) | 2013-02-21 | 2014-02-07 | インクジェット捺染用インク及び染色方法 |
US14/398,354 US9340695B2 (en) | 2013-02-21 | 2014-02-07 | Ink for inkjet textile printing and dyeing method |
KR1020147032051A KR101681398B1 (ko) | 2013-02-21 | 2014-02-07 | 잉크젯 날염용 잉크 및 염색 방법 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013032054 | 2013-02-21 | ||
JP2013-032054 | 2013-02-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014129323A1 true WO2014129323A1 (ja) | 2014-08-28 |
Family
ID=51391119
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2014/052923 WO2014129323A1 (ja) | 2013-02-21 | 2014-02-07 | インクジェット捺染用インク及び染色方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US9340695B2 (ja) |
EP (1) | EP2960305B1 (ja) |
JP (1) | JP6010123B2 (ja) |
KR (1) | KR101681398B1 (ja) |
CN (1) | CN104271688B (ja) |
WO (1) | WO2014129323A1 (ja) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015227398A (ja) * | 2014-05-30 | 2015-12-17 | セーレン株式会社 | インクジェット用インクセット、インクジェットプリント方法、及びインクジェットプリント物 |
WO2016125869A1 (ja) * | 2015-02-06 | 2016-08-11 | コニカミノルタ株式会社 | インクジェットインク、インクジェット捺染方法、インクジェット捺染方法によって捺染された布帛およびインクジェット捺染システム |
WO2016147854A1 (ja) * | 2015-03-13 | 2016-09-22 | セーレン株式会社 | インクジェット用インクセットおよびインクジェットプリント物の製造方法 |
JP2017082181A (ja) * | 2015-10-30 | 2017-05-18 | 日本化薬株式会社 | インク用エマルション組成物及び水性インク |
JP2017082182A (ja) * | 2015-10-30 | 2017-05-18 | 日本化薬株式会社 | インク用分散液組成物及び水性インク |
JPWO2018021159A1 (ja) * | 2016-07-28 | 2019-06-13 | 富士フイルム株式会社 | インクジェット捺染方法、着色組成物、インクジェットインク、インクカートリッジ、及び染料ポリマー |
WO2020017431A1 (ja) * | 2018-07-18 | 2020-01-23 | 日本化薬株式会社 | インクジェット捺染用インク組成物及び疎水性繊維の捺染方法 |
JP2022070904A (ja) * | 2015-10-30 | 2022-05-13 | 日本化薬株式会社 | インク用エマルション組成物及び水性インク |
EP4345140A1 (en) | 2022-09-29 | 2024-04-03 | Nissin Chemical Industry Co., Ltd. | Dispersant, dispersion, ink composition, and method for producing same |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017172380A1 (en) * | 2016-04-01 | 2017-10-05 | Eastman Kodak Company | Inkjet ink compositions and aqueous inkjet printing |
CN106049090A (zh) * | 2016-06-30 | 2016-10-26 | 绍兴英科数码科技有限公司 | 一种分散染料直喷工艺 |
MX2019008835A (es) * | 2017-01-25 | 2019-10-24 | Kornit Digital Ltd | Impresion por chorro de tinta en telas sinteticas te?idas. |
KR102274974B1 (ko) * | 2017-06-01 | 2021-07-07 | 닛뽄 가야쿠 가부시키가이샤 | 잉크젯 날염용 잉크 조성물 및 소수성 섬유의 날염 방법 |
EP3622111B1 (en) | 2017-10-18 | 2021-05-26 | Hewlett-Packard Development Company, L.P. | Printing on a textile |
WO2019094008A1 (en) | 2017-11-08 | 2019-05-16 | Hewlett-Packard Development Company, L.P. | Inkjet pre-treatment fluid for dye sublimation printing |
CN108193528B (zh) * | 2018-01-30 | 2023-09-01 | 江苏华尔化工有限公司 | 一种分散染料商品化性能提升剂及其制备方法 |
EP3549989B1 (en) * | 2018-04-05 | 2021-12-01 | Agfa Nv | Aqueous inkjet ink comprising disperse dyestuff |
JP7408920B2 (ja) * | 2019-03-27 | 2024-01-09 | セイコーエプソン株式会社 | 記録物の製造方法 |
CN109972421A (zh) * | 2019-04-22 | 2019-07-05 | 浙江海印数码科技有限公司 | 一种适用于超高速数码打印的活性染料墨水及其制备方法 |
KR102215197B1 (ko) * | 2019-11-25 | 2021-02-10 | 세종대학교산학협력단 | 초고속 프린터용 잉크 조성물 |
CN112796119B (zh) * | 2020-12-31 | 2022-11-29 | 珠海天威新材料股份有限公司 | 一种高温直喷分散染料墨水及其制备方法、打印方法 |
EP4119724A3 (en) * | 2021-07-12 | 2023-04-05 | Konica Minolta, Inc. | Fabric treatment agent, textile ink set, textile printing method, and textile printed fabric |
CN114574029B (zh) * | 2022-02-28 | 2023-10-24 | 福建赛孔雀新材料科技有限公司 | 一种高强渗透型墨水及其在数码印花中的应用 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999005230A1 (fr) | 1997-07-28 | 1999-02-04 | Seiko Epson Corporation | Composition d'encre |
JP2000095990A (ja) * | 1998-09-22 | 2000-04-04 | Mitsubishi Pencil Co Ltd | 水性インキ組成物 |
JP2001294789A (ja) | 1999-11-11 | 2001-10-23 | Mitsubishi Chemicals Corp | 記録液および記録液用分散液の調製方法ならびに記録液の調製方法 |
JP2002201428A (ja) * | 2000-04-10 | 2002-07-19 | Seiko Epson Corp | コート液及びこれを用いた画像記録方法並びに記録物 |
JP2003246954A (ja) | 2001-12-18 | 2003-09-05 | Kiwa Kagaku Kogyo Kk | インクジェット記録用インク |
JP2006160950A (ja) * | 2004-12-09 | 2006-06-22 | Kiwa Kagaku Kogyo Kk | 水性顔料分散体、インクジェット記録用インク並びにこれを用いた記録方法及び捺染方法 |
JP2008291079A (ja) | 2007-05-23 | 2008-12-04 | Konica Minolta Ij Technologies Inc | インクジェットインク及びインクジェット画像形成方法 |
JP2011174007A (ja) * | 2010-02-25 | 2011-09-08 | Fujifilm Corp | インクジェット捺染用インク、インクジェット捺染方法及び捺染物 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1020499B1 (en) * | 1998-07-14 | 2006-02-22 | Seiko Epson Corporation | Sublimation transfer ink jet recording method |
ATE402022T1 (de) | 2000-04-10 | 2008-08-15 | Seiko Epson Corp | Beschichtungsflüssigkeit, bildaufzeichnungsverfahren und eine damit erzeugte aufzeichnung |
KR100555336B1 (ko) | 2001-12-18 | 2006-02-24 | 기와 가가쿠 고교 가부시키가이샤 | 잉크젯 기록용 잉크 |
US6890378B2 (en) * | 2002-01-18 | 2005-05-10 | Seiko Epson Corporation | Inkjet ink |
JP2003213164A (ja) * | 2002-01-18 | 2003-07-30 | Fuji Shikiso Kk | インクジェット印刷用水系顔料インク組成物 |
WO2005044574A1 (en) * | 2003-11-07 | 2005-05-19 | Ricoh Company, Ltd. | Ink set, treating liquid, recording liquid, image recording apparatus and image recording method |
US8777390B2 (en) * | 2004-04-15 | 2014-07-15 | Hewlett-Packard Development Company, L.P. | Ink-jet printing system with reduced nozzle clogging |
JP5198745B2 (ja) | 2006-02-08 | 2013-05-15 | 花王株式会社 | インクジェット記録用水系インク |
JP5039022B2 (ja) * | 2006-03-06 | 2012-10-03 | 日本化薬株式会社 | インクジェット捺染用インク及びそれを用いるインクジェット捺染方法 |
US7758684B2 (en) * | 2006-06-07 | 2010-07-20 | Nissin Chemical Industry Co., Ltd. | Ink additive and ink using same |
EP2075293B1 (en) * | 2007-12-28 | 2014-03-12 | Konica Minolta Holdings, Inc. | Ink-jet ink and ink-jet recording method |
JP2009173879A (ja) | 2007-12-28 | 2009-08-06 | Konica Minolta Holdings Inc | インクジェットインク及びインクジェット記録方法 |
-
2014
- 2014-02-07 CN CN201480001144.7A patent/CN104271688B/zh active Active
- 2014-02-07 JP JP2014524976A patent/JP6010123B2/ja active Active
- 2014-02-07 EP EP14754474.6A patent/EP2960305B1/en active Active
- 2014-02-07 US US14/398,354 patent/US9340695B2/en active Active
- 2014-02-07 KR KR1020147032051A patent/KR101681398B1/ko active IP Right Grant
- 2014-02-07 WO PCT/JP2014/052923 patent/WO2014129323A1/ja active Application Filing
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999005230A1 (fr) | 1997-07-28 | 1999-02-04 | Seiko Epson Corporation | Composition d'encre |
JP2000095990A (ja) * | 1998-09-22 | 2000-04-04 | Mitsubishi Pencil Co Ltd | 水性インキ組成物 |
JP2001294789A (ja) | 1999-11-11 | 2001-10-23 | Mitsubishi Chemicals Corp | 記録液および記録液用分散液の調製方法ならびに記録液の調製方法 |
JP2002201428A (ja) * | 2000-04-10 | 2002-07-19 | Seiko Epson Corp | コート液及びこれを用いた画像記録方法並びに記録物 |
JP2003246954A (ja) | 2001-12-18 | 2003-09-05 | Kiwa Kagaku Kogyo Kk | インクジェット記録用インク |
JP2006160950A (ja) * | 2004-12-09 | 2006-06-22 | Kiwa Kagaku Kogyo Kk | 水性顔料分散体、インクジェット記録用インク並びにこれを用いた記録方法及び捺染方法 |
JP2008291079A (ja) | 2007-05-23 | 2008-12-04 | Konica Minolta Ij Technologies Inc | インクジェットインク及びインクジェット画像形成方法 |
JP2011174007A (ja) * | 2010-02-25 | 2011-09-08 | Fujifilm Corp | インクジェット捺染用インク、インクジェット捺染方法及び捺染物 |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015227398A (ja) * | 2014-05-30 | 2015-12-17 | セーレン株式会社 | インクジェット用インクセット、インクジェットプリント方法、及びインクジェットプリント物 |
WO2016125869A1 (ja) * | 2015-02-06 | 2016-08-11 | コニカミノルタ株式会社 | インクジェットインク、インクジェット捺染方法、インクジェット捺染方法によって捺染された布帛およびインクジェット捺染システム |
US9957400B2 (en) | 2015-03-13 | 2018-05-01 | Seiren Co., Ltd. | Ink set for ink jet and method for producing ink jet printed matter |
JP2016169342A (ja) * | 2015-03-13 | 2016-09-23 | セーレン株式会社 | インクジェット用インクセットおよびインクジェットプリント物の製造方法 |
WO2016147854A1 (ja) * | 2015-03-13 | 2016-09-22 | セーレン株式会社 | インクジェット用インクセットおよびインクジェットプリント物の製造方法 |
JP2017082181A (ja) * | 2015-10-30 | 2017-05-18 | 日本化薬株式会社 | インク用エマルション組成物及び水性インク |
JP2017082182A (ja) * | 2015-10-30 | 2017-05-18 | 日本化薬株式会社 | インク用分散液組成物及び水性インク |
JP2022070904A (ja) * | 2015-10-30 | 2022-05-13 | 日本化薬株式会社 | インク用エマルション組成物及び水性インク |
JPWO2018021159A1 (ja) * | 2016-07-28 | 2019-06-13 | 富士フイルム株式会社 | インクジェット捺染方法、着色組成物、インクジェットインク、インクカートリッジ、及び染料ポリマー |
WO2020017431A1 (ja) * | 2018-07-18 | 2020-01-23 | 日本化薬株式会社 | インクジェット捺染用インク組成物及び疎水性繊維の捺染方法 |
JPWO2020017431A1 (ja) * | 2018-07-18 | 2021-08-02 | 日本化薬株式会社 | インクジェット捺染用インク組成物及び疎水性繊維の捺染方法 |
JP7349430B2 (ja) | 2018-07-18 | 2023-09-22 | 日本化薬株式会社 | インクジェット捺染用インク組成物及び疎水性繊維の捺染方法 |
EP4345140A1 (en) | 2022-09-29 | 2024-04-03 | Nissin Chemical Industry Co., Ltd. | Dispersant, dispersion, ink composition, and method for producing same |
Also Published As
Publication number | Publication date |
---|---|
EP2960305B1 (en) | 2017-09-13 |
EP2960305A1 (en) | 2015-12-30 |
CN104271688B (zh) | 2016-08-31 |
US9340695B2 (en) | 2016-05-17 |
EP2960305A4 (en) | 2016-11-02 |
JP6010123B2 (ja) | 2016-10-19 |
CN104271688A (zh) | 2015-01-07 |
US20150116419A1 (en) | 2015-04-30 |
KR101681398B1 (ko) | 2016-11-30 |
JPWO2014129323A1 (ja) | 2017-02-02 |
KR20150005971A (ko) | 2015-01-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6010123B2 (ja) | インクジェット捺染用インク及び染色方法 | |
JP6010122B2 (ja) | インクジェット用昇華性染料インク及び染色方法 | |
JP4818102B2 (ja) | 水性分散液、インク組成物及びそれを用いるインクジェット記録方法 | |
US9040623B2 (en) | Ink for inkjet textile printing and an inkjet textile printing method using the same | |
JP2009507991A (ja) | インクジェットインクおよびインクセット | |
WO2003052009A1 (en) | Ink for inkjet recording | |
JP6156842B2 (ja) | 水性分散液、インク組成物及びインクジェット捺染方法 | |
JP2002285048A (ja) | インクジェット記録用インク | |
JP6238685B2 (ja) | 水性分散液、インク組成物及びインクジェット捺染方法 | |
CN112384578A (zh) | 喷墨印染用印墨组合物及疏水性纤维的印染方法 | |
JP7491913B2 (ja) | 着色分散液、記録メディア、及び疎水性繊維の捺染方法 | |
JP7245671B2 (ja) | 印刷物の製造方法 | |
JP7310418B2 (ja) | 水系インクジェットインク組成物及びインクジェット記録方法 | |
JP7479342B2 (ja) | 染料分散液及び疎水性繊維の捺染方法 | |
JP2022180836A (ja) | 捺染物の製造方法 | |
JP2022147718A (ja) | 着色分散液、それを用いるインク組成物、および、それらを用いた分散安定性向上方法及び疎水性繊維の捺染方法。 | |
JP2015199781A (ja) | インクセット、及びインクジェット記録方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ENP | Entry into the national phase |
Ref document number: 2014524976 Country of ref document: JP Kind code of ref document: A |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 14754474 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14398354 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 20147032051 Country of ref document: KR Kind code of ref document: A |
|
REEP | Request for entry into the european phase |
Ref document number: 2014754474 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2014754474 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |