WO2014069605A1 - ポリイソシアネート組成物及びイソシアネート重合体組成物 - Google Patents
ポリイソシアネート組成物及びイソシアネート重合体組成物 Download PDFInfo
- Publication number
- WO2014069605A1 WO2014069605A1 PCT/JP2013/079639 JP2013079639W WO2014069605A1 WO 2014069605 A1 WO2014069605 A1 WO 2014069605A1 JP 2013079639 W JP2013079639 W JP 2013079639W WO 2014069605 A1 WO2014069605 A1 WO 2014069605A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- compound
- polyisocyanate
- mass
- reaction
- Prior art date
Links
- 239000005056 polyisocyanate Substances 0.000 title claims abstract description 559
- 229920001228 polyisocyanate Polymers 0.000 title claims abstract description 559
- 239000000203 mixture Substances 0.000 title claims abstract description 461
- 239000012948 isocyanate Substances 0.000 title claims description 241
- 150000002513 isocyanates Chemical class 0.000 title claims description 159
- 229920000642 polymer Polymers 0.000 title claims description 99
- -1 ether compound Chemical class 0.000 claims abstract description 504
- 150000001875 compounds Chemical class 0.000 claims abstract description 483
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 78
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 48
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 48
- 239000010703 silicon Substances 0.000 claims abstract description 46
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 36
- 150000008282 halocarbons Chemical class 0.000 claims abstract description 12
- 238000004821 distillation Methods 0.000 claims description 168
- 125000003118 aryl group Chemical group 0.000 claims description 86
- 238000000034 method Methods 0.000 claims description 81
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 61
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical compound C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 claims description 60
- 238000004040 coloring Methods 0.000 claims description 59
- 238000000746 purification Methods 0.000 claims description 45
- 125000000962 organic group Chemical group 0.000 claims description 37
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 claims description 30
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 29
- 229910052799 carbon Inorganic materials 0.000 claims description 28
- 229910052757 nitrogen Inorganic materials 0.000 claims description 24
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 20
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims description 20
- 125000005442 diisocyanate group Chemical group 0.000 claims description 19
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 18
- QLVWOKQMDLQXNN-UHFFFAOYSA-N dibutyl carbonate Chemical compound CCCCOC(=O)OCCCC QLVWOKQMDLQXNN-UHFFFAOYSA-N 0.000 claims description 13
- 150000002170 ethers Chemical class 0.000 claims description 12
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 11
- 150000003568 thioethers Chemical class 0.000 claims description 11
- 150000001721 carbon Chemical group 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 9
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 7
- 150000004651 carbonic acid esters Chemical class 0.000 claims description 6
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 5
- OKQDSOXFNBWWJL-UHFFFAOYSA-N dihexyl carbonate Chemical compound CCCCCCOC(=O)OCCCCCC OKQDSOXFNBWWJL-UHFFFAOYSA-N 0.000 claims description 5
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 5
- HSNQKJVQUFYBBY-UHFFFAOYSA-N dipentyl carbonate Chemical compound CCCCCOC(=O)OCCCCC HSNQKJVQUFYBBY-UHFFFAOYSA-N 0.000 claims description 5
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 3
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 478
- 239000003054 catalyst Substances 0.000 description 173
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 130
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 116
- 125000004432 carbon atom Chemical group C* 0.000 description 101
- 125000001931 aliphatic group Chemical group 0.000 description 62
- 230000000694 effects Effects 0.000 description 56
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 55
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 55
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 53
- 239000005058 Isophorone diisocyanate Substances 0.000 description 52
- 125000000753 cycloalkyl group Chemical group 0.000 description 52
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 52
- 238000004519 manufacturing process Methods 0.000 description 51
- 239000002904 solvent Substances 0.000 description 50
- 235000019441 ethanol Nutrition 0.000 description 47
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 43
- 229920005862 polyol Polymers 0.000 description 41
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 40
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 33
- 239000000047 product Substances 0.000 description 32
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 31
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 28
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 28
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 27
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 27
- 125000000217 alkyl group Chemical group 0.000 description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 25
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 25
- 239000003795 chemical substances by application Substances 0.000 description 25
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 23
- 238000000926 separation method Methods 0.000 description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 22
- 125000004429 atom Chemical group 0.000 description 22
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 21
- 235000013877 carbamide Nutrition 0.000 description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 20
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 20
- 239000004202 carbamide Substances 0.000 description 20
- 125000005843 halogen group Chemical group 0.000 description 20
- 229910052739 hydrogen Inorganic materials 0.000 description 20
- 239000001257 hydrogen Substances 0.000 description 20
- 238000012856 packing Methods 0.000 description 20
- 239000000243 solution Substances 0.000 description 20
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 description 18
- 125000003710 aryl alkyl group Chemical group 0.000 description 18
- 239000007788 liquid Substances 0.000 description 18
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 18
- 229920001223 polyethylene glycol Polymers 0.000 description 18
- 239000010409 thin film Substances 0.000 description 18
- 239000002202 Polyethylene glycol Substances 0.000 description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 17
- 229910052760 oxygen Inorganic materials 0.000 description 17
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 16
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 16
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 description 16
- 230000007246 mechanism Effects 0.000 description 16
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 16
- 239000001301 oxygen Substances 0.000 description 16
- YCOZIPAWZNQLMR-UHFFFAOYSA-N pentadecane Chemical compound CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 16
- 125000001424 substituent group Chemical group 0.000 description 16
- 150000002433 hydrophilic molecules Chemical class 0.000 description 15
- 238000004383 yellowing Methods 0.000 description 15
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 14
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 14
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 14
- 150000001298 alcohols Chemical class 0.000 description 13
- 150000004945 aromatic hydrocarbons Chemical group 0.000 description 13
- 238000000576 coating method Methods 0.000 description 13
- 150000003077 polyols Chemical class 0.000 description 13
- 230000009257 reactivity Effects 0.000 description 13
- 239000000523 sample Substances 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 12
- 125000002723 alicyclic group Chemical group 0.000 description 12
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 12
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 12
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 229910052717 sulfur Inorganic materials 0.000 description 12
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 11
- QEGNUYASOUJEHD-UHFFFAOYSA-N 1,1-dimethylcyclohexane Chemical compound CC1(C)CCCCC1 QEGNUYASOUJEHD-UHFFFAOYSA-N 0.000 description 10
- IUVCFHHAEHNCFT-INIZCTEOSA-N 2-[(1s)-1-[4-amino-3-(3-fluoro-4-propan-2-yloxyphenyl)pyrazolo[3,4-d]pyrimidin-1-yl]ethyl]-6-fluoro-3-(3-fluorophenyl)chromen-4-one Chemical compound C1=C(F)C(OC(C)C)=CC=C1C(C1=C(N)N=CN=C11)=NN1[C@@H](C)C1=C(C=2C=C(F)C=CC=2)C(=O)C2=CC(F)=CC=C2O1 IUVCFHHAEHNCFT-INIZCTEOSA-N 0.000 description 10
- 125000004122 cyclic group Chemical group 0.000 description 10
- 238000004817 gas chromatography Methods 0.000 description 10
- 150000002440 hydroxy compounds Chemical class 0.000 description 10
- RGCLLPNLLBQHPF-HJWRWDBZSA-N phosphamidon Chemical compound CCN(CC)C(=O)C(\Cl)=C(/C)OP(=O)(OC)OC RGCLLPNLLBQHPF-HJWRWDBZSA-N 0.000 description 10
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical compound CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 description 9
- 125000003545 alkoxy group Chemical group 0.000 description 9
- 150000001491 aromatic compounds Chemical class 0.000 description 9
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 9
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical group CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 229940005657 pyrophosphoric acid Drugs 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000011593 sulfur Substances 0.000 description 9
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 8
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 8
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 8
- 239000007795 chemical reaction product Substances 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 8
- 239000000945 filler Substances 0.000 description 8
- 239000010408 film Substances 0.000 description 8
- 239000000499 gel Substances 0.000 description 8
- 230000003472 neutralizing effect Effects 0.000 description 8
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 8
- 239000003973 paint Substances 0.000 description 8
- 229920000137 polyphosphoric acid Polymers 0.000 description 8
- 238000007086 side reaction Methods 0.000 description 8
- 239000008096 xylene Substances 0.000 description 8
- 229910052726 zirconium Inorganic materials 0.000 description 8
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 7
- LTSWUFKUZPPYEG-UHFFFAOYSA-N 1-decoxydecane Chemical compound CCCCCCCCCCOCCCCCCCCCC LTSWUFKUZPPYEG-UHFFFAOYSA-N 0.000 description 7
- 229940126062 Compound A Drugs 0.000 description 7
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 7
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 7
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 description 7
- 125000002015 acyclic group Chemical group 0.000 description 7
- 239000003463 adsorbent Substances 0.000 description 7
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 7
- YFNONBGXNFCTMM-UHFFFAOYSA-N butoxybenzene Chemical compound CCCCOC1=CC=CC=C1 YFNONBGXNFCTMM-UHFFFAOYSA-N 0.000 description 7
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 238000005227 gel permeation chromatography Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 125000001624 naphthyl group Chemical group 0.000 description 7
- 125000004346 phenylpentyl group Chemical group C1(=CC=CC=C1)CCCCC* 0.000 description 7
- 125000004344 phenylpropyl group Chemical group 0.000 description 7
- 238000012643 polycondensation polymerization Methods 0.000 description 7
- 230000001737 promoting effect Effects 0.000 description 7
- 235000013772 propylene glycol Nutrition 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical group CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- LTEQMZWBSYACLV-UHFFFAOYSA-N Hexylbenzene Chemical compound CCCCCCC1=CC=CC=C1 LTEQMZWBSYACLV-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000004305 biphenyl Substances 0.000 description 6
- 235000010290 biphenyl Nutrition 0.000 description 6
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 6
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 238000005755 formation reaction Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 6
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 6
- 125000003367 polycyclic group Chemical group 0.000 description 6
- 239000004814 polyurethane Substances 0.000 description 6
- 229920002635 polyurethane Polymers 0.000 description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 230000035484 reaction time Effects 0.000 description 6
- 125000003003 spiro group Chemical group 0.000 description 6
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 5
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 5
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 150000007824 aliphatic compounds Chemical class 0.000 description 5
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 5
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 5
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 5
- 125000002102 aryl alkyloxo group Chemical group 0.000 description 5
- 239000002981 blocking agent Substances 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 5
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 description 5
- 239000004914 cyclooctane Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 229910052751 metal Chemical class 0.000 description 5
- 239000002184 metal Chemical class 0.000 description 5
- 125000002950 monocyclic group Chemical group 0.000 description 5
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
- 229920005906 polyester polyol Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 125000003944 tolyl group Chemical group 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 4
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 4
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 4
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 description 4
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical class CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 4
- IFTRQJLVEBNKJK-UHFFFAOYSA-N Ethylcyclopentane Chemical compound CCC1CCCC1 IFTRQJLVEBNKJK-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000006267 biphenyl group Chemical group 0.000 description 4
- 239000001273 butane Substances 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- GGBJHURWWWLEQH-UHFFFAOYSA-N butylcyclohexane Chemical compound CCCCC1CCCCC1 GGBJHURWWWLEQH-UHFFFAOYSA-N 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 239000008199 coating composition Substances 0.000 description 4
- JNGZXGGOCLZBFB-IVCQMTBJSA-N compound E Chemical compound N([C@@H](C)C(=O)N[C@@H]1C(N(C)C2=CC=CC=C2C(C=2C=CC=CC=2)=N1)=O)C(=O)CC1=CC(F)=CC(F)=C1 JNGZXGGOCLZBFB-IVCQMTBJSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 229960002887 deanol Drugs 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical class CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 239000012972 dimethylethanolamine Substances 0.000 description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 4
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 4
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 150000002334 glycols Chemical class 0.000 description 4
- 125000000623 heterocyclic group Chemical group 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 4
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 4
- 229940038384 octadecane Drugs 0.000 description 4
- GJYCVCVHRSWLNY-UHFFFAOYSA-N ortho-butylphenol Natural products CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 4
- 125000004430 oxygen atom Chemical group O* 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 4
- DEDZSLCZHWTGOR-UHFFFAOYSA-N propylcyclohexane Chemical compound CCCC1CCCCC1 DEDZSLCZHWTGOR-UHFFFAOYSA-N 0.000 description 4
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 4
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- SEKSWDGNGZWLDU-UHFFFAOYSA-N 1,1,2,2-tetramethylcyclohexane Chemical compound CC1(C)CCCCC1(C)C SEKSWDGNGZWLDU-UHFFFAOYSA-N 0.000 description 3
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 3
- DFPJRUKWEPYFJT-UHFFFAOYSA-N 1,5-diisocyanatopentane Chemical compound O=C=NCCCCCN=C=O DFPJRUKWEPYFJT-UHFFFAOYSA-N 0.000 description 3
- ATOUXIOKEJWULN-UHFFFAOYSA-N 1,6-diisocyanato-2,2,4-trimethylhexane Chemical compound O=C=NCCC(C)CC(C)(C)CN=C=O ATOUXIOKEJWULN-UHFFFAOYSA-N 0.000 description 3
- IBJBHMZOIGTRMP-UHFFFAOYSA-N 1-butyl-2-(2-butylphenoxy)benzene Chemical class CCCCC1=CC=CC=C1OC1=CC=CC=C1CCCC IBJBHMZOIGTRMP-UHFFFAOYSA-N 0.000 description 3
- URGSMJLDEFDWNX-UHFFFAOYSA-N 1-butylnaphthalene Chemical compound C1=CC=C2C(CCCC)=CC=CC2=C1 URGSMJLDEFDWNX-UHFFFAOYSA-N 0.000 description 3
- ZMXIYERNXPIYFR-UHFFFAOYSA-N 1-ethylnaphthalene Chemical compound C1=CC=C2C(CC)=CC=CC2=C1 ZMXIYERNXPIYFR-UHFFFAOYSA-N 0.000 description 3
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 3
- RIYRDRZNXDRTIL-UHFFFAOYSA-L 2-ethylhexanoate;zirconium(2+) Chemical compound [Zr+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O RIYRDRZNXDRTIL-UHFFFAOYSA-L 0.000 description 3
- GNDOBZLRZOCGAS-JTQLQIEISA-N 2-isocyanatoethyl (2s)-2,6-diisocyanatohexanoate Chemical compound O=C=NCCCC[C@H](N=C=O)C(=O)OCCN=C=O GNDOBZLRZOCGAS-JTQLQIEISA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 3
- 235000021360 Myristic acid Nutrition 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 150000001242 acetic acid derivatives Chemical class 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 3
- 125000005011 alkyl ether group Chemical group 0.000 description 3
- 125000005233 alkylalcohol group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- RJTJVVYSTUQWNI-UHFFFAOYSA-N beta-ethyl naphthalene Natural products C1=CC=CC2=CC(CC)=CC=C21 RJTJVVYSTUQWNI-UHFFFAOYSA-N 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 3
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- XXKOQQBKBHUATC-UHFFFAOYSA-N cyclohexylmethylcyclohexane Chemical compound C1CCCCC1CC1CCCCC1 XXKOQQBKBHUATC-UHFFFAOYSA-N 0.000 description 3
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 3
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 150000003949 imides Chemical class 0.000 description 3
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000000691 measurement method Methods 0.000 description 3
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 3
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- VXNSQGRKHCZUSU-UHFFFAOYSA-N octylbenzene Chemical compound [CH2]CCCCCCCC1=CC=CC=C1 VXNSQGRKHCZUSU-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 3
- 239000012264 purified product Substances 0.000 description 3
- 150000003217 pyrazoles Chemical class 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 238000000638 solvent extraction Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 125000004434 sulfur atom Chemical group 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000013638 trimer Substances 0.000 description 3
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 2
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 2
- GCYUJISWSVALJD-UHFFFAOYSA-N 1,1-diethylcyclohexane Chemical compound CCC1(CC)CCCCC1 GCYUJISWSVALJD-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- NMUWSGQKPAEPBA-UHFFFAOYSA-N 1,2-dibutylbenzene Chemical compound CCCCC1=CC=CC=C1CCCC NMUWSGQKPAEPBA-UHFFFAOYSA-N 0.000 description 2
- GVSYDCGFYSVNAX-UHFFFAOYSA-N 1,2-dihexylbenzene Chemical compound CCCCCCC1=CC=CC=C1CCCCCC GVSYDCGFYSVNAX-UHFFFAOYSA-N 0.000 description 2
- ZZECXNVRWUIJSW-UHFFFAOYSA-N 1,2-dioctylbenzene Chemical compound CCCCCCCCC1=CC=CC=C1CCCCCCCC ZZECXNVRWUIJSW-UHFFFAOYSA-N 0.000 description 2
- VPHBYBUYWBZLEX-UHFFFAOYSA-N 1,2-dipropylbenzene Chemical compound CCCC1=CC=CC=C1CCC VPHBYBUYWBZLEX-UHFFFAOYSA-N 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- LUBJCRLGQSPQNN-UHFFFAOYSA-N 1-Phenylurea Chemical compound NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- BRIKTKRHROTQFO-UHFFFAOYSA-N 1-methoxynonane Chemical compound CCCCCCCCCOC BRIKTKRHROTQFO-UHFFFAOYSA-N 0.000 description 2
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 2
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 2
- IUGOPULVANEDRX-UHFFFAOYSA-N 2-ethylhexane-1,1-diol Chemical compound CCCCC(CC)C(O)O IUGOPULVANEDRX-UHFFFAOYSA-N 0.000 description 2
- LJKDOMVGKKPJBH-UHFFFAOYSA-N 2-ethylhexyl dihydrogen phosphate Chemical compound CCCCC(CC)COP(O)(O)=O LJKDOMVGKKPJBH-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- BTVWZWFKMIUSGS-UHFFFAOYSA-N 2-methylpropane-1,2-diol Chemical compound CC(C)(O)CO BTVWZWFKMIUSGS-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical group OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- RDFQSFOGKVZWKF-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanoic acid Chemical compound OCC(C)(C)C(O)=O RDFQSFOGKVZWKF-UHFFFAOYSA-N 0.000 description 2
- AACHVWXCVWWMSI-UHFFFAOYSA-N 3-hydroxypropyl(trimethyl)azanium Chemical compound C[N+](C)(C)CCCO AACHVWXCVWWMSI-UHFFFAOYSA-N 0.000 description 2
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 description 2
- PJMDLNIAGSYXLA-UHFFFAOYSA-N 6-iminooxadiazine-4,5-dione Chemical group N=C1ON=NC(=O)C1=O PJMDLNIAGSYXLA-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical group OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 2
- 241000534000 Berula erecta Species 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical class CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 2
- 239000004215 Carbon black (E152) Chemical group 0.000 description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- UNXHWFMMPAWVPI-QWWZWVQMSA-N D-threitol Chemical compound OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 description 2
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- YWHLKYXPLRWGSE-UHFFFAOYSA-N Dimethyl trisulfide Chemical compound CSSSC YWHLKYXPLRWGSE-UHFFFAOYSA-N 0.000 description 2
- BPLQKQKXWHCZSS-UHFFFAOYSA-N Elemicin Chemical compound COC1=CC(CC=C)=CC(OC)=C1OC BPLQKQKXWHCZSS-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 2
- PWATWSYOIIXYMA-UHFFFAOYSA-N Pentylbenzene Chemical compound CCCCCC1=CC=CC=C1 PWATWSYOIIXYMA-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229940072049 amyl acetate Drugs 0.000 description 2
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- 150000008378 aryl ethers Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 2
- 229940112021 centrally acting muscle relaxants carbamic acid ester Drugs 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 2
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000001944 continuous distillation Methods 0.000 description 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 125000006612 decyloxy group Chemical group 0.000 description 2
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 description 2
- UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical compound CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 description 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 2
- UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical compound O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 125000001033 ether group Chemical group 0.000 description 2
- ZJXZSIYSNXKHEA-UHFFFAOYSA-N ethyl dihydrogen phosphate Chemical compound CCOP(O)(O)=O ZJXZSIYSNXKHEA-UHFFFAOYSA-N 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000001641 gel filtration chromatography Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 2
- 125000005446 heptyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- QHWAQXOSHHKCFK-UHFFFAOYSA-N hexylcyclohexane Chemical compound CCCCCCC1CCCCC1 QHWAQXOSHHKCFK-UHFFFAOYSA-N 0.000 description 2
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000000199 molecular distillation Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 125000005609 naphthenate group Chemical group 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- LQERIDTXQFOHKA-UHFFFAOYSA-N nonadecane Chemical compound CCCCCCCCCCCCCCCCCCC LQERIDTXQFOHKA-UHFFFAOYSA-N 0.000 description 2
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 2
- 125000006611 nonyloxy group Chemical group 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 2
- WPRDEDGZJLTOFJ-UHFFFAOYSA-N oxadiazin-4-imine Chemical compound N=C1C=CON=N1 WPRDEDGZJLTOFJ-UHFFFAOYSA-N 0.000 description 2
- 150000002923 oximes Chemical class 0.000 description 2
- 125000004115 pentoxy group Chemical group [*]OC([H])([H])C([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- HLTMUYBTNSVOFY-UHFFFAOYSA-N pentylcyclohexane Chemical compound CCCCCC1CCCCC1 HLTMUYBTNSVOFY-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- IVDFJHOHABJVEH-UHFFFAOYSA-N pinacol Chemical compound CC(C)(O)C(C)(C)O IVDFJHOHABJVEH-UHFFFAOYSA-N 0.000 description 2
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 2
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 229940116423 propylene glycol diacetate Drugs 0.000 description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 2
- 150000003459 sulfonic acid esters Chemical class 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 2
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 2
- NQISDOIAJWWPGA-UHFFFAOYSA-N triethyl(3-hydroxypropyl)azanium Chemical compound CC[N+](CC)(CC)CCCO NQISDOIAJWWPGA-UHFFFAOYSA-N 0.000 description 2
- GZBUMTPCIKCWFW-UHFFFAOYSA-N triethylcholine Chemical compound CC[N+](CC)(CC)CCO GZBUMTPCIKCWFW-UHFFFAOYSA-N 0.000 description 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- QQSRMERJTBKKCV-UHFFFAOYSA-N (1,1-dibromo-2-phenylethyl)benzene Chemical compound C=1C=CC=CC=1C(Br)(Br)CC1=CC=CC=C1 QQSRMERJTBKKCV-UHFFFAOYSA-N 0.000 description 1
- SNLOCRBUBDQVOC-UHFFFAOYSA-N (1,1-dichloro-2-phenylethyl)benzene Chemical compound C=1C=CC=CC=1C(Cl)(Cl)CC1=CC=CC=C1 SNLOCRBUBDQVOC-UHFFFAOYSA-N 0.000 description 1
- CDFYQLMZMDUCNC-UHFFFAOYSA-N (1,1-difluoro-2-phenylethyl)benzene Chemical compound C=1C=CC=CC=1C(F)(F)CC1=CC=CC=C1 CDFYQLMZMDUCNC-UHFFFAOYSA-N 0.000 description 1
- OBQKOUHLSRZFBG-UHFFFAOYSA-N (1,2-dibromo-1-phenylethyl)benzene Chemical compound C=1C=CC=CC=1C(Br)(CBr)C1=CC=CC=C1 OBQKOUHLSRZFBG-UHFFFAOYSA-N 0.000 description 1
- XNJYRGMCZCPTJE-UHFFFAOYSA-N (1,2-dibromo-2-phenylethenyl)benzene Chemical compound C=1C=CC=CC=1C(Br)=C(Br)C1=CC=CC=C1 XNJYRGMCZCPTJE-UHFFFAOYSA-N 0.000 description 1
- FTIHFTVXYNBUSM-UHFFFAOYSA-N (1,2-dichloro-2-phenylethenyl)benzene Chemical compound C=1C=CC=CC=1C(Cl)=C(Cl)C1=CC=CC=C1 FTIHFTVXYNBUSM-UHFFFAOYSA-N 0.000 description 1
- VIWUJKBBJRFTMC-UHFFFAOYSA-N (1,2-difluoro-2-phenylethenyl)benzene Chemical compound C=1C=CC=CC=1C(F)=C(F)C1=CC=CC=C1 VIWUJKBBJRFTMC-UHFFFAOYSA-N 0.000 description 1
- VBCGWXRNJSINCA-UHFFFAOYSA-N (1-chloro-1-phenylethyl)benzene Chemical compound C=1C=CC=CC=1C(Cl)(C)C1=CC=CC=C1 VBCGWXRNJSINCA-UHFFFAOYSA-N 0.000 description 1
- UVROAJFELBNMRA-UHFFFAOYSA-N (1-chloro-2-phenylethyl)benzene Chemical compound C=1C=CC=CC=1C(Cl)CC1=CC=CC=C1 UVROAJFELBNMRA-UHFFFAOYSA-N 0.000 description 1
- IGPWAITWXGQPMD-ONEGZZNKSA-N (1e)-1-fluorobuta-1,3-diene Chemical compound F\C=C\C=C IGPWAITWXGQPMD-ONEGZZNKSA-N 0.000 description 1
- CAFQWXOCTUALTE-UHFFFAOYSA-N (2,3,4-tributylphenyl)urea Chemical compound CCCCC1=CC=C(NC(N)=O)C(CCCC)=C1CCCC CAFQWXOCTUALTE-UHFFFAOYSA-N 0.000 description 1
- XHLLYJGOQLQZDX-UHFFFAOYSA-N (2,3,4-triethylphenyl)urea Chemical compound CCC1=CC=C(NC(N)=O)C(CC)=C1CC XHLLYJGOQLQZDX-UHFFFAOYSA-N 0.000 description 1
- XJRZZMNOJIHRTH-UHFFFAOYSA-N (2,3,4-trimethylphenyl)urea Chemical compound CC1=CC=C(NC(N)=O)C(C)=C1C XJRZZMNOJIHRTH-UHFFFAOYSA-N 0.000 description 1
- QZRIBZOEOFYNDN-UHFFFAOYSA-N (2,3,4-tripropylphenyl)urea Chemical compound CCCC1=CC=C(NC(N)=O)C(CCC)=C1CCC QZRIBZOEOFYNDN-UHFFFAOYSA-N 0.000 description 1
- ACADOFCZGYXDPF-UHFFFAOYSA-N (2,3-dibutylphenyl)urea Chemical compound CCCCC1=CC=CC(NC(N)=O)=C1CCCC ACADOFCZGYXDPF-UHFFFAOYSA-N 0.000 description 1
- BLXPVQZWXLPAHQ-UHFFFAOYSA-N (2,3-diethylphenyl)urea Chemical compound CCC1=CC=CC(NC(N)=O)=C1CC BLXPVQZWXLPAHQ-UHFFFAOYSA-N 0.000 description 1
- ZIKKRKVIAZZANA-UHFFFAOYSA-N (2,3-diheptylphenyl)urea Chemical compound CCCCCCCC1=CC=CC(NC(N)=O)=C1CCCCCCC ZIKKRKVIAZZANA-UHFFFAOYSA-N 0.000 description 1
- TYJWADQPXMOASZ-UHFFFAOYSA-N (2,3-dihexylphenyl)urea Chemical compound CCCCCCC1=CC=CC(NC(N)=O)=C1CCCCCC TYJWADQPXMOASZ-UHFFFAOYSA-N 0.000 description 1
- IAKBHGAJOFUBGG-UHFFFAOYSA-N (2,3-dipentylphenyl)urea Chemical compound CCCCCC1=CC=CC(NC(N)=O)=C1CCCCC IAKBHGAJOFUBGG-UHFFFAOYSA-N 0.000 description 1
- YBRDBLOLRXJJKJ-UHFFFAOYSA-N (2,3-dipropylphenyl)urea Chemical compound CCCC1=CC=CC(NC(N)=O)=C1CCC YBRDBLOLRXJJKJ-UHFFFAOYSA-N 0.000 description 1
- XXHJFZJMDUBSNN-UHFFFAOYSA-N (2-butylphenyl)urea Chemical compound CCCCC1=CC=CC=C1NC(N)=O XXHJFZJMDUBSNN-UHFFFAOYSA-N 0.000 description 1
- JVCAOEDDDQNLJU-UHFFFAOYSA-N (2-ethylphenyl)urea Chemical compound CCC1=CC=CC=C1NC(N)=O JVCAOEDDDQNLJU-UHFFFAOYSA-N 0.000 description 1
- PLMCHDBIRSBITF-UHFFFAOYSA-N (2-heptylphenyl)urea Chemical compound CCCCCCCC1=CC=CC=C1NC(N)=O PLMCHDBIRSBITF-UHFFFAOYSA-N 0.000 description 1
- XNNALCUAUGURCY-UHFFFAOYSA-N (2-hexylphenyl)urea Chemical compound CCCCCCC1=CC=CC=C1NC(N)=O XNNALCUAUGURCY-UHFFFAOYSA-N 0.000 description 1
- BLSVCHHBHKGCSQ-UHFFFAOYSA-N (2-methylphenyl)urea Chemical compound CC1=CC=CC=C1NC(N)=O BLSVCHHBHKGCSQ-UHFFFAOYSA-N 0.000 description 1
- ADCQVSATNFABHL-UHFFFAOYSA-N (2-octylphenyl)urea Chemical compound CCCCCCCCC1=CC=CC=C1NC(N)=O ADCQVSATNFABHL-UHFFFAOYSA-N 0.000 description 1
- BCZINUFOVQWMON-UHFFFAOYSA-N (2-pentylphenyl)urea Chemical compound CCCCCC1=CC=CC=C1NC(N)=O BCZINUFOVQWMON-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- OWXJKYNZGFSVRC-NSCUHMNNSA-N (e)-1-chloroprop-1-ene Chemical compound C\C=C\Cl OWXJKYNZGFSVRC-NSCUHMNNSA-N 0.000 description 1
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 1
- RZFSUSLICLSEKU-UHFFFAOYSA-N 1,1'-biphenyl;urea Chemical compound NC(N)=O.C1=CC=CC=C1C1=CC=CC=C1.C1=CC=CC=C1C1=CC=CC=C1 RZFSUSLICLSEKU-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- RPROQTRWYGYMRN-UHFFFAOYSA-N 1,1-dibromo-4,4-dibutylcyclohexane Chemical compound BrC1(CCC(CC1)(CCCC)CCCC)Br RPROQTRWYGYMRN-UHFFFAOYSA-N 0.000 description 1
- HGZNOYPOSHKZNL-UHFFFAOYSA-N 1,1-dibromo-4,4-diethylcyclohexane Chemical compound BrC1(CCC(CC1)(CC)CC)Br HGZNOYPOSHKZNL-UHFFFAOYSA-N 0.000 description 1
- FGXZPXLVOVDXGW-UHFFFAOYSA-N 1,1-dibromo-4,4-dimethylcyclohexane Chemical compound BrC1(CCC(CC1)(C)C)Br FGXZPXLVOVDXGW-UHFFFAOYSA-N 0.000 description 1
- IFTGEZOPUAJVMG-UHFFFAOYSA-N 1,1-dibromobut-1-ene Chemical compound CCC=C(Br)Br IFTGEZOPUAJVMG-UHFFFAOYSA-N 0.000 description 1
- CZJYVQRDEVTEFZ-UHFFFAOYSA-N 1,1-dibromocycloheptane Chemical compound BrC1(Br)CCCCCC1 CZJYVQRDEVTEFZ-UHFFFAOYSA-N 0.000 description 1
- BWNYAKOZXVLZQO-UHFFFAOYSA-N 1,1-dibromocyclohexane Chemical compound BrC1(Br)CCCCC1 BWNYAKOZXVLZQO-UHFFFAOYSA-N 0.000 description 1
- GWQVVHDIWWQPDS-UHFFFAOYSA-N 1,1-dibromocyclooctane Chemical compound BrC1(Br)CCCCCCC1 GWQVVHDIWWQPDS-UHFFFAOYSA-N 0.000 description 1
- PWUAOMOCADDDFI-UHFFFAOYSA-N 1,1-dibromocyclopentane Chemical compound BrC1(Br)CCCC1 PWUAOMOCADDDFI-UHFFFAOYSA-N 0.000 description 1
- YPXJOWQHBUFHBK-UHFFFAOYSA-N 1,1-dibromodec-1-ene Chemical compound CCCCCCCCC=C(Br)Br YPXJOWQHBUFHBK-UHFFFAOYSA-N 0.000 description 1
- HFVIYAZBVIGNAN-UHFFFAOYSA-N 1,1-dibromodecane Chemical compound CCCCCCCCCC(Br)Br HFVIYAZBVIGNAN-UHFFFAOYSA-N 0.000 description 1
- LCUQJELQVHGIJS-UHFFFAOYSA-N 1,1-dibromododecane Chemical compound CCCCCCCCCCCC(Br)Br LCUQJELQVHGIJS-UHFFFAOYSA-N 0.000 description 1
- APQIUTYORBAGEZ-UHFFFAOYSA-N 1,1-dibromoethane Chemical compound CC(Br)Br APQIUTYORBAGEZ-UHFFFAOYSA-N 0.000 description 1
- KZHPAFJTWIJUJM-UHFFFAOYSA-N 1,1-dibromohex-1-ene Chemical compound CCCCC=C(Br)Br KZHPAFJTWIJUJM-UHFFFAOYSA-N 0.000 description 1
- UWFXQPISTFCLAI-UHFFFAOYSA-N 1,1-dibromohexadec-1-ene Chemical compound BrC(=CCCCCCCCCCCCCCC)Br UWFXQPISTFCLAI-UHFFFAOYSA-N 0.000 description 1
- DFGWNRQUSZGHBQ-UHFFFAOYSA-N 1,1-dibromohexadecane Chemical compound CCCCCCCCCCCCCCCC(Br)Br DFGWNRQUSZGHBQ-UHFFFAOYSA-N 0.000 description 1
- SAWCWRKKWROPRB-UHFFFAOYSA-N 1,1-dibromohexane Chemical compound CCCCCC(Br)Br SAWCWRKKWROPRB-UHFFFAOYSA-N 0.000 description 1
- CXWWZHFLDMDZEQ-UHFFFAOYSA-N 1,1-dibromonon-1-ene Chemical compound CCCCCCCC=C(Br)Br CXWWZHFLDMDZEQ-UHFFFAOYSA-N 0.000 description 1
- FSTKSTMFMLANPA-UHFFFAOYSA-N 1,1-dibromononane Chemical compound CCCCCCCCC(Br)Br FSTKSTMFMLANPA-UHFFFAOYSA-N 0.000 description 1
- PHBMJDSRZYQBPS-UHFFFAOYSA-N 1,1-dibromooct-1-ene Chemical compound CCCCCCC=C(Br)Br PHBMJDSRZYQBPS-UHFFFAOYSA-N 0.000 description 1
- STBMZSJLFYGOJU-UHFFFAOYSA-N 1,1-dibromooctane Chemical compound CCCCCCCC(Br)Br STBMZSJLFYGOJU-UHFFFAOYSA-N 0.000 description 1
- JWMUSIPRTLTALQ-UHFFFAOYSA-N 1,1-dibromopent-1-ene Chemical compound CCCC=C(Br)Br JWMUSIPRTLTALQ-UHFFFAOYSA-N 0.000 description 1
- PQQAVRNNAPPTJZ-UHFFFAOYSA-N 1,1-dibromopenta-1,3-diene Chemical compound CC=CC=C(Br)Br PQQAVRNNAPPTJZ-UHFFFAOYSA-N 0.000 description 1
- HTEJLXYOJZOXKM-UHFFFAOYSA-N 1,1-dibromoprop-1-ene Chemical compound CC=C(Br)Br HTEJLXYOJZOXKM-UHFFFAOYSA-N 0.000 description 1
- ATWLRNODAYAMQS-UHFFFAOYSA-N 1,1-dibromopropane Chemical compound CCC(Br)Br ATWLRNODAYAMQS-UHFFFAOYSA-N 0.000 description 1
- MYRYOXBGZFTRGB-UHFFFAOYSA-N 1,1-dibromotetradecane Chemical compound CCCCCCCCCCCCCC(Br)Br MYRYOXBGZFTRGB-UHFFFAOYSA-N 0.000 description 1
- KWHMXITXZHXKJX-UHFFFAOYSA-N 1,1-dibutyl-4,4-dichlorocyclohexane Chemical compound ClC1(CCC(CC1)(CCCC)CCCC)Cl KWHMXITXZHXKJX-UHFFFAOYSA-N 0.000 description 1
- DHVDCVZGPGJKQE-UHFFFAOYSA-N 1,1-dibutyl-4,4-difluorocyclohexane Chemical compound FC1(CCC(CC1)(CCCC)CCCC)F DHVDCVZGPGJKQE-UHFFFAOYSA-N 0.000 description 1
- GHSINJUDKUAWQY-UHFFFAOYSA-N 1,1-dichloro-4,4-diethylcyclohexane Chemical compound ClC1(CCC(CC1)(CC)CC)Cl GHSINJUDKUAWQY-UHFFFAOYSA-N 0.000 description 1
- RXDAGDXJEVLHOA-UHFFFAOYSA-N 1,1-dichloro-4,4-dimethylcyclohexane Chemical compound ClC1(CCC(CC1)(C)C)Cl RXDAGDXJEVLHOA-UHFFFAOYSA-N 0.000 description 1
- UAZUEJTXWAXSMA-UHFFFAOYSA-N 1,1-dichlorobut-1-ene Chemical compound CCC=C(Cl)Cl UAZUEJTXWAXSMA-UHFFFAOYSA-N 0.000 description 1
- PDKAXHLOFWCWIH-UHFFFAOYSA-N 1,1-dichlorobuta-1,3-diene Chemical compound ClC(Cl)=CC=C PDKAXHLOFWCWIH-UHFFFAOYSA-N 0.000 description 1
- SEQRDAAUNCRFIT-UHFFFAOYSA-N 1,1-dichlorobutane Chemical compound CCCC(Cl)Cl SEQRDAAUNCRFIT-UHFFFAOYSA-N 0.000 description 1
- LCSFEUTXHGQLCY-UHFFFAOYSA-N 1,1-dichlorocycloheptane Chemical compound ClC1(Cl)CCCCCC1 LCSFEUTXHGQLCY-UHFFFAOYSA-N 0.000 description 1
- LQRDJCBZCLUBRY-UHFFFAOYSA-N 1,1-dichlorocyclohexane Chemical compound ClC1(Cl)CCCCC1 LQRDJCBZCLUBRY-UHFFFAOYSA-N 0.000 description 1
- XHNVGCYFMWQCAH-UHFFFAOYSA-N 1,1-dichlorocyclooctane Chemical compound ClC1(Cl)CCCCCCC1 XHNVGCYFMWQCAH-UHFFFAOYSA-N 0.000 description 1
- XZBCEESOMMQJJD-UHFFFAOYSA-N 1,1-dichlorocyclopentane Chemical compound ClC1(Cl)CCCC1 XZBCEESOMMQJJD-UHFFFAOYSA-N 0.000 description 1
- WHEZQSAGGVGZDP-UHFFFAOYSA-N 1,1-dichlorodec-1-ene Chemical compound CCCCCCCCC=C(Cl)Cl WHEZQSAGGVGZDP-UHFFFAOYSA-N 0.000 description 1
- IXADHCVQNVXURI-UHFFFAOYSA-N 1,1-dichlorodecane Chemical compound CCCCCCCCCC(Cl)Cl IXADHCVQNVXURI-UHFFFAOYSA-N 0.000 description 1
- NDDJVGQZDQBORS-UHFFFAOYSA-N 1,1-dichlorododecane Chemical compound CCCCCCCCCCCC(Cl)Cl NDDJVGQZDQBORS-UHFFFAOYSA-N 0.000 description 1
- HUURUXFGQMRTPV-UHFFFAOYSA-N 1,1-dichlorohex-1-ene Chemical compound CCCCC=C(Cl)Cl HUURUXFGQMRTPV-UHFFFAOYSA-N 0.000 description 1
- DYCZBZNSJYSFMA-UHFFFAOYSA-N 1,1-dichlorohexadec-1-ene Chemical compound CCCCCCCCCCCCCCC=C(Cl)Cl DYCZBZNSJYSFMA-UHFFFAOYSA-N 0.000 description 1
- HLYSUDKSAQOMSL-UHFFFAOYSA-N 1,1-dichlorohexadecane Chemical compound CCCCCCCCCCCCCCCC(Cl)Cl HLYSUDKSAQOMSL-UHFFFAOYSA-N 0.000 description 1
- RQXXCWHCUOJQGR-UHFFFAOYSA-N 1,1-dichlorohexane Chemical compound CCCCCC(Cl)Cl RQXXCWHCUOJQGR-UHFFFAOYSA-N 0.000 description 1
- NXWYNQYIDYLFSI-UHFFFAOYSA-N 1,1-dichloronon-1-ene Chemical compound CCCCCCCC=C(Cl)Cl NXWYNQYIDYLFSI-UHFFFAOYSA-N 0.000 description 1
- FBTKIMWGAQACHU-UHFFFAOYSA-N 1,1-dichlorononane Chemical compound CCCCCCCCC(Cl)Cl FBTKIMWGAQACHU-UHFFFAOYSA-N 0.000 description 1
- LIBAHLPMHOXNEK-UHFFFAOYSA-N 1,1-dichlorooct-1-ene Chemical compound CCCCCCC=C(Cl)Cl LIBAHLPMHOXNEK-UHFFFAOYSA-N 0.000 description 1
- OQYNFBPKTVQOKO-UHFFFAOYSA-N 1,1-dichlorooctane Chemical compound CCCCCCCC(Cl)Cl OQYNFBPKTVQOKO-UHFFFAOYSA-N 0.000 description 1
- ZNPAFRLFBXOLET-UHFFFAOYSA-N 1,1-dichloropent-1-ene Chemical compound CCCC=C(Cl)Cl ZNPAFRLFBXOLET-UHFFFAOYSA-N 0.000 description 1
- PGEVTVXEERFABN-UHFFFAOYSA-N 1,1-dichloropentane Chemical compound CCCCC(Cl)Cl PGEVTVXEERFABN-UHFFFAOYSA-N 0.000 description 1
- ZAIDIVBQUMFXEC-UHFFFAOYSA-N 1,1-dichloroprop-1-ene Chemical compound CC=C(Cl)Cl ZAIDIVBQUMFXEC-UHFFFAOYSA-N 0.000 description 1
- ILTTYLXNRDSQCT-UHFFFAOYSA-N 1,1-dichlorotetradecane Chemical compound CCCCCCCCCCCCCC(Cl)Cl ILTTYLXNRDSQCT-UHFFFAOYSA-N 0.000 description 1
- ZXKWODZIBNPRNA-UHFFFAOYSA-N 1,1-diethyl-4,4-difluorocyclohexane Chemical compound CCC1(CC)CCC(F)(F)CC1 ZXKWODZIBNPRNA-UHFFFAOYSA-N 0.000 description 1
- TUMNHQRORINJKE-UHFFFAOYSA-N 1,1-diethylurea Chemical compound CCN(CC)C(N)=O TUMNHQRORINJKE-UHFFFAOYSA-N 0.000 description 1
- POQVTERACUNDCB-UHFFFAOYSA-N 1,1-difluoro-4,4-dimethylcyclohexane Chemical compound CC1(C)CCC(F)(F)CC1 POQVTERACUNDCB-UHFFFAOYSA-N 0.000 description 1
- CYICOSUAVXTZOD-UHFFFAOYSA-N 1,1-difluorobut-1-ene Chemical compound CCC=C(F)F CYICOSUAVXTZOD-UHFFFAOYSA-N 0.000 description 1
- CPLSOYONVLSMGL-UHFFFAOYSA-N 1,1-difluorobutane Chemical compound CCCC(F)F CPLSOYONVLSMGL-UHFFFAOYSA-N 0.000 description 1
- QMPLRMBRFCVKDN-UHFFFAOYSA-N 1,1-difluorocycloheptane Chemical compound FC1(F)CCCCCC1 QMPLRMBRFCVKDN-UHFFFAOYSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- QDSFHJYWUOLCMP-UHFFFAOYSA-N 1,1-difluorocyclooctane Chemical compound FC1(F)CCCCCCC1 QDSFHJYWUOLCMP-UHFFFAOYSA-N 0.000 description 1
- QPTDDOUBRQFLQW-UHFFFAOYSA-N 1,1-difluorocyclopentane Chemical compound FC1(F)CCCC1 QPTDDOUBRQFLQW-UHFFFAOYSA-N 0.000 description 1
- BKZPWIFVSVSRGM-UHFFFAOYSA-N 1,1-difluorodec-1-ene Chemical compound CCCCCCCCC=C(F)F BKZPWIFVSVSRGM-UHFFFAOYSA-N 0.000 description 1
- RWRHXNXYHWXCCL-UHFFFAOYSA-N 1,1-difluorodecane Chemical compound CCCCCCCCCC(F)F RWRHXNXYHWXCCL-UHFFFAOYSA-N 0.000 description 1
- JTKAJWQYBOFEEW-UHFFFAOYSA-N 1,1-difluorododecane Chemical compound CCCCCCCCCCCC(F)F JTKAJWQYBOFEEW-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- OABXUFVTRAEJRN-UHFFFAOYSA-N 1,1-difluorohex-1-ene Chemical compound CCCCC=C(F)F OABXUFVTRAEJRN-UHFFFAOYSA-N 0.000 description 1
- COLPXXBLDLMGLS-UHFFFAOYSA-N 1,1-difluorohexadec-1-ene Chemical compound CCCCCCCCCCCCCCC=C(F)F COLPXXBLDLMGLS-UHFFFAOYSA-N 0.000 description 1
- XGHWPMQMDUXYFF-UHFFFAOYSA-N 1,1-difluorohexadecane Chemical compound CCCCCCCCCCCCCCCC(F)F XGHWPMQMDUXYFF-UHFFFAOYSA-N 0.000 description 1
- PEGQMHNLNMIEQD-UHFFFAOYSA-N 1,1-difluorohexane Chemical compound CCCCCC(F)F PEGQMHNLNMIEQD-UHFFFAOYSA-N 0.000 description 1
- JSCRLHAXHUFQLN-UHFFFAOYSA-N 1,1-difluoronon-1-ene Chemical compound CCCCCCCC=C(F)F JSCRLHAXHUFQLN-UHFFFAOYSA-N 0.000 description 1
- YZYRXIMUNRCECU-UHFFFAOYSA-N 1,1-difluorooct-1-ene Chemical compound CCCCCCC=C(F)F YZYRXIMUNRCECU-UHFFFAOYSA-N 0.000 description 1
- DVQDTBDVUIXQMV-UHFFFAOYSA-N 1,1-difluorooctane Chemical compound CCCCCCCC(F)F DVQDTBDVUIXQMV-UHFFFAOYSA-N 0.000 description 1
- TVMVISNVWGBUGD-UHFFFAOYSA-N 1,1-difluoropent-1-ene Chemical compound CCCC=C(F)F TVMVISNVWGBUGD-UHFFFAOYSA-N 0.000 description 1
- VSPNUIQZOFPOJC-UHFFFAOYSA-N 1,1-difluoropenta-1,3-diene Chemical compound C(C)=CC=C(F)F VSPNUIQZOFPOJC-UHFFFAOYSA-N 0.000 description 1
- PSSHQAXMSKKIBE-UHFFFAOYSA-N 1,1-difluoropentane Chemical compound CCCCC(F)F PSSHQAXMSKKIBE-UHFFFAOYSA-N 0.000 description 1
- YHLIEGBCOUQKHU-UHFFFAOYSA-N 1,1-difluoroprop-1-ene Chemical compound CC=C(F)F YHLIEGBCOUQKHU-UHFFFAOYSA-N 0.000 description 1
- YHGAQOTZTPECKY-UHFFFAOYSA-N 1,1-difluorotetradecane Chemical compound CCCCCCCCCCCCCC(F)F YHGAQOTZTPECKY-UHFFFAOYSA-N 0.000 description 1
- CRIIMEOFWXKQLD-UHFFFAOYSA-N 1,1-dioctylurea Chemical compound CCCCCCCCN(C(N)=O)CCCCCCCC CRIIMEOFWXKQLD-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- IRBAZWGOCNZHPN-UHFFFAOYSA-N 1,2-bis(ethenyl)-3,4-difluorobenzene Chemical compound FC1=C(C(=C(C=C1)C=C)C=C)F IRBAZWGOCNZHPN-UHFFFAOYSA-N 0.000 description 1
- IUGPRERXXKWPFI-UHFFFAOYSA-N 1,2-di(propan-2-yloxy)propane Chemical compound CC(C)OCC(C)OC(C)C IUGPRERXXKWPFI-UHFFFAOYSA-N 0.000 description 1
- NKFFDXYMZBDOJS-UHFFFAOYSA-N 1,2-dibromo-1-ethylcyclopentane Chemical compound BrC1C(CCC1)(CC)Br NKFFDXYMZBDOJS-UHFFFAOYSA-N 0.000 description 1
- ABAQMUXZGNZRSI-UHFFFAOYSA-N 1,2-dibromo-3,4-bis(ethenyl)benzene Chemical compound BrC1=C(C(=C(C=C1)C=C)C=C)Br ABAQMUXZGNZRSI-UHFFFAOYSA-N 0.000 description 1
- IOAFFMBGDUUARX-UHFFFAOYSA-N 1,2-dibromo-3-(2-phenylphenyl)benzene Chemical group BrC1=CC=CC(C=2C(=CC=CC=2)C=2C=CC=CC=2)=C1Br IOAFFMBGDUUARX-UHFFFAOYSA-N 0.000 description 1
- KMUOJHYDIKYRQO-UHFFFAOYSA-N 1,2-dibromo-3-methoxybenzene Chemical compound COC1=CC=CC(Br)=C1Br KMUOJHYDIKYRQO-UHFFFAOYSA-N 0.000 description 1
- NHJTVHYSKQMRDG-UHFFFAOYSA-N 1,2-dibromo-3-prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC(Br)=C1Br NHJTVHYSKQMRDG-UHFFFAOYSA-N 0.000 description 1
- WQONPSCCEXUXTQ-UHFFFAOYSA-N 1,2-dibromobenzene Chemical compound BrC1=CC=CC=C1Br WQONPSCCEXUXTQ-UHFFFAOYSA-N 0.000 description 1
- UWTUEMKLYAGTNQ-UHFFFAOYSA-N 1,2-dibromoethene Chemical group BrC=CBr UWTUEMKLYAGTNQ-UHFFFAOYSA-N 0.000 description 1
- QGZAUMUFTXCDBD-UHFFFAOYSA-N 1,2-dibromonaphthalene Chemical compound C1=CC=CC2=C(Br)C(Br)=CC=C21 QGZAUMUFTXCDBD-UHFFFAOYSA-N 0.000 description 1
- HAOYIMQQADJKJN-UHFFFAOYSA-N 1,2-dichloro-3,4-bis(ethenyl)benzene Chemical compound C(=C)C1=C(C(=C(C=C1)Cl)Cl)C=C HAOYIMQQADJKJN-UHFFFAOYSA-N 0.000 description 1
- LPZAVKHEMKLMRI-UHFFFAOYSA-N 1,2-dichloro-3-(2-phenylphenyl)benzene Chemical group ClC=1C(=C(C=CC=1)C=1C(=CC=CC=1)C1=CC=CC=C1)Cl LPZAVKHEMKLMRI-UHFFFAOYSA-N 0.000 description 1
- RCMGXARQSFXMPO-UHFFFAOYSA-N 1,2-dichloro-3-prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC(Cl)=C1Cl RCMGXARQSFXMPO-UHFFFAOYSA-N 0.000 description 1
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- VPBZZPOGZPKYKX-UHFFFAOYSA-N 1,2-diethoxypropane Chemical compound CCOCC(C)OCC VPBZZPOGZPKYKX-UHFFFAOYSA-N 0.000 description 1
- IFKOHNNMBNGVJQ-UHFFFAOYSA-N 1,2-difluoro-3-(2-phenylphenyl)benzene Chemical group FC1=C(C=CC=C1F)C=1C(=CC=CC=1)C1=CC=CC=C1 IFKOHNNMBNGVJQ-UHFFFAOYSA-N 0.000 description 1
- OAECWKYXBMRZTA-UHFFFAOYSA-N 1,2-difluoro-3-prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC(F)=C1F OAECWKYXBMRZTA-UHFFFAOYSA-N 0.000 description 1
- GOYDNIKZWGIXJT-UHFFFAOYSA-N 1,2-difluorobenzene Chemical compound FC1=CC=CC=C1F GOYDNIKZWGIXJT-UHFFFAOYSA-N 0.000 description 1
- WFLOTYSKFUPZQB-UHFFFAOYSA-N 1,2-difluoroethene Chemical group FC=CF WFLOTYSKFUPZQB-UHFFFAOYSA-N 0.000 description 1
- PDHDZHIJGXQIIH-UHFFFAOYSA-N 1,2-difluoronaphthalene Chemical compound C1=CC=CC2=C(F)C(F)=CC=C21 PDHDZHIJGXQIIH-UHFFFAOYSA-N 0.000 description 1
- ZTNJGMFHJYGMDR-UHFFFAOYSA-N 1,2-diisocyanatoethane Chemical compound O=C=NCCN=C=O ZTNJGMFHJYGMDR-UHFFFAOYSA-N 0.000 description 1
- LEEANUDEDHYDTG-UHFFFAOYSA-N 1,2-dimethoxypropane Chemical compound COCC(C)OC LEEANUDEDHYDTG-UHFFFAOYSA-N 0.000 description 1
- BQOUBESKDQLUBN-UHFFFAOYSA-N 1,2-diphenylbenzene;urea Chemical compound NC(N)=O.C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1.C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1 BQOUBESKDQLUBN-UHFFFAOYSA-N 0.000 description 1
- PVMMVWNXKOSPRB-UHFFFAOYSA-N 1,2-dipropoxypropane Chemical compound CCCOCC(C)OCCC PVMMVWNXKOSPRB-UHFFFAOYSA-N 0.000 description 1
- 229940015975 1,2-hexanediol Drugs 0.000 description 1
- 229940031723 1,2-octanediol Drugs 0.000 description 1
- ACCWHMPSEBZRPM-UHFFFAOYSA-N 1,3-bis(2,3,4-tributylphenyl)urea Chemical compound CCCCC1=C(CCCC)C(CCCC)=CC=C1NC(=O)NC1=CC=C(CCCC)C(CCCC)=C1CCCC ACCWHMPSEBZRPM-UHFFFAOYSA-N 0.000 description 1
- JBLQXGFSCYVSDP-UHFFFAOYSA-N 1,3-bis(2,3,4-triethylphenyl)urea Chemical compound CCC1=C(CC)C(CC)=CC=C1NC(=O)NC1=CC=C(CC)C(CC)=C1CC JBLQXGFSCYVSDP-UHFFFAOYSA-N 0.000 description 1
- MCTYOWLBIDRXQE-UHFFFAOYSA-N 1,3-bis(2,3,4-trimethylphenyl)urea Chemical compound CC1=C(C)C(C)=CC=C1NC(=O)NC1=CC=C(C)C(C)=C1C MCTYOWLBIDRXQE-UHFFFAOYSA-N 0.000 description 1
- QACRFRUEBVFQCS-UHFFFAOYSA-N 1,3-bis(2,3,4-tripropylphenyl)urea Chemical compound CCCC1=C(CCC)C(CCC)=CC=C1NC(=O)NC1=CC=C(CCC)C(CCC)=C1CCC QACRFRUEBVFQCS-UHFFFAOYSA-N 0.000 description 1
- OSOWOBRRZRZHMP-UHFFFAOYSA-N 1,3-bis(2,3-dibutylphenyl)urea Chemical compound CCCCC1=CC=CC(NC(=O)NC=2C(=C(CCCC)C=CC=2)CCCC)=C1CCCC OSOWOBRRZRZHMP-UHFFFAOYSA-N 0.000 description 1
- BDSBVAYAFIFSLF-UHFFFAOYSA-N 1,3-bis(2,3-diethylphenyl)urea Chemical compound CCC1=CC=CC(NC(=O)NC=2C(=C(CC)C=CC=2)CC)=C1CC BDSBVAYAFIFSLF-UHFFFAOYSA-N 0.000 description 1
- LBWQSWVGFUBKDA-UHFFFAOYSA-N 1,3-bis(2,3-diheptylphenyl)urea Chemical compound CCCCCCCC1=CC=CC(NC(=O)NC=2C(=C(CCCCCCC)C=CC=2)CCCCCCC)=C1CCCCCCC LBWQSWVGFUBKDA-UHFFFAOYSA-N 0.000 description 1
- ORRNKACWMOVBCC-UHFFFAOYSA-N 1,3-bis(2,3-dihexylphenyl)urea Chemical compound CCCCCCC1=CC=CC(NC(=O)NC=2C(=C(CCCCCC)C=CC=2)CCCCCC)=C1CCCCCC ORRNKACWMOVBCC-UHFFFAOYSA-N 0.000 description 1
- KHCOIYBYWANAGX-UHFFFAOYSA-N 1,3-bis(2,3-dimethylphenyl)urea Chemical compound CC1=CC=CC(NC(=O)NC=2C(=C(C)C=CC=2)C)=C1C KHCOIYBYWANAGX-UHFFFAOYSA-N 0.000 description 1
- ANVMELZMVMGVSR-UHFFFAOYSA-N 1,3-bis(2,3-dipentylphenyl)urea Chemical compound CCCCCC1=CC=CC(NC(=O)NC=2C(=C(CCCCC)C=CC=2)CCCCC)=C1CCCCC ANVMELZMVMGVSR-UHFFFAOYSA-N 0.000 description 1
- HCTLPBCJAKKFQC-UHFFFAOYSA-N 1,3-bis(2-butylphenyl)urea Chemical compound CCCCC1=CC=CC=C1NC(=O)NC1=CC=CC=C1CCCC HCTLPBCJAKKFQC-UHFFFAOYSA-N 0.000 description 1
- LBGRGGSUUPQZTO-UHFFFAOYSA-N 1,3-bis(2-decylphenyl)urea Chemical compound CCCCCCCCCCC1=CC=CC=C1NC(=O)NC1=CC=CC=C1CCCCCCCCCC LBGRGGSUUPQZTO-UHFFFAOYSA-N 0.000 description 1
- IOBPNRZCZZMQPG-UHFFFAOYSA-N 1,3-bis(2-ethylphenyl)urea Chemical compound CCC1=CC=CC=C1NC(=O)NC1=CC=CC=C1CC IOBPNRZCZZMQPG-UHFFFAOYSA-N 0.000 description 1
- RZBXRATWMFWFJW-UHFFFAOYSA-N 1,3-bis(2-heptylphenyl)urea Chemical compound CCCCCCCC1=CC=CC=C1NC(=O)NC1=CC=CC=C1CCCCCCC RZBXRATWMFWFJW-UHFFFAOYSA-N 0.000 description 1
- HCMVEICAMAOWHP-UHFFFAOYSA-N 1,3-bis(2-hexylphenyl)urea Chemical compound CCCCCCC1=CC=CC=C1NC(=O)NC1=CC=CC=C1CCCCCC HCMVEICAMAOWHP-UHFFFAOYSA-N 0.000 description 1
- WVYBLYKUAKXDLA-UHFFFAOYSA-N 1,3-bis(2-methylphenyl)urea Chemical compound CC1=CC=CC=C1NC(=O)NC1=CC=CC=C1C WVYBLYKUAKXDLA-UHFFFAOYSA-N 0.000 description 1
- VDUWXNKQQGUTJF-UHFFFAOYSA-N 1,3-bis(2-nonylphenyl)urea Chemical compound C(CCCCCCCC)C1=C(C=CC=C1)NC(=O)NC1=C(C=CC=C1)CCCCCCCCC VDUWXNKQQGUTJF-UHFFFAOYSA-N 0.000 description 1
- DRJMDXBVXHEJMF-UHFFFAOYSA-N 1,3-bis(2-octylphenyl)urea Chemical compound CCCCCCCCC1=CC=CC=C1NC(=O)NC1=CC=CC=C1CCCCCCCC DRJMDXBVXHEJMF-UHFFFAOYSA-N 0.000 description 1
- VZPUSZCMPKROED-UHFFFAOYSA-N 1,3-bis(2-pentylphenyl)urea Chemical compound CCCCCC1=CC=CC=C1NC(=O)NC1=CC=CC=C1CCCCC VZPUSZCMPKROED-UHFFFAOYSA-N 0.000 description 1
- VMQLWVGHPWFHEI-UHFFFAOYSA-N 1,3-bis(2-phenylethyl)urea Chemical compound C=1C=CC=CC=1CCNC(=O)NCCC1=CC=CC=C1 VMQLWVGHPWFHEI-UHFFFAOYSA-N 0.000 description 1
- VHCPTKZAEKPMCE-UHFFFAOYSA-N 1,3-bis(2-propylphenyl)urea Chemical compound CCCC1=CC=CC=C1NC(=O)NC1=CC=CC=C1CCC VHCPTKZAEKPMCE-UHFFFAOYSA-N 0.000 description 1
- IUDNSGHPXXHSSI-UHFFFAOYSA-N 1,3-bis(3-phenylpropyl)urea Chemical compound C=1C=CC=CC=1CCCNC(=O)NCCCC1=CC=CC=C1 IUDNSGHPXXHSSI-UHFFFAOYSA-N 0.000 description 1
- JBYWYDXWKRAFSU-UHFFFAOYSA-N 1,3-bis(4-phenylbutyl)urea Chemical compound C=1C=CC=CC=1CCCCNC(=O)NCCCCC1=CC=CC=C1 JBYWYDXWKRAFSU-UHFFFAOYSA-N 0.000 description 1
- YNHPDWDLRXOCMR-UHFFFAOYSA-N 1,3-bis(6-phenylhexyl)urea Chemical compound C=1C=CC=CC=1CCCCCCNC(=O)NCCCCCCC1=CC=CC=C1 YNHPDWDLRXOCMR-UHFFFAOYSA-N 0.000 description 1
- CFUSTHBYRREFQK-UHFFFAOYSA-N 1,3-bis(7-phenylheptyl)urea Chemical compound C=1C=CC=CC=1CCCCCCCNC(=O)NCCCCCCCC1=CC=CC=C1 CFUSTHBYRREFQK-UHFFFAOYSA-N 0.000 description 1
- WODYGWNMILMWFE-UHFFFAOYSA-N 1,3-bis(8-phenyloctyl)urea Chemical compound C=1C=CC=CC=1CCCCCCCCNC(=O)NCCCCCCCCC1=CC=CC=C1 WODYGWNMILMWFE-UHFFFAOYSA-N 0.000 description 1
- HWUYSWZVLDYIJD-UHFFFAOYSA-N 1,3-bis(9-phenylnonyl)urea Chemical compound C=1C=CC=CC=1CCCCCCCCCNC(=O)NCCCCCCCCCC1=CC=CC=C1 HWUYSWZVLDYIJD-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- KJLAFMAXPKFAGP-UHFFFAOYSA-N 1,3-di(heptadecyl)urea Chemical compound C(CCCCCCCCCCCCCCCC)NC(NCCCCCCCCCCCCCCCCC)=O KJLAFMAXPKFAGP-UHFFFAOYSA-N 0.000 description 1
- GLXYJUVUMIMHNV-UHFFFAOYSA-N 1,3-di(pentadecyl)urea Chemical compound C(CCCCCCCCCCCCCC)NC(=O)NCCCCCCCCCCCCCCC GLXYJUVUMIMHNV-UHFFFAOYSA-N 0.000 description 1
- YQKDMDVDMWPYTF-UHFFFAOYSA-N 1,3-di(tetradecyl)urea Chemical compound CCCCCCCCCCCCCCNC(=O)NCCCCCCCCCCCCCC YQKDMDVDMWPYTF-UHFFFAOYSA-N 0.000 description 1
- ADPZFOVTYVSORN-UHFFFAOYSA-N 1,3-di(tridecyl)urea Chemical compound CCCCCCCCCCCCCNC(=O)NCCCCCCCCCCCCC ADPZFOVTYVSORN-UHFFFAOYSA-N 0.000 description 1
- IRGYLBTYWVEHFW-UHFFFAOYSA-N 1,3-di(undecyl)urea Chemical compound CCCCCCCCCCCNC(=O)NCCCCCCCCCCC IRGYLBTYWVEHFW-UHFFFAOYSA-N 0.000 description 1
- KATOLVAXCGIBLO-UHFFFAOYSA-N 1,3-dibenzylurea Chemical compound C=1C=CC=CC=1CNC(=O)NCC1=CC=CC=C1 KATOLVAXCGIBLO-UHFFFAOYSA-N 0.000 description 1
- AQSQFWLMFCKKMG-UHFFFAOYSA-N 1,3-dibutylurea Chemical compound CCCCNC(=O)NCCCC AQSQFWLMFCKKMG-UHFFFAOYSA-N 0.000 description 1
- AMCBMCWLCDERHY-UHFFFAOYSA-N 1,3-dichloronaphthalene Chemical compound C1=CC=CC2=CC(Cl)=CC(Cl)=C21 AMCBMCWLCDERHY-UHFFFAOYSA-N 0.000 description 1
- YLOGJPLTYYDQCN-UHFFFAOYSA-N 1,3-didodecylurea Chemical compound CCCCCCCCCCCCNC(=O)NCCCCCCCCCCCC YLOGJPLTYYDQCN-UHFFFAOYSA-N 0.000 description 1
- YIPGJIPRXFGTCH-UHFFFAOYSA-N 1,3-diheptylurea Chemical compound CCCCCCCNC(=O)NCCCCCCC YIPGJIPRXFGTCH-UHFFFAOYSA-N 0.000 description 1
- NMNHNRDWIVEISI-UHFFFAOYSA-N 1,3-dihexadecylurea Chemical compound CCCCCCCCCCCCCCCCNC(=O)NCCCCCCCCCCCCCCCC NMNHNRDWIVEISI-UHFFFAOYSA-N 0.000 description 1
- AOZVWUCYHOWWPH-UHFFFAOYSA-N 1,3-dioctadecylurea Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)NCCCCCCCCCCCCCCCCCC AOZVWUCYHOWWPH-UHFFFAOYSA-N 0.000 description 1
- GWEHVDNNLFDJLR-UHFFFAOYSA-N 1,3-diphenylurea Chemical compound C=1C=CC=CC=1NC(=O)NC1=CC=CC=C1 GWEHVDNNLFDJLR-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- JDDQNFPRBVOWJI-UHFFFAOYSA-N 1,5-dibromo-2,3,4-trimethoxy-6-prop-2-enylbenzene Chemical compound BrC1=C(C(=C(C(=C1OC)OC)OC)Br)CC=C JDDQNFPRBVOWJI-UHFFFAOYSA-N 0.000 description 1
- VWJOEUBPMHYJPO-UHFFFAOYSA-N 1,5-dichloro-2,3,4-trimethoxy-6-prop-2-enylbenzene Chemical compound ClC1=C(C(=C(C(=C1OC)OC)OC)Cl)CC=C VWJOEUBPMHYJPO-UHFFFAOYSA-N 0.000 description 1
- HIVOVDWEGFIBBF-UHFFFAOYSA-N 1,5-difluoro-2,3,4-trimethoxy-6-prop-2-enylbenzene Chemical compound FC1=C(C(=C(C(=C1OC)OC)OC)F)CC=C HIVOVDWEGFIBBF-UHFFFAOYSA-N 0.000 description 1
- OOQGZTBCTIWDJF-UHFFFAOYSA-N 1-(1,2-dibromo-1-phenylethyl)-2-methylbenzene Chemical compound BrCC(C1=CC=CC=C1)(C1=C(C=CC=C1)C)Br OOQGZTBCTIWDJF-UHFFFAOYSA-N 0.000 description 1
- KHYNYWWKDIOKIV-UHFFFAOYSA-N 1-(1,2-dichloro-1-phenylethyl)-2-methylbenzene Chemical compound ClCC(C1=CC=CC=C1)(C1=C(C=CC=C1)C)Cl KHYNYWWKDIOKIV-UHFFFAOYSA-N 0.000 description 1
- QVPXWMCSLBAVRO-UHFFFAOYSA-N 1-(1,2-difluoro-1-phenylethyl)-2-methylbenzene Chemical compound FCC(C1=CC=CC=C1)(C1=C(C=CC=C1)C)F QVPXWMCSLBAVRO-UHFFFAOYSA-N 0.000 description 1
- FQUIWFVBXQDCRZ-UHFFFAOYSA-N 1-(1-chloro-1-phenylethyl)-2-methylbenzene Chemical compound ClC(C)(C1=CC=CC=C1)C1=C(C=CC=C1)C FQUIWFVBXQDCRZ-UHFFFAOYSA-N 0.000 description 1
- WXAVSTZWKNIWCN-UHFFFAOYSA-N 1-(1-phenylethoxy)ethylbenzene Chemical class C=1C=CC=CC=1C(C)OC(C)C1=CC=CC=C1 WXAVSTZWKNIWCN-UHFFFAOYSA-N 0.000 description 1
- NTKXWHALINJHQX-UHFFFAOYSA-N 1-(1-phenylethylsulfanyl)ethylbenzene Chemical compound C=1C=CC=CC=1C(C)SC(C)C1=CC=CC=C1 NTKXWHALINJHQX-UHFFFAOYSA-N 0.000 description 1
- ABWFFTHMMUPNPK-UHFFFAOYSA-N 1-(1-phenylheptoxy)heptylbenzene Chemical class C=1C=CC=CC=1C(CCCCCC)OC(CCCCCC)C1=CC=CC=C1 ABWFFTHMMUPNPK-UHFFFAOYSA-N 0.000 description 1
- ONZGDFNNPZIIPQ-UHFFFAOYSA-N 1-(1-phenylheptylsulfanyl)heptylbenzene Chemical compound C=1C=CC=CC=1C(CCCCCC)SC(CCCCCC)C1=CC=CC=C1 ONZGDFNNPZIIPQ-UHFFFAOYSA-N 0.000 description 1
- AUWXASLZAWSIDA-UHFFFAOYSA-N 1-(1-phenylhexoxy)hexylbenzene Chemical class C=1C=CC=CC=1C(CCCCC)OC(CCCCC)C1=CC=CC=C1 AUWXASLZAWSIDA-UHFFFAOYSA-N 0.000 description 1
- LUCSUILYURWCHS-UHFFFAOYSA-N 1-(1-phenylhexylsulfanyl)hexylbenzene Chemical compound C=1C=CC=CC=1C(CCCCC)SC(CCCCC)C1=CC=CC=C1 LUCSUILYURWCHS-UHFFFAOYSA-N 0.000 description 1
- RKOUZUVPTGTSMO-UHFFFAOYSA-N 1-(1-phenylnonoxy)nonylbenzene Chemical class C=1C=CC=CC=1C(CCCCCCCC)OC(CCCCCCCC)C1=CC=CC=C1 RKOUZUVPTGTSMO-UHFFFAOYSA-N 0.000 description 1
- GSOXINXEFXLXGS-UHFFFAOYSA-N 1-(1-phenylnonylsulfanyl)nonylbenzene Chemical compound C=1C=CC=CC=1C(CCCCCCCC)SC(CCCCCCCC)C1=CC=CC=C1 GSOXINXEFXLXGS-UHFFFAOYSA-N 0.000 description 1
- HCLKISWJKHBFND-UHFFFAOYSA-N 1-(1-phenylpentoxy)pentylbenzene Chemical class C=1C=CC=CC=1C(CCCC)OC(CCCC)C1=CC=CC=C1 HCLKISWJKHBFND-UHFFFAOYSA-N 0.000 description 1
- WUHROALPZRIHIX-UHFFFAOYSA-N 1-(1-phenylpentylsulfanyl)pentylbenzene Chemical compound C=1C=CC=CC=1C(CCCC)SC(CCCC)C1=CC=CC=C1 WUHROALPZRIHIX-UHFFFAOYSA-N 0.000 description 1
- PGKLYHVOQICWSC-UHFFFAOYSA-N 1-(1-phenylpropoxy)propylbenzene Chemical class C=1C=CC=CC=1C(CC)OC(CC)C1=CC=CC=C1 PGKLYHVOQICWSC-UHFFFAOYSA-N 0.000 description 1
- WLIRDHRLKWCHCJ-UHFFFAOYSA-N 1-(1-phenylpropylsulfanyl)propylbenzene Chemical compound C=1C=CC=CC=1C(CC)SC(CC)C1=CC=CC=C1 WLIRDHRLKWCHCJ-UHFFFAOYSA-N 0.000 description 1
- WJCLCQFOLYOBDK-UHFFFAOYSA-N 1-(2,2-dibromoethyl)naphthalene Chemical compound C1=CC=C2C(CC(Br)Br)=CC=CC2=C1 WJCLCQFOLYOBDK-UHFFFAOYSA-N 0.000 description 1
- WHMXNINSAVQZDE-UHFFFAOYSA-N 1-(2,2-dichloroethenyl)-2-methoxybenzene Chemical compound COC1=CC=CC=C1C=C(Cl)Cl WHMXNINSAVQZDE-UHFFFAOYSA-N 0.000 description 1
- KPKVPDTYBTVWDF-UHFFFAOYSA-N 1-(2,2-dichloroethyl)naphthalene Chemical compound C1=CC=C2C(CC(Cl)Cl)=CC=CC2=C1 KPKVPDTYBTVWDF-UHFFFAOYSA-N 0.000 description 1
- ZHMNAPLVILMYIA-UHFFFAOYSA-N 1-(2,2-difluoroethenyl)-2-methoxybenzene Chemical compound COC1=CC=CC=C1C=C(F)F ZHMNAPLVILMYIA-UHFFFAOYSA-N 0.000 description 1
- BNNXVTCHXNVUJC-UHFFFAOYSA-N 1-(2,2-difluoroethyl)naphthalene Chemical compound C1=CC=C2C(CC(F)F)=CC=CC2=C1 BNNXVTCHXNVUJC-UHFFFAOYSA-N 0.000 description 1
- QVLGTXPQVOQRLD-UHFFFAOYSA-N 1-(2-bromoethenyl)-2-methoxybenzene Chemical compound COC1=CC=CC=C1C=CBr QVLGTXPQVOQRLD-UHFFFAOYSA-N 0.000 description 1
- GDXHBFHOEYVPED-UHFFFAOYSA-N 1-(2-butoxyethoxy)butane Chemical compound CCCCOCCOCCCC GDXHBFHOEYVPED-UHFFFAOYSA-N 0.000 description 1
- QMGJMGFZLXYHCR-UHFFFAOYSA-N 1-(2-butoxypropoxy)butane Chemical compound CCCCOCC(C)OCCCC QMGJMGFZLXYHCR-UHFFFAOYSA-N 0.000 description 1
- RWRFBKIDWTWLIO-UHFFFAOYSA-N 1-(2-chloroethenyl)-2-methoxybenzene Chemical compound ClC=CC1=C(C=CC=C1)OC RWRFBKIDWTWLIO-UHFFFAOYSA-N 0.000 description 1
- COIBFCUQUWJKEN-UHFFFAOYSA-N 1-(2-chloroethyl)naphthalene Chemical compound C1=CC=C2C(CCCl)=CC=CC2=C1 COIBFCUQUWJKEN-UHFFFAOYSA-N 0.000 description 1
- GSMWSGHITUFGKX-UHFFFAOYSA-N 1-(2-methylhexan-3-yloxy)propan-2-ol Chemical compound C(C)(C)C(CCC)OCC(C)O GSMWSGHITUFGKX-UHFFFAOYSA-N 0.000 description 1
- HQSLKNLISLWZQH-UHFFFAOYSA-N 1-(2-propoxyethoxy)propane Chemical compound CCCOCCOCCC HQSLKNLISLWZQH-UHFFFAOYSA-N 0.000 description 1
- ATNNZILFVKYDAI-UHFFFAOYSA-N 1-(3,3-dibromoprop-1-enyl)-2-methoxybenzene Chemical compound BrC(C=CC1=C(C=CC=C1)OC)Br ATNNZILFVKYDAI-UHFFFAOYSA-N 0.000 description 1
- NPAMNTLGCMMZRI-UHFFFAOYSA-N 1-(3,3-dichloroprop-1-enyl)-2-methoxybenzene Chemical compound ClC(C=CC1=C(C=CC=C1)OC)Cl NPAMNTLGCMMZRI-UHFFFAOYSA-N 0.000 description 1
- OSGDQVIHYBHFHF-UHFFFAOYSA-N 1-(3,3-difluoroprop-1-enyl)-2-methoxybenzene Chemical compound FC(C=CC1=C(C=CC=C1)OC)F OSGDQVIHYBHFHF-UHFFFAOYSA-N 0.000 description 1
- FYBQHHCDWXVPDF-UHFFFAOYSA-N 1-(3-bromoprop-1-enyl)-2-methoxybenzene Chemical compound COC1=CC=CC=C1C=CCBr FYBQHHCDWXVPDF-UHFFFAOYSA-N 0.000 description 1
- RXTIBZUJTOHSPJ-UHFFFAOYSA-N 1-(3-chloroprop-1-enyl)-2-methoxybenzene Chemical compound COC1=CC=CC=C1C=CCCl RXTIBZUJTOHSPJ-UHFFFAOYSA-N 0.000 description 1
- RVRZPYCGDGJFQZ-UHFFFAOYSA-N 1-(4,4-dichlorobutyl)naphthalene Chemical compound C1=CC=C2C(CCCC(Cl)Cl)=CC=CC2=C1 RVRZPYCGDGJFQZ-UHFFFAOYSA-N 0.000 description 1
- CIKFQQQXGYCEFK-UHFFFAOYSA-N 1-(4,4-difluorobutyl)naphthalene Chemical compound FC(CCCC1=CC=CC2=CC=CC=C12)F CIKFQQQXGYCEFK-UHFFFAOYSA-N 0.000 description 1
- PQGPPKUUDRWUKU-UHFFFAOYSA-N 1-(4-chlorobutyl)naphthalene Chemical compound C1=CC=C2C(CCCCCl)=CC=CC2=C1 PQGPPKUUDRWUKU-UHFFFAOYSA-N 0.000 description 1
- BVMYLIYGDBEEAX-UHFFFAOYSA-N 1-(Difluoromethyl)naphthalene Chemical compound C1=CC=C2C(C(F)F)=CC=CC2=C1 BVMYLIYGDBEEAX-UHFFFAOYSA-N 0.000 description 1
- VQMDIKQRLTVXEO-UHFFFAOYSA-N 1-(bromomethoxy)-2,3-dimethoxy-5-prop-2-enylbenzene Chemical compound BrCOC1=C(OC)C(OC)=CC(CC=C)=C1 VQMDIKQRLTVXEO-UHFFFAOYSA-N 0.000 description 1
- BMMMCQYYFJSEKH-UHFFFAOYSA-N 1-(chloromethoxy)-2,3-dimethoxy-5-prop-2-enylbenzene Chemical compound ClCOC1=C(OC)C(OC)=CC(CC=C)=C1 BMMMCQYYFJSEKH-UHFFFAOYSA-N 0.000 description 1
- XMWGTKZEDLCVIG-UHFFFAOYSA-N 1-(chloromethyl)naphthalene Chemical compound C1=CC=C2C(CCl)=CC=CC2=C1 XMWGTKZEDLCVIG-UHFFFAOYSA-N 0.000 description 1
- DYBVWMVJRMNQHW-UHFFFAOYSA-N 1-(dibromomethyl)naphthalene Chemical compound C1=CC=C2C(C(Br)Br)=CC=CC2=C1 DYBVWMVJRMNQHW-UHFFFAOYSA-N 0.000 description 1
- PENXUAAQSIVXBE-UHFFFAOYSA-N 1-(dichloromethyl)naphthalene Chemical compound C1=CC=C2C(C(Cl)Cl)=CC=CC2=C1 PENXUAAQSIVXBE-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- KZVBBTZJMSWGTK-UHFFFAOYSA-N 1-[2-(2-butoxyethoxy)ethoxy]butane Chemical compound CCCCOCCOCCOCCCC KZVBBTZJMSWGTK-UHFFFAOYSA-N 0.000 description 1
- UOWSVNMPHMJCBZ-UHFFFAOYSA-N 1-[2-(2-butoxypropoxy)propoxy]butane Chemical compound CCCCOCC(C)OCC(C)OCCCC UOWSVNMPHMJCBZ-UHFFFAOYSA-N 0.000 description 1
- PXQCQQARRAYIFS-UHFFFAOYSA-N 1-[2-(2-ethoxyethoxy)ethoxy]propane Chemical compound CCCOCCOCCOCC PXQCQQARRAYIFS-UHFFFAOYSA-N 0.000 description 1
- HYLLZXPMJRMUHH-UHFFFAOYSA-N 1-[2-(2-methoxyethoxy)ethoxy]butane Chemical compound CCCCOCCOCCOC HYLLZXPMJRMUHH-UHFFFAOYSA-N 0.000 description 1
- MBRRDORCFVPYMA-UHFFFAOYSA-N 1-[2-(2-methoxyethoxy)ethoxy]propane Chemical compound CCCOCCOCCOC MBRRDORCFVPYMA-UHFFFAOYSA-N 0.000 description 1
- BOGFHOWTVGAYFK-UHFFFAOYSA-N 1-[2-(2-propoxyethoxy)ethoxy]propane Chemical compound CCCOCCOCCOCCC BOGFHOWTVGAYFK-UHFFFAOYSA-N 0.000 description 1
- OSUGFRWHSFLXPG-UHFFFAOYSA-N 1-bromo-2,3-bis(ethenyl)benzene Chemical compound BrC1=CC=CC(C=C)=C1C=C OSUGFRWHSFLXPG-UHFFFAOYSA-N 0.000 description 1
- FRBANDMAHCQSMS-UHFFFAOYSA-N 1-bromo-2-(2-phenylethenyl)benzene Chemical compound BrC1=CC=CC=C1C=CC1=CC=CC=C1 FRBANDMAHCQSMS-UHFFFAOYSA-N 0.000 description 1
- XAJLFMOXQLPTIL-UHFFFAOYSA-N 1-bromo-2-prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1Br XAJLFMOXQLPTIL-UHFFFAOYSA-N 0.000 description 1
- HQJQYILBCQPYBI-UHFFFAOYSA-N 1-bromo-4-(4-bromophenyl)benzene Chemical group C1=CC(Br)=CC=C1C1=CC=C(Br)C=C1 HQJQYILBCQPYBI-UHFFFAOYSA-N 0.000 description 1
- IUXHPSPHPKXTPA-UHFFFAOYSA-N 1-bromobut-1-ene Chemical compound CCC=CBr IUXHPSPHPKXTPA-UHFFFAOYSA-N 0.000 description 1
- LKNKAEWGISYACD-UHFFFAOYSA-N 1-bromobuta-1,3-diene Chemical compound BrC=CC=C LKNKAEWGISYACD-UHFFFAOYSA-N 0.000 description 1
- SDUBGZLBHQJQQS-UHFFFAOYSA-N 1-bromobuta-1,3-dienylbenzene Chemical compound C=CC=C(Br)C1=CC=CC=C1 SDUBGZLBHQJQQS-UHFFFAOYSA-N 0.000 description 1
- PWJJHLRABLZGCK-UHFFFAOYSA-N 1-bromodec-1-ene Chemical compound CCCCCCCCC=CBr PWJJHLRABLZGCK-UHFFFAOYSA-N 0.000 description 1
- FBUZNPORDKVYFD-UHFFFAOYSA-N 1-bromohex-1-ene Chemical compound CCCCC=CBr FBUZNPORDKVYFD-UHFFFAOYSA-N 0.000 description 1
- ADPNZTCDHSGHOG-UHFFFAOYSA-N 1-bromohexa-1,3-diene Chemical compound CCC=CC=CBr ADPNZTCDHSGHOG-UHFFFAOYSA-N 0.000 description 1
- LFAGPDBOOVWORI-UHFFFAOYSA-N 1-bromohexadec-1-ene Chemical compound CCCCCCCCCCCCCCC=CBr LFAGPDBOOVWORI-UHFFFAOYSA-N 0.000 description 1
- MMUAEPCEWCXZTJ-UHFFFAOYSA-N 1-bromonon-1-ene Chemical compound CCCCCCCC=CBr MMUAEPCEWCXZTJ-UHFFFAOYSA-N 0.000 description 1
- WTCSRYZMCHRXLM-UHFFFAOYSA-N 1-bromooct-1-ene Chemical compound CCCCCCC=CBr WTCSRYZMCHRXLM-UHFFFAOYSA-N 0.000 description 1
- WSXIDSNEEOYBFA-UHFFFAOYSA-N 1-bromopent-1-ene Chemical compound CCCC=CBr WSXIDSNEEOYBFA-UHFFFAOYSA-N 0.000 description 1
- NEKANQSSYILWHA-UHFFFAOYSA-N 1-bromopenta-1,3-diene Chemical compound CC=CC=CBr NEKANQSSYILWHA-UHFFFAOYSA-N 0.000 description 1
- NNQDMQVWOWCVEM-UHFFFAOYSA-N 1-bromoprop-1-ene Chemical compound CC=CBr NNQDMQVWOWCVEM-UHFFFAOYSA-N 0.000 description 1
- HJWWCGJBRCSDPY-UHFFFAOYSA-N 1-butoxy-2-ethylbenzene Chemical compound CCCCOC1=CC=CC=C1CC HJWWCGJBRCSDPY-UHFFFAOYSA-N 0.000 description 1
- JRMXMUCILWKNNW-UHFFFAOYSA-N 1-butoxy-2-methylbenzene Chemical compound CCCCOC1=CC=CC=C1C JRMXMUCILWKNNW-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- CGTNCTXIQDWSOL-UHFFFAOYSA-N 1-butoxydecane Chemical compound CCCCCCCCCCOCCCC CGTNCTXIQDWSOL-UHFFFAOYSA-N 0.000 description 1
- GUMQAMJLPBGQLH-UHFFFAOYSA-N 1-butoxynonane Chemical compound CCCCCCCCCOCCCC GUMQAMJLPBGQLH-UHFFFAOYSA-N 0.000 description 1
- HLKBESQBAMRXPZ-UHFFFAOYSA-N 1-butoxyoctane Chemical compound CCCCCCCCOCCCC HLKBESQBAMRXPZ-UHFFFAOYSA-N 0.000 description 1
- FUWDFGKRNIDKAE-UHFFFAOYSA-N 1-butoxypropan-2-yl acetate Chemical compound CCCCOCC(C)OC(C)=O FUWDFGKRNIDKAE-UHFFFAOYSA-N 0.000 description 1
- VNGMSZNYZUBNBL-UHFFFAOYSA-N 1-butyl-2-(2-butylphenyl)sulfanylbenzene Chemical compound CCCCC1=CC=CC=C1SC1=CC=CC=C1CCCC VNGMSZNYZUBNBL-UHFFFAOYSA-N 0.000 description 1
- POPCPGJEDJSSFO-UHFFFAOYSA-N 1-butyl-2-decoxybenzene Chemical compound C(CCCCCCCCC)OC1=C(C=CC=C1)CCCC POPCPGJEDJSSFO-UHFFFAOYSA-N 0.000 description 1
- BIWACSGPFBWNHY-UHFFFAOYSA-N 1-butyl-2-nonoxybenzene Chemical compound C(CCC)C1=C(C=CC=C1)OCCCCCCCCC BIWACSGPFBWNHY-UHFFFAOYSA-N 0.000 description 1
- QAKGEILYTHKWCY-UHFFFAOYSA-N 1-butyl-2-octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1CCCC QAKGEILYTHKWCY-UHFFFAOYSA-N 0.000 description 1
- ZWUNPBJRZHGSPD-UHFFFAOYSA-N 1-butyl-2-phenoxybenzene Chemical class CCCCC1=CC=CC=C1OC1=CC=CC=C1 ZWUNPBJRZHGSPD-UHFFFAOYSA-N 0.000 description 1
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 1
- PXFUDTJLVXRPNF-UHFFFAOYSA-N 1-butyl-2-phenylsulfanylbenzene Chemical compound CCCCC1=CC=CC=C1SC1=CC=CC=C1 PXFUDTJLVXRPNF-UHFFFAOYSA-N 0.000 description 1
- CLBLVLKZMJDLOT-UHFFFAOYSA-N 1-butylsulfanyldecane Chemical compound CCCCCCCCCCSCCCC CLBLVLKZMJDLOT-UHFFFAOYSA-N 0.000 description 1
- YZUHMAFUXBPUKH-UHFFFAOYSA-N 1-butylsulfanylhexane Chemical compound CCCCCCSCCCC YZUHMAFUXBPUKH-UHFFFAOYSA-N 0.000 description 1
- FWRIVMHSSSZAFD-UHFFFAOYSA-N 1-butylsulfanylnonane Chemical compound CCCCCCCCCSCCCC FWRIVMHSSSZAFD-UHFFFAOYSA-N 0.000 description 1
- UNIAPWPIAGJFDG-UHFFFAOYSA-N 1-butylsulfanyloctane Chemical compound CCCCCCCCSCCCC UNIAPWPIAGJFDG-UHFFFAOYSA-N 0.000 description 1
- IROFMMHLTOVXFS-UHFFFAOYSA-N 1-chloro-2,3-bis(ethenyl)benzene Chemical compound ClC1=CC=CC(C=C)=C1C=C IROFMMHLTOVXFS-UHFFFAOYSA-N 0.000 description 1
- WTVKFPGVKKXUHG-UHFFFAOYSA-N 1-chloro-2-(2-phenylethenyl)benzene Chemical compound ClC1=CC=CC=C1C=CC1=CC=CC=C1 WTVKFPGVKKXUHG-UHFFFAOYSA-N 0.000 description 1
- JEXTXOAHCIIIKH-UHFFFAOYSA-N 1-chloro-2-(2-phenylphenyl)benzene Chemical group ClC1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1 JEXTXOAHCIIIKH-UHFFFAOYSA-N 0.000 description 1
- AAVXAQDZDGZZAO-UHFFFAOYSA-N 1-chloro-2-prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1Cl AAVXAQDZDGZZAO-UHFFFAOYSA-N 0.000 description 1
- DUDKKPVINWLFBI-UHFFFAOYSA-N 1-chlorobut-1-ene Chemical compound CCC=CCl DUDKKPVINWLFBI-UHFFFAOYSA-N 0.000 description 1
- KLDLECRWJRAFQH-UHFFFAOYSA-N 1-chlorobuta-1,3-dienylbenzene Chemical compound C=CC=C(Cl)C1=CC=CC=C1 KLDLECRWJRAFQH-UHFFFAOYSA-N 0.000 description 1
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
- FBECTVVCBRAZRM-UHFFFAOYSA-N 1-chlorodec-1-ene Chemical compound CCCCCCCCC=CCl FBECTVVCBRAZRM-UHFFFAOYSA-N 0.000 description 1
- ZTEHOZMYMCEYRM-UHFFFAOYSA-N 1-chlorodecane Chemical compound CCCCCCCCCCCl ZTEHOZMYMCEYRM-UHFFFAOYSA-N 0.000 description 1
- YAYNEUUHHLGGAH-UHFFFAOYSA-N 1-chlorododecane Chemical compound CCCCCCCCCCCCCl YAYNEUUHHLGGAH-UHFFFAOYSA-N 0.000 description 1
- DZMDPHNGKBEVRE-UHFFFAOYSA-N 1-chloroheptane Chemical compound CCCCCCCCl DZMDPHNGKBEVRE-UHFFFAOYSA-N 0.000 description 1
- UZIBPOIXTCIHBH-UHFFFAOYSA-N 1-chlorohex-1-ene Chemical compound CCCCC=CCl UZIBPOIXTCIHBH-UHFFFAOYSA-N 0.000 description 1
- YNHSMXYDYCINCR-UHFFFAOYSA-N 1-chlorohexa-1,3-diene Chemical compound CCC=CC=CCl YNHSMXYDYCINCR-UHFFFAOYSA-N 0.000 description 1
- SRITYGSDILBHBS-UHFFFAOYSA-N 1-chlorohexadec-1-ene Chemical compound CCCCCCCCCCCCCCC=CCl SRITYGSDILBHBS-UHFFFAOYSA-N 0.000 description 1
- CLWAXFZCVYJLLM-UHFFFAOYSA-N 1-chlorohexadecane Chemical compound CCCCCCCCCCCCCCCCCl CLWAXFZCVYJLLM-UHFFFAOYSA-N 0.000 description 1
- MLRVZFYXUZQSRU-UHFFFAOYSA-N 1-chlorohexane Chemical compound CCCCCCCl MLRVZFYXUZQSRU-UHFFFAOYSA-N 0.000 description 1
- JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 1
- DPFHKZQZYLXEKH-UHFFFAOYSA-N 1-chloronon-1-ene Chemical compound CCCCCCCC=CCl DPFHKZQZYLXEKH-UHFFFAOYSA-N 0.000 description 1
- ZPHKHTAJPZOPHM-UHFFFAOYSA-N 1-chlorononadecane Chemical compound CCCCCCCCCCCCCCCCCCCCl ZPHKHTAJPZOPHM-UHFFFAOYSA-N 0.000 description 1
- RKAMCQVGHFRILV-UHFFFAOYSA-N 1-chlorononane Chemical compound CCCCCCCCCCl RKAMCQVGHFRILV-UHFFFAOYSA-N 0.000 description 1
- MXUOKRUYNYDCDL-UHFFFAOYSA-N 1-chlorooct-1-ene Chemical compound CCCCCCC=CCl MXUOKRUYNYDCDL-UHFFFAOYSA-N 0.000 description 1
- RDFOBGBTABWBDM-UHFFFAOYSA-N 1-chlorooctadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=CCl RDFOBGBTABWBDM-UHFFFAOYSA-N 0.000 description 1
- VUQPJRPDRDVQMN-UHFFFAOYSA-N 1-chlorooctadecane Chemical compound CCCCCCCCCCCCCCCCCCCl VUQPJRPDRDVQMN-UHFFFAOYSA-N 0.000 description 1
- CNDHHGUSRIZDSL-UHFFFAOYSA-N 1-chlorooctane Chemical compound CCCCCCCCCl CNDHHGUSRIZDSL-UHFFFAOYSA-N 0.000 description 1
- NKNYZKFBNQUWTM-UHFFFAOYSA-N 1-chloropent-1-ene Chemical compound CCCC=CCl NKNYZKFBNQUWTM-UHFFFAOYSA-N 0.000 description 1
- PEUWKAAVXXUTRM-UHFFFAOYSA-N 1-chloropenta-1,3-diene Chemical compound CC=CC=CCl PEUWKAAVXXUTRM-UHFFFAOYSA-N 0.000 description 1
- WFDSCHJVWDKDFK-UHFFFAOYSA-N 1-chloropentadecane Chemical compound CCCCCCCCCCCCCCCCl WFDSCHJVWDKDFK-UHFFFAOYSA-N 0.000 description 1
- SQCZQTSHSZLZIQ-UHFFFAOYSA-N 1-chloropentane Chemical compound CCCCCCl SQCZQTSHSZLZIQ-UHFFFAOYSA-N 0.000 description 1
- RNHWYOLIEJIAMV-UHFFFAOYSA-N 1-chlorotetradecane Chemical compound CCCCCCCCCCCCCCCl RNHWYOLIEJIAMV-UHFFFAOYSA-N 0.000 description 1
- KYNCQOOPQKRSTR-UHFFFAOYSA-N 1-decoxy-2-methylbenzene Chemical compound CCCCCCCCCCOC1=CC=CC=C1C KYNCQOOPQKRSTR-UHFFFAOYSA-N 0.000 description 1
- RKYMVQJWYYOIJB-UHFFFAOYSA-N 1-decylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCCCC RKYMVQJWYYOIJB-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- CNJRPYFBORAQAU-UHFFFAOYSA-N 1-ethoxy-2-(2-methoxyethoxy)ethane Chemical compound CCOCCOCCOC CNJRPYFBORAQAU-UHFFFAOYSA-N 0.000 description 1
- JXFITNNCZLPZNX-UHFFFAOYSA-N 1-ethoxy-2-(2-methoxypropoxy)propane Chemical compound CCOCC(C)OCC(C)OC JXFITNNCZLPZNX-UHFFFAOYSA-N 0.000 description 1
- OSMLONWXLNJOPG-UHFFFAOYSA-N 1-ethoxy-2-ethylbenzene Chemical compound CCOC1=CC=CC=C1CC OSMLONWXLNJOPG-UHFFFAOYSA-N 0.000 description 1
- CAQYAZNFWDDMIT-UHFFFAOYSA-N 1-ethoxy-2-methoxyethane Chemical compound CCOCCOC CAQYAZNFWDDMIT-UHFFFAOYSA-N 0.000 description 1
- JWMKUKRBNODZFA-UHFFFAOYSA-N 1-ethoxy-2-methylbenzene Chemical compound CCOC1=CC=CC=C1C JWMKUKRBNODZFA-UHFFFAOYSA-N 0.000 description 1
- JHTZSSLGAWBJBR-UHFFFAOYSA-N 1-ethoxy-2-propan-2-yloxypropane Chemical compound CCOCC(C)OC(C)C JHTZSSLGAWBJBR-UHFFFAOYSA-N 0.000 description 1
- PZHIWRCQKBBTOW-UHFFFAOYSA-N 1-ethoxybutane Chemical compound CCCCOCC PZHIWRCQKBBTOW-UHFFFAOYSA-N 0.000 description 1
- LOLANUHFGPZTLQ-UHFFFAOYSA-N 1-ethoxydecane Chemical compound CCCCCCCCCCOCC LOLANUHFGPZTLQ-UHFFFAOYSA-N 0.000 description 1
- WJVJBXHEMGVIMM-UHFFFAOYSA-N 1-ethoxyoctane Chemical compound CCCCCCCCOCC WJVJBXHEMGVIMM-UHFFFAOYSA-N 0.000 description 1
- LIPRQQHINVWJCH-UHFFFAOYSA-N 1-ethoxypropan-2-yl acetate Chemical compound CCOCC(C)OC(C)=O LIPRQQHINVWJCH-UHFFFAOYSA-N 0.000 description 1
- NVJUHMXYKCUMQA-UHFFFAOYSA-N 1-ethoxypropane Chemical compound CCCOCC NVJUHMXYKCUMQA-UHFFFAOYSA-N 0.000 description 1
- YIMFCJMGPKCUNS-UHFFFAOYSA-N 1-ethyl-2-(2-ethylphenoxy)benzene Chemical class CCC1=CC=CC=C1OC1=CC=CC=C1CC YIMFCJMGPKCUNS-UHFFFAOYSA-N 0.000 description 1
- OGCNSPNRVQDSNZ-UHFFFAOYSA-N 1-ethyl-2-(2-ethylphenyl)sulfanylbenzene Chemical compound CCC1=CC=CC=C1SC1=CC=CC=C1CC OGCNSPNRVQDSNZ-UHFFFAOYSA-N 0.000 description 1
- KFVSWHWZOQRCCS-UHFFFAOYSA-N 1-ethyl-2-nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1CC KFVSWHWZOQRCCS-UHFFFAOYSA-N 0.000 description 1
- FVPJKVZEXJOOJP-UHFFFAOYSA-N 1-ethyl-2-octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1CC FVPJKVZEXJOOJP-UHFFFAOYSA-N 0.000 description 1
- OZULZIWPUGFZCY-UHFFFAOYSA-N 1-ethyl-2-phenoxybenzene Chemical class CCC1=CC=CC=C1OC1=CC=CC=C1 OZULZIWPUGFZCY-UHFFFAOYSA-N 0.000 description 1
- LFIXDNGUDLUZPX-UHFFFAOYSA-N 1-ethyl-2-phenylsulfanylbenzene Chemical compound CCC1=CC=CC=C1SC1=CC=CC=C1 LFIXDNGUDLUZPX-UHFFFAOYSA-N 0.000 description 1
- XJIRSLHMKBUGMR-UHFFFAOYSA-N 1-ethylsulfanylbutane Chemical compound CCCCSCC XJIRSLHMKBUGMR-UHFFFAOYSA-N 0.000 description 1
- VSSRSPLEFYQIEK-UHFFFAOYSA-N 1-ethylsulfanyldecane Chemical compound CCCCCCCCCCSCC VSSRSPLEFYQIEK-UHFFFAOYSA-N 0.000 description 1
- LUAABLIRQSWMGZ-UHFFFAOYSA-N 1-ethylsulfanylnonane Chemical compound CCCCCCCCCSCC LUAABLIRQSWMGZ-UHFFFAOYSA-N 0.000 description 1
- WAITXWGCJQLPGH-UHFFFAOYSA-N 1-ethylsulfanyloctane Chemical compound CCCCCCCCSCC WAITXWGCJQLPGH-UHFFFAOYSA-N 0.000 description 1
- PZDAAZQDQJGXSW-UHFFFAOYSA-N 1-fluoro-4-(4-fluorophenyl)benzene Chemical group C1=CC(F)=CC=C1C1=CC=C(F)C=C1 PZDAAZQDQJGXSW-UHFFFAOYSA-N 0.000 description 1
- WFOIWBGKCSYBJN-UHFFFAOYSA-N 1-fluorobut-1-ene Chemical compound CCC=CF WFOIWBGKCSYBJN-UHFFFAOYSA-N 0.000 description 1
- RZBKDLVWLNAKAJ-UHFFFAOYSA-N 1-fluorohex-1-ene Chemical compound CCCCC=CF RZBKDLVWLNAKAJ-UHFFFAOYSA-N 0.000 description 1
- DGSSLUGSBNCKBU-UHFFFAOYSA-N 1-fluoropenta-1,3-diene Chemical compound CC=CC=CF DGSSLUGSBNCKBU-UHFFFAOYSA-N 0.000 description 1
- VJGCZWVJDRIHNC-UHFFFAOYSA-N 1-fluoroprop-1-ene Chemical compound CC=CF VJGCZWVJDRIHNC-UHFFFAOYSA-N 0.000 description 1
- MCUPSZIPZGVKIB-UHFFFAOYSA-N 1-heptan-4-yloxypropan-2-ol Chemical compound C(CC)C(CCC)OCC(C)O MCUPSZIPZGVKIB-UHFFFAOYSA-N 0.000 description 1
- UVQCDDWFPNPHEQ-UHFFFAOYSA-N 1-hexan-3-yloxypropan-2-ol Chemical compound C(C)C(CCC)OCC(C)O UVQCDDWFPNPHEQ-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- GVXVYGRPSBFIBS-UHFFFAOYSA-N 1-hexyl-2-(2-hexylphenoxy)benzene Chemical class CCCCCCC1=CC=CC=C1OC1=CC=CC=C1CCCCCC GVXVYGRPSBFIBS-UHFFFAOYSA-N 0.000 description 1
- OIKDAZIOEMIVDW-UHFFFAOYSA-N 1-hexyl-2-phenoxybenzene Chemical class CCCCCCC1=CC=CC=C1OC1=CC=CC=C1 OIKDAZIOEMIVDW-UHFFFAOYSA-N 0.000 description 1
- FSQFYRSMQZXJTP-UHFFFAOYSA-N 1-hexyl-2-phenylsulfanylbenzene Chemical compound C1(=CC=CC=C1)SC1=C(C=CC=C1)CCCCCC FSQFYRSMQZXJTP-UHFFFAOYSA-N 0.000 description 1
- PYWYAAZCDBLBAN-UHFFFAOYSA-N 1-isocyanato-2-[2-(2-isocyanatophenyl)propan-2-yl]benzene Chemical compound C=1C=CC=C(N=C=O)C=1C(C)(C)C1=CC=CC=C1N=C=O PYWYAAZCDBLBAN-UHFFFAOYSA-N 0.000 description 1
- RRPOMRAIAKJYKL-UHFFFAOYSA-N 1-isocyanatoethoxybenzene Chemical compound O=C=NC(C)OC1=CC=CC=C1 RRPOMRAIAKJYKL-UHFFFAOYSA-N 0.000 description 1
- SQNQPRDLKOZZJK-UHFFFAOYSA-N 1-methoxy-2-prop-1-enylbenzene Chemical compound COC1=CC=CC=C1C=CC SQNQPRDLKOZZJK-UHFFFAOYSA-N 0.000 description 1
- YBGBTUGNSNHBCP-UHFFFAOYSA-N 1-methoxy-2-propan-2-yloxypropane Chemical compound COCC(C)OC(C)C YBGBTUGNSNHBCP-UHFFFAOYSA-N 0.000 description 1
- CXBDYQVECUFKRK-UHFFFAOYSA-N 1-methoxybutane Chemical compound CCCCOC CXBDYQVECUFKRK-UHFFFAOYSA-N 0.000 description 1
- JPEWDCTZJFUITH-UHFFFAOYSA-N 1-methoxydecane Chemical compound CCCCCCCCCCOC JPEWDCTZJFUITH-UHFFFAOYSA-N 0.000 description 1
- RIAWWRJHTAZJSU-UHFFFAOYSA-N 1-methoxyoctane Chemical compound CCCCCCCCOC RIAWWRJHTAZJSU-UHFFFAOYSA-N 0.000 description 1
- AOWVXBUUWBOTKP-UHFFFAOYSA-N 1-methyl-2-(1-phenylethyl)benzene Chemical compound C=1C=CC=C(C)C=1C(C)C1=CC=CC=C1 AOWVXBUUWBOTKP-UHFFFAOYSA-N 0.000 description 1
- CYXMOAZSOPXQOD-UHFFFAOYSA-N 1-methyl-2-(2-methylphenoxy)benzene Chemical class CC1=CC=CC=C1OC1=CC=CC=C1C CYXMOAZSOPXQOD-UHFFFAOYSA-N 0.000 description 1
- BDAJBOIAMYRWFR-UHFFFAOYSA-N 1-methyl-2-(2-methylphenyl)sulfanylbenzene Chemical compound CC1=CC=CC=C1SC1=CC=CC=C1C BDAJBOIAMYRWFR-UHFFFAOYSA-N 0.000 description 1
- RLSSBERCVNQNTL-UHFFFAOYSA-N 1-methyl-2-nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1C RLSSBERCVNQNTL-UHFFFAOYSA-N 0.000 description 1
- HLMGHLNHOWCEFW-UHFFFAOYSA-N 1-methyl-2-octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1C HLMGHLNHOWCEFW-UHFFFAOYSA-N 0.000 description 1
- WCOYPFBMFKXWBM-UHFFFAOYSA-N 1-methyl-2-phenoxybenzene Chemical class CC1=CC=CC=C1OC1=CC=CC=C1 WCOYPFBMFKXWBM-UHFFFAOYSA-N 0.000 description 1
- RZTDESRVPFKCBH-UHFFFAOYSA-N 1-methyl-4-(4-methylphenyl)benzene Chemical group C1=CC(C)=CC=C1C1=CC=C(C)C=C1 RZTDESRVPFKCBH-UHFFFAOYSA-N 0.000 description 1
- WCXXISMIJBRDQK-UHFFFAOYSA-N 1-methylsulfanylbutane Chemical compound CCCCSC WCXXISMIJBRDQK-UHFFFAOYSA-N 0.000 description 1
- HKGUUZAACYBIID-UHFFFAOYSA-N 1-methylsulfanyldecane Chemical compound CCCCCCCCCCSC HKGUUZAACYBIID-UHFFFAOYSA-N 0.000 description 1
- FCRSULZJMFDBIK-UHFFFAOYSA-N 1-methylsulfanylnonane Chemical compound CCCCCCCCCSC FCRSULZJMFDBIK-UHFFFAOYSA-N 0.000 description 1
- AHCJTMBRROLNHV-UHFFFAOYSA-N 1-methylsulfanyloctane Chemical compound CCCCCCCCSC AHCJTMBRROLNHV-UHFFFAOYSA-N 0.000 description 1
- DKZRLCHWDNEKRH-UHFFFAOYSA-N 1-nonoxynonane Chemical compound CCCCCCCCCOCCCCCCCCC DKZRLCHWDNEKRH-UHFFFAOYSA-N 0.000 description 1
- KMKSVAGOBVUFRO-UHFFFAOYSA-N 1-nonylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCCCCC KMKSVAGOBVUFRO-UHFFFAOYSA-N 0.000 description 1
- BTWPHTDACLVGMG-UHFFFAOYSA-N 1-octoxydecane Chemical compound CCCCCCCCCCOCCCCCCCC BTWPHTDACLVGMG-UHFFFAOYSA-N 0.000 description 1
- OYBQYQOMBVAHKF-UHFFFAOYSA-N 1-octoxynonane Chemical compound CCCCCCCCCOCCCCCCCC OYBQYQOMBVAHKF-UHFFFAOYSA-N 0.000 description 1
- YWNBSWRNQJVBMN-UHFFFAOYSA-N 1-octylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCC YWNBSWRNQJVBMN-UHFFFAOYSA-N 0.000 description 1
- LETNMUGZXOWDDB-UHFFFAOYSA-N 1-octylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCCCC LETNMUGZXOWDDB-UHFFFAOYSA-N 0.000 description 1
- LOXRGHGHQYWXJK-UHFFFAOYSA-N 1-octylsulfanyloctane Chemical compound CCCCCCCCSCCCCCCCC LOXRGHGHQYWXJK-UHFFFAOYSA-N 0.000 description 1
- ICBNIQPVSXNVCW-UHFFFAOYSA-N 1-pentan-3-yloxypropan-2-ol Chemical compound CCC(CC)OCC(C)O ICBNIQPVSXNVCW-UHFFFAOYSA-N 0.000 description 1
- 125000004343 1-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NAFPAOUIKZHXDV-UHFFFAOYSA-N 1-propan-2-yloxy-2-(2-propan-2-yloxypropoxy)propane Chemical compound CC(C)OCC(C)OCC(C)OC(C)C NAFPAOUIKZHXDV-UHFFFAOYSA-N 0.000 description 1
- GPDFVOVLOXMSBT-UHFFFAOYSA-N 1-propan-2-yloxybutane Chemical compound CCCCOC(C)C GPDFVOVLOXMSBT-UHFFFAOYSA-N 0.000 description 1
- JQTIDYJFCNWJFO-UHFFFAOYSA-N 1-propan-2-yloxypropan-2-yl acetate Chemical compound CC(C)OCC(C)OC(C)=O JQTIDYJFCNWJFO-UHFFFAOYSA-N 0.000 description 1
- JOERQAIRIDZWHX-UHFFFAOYSA-N 1-propoxy-2-(2-propoxypropoxy)propane Chemical compound CCCOCC(C)OCC(C)OCCC JOERQAIRIDZWHX-UHFFFAOYSA-N 0.000 description 1
- DMFAHCVITRDZQB-UHFFFAOYSA-N 1-propoxypropan-2-yl acetate Chemical compound CCCOCC(C)OC(C)=O DMFAHCVITRDZQB-UHFFFAOYSA-N 0.000 description 1
- BQLXDRRCGWDMGA-UHFFFAOYSA-N 10,10-dibromononadecane Chemical compound BrC(CCCCCCCCC)(CCCCCCCCC)Br BQLXDRRCGWDMGA-UHFFFAOYSA-N 0.000 description 1
- ZWQHEQYFUHJJGH-UHFFFAOYSA-N 10,10-difluorononadecane Chemical compound FC(CCCCCCCCC)(CCCCCCCCC)F ZWQHEQYFUHJJGH-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- XOCOMEGNVMCRMP-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octaethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound CC[Si]1(CC)O[Si](CC)(CC)O[Si](CC)(CC)O[Si](CC)(CC)O1 XOCOMEGNVMCRMP-UHFFFAOYSA-N 0.000 description 1
- VSIKJPJINIDELZ-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octakis-phenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VSIKJPJINIDELZ-UHFFFAOYSA-N 0.000 description 1
- KSHXMBZGEVBSTC-UHFFFAOYSA-N 2,2,4,4,6,6-hexacyclohexyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound C1(CCCCC1)[Si]1(O[Si](O[Si](O1)(C1CCCCC1)C1CCCCC1)(C1CCCCC1)C1CCCCC1)C1CCCCC1 KSHXMBZGEVBSTC-UHFFFAOYSA-N 0.000 description 1
- KMPBCFZCRNKXSA-UHFFFAOYSA-N 2,2,4,4,6,6-hexaethyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound CC[Si]1(CC)O[Si](CC)(CC)O[Si](CC)(CC)O1 KMPBCFZCRNKXSA-UHFFFAOYSA-N 0.000 description 1
- VCYDUTCMKSROID-UHFFFAOYSA-N 2,2,4,4,6,6-hexakis-phenyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VCYDUTCMKSROID-UHFFFAOYSA-N 0.000 description 1
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 1
- JVYDLYGCSIHCMR-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butanoic acid Chemical compound CCC(CO)(CO)C(O)=O JVYDLYGCSIHCMR-UHFFFAOYSA-N 0.000 description 1
- CYLVUSZHVURAOY-UHFFFAOYSA-N 2,2-dibromoethenylbenzene Chemical compound BrC(Br)=CC1=CC=CC=C1 CYLVUSZHVURAOY-UHFFFAOYSA-N 0.000 description 1
- SYHAHHTUPPCPTM-UHFFFAOYSA-N 2,2-dibromoethylbenzene Chemical compound BrC(Br)CC1=CC=CC=C1 SYHAHHTUPPCPTM-UHFFFAOYSA-N 0.000 description 1
- VTZCVSPSJSMDPY-UHFFFAOYSA-N 2,2-dibromoethylcyclohexane Chemical compound BrC(Br)CC1CCCCC1 VTZCVSPSJSMDPY-UHFFFAOYSA-N 0.000 description 1
- CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
- NGQTUWCDHLILAX-UHFFFAOYSA-N 2,2-dichloroethylbenzene Chemical compound ClC(Cl)CC1=CC=CC=C1 NGQTUWCDHLILAX-UHFFFAOYSA-N 0.000 description 1
- ZCYFGVLFJDLYCL-UHFFFAOYSA-N 2,2-dichloroethylcyclohexane Chemical compound ClC(Cl)CC1CCCCC1 ZCYFGVLFJDLYCL-UHFFFAOYSA-N 0.000 description 1
- CSNUBZFHHXSACU-UHFFFAOYSA-N 2,2-dichloroethylcyclopentane Chemical compound ClC(Cl)CC1CCCC1 CSNUBZFHHXSACU-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- DPYJMQGTOTVJBV-UHFFFAOYSA-N 2,2-difluoroethenylbenzene Chemical compound FC(F)=CC1=CC=CC=C1 DPYJMQGTOTVJBV-UHFFFAOYSA-N 0.000 description 1
- SVQHPJKYUJYLJD-UHFFFAOYSA-N 2,2-difluoroethylbenzene Chemical compound FC(F)CC1=CC=CC=C1 SVQHPJKYUJYLJD-UHFFFAOYSA-N 0.000 description 1
- DKCLBVYFGUVPAG-UHFFFAOYSA-N 2,2-difluoroethylcyclohexane Chemical compound FC(F)CC1CCCCC1 DKCLBVYFGUVPAG-UHFFFAOYSA-N 0.000 description 1
- QAAGCMSOLXNEHL-UHFFFAOYSA-N 2,2-difluoroethylcyclopentane Chemical compound FC(F)CC1CCCC1 QAAGCMSOLXNEHL-UHFFFAOYSA-N 0.000 description 1
- YZXSQDNPKVBDOG-UHFFFAOYSA-N 2,2-difluoropropane Chemical compound CC(C)(F)F YZXSQDNPKVBDOG-UHFFFAOYSA-N 0.000 description 1
- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
- HEKCLWXKTVQKEF-UHFFFAOYSA-N 2,3-dibromo-1-methyl-4-(4-methylphenyl)benzene Chemical group BrC=1C(=C(C=CC=1C)C1=CC=C(C=C1)C)Br HEKCLWXKTVQKEF-UHFFFAOYSA-N 0.000 description 1
- GVTJVTFUVRQJKK-UHFFFAOYSA-N 2,3-dibromobuta-1,3-diene Chemical compound BrC(=C)C(Br)=C GVTJVTFUVRQJKK-UHFFFAOYSA-N 0.000 description 1
- BXXWFOGWXLJPPA-UHFFFAOYSA-N 2,3-dibromobutane Chemical compound CC(Br)C(C)Br BXXWFOGWXLJPPA-UHFFFAOYSA-N 0.000 description 1
- NSENZNPLAVRFMJ-UHFFFAOYSA-N 2,3-dibutylphenol Chemical compound CCCCC1=CC=CC(O)=C1CCCC NSENZNPLAVRFMJ-UHFFFAOYSA-N 0.000 description 1
- QFUAOVFOAMUJMU-UHFFFAOYSA-N 2,3-dichloro-1-methyl-4-(4-methylphenyl)benzene Chemical group C1=CC(C)=CC=C1C1=CC=C(C)C(Cl)=C1Cl QFUAOVFOAMUJMU-UHFFFAOYSA-N 0.000 description 1
- VQRDHUIACWSKLR-UHFFFAOYSA-N 2,3-difluoro-1-methyl-4-(4-methylphenyl)benzene Chemical group C1=CC(C)=CC=C1C1=CC=C(C)C(F)=C1F VQRDHUIACWSKLR-UHFFFAOYSA-N 0.000 description 1
- XQQOMTYXDIGHNA-UHFFFAOYSA-N 2,3-difluorobuta-1,3-diene Chemical compound FC(=C)C(F)=C XQQOMTYXDIGHNA-UHFFFAOYSA-N 0.000 description 1
- RPUVITOGCTVKMO-UHFFFAOYSA-N 2,3-diisocyanato-1-methylnaphthalene Chemical compound C1=CC=C2C(C)=C(N=C=O)C(N=C=O)=CC2=C1 RPUVITOGCTVKMO-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- IXKVYSRDIVLASR-UHFFFAOYSA-N 2,3-dioctylphenol Chemical compound CCCCCCCCC1=CC=CC(O)=C1CCCCCCCC IXKVYSRDIVLASR-UHFFFAOYSA-N 0.000 description 1
- HRQPPTDGMMGDKC-UHFFFAOYSA-N 2,3-dipropylphenol Chemical compound CCCC1=CC=CC(O)=C1CCC HRQPPTDGMMGDKC-UHFFFAOYSA-N 0.000 description 1
- SKDGWNHUETZZCS-UHFFFAOYSA-N 2,3-ditert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(O)=C1C(C)(C)C SKDGWNHUETZZCS-UHFFFAOYSA-N 0.000 description 1
- IEVUIBXSRCSCHY-UHFFFAOYSA-N 2,4,6,8-tetracyclohexyl-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C)(C2CCCCC2)O[Si](C)(C2CCCCC2)O[Si](C)(C2CCCCC2)O[Si]1(C)C1CCCCC1 IEVUIBXSRCSCHY-UHFFFAOYSA-N 0.000 description 1
- IRVZFACCNZRHSJ-UHFFFAOYSA-N 2,4,6,8-tetramethyl-2,4,6,8-tetraphenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si]1(C)C1=CC=CC=C1 IRVZFACCNZRHSJ-UHFFFAOYSA-N 0.000 description 1
- OOWDXERKWRKEHW-UHFFFAOYSA-N 2,4,6-tricyclohexyl-2,4,6-trimethyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound O1[Si](C)(C2CCCCC2)O[Si](C)(C2CCCCC2)O[Si]1(C)C1CCCCC1 OOWDXERKWRKEHW-UHFFFAOYSA-N 0.000 description 1
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 1
- FHTGJZOULSYEOB-UHFFFAOYSA-N 2,6-di(butan-2-yl)phenol Chemical compound CCC(C)C1=CC=CC(C(C)CC)=C1O FHTGJZOULSYEOB-UHFFFAOYSA-N 0.000 description 1
- FLPPEMNGWYFRSK-UHFFFAOYSA-N 2-(2-acetyloxypropoxy)propyl acetate Chemical compound CC(=O)OCC(C)OCC(C)OC(C)=O FLPPEMNGWYFRSK-UHFFFAOYSA-N 0.000 description 1
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- JONNRYNDZVEZFH-UHFFFAOYSA-N 2-(2-butoxypropoxy)propyl acetate Chemical compound CCCCOC(C)COC(C)COC(C)=O JONNRYNDZVEZFH-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- WHRXYZCLPICICK-UHFFFAOYSA-N 2-(2-ethoxyethoxy)propane Chemical compound CCOCCOC(C)C WHRXYZCLPICICK-UHFFFAOYSA-N 0.000 description 1
- XTABCMMCSGUJSB-UHFFFAOYSA-N 2-(2-ethoxypropoxy)-1-propan-2-yloxypropane Chemical compound CCOC(C)COC(C)COC(C)C XTABCMMCSGUJSB-UHFFFAOYSA-N 0.000 description 1
- CKCGJBFTCUCBAJ-UHFFFAOYSA-N 2-(2-ethoxypropoxy)propyl acetate Chemical compound CCOC(C)COC(C)COC(C)=O CKCGJBFTCUCBAJ-UHFFFAOYSA-N 0.000 description 1
- RRKBRXPIJHVKIC-UHFFFAOYSA-N 2-(2-ethylhexyl)phenol Chemical compound CCCCC(CC)CC1=CC=CC=C1O RRKBRXPIJHVKIC-UHFFFAOYSA-N 0.000 description 1
- SOHOWSNETCKHKH-UHFFFAOYSA-N 2-(2-heptan-4-yloxyethoxy)ethanol Chemical compound CCCC(CCC)OCCOCCO SOHOWSNETCKHKH-UHFFFAOYSA-N 0.000 description 1
- WDTSCGTYITZZEA-UHFFFAOYSA-N 2-(2-heptan-4-yloxypropoxy)propan-1-ol Chemical compound C(CC)C(CCC)OC(C)COC(C)CO WDTSCGTYITZZEA-UHFFFAOYSA-N 0.000 description 1
- WGYWCLNFFONDQZ-UHFFFAOYSA-N 2-(2-hexan-3-yloxyethoxy)ethanol Chemical compound CCCC(CC)OCCOCCO WGYWCLNFFONDQZ-UHFFFAOYSA-N 0.000 description 1
- CQGYCMPFUFLPQI-UHFFFAOYSA-N 2-(2-hexan-3-yloxypropoxy)propan-1-ol Chemical compound C(C)C(CCC)OC(C)COC(C)CO CQGYCMPFUFLPQI-UHFFFAOYSA-N 0.000 description 1
- BJINVQNEBGOMCR-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethyl acetate Chemical compound COCCOCCOC(C)=O BJINVQNEBGOMCR-UHFFFAOYSA-N 0.000 description 1
- OAXIUZFXLOZILE-UHFFFAOYSA-N 2-(2-methoxyethoxy)propane Chemical compound COCCOC(C)C OAXIUZFXLOZILE-UHFFFAOYSA-N 0.000 description 1
- LFFRWTARFBLLCP-UHFFFAOYSA-N 2-(2-methoxypropoxy)-1-propan-2-yloxypropane Chemical compound COC(C)COC(C)COC(C)C LFFRWTARFBLLCP-UHFFFAOYSA-N 0.000 description 1
- RZXAHVCTRLTLNA-UHFFFAOYSA-N 2-(2-methoxypropoxy)-1-propoxypropane Chemical compound CCCOCC(C)OCC(C)OC RZXAHVCTRLTLNA-UHFFFAOYSA-N 0.000 description 1
- DRLRGHZJOQGQEC-UHFFFAOYSA-N 2-(2-methoxypropoxy)propyl acetate Chemical compound COC(C)COC(C)COC(C)=O DRLRGHZJOQGQEC-UHFFFAOYSA-N 0.000 description 1
- KLRJLGMZEXPIMC-UHFFFAOYSA-N 2-(2-methylhexan-3-yloxy)ethanol Chemical compound C(C)(C)C(CCC)OCCO KLRJLGMZEXPIMC-UHFFFAOYSA-N 0.000 description 1
- VOUYYPDCXYMDAN-UHFFFAOYSA-N 2-(2-pentan-3-yloxypropoxy)propan-1-ol Chemical compound C(C)C(CC)OC(C)COC(C)CO VOUYYPDCXYMDAN-UHFFFAOYSA-N 0.000 description 1
- IZZVHOPLTANRPW-UHFFFAOYSA-N 2-(2-propan-2-yloxyethoxy)ethyl acetate Chemical compound CC(C)OCCOCCOC(C)=O IZZVHOPLTANRPW-UHFFFAOYSA-N 0.000 description 1
- MGZCLRWCEUBEGO-UHFFFAOYSA-N 2-(2-propan-2-yloxyethoxy)propane Chemical compound CC(C)OCCOC(C)C MGZCLRWCEUBEGO-UHFFFAOYSA-N 0.000 description 1
- LEDYRHPAPPWTNW-UHFFFAOYSA-N 2-(2-propan-2-yloxypropoxy)propyl acetate Chemical compound C(C)(=O)OCC(OCC(C)OC(C)C)C LEDYRHPAPPWTNW-UHFFFAOYSA-N 0.000 description 1
- GWQAFGZJIHVLGX-UHFFFAOYSA-N 2-(2-propoxyethoxy)ethyl acetate Chemical compound CCCOCCOCCOC(C)=O GWQAFGZJIHVLGX-UHFFFAOYSA-N 0.000 description 1
- UFBBZQDFWTVNGP-UHFFFAOYSA-N 2-(2-propoxypropoxy)propyl acetate Chemical compound CCCOC(C)COC(C)COC(C)=O UFBBZQDFWTVNGP-UHFFFAOYSA-N 0.000 description 1
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- WMYINDVYGQKYMI-UHFFFAOYSA-N 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol Chemical compound CCC(CO)(CO)COCC(CC)(CO)CO WMYINDVYGQKYMI-UHFFFAOYSA-N 0.000 description 1
- ZZHKLWVSWMWRFF-UHFFFAOYSA-N 2-[2-(2-ethoxyethoxy)ethoxy]propane Chemical compound CCOCCOCCOC(C)C ZZHKLWVSWMWRFF-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- RJBIZCOYFBKBIM-UHFFFAOYSA-N 2-[2-(2-methoxyethoxy)ethoxy]propane Chemical compound COCCOCCOC(C)C RJBIZCOYFBKBIM-UHFFFAOYSA-N 0.000 description 1
- NVUHFTUYHDNKSA-UHFFFAOYSA-N 2-[2-(2-methylhexan-3-yloxy)ethoxy]ethanol Chemical compound C(C)(C)C(CCC)OCCOCCO NVUHFTUYHDNKSA-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- AJTVSSFTXWNIRG-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanesulfonic acid Chemical compound OCC[NH+](CCO)CCS([O-])(=O)=O AJTVSSFTXWNIRG-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical compound CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 description 1
- QQDDAVDLXNZTBN-UHFFFAOYSA-N 2-chloro-1,1-diethylcyclohexane Chemical compound ClC1C(CCCC1)(CC)CC QQDDAVDLXNZTBN-UHFFFAOYSA-N 0.000 description 1
- KXSJTRRJBJAAQU-UHFFFAOYSA-N 2-chloro-1,1-dimethylcyclohexane Chemical compound CC1(C)CCCCC1Cl KXSJTRRJBJAAQU-UHFFFAOYSA-N 0.000 description 1
- MNFFTFICWZXVOS-UHFFFAOYSA-N 2-chloro-4-methyl-1-(4-methylphenyl)benzene Chemical group C1=CC(C)=CC=C1C1=CC=C(C)C=C1Cl MNFFTFICWZXVOS-UHFFFAOYSA-N 0.000 description 1
- LAXBNTIAOJWAOP-UHFFFAOYSA-N 2-chlorobiphenyl Chemical group ClC1=CC=CC=C1C1=CC=CC=C1 LAXBNTIAOJWAOP-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- MNNZINNZIQVULG-UHFFFAOYSA-N 2-chloroethylbenzene Chemical compound ClCCC1=CC=CC=C1 MNNZINNZIQVULG-UHFFFAOYSA-N 0.000 description 1
- TYRMEBINDCQOHD-UHFFFAOYSA-N 2-chloroethylcyclohexane Chemical compound ClCCC1CCCCC1 TYRMEBINDCQOHD-UHFFFAOYSA-N 0.000 description 1
- JQXYEQHHLIYKAT-UHFFFAOYSA-N 2-chloroethylcyclopentane Chemical compound ClCCC1CCCC1 JQXYEQHHLIYKAT-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- ZKCCKKDTLQTPKF-UHFFFAOYSA-N 2-ethoxy-1-methoxypropane Chemical compound CCOC(C)COC ZKCCKKDTLQTPKF-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- KBKNKFIRGXQLDB-UHFFFAOYSA-N 2-fluoroethenylbenzene Chemical compound FC=CC1=CC=CC=C1 KBKNKFIRGXQLDB-UHFFFAOYSA-N 0.000 description 1
- RWLREIIYUMOGGY-UHFFFAOYSA-N 2-hexan-3-yloxyethanol Chemical compound CCCC(CC)OCCO RWLREIIYUMOGGY-UHFFFAOYSA-N 0.000 description 1
- ABMULKFGWTYIIK-UHFFFAOYSA-N 2-hexylphenol Chemical compound CCCCCCC1=CC=CC=C1O ABMULKFGWTYIIK-UHFFFAOYSA-N 0.000 description 1
- CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- IDEOPBXRUBNYBN-UHFFFAOYSA-N 2-methylbutane-2,3-diol Chemical compound CC(O)C(C)(C)O IDEOPBXRUBNYBN-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- OJJUCAQFBVCYIW-UHFFFAOYSA-N 2-pentan-2-yloxyethanol Chemical compound CCCC(C)OCCO OJJUCAQFBVCYIW-UHFFFAOYSA-N 0.000 description 1
- ZMTSMVZAFDWQRM-UHFFFAOYSA-N 2-phenylethylurea Chemical compound NC(=O)NCCC1=CC=CC=C1 ZMTSMVZAFDWQRM-UHFFFAOYSA-N 0.000 description 1
- HCDJVEYJSSTYSW-UHFFFAOYSA-N 2-propan-2-yloxyethyl acetate Chemical compound CC(C)OCCOC(C)=O HCDJVEYJSSTYSW-UHFFFAOYSA-N 0.000 description 1
- QMAQLCVJIYANPZ-UHFFFAOYSA-N 2-propoxyethyl acetate Chemical compound CCCOCCOC(C)=O QMAQLCVJIYANPZ-UHFFFAOYSA-N 0.000 description 1
- LCHYEKKJCUJAKN-UHFFFAOYSA-N 2-propylphenol Chemical compound CCCC1=CC=CC=C1O LCHYEKKJCUJAKN-UHFFFAOYSA-N 0.000 description 1
- NGFPWHGISWUQOI-UHFFFAOYSA-N 2-sec-butylphenol Chemical compound CCC(C)C1=CC=CC=C1O NGFPWHGISWUQOI-UHFFFAOYSA-N 0.000 description 1
- KSNKQSPJFRQSEI-UHFFFAOYSA-N 3,3,3-trifluoropropanoic acid Chemical compound OC(=O)CC(F)(F)F KSNKQSPJFRQSEI-UHFFFAOYSA-N 0.000 description 1
- UVLNQGHDUGHTGV-UHFFFAOYSA-N 3,3,4,4,4-pentafluorobutanoic acid Chemical compound OC(=O)CC(F)(F)C(F)(F)F UVLNQGHDUGHTGV-UHFFFAOYSA-N 0.000 description 1
- NLAGAXIWWHZGCK-UHFFFAOYSA-N 3,3,4,4,5,5,5-heptafluoropentanoic acid Chemical compound OC(=O)CC(F)(F)C(F)(F)C(F)(F)F NLAGAXIWWHZGCK-UHFFFAOYSA-N 0.000 description 1
- NTIGNJOEVBTPJJ-UHFFFAOYSA-N 3,3-dibromopentane Chemical compound CCC(Br)(Br)CC NTIGNJOEVBTPJJ-UHFFFAOYSA-N 0.000 description 1
- XTSFFGPWZRBWLG-UHFFFAOYSA-N 3,3-dibromoprop-1-enylbenzene Chemical compound BrC(C=CC1=CC=CC=C1)Br XTSFFGPWZRBWLG-UHFFFAOYSA-N 0.000 description 1
- BRBWMNNCIJWRKG-UHFFFAOYSA-N 3,3-dibromopropylcyclohexane Chemical compound BrC(Br)CCC1CCCCC1 BRBWMNNCIJWRKG-UHFFFAOYSA-N 0.000 description 1
- PLNSKVFVQQBEMJ-UHFFFAOYSA-N 3,3-dichloroprop-1-enylbenzene Chemical compound ClC(Cl)C=CC1=CC=CC=C1 PLNSKVFVQQBEMJ-UHFFFAOYSA-N 0.000 description 1
- VIVDIGLJIQGLHM-UHFFFAOYSA-N 3,3-dichloropropylcyclohexane Chemical compound ClC(CCC1CCCCC1)Cl VIVDIGLJIQGLHM-UHFFFAOYSA-N 0.000 description 1
- XJGGLPBZNXEBLL-UHFFFAOYSA-N 3,3-difluoroprop-1-enylbenzene Chemical compound FC(F)C=CC1=CC=CC=C1 XJGGLPBZNXEBLL-UHFFFAOYSA-N 0.000 description 1
- KJBJUTSBUKQIKR-UHFFFAOYSA-N 3,3-difluoroprop-2-enoic acid Chemical compound OC(=O)C=C(F)F KJBJUTSBUKQIKR-UHFFFAOYSA-N 0.000 description 1
- VXGSZMWTESTQCX-UHFFFAOYSA-N 3,3-difluoropropylcyclohexane Chemical compound FC(F)CCC1CCCCC1 VXGSZMWTESTQCX-UHFFFAOYSA-N 0.000 description 1
- XDFQCCVUKOQKQD-UHFFFAOYSA-N 3,4-diisocyanato-2-methylpyridine Chemical compound N(=C=O)C1=C(C(=NC=C1)C)N=C=O XDFQCCVUKOQKQD-UHFFFAOYSA-N 0.000 description 1
- SDXAWLJRERMRKF-UHFFFAOYSA-N 3,5-dimethyl-1h-pyrazole Chemical compound CC=1C=C(C)NN=1 SDXAWLJRERMRKF-UHFFFAOYSA-N 0.000 description 1
- RQRRYBYOBATMDC-UHFFFAOYSA-N 3-(hydroxymethyl)nonane-1,9-diol Chemical compound OCCCCCCC(CO)CCO RQRRYBYOBATMDC-UHFFFAOYSA-N 0.000 description 1
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical group OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 1
- RUROFEVDCUGKHD-UHFFFAOYSA-N 3-bromoprop-1-enylbenzene Chemical compound BrCC=CC1=CC=CC=C1 RUROFEVDCUGKHD-UHFFFAOYSA-N 0.000 description 1
- IWTYTFSSTWXZFU-UHFFFAOYSA-N 3-chloroprop-1-enylbenzene Chemical compound ClCC=CC1=CC=CC=C1 IWTYTFSSTWXZFU-UHFFFAOYSA-N 0.000 description 1
- QEISABAAOUXQNG-UHFFFAOYSA-N 3-chloropropylcyclohexane Chemical compound ClCCCC1CCCCC1 QEISABAAOUXQNG-UHFFFAOYSA-N 0.000 description 1
- YDORGPSKSSWFBX-UHFFFAOYSA-N 3-phenylpropylurea Chemical compound NC(=O)NCCCC1=CC=CC=C1 YDORGPSKSSWFBX-UHFFFAOYSA-N 0.000 description 1
- YTBRNEUEFCNVHC-UHFFFAOYSA-N 4,4'-dichlorobiphenyl Chemical group C1=CC(Cl)=CC=C1C1=CC=C(Cl)C=C1 YTBRNEUEFCNVHC-UHFFFAOYSA-N 0.000 description 1
- OEMCCLHFMFNLFU-UHFFFAOYSA-N 4,4-dibromobuta-1,3-dienylbenzene Chemical compound BrC(Br)=CC=CC1=CC=CC=C1 OEMCCLHFMFNLFU-UHFFFAOYSA-N 0.000 description 1
- QLLLXJPZUWXKLE-UHFFFAOYSA-N 4,4-dibromobutylbenzene Chemical compound BrC(Br)CCCC1=CC=CC=C1 QLLLXJPZUWXKLE-UHFFFAOYSA-N 0.000 description 1
- ONXREHGEYAAGFZ-UHFFFAOYSA-N 4,4-dibromobutylcyclohexane Chemical compound BrC(CCCC1CCCCC1)Br ONXREHGEYAAGFZ-UHFFFAOYSA-N 0.000 description 1
- TZFKFDQPHRPMKH-UHFFFAOYSA-N 4,4-dibromoheptane Chemical compound CCCC(Br)(Br)CCC TZFKFDQPHRPMKH-UHFFFAOYSA-N 0.000 description 1
- LCWWIIXIFMSPHG-UHFFFAOYSA-N 4,4-dichlorobuta-1,3-dienylbenzene Chemical compound ClC(Cl)=CC=CC1=CC=CC=C1 LCWWIIXIFMSPHG-UHFFFAOYSA-N 0.000 description 1
- ZQPJOUALOKGDGK-UHFFFAOYSA-N 4,4-dichlorobutylbenzene Chemical compound ClC(Cl)CCCC1=CC=CC=C1 ZQPJOUALOKGDGK-UHFFFAOYSA-N 0.000 description 1
- XEWLVTMNJAVBNZ-UHFFFAOYSA-N 4,4-dichlorobutylcyclohexane Chemical compound ClC(CCCC1CCCCC1)Cl XEWLVTMNJAVBNZ-UHFFFAOYSA-N 0.000 description 1
- DLEUJDNDBMGGLN-UHFFFAOYSA-N 4,4-dichloroheptane Chemical compound CCCC(Cl)(Cl)CCC DLEUJDNDBMGGLN-UHFFFAOYSA-N 0.000 description 1
- RJMIJTCQUMTFSQ-UHFFFAOYSA-N 4,4-difluorobuta-1,3-dienylbenzene Chemical compound FC(F)=CC=CC1=CC=CC=C1 RJMIJTCQUMTFSQ-UHFFFAOYSA-N 0.000 description 1
- OKGZHVLJQPXHQR-UHFFFAOYSA-N 4,4-difluorobutylbenzene Chemical compound FC(F)CCCC1=CC=CC=C1 OKGZHVLJQPXHQR-UHFFFAOYSA-N 0.000 description 1
- CCMAKHDYFUAWRT-UHFFFAOYSA-N 4,4-difluorobutylcyclohexane Chemical compound FC(CCCC1CCCCC1)F CCMAKHDYFUAWRT-UHFFFAOYSA-N 0.000 description 1
- FDZUPHXVDHGJQR-UHFFFAOYSA-N 4,4-difluoroheptane Chemical compound CCCC(F)(F)CCC FDZUPHXVDHGJQR-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- UNDXPKDBFOOQFC-UHFFFAOYSA-N 4-[2-nitro-4-(trifluoromethyl)phenyl]morpholine Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=CC=C1N1CCOCC1 UNDXPKDBFOOQFC-UHFFFAOYSA-N 0.000 description 1
- LWMDPZVQAMQFOC-UHFFFAOYSA-N 4-butylpyridine Chemical compound CCCCC1=CC=NC=C1 LWMDPZVQAMQFOC-UHFFFAOYSA-N 0.000 description 1
- FLLZCZIHURYEQP-UHFFFAOYSA-N 4-chlorobutylbenzene Chemical compound ClCCCCC1=CC=CC=C1 FLLZCZIHURYEQP-UHFFFAOYSA-N 0.000 description 1
- MOYMSRFEQFNEOX-UHFFFAOYSA-N 4-chlorobutylcyclohexane Chemical compound ClCCCCC1CCCCC1 MOYMSRFEQFNEOX-UHFFFAOYSA-N 0.000 description 1
- LDZLXQFDGRCELX-UHFFFAOYSA-N 4-phenylbutan-1-ol Chemical group OCCCCC1=CC=CC=C1 LDZLXQFDGRCELX-UHFFFAOYSA-N 0.000 description 1
- BJIYQBIFXLHQRV-UHFFFAOYSA-N 4-phenylbutylurea Chemical compound NC(=O)NCCCCC1=CC=CC=C1 BJIYQBIFXLHQRV-UHFFFAOYSA-N 0.000 description 1
- SARKJMLSMKMIDV-UHFFFAOYSA-N 5,5-dibromopentylbenzene Chemical compound BrC(Br)CCCCC1=CC=CC=C1 SARKJMLSMKMIDV-UHFFFAOYSA-N 0.000 description 1
- ACLWDLAPEVAFKK-UHFFFAOYSA-N 5,5-dibromopentylcyclohexane Chemical compound BrC(CCCCC1CCCCC1)Br ACLWDLAPEVAFKK-UHFFFAOYSA-N 0.000 description 1
- XWLNCOJEAJBNCO-UHFFFAOYSA-N 5,5-dichloropentylbenzene Chemical compound ClC(Cl)CCCCC1=CC=CC=C1 XWLNCOJEAJBNCO-UHFFFAOYSA-N 0.000 description 1
- CVHRZKDQALISSY-UHFFFAOYSA-N 5,5-dichloropentylcyclohexane Chemical compound ClC(CCCCC1CCCCC1)Cl CVHRZKDQALISSY-UHFFFAOYSA-N 0.000 description 1
- AVIAEXWPUZPNKN-UHFFFAOYSA-N 5,5-difluorononane Chemical compound CCCCC(F)(F)CCCC AVIAEXWPUZPNKN-UHFFFAOYSA-N 0.000 description 1
- DPYHWOVCCOAWPV-UHFFFAOYSA-N 5,5-difluoropentylbenzene Chemical compound FC(F)CCCCC1=CC=CC=C1 DPYHWOVCCOAWPV-UHFFFAOYSA-N 0.000 description 1
- CYBADEAMKSMJAE-UHFFFAOYSA-N 5,5-difluoropentylcyclohexane Chemical compound FC(CCCCC1CCCCC1)F CYBADEAMKSMJAE-UHFFFAOYSA-N 0.000 description 1
- UXJLBVYYDZDPBV-UHFFFAOYSA-N 5-chloropentylbenzene Chemical compound ClCCCCCC1=CC=CC=C1 UXJLBVYYDZDPBV-UHFFFAOYSA-N 0.000 description 1
- WVDAITFVJVSVPJ-UHFFFAOYSA-N 5-chloropentylcyclohexane Chemical compound ClCCCCCC1CCCCC1 WVDAITFVJVSVPJ-UHFFFAOYSA-N 0.000 description 1
- XKVUYEYANWFIJX-UHFFFAOYSA-N 5-methyl-1h-pyrazole Chemical compound CC1=CC=NN1 XKVUYEYANWFIJX-UHFFFAOYSA-N 0.000 description 1
- PUDGIAARABXXAN-UHFFFAOYSA-N 5-phenylpentylurea Chemical compound NC(=O)NCCCCCC1=CC=CC=C1 PUDGIAARABXXAN-UHFFFAOYSA-N 0.000 description 1
- BZDKUHSBDDQDRT-UHFFFAOYSA-N 6,6-dibromohexylbenzene Chemical compound BrC(Br)CCCCCC1=CC=CC=C1 BZDKUHSBDDQDRT-UHFFFAOYSA-N 0.000 description 1
- DXKYVURRHLDVEZ-UHFFFAOYSA-N 6,6-dibromohexylcyclohexane Chemical compound BrC(CCCCCC1CCCCC1)Br DXKYVURRHLDVEZ-UHFFFAOYSA-N 0.000 description 1
- CBXIUTIHDRKGJR-UHFFFAOYSA-N 6,6-dichlorohexylbenzene Chemical compound ClC(Cl)CCCCCC1=CC=CC=C1 CBXIUTIHDRKGJR-UHFFFAOYSA-N 0.000 description 1
- ODSNGVWQWMFBOX-UHFFFAOYSA-N 6,6-dichlorohexylcyclohexane Chemical compound ClC(Cl)CCCCCC1CCCCC1 ODSNGVWQWMFBOX-UHFFFAOYSA-N 0.000 description 1
- ZVZNOHZXLBZPJF-UHFFFAOYSA-N 6,6-difluorohexylbenzene Chemical compound FC(F)CCCCCC1=CC=CC=C1 ZVZNOHZXLBZPJF-UHFFFAOYSA-N 0.000 description 1
- RCVNHNOEUMFFDY-UHFFFAOYSA-N 6-chlorohexylbenzene Chemical compound ClCCCCCCC1=CC=CC=C1 RCVNHNOEUMFFDY-UHFFFAOYSA-N 0.000 description 1
- DAMKODJICBADKA-UHFFFAOYSA-N 6-chlorohexylcyclohexane Chemical compound ClCCCCCCC1CCCCC1 DAMKODJICBADKA-UHFFFAOYSA-N 0.000 description 1
- QOLQCMKXNHQGDA-UHFFFAOYSA-N 6-phenylhexylurea Chemical compound NC(=O)NCCCCCCC1=CC=CC=C1 QOLQCMKXNHQGDA-UHFFFAOYSA-N 0.000 description 1
- UXMUSYTXSNVRMW-UHFFFAOYSA-N 7-phenylheptan-1-ol Chemical group OCCCCCCCC1=CC=CC=C1 UXMUSYTXSNVRMW-UHFFFAOYSA-N 0.000 description 1
- ZNVAGVGOLUCXJK-UHFFFAOYSA-N 7-phenylheptylurea Chemical compound NC(=O)NCCCCCCCC1=CC=CC=C1 ZNVAGVGOLUCXJK-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- SJLKJWXPKNQWPC-UHFFFAOYSA-N 8,8-dibromooctylbenzene Chemical compound BrC(Br)CCCCCCCC1=CC=CC=C1 SJLKJWXPKNQWPC-UHFFFAOYSA-N 0.000 description 1
- PFKDZWKSHBWCEH-UHFFFAOYSA-N 8,8-dibromopentadecane Chemical compound BrC(CCCCCCC)(CCCCCCC)Br PFKDZWKSHBWCEH-UHFFFAOYSA-N 0.000 description 1
- RRUYFQMQPYYZSH-UHFFFAOYSA-N 8,8-dichlorooctylbenzene Chemical compound ClC(Cl)CCCCCCCC1=CC=CC=C1 RRUYFQMQPYYZSH-UHFFFAOYSA-N 0.000 description 1
- FNOJOAFROJLERL-UHFFFAOYSA-N 8,8-dichloropentadecane Chemical compound ClC(CCCCCCC)(CCCCCCC)Cl FNOJOAFROJLERL-UHFFFAOYSA-N 0.000 description 1
- AUXLFVDBSCESCI-UHFFFAOYSA-N 8,8-difluorooctylbenzene Chemical compound FC(CCCCCCCC1=CC=CC=C1)F AUXLFVDBSCESCI-UHFFFAOYSA-N 0.000 description 1
- BZZBSGWEOAQEMQ-UHFFFAOYSA-N 8,8-difluoropentadecane Chemical compound FC(CCCCCCC)(CCCCCCC)F BZZBSGWEOAQEMQ-UHFFFAOYSA-N 0.000 description 1
- GVDYDOFBAKCSGC-UHFFFAOYSA-N 8-chlorooctylbenzene Chemical compound ClCCCCCCCCC1=CC=CC=C1 GVDYDOFBAKCSGC-UHFFFAOYSA-N 0.000 description 1
- YTPSGTOBGFAQJT-UHFFFAOYSA-N 8-phenyloctylurea Chemical compound NC(=O)NCCCCCCCCC1=CC=CC=C1 YTPSGTOBGFAQJT-UHFFFAOYSA-N 0.000 description 1
- ZSDCEUUGELIOCD-UHFFFAOYSA-N 9-phenylnonylurea Chemical compound NC(=O)NCCCCCCCCCC1=CC=CC=C1 ZSDCEUUGELIOCD-UHFFFAOYSA-N 0.000 description 1
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical compound ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 description 1
- OUIZZSCVKVCNFW-UHFFFAOYSA-N BrC(=CC=CCC)Br Chemical compound BrC(=CC=CCC)Br OUIZZSCVKVCNFW-UHFFFAOYSA-N 0.000 description 1
- KEESEGLEIMQMQZ-UHFFFAOYSA-N C(CC)C(CCC)OCCO Chemical compound C(CC)C(CCC)OCCO KEESEGLEIMQMQZ-UHFFFAOYSA-N 0.000 description 1
- BLLMYINZRTXDIQ-UHFFFAOYSA-N C(CCCC)C1=C(C=CC=C1)O.C(N)(O)=O Chemical compound C(CCCC)C1=C(C=CC=C1)O.C(N)(O)=O BLLMYINZRTXDIQ-UHFFFAOYSA-N 0.000 description 1
- XDANFXXYNDCGKJ-UHFFFAOYSA-N C(CCCCCCCC)NC(=O)NCCCCCCCCC Chemical compound C(CCCCCCCC)NC(=O)NCCCCCCCCC XDANFXXYNDCGKJ-UHFFFAOYSA-N 0.000 description 1
- CQXYLMHYWNVYON-UHFFFAOYSA-N C(CCCCCCCCC)C1=C(C=CC=C1)NC(=O)N.C(CCCCCCCC)C1=C(C=CC=C1)NC(=O)N Chemical compound C(CCCCCCCCC)C1=C(C=CC=C1)NC(=O)N.C(CCCCCCCC)C1=C(C=CC=C1)NC(=O)N CQXYLMHYWNVYON-UHFFFAOYSA-N 0.000 description 1
- XSNBBOZIANKMJF-UHFFFAOYSA-N C1(=CC=CC=C1)SC1=CC=CC=C1.CC1=C(C=CC=C1)O Chemical compound C1(=CC=CC=C1)SC1=CC=CC=C1.CC1=C(C=CC=C1)O XSNBBOZIANKMJF-UHFFFAOYSA-N 0.000 description 1
- CIURCIMZEPBPPG-UHFFFAOYSA-N CC(CCC)OC(C)COC(C)CO Chemical compound CC(CCC)OC(C)COC(C)CO CIURCIMZEPBPPG-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- KREWDOWTKOAPKQ-UHFFFAOYSA-N ClC(=CC=CCC)Cl.ClC(=CC=CC)Cl Chemical compound ClC(=CC=CCC)Cl.ClC(=CC=CC)Cl KREWDOWTKOAPKQ-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- ZFMSMUAANRJZFM-UHFFFAOYSA-N Estragole Chemical compound COC1=CC=C(CC=C)C=C1 ZFMSMUAANRJZFM-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- RYECOJGRJDOGPP-UHFFFAOYSA-N Ethylurea Chemical compound CCNC(N)=O RYECOJGRJDOGPP-UHFFFAOYSA-N 0.000 description 1
- GTTCDFYYUNKPJE-UHFFFAOYSA-N FC(=CC=CCC)F Chemical compound FC(=CC=CCC)F GTTCDFYYUNKPJE-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- HEBKCHPVOIAQTA-IMJSIDKUSA-N L-arabinitol Chemical compound OC[C@H](O)C(O)[C@@H](O)CO HEBKCHPVOIAQTA-IMJSIDKUSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 description 1
- MGJKQDOBUOMPEZ-UHFFFAOYSA-N N,N'-dimethylurea Chemical compound CNC(=O)NC MGJKQDOBUOMPEZ-UHFFFAOYSA-N 0.000 description 1
- XGEGHDBEHXKFPX-UHFFFAOYSA-N N-methylthiourea Natural products CNC(N)=O XGEGHDBEHXKFPX-UHFFFAOYSA-N 0.000 description 1
- AYRXSINWFIIFAE-UHFFFAOYSA-N O6-alpha-D-Galactopyranosyl-D-galactose Natural products OCC1OC(OCC(O)C(O)C(O)C(O)C=O)C(O)C(O)C1O AYRXSINWFIIFAE-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- JVWLUVNSQYXYBE-UHFFFAOYSA-N Ribitol Natural products OCC(C)C(O)C(O)CO JVWLUVNSQYXYBE-UHFFFAOYSA-N 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 1
- QROGIFZRVHSFLM-QHHAFSJGSA-N [(e)-prop-1-enyl]benzene Chemical compound C\C=C\C1=CC=CC=C1 QROGIFZRVHSFLM-QHHAFSJGSA-N 0.000 description 1
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 1
- RPHNZTCPYDHOHL-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-diphenyl-triphenylsilyloxysilane Chemical compound C[Si](O[Si](O[Si](O[Si](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)(C)C)(C)C RPHNZTCPYDHOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- JDPAVWAQGBGGHD-UHFFFAOYSA-N aceanthrylene Chemical group C1=CC=C2C(C=CC3=CC=C4)=C3C4=CC2=C1 JDPAVWAQGBGGHD-UHFFFAOYSA-N 0.000 description 1
- 125000004054 acenaphthylenyl group Chemical group C1(=CC2=CC=CC3=CC=CC1=C23)* 0.000 description 1
- SQFPKRNUGBRTAR-UHFFFAOYSA-N acephenanthrylene Chemical group C1=CC(C=C2)=C3C2=CC2=CC=CC=C2C3=C1 SQFPKRNUGBRTAR-UHFFFAOYSA-N 0.000 description 1
- 229960001413 acetanilide Drugs 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000005577 anthracene group Chemical group 0.000 description 1
- 125000003828 azulenyl group Chemical group 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- LUFPJJNWMYZRQE-UHFFFAOYSA-N benzylsulfanylmethylbenzene Chemical compound C=1C=CC=CC=1CSCC1=CC=CC=C1 LUFPJJNWMYZRQE-UHFFFAOYSA-N 0.000 description 1
- RJNJWHFSKNJCTB-UHFFFAOYSA-N benzylurea Chemical compound NC(=O)NCC1=CC=CC=C1 RJNJWHFSKNJCTB-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- DLRVVLDZNNYCBX-ZZFZYMBESA-N beta-melibiose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)O1 DLRVVLDZNNYCBX-ZZFZYMBESA-N 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000319 biphenyl-4-yl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 description 1
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 description 1
- FWRXBOKRNGWMDD-UHFFFAOYSA-N bis(2-butylphenyl) carbonate Chemical compound CCCCC1=CC=CC=C1OC(=O)OC1=CC=CC=C1CCCC FWRXBOKRNGWMDD-UHFFFAOYSA-N 0.000 description 1
- YAPBIDJHZIYQSK-UHFFFAOYSA-N bis(2-ethylphenyl) carbonate Chemical compound CCC1=CC=CC=C1OC(=O)OC1=CC=CC=C1CC YAPBIDJHZIYQSK-UHFFFAOYSA-N 0.000 description 1
- POZGCGJFBOZPCM-UHFFFAOYSA-N bis(2-methylphenyl) carbonate Chemical compound CC1=CC=CC=C1OC(=O)OC1=CC=CC=C1C POZGCGJFBOZPCM-UHFFFAOYSA-N 0.000 description 1
- NXWNUSGXRSUNBA-UHFFFAOYSA-N bis(2-propylphenyl) carbonate Chemical compound CCCC1=CC=CC=C1OC(=O)OC1=CC=CC=C1CCC NXWNUSGXRSUNBA-UHFFFAOYSA-N 0.000 description 1
- UIMMIZFQKKQYGW-UHFFFAOYSA-N bis(4-phenylbutyl) carbonate Chemical compound C=1C=CC=CC=1CCCCOC(=O)OCCCCC1=CC=CC=C1 UIMMIZFQKKQYGW-UHFFFAOYSA-N 0.000 description 1
- VEWFBWYHSIGPGE-UHFFFAOYSA-N bis(5-phenylpentyl) carbonate Chemical compound C=1C=CC=CC=1CCCCCOC(=O)OCCCCCC1=CC=CC=C1 VEWFBWYHSIGPGE-UHFFFAOYSA-N 0.000 description 1
- UCSGLZXKQODUOA-UHFFFAOYSA-N bis(6-phenylhexyl) carbonate Chemical compound C=1C=CC=CC=1CCCCCCOC(=O)OCCCCCCC1=CC=CC=C1 UCSGLZXKQODUOA-UHFFFAOYSA-N 0.000 description 1
- ZSCAODKZXWOTTE-UHFFFAOYSA-N bis(7-phenylheptyl) carbonate Chemical compound C=1C=CC=CC=1CCCCCCCOC(=O)OCCCCCCCC1=CC=CC=C1 ZSCAODKZXWOTTE-UHFFFAOYSA-N 0.000 description 1
- TVFMFNIIJNIRKW-UHFFFAOYSA-N bis(8-phenyloctyl) carbonate Chemical compound C=1C=CC=CC=1CCCCCCCCOC(=O)OCCCCCCCCC1=CC=CC=C1 TVFMFNIIJNIRKW-UHFFFAOYSA-N 0.000 description 1
- TXZWTLIBBPJBRD-UHFFFAOYSA-N bis(9-phenylnonyl) carbonate Chemical compound C=1C=CC=CC=1CCCCCCCCCOC(=O)OCCCCCCCCCC1=CC=CC=C1 TXZWTLIBBPJBRD-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical group BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- GKRALBJDXHXFNB-UHFFFAOYSA-N butoxycyclohexane Chemical compound CCCCOC1CCCCC1 GKRALBJDXHXFNB-UHFFFAOYSA-N 0.000 description 1
- MAYUYFCAPVDYBQ-UHFFFAOYSA-N butoxymethylbenzene Chemical compound CCCCOCC1=CC=CC=C1 MAYUYFCAPVDYBQ-UHFFFAOYSA-N 0.000 description 1
- SKKTUOZKZKCGTB-UHFFFAOYSA-N butyl carbamate Chemical compound CCCCOC(N)=O SKKTUOZKZKCGTB-UHFFFAOYSA-N 0.000 description 1
- CNWSQCLBDWYLAN-UHFFFAOYSA-N butylurea Chemical compound CCCCNC(N)=O CNWSQCLBDWYLAN-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- VHCISIXWAAFVQC-UHFFFAOYSA-N carbamic acid 1,2-diphenylbenzene Chemical group NC(O)=O.C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1 VHCISIXWAAFVQC-UHFFFAOYSA-N 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- OYEOMXKDDUASEI-UHFFFAOYSA-N carbonic acid;carboxy hydrogen carbonate Chemical compound OC(O)=O.OC(=O)OC(O)=O OYEOMXKDDUASEI-UHFFFAOYSA-N 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- KMJSGLZXFNSANB-UHFFFAOYSA-N chlorocycloheptane Chemical compound ClC1CCCCCC1 KMJSGLZXFNSANB-UHFFFAOYSA-N 0.000 description 1
- LDOZEEFSUYHNPM-UHFFFAOYSA-N chlorocyclooctane Chemical compound ClC1CCCCCCC1 LDOZEEFSUYHNPM-UHFFFAOYSA-N 0.000 description 1
- NDTCXABJQNJPCF-UHFFFAOYSA-N chlorocyclopentane Chemical compound ClC1CCCC1 NDTCXABJQNJPCF-UHFFFAOYSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- OMEGHMBBBTYRFT-UHFFFAOYSA-N chloromethylcyclohexane Chemical compound ClCC1CCCCC1 OMEGHMBBBTYRFT-UHFFFAOYSA-N 0.000 description 1
- NQIIILQXTJXSCA-UHFFFAOYSA-N chloromethylcyclopentane Chemical compound ClCC1CCCC1 NQIIILQXTJXSCA-UHFFFAOYSA-N 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 125000005578 chrysene group Chemical group 0.000 description 1
- HAURRGANAANPSQ-UHFFFAOYSA-N cis-2,4,6-Trimethyl-2,4,6-triphenylcyclotrisiloxane Chemical compound O1[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si]1(C)C1=CC=CC=C1 HAURRGANAANPSQ-UHFFFAOYSA-N 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 125000000000 cycloalkoxy group Chemical group 0.000 description 1
- 125000003113 cycloheptyloxy group Chemical group C1(CCCCCC1)O* 0.000 description 1
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 1
- 125000002933 cyclohexyloxy group Chemical group C1(CCCCC1)O* 0.000 description 1
- OCDXZFSOHJRGIL-UHFFFAOYSA-N cyclohexyloxycyclohexane Chemical compound C1CCCCC1OC1CCCCC1 OCDXZFSOHJRGIL-UHFFFAOYSA-N 0.000 description 1
- FTAORUVBXKFVDA-UHFFFAOYSA-N cyclohexylsulfanylcyclohexane Chemical compound C1CCCCC1SC1CCCCC1 FTAORUVBXKFVDA-UHFFFAOYSA-N 0.000 description 1
- FHADSMKORVFYOS-UHFFFAOYSA-N cyclooctanol Chemical compound OC1CCCCCCC1 FHADSMKORVFYOS-UHFFFAOYSA-N 0.000 description 1
- 125000004410 cyclooctyloxy group Chemical group C1(CCCCCCC1)O* 0.000 description 1
- DRTWGLDIOYISRH-UHFFFAOYSA-N cyclooctyloxycyclooctane Chemical compound C1CCCCCCC1OC1CCCCCCC1 DRTWGLDIOYISRH-UHFFFAOYSA-N 0.000 description 1
- UAIZOVQYOPNYIW-UHFFFAOYSA-N cyclooctylsulfanylcyclooctane Chemical compound C1CCCCCCC1SC1CCCCCCC1 UAIZOVQYOPNYIW-UHFFFAOYSA-N 0.000 description 1
- XCIXKGXIYUWCLL-UHFFFAOYSA-N cyclopentanol Chemical compound OC1CCCC1 XCIXKGXIYUWCLL-UHFFFAOYSA-N 0.000 description 1
- 125000001887 cyclopentyloxy group Chemical group C1(CCCC1)O* 0.000 description 1
- BOTLEXFFFSMRLQ-UHFFFAOYSA-N cyclopentyloxycyclopentane Chemical compound C1CCCC1OC1CCCC1 BOTLEXFFFSMRLQ-UHFFFAOYSA-N 0.000 description 1
- MSXKFSFICXVOAJ-UHFFFAOYSA-N cyclopentylsulfanylcyclopentane Chemical compound C1CCCC1SC1CCCC1 MSXKFSFICXVOAJ-UHFFFAOYSA-N 0.000 description 1
- YSRSBDQINUMTIF-UHFFFAOYSA-N decane-1,2-diol Chemical compound CCCCCCCCC(O)CO YSRSBDQINUMTIF-UHFFFAOYSA-N 0.000 description 1
- QECQLMGRLZYSEW-UHFFFAOYSA-N decoxybenzene Chemical compound CCCCCCCCCCOC1=CC=CC=C1 QECQLMGRLZYSEW-UHFFFAOYSA-N 0.000 description 1
- YKPAJSTVQORZSF-UHFFFAOYSA-N decoxycyclohexane Chemical compound CCCCCCCCCCOC1CCCCC1 YKPAJSTVQORZSF-UHFFFAOYSA-N 0.000 description 1
- LWQKAKYEXISZJN-UHFFFAOYSA-N decoxymethylbenzene Chemical compound CCCCCCCCCCOCC1=CC=CC=C1 LWQKAKYEXISZJN-UHFFFAOYSA-N 0.000 description 1
- ANWCICBGKAHUEY-UHFFFAOYSA-N decyl carbamate Chemical compound CCCCCCCCCCOC(N)=O ANWCICBGKAHUEY-UHFFFAOYSA-N 0.000 description 1
- DQXXYXQMGCYQRE-UHFFFAOYSA-N decylsulfanylcyclohexane Chemical compound CCCCCCCCCCSC1CCCCC1 DQXXYXQMGCYQRE-UHFFFAOYSA-N 0.000 description 1
- HHCZYYBKCPWBMS-UHFFFAOYSA-N decylurea Chemical compound CCCCCCCCCCNC(N)=O HHCZYYBKCPWBMS-UHFFFAOYSA-N 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229910052805 deuterium Inorganic materials 0.000 description 1
- XYWDPYKBIRQXQS-UHFFFAOYSA-N di-isopropyl sulphide Natural products CC(C)SC(C)C XYWDPYKBIRQXQS-UHFFFAOYSA-N 0.000 description 1
- 125000000950 dibromo group Chemical group Br* 0.000 description 1
- VCJZTATVUDMNLU-UHFFFAOYSA-N dibromomethylbenzene Chemical compound BrC(Br)C1=CC=CC=C1 VCJZTATVUDMNLU-UHFFFAOYSA-N 0.000 description 1
- HJYNWRJCZOLEBZ-UHFFFAOYSA-N dibromomethylcyclopentane Chemical compound BrC(Br)C1CCCC1 HJYNWRJCZOLEBZ-UHFFFAOYSA-N 0.000 description 1
- VKSYBGWRTXFORQ-UHFFFAOYSA-N dibutyl(dimethyl)silane Chemical compound CCCC[Si](C)(C)CCCC VKSYBGWRTXFORQ-UHFFFAOYSA-N 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- WUIZXVIJYDEKPU-UHFFFAOYSA-N dichloromethylcyclohexane Chemical compound ClC(Cl)C1CCCCC1 WUIZXVIJYDEKPU-UHFFFAOYSA-N 0.000 description 1
- BOROJSBBTJGBRP-UHFFFAOYSA-N dichloromethylcyclopentane Chemical compound ClC(Cl)C1CCCC1 BOROJSBBTJGBRP-UHFFFAOYSA-N 0.000 description 1
- OILVSJASOSICMQ-UHFFFAOYSA-N dicyclohexyl(dimethyl)silane Chemical compound C1CCCCC1[Si](C)(C)C1CCCCC1 OILVSJASOSICMQ-UHFFFAOYSA-N 0.000 description 1
- ZEBJPYUECLCDRQ-UHFFFAOYSA-N didecyl carbonate Chemical compound CCCCCCCCCCOC(=O)OCCCCCCCCCC ZEBJPYUECLCDRQ-UHFFFAOYSA-N 0.000 description 1
- GOAUNPQUDWQWCP-UHFFFAOYSA-N didodecyl carbonate Chemical compound CCCCCCCCCCCCOC(=O)OCCCCCCCCCCCC GOAUNPQUDWQWCP-UHFFFAOYSA-N 0.000 description 1
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 1
- UBPGILLNMDGSDS-UHFFFAOYSA-N diethylene glycol diacetate Chemical compound CC(=O)OCCOCCOC(C)=O UBPGILLNMDGSDS-UHFFFAOYSA-N 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- JDZLOJYSBBLXQD-UHFFFAOYSA-N difluoromethylbenzene Chemical compound FC(F)C1=CC=CC=C1 JDZLOJYSBBLXQD-UHFFFAOYSA-N 0.000 description 1
- JOCDQQMYNFSIRO-UHFFFAOYSA-N difluoromethylcyclohexane Chemical compound FC(F)C1CCCCC1 JOCDQQMYNFSIRO-UHFFFAOYSA-N 0.000 description 1
- RUGHMAVBASTTPA-UHFFFAOYSA-N difluoromethylcyclopentane Chemical compound FC(F)C1CCCC1 RUGHMAVBASTTPA-UHFFFAOYSA-N 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- WKLIBSXVDBSEKQ-UHFFFAOYSA-N diheptadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCCOC(=O)OCCCCCCCCCCCCCCCCC WKLIBSXVDBSEKQ-UHFFFAOYSA-N 0.000 description 1
- ZYKOICDLSSOLAN-UHFFFAOYSA-N diheptyl carbonate Chemical compound CCCCCCCOC(=O)OCCCCCCC ZYKOICDLSSOLAN-UHFFFAOYSA-N 0.000 description 1
- RAIOXDBEGGPDRH-UHFFFAOYSA-N dihexadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCOC(=O)OCCCCCCCCCCCCCCCC RAIOXDBEGGPDRH-UHFFFAOYSA-N 0.000 description 1
- JXCHMDATRWUOAP-UHFFFAOYSA-N diisocyanatomethylbenzene Chemical compound O=C=NC(N=C=O)C1=CC=CC=C1 JXCHMDATRWUOAP-UHFFFAOYSA-N 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 1
- WJKVFIFBAASZJX-UHFFFAOYSA-N dimethyl(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](C)(C)C1=CC=CC=C1 WJKVFIFBAASZJX-UHFFFAOYSA-N 0.000 description 1
- YFCVAZGXPLMNDG-UHFFFAOYSA-N dimethyl-bis[[methyl(diphenyl)silyl]oxy]silane Chemical compound C=1C=CC=CC=1[Si](C)(C=1C=CC=CC=1)O[Si](C)(C)O[Si](C)(C=1C=CC=CC=1)C1=CC=CC=C1 YFCVAZGXPLMNDG-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- AZTIBGIAIDOHEN-UHFFFAOYSA-N dinonadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCCCCOC(=O)OCCCCCCCCCCCCCCCCCCC AZTIBGIAIDOHEN-UHFFFAOYSA-N 0.000 description 1
- FHWFURWDUGYUMA-UHFFFAOYSA-N dinonyl carbonate Chemical compound CCCCCCCCCOC(=O)OCCCCCCCCC FHWFURWDUGYUMA-UHFFFAOYSA-N 0.000 description 1
- XZMJPSTVHZJNLE-UHFFFAOYSA-N dioctadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)OCCCCCCCCCCCCCCCCCC XZMJPSTVHZJNLE-UHFFFAOYSA-N 0.000 description 1
- PKPOVTYZGGYDIJ-UHFFFAOYSA-N dioctyl carbonate Chemical compound CCCCCCCCOC(=O)OCCCCCCCC PKPOVTYZGGYDIJ-UHFFFAOYSA-N 0.000 description 1
- YLFONCAVNUZRNG-UHFFFAOYSA-N dipentadecyl carbonate Chemical compound CCCCCCCCCCCCCCCOC(=O)OCCCCCCCCCCCCCCC YLFONCAVNUZRNG-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- JTUSQSYFVVBAED-UHFFFAOYSA-N ditetradecyl carbonate Chemical compound CCCCCCCCCCCCCCOC(=O)OCCCCCCCCCCCCCC JTUSQSYFVVBAED-UHFFFAOYSA-N 0.000 description 1
- GKVQWKKFAVIRMY-UHFFFAOYSA-N ditridecyl carbonate Chemical compound CCCCCCCCCCCCCOC(=O)OCCCCCCCCCCCCC GKVQWKKFAVIRMY-UHFFFAOYSA-N 0.000 description 1
- CNHLKAHXHBXEHS-UHFFFAOYSA-N diundecyl carbonate Chemical compound CCCCCCCCCCCOC(=O)OCCCCCCCCCCC CNHLKAHXHBXEHS-UHFFFAOYSA-N 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- CNRDTAOOANTPCG-UHFFFAOYSA-N dodecyl carbamate Chemical compound CCCCCCCCCCCCOC(N)=O CNRDTAOOANTPCG-UHFFFAOYSA-N 0.000 description 1
- WRNOAELBRPKVHC-UHFFFAOYSA-N dodecylurea Chemical compound CCCCCCCCCCCCNC(N)=O WRNOAELBRPKVHC-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 229940035423 ethyl ether Drugs 0.000 description 1
- MSFZETFHSWQOQR-UHFFFAOYSA-N ethylsulfanylcyclohexane Chemical compound CCSC1CCCCC1 MSFZETFHSWQOQR-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- FBPFZTCFMRRESA-GUCUJZIJSA-N galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- DLRVVLDZNNYCBX-CQUJWQHSSA-N gentiobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-CQUJWQHSSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- XSBIDHSRRHZHPZ-UHFFFAOYSA-N heptadecyl carbamate Chemical compound CCCCCCCCCCCCCCCCCOC(N)=O XSBIDHSRRHZHPZ-UHFFFAOYSA-N 0.000 description 1
- ZZUXQMKCDKYDRB-UHFFFAOYSA-N heptadecylurea Chemical compound CCCCCCCCCCCCCCCCCNC(N)=O ZZUXQMKCDKYDRB-UHFFFAOYSA-N 0.000 description 1
- 125000002192 heptalenyl group Chemical group 0.000 description 1
- AXMPFOXRWZXZFA-UHFFFAOYSA-N heptyl carbamate Chemical compound CCCCCCCOC(N)=O AXMPFOXRWZXZFA-UHFFFAOYSA-N 0.000 description 1
- LDNJCDRFTFLQLF-UHFFFAOYSA-N heptylurea Chemical compound CCCCCCCNC(N)=O LDNJCDRFTFLQLF-UHFFFAOYSA-N 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- DJPWEXJHYGPFIU-UHFFFAOYSA-N hexadecyl carbamate Chemical compound CCCCCCCCCCCCCCCCOC(N)=O DJPWEXJHYGPFIU-UHFFFAOYSA-N 0.000 description 1
- NKOHYPZTBAEGGO-UHFFFAOYSA-N hexadecylurea Chemical compound CCCCCCCCCCCCCCCCNC(N)=O NKOHYPZTBAEGGO-UHFFFAOYSA-N 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 description 1
- ROASJEHPZNKHOF-UHFFFAOYSA-N hexyl carbamate Chemical compound CCCCCCOC(N)=O ROASJEHPZNKHOF-UHFFFAOYSA-N 0.000 description 1
- JUVJQIPDVWOVNP-UHFFFAOYSA-N hexylurea Chemical compound CCCCCCNC(N)=O JUVJQIPDVWOVNP-UHFFFAOYSA-N 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 125000003427 indacenyl group Chemical group 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 1
- INBDPOJZYZJUDA-UHFFFAOYSA-N methanedithiol Chemical compound SCS INBDPOJZYZJUDA-UHFFFAOYSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- WXEHBUMAEPOYKP-UHFFFAOYSA-N methylsulfanylethane Chemical compound CCSC WXEHBUMAEPOYKP-UHFFFAOYSA-N 0.000 description 1
- XGEGHDBEHXKFPX-NJFSPNSNSA-N methylurea Chemical compound [14CH3]NC(N)=O XGEGHDBEHXKFPX-NJFSPNSNSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- UNFUYWDGSFDHCW-UHFFFAOYSA-N monochlorocyclohexane Chemical compound ClC1CCCCC1 UNFUYWDGSFDHCW-UHFFFAOYSA-N 0.000 description 1
- YNTOKMNHRPSGFU-UHFFFAOYSA-N n-Propyl carbamate Chemical compound CCCOC(N)=O YNTOKMNHRPSGFU-UHFFFAOYSA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- RIVIDPPYRINTTH-UHFFFAOYSA-N n-ethylpropan-2-amine Chemical compound CCNC(C)C RIVIDPPYRINTTH-UHFFFAOYSA-N 0.000 description 1
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
- LRQBHTDUZSOFMG-UHFFFAOYSA-N nonadecyl carbamate Chemical compound CCCCCCCCCCCCCCCCCCCOC(N)=O LRQBHTDUZSOFMG-UHFFFAOYSA-N 0.000 description 1
- IEHDXHZRPHVZEA-UHFFFAOYSA-N nonadecylurea Chemical compound CCCCCCCCCCCCCCCCCCCNC(N)=O IEHDXHZRPHVZEA-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- LUZHBLZCTFCXSQ-UHFFFAOYSA-N nonoxycyclohexane Chemical compound CCCCCCCCCOC1CCCCC1 LUZHBLZCTFCXSQ-UHFFFAOYSA-N 0.000 description 1
- ZOTZDOHZKCYLFS-UHFFFAOYSA-N nonoxymethylbenzene Chemical compound CCCCCCCCCOCC1=CC=CC=C1 ZOTZDOHZKCYLFS-UHFFFAOYSA-N 0.000 description 1
- ITCNMBZZNCMZMS-UHFFFAOYSA-N nonyl carbamate Chemical compound CCCCCCCCCOC(N)=O ITCNMBZZNCMZMS-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- UWOOQFOHVDZTOD-UHFFFAOYSA-N nonylurea Chemical compound CCCCCCCCCNC(N)=O UWOOQFOHVDZTOD-UHFFFAOYSA-N 0.000 description 1
- SFBTTWXNCQVIEC-UHFFFAOYSA-N o-Vinylanisole Chemical compound COC1=CC=CC=C1C=C SFBTTWXNCQVIEC-UHFFFAOYSA-N 0.000 description 1
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
- IULGYNXPKZHCIA-UHFFFAOYSA-N octadecyl carbamate Chemical compound CCCCCCCCCCCCCCCCCCOC(N)=O IULGYNXPKZHCIA-UHFFFAOYSA-N 0.000 description 1
- GJNDMSSZEBNLPU-UHFFFAOYSA-N octadecylurea Chemical compound CCCCCCCCCCCCCCCCCCNC(N)=O GJNDMSSZEBNLPU-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- ZPIRTVJRHUMMOI-UHFFFAOYSA-N octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1 ZPIRTVJRHUMMOI-UHFFFAOYSA-N 0.000 description 1
- KBWPMBBIEDAAKA-UHFFFAOYSA-N octoxycyclohexane Chemical compound CCCCCCCCOC1CCCCC1 KBWPMBBIEDAAKA-UHFFFAOYSA-N 0.000 description 1
- NXZJVIKVJAKQOU-UHFFFAOYSA-N octoxymethylbenzene Chemical compound CCCCCCCCOCC1=CC=CC=C1 NXZJVIKVJAKQOU-UHFFFAOYSA-N 0.000 description 1
- YPNZTHVEMNUDND-UHFFFAOYSA-N octyl carbamate Chemical compound CCCCCCCCOC(N)=O YPNZTHVEMNUDND-UHFFFAOYSA-N 0.000 description 1
- VIWUSEFNWFZOTP-UHFFFAOYSA-N octylsulfanylcyclohexane Chemical compound CCCCCCCCSC1CCCCC1 VIWUSEFNWFZOTP-UHFFFAOYSA-N 0.000 description 1
- UBBIDOUCHSVOFY-UHFFFAOYSA-N octylurea Chemical compound CCCCCCCCNC(N)=O UBBIDOUCHSVOFY-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- KFKNEHAORPTUSX-UHFFFAOYSA-N pentadecyl carbamate Chemical compound CCCCCCCCCCCCCCCOC(N)=O KFKNEHAORPTUSX-UHFFFAOYSA-N 0.000 description 1
- IONSVUKMXBLZAZ-UHFFFAOYSA-N pentadecylurea Chemical compound CCCCCCCCCCCCCCCNC(N)=O IONSVUKMXBLZAZ-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- GUVXZFRDPCKWEM-UHFFFAOYSA-N pentalene group Chemical group C1=CC=C2C=CC=C12 GUVXZFRDPCKWEM-UHFFFAOYSA-N 0.000 description 1
- MYDQAEQZZKVJSL-UHFFFAOYSA-N pentyl carbamate Chemical compound CCCCCOC(N)=O MYDQAEQZZKVJSL-UHFFFAOYSA-N 0.000 description 1
- MONRWRVYLOHUFA-UHFFFAOYSA-N pentylurea Chemical compound CCCCCNC(N)=O MONRWRVYLOHUFA-UHFFFAOYSA-N 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical group C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- DLRJIFUOBPOJNS-UHFFFAOYSA-N phenetole Chemical compound CCOC1=CC=CC=C1 DLRJIFUOBPOJNS-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- BSCCSDNZEIHXOK-UHFFFAOYSA-N phenyl carbamate Chemical compound NC(=O)OC1=CC=CC=C1 BSCCSDNZEIHXOK-UHFFFAOYSA-N 0.000 description 1
- 125000000109 phenylethoxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])O* 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 229930015698 phenylpropene Natural products 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 229950006800 prenderol Drugs 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- ZQZJKHIIQFPZCS-UHFFFAOYSA-N propylurea Chemical compound CCCNC(N)=O ZQZJKHIIQFPZCS-UHFFFAOYSA-N 0.000 description 1
- 125000005581 pyrene group Chemical group 0.000 description 1
- UBQKCCHYAOITMY-UHFFFAOYSA-N pyridin-2-ol Chemical compound OC1=CC=CC=N1 UBQKCCHYAOITMY-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- HEBKCHPVOIAQTA-ZXFHETKHSA-N ribitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)CO HEBKCHPVOIAQTA-ZXFHETKHSA-N 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229960002317 succinimide Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- REWDXIKKFOQRID-UHFFFAOYSA-N tetrabutylsilane Chemical compound CCCC[Si](CCCC)(CCCC)CCCC REWDXIKKFOQRID-UHFFFAOYSA-N 0.000 description 1
- 125000001935 tetracenyl group Chemical group C1(=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C12)* 0.000 description 1
- WBMDWTWRKMOVCT-UHFFFAOYSA-N tetracyclohexylsilane Chemical compound C1CCCCC1[Si](C1CCCCC1)(C1CCCCC1)C1CCCCC1 WBMDWTWRKMOVCT-UHFFFAOYSA-N 0.000 description 1
- IUODKOVOMUTKCL-UHFFFAOYSA-N tetradecyl carbamate Chemical compound CCCCCCCCCCCCCCOC(N)=O IUODKOVOMUTKCL-UHFFFAOYSA-N 0.000 description 1
- IPOBMWQSKXACEW-UHFFFAOYSA-N tetradecylurea Chemical compound CCCCCCCCCCCCCCNC(N)=O IPOBMWQSKXACEW-UHFFFAOYSA-N 0.000 description 1
- QSUJAUYJBJRLKV-UHFFFAOYSA-M tetraethylazanium;fluoride Chemical compound [F-].CC[N+](CC)(CC)CC QSUJAUYJBJRLKV-UHFFFAOYSA-M 0.000 description 1
- VCZQFJFZMMALHB-UHFFFAOYSA-N tetraethylsilane Chemical compound CC[Si](CC)(CC)CC VCZQFJFZMMALHB-UHFFFAOYSA-N 0.000 description 1
- MYJBEPMHOLQMFJ-UHFFFAOYSA-N tetrahexylsilane Chemical compound CCCCCC[Si](CCCCCC)(CCCCCC)CCCCCC MYJBEPMHOLQMFJ-UHFFFAOYSA-N 0.000 description 1
- IHZHBXXJOFDTPG-UHFFFAOYSA-M tetramethylazanium;fluoride;hydrate Chemical compound O.[F-].C[N+](C)(C)C IHZHBXXJOFDTPG-UHFFFAOYSA-M 0.000 description 1
- JLAVCPKULITDHO-UHFFFAOYSA-N tetraphenylsilane Chemical compound C1=CC=CC=C1[Si](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 JLAVCPKULITDHO-UHFFFAOYSA-N 0.000 description 1
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- QALJFPILSNRZQT-UHFFFAOYSA-N tridecyl carbamate Chemical compound CCCCCCCCCCCCCOC(N)=O QALJFPILSNRZQT-UHFFFAOYSA-N 0.000 description 1
- VIFASLUWVPBABR-UHFFFAOYSA-N tridecylurea Chemical compound CCCCCCCCCCCCCNC(N)=O VIFASLUWVPBABR-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 125000005580 triphenylene group Chemical group 0.000 description 1
- RXPQRKFMDQNODS-UHFFFAOYSA-N tripropyl phosphate Chemical compound CCCOP(=O)(OCCC)OCCC RXPQRKFMDQNODS-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- IDGNOEREFKPSJG-UHFFFAOYSA-N undecyl carbamate Chemical compound CCCCCCCCCCCOC(N)=O IDGNOEREFKPSJG-UHFFFAOYSA-N 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
- C08G18/022—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
- C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/16—Preparation of derivatives of isocyanic acid by reactions not involving the formation of isocyanate groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/18—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/18—Separation; Purification; Stabilisation; Use of additives
- C07C263/20—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/14—Derivatives of isocyanic acid containing at least two isocyanate groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C269/02—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups from isocyanates with formation of carbamate groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/20—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by nitrogen atoms not being part of nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/40—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings
- C07C271/42—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/52—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by nitrogen atoms not being part of nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/40—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings
- C07C271/56—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a ring other than a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
- C08G18/027—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing urethodione groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0809—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8125—Unsaturated isocyanates or isothiocyanates having two or more isocyanate or isothiocyanate groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
- C09K15/24—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen containing a phenol or quinone moiety
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
Definitions
- the present invention relates to a polyisocyanate composition and an isocyanate polymer composition produced using the polyisocyanate composition.
- Polyurethane having a urethane bond is a polymer produced mainly by the reaction of a difunctional or higher isocyanate with a difunctional or higher alcohol, and is excellent in tensile strength, abrasion resistance and oil resistance.
- Flexible foam, rigid foam, elastomer It is used in a wide range of fields such as adhesives, paints, and binders.
- polyurethanes made from chain or cyclic aliphatic isocyanates are excellent in weather resistance and light resistance, and are used in fields requiring appearance quality such as baking coating, automobile clear coating materials, coil coating materials and the like.
- Diisocyanate which is a difunctional isocyanate, may be used as the isocyanate.
- the following formulas (a) to (c) are used.
- diisocyanate is polymerized by the reaction shown and used as an isocyanate polymer.
- R represents a divalent organic group
- R ′ represents a trivalent organic group
- Patent Documents 1 to 6 disclose biuret type isocyanate polymers.
- Patent Documents 7 to 10 disclose isocyanurate type isocyanate polymers.
- the allophanate type isocyanate polymer is disclosed in Patent Documents 11 and 12.
- polyurethane is required to be less colored when used in a field where appearance quality is required.
- it is important not only to not color the polyurethane-forming reaction, but also to reduce the coloration of the starting isocyanate (bifunctional or higher polyisocyanate).
- isocyanate is oxidized by oxygen in the air and tends to be altered or colored.
- an isocyanate polymer is produced by polymerization of diisocyanate, there is a tendency that the isocyanate is likely to be colored due to the catalyst or solvent used in the polymerization reaction.
- Patent Document 13 discloses a method of treating with a peroxide after modifying the isocyanate in order to produce a polyisocyanate for a light-colored polyurethane lacquer.
- Patent Document 14 discusses a method for producing an isocyanate having reduced coloring by bringing an ozone-containing gas into contact with a colored isocyanate.
- Patent Document 15 a method for producing an isocyanate with reduced coloring by irradiating colored isocyanate with light having a wavelength of 200 to 600 nm is also studied.
- the present invention provides a method for producing a distillation-purified isocyanate capable of obtaining a polyisocyanate whose coloring is sufficiently suppressed, and a polyisocyanate composition for carrying out the method.
- Another object of the present invention is to provide a method for producing an isocyanate polymer in which coloring is suppressed by polymerization of polyisocyanate, and a polyisocyanate composition for carrying out the method.
- an isocyanate composition in which coloring is sufficiently suppressed by distilling and separating isocyanate by a distillation purification method using an isocyanate composition comprising a specific component. It has been found that an isocyanate polymer whose coloring is sufficiently suppressed can be produced by the production method using the isocyanate composition, and the present invention has been completed.
- the present invention relates to the following contents.
- [1] Based on the total mass of the polyisocyanate composition, 97 wt% or more of polyisocyanate and 2.0 to 1.0 ⁇ 10 4 mass ppm of a compound different from the polyisocyanate and at least 1 A compound having one unsaturated bond, or a hydrocarbon compound, an ether compound, a sulfide compound, a halogenated hydrocarbon compound, a silicon-containing hydrocarbon compound, of 5.0 mass ppm to 2.0 ⁇ 10 4 mass ppm A polyisocyanate composition containing at least one inert compound selected from the group consisting of a silicon ether compound and a silicon-containing sulfide compound.
- [2] containing the polyisocyanate and the compound having at least one unsaturated bond, wherein the unsaturated bond is a carbon-carbon double bond or a carbon-oxygen double bond.
- the composition according to [2], wherein the compound having at least one unsaturated bond includes a carbonic acid derivative.
- the carbonic acid derivative is at least one carbonic acid ester or N-unsubstituted carbamic acid ester selected from the group consisting of dimethyl carbonate, diethyl carbonate, dibutyl carbonate, dipentyl carbonate and dihexyl carbonate.
- composition according to [3] or [4], wherein the compound having at least one unsaturated bond further comprises a compound represented by the following formula (1).
- R 1 and R 2 each independently represents an organic group, a represents an integer of 1 to 5, b represents an integer of 0 to 4, and the sum of a and b is 2 to 5.
- [6] At least one selected from the group consisting of the hydrocarbon compound, the ether compound, the sulfide compound, the halogenated hydrocarbon compound, the silicon-containing hydrocarbon compound, the silicon-containing ether compound, and the silicon-containing sulfide compound.
- the compound containing the polyisocyanate and the compound having at least one unsaturated bond, and the compound having the at least one unsaturated bond includes a compound represented by the following formula (1): [1] ]
- the composition of description (Wherein R 1 and R 2 each independently represents an organic group, a represents an integer of 1 to 5, b represents an integer of 0 to 4, and the sum of a and b is 2 to 5. )
- [8] At least one selected from the group consisting of the hydrocarbon compound, the ether compound, the sulfide compound, the halogenated hydrocarbon compound, the silicon-containing hydrocarbon compound, the silicon-containing ether compound, and the silicon-containing sulfide compound.
- the method further comprises a compound having at least one unsaturated bond, wherein the unsaturated bond is a carbon-carbon double bond or a carbon-oxygen double bond,
- the composition according to [9], wherein the double bond between is not a carbon-carbon double bond constituting an aromatic ring.
- composition according to [10], wherein the compound having at least one unsaturated bond includes a carbonic acid derivative.
- the carbonic acid derivative is at least one carbonic acid ester or N-unsubstituted carbamic acid ester selected from the group consisting of dimethyl carbonate, diethyl carbonate, dibutyl carbonate, dipentyl carbonate and dihexyl carbonate.
- Composition [13] The composition according to [5] or [7], wherein the compound represented by the formula (1) is a compound represented by the following formula (1-3) or (1-4). (In the formula, each R 1 independently represents an organic group.) [14] The composition according to [13], wherein R 1 is a hexamethylene group.
- the compound having at least one unsaturated bond is at least one compound selected from the group consisting of styrene, ⁇ -methylstyrene, pentene, and octene. .
- a method for preventing coloration in distillation purification of a polyisocyanate, wherein before the distillation purification, the polyisocyanate is a compound different from the polyisocyanate and having at least one unsaturated bond A method comprising a step of adding 2.0 mass ppm to 1.0 ⁇ 10 4 mass ppm based on the total amount of polyisocyanate.
- a polyisocyanate composition comprising a polyisocyanate distilled and purified by the method according to [17].
- a process for producing an isocyanate polymer comprising reacting the polyisocyanate contained in the composition according to any one of [1] to [16] and [18], wherein the polyisocyanate contained in the composition Is a diisocyanate, and the isocyanate polymer comprises a unit represented by the following formula (2) and the following formulas (3), (4), (5), (6), (7), (8) and ( 9) each having at least one unit selected from the group consisting of the units represented by the formula (9), and a nitrogen atom constituting the isocyanate polymer is bonded to a carbon atom.
- each R 3 independently represents a divalent hydrocarbon group
- each R 4 independently represents a monovalent organic group.
- a method for producing a purified polyisocyanate capable of obtaining a polyisocyanate whose coloring is sufficiently suppressed and a polyisocyanate composition for carrying out the method.
- the method of suppressing the coloring at the time of distillation purification of polyisocyanate is provided.
- organometallic compounds and metal complexes include organometallic compounds and metal complexes.
- terms such as “organic group” and “substituent” mean groups composed of atoms that do not contain metal atoms and / or metalloids. Further, in this embodiment, preferably, H (hydrogen atom), C (carbon atom), N (nitrogen atom), O (oxygen atom), S (sulfur atom), Cl (chlorine atom), Br (bromine atom) , “Organic compounds”, “organic groups” or “substituents” composed of atoms selected from I (iodine atoms) are used.
- an aliphatic compound is a definition of a group in line with an aliphatic compound based on the 1995 IUPAC recommendation. In this recommendation, an aliphatic compound is defined as “Acyclic or cyclic, saturated or unsaturated carbon compounds, or excluded aromatic compounds”.
- the “aliphatic compound” used in the description of the present embodiment contains both saturated and unsaturated, chain and cyclic, and the above-described H (hydrogen atom); C (carbon atom); N ( Nitrogen atom); O (oxygen atom); S (sulfur atom); Si (silicon atom); composed of atoms selected from halogen atoms selected from Cl (chlorine atom), Br (bromine atom) and I (iodine atom) “Organic compound”, “organic group” or “substituent”.
- an aromatic group such as an aralkyl group is bonded to an aliphatic group
- an aliphatic group substituted with an aromatic group or “a group consisting of an aliphatic group bonded with an aromatic group”
- a non-aromatic reactive group including an aralkyl group, an alkyl group, etc. is an “aliphatic group optionally substituted with an aromatic group” or an “aliphatic group optionally substituted with an aromatic group”.
- active hydrogen means a hydrogen atom bonded to an oxygen atom, a sulfur atom, a nitrogen atom, a silicon atom, etc. (excluding an aromatic hydroxy group), and a hydrogen atom of a terminal methine group. Point to. “Active hydrogen” includes, for example, —C ( ⁇ O) OH group, —C ( ⁇ O) H group, —SH group, —SO 3 H group, —SO 2 H group, —SOH group, —NH 2 group. , —NH— group, —SiH group, —C ⁇ CH group and the like.
- a hydrogen atom contained in a hydroxy group is included in the definition of “active hydrogen”, but unless otherwise specified, a hydroxy group (—OH group) is a group containing “active hydrogen”. Not included.
- Examples of the compound having a hydroxy group include alcohols and aromatic hydroxy compounds.
- aromatic hydroxy compound refers to phenols described in the definition of IUPAC (Rule C-202) “one or more hydroxy groups are bonded to a benzene ring or another arene ring. Bound compound (Compounds having one or more hydroxyl groups attached to a benzene or other area ring.) ”.
- the polyisocyanate according to this embodiment is not particularly limited as long as it is a compound having two or more isocyanate groups, but a compound represented by the following formula (10) is preferably used.
- c represents an integer of 2 to 5
- R 1 represents a c-valent organic group.
- R 1 is preferably an organic group having 1 to 85 carbon atoms.
- R 1 represents an aliphatic group, an aromatic group, or a group formed by bonding an aliphatic group and an aromatic group, specifically, a cyclic hydrocarbon group (monocyclic hydrocarbon group, condensed Polycyclic hydrocarbon group, bridged cyclic hydrocarbon group, spiro hydrocarbon group, ring assembly hydrocarbon group, cyclic hydrocarbon group hydrocarbon group with side chain), heterocyclic group, heterocyclic spiro group, hetero A cyclic group such as a bridged cyclic group, a non-cyclic hydrocarbon group, a group bonded to one or more groups selected from a non-cyclic hydrocarbon group and a cyclic group, and the above group is a specific nonmetal And a group bonded through a covalent bond with an atom (carbon, oxygen, nitrogen, sulfur or silicon).
- a cyclic hydrocarbon group monocyclic hydrocarbon group, condensed Polycyclic hydrocarbon group, bridged cyclic hydrocarbon group, spiro hydrocarbon group, ring assembly
- the covalent bond with a specific nonmetallic atom is, for example, a state in which the above-described group is covalently bonded to any group represented by the following formulas (11) to (19).
- the R 1 group that can be preferably used in the present embodiment is an acyclic carbonization selected from an aliphatic group, an aromatic group, and a group in which an aliphatic group and an aromatic group are combined from the viewpoint of the difficulty of side reactions.
- Hydrogen group, cyclic hydrocarbon group (monocyclic hydrocarbon group, condensed polycyclic hydrocarbon group, bridged cyclic hydrocarbon group, spiro hydrocarbon group, ring assembly hydrocarbon group, cyclic hydrocarbon with side chain A group selected from the group consisting of a group) and a group (group substituted with each other) to which at least one group selected from the above group is bonded, and a group having 1 to 85 carbon atoms.
- a group having 1 to 70 carbon atoms is preferable. More preferred is a group having 1 to 13 carbon atoms.
- R 1 group is a group having 6 to 85 carbon atoms containing at least one aromatic ring optionally substituted with an aliphatic group and / or an aromatic group
- the aromatic group in R 1 group is An aromatic polyisocyanate in which the isocyanate group is substituted and c is an integer of 2 to 5
- the R 1 group is an aliphatic group having 1 to 85 carbon atoms which may be substituted with an aromatic group
- c is an aliphatic polyisocyanate having 2 or 3 carbon atoms.
- a more preferable aliphatic group is an aliphatic group having 6 to 70 carbon atoms, and is a chain hydrocarbon group, a cyclic hydrocarbon group, or at least one selected from the chain hydrocarbon group and the cyclic hydrocarbon group.
- a group to which a group of species is bonded for example, a cyclic hydrocarbon group substituted with a chain hydrocarbon group, a chain hydrocarbon group substituted with a cyclic hydrocarbon group, or the like).
- Aromatic polyisocyanate R 1 group is a group having 6 to 85 carbon atoms containing one or more aromatic rings which may be aliphatic and / or aromatically substituted, and the aromatic group in R 1 group
- An aromatic polyisocyanate in which one or more hydrogen atoms are substituted with an isocyanate group and a is 2.
- R 1 group is a group having 6 to 70 carbon atoms and c is an integer of 2 to 5, and in consideration of fluidity, R 1 group is more preferably An aromatic polyisocyanate having 6 to 13 carbon atoms and containing one or more “isocyanate-substituted” aromatic rings, wherein c is an integer of 2 to 5; Group, aryl group and aralkyl group may be substituted.
- aromatic polyisocyanates include diisocyanatobenzene, diisocyanatotoluene, diphenylmethane diisocyanate, diisocyanatomesitylene, diisocyanatobiphenyl, diisocyanatodibenzyl, bis (isocyanatophenyl) propane, and bis (isocyanato).
- Phenyl) ether bis (isocyanatophenoxyethane), diisocyanatoxylene, diisocyanatoanisole, diisocyanatophenetole, diisocyanatonaphthalene, diisocyanato-methylbenzene, diisocyanato-methylpyridine, diisocyanato-methylnaphthalene, and
- the polymethylene polyphenyl polyamine represented by following formula (20) can be mentioned.
- g is an integer of 0-6.
- Aliphatic polyisocyanate The polyisocyanate represented by the formula (10) is an aliphatic polyisocyanate in which R 1 group is an aliphatic group having 1 to 85 carbon atoms and c is 2 or 3. The aliphatic group may be further substituted with an aromatic group. Further preferred polyisocyanates are aliphatic polyisocyanates in which the aliphatic group is a chain hydrocarbon group, a cyclic hydrocarbon group, or a group composed of a chain hydrocarbon group and a cyclic hydrocarbon group.
- the R 1 group is an aliphatic group, and includes an acyclic hydrocarbon group and a cyclic hydrocarbon group having 1 to 70 carbon atoms, and an acyclic hydrocarbon group and a cyclic hydrocarbon group. It is a constituent group, and c is an aliphatic polyisocyanate having 2 or 3. From the viewpoint of fluidity when producing a large amount industrially, most preferably, the R 1 group is an acyclic hydrocarbon group having 6 to 13 carbon atoms, a cyclic hydrocarbon group, and an acyclic carbonization. It is an aliphatic polyisocyanate that is a group composed of a hydrogen group and a cyclic hydrocarbon group. That is, the R 1 group is a group composed of a linear and / or branched alkyl group, a cycloalkyl group, and a linear and / or branched alkyl group and the cycloalkyl group.
- Aliphatic diisocyanates such as, for example, ethylene diisocyanate, diisocyanatopropane, diisocyanatobutane, diisocyanatopentane, diisocyanatohexane, diisocyanatodecane; triisocyanatohexane, triisocyanatono Aliphatic triisocyanates such as nan and triisocyanatodecane; diisocyanatocyclobutane, diisocyanatocyclohexane, 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate (also referred to as “isophorone diisocyanate”), methylenebis ( And substituted cycloaliphatic isocyanates such as cyclohexyl isocyanate).
- diisocyanates having two isocyanate groups in one molecule are preferable.
- Hexamethylene diisocyanate or isophorone diisocyanate is more preferred from the viewpoint of being suitable for applications requiring weather resistance and heat-resistant yellowing and being industrially easily available.
- the said polyisocyanate may be used independently or may use 2 or more types together.
- the polyisocyanate composition of the present embodiment includes a compound having at least one unsaturated bond other than polyisocyanate and / or at least one compound selected from the group consisting of compounds A to E described later together with polyisocyanate. , Containing.
- the compound having an unsaturated bond according to the present embodiment is preferably such that the unsaturated bond is a carbon-carbon unsaturated bond or a carbon-nitrogen unsaturated.
- the unsaturated bond is preferably a compound that is a double bond, and a carbon-carbon double bond (C ⁇ C) or a carbon-oxygen double bond (C ⁇ O). ) Is more preferable.
- the carbon-carbon double bond may be a carbon-carbon double bond constituting an aromatic ring, but in this embodiment, the carbon-carbon double bond constituting the aromatic ring is preferably used. It is not a double bond.
- Examples of such a compound include a carbonic acid derivative, a compound represented by the following formula (1), and a compound represented by the following formula (21).
- R 1 and R 2 each independently represents an organic group, a represents an integer of 1 to 5, b represents an integer of 0 to 4, and the sum of a and b is 2 to 5.
- R 5 , R 6 , R 7 and R 8 each independently represent a hydrogen atom, a halogen atom or an organic group having 1 to 10 carbon atoms, and R 5 to R 8 are not hydrogen atoms at the same time, d Represents an integer of 1 to 3.
- the carbonic acid derivative according to this embodiment refers to a compound represented by the following formula (22).
- X represents an amino group which may be substituted with an organic group having 1 to 20 carbon atoms
- Y is substituted with an organic group having 1 to 20 carbon atoms or an organic group having 0 to 20 carbon atoms.
- Examples of the compound represented by the above formula (22) include urea compounds, N-unsubstituted carbamic acid esters and carbonate esters.
- the urea compound is a compound having at least one urea bond in the molecule, and preferably a compound having one urea bond, and is represented by the following formula (23).
- R 9 , R 10 , R 11 and R 12 are each independently an aliphatic group having 1 to 20 carbon atoms, an aliphatic group substituted with an aromatic compound having 7 to 20 carbon atoms, carbon An aromatic group having 6 to 20 atoms or a hydrogen atom is shown.
- the total number of carbon atoms constituting R 9 and R 11 is an integer from 0 to 20, and the total number of carbon atoms constituting R 10 and R 12 is an integer from 0 to 20.
- R 9 , R 10 , R 11 and R 12 are each a hydrogen atom; methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, Chain alkyl groups such as dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group; phenyl group, methylphenyl group, ethylphenyl group, propylphenyl group, butylphenyl group, pentyl Phenyl group, hexylphenyl group, heptylphenyl group, octylphenyl group, nonylphenyl group, de
- urea compound represented by the formula (23) examples include urea, methylurea, ethylurea, propylurea, butylurea, pentylurea, hexylurea, heptylurea, octylurea, nonylurea, decylurea, undecyl.
- R 13 represents an aliphatic group having 1 to 50 carbon atoms, an aralkyl group having 7 to 50 carbon atoms, or an aromatic group having 6 to 50 carbon atoms.
- Examples of the aliphatic group for R 13 are groups composed of a specific nonmetallic atom (carbon, oxygen, nitrogen, sulfur, silicon, or halogen atom).
- Preferred examples of the aliphatic group include a chain hydrocarbon group, a cyclic hydrocarbon group, and a group composed of a chain hydrocarbon group and a cyclic hydrocarbon group.
- Examples of the aralkyl group include groups in which a chain or branched alkyl group having 1 to 44 carbon atoms is substituted with an aromatic group having 6 to 49 carbon atoms.
- a preferable aromatic group is a group composed of a specific nonmetallic atom (carbon, oxygen, nitrogen, sulfur, silicon or halogen atom), and is a monocyclic aromatic group or a condensed polycyclic aromatic group.
- a substituted anthryl group is a group composed of a specific nonmetallic atom (carbon, oxygen, nitrogen, sulfur, silicon or halogen atom), and is a monocyclic aromatic group or a condensed polycyclic aromatic group.
- Examples of the aromatic group of R 13 are groups composed of a specific nonmetallic atom (carbon, oxygen, nitrogen, sulfur, silicon or halogen atom), which are monocyclic aromatic groups, condensed polycyclic groups
- An aromatic group, a bridged cyclic aromatic group, a ring assembly aromatic group, a heterocyclic aromatic group and the like can be mentioned, preferably a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted A substituted anthryl group.
- Examples of such a substituent include a hydrogen atom and an aliphatic group (a chain hydrocarbon group, a cyclic hydrocarbon group, and a group composed of a chain hydrocarbon group and a cyclic hydrocarbon group). It may be a group composed of an aliphatic group and an aromatic group.
- R 13 specifically, methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group
- a chain alkyl group having 1 to 50 carbon atoms such as pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl, eicosyl group; phenyl group, methylphenyl group, ethylphenyl group, propylphenyl group, butylphenyl group Pentylphenyl group, hexylphenyl group, heptylphenyl group, octylphenyl group, nonylphenyl group, decyl
- N-unsubstituted carbamic acid esters include methyl carbamate, ethyl carbamate, propyl carbamate, butyl carbamate, pentyl carbamate, hexyl carbamate, heptyl carbamate, octyl carbamate, and nonyl carbamate.
- Carbonic acid ester refers to a compound in which one or two hydrogen atoms in carbonic acid CO (OH) 2 are substituted with an aliphatic group or an aromatic group.
- a compound represented by the following formula (25) is preferably used.
- each of R 14 and R 15 independently represents an aliphatic group having 1 to 20 carbon atoms, an aralkyl group having 7 to 50 carbon atoms, or an aromatic group having 6 to 50 carbon atoms.
- Examples of the aliphatic group of R 14 and R 15 include a group composed of a specific nonmetallic atom (carbon, oxygen, nitrogen, sulfur, silicon, or halogen atom).
- Preferred examples of the aliphatic group include a chain hydrocarbon group, a cyclic hydrocarbon group, and a group composed of a chain hydrocarbon group and a cyclic hydrocarbon group.
- An example of an aralkyl group is a group in which a chain alkyl group having 1 to 44 carbon atoms is substituted with an aromatic group having 6 to 49 carbon atoms.
- the aromatic group is preferably a group composed of a specific nonmetallic atom (carbon, oxygen, nitrogen, sulfur, silicon or halogen atom), and is a monocyclic aromatic group or a condensed polycyclic aromatic group.
- Anthryl group is preferably a group composed of a specific nonmetallic atom (carbon, oxygen, nitrogen, sulfur, silicon or halogen atom), and is a monocyclic aromatic group or a condensed polycyclic aromatic group.
- Examples of the aromatic group of R 14 and R 15 are groups composed of specific nonmetallic atoms (carbon, oxygen, nitrogen, sulfur, silicon or halogen atoms), which are monocyclic aromatic groups, condensed Examples include polycyclic aromatic groups, bridged cyclic aromatic groups, ring assembly aromatic groups, heterocyclic aromatic groups, and more preferably, substituted or unsubstituted phenyl groups, substituted or unsubstituted naphthyl groups. , A substituted or unsubstituted anthryl group. Examples of such a substituent include a hydrogen atom and an aliphatic group (a chain hydrocarbon group, a cyclic hydrocarbon group, and a group composed of a chain hydrocarbon group and a cyclic hydrocarbon group). It may be a group composed of an aliphatic group and an aromatic group.
- R 14 and R 15 include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, Chain alkyl groups such as tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group; phenyl group, methylphenyl group, ethylphenyl group, propylphenyl group, butylphenyl group, pentylphenyl group, Hexylphenyl group, heptylphenyl group, octylphenyl group, nonylphenyl group, decylphenyl group, bi
- carbonate esters include dimethyl carbonate, diethyl carbonate, dipropyl carbonate, dibutyl carbonate, dipentyl carbonate, dihexyl carbonate, diheptyl carbonate, dioctyl carbonate, dinonyl carbonate, didecyl carbonate, diundecyl carbonate, didodecyl carbonate, ditridecyl carbonate, ditetradecyl carbonate , Dipentadecyl carbonate, dihexadecyl carbonate, diheptadecyl carbonate, dioctadecyl carbonate, dinonadecyl carbonate, diphenyl carbonate, di (methylphenyl) carbonate, di (ethylphenyl) carbonate, di (propylphenyl) carbonate, di (butylphenyl) carbonate, dicarbonate carbonate (Pentylphenyl), carbonic acid di (hexylphenyl), carbonic
- the carbonate derivative or N-unsubstituted carbamic acid ester is preferable. Carbonic acid esters are more preferable.
- Examples of the unsaturated bond compound according to this embodiment include a compound represented by the following formula (1).
- R 1 has the same meaning as R 1 defined in the above formula (10)
- R 2 represents a monovalent organic group
- a represents an integer of 1 to 5
- b represents an integer of 0 to 4.
- the sum of a and b is c
- c is an integer of 2 to 5.
- R 2 is derived from a hydroxy compound and can be represented as a residue excluding the hydroxy group (—OH) constituting the hydroxy compound, hereinafter, in order to simplify the description of R 2 , R 2 is defined as a hydroxy compound (R 2 OH) obtained by adding a hydroxy group to R 2 .
- the hydroxy compound (R 2 OH) may be an alcohol or an aromatic hydroxy compound.
- R 2 represents a group consisting of an aliphatic group having 1 to 50 carbon atoms or an aliphatic group bonded with an aromatic group having 7 to 50 carbon atoms, substituted with e hydroxy groups, and e is An integer of 1 to 3 is shown. However, R 2 is a group having no active hydrogen other than the hydroxy group. )
- the aliphatic hydrocarbon group for R 2 is an aliphatic hydrocarbon group in which an atom other than a hydrogen atom constituting the above group is a specific nonmetallic atom (carbon, oxygen, nitrogen, sulfur, silicon, or halogen atom). is there.
- Preferred examples of the aliphatic group include a chain hydrocarbon group, a cyclic hydrocarbon group, and a group in which at least one group selected from the chain hydrocarbon group and the cyclic hydrocarbon group is bonded. (For example, a cyclic hydrocarbon group substituted with a chain hydrocarbon group, a chain hydrocarbon group substituted with a cyclic hydrocarbon group, or the like).
- Examples of the aliphatic group substituted with an aromatic group include a chain alkyl group, a cycloalkyl group substituted with an aromatic group, or the above aromatic group having 6 to 49 carbon atoms.
- the aromatic group is preferably a specific nonmetallic atom (carbon, oxygen, nitrogen, sulfur, silicon halogen atom) other than a hydrogen atom constituting the aromatic group.
- Aromatic groups including monocyclic aromatic groups, condensed polycyclic aromatic groups, bridged cyclic aromatic groups, ring assembly aromatic groups, heterocyclic aromatic groups, and more preferably, A substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, or a substituted or unsubstituted anthryl group.
- R 2 examples include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, dodecyl group, octadecyl group, and structural isomers thereof.
- a cycloalkyl group such as cyclopentyl group, cyclohexyl group, cycloheptyl group, cyclooctyl group and structural isomers thereof; methylcyclopentyl group, ethylcyclopentyl group, methylcyclohexyl group, ethylcyclohexyl group, propylcyclohexyl group Groups composed of chain alkyl groups and cycloalkyl groups, such as butylcyclohexyl group, pentylcyclohexyl group, hexylcyclohexyl group, dimethylcyclohexyl group, diethylcyclohexyl group, dibutylcyclohexyl group and structural isomers thereof
- alcohols having one or two alcoholic hydroxy groups are generally low.
- a monoalcohol having one alcoholic hydroxy group is more preferred because of its viscosity.
- alcohol examples include methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol, pentyl alcohol, hexyl alcohol, heptyl alcohol, octyl alcohol, nonyl alcohol, decyl alcohol, dodecyl alcohol, octadecyl alcohol, and structural isomers thereof.
- Unsubstituted alkyl alcohols of the following: Unsubstituted cycloalkyl alcohols such as cyclopentyl alcohol, cyclohexyl alcohol, cycloheptyl alcohol, cyclooctyl alcohol and structural isomers thereof; methylcyclopentyl alcohol, ethylcyclopentyl alcohol, methylcyclohexyl alcohol, ethylcyclohexyl alcohol, propyl Cyclohexyl alcohol, butyl cyclohexyl alcohol , Pentylcyclohexyl alcohol, hexylcyclohexyl alcohol, dimethylcyclohexyl alcohol, diethylcyclohexyl alcohol, dibutylcyclohexyl alcohol, and alcohols composed of chain alkyl groups and cycloalkyl alcohols such as these structural isomers; phenylmethyl alcohol, phenylethyl alcohol And alkyl alcohols substituted with aromatic groups such
- alkyl alcohols having 1 to 20 carbon atoms are preferably used from the viewpoints of availability, solubility of raw materials and products, and the like.
- the hydroxy compound (R 2 OH) is an aromatic hydroxy compound, it can be used industrially and generally has a low viscosity, so that it is monovalent to trivalent (ie, a hydroxy group bonded to an aromatic ring). 1 to 3 integer) aromatic hydroxy compounds are preferred.
- aromatic hydroxy compound the compound represented by following formula (26) is mentioned, for example.
- ring A represents an aromatic hydrocarbon ring which may have a substituent
- ring A may be monocyclic or polycyclic
- f represents an integer of 1 to 3.
- aromatic hydroxy compounds represented by the above formula (26) a monovalent aromatic hydroxy compound in which f is 1 is more preferable.
- the substituent for substituting the aromatic hydrocarbon ring is selected from a halogen atom, an aliphatic group and an aromatic group, and is a cyclic hydrocarbon group (monocyclic hydrocarbon group, condensed polycyclic hydrocarbon group, bridge)
- a cyclic group such as a cyclic hydrocarbon group, a spiro hydrocarbon group, a ring assembly hydrocarbon group, a cyclic hydrocarbon group having a side chain), a heterocyclic group, a heterocyclic spiro group, a hetero-bridged cyclic group, a non-ring
- the substituent that can be preferably used in the present embodiment is a non-cyclic hydrocarbon group, a cyclic hydrocarbon group (monocyclic hydrocarbon group, A group selected from the group consisting of a condensed polycyclic hydrocarbon group, a bridged cyclic hydrocarbon group, a spiro hydrocarbon group, a ring assembly hydrocarbon group, a cyclic hydrocarbon group having a side chain, and the above group A group in which at least one selected group is bonded (a group substituted with each other).
- a cyclic hydrocarbon group monocyclic hydrocarbon group, A group selected from the group consisting of a condensed polycyclic hydrocarbon group, a bridged cyclic hydrocarbon group, a spiro hydrocarbon group, a ring assembly hydrocarbon group, a cyclic hydrocarbon group having a side chain, and the above group A group in which at least one selected group is bonded (a group substituted with each other).
- the substituent for substituting ring A is a group selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group, an aralkyl group, and an ether group (substituted or unsubstituted alkyl ether, aryl ether, or aralkyl ether); 1 A group to which a group selected from the above group is bonded; a group selected from a group in which a group selected from one or more of the above groups is bonded by a saturated hydrocarbon bond or an ether bond; or a halogen atom And the sum of the number of carbon atoms constituting ring A and the number of carbon atoms constituting all substituents replacing ring A is an integer of 6 to 50.
- Ring A includes a benzene ring, naphthalene ring, anthracene ring, phenanthrene ring, naphthacene ring, chrysene ring, pyrene ring, triphenylene ring, pentalene ring, azulene ring, heptalene ring, indacene ring, biphenylene ring, acenaphthylene ring, and aceanthrylene. Examples thereof include a ring and an acephenanthrylene ring, and a structure containing at least one structure selected from a benzene ring and a naphthalene ring is preferable.
- an aromatic hydroxy compound having a benzene ring as a skeleton which is easily available, is preferable.
- aromatic hydroxy compound examples include an aromatic hydroxy compound represented by the following formula (27).
- R 14 , R 15 , R 16 , R 17 and R 18 are each independently a chain alkyl group, a cycloalkyl group, an aryl group, an aralkyl group, an ether group (substituted or unsubstituted alkyl ether, A group selected from the group consisting of aryl ethers and aralkyl ethers; a group in which one or more groups selected from the above group are bonded; a group selected from one or more groups in the above are bonded by a saturated aliphatic bond or an ether bond.
- a group selected from the group consisting of the above groups; a halogen atom; or a hydrogen atom, and the total number of carbon atoms constituting R 14 to R 18 is an integer of 0 to 44.
- preferred R 14 to R 18 are groups independently selected from the groups shown in the following (i) to (v).
- aralkyloxy group represents a group in which an oxygen atom is bonded to the aralkyl group defined above.
- R 14 to R 18 examples include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, dodecyl group, octadecyl group and structural isomers thereof.
- Chain alkyl groups such as cyclopentyl group, cyclohexyl group, cycloheptyl group, cyclooctyl group, etc .; methylcyclopentyl group, ethylcyclopentyl group, methylcyclohexyl group, ethylcyclohexyl group, propylcyclohexyl group, butylcyclohexyl A group composed of a chain alkyl group and a cycloalkyl group such as a group, a pentylcyclohexyl group, a hexylcyclohexyl group, a dimethylcyclohexyl group, a diethylcyclohexyl group, a dibutylcyclohexyl group, and structural isomers thereof; Chain alkyloxy such as xy group, propoxy group, butyloxy group, pentyloxy group, hexyloxy group, hept
- R 2 O is a group obtained by removing a hydrogen atom from the hydroxy group of the aromatic hydroxy compound represented by formula (26), and a is 1 or 2
- a is 1 or 2
- a is 1 or 2
- the compound represented by the formula (1) may be produced by a combination of a diisocyanate and a hydroxy compound.
- R 1 represents an R 1 group having the same meaning as defined in formula (1).
- Examples of the compound having a carbon-carbon unsaturated bond in the present embodiment include a compound represented by the following formula (21).
- R 5 , R 6 , R 7 and R 8 each independently represent a hydrogen atom, a halogen atom or an organic group having 1 to 10 carbon atoms, and R 5 to R 8 are not hydrogen atoms at the same time
- d represents an integer of 1 to 3.
- R 6 to R 8 are preferably a hydrogen atom or an organic group having 1 to 10 carbon atoms.
- R 6 to R 8 are organic groups, they are preferably aliphatic groups having 1 to 10 carbon atoms or aromatic groups having 6 to 10 carbon atoms.
- examples of such R 6 to R 8 include methyl groups, ethyl groups, propyl groups, butyl groups, pentyl groups, hexyl groups, heptyl groups, octyl groups, nonyl groups, decyl groups, and alkyl groups such as structural isomers thereof.
- Chain alkyloxy groups such as methyloxy group, ethyloxy group, propyloxy group, butyloxy group, pentyloxy group, hexyloxy group, heptyloxy group, octyloxy group, nonyloxy group, decyloxy group and structural isomers thereof; Cyclopentyl group, cyclohexyl group, cycloheptyl group, cyclooctyl group, methylcyclopentyl group, ethylcyclopentyl group, methylcyclohexyl group, ethylcyclohexyl group, propylcyclohexyl group, butylcyclohexyl group, pentylcyclohexyl group, hexylcyclohexyl group, di Cycloalkyl groups such as til cyclohexyl group, diethyl cyclohexyl group, dibutyl cyclohex
- R 5 is preferably a hydrogen atom or an organic group having 1 to 10 carbon atoms.
- R 5 is an organic group, it is preferably an aliphatic group having 1 to 10 carbon atoms or an aromatic group having 6 to 10 carbon atoms.
- Such R 5 includes a group formed by removing d hydrogen atoms from an alkane such as methane, ethane, propane, butane, pentane, hexane, heptane, octane, nonane, decane and structural isomers thereof; Groups formed by removing d hydrogen atoms from an alkane such as cyclopentane, cyclohexane, cycloheptane, cyclooctane; methylcyclopentane, ethylcyclopentane, methylcyclohexane, ethylcyclohexane, propylcyclohexane, butylcyclohexane, pen
- Examples of the compound represented by the above formula (21) include propene, butene, pentene, 2-methylbutene, 2,4,4-trimethylpentene-1, hexene, octene, nonene, decene, hexadecene, octadecene, butadiene, pentadiene, Hexadiene, chloroethylene, chloropropene, chlorobutene, chloropentene, chlorohexene, chlorooctene, chlorononene, chlorodecene, chlorohexadecene, chlorooctadecene, chlorobutadiene, chloropentadiene, chlorohexadiene, dichloroethylene, dichloropropene, dichlorobutene, dichloropentene, Dichlorohexene, dichlorooctene, dichlorononene, dichlorodecene, dichlorohexadecen
- the compound having at least one unsaturated bond among carbonic acid derivatives, compounds represented by the above formula (1) and compounds represented by the above formula (21), stability to heat, the composition of the present embodiment In consideration of the stability to oxygen, water and the like mixed during storage and storage, the compound represented by the above formula (1) and the compound represented by the above formula (21) are preferred.
- the composition of this embodiment is at least one compound selected from the group consisting of hydrocarbon compounds, ether compounds, sulfide compounds, halogenated hydrocarbon compounds, silicon-containing hydrocarbon compounds, silicon-containing ether compounds, and silicon-containing sulfide compounds. (Hereinafter also referred to as “inert compound”). Inactive compounds are classified into the following compounds A to G.
- the hydrocarbon compounds are compounds A and B
- the ether compounds and sulfide compounds are the following compounds C to E
- the halogenated hydrocarbon compounds are the following compounds F
- silicon-containing hydrocarbon compounds, silicon-containing ether compounds and silicon-containing sulfide compounds are classified into the following compounds G, respectively.
- Compound A An aliphatic hydrocarbon compound having a linear, branched or cyclic structure.
- Compound B An aromatic hydrocarbon compound which may be substituted with an aliphatic hydrocarbon group.
- Compound C A compound having an ether bond or sulfide bond and an aliphatic hydrocarbon group, wherein the same or different aliphatic hydrocarbon compounds are bonded via an ether bond or a sulfide bond.
- Compound D A compound having an ether bond or a sulfide bond and an aromatic hydrocarbon group, wherein the same or different aromatic hydrocarbon compounds are bonded via an ether bond or a sulfide bond.
- Compound E A compound having an ether bond or sulfide bond, an aliphatic hydrocarbon group, and an aromatic hydrocarbon group.
- Compound F A halide in which at least one hydrogen atom constituting an aliphatic hydrocarbon compound or at least one hydrogen atom constituting an aromatic hydrocarbon compound is substituted with a halogen atom.
- Compound G A compound in which some or all of the carbon atoms of Compounds A to E are substituted with silicon atoms.
- Compound A is preferably a hydrocarbon compound having 5 to 20 carbon atoms.
- Specific examples of compound A include pentane, hexane, heptane, octane, nonane, decane, dodecane, tetradecane, pentadecane, hexadecane, octadecane, nonadecane, cyclopentane, cyclohexane, cycloheptane, cyclooctane, methylcyclopentane, ethylcyclopentane.
- Compound B is preferably a hydrocarbon compound having 5 to 20 carbon atoms.
- Specific examples of compound B include benzene, toluene, ethylbenzene, butylbenzene, pentylbenzene, hexylbenzene, octylbenzene, biphenyl, terphenyl, diphenylethane, (methylphenyl) phenylethane, dimethylbiphenyl, benzyltoluene, naphthalene, methyl.
- Naphthalene, ethyl naphthalene, butyl naphthalene, structural isomers thereof and the like can be mentioned.
- Compound C is preferably a compound having 2 to 20 carbon atoms.
- Specific examples of compound C include ethyl ether, butyl ether, octyl ether, nonyl ether, decyl ether, methyl ethyl ether, methyl butyl ether, methyl octyl ether, methyl nonyl ether, methyl decyl ether, ethyl butyl ether, ethyl octyl ether, ethyl nonyl.
- Ether ethyl decyl ether, butyl octyl ether, butyl nonyl ether, butyl decyl ether, octyl nonyl ether, octyl decyl ether, dicyclopentyl ether, dicyclohexyl ether, dicyclooctyl ether, cyclohexyl ethyl ether, cyclohexyl butyl ether, cyclohexyl octyl ether, cyclohexyl Nonyl ether, cyclohexyl decyl ether, tetraethyl Ethers in which hydrocarbon compounds such as N-glycol dimethyl ether and structural isomers thereof are bonded through an ether bond; ethyl sulfide, butyl sulfide, octyl sulfide, nonyl sulfide,
- Compound D is preferably a compound having 2 to 20 carbon atoms.
- Specific examples of compound D include diphenyl ether, (methylphenyl) -phenyl ether, (ethylphenyl) -phenylether, (butylphenyl) -phenylether, (hexylphenyl) -phenylether, (methylphenyl) ether, (ethyl Phenyl) ether, (butylphenyl) ether, (hexylphenyl) ether, dibenzylether, di (methylbenzyl) ether, di (ethylbenzyl) ether, di (butylbenzyl) ether, di (pentylbenzyl) ether, di ( Hexylbenzyl) ether, di (octylbenzyl) ether, diphenylether and aromatic hydrocarbon compounds such as structural isomers thereof bonded via an ether bond; diphenyl sulfide
- Compound E is preferably a compound having 7 to 20 carbon atoms.
- Specific examples of compound E include phenyl-methyl-ether, phenyl-ethyl-ether, phenyl-butyl-ether, phenyl-octyl-ether, phenyl-nonyl-ether, phenyl-decyl-ether, benzyl-ethyl-ether, Benzyl-butyl-ether, benzyl-octyl-ether, benzyl-nonyl-ether, benzyl-decyl-ether, (methylphenyl) ethyl ether, (methylphenyl) butyl ether, (methylphenyl) octyl ether, (methylphenyl) nonyl ether , (Methylphenyl) decyl ether, (ethylphenyl) ethyl ether, (ethylphenyl) butyl
- Compound F is preferably a compound having 2 to 20 carbon atoms. Specifically, chloroethane, chloropropane, chlorobutane, chloropentane, chlorohexane, chloroheptane, chlorooctane, chlorononane, chlorodecane, chlorododecane, chlorotetradecane, chloropentadecane, chlorohexadecane, chlorooctadecane, chlorononadecane, chlorocyclopentane, chlorocyclohexane , Chlorocycloheptane, chlorocyclooctane, chloromethylcyclopentane, chloroethylcyclopentane, chloromethylcyclohexane, chloroethylcyclohexane, chloropropylcyclohexane, chlorobutylcyclohexane, chloropentylcyclohexane, chlorohexyl
- the compound G is a compound in which some or all of the carbon atoms of the compounds A to E are substituted with silicon atoms. Specifically, tetraethylsilane, tetrabutylsilane, tetrahexylsilane, tetracyclohexylsilane, tetraphenyl Silane, dimethyldibutylsilane, dimethyldicyclohexylsilane, dimethyldiphenylsilane, hexamethylcyclotrisiloxane, hexaethylcyclotrisiloxane, hexacyclohexylcyclotrisiloxane, trimethyltricyclohexylcyclotrisiloxane, trimethyltriphenylcyclotrisiloxane, hexaphenylcyclotri Siloxane, Octamethylcyclotetrasiloxane, Octaethylcyclotetrasiloxan
- a compound containing a halogen atom such as Compound F may cause an unexpected side reaction accompanying the generation of a halogen radical depending on the handling and storage conditions of the polyisocyanate composition of the present embodiment.
- a compound having an ether bond or a sulfide bond such as Compound C, Compound D, and Compound E may generate an oxide or a peroxide depending on conditions. From the viewpoint of being thermally stable, Compound A, Compound B or Compound G is preferred.
- the polyisocyanate composition of the present embodiment includes a polyisocyanate and a compound different from the polyisocyanate and having at least one unsaturated bond, or a hydrocarbon compound, an ether compound, a sulfide compound, a halogenated hydrocarbon compound, And at least one inert compound selected from the group consisting of silicon-containing hydrocarbon compounds, silicon-containing ether compounds, and silicon-containing sulfide compounds.
- the polyisocyanate content is 97% by mass or more based on the total mass of the polyisocyanate, and the content of the unsaturated bond compound is 2.0 mass ppm or more and 1.0 ⁇ 10 4 mass ppm or less.
- the method of suppressing the coloring in the distillation purification of polyisocyanate can be provided.
- an unsaturated bond compound of 2.0 mass ppm or more and 1.0 ⁇ 10 4 mass ppm or less is added to the polyisocyanate based on the total mass of the polyisocyanate before distillation purification.
- the polyisocyanate content is 97% by mass or more, and preferably 98% by mass or more. In addition, 99.5 mass% or less may be sufficient as content of polyisocyanate, and 99 mass% or less may be sufficient as it.
- the content of the unsaturated bond compound is 2.0 mass ppm or more and 1.0 ⁇ 10 4 mass ppm or less (0.0002 mass% or more and 1 mass% or less) based on the total mass of the polyisocyanate composition.
- unsaturated bond compounds tend to oxidize unsaturated bonds, and unsaturated bond compounds as contaminants tend to cause coloration.
- the unsaturated bond compound acts effectively during distillation purification of the polyisocyanate, and has an effect of suppressing coloring of the polyisocyanate to be purified by distillation.
- the unsaturated bond compound selectively acts with a compound that causes coloring such as oxygen to suppress the coloring of the polyisocyanate.
- a colored product derived from the unsaturated compound is produced by a reaction between the unsaturated bond compound and a color-causing compound such as oxygen.
- the colored product and polyisocyanate can be separated by distillation, In this polyisocyanate, it is considered that coloring due to mixing of the colored material is sufficiently suppressed.
- the content of the unsaturated bond compound is 2.0 mass ppm or more and 1.0 ⁇ 10 4 mass ppm or less, and the polyisocyanate containing the unsaturated bond compound in such a range is distilled. The coloration of the polyisocyanate can be sufficiently suppressed while sufficiently maintaining the purification efficiency.
- the content of the unsaturated bond compound is preferably 3.0 mass ppm or more, more preferably 5.0 mass ppm or more, and 10 mass ppm or more. More preferably.
- the content of the unsaturated bond compound is preferably 5.0 ⁇ 10 3 mass ppm or less, and preferably 3.0 ⁇ 10 3 mass ppm or less. More preferably, it is 1.0 ⁇ 10 3 mass ppm or less.
- the polyisocyanate composition further contains a compound represented by the formula (1), coloring of the polyisocyanate in the distillation purification tends to be further suppressed.
- a part of the compound represented by the formula (1) is thermally dissociated to produce a hydroxy compound. It is speculated that it may be used to develop functions similar to antioxidants.
- R 2 in the above formula (1) is preferably a residue obtained by removing a hydroxy group from an aromatic hydroxy compound.
- the colored substance derived from a hydroxy compound arises by addition of the compound represented by the said Formula (1), even when the said colored substance arises, the compound represented by the said Formula (1) It is considered that the polyisocyanate and the colored product are sufficiently separated by distillation purification by appropriately selecting. In order to suppress coloring of the polyisocyanate, it is preferable to increase the content of the compound represented by the above formula (1).
- content of the compound represented by Formula (1) in a polyisocyanate composition is 2.0 mass ppm or more and 1.0 * 10 ⁇ 4 > on the basis of the total mass of a polyisocyanate composition.
- the mass is preferably not more than ppm.
- the content of the compound represented by the formula (1) is more preferably 3 mass ppm or more, and 5 mass ppm or more. Is more preferable, and more preferably 10 ppm by mass or more.
- the content of the compound represented by the formula (1) is more preferably 5.0 ⁇ 10 3 mass ppm or less, and 3.0 ⁇ 10 3 More preferably, it is not more than mass ppm, and more preferably not more than 1.0 ⁇ 10 3 mass ppm.
- the compound represented by the formula (1) contained in the polyisocyanate composition may be used alone or in combination of two or more.
- content of the compound represented by Formula (1) is made into the total amount of the said multiple types.
- the polyisocyanate composition in the present embodiment may further contain the above inert compound.
- any isomer may be used, and a mixture of these isomers may be used.
- content of the below-mentioned inactive compound shows the total content of an isomer.
- the content of the inert compound in the polyisocyanate composition of the present embodiment is a range in which the above effects are sufficiently exhibited and does not hinder the distillation purification, or a range in which the performance of the purified polyisocyanate is not impaired. Specifically, it is preferably 5.0 mass ppm or more and 2.0 ⁇ 10 4 mass ppm or less.
- the content of the inert compound is more preferably 20 ppm by mass or more, further preferably 100 ppm by mass or more, and particularly preferably 300 ppm by mass or more, from the viewpoint of more effectively obtaining the above effect.
- the content of the inert compound is preferably 1.5 ⁇ 10 4 mass ppm or less, more preferably 1.3 ⁇ 10 4 mass ppm or less, and 1.0 ⁇ 10 4 mass ppm or less is more preferable.
- the manufacturing method of the refined polyisocyanate which concerns on this embodiment comprises the process of distilling and purifying polyisocyanate from the above-mentioned polyisocyanate composition, and obtaining the refined polyisocyanate.
- the material of the apparatus and line in which the polyisocyanate is purified by distillation may be any known material as long as it does not adversely affect the starting materials and reactants.
- SUS304, SUS316, SUS316L or the like is inexpensive and can be preferably used as the material of the device and line.
- distillation apparatus there is no particular limitation on the type of distillation apparatus, and a known distillation apparatus can be used.
- a known distillation apparatus for example, various known distillation apparatuses such as a multistage distillation column, a distillation apparatus including any one of a continuous multistage distillation column and a packed column, a distillation apparatus combining these, and the like can be used.
- the multi-stage distillation column refers to a distillation column having multiple stages with three or more theoretical stages of distillation.
- the multistage distillation column for example, one capable of continuous distillation can be used as appropriate.
- the number of theoretical plates is preferably 500 or less.
- Examples of the multistage distillation column include a plate column type using a tray such as a bubble tray, a perforated plate tray, a valve tray, a countercurrent tray, a Raschig ring, a lessing ring, a pole ring, a Berle saddle, an interlock saddle, and Dixon.
- Any packing column type packed with various packing materials such as packing, McMahon packing, helipack, sulzer packing, and melapack can be used as long as it is normally used as a multistage distillation column.
- a shelf-packed mixing type having both a shelf portion and a portion filled with a packing is also preferably used.
- the pressure at which the distillation purification is performed can be appropriately changed according to the composition of the polyisocyanate composition supplied to the distillation apparatus in which the distillation purification is performed, the temperature, the type of the distillation apparatus, and the like. Although it is carried out under pressure or under pressure, it is usually preferably carried out in the range of 0.01 kPa to 10 MPa (absolute pressure), and more preferably 0.1 kPa to 1 MPa (in view of ease of industrial implementation). Absolute pressure), more preferably 0.5 kPa to 50 kPa (absolute pressure).
- the temperature at which the distillation purification is performed can be appropriately changed according to the composition of the polyisocyanate composition supplied to the distillation apparatus in which the distillation purification is performed, the temperature, the type of the distillation apparatus, etc. In some cases, the polyisocyanate may be heat-denatured. On the other hand, if the temperature is too low, it is necessary to provide a new facility for cooling, and industrial implementation becomes difficult.
- the reaction is carried out in the range of from ° C to 350 ° C, more preferably from 80 ° C to 300 ° C, still more preferably from 100 ° C to 250 ° C.
- the compound represented by the formula (1) of 2.0 mass ppm or more and 1.0 ⁇ 10 4 mass ppm or less is further added to the polyisocyanate composition based on the total mass of the polyisocyanate composition. Can be added.
- the polyisocyanate is mixed with 5.0 to 10 ⁇ 4 4 ppm by mass of an inert compound (from compound A to compound G based on the total mass of the polyisocyanate). It is also possible to further add at least one compound selected from the group consisting of:
- this embodiment relates to a purified polyisocyanate produced by the above method.
- the polyisocyanate produced in this embodiment can sufficiently suppress the coloration derived from heating during distillation purification and can be suitably used for applications in which quality such as appearance is regarded as important.
- the polyisocyanate composition of this embodiment contains a polyisocyanate having an isocyanate group and ⁇ -methylstyrene.
- the polyisocyanate content is 97% by mass or more based on the total mass of the polyisocyanate composition
- the ⁇ -methylstyrene content is 2.0 mass ppm based on the total mass of the polyisocyanate composition.
- the above is 1.0 ⁇ 10 4 mass ppm (0.0002 mass% to 1 mass%).
- aromatic compounds particularly aromatic compounds having an unsaturated bond such as styrene
- styrene tend to be oxidized, and in many cases, aromatic compounds as contaminants cause coloring.
- ⁇ -methylstyrene acts effectively during distillation separation of the polyisocyanate, and has an effect of suppressing coloring of the polyisocyanate separated by distillation.
- the content of ⁇ -methylstyrene is 2.0 mass ppm or more and 1.0 ⁇ 10 4 mass ppm or less. In such a range, in the polyisocyanate composition containing ⁇ -methylstyrene, The coloration of the polyisocyanate can be sufficiently suppressed while sufficiently maintaining the efficiency of distillation separation.
- the content of ⁇ -methylstyrene is preferably 3.0 ppm by mass or more, and more preferably 5.0 ppm by mass or more. More preferably, it is 10 mass ppm or more.
- the content of ⁇ -methylstyrene is preferably 5.0 ⁇ 10 3 mass ppm or less, and preferably 3.0 ⁇ 10 3 mass ppm or less. Is more preferably 1.0 ⁇ 10 3 mass ppm or less.
- the polyisocyanate in the present embodiment is not particularly limited, and for example, a polyisocyanate that can be purified by distillation can be used depending on the purpose.
- a polyisocyanate that can be purified by distillation can be used depending on the purpose.
- aliphatic diisocyanate and / or alicyclic diisocyanate can be selected from the viewpoint that it can be suitably used for applications requiring weather resistance and heat-resistant yellowing.
- An aromatic diisocyanate can also be selected for the purpose of applying to a field where weather resistance or the like is not required.
- the polyisocyanate may be a polyisocyanate having two or more isocyanate groups, or may be a polyisocyanate having 2 to 4 isocyanate groups. May be a polyisocyanate having two.
- the polyisocyanate may be a compound represented by the following formula (1).
- c represents an integer of 2 to 4
- R 1 represents a c-valent organic group.
- R 1 examples include an aliphatic hydrocarbon group, an alicyclic hydrocarbon group (a hydrocarbon group having an alicyclic group), and an aromatic hydrocarbon group (a hydrocarbon group having an aromatic ring).
- Examples of the aliphatic hydrocarbon group include groups having 1 to 40 (preferably 4 to 30) carbon atoms. Specific examples of the aliphatic hydrocarbon group include butane (each isomer), pentane (each isomer), hexane (each isomer), heptane (each isomer), octane (each isomer), decane ( Each isomer), dodecane (each isomer), octadecane (each isomer) and the like, and a group obtained by removing c hydrogen atoms from an aliphatic hydrocarbon.
- Examples of the alicyclic hydrocarbon group include groups having 6 to 40 (preferably 8 to 30) carbon atoms. Specific examples of the alicyclic hydrocarbon group include cyclohexane, dimethylcyclohexane (each isomer), tetramethylcyclohexane (each isomer), dicyclohexylmethane, cycloheptane, cyclooctane, and other alicyclic hydrocarbons. And groups in which one hydrogen atom is removed.
- aromatic hydrocarbon group examples include groups having 6 to 40 (preferably 8 to 30) carbon atoms.
- Specific examples of the aromatic hydrocarbon group include groups in which c hydrogen atoms have been removed from an aromatic hydrocarbon such as benzene, toluene, xylene (each isomer), naphthalene, diphenylmethane, biphenyl and the like.
- R 1 may be a group in which a substituent such as a halogen atom, an alkoxy group, or an alkoxycarbonyl group is substituted on the above group.
- polyisocyanate examples include tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, 2,2,4-trimethyl-1,6-diisocyanatohexane, lysine diisocyanate, isophorone diisocyanate, 1,3-bis (isocyanate). Naphthomethyl) -cyclohexane, 4,4′-dicyclohexylmethane diisocyanate, 4,4′-diphenylmethane diisocyanate, toluene diisocyanate (each isomer), lysine triisocyanate, and the like. Of these, hexamethylene diisocyanate and isophorone diisocyanate are preferred from the viewpoint of being suitable for applications requiring weather resistance and heat yellowing resistance and being easily available industrially. Polyisocyanates may be used alone or in combination.
- the polyisocyanate content is 97% by mass or more, and preferably 98% by mass or more. In addition, 99.5 mass% or less may be sufficient as content of polyisocyanate, and 99 mass% or less may be sufficient as it.
- the polyisocyanate composition of the present embodiment may further contain a compound in which a part or all of the isocyanate groups of the polyisocyanate reacts with phenol to form a urethane bond. That is, when the polyisocyanate is a compound represented by the formula (10), the polyisocyanate composition may further contain a compound represented by the following formula (1).
- the polyisocyanate composition contains the compound represented by the formula (1) in addition to ⁇ -methylstyrene, the coloration of the polyisocyanate in the distillation separation tends to be further suppressed.
- a part of the compound represented by the formula (1) is thermally dissociated, for example, R in the formula (1).
- R in the formula (1).
- 2 is a phenyl group
- phenol is generated, and it is presumed that the phenol may exhibit a function similar to an antioxidant.
- the colored substance derived from phenol arises by addition of the compound represented by Formula (1), even when the said colored substance arises, polyisocyanate and colored substance are fully separated by distillation separation. It is considered to be separated.
- the content of the compound represented by the formula (1) In order to suppress coloring of the polyisocyanate, it is preferable to increase the content of the compound represented by the formula (1). On the other hand, if the content of the compound represented by the formula (1) is too large, There is a possibility that the efficiency of distillation separation between the polyisocyanate and the compound represented by the formula (1) is lowered, and the yield of purified polyisocyanate is lowered. For this reason, in this embodiment, it is preferable that content of the compound represented by Formula (1) in a polyisocyanate composition is 2.0 mass ppm or more and 1.0 * 10 ⁇ 4 > mass ppm or less. In such a range, the polyisocyanate composition containing the compound represented by the formula (1) can sufficiently suppress the coloration of the polyisocyanate while sufficiently maintaining the efficiency of distillation separation.
- the content of the compound represented by the formula (1) is more preferably 3 mass ppm or more, and 5.0 mass ppm or more. It is more preferable that it is 10 mass ppm or more.
- the content of the compound represented by the formula (1) is more preferably 5.0 ⁇ 10 3 mass ppm or less, and 3.0 ⁇ 10 3 More preferably, it is not more than mass ppm, more preferably not more than 1.0 ⁇ 10 3 mass ppm.
- the polyisocyanate composition may contain only one type of compound represented by the formula (1), or may contain multiple types. In addition, when containing multiple types of compounds represented by Formula (1), content of the compound represented by Formula (1) is made into the total amount of the said multiple types.
- the compound represented by formula (1) includes a compound represented by the following formula (1-3) and a compound represented by the following formula (1-4).
- R 1 represents the same divalent organic group as R 1 in Formula (1).
- the polyisocyanate composition according to this embodiment may further contain benzyltoluene.
- benzyltoluene has three isomers represented by the following formulas (3-1), (3-2), and (3-3).
- benzyltoluene includes Any of these isomers may be used, and a mixture of these isomers may be used.
- the content of benzyltoluene described later indicates the total content of isomers.
- the fluidity of the polyisocyanate composition can be improved.
- a polyisocyanate composition contains the compound represented by Formula (1)
- the solubility of the compound represented by Formula (1) in a polyisocyanate composition is improved by containing benzyl toluene further. be able to.
- the content of benzyltoluene in the polyisocyanate composition is 5.0 mass ppm or more as a range in which the above effects are sufficiently exhibited and the distillation separation is not hindered or the performance of the purified polyisocyanate is not impaired. It is preferably 0.0 ⁇ 10 4 mass ppm or less.
- the content of benzyltoluene is preferably 20 ppm by mass or more, more preferably 100 ppm by mass or more, and even more preferably 300 ppm by mass or more from the viewpoint of more effectively obtaining the above effect.
- the content of benzyltoluene is preferably 1.5 ⁇ 10 4 mass ppm or less, more preferably 1.3 ⁇ 10 4 mass ppm or less, and 1.0 ⁇ More preferably, it is 10 4 mass ppm or less.
- benzyltoluene and the like may contain compounds represented by the following formulas (4-1) to (4-8).
- benzyltoluene containing these compounds is included. May be used as they are, or benzyltoluene purified by distillation purification or the like may be used.
- content of these compounds is 5 mass parts or less with respect to 100 mass parts of benzyl toluene.
- the method for producing a purified polyisocyanate according to the present embodiment obtains a polyisocyanate purified product by distilling and separating the polyisocyanate from the polyisocyanate composition described above. A process is provided.
- the material of the apparatus and line in which the polyisocyanate is separated by distillation may be any known material as long as it does not adversely affect the starting materials and reactants.
- As the material for example, SUS304, SUS316, SUS316L and the like are inexpensive and can be preferably used.
- distillation apparatus there is no particular limitation on the type of distillation apparatus, and a known distillation apparatus can be used.
- a known distillation apparatus for example, various known distillation apparatuses such as a multistage distillation column, a distillation apparatus including any one of a continuous multistage distillation column and a packed column, a distillation apparatus combining these, and the like can be used.
- the multi-stage distillation column refers to a distillation column having multiple stages with three or more theoretical stages of distillation.
- the multistage distillation column for example, one capable of continuous distillation can be used as appropriate.
- the number of theoretical plates is preferably 500 or less.
- Examples of the multistage distillation column include a plate column type using a tray such as a bubble tray, a perforated plate tray, a valve tray, a countercurrent tray, a Raschig ring, a lessing ring, a pole ring, a Berle saddle, an interlock saddle, and Dixon.
- Any packing column type packed with various packing materials such as packing, McMahon packing, helipack, sulzer packing, and melapack can be used as long as it is normally used as a multistage distillation column.
- a shelf-packed mixing type having both a shelf portion and a portion filled with a packing is also preferably used.
- the pressure at which the distillation separation is performed can be appropriately changed according to the composition of the polyisocyanate composition supplied to the distillation apparatus in which the distillation separation is carried out, the temperature, the type of the distillation apparatus, etc. Although it is carried out under pressure or under pressure, it is usually preferably carried out in the range of 0.01 kPa to 10 MPa (absolute pressure), and more preferably 0.1 kPa to 1 MPa (in view of ease of industrial implementation). Absolute pressure), more preferably 0.5 kPa to 50 kPa (absolute pressure).
- the temperature at which the distillation separation is performed can be appropriately changed according to the composition of the polyisocyanate composition supplied to the distillation apparatus in which the distillation separation is performed, the temperature, the type of the distillation apparatus, etc. In some cases, the polyisocyanate may be heat-denatured. On the other hand, if the temperature is too low, it is necessary to provide a new facility for cooling, and industrial implementation becomes difficult.
- the reaction is carried out in the range of from ° C to 350 ° C, more preferably from 80 ° C to 300 ° C, still more preferably from 100 ° C to 250 ° C.
- one embodiment of the present invention relates to a method for suppressing coloring in distillation purification of a polyisocyanate having an isocyanate group.
- ⁇ -methylstyrene of 2.0 mass ppm or more and 1.0 ⁇ 10 4 mass ppm or less is added to the polyisocyanate based on the total mass of the polyisocyanate.
- components other than ⁇ -methylstyrene may be added for the preparation of the polyisocyanate composition.
- the compound represented by the formula (1) of 2.0 mass ppm or more and 1.0 ⁇ 10 4 mass ppm or less based on the total mass of the polyisocyanate is added to the polyisocyanate before distillation purification. Further, it can be added.
- benzyltoluene of 5.0 to 2.0 ⁇ 10 4 ppm by mass based on the total mass of the polyisocyanate can be further added to the polyisocyanate.
- another aspect of the present invention relates to a purified polyisocyanate (purified polyisocyanate) produced by the above-described method for producing a purified polyisocyanate. Since the polyisocyanate purified product of this embodiment is obtained by the above-described method, the coloration derived from heating during distillation separation is sufficiently suppressed, and the polyisocyanate for applications in which appearance quality is important. Can be suitably used.
- a polyisocyanate composition containing polyisocyanate and a compound represented by the following formula (1) is represented by 97 mass% or more of polyisocyanate and the following formula (1) of 2.0 mass ppm or more and 1.0 ⁇ 10 4 mass ppm or less based on the total mass. Compound.
- R 1 represents a group having the same meaning as R 1 defined in the above formula (10)
- R 2 represents a monovalent organic group
- a represents an integer of 1 to 5
- b represents 0 to 4
- the sum of a and b is c
- c is an integer of 2 to 5.
- the polyisocyanate composition according to the present embodiment is effective when an isocyanate polymer is produced by polymerizing the polyisocyanate contained in the composition and when a composition containing the isocyanate polymer is produced.
- the isocyanate polymer has a urethane bond (structure represented by the formula (9)), an allophanate bond (structure represented by the formula (6)), a biuret bond (structure represented by the formula (4)), An isocyanurate bond (structure represented by the formula (3)) or the like may be contained.
- the polyisocyanate content is 97% by mass or more, preferably 98% by mass or more, based on the total mass of the polyisocyanate composition.
- 99.5 mass% or less may be sufficient as content of polyisocyanate, and 99 mass% or less may be sufficient as it.
- the compound represented by the above formula (1) is preferably 2.0 ⁇ 10 ⁇ 4 parts by mass or more and 1.0 parts by mass or less with respect to 100 parts by mass of the polyisocyanate.
- the polyisocyanate composition according to the present embodiment has an effect that an isocyanate polymer can be efficiently obtained in the reaction of polyisocyanate and polyol.
- the present inventors surprisingly performed the reaction between the polyisocyanate and the polyol by performing the reaction between the polyisocyanate and the polyol in a reaction system to which a predetermined amount of the compound represented by the formula (1) was added. It has been found that the reaction rate of the condensation polymerization reaction (in particular, the condensation polymerization reaction for producing a urethane compound) is improved and the production efficiency of the isocyanate polymer can be improved.
- the amount of the compound represented by the formula (1) is preferably 3.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the polyisocyanate.
- the amount is more preferably 0.0 ⁇ 10 ⁇ 4 parts by mass or more, and further preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the amount of the compound represented by the formula (1) is 0 with respect to 100 parts by mass of the polyisocyanate. It is preferably 0.5 parts by mass or less, more preferably 0.3 parts by mass or less, and still more preferably 0.1 parts by mass or less.
- the reaction system only one kind of the compound represented by the formula (1) may be added, or plural kinds may be added.
- the addition amount of the compound represented by Formula (1) is the total amount of the multiple types.
- an unsaturated bond compound can be further added to the reaction system of the reaction between polyisocyanate and polyol.
- an effect of particularly promoting the allophanatization reaction reaction in which isocyanate is added to the urethane bond is exhibited.
- the above polyol refers to a compound containing two or more hydroxy groups in one molecule.
- Such polyols include, for example, dihydric alcohols to octahydric alcohols.
- dihydric alcohols include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, 2-methyl-1,2-propanediol, 1,5-pentanediol, 2-methyl-2,3-butanediol, 1,6-hexanediol, 1,2-hexanediol, 2,5-hexanediol, 2-methyl-2,4-pentanediol, 2,3-dimethyl-2,3-butanediol, 2-ethyl-hexane Diol, 1,2-octanediol, 1,2-decanediol, 2,2 4- trimethylp
- Examples of trihydric alcohols include glycerin and trimethylolpropane.
- Examples of tetrahydric alcohols include diglycerin, ditrimethylolpropane, pentaerythritol, dipentaerythritol, and D-threitol.
- Examples of pentahydric alcohols include L-arabinitol, ribitol, xylitol, L-ramnitol and the like.
- Examples of hexavalent alcohols include D-glucitol, D-mannitol, galactitol and the like.
- Examples of the 7-valent alcohol include trehalol.
- octahydric alcohol examples include sucrose, maltose, gentiobiose, lactose, melibiose and the like. Further, compounds obtained by adding ⁇ -caprolactone or the like to these polyols can also be used.
- the average value of the number of hydroxy groups per molecule of the polyol used in the present embodiment is preferably 2 to 8, more preferably 2 to 6, and further preferably 2 to 4.
- the allophanate reaction proceeds only by heating, but usually requires heating for several hours or more at a temperature of 150 ° C. or higher, and the composition of the isocyanate polymer obtained by passing through a long thermal history at that high temperature. Things sometimes colored.
- the reaction is carried out in the presence of a catalyst, but the reaction is promoted by addition of an unsaturated bond compound, and the amount of the catalyst necessary for the progress of the allophanatization reaction may be reduced. it can.
- the addition amount of the unsaturated bond compound is 2.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass with respect to 100 parts by mass of the polyisocyanate. It is preferable.
- the amount of the unsaturated bond compound added is more preferably 3.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the polyisocyanate from the viewpoint of further promoting the allophanatization reaction, and 5.0 ⁇
- the amount is more preferably 10 ⁇ 4 parts by mass or more, and further preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the amount of the unsaturated bond compound added is more preferably 0.5 parts by mass or less, more preferably 0.3 parts by mass or less, relative to 100 parts by mass of the polyisocyanate. Preferably, the amount is 0.1 parts by mass or less.
- an inert compound may be further added to the reaction system of the polyisocyanate and the polyol compound.
- an inert compound By adding an inert compound, the solubility of the polyisocyanate in the reaction system is improved, and the reaction efficiency is further improved.
- the addition of the inert compound also has an effect that the unreacted polyisocyanate can be easily distilled off after the reaction.
- the addition amount of the inert compound is preferably 5.0 ⁇ 10 ⁇ 4 parts by mass or more, more preferably 2 parts per 100 parts by mass of the polyisocyanate, from the viewpoint of obtaining the above effect more effectively.
- the addition amount of the inert compound is preferably 1.5 parts by mass or less with respect to 100 parts by mass of the polyisocyanate, and 1.3 parts by mass. More preferably, it is more preferably 1.0 part by mass or less.
- a urethane compound is obtained by a urethanization reaction (condensation polymerization reaction) between a polyisocyanate and a polyol compound, and then by an allophanatization reaction (reaction in which isocyanate is added to a urethane bond) between the polyisocyanate and the urethane compound.
- An allophanate compound is obtained.
- the urethanization reaction and the allophanatization reaction can be performed simultaneously, and after the urethanization reaction, the allophanatization reaction is performed by further adding an allophanatization catalyst into the reaction system. You can also
- the ratio of the polyisocyanate and the polyol compound to be subjected to the reaction is preferably such that the number of moles of the isocyanate group of the polyisocyanate is 3 to 100 when the number of moles of the hydroxyl group of the polyol compound is 1.
- the lower limit of the number of moles of isocyanate groups of the polyisocyanate is more preferably 6, more preferably 8, and most preferably 10.
- the upper limit is more preferably 80, still more preferably 60, and most preferably 30. If the isocyanate group is excessive to 3 or more, a low viscosity isocyanate polymer can be produced. Moreover, if the number of moles of the isocyanate group of the polyisocyanate is 100 or less, sufficient production efficiency can be maintained.
- the urethanization reaction is preferably 20 ° C to 200 ° C.
- the lower limit value of the urethanization reaction temperature is more preferably 40 ° C, further preferably 50 ° C, and most preferably 60 ° C.
- the upper limit of the urethanization reaction temperature is more preferably 160 ° C., further preferably 140 ° C., and particularly preferably 120 ° C.
- the reaction time is preferably 10 minutes to 24 hours, more preferably 15 minutes to 15 hours, still more preferably 20 minutes to 10 hours. If the reaction temperature is 20 ° C. or higher, a sufficient reaction rate can be obtained, and if it is 200 ° C. or lower, coloring can be suppressed.
- the urethanization reaction may be carried out without a catalyst or in the presence of a catalyst such as a tin-based or amine-based catalyst.
- the allophanatization reaction can be performed using a known allophanate catalyst.
- preferred catalysts are compounds containing lead, compounds containing zinc, compounds containing tin, compounds containing zirconium, compounds containing bismuth, and compounds containing lithium. These catalysts can be used individually by 1 type or in combination of 2 or more types.
- a compound containing zinc, a compound containing lead, a compound containing tin, or a compound containing zirconium is preferable, and a compound containing zirconium is more preferable.
- compounds containing zirconium include zirconyl naphthenate and zirconyl 2-ethylhexanoate. These are particularly preferable because they are relatively inexpensive, easily available industrially, have a high selectivity for the allophanatization reaction, and have high safety.
- the method for adding the allophanatization catalyst is not limited.
- it may be added before the production of the urethane compound, that is, before the urethanization reaction between the polyisocyanate and the polyol compound, or may be added during the urethanization reaction. It may be added after the is manufactured.
- a required amount of the allophanate catalyst may be added all at once, or may be added in several divided portions. Moreover, the method of adding continuously at a fixed addition rate is also employable.
- the allophanatization reaction is generally performed at a temperature of 20 ° C to 200 ° C.
- the lower limit of the reaction temperature at the time of carrying out the allophanatization reaction is more preferably 30 ° C., further preferably 60 ° C., and most preferably 80 ° C.
- the upper limit of the reaction temperature at the time of performing the allophanatization reaction is more preferably 180 ° C, and further preferably 160 ° C.
- reaction temperature is 20 ° C. or higher, the allophanatization reaction can proceed at an appropriate reaction rate without causing side reactions.
- reaction temperature is 200 degrees C or less, it exists in the tendency which is hard to produce a side reaction and coloring.
- the conversion rate from the urethane group to the allophanate group is preferably as high as possible.
- the conversion rate is preferably 80% or more, more preferably 90% or more, and further preferably 92% or more.
- the average value (fn) of the number of isocyanate groups is a statistical average value of the number of isocyanate groups that one molecule of the isocyanate polymer has, and is calculated by the following formula.
- Average number of isocyanate groups (fn) (Number average molecular weight of isocyanate polymer ⁇ mass% of isocyanate group ⁇ 0.01) / 42
- the average value of the number of isocyanate groups in the isocyanate polymer containing allophanate groups obtained in this embodiment is preferably 2.5 or more. More preferably, it is 2.8 or more, More preferably, it is 3.0 or more, Most preferably, it is 3.2 or more.
- the crosslinkability when used as a curing agent for paints can be expressed.
- the urethanization reaction and allophanation reaction can be carried out in the absence of a solvent, but if necessary, the reactivity with isocyanate groups such as butyl acetate, methyl ethyl ketone, toluene, xylene, hydrocarbon solvents, aromatic solvents, etc.
- the organic solvent which does not have can also be used as a solvent.
- the progress of the reaction between the polyisocyanate and the polyol compound can be traced by measuring the concentration of isocyanate groups in the reaction mixture or measuring the refractive index.
- the allophanatization reaction can be stopped by cooling to room temperature or adding a reaction terminator.
- a reaction terminator it is preferable to stop by adding a reaction terminator because the stability of the isocyanate polymer is improved.
- the addition amount of the reaction terminator is 0.2 to 100 times the molar amount, preferably 0.5 to 50 times the molar amount, more preferably 1.0 to 20 times the molar amount relative to the allophanatization catalyst. . If it is 0.2 times or more, the allophanatization catalyst can be sufficiently deactivated. Moreover, if it is 100 times or less, generation
- reaction terminator is not particularly limited as long as it can deactivate the allophanatization catalyst.
- reaction terminators include phosphoric acid, pyrophosphoric acid, metaphosphoric acid, polyphosphoric acid and other phosphoric acid compounds, phosphoric acid, pyrophosphoric acid, metaphosphoric acid, monoalkyl esters or dialkyl esters of polyphosphoric acid; monochloroacetic acid, etc. Benzoyl chloride; sulfonic acid ester; sulfuric acid; sulfate ester; ion exchange resin; chelating agent and the like.
- phosphoric acid pyrophosphoric acid, metaphosphoric acid, polyphosphoric acid, phosphoric acid monoalkyl ester or phosphoric acid dialkyl ester is preferable as the reaction terminator because it hardly corrodes stainless steel.
- phosphoric acid monoester and phosphoric acid diester include phosphoric acid monoethyl ester, phosphoric acid diethyl ester, phosphoric acid monobutyl ester, phosphoric acid dibutyl ester, phosphoric acid mono (2-ethylhexyl) ester, phosphoric acid di (2 -Ethylhexyl) ester and the like.
- phosphoric acid, pyrophosphoric acid, metaphosphoric acid, and polyphosphoric acid that do not substantially contain water are more preferable as a reaction terminator.
- a reaction terminator containing substantially no water the reaction product between the reaction terminator and the catalyst is likely to precipitate, so that the reaction between the reaction terminator and the catalyst occurs in the composition containing the isocyanate polymer. There is an effect that the product hardly remains.
- the term “substantially does not contain water” means that water may be included as long as the above effect is exhibited. Specifically, 5.0 mass with respect to the reaction terminator. %, Preferably less than 2.0% by weight, more preferably less than 0.50% by weight of water.
- adsorbing the catalyst with an adsorbent there is a method of adsorbing the catalyst with an adsorbent. Moreover, you may stop reaction combining an adsorption agent and the said reaction terminator.
- the adsorbent include silica gel, activated carbon, and activated alumina.
- the addition amount of the adsorbent is preferably 0.05 to 10% by mass with respect to the mass of the polyisocyanate used in the reaction.
- the unreacted polyisocyanate and the solvent can be separated from the composition containing the isocyanate polymer by a treatment such as a thin film distillation method or a solvent extraction method.
- the concentration of polyisocyanate contained in the composition containing the isocyanate polymer is 1% by mass or less.
- the upper limit value of the polyisocyanate concentration in the composition containing the isocyanate polymer is more preferably 0.7% by mass or less, still more preferably 0.5% by mass or less, and particularly preferably 0.3% by mass. It is as follows. By setting the polyisocyanate concentration to be not more than the above upper limit, the toxicity of the composition containing the isocyanate polymer can be further reduced, and the safety can be improved.
- the urethanization reaction and the allophanatization reaction can be performed in one reactor.
- two reactors can be connected and the process of a urethanation reaction and the process of an allophanatization reaction can also be implemented separately.
- it can also implement continuously by arrange
- the polyisocyanate composition according to this embodiment is obtained by a reaction between an isocyanate compound represented by the formula (1) and a polyol compound having two or more hydroxy groups, and includes at least one allophanate group and two The allophanate compound which has the above isocyanate groups is contained.
- c represents an integer of 2 to 4
- R 1 represents a c-valent organic group.
- the isocyanate compound is not particularly limited as long as it is a compound represented by the formula (10), and can be appropriately changed according to the target polyisocyanate composition.
- aliphatic diisocyanate and / or alicyclic diisocyanate are preferable from the viewpoint of obtaining a polyisocyanate composition that can be suitably used for applications requiring weather resistance.
- An aromatic diisocyanate can also be selected for the purpose of applying to a field where weather resistance or the like is not required.
- R 1 examples include an aliphatic hydrocarbon group, an alicyclic hydrocarbon group (a hydrocarbon group having an alicyclic group), and an aromatic hydrocarbon group (a hydrocarbon group having an aromatic ring).
- Examples of the aliphatic hydrocarbon group include groups having 1 to 40 (preferably 4 to 30) carbon atoms. Specific examples of the aliphatic hydrocarbon group include butane (each isomer), pentane (each isomer), hexane (each isomer), heptane (each isomer), octane (each isomer), decane ( Each isomer), dodecane (each isomer), octadecane (each isomer) and the like, and a group obtained by removing c hydrogen atoms from an aliphatic hydrocarbon.
- Examples of the alicyclic hydrocarbon group include groups having 6 to 40 (preferably 8 to 30) carbon atoms. Specific examples of the alicyclic hydrocarbon group include cyclohexane, dimethylcyclohexane (each isomer), tetramethylcyclohexane (each isomer), dicyclohexylmethane, cycloheptane, cyclooctane, and other alicyclic hydrocarbons. And groups in which one hydrogen atom is removed.
- aromatic hydrocarbon group examples include groups having 6 to 40 (preferably 8 to 30) carbon atoms.
- Specific examples of the aromatic hydrocarbon group include groups in which c hydrogen atoms have been removed from an aromatic hydrocarbon such as benzene, toluene, xylene (each isomer), naphthalene, diphenylmethane, biphenyl and the like.
- R 1 may be a group in which a substituent such as a halogen atom, an alkoxy group, or an alkoxycarbonyl group is substituted on the above group.
- isocyanate compound examples include tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, 2,2,4-trimethyl-1,6-diisocyanatohexane, lysine diisocyanate, isophorone diisocyanate, 1,3-bis (isocyanate). Naphthomethyl) -cyclohexane, 4,4′-dicyclohexylmethane diisocyanate, 4,4′-diphenylmethane diisocyanate, toluene diisocyanate (each isomer), lysine triisocyanate, and the like.
- hexamethylene diisocyanate and isophorone diisocyanate are preferred from the viewpoint of being suitable for applications requiring weather resistance and heat yellowing resistance and being easily available industrially.
- an isocyanate compound may be used individually or may be used together.
- the polyol compound is a compound having two or more hydroxy groups.
- examples of the polyol compound include polyester-based polyols.
- a polyol compound may be used individually by 1 type, or 2 or more types may be mixed and used for it.
- the polyol compound is preferably a polyester polyol obtained from a dihydric or trivalent alcohol and ⁇ -caprolactone, and the polyester polyol preferably has a number average molecular weight of 250 to 2,000.
- the upper limit of the number average molecular weight of the polyester polyol is preferably 1800, more preferably 1400, and still more preferably 1000.
- the resulting coating composition using the polyisocyanate composition is excellent in the stretchability of the coating film, and the viscosity of the coating composition is also in a practically preferred range.
- dihydric to trihydric alcohol examples include 1,2-propylene glycol, 1,3-butylene glycol, neopentyl glycol, hydroxypivalate ester of neopentyl glycol, 2-methyl-1,3-propanediol, , 3,5-trimethylpentanediol, ethylene glycol, diethylene glycol, 1,3-propanediol, 1,4-butylenediol, 1,5-pentanediol, 1,6-hexanediol, trimethylolpropane, glycerin, 1, Examples include 1,7-trimethylol heptane and 1,2,7-trimethylol heptane. These may be used alone or in combination of two or more.
- the polyisocyanate composition contains at least an allophanate compound.
- An allophanate compound is a compound in which an isocyanate compound is further added to a urethane bond of a urethane compound that is a condensation polymerization product of an isocyanate compound and a polyol compound.
- the viscosity of the polyisocyanate composition is preferably 500 to 15000 mPa ⁇ s from the viewpoint of the amount of organic solvent and the number of functional groups. If it is 500 mPa ⁇ s or more, the number of functional groups can be sufficiently increased, and if it is 15000 mPa ⁇ s or less, the amount of organic solvent can be sufficiently reduced.
- the viscosity of the polyisocyanate composition is more preferably 600 to 12000 mPa ⁇ s, and still more preferably 700 to 10000 mPa ⁇ s.
- the viscosity shown here is the value measured at 25 degreeC using the E-type viscosity meter (Tokimec Co., Ltd.).
- the number average functional group number (hereinafter referred to as “fn”) of the polyisocyanate composition is preferably 3.5 to 7.0 from the viewpoint of excellent curability and good viscosity. If fn is 3.5 or more, sufficient curability is obtained, and if it is 7.0 or less, the viscosity does not become too high.
- the fn of the polyisocyanate composition is preferably 3.6 to 6.9, and more preferably 3.7 to 6.8.
- fn of a polyisocyanate composition can be calculated
- required from following Formula. (Fn of polyisocyanate composition) (number average molecular weight) ⁇ NCO% / 4200
- the number average molecular weight is determined from gel filtration chromatography (hereinafter referred to as GPC). Specifically, HLC-8120 (manufactured by Tosoh Corporation) is used as a device used, TSK GEL SuperH1000, TSK GEL SuperH2000, TSK GEL SuperH3000 (all manufactured by Tosoh Corporation) are used as columns, and the sample concentration is 5 mass.
- GPC gel filtration chromatography
- the NCO% of the polyisocyanate composition (the proportion of the mass of the isocyanate group per unit mass of the solid content of the polyisocyanate composition) is preferably 3.0% to 25.0% based on the solid content of 100%. If it is 3.0% or more, it tends to show better performance when a coating composition using a polyisocyanate composition is used as a coating film. If it is 25.0% or less, the crosslinking density becomes too high. Thus, a coating film that is difficult to break is formed.
- the NCO% of the polyisocyanate composition is more preferably 3.2% to 24.0%, and still more preferably 3.4% to 23.0%. NCO% can be determined by back titration with 1N hydrochloric acid after neutralizing the isocyanate group with an excess of 2N amine.
- the polyisocyanate composition contains an allophanate group and does not substantially contain an isocyanurate group.
- substantially containing no isocyanurate groups means that the molar ratio of allophanate groups to isocyanurate groups is 91/9 to 100/0. The ratio is preferably 93/7 to 100/0, more preferably 95/5 to 100/0, and still more preferably 97/3 to 100/0.
- the viscosity of the polyisocyanate composition can be sufficiently lowered, and depending on the coating composition using the polyisocyanate composition, It becomes possible to form a coating film having excellent extensibility.
- the polyisocyanate composition preferably has a low content of the uretdione body.
- the content of the uretdione body is preferably 10% by mass or less, more preferably 8% by mass or less, and still more preferably 5% by mass or less, based on the total solid content of the polyisocyanate composition.
- the content of the uretdione compound can be determined by measuring the ratio of the area of the peak having a molecular weight of about 336 in gel filtration chromatography (hereinafter referred to as GPC) with a differential refractometer.
- GPC gel filtration chromatography
- the peak of the uretdione group of about 1770 cm -1 and height of allophanate groups of about 1720 cm -1 The ratio of peak heights can also be determined by a method of quantifying using an internal standard.
- the biuret body and other isocyanate polymers may adversely affect the weather resistance and the like of the coating film.
- the range of the amount of biuret and other isocyanate polymer contained in the polyisocyanate composition is preferably 10% by mass or less, more preferably 5% by mass or less, even more based on the total solid content of the polyisocyanate composition. Preferably 3 mass% or less is suitable.
- the urethane body may improve the adhesion to the substrate, but if it is too much, the number average functional group number may decrease and the crosslinkability may decrease.
- the range of the amount of urethane contained is represented by the ratio (mol%) of the number of moles of urethane groups to the total number of moles of allophanate groups and isocyanurate groups, preferably less than 10 mole%, more preferably 8 moles. % Or less, still more preferably 6 mol% or less is appropriate.
- the mol% of the urethane group can be determined using 1 H-NMR.
- Specific examples of 1 H-NMR measurement methods are as follows.
- the standard of chemical shift is defined as a hydrogen atom signal of tetramethylsilane, and the signal is defined as 0 ppm.
- the isocyanurate group has a signal area of a hydrogen atom of a methylene group adjacent to the isocyanurate group at about 3.85 ppm (6 mol of hydrogen atom with respect to 1 mol of isocyanurate group), and a hydrogen atom of tetramethylsilane. It can quantify from ratio with the area of signal.
- the urethane group has a signal area of hydrogen atoms bonded to nitrogen of the urethane group in the vicinity of 4 to 5 ppm (1 mol of hydrogen atoms relative to 1 mol of urethane groups), and a signal area of hydrogen atoms of tetramethylsilane. It can be quantified from the ratio.
- the residual amount of the isocyanate compound is preferably 5% by mass or less, more preferably 2% by mass or less, based on the total solid content.
- the residual amount of the isocyanate compound can be measured by a method such as gas chromatography.
- the method for producing a polyisocyanate composition according to this embodiment is obtained by a reaction between an isocyanate compound and a polyol compound. More specifically, it can be obtained by adding an isocyanate compound to a urethane bond of a urethane compound that is a condensation polymerization product of an isocyanate compound and a polyol compound.
- the reaction between the isocyanate compound and the polyol compound is a compound represented by the following formula (1) of 2.0 ⁇ 10 ⁇ 4 to 1.0 part by mass with respect to 100 parts by mass of the isocyanate compound. Is carried out in a reaction system to which is added.
- a represents an integer of 1 to 4
- b represents an integer of 0 to 3
- a polyisocyanate composition can be obtained efficiently.
- the present inventors have surprisingly performed the reaction between the isocyanate compound and the polyol compound by performing the reaction between the isocyanate compound and the polyol compound in a reaction system to which a predetermined amount of the compound represented by the formula (1) is added. It has been found that the reaction rate of the reaction (particularly the condensation polymerization reaction for producing a urethane compound) can be improved, and the production efficiency of the polyisocyanate composition can be improved.
- the present inventors have made the reaction between the isocyanate composition and the polyol compound by the urethane bond (—NHCOO—) of the compound represented by the formula (1). I'm guessing that it will be promoted. In order to effectively exhibit this effect, the amount of the compound represented by the formula (1) is 2.0 ⁇ 10 ⁇ 4 parts by mass or more and 1.0 part by mass or less with respect to 100 parts by mass of the isocyanate compound.
- a urethane bond is produced
- the amount of the compound represented by the formula (1) is preferably 3.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the isocyanate compound. It is more preferably 0.0 ⁇ 10 ⁇ 4 parts by mass or more, and further preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the addition amount of the compound represented by the formula (1) is based on 100 parts by mass of the isocyanate compound.
- the amount is preferably 0.5 parts by mass or less, more preferably 0.3 parts by mass or less, and further preferably 0.1 parts by mass or less.
- the reaction system only one kind of the compound represented by the formula (1) may be added, or plural kinds may be added.
- the addition amount of the compound represented by Formula (1) is the total amount of the multiple types.
- the compound represented by formula (1) includes a compound represented by the following formula (1-3) and a compound represented by the following formula (1-4).
- R 1 represents the same divalent organic group as R 1 in Formula (1).
- ⁇ -methylstyrene can be further added to the reaction system of the reaction between the isocyanate compound and the polyol compound. Addition of ⁇ -methylstyrene has an effect of accelerating the reaction of allophanatization reaction (reaction in which an isocyanate compound is added to a urethane bond).
- the allophanatization reaction is often carried out in the presence of a catalyst, but the amount of catalyst required for the allophanate reaction can be reduced by promoting the reaction by the addition of ⁇ -methylstyrene.
- the amount of ⁇ -methylstyrene added is 2.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass with respect to 100 parts by mass of the isocyanate compound. It is preferable.
- the addition amount of ⁇ -methylstyrene is more preferably 3.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the isocyanate compound from the viewpoint of further promoting the allophanatization reaction, and 5.0 ⁇
- the amount is more preferably 10 ⁇ 4 parts by mass or more, and further preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the addition amount of ⁇ -methylstyrene is more preferably 0.5 parts by mass or less and more preferably 0.3 parts by mass or less with respect to 100 parts by mass of the isocyanate compound.
- the amount is 0.1 parts by mass or less.
- benzyltoluene may be further added to the reaction system of the reaction between the isocyanate compound and the polyol compound.
- benzyltoluene By adding benzyltoluene, the solubility of the isocyanate compound in the reaction system is improved, and the reaction efficiency is further improved.
- the addition of benzyltoluene also has an effect that the unreacted isocyanate compound can be easily distilled off after the reaction.
- benzyltoluene There are three types of isomers represented by the following formulas (3-1), (3-2), and (3-3) in benzyltoluene.
- benzyltoluene is any of these. These isomers may be used, or a mixture of these isomers may be used.
- the content of benzyltoluene indicates the total content of isomers.
- the amount of benzyltoluene added is preferably 5.0 ⁇ 10 ⁇ 4 parts by mass or more, more preferably 2.0 ⁇ 10 parts by mass with respect to 100 parts by mass of the isocyanate compound from the viewpoint of more effectively obtaining the above effect. It is 10 ⁇ 3 parts by mass or more, more preferably 3.0 ⁇ 10 ⁇ 2 parts by mass or more.
- the amount of benzyltoluene added is preferably 1.5 parts by mass or less with respect to 100 parts by mass of the isocyanate compound, and 1.3 parts by mass. More preferably, it is more preferably 1.0 part by mass or less.
- benzyltoluene and the like may contain compounds represented by the following formulas (4-1) to (4-8).
- benzyltoluene containing these compounds is included. May be used as they are, or benzyltoluene purified by distillation purification or the like may be used.
- content of these compounds in a reaction system is 10 mass parts or less with respect to 100 mass parts of benzyl toluene.
- a urethane compound is obtained by a urethanization reaction (condensation polymerization reaction) between an isocyanate compound and a polyol compound, and then an allophanatization reaction between the isocyanate compound and the urethane compound (reaction in which the isocyanate compound is added to the urethane bond). ) To obtain an allophanate compound.
- the urethanization reaction and the allophanatization reaction can be performed together, and after the urethanization reaction, the allophanatization reaction is performed by adding an allophanate catalyst into the reaction system. You can also
- the ratio of the isocyanate compound and polyol compound subjected to the reaction is preferably such that the ratio of the number of moles of isocyanate groups of the isocyanate compound to the number of moles of hydroxy groups of the polyol compound is 6/1 to 100/1. This ratio is preferably 8/1 to 80/1, more preferably 10/1 to 60/1. If the isocyanate group is excessive to 6/1 or more, a low-viscosity polyisocyanate composition can be produced. Moreover, if a hydroxyl group exists in 100/1 or more, sufficient production efficiency can be maintained.
- the urethanization reaction is preferably performed at 20 ° C. to 200 ° C., more preferably 40 ° C. to 150 ° C., and further preferably 60 ° C. to 120 ° C.
- the reaction time is preferably 10 minutes to 24 hours, more preferably 15 minutes to 15 hours, and even more preferably 20 minutes to 10 hours. If it is 20 degreeC or more, while sufficient reaction rate will be obtained, coloring can be suppressed by setting it as 200 degrees C or less.
- the urethanization reaction may be carried out without a catalyst or in the presence of a catalyst such as tin or amine.
- the allophanatization reaction can be performed using a known allophanate catalyst.
- preferred catalysts are compounds containing lead, compounds containing zinc, compounds containing tin, compounds containing zirconium, compounds containing bismuth, and compounds containing lithium. One or two or more of these compounds can be used.
- a compound containing zinc, a compound containing lead, a compound containing tin, and a compound containing zirconium are more preferable, and a compound containing zirconium is more preferable.
- the compound containing zirconium include zirconyl naphthenate and zirconyl 2-ethylhexanoate. These are particularly preferable because they are relatively inexpensive, easily available industrially, have high selectivity for the allophanatization reaction, and have high safety.
- the method for adding the allophanatization catalyst is not limited. For example, it may be added before the urethane compound is produced, that is, prior to the urethanization reaction between the isocyanate compound and the polyol compound, or may be added during the urethanation reaction between the isocyanate compound and the polyol compound. It may be added after the urethane compound has been produced.
- a required amount of the allophanate catalyst may be added all at once, or may be added in several divided portions. Moreover, the method of adding continuously at a fixed addition rate is also employable.
- the allophanatization reaction is generally performed at a temperature of 20 to 200 ° C.
- the temperature is 30 to 180 ° C, more preferably 60 to 160 ° C. If it is 20 degreeC or more, an allophanatization reaction can be advanced at a suitable reaction rate, without raising a side reaction. If it is 200 degrees C or less, it will become possible not to raise
- the conversion rate from the urethane group to the allophanate group is preferably as high as possible.
- the conversion rate is preferably 91% or more, more preferably 92% or more.
- the urethanization reaction and allophanation reaction can be carried out in the absence of a solvent, but if necessary, the reactivity with isocyanate groups such as butyl acetate, methyl ethyl ketone, toluene, xylene, hydrocarbon solvents, aromatic solvents, etc.
- the organic solvent which does not have can also be used as a solvent.
- the process of the reaction between the isocyanate compound and the polyol compound can be traced by measuring NCO% of the reaction mixture or measuring the refractive index.
- the allophanatization reaction can be stopped by cooling to room temperature or adding a reaction terminator, but when using an allophanate catalyst, it is more stable to add a reaction terminator to stop the stability of the polyisocyanate composition. Is preferable.
- the addition amount of the reaction terminator is 0.2 to 100 times the molar amount, preferably 0.5 to 50 times the molar amount, more preferably 1.0 to 20 times the molar amount relative to the allophanatization catalyst. . If it is 0.2 times or more, the catalyst can be sufficiently deactivated. Moreover, if it is 100 times or less, generation
- reaction terminator is not particularly limited as long as it can deactivate the allophanatization catalyst.
- reaction terminators include phosphoric acid, pyrophosphoric acid, metaphosphoric acid, polyphosphoric acid and other phosphoric acid compounds; phosphoric acid, pyrophosphoric acid, metaphosphoric acid, monoalkyl or dialkyl esters of polyphosphoric acid; monochloroacetic acid, etc. Examples thereof include halogenated acetic acid; benzoyl chloride; sulfonic acid ester; sulfuric acid; sulfate ester; ion exchange resin;
- phosphoric acid, pyrophosphoric acid, metaphosphoric acid, polyphosphoric acid, phosphoric acid monoalkyl ester and phosphoric acid dialkyl ester are preferred because they hardly corrode stainless steel.
- phosphoric acid monoester and phosphoric acid diester include phosphoric acid monoethyl ester, phosphoric acid diethyl ester, phosphoric acid monobutyl ester, phosphoric acid dibutyl ester, phosphoric acid mono (2-ethylhexyl) ester, phosphoric acid di (2 -Ethylhexyl) ester and the like.
- phosphoric acid, pyrophosphoric acid, metaphosphoric acid, and polyphosphoric acid substantially not containing water are more preferable as a terminator.
- the reaction product of the terminator and the catalyst is likely to precipitate, so that the reaction product of the terminator and the catalyst is less likely to remain in the polyisocyanate composition. .
- substantially not containing water means that water may be contained as long as the above-described effects are exhibited. Less than 0.0 mass%, preferably less than 2.0 mass%, more preferably less than 0.50 mass%.
- an allophanatization catalyst there is a method of stopping the reaction by adsorbing the catalyst with an adsorbent. It is also a preferable method to stop by combining the adsorbent and the above reaction terminator.
- the adsorbent include silica gel, activated carbon, activated alumina and the like.
- the amount of adsorbent added is preferably 0.05 to 10% by weight based on the isocyanate compound used in the reaction.
- the unreacted isocyanate compound and solvent can be separated from the polyisocyanate composition by, for example, a thin film distillation method or a solvent extraction method.
- the urethanization reaction and the allophanatization reaction can be performed in one reactor.
- two reactors can be connected, and the urethanization reaction step and the allophanatization reaction step can be carried out separately.
- it can be carried out continuously by arranging several reactors side by side.
- one embodiment of the present invention may be a method for producing a urethane compound in which a urethane compound having a urethane bond is obtained by the above-described urethanization reaction step.
- the urethane compound can be efficiently obtained because the urethanization reaction is promoted by the addition of the compound represented by the formula (1).
- another aspect of the present invention may be an isocyanate composition for use in the method for producing the polyisocyanate composition or the method for producing the urethane compound.
- the isocyanate compound and the compound represented by Formula (1) may be separately used for a reaction system, and the isocyanate composition containing the isocyanate compound and the compound represented by Formula (1) in advance
- the isocyanate composition can be subjected to a reaction system.
- the isocyanate composition of this embodiment includes an isocyanate compound and a compound represented by the formula (1) having a ratio of 2.0 ⁇ 10 ⁇ 3 parts by mass to 2.0 parts by mass with respect to 100 parts by mass of the isocyanate composition. , Containing.
- the content of the isocyanate compound in the isocyanate composition may be 98% by mass or more, or 99% by mass or more based on the total mass of the isocyanate composition.
- the isocyanate composition may further contain ⁇ -methylstyrene, and the content is preferably 2.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass. This makes it possible to more easily carry out the above production method in which ⁇ -methylstyrene is added.
- the isocyanate composition may further contain benzyltoluene, and the content thereof is 5.0 ⁇ 10 ⁇ 4 parts by mass to 2.0 parts by mass with respect to 100 parts by mass of the isocyanate compound. Is preferred. Thereby, the said manufacturing method with which benzyltoluene was added can be implemented still more simply.
- the biuretizing agent is not particularly limited as long as it is a compound capable of forming a biuret bond.
- water monovalent tertiary alcohol, formic acid, hydrogen sulfide, organic primary monoamine, organic primary A primary diamine etc. can be illustrated. Of these, water is preferred.
- the present inventors surprisingly added a predetermined amount of the compound represented by the formula (1) to the reaction between the polyisocyanate and the biuretizing agent (especially the reaction for producing a urea compound), It has been found that the reaction rate and the production efficiency of the isocyanate polymer can be improved.
- the urethane bond (—NHCOO—) of the compound represented by the formula (1) causes the reaction between the polyisocyanate and the biuretizing agent. I guess it will promote. Further, when the amount of the compound represented by the formula (1) is 2.0 ⁇ 10 ⁇ 4 parts by mass or more and 1.0 part by mass or less with respect to 100 parts by mass of the polyisocyanate, the above-described effect is further improved. can do.
- the amount of the compound represented by the formula (1) is preferably 3.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the polyisocyanate.
- the amount is more preferably 0.0 ⁇ 10 ⁇ 4 parts by mass or more, and further preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the amount of the compound represented by the formula (1) is 0.5 parts by mass or less with respect to 100 parts by mass of the polyisocyanate. Preferably, it is 0.3 parts by mass or less, and more preferably 0.1 part by mass or less.
- the addition amount of the compound represented by Formula (1) is the total amount of the multiple types.
- an unsaturated bond compound can be further added to the reaction between the polyisocyanate and the biuretizing agent.
- an effect that the reaction of the biuretization reaction reaction in which isocyanate is added to the urea bond
- isocyanate reaction in which isocyanate is added to the urea bond
- the biuretization reaction can be promoted, the reaction time can be shortened, and the composition containing the isocyanate polymer as a product can be colored. Can be sufficiently suppressed.
- the addition amount of the unsaturated bond compound is 2.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass with respect to 100 parts by mass of the polyisocyanate. It is preferable.
- the amount of the unsaturated bond compound added is more preferably 3.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the polyisocyanate from the viewpoint of further promoting the biuretization reaction, and 5.0 ⁇
- the amount is more preferably 10 ⁇ 4 parts by mass or more, and further preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the amount of the unsaturated bond compound added is more preferably 0.5 parts by mass or less, more preferably 0.3 parts by mass or less, relative to 100 parts by mass of the polyisocyanate. Preferably, the amount is 0.1 parts by mass or less.
- an inert compound may be further added to the reaction between the polyisocyanate and the biuretizing agent.
- an inert compound By adding an inert compound, the solubility of the polyisocyanate in the reaction system is improved, and the reaction efficiency is further improved. Further, the addition of the inert compound also has an effect that the unreacted polyisocyanate can be easily distilled off after the reaction between the polyisocyanate and the biuretizing agent.
- the addition amount of the inert compound is preferably 2.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the polyisocyanate, and more preferably, from the viewpoint of obtaining the above effect more effectively. The amount is 2.0 ⁇ 10 ⁇ 3 parts by mass or more, more preferably 3.0 ⁇ 10 ⁇ 2 parts by mass or more.
- the addition amount of the inert compound is preferably 1.5 parts by mass or less with respect to 100 parts by mass of the polyisocyanate, and 1.3 parts by mass. More preferably, it is more preferably 1.0 part by mass or less.
- a urea compound is obtained by a urea reaction of a polyisocyanate and a biuret agent, and then a biuret compound is obtained by a biuret reaction (reaction in which isocyanate is added to a urea bond) between the polyisocyanate and the urea compound. can get.
- the ratio of the polyisocyanate to the biuretizing agent used in the reaction is preferably 4 to 40 when the number of moles of the isocyanate group of the polyisocyanate is 1 mole of the biuretizing agent.
- This lower limit is more preferably 5.
- the upper limit is more preferably 30, and still more preferably 20. If the number of moles of isocyanate groups of the polyisocyanate is 4 or more, a low-viscosity polyisocyanate composition can be produced. Moreover, if the number of moles of the isocyanate group of the polyisocyanate is less than 40, sufficient production efficiency can be maintained.
- the reaction temperature of the urea reaction and the subsequent biuret reaction is preferably 70 ° C to 200 ° C.
- the lower limit is more preferably 80 ° C, and still more preferably 90 ° C.
- the upper limit is more preferably 180 ° C, and further preferably 170 ° C. Sufficient reaction rate can be maintained by being 70 degreeC or more, and coloring of the composition containing the isocyanate polymer obtained can be suppressed by being 200 degreeC or less.
- the reaction time is preferably 10 minutes to 24 hours, more preferably 15 minutes to 15 hours, and further preferably 20 minutes to 10 hours.
- reaction product is further introduced into a pipe reactor, and the extrusion flow in the pipe reactor is performed. It is preferable to apply a continuous production method in which the reaction proceeds under.
- a solvent can be used in the biuretization reaction.
- a solvent By using a solvent, the polyisocyanate and the biuretizing agent can be dissolved, and a homogeneous phase can be formed under the reaction conditions.
- generation of by-products such as polyurea can be suppressed.
- a solvent having a low solubility of the biuretizing agent such as water is not preferable because the amount added is increased by that amount, and it is uneconomical when the solvent is separated and recovered after the completion of the reaction.
- This solvent preferably has a solubility of a biuretizing agent such as water of 0.5% by mass or more.
- the boiling point of the solvent is preferably lower than the boiling point of the raw material diisocyanate in consideration of recovery and separation of unreacted diisocyanate and the like.
- the solvent include an ethylene glycol solvent, a propylene glycol solvent, and an alkyl phosphate solvent that do not contain an active hydrogen group.
- the ethylene glycol solvents include ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol mono-n-propyl ether acetate, ethylene glycol monoisopropyl ether acetate, ethylene glycol mono-n-butyl ether acetate, ethylene glycol diacetate , Ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol di-n-propyl ether, ethylene glycol diisopropyl ether, ethylene glycol di-n-butyl ether, ethylene glycol methyl ethyl ether, ethylene glycol methyl isopropyl ether, ethylene glycol methyl-n- Butyl ether, ethylene Recall ethyl-n-propyl
- Propylene glycol solvents include propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol mono-n-propyl ether acetate, propylene glycol monoisopropyl ether acetate, propylene glycol mono-n-butyl ether acetate, propylene glycol Diacetate, propylene glycol dimethyl ether, propylene glycol diethyl ether, propylene glycol di-n-propyl ether, propylene glycol diisopropyl ether, propylene glycol di-n-butyl ether, propylene glycol methyl ethyl ether, propylene glycol methyl isopropyl ether, propylene glycol Chill-n-butyl ether, propylene glycol ethyl-n-propyl ether, propylene glycol ethyl isopropyl ether, propylene glycol e
- Preferred ethylene glycol solvents include ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol diacetate, diethylene glycol dimethyl ether, etc.
- Preferred propylene glycol solvents include propylene glycol monomethyl ether acetate, propylene glycol monoethyl. Examples include ether acetate, propylene glycol diacetate, and dipropylene glycol dimethyl ether.
- examples of the alkyl phosphate solvent include trimethyl phosphate, triethyl phosphate, tripropyl phosphate, tributyl phosphate, and the like, and trimethyl phosphate or triethyl phosphate is preferable. These may be used alone or in admixture of two or more.
- the mixing mass ratio of the solvent is preferably 3/7 to 9/1 in the ethylene glycol solvent / phosphoric acid solvent, and the preferable amount used is 20 to 50 mass% with respect to the total mass of the diisocyanate and the solvent.
- unreacted polyisocyanate and solvent can be separated from the composition containing the isocyanate polymer, for example, by treatment such as thin film distillation or solvent extraction.
- the polyisocyanate concentration contained in the composition containing the isocyanate polymer is 2% by mass or less based on the total mass of the composition containing the isocyanate polymer by performing these treatments.
- the upper limit of the polyisocyanate concentration is more preferably 1.5% by mass or less, still more preferably 1.0% by mass or less, still more preferably 0.7% by mass or less, and still more preferably 0.00. 5% by mass or less.
- the average value of the number of isocyanate groups in the composition containing the isocyanate polymer having a biuret bond obtained in the present embodiment is 3.0 or more. Moreover, More preferably, it is 3.1 or more, More preferably, it is 3.2 or more. When the average value of the number of isocyanate groups in the isocyanate polymer is 3.0 or more, crosslinkability when used as a curing agent for paints can be expressed.
- a polyisocyanate composition containing a polyisocyanate and an inert compound is composed of 97 mass% or more of polyisocyanate and 20 mass ppm or more and 2.0 ⁇ 10 4 mass ppm or less of inert compounds (compound A to compound G based on the total mass). And at least one compound selected from the group).
- the polyisocyanate content is 97% by mass or more, and preferably 98% by mass or more. In addition, 99.5 mass% or less may be sufficient as content of diisocyanate, and 99 mass% or less may be sufficient as it.
- the content of the inert compound is preferably 2.0 ⁇ 10 ⁇ 3 parts by mass to 2.0 parts by mass with respect to 100 parts by mass with respect to the polyisocyanate.
- the present inventors have used the polyisocyanate composition of the present embodiment to provide an isocyanurate structure (structure represented by the formula (3)), an iminooxadiazinedione structure (structure represented by the formula (5)) or When producing an isocyanate polymer containing a uretdione structure (structure represented by the formula (7)), a smaller amount of catalyst is used for simultaneously proceeding isocyanurate reaction, iminooxadiazine diion reaction and uretdione reaction. I found that it can be promoted.
- Isocyanate polymer obtained by reducing the amount of catalyst used in the above-mentioned method for producing isocyanate polymer because it causes increase in thermal yellowing and deterioration of weather resistance of the composition containing isocyanate polymer
- the heat yellowing and weather resistance of the composition comprising
- the amount of the inert compound contained in the polyisocyanate composition of the present embodiment is preferably 2.0 ⁇ 10 ⁇ 4 parts by mass with respect to 100 parts by mass of the polyisocyanate from the viewpoint of obtaining the above effect more effectively. Or more, more preferably 2.0 ⁇ 10 ⁇ 3 parts by mass or more, and still more preferably 3.0 ⁇ 10 ⁇ 2 parts by mass or more.
- the content of the inert compound is preferably 2.0 parts by mass or less, more preferably 1.3 parts by mass or less, and 1.0 part by mass or less with respect to 100 parts by mass of the polyisocyanate. More preferably. When the content of the inert compound is 2.0 parts by mass or less, there is a tendency that it is difficult to cause coloring.
- the polyisocyanate composition of the present embodiment may contain a compound represented by the formula (1).
- a reaction such as an isocyanurate reaction using a diisocyanate composition further containing a compound represented by the formula (1)
- the reactivity of the reaction such as an isocyanurate reaction is further improved, and the amount of catalyst is reduced. This can be further reduced.
- the present inventors stabilize the catalyst by the coordination of the urethane group (—NHCOO—) of the compound represented by the formula (1) to the catalyst. I guess because.
- the urethane group (—NHCOO—) remains in the isocyanate polymer, it may cause thermal yellowing or coloring.
- the urethane group of the compound represented by the formula (1) has a low thermal decomposition temperature, it is often thermally decomposed by heating when distilling and purifying unreacted polyisocyanate after the reaction such as isocyanurate reaction. It is difficult to remain in a composition containing an isocyanate polymer as an impurity. For this reason, the compound represented by Formula (1) has the advantage that it is difficult to cause thermal yellowing and deterioration of weather resistance of the composition containing the obtained isocyanate polymer.
- the amount of the compound represented by the formula (1) contained in the polyisocyanate composition of the present embodiment is 2.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass with respect to 100 parts by mass of the polyisocyanate. Preferably there is.
- the content of the compound represented by the formula (1) is more preferably 3.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the polyisocyanate.
- the amount is more preferably 0.0 ⁇ 10 ⁇ 4 parts by mass or more, and further preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the content of the compound represented by the formula (1) is more preferably 0.5 parts by mass or less, and 0.3 parts by mass or less with respect to 100 parts by mass of the polyisocyanate. It is more preferable that it is 0.1 mass part or less.
- the polyisocyanate composition of the present embodiment can further contain an unsaturated bond compound.
- an unsaturated bond compound By further containing an unsaturated bond compound, the reactivity of the polyisocyanate composition of this embodiment in the reaction such as the isocyanurate reaction can be further improved, and the amount of catalyst can be further reduced.
- the present inventors presume that the catalytic activity is increased by the coordination of the unsaturated bond of the unsaturated bond compound to the catalyst.
- the amount of the unsaturated bond compound to be subjected to a reaction such as an isocyanuration reaction.
- the amount of the unsaturated bond compound added to the reaction system of the isocyanurate reaction is 2.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass with respect to 100 parts by mass of the polyisocyanate. It is preferable.
- the unsaturated bond compound is contained in such a range, the reactivity of the reaction such as isocyanurate reaction is further improved, and the amount of catalyst can be further reduced.
- the amount of the unsaturated bond compound contained in the polyisocyanate composition is more preferably 3.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the polyisocyanate. Preferably, it is 5.0 ⁇ 10 ⁇ 4 parts by mass or more, and more preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the amount of the unsaturated bond compound added to the reaction system of the reaction such as isocyanurate reaction is 0.5 parts by weight relative to 100 parts by weight of isocyanate. It is more preferably no greater than part by mass, even more preferably no greater than 0.3 part by mass, and even more preferably no greater than 0.1 part by mass.
- a method for producing an isocyanate polymer using the polyisocyanate composition of the present embodiment will be described.
- isocyanurate formation reaction is mainly described, as will be described later, iminooxadiazine diionization reaction and uretdiionization reaction can also occur depending on the catalyst or reaction conditions used.
- the isocyanuration reaction is preferably performed in the presence of an isocyanuration catalyst.
- a catalyst having basicity is generally preferable, and the following compounds are exemplified.
- tetraalkylammonium hydroxide tetramethylammonium, tetraethylammonium, etc.
- organic acid salt for example, salts of acetate, butyrate, decanoate, etc.
- hydroxide or organic acid salt for example, acetate, butyrate, decanoate, etc.
- trialkylhydroxyalkylammonium trimethylhydroxypropylammonium, trimethylhydroxyethylammonium, triethylhydroxypropylammonium, triethylhydroxyethylammonium, etc.
- metal salts of alkyl carboxylic acids such as acetic acid, capric acid, octylic acid, myristic acid (for example, tin salt, zinc salt, lead salt
- Vi Phosphorus compounds such as tributylphosphine.
- Fluorine compound or polyhydrofluoride compound for example, tetraalkylammonium fluoride such as tetramethylammonium fluoride hydrate, tetraethylammonium fluoride, etc.
- a compound having a structure represented by the following formula (28) or formula (29) for example, 3,3,3-trifluoropropanoic acid; 3,3,4,4,4-pentafluorobutanoic acid; 3,3,4,4,5,5,5-heptafluoropentanoic acid; 3,3-difluoroprop-2-enoic acid and the like
- quaternary ammonium ion or quaternary phosphonium ion for example, 3,3,3-trifluoropropanoic acid; 3,3,4,4,4-pentafluorobutanoic acid; 3,3,4,4,5,5,5-heptafluoropentanoic acid;
- R 19 CR′-C ( ⁇ O) O— (28)
- R 20 —CR ′ 2 —C ( ⁇ O) O— (29)
- R 19 and R 20 each independently represents a perfluoroalkyl group having 1 to 30 carbon atoms
- R ′ each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, And one selected from the group consisting of aromatic groups, and these may contain heteroatoms.
- R 19 and R 20 may each independently be a linear, branched or cyclic saturated perfluoroalkyl group or an unsaturated perfluoroalkyl group.
- the catalyst (i) or (ii) is preferable from the viewpoint of catalyst efficiency and isocyanuration reaction selectivity.
- the use of the catalyst (vi) is preferable.
- the amount of the isocyanuration catalyst added to the reaction system of the isocyanuration reaction can be adjusted as appropriate according to the type of catalyst used, the concentration of other components in the reaction system, etc. 1.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass.
- the upper limit of the amount of the isocyanurate-forming catalyst used is preferably 5.0 ⁇ 10 ⁇ 1 part by mass or less, more preferably from the viewpoint of suppressing coloration or discoloration of the product and controlling the reaction. It is 0 ⁇ 10 ⁇ 1 part by mass or less, more preferably 2.0 ⁇ 10 ⁇ 2 part by mass or less. From the viewpoint of reactivity, the lower limit of the amount of the isocyanurate-forming catalyst used is more preferably 1.0 ⁇ 10 ⁇ 3 parts by mass, and still more preferably 2.0 ⁇ 10 ⁇ 3 parts by mass.
- the above-mentioned isocyanurate-forming catalyst can simultaneously be an allophanate catalyst. Therefore, it is also possible to add the hydroxy group-containing compound before or during the isocyanuration reaction and to proceed the isocyanuration reaction and the allophanate reaction simultaneously.
- the hydroxy group-containing compound is preferably a compound having one or two hydroxy groups in one molecule formed only of carbon, hydrogen and oxygen. More preferred is a compound having only one hydroxy group.
- Specific examples of the compound having one hydroxy group include methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol, pentyl alcohol, hexyl alcohol, heptyl alcohol, octyl alcohol, nonyl alcohol and the like, which have two hydroxy groups.
- Examples of the compound include ethylene glycol, 1,3-butanediol, 1,4-butanediol, neopentyl glycol, 2-ethylhexanediol and the like, and two or more kinds can be used in combination.
- the reaction temperature of the isocyanuration reaction is not particularly limited, but is preferably 0 ° C. to 200 ° C. If it is less than 0 ° C., the reaction rate is small and not practical, and if it is reacted at a high temperature exceeding 200 ° C., side reactions or extreme coloring of the product tends to occur.
- the lower limit of the reaction temperature is more preferably 40 ° C., further preferably 50 ° C., and most preferably 60 ° C. from the viewpoint of the reaction rate.
- the upper limit of the reaction temperature is more preferably the product itself, the obtained polyisocyanate or 150 ° C., and preferably 40 ° C. to 150 ° C.
- the upper limit of the polymerization reaction temperature is more preferably 150 ° C. or less, still more preferably 120 ° C., and most preferably 110 ° C. from the viewpoint of coloring the product.
- the reaction time of the isocyanuration reaction is not particularly limited, and can be carried out, for example, in the range of 10 seconds to 24 hours.
- Examples of methods for confirming the end point of the isocyanuration reaction include a method for measuring the isocyanate group content (NCO%) in the reaction mixture, a method for measuring the refractive index, and a method for measuring the reaction mixture by gel permeation chromatography. Is done. In addition, the measuring method of the content rate (NCO%) of the isocyanate group in a reaction mixture is mentioned later.
- the ratio of the reacted polyisocyanate to the initial amount is preferably 50% or less (more preferably 40% or less, still more preferably 25% or less). Further, from the viewpoint of sufficiently obtaining the yield of the isocyanurate compound, the conversion rate of the reaction is preferably 5% or more, more preferably 10% or more, and more preferably 15% or more.
- the isocyanuration reaction when the isocyanuration reaction reaches the target conversion rate, the isocyanuration reaction can be stopped by adding a catalyst terminator to deactivate the isocyanuration catalyst. If a catalyst terminator is not added, the isocyanurate-forming reaction further proceeds during the distillation purification of the isocyanate polymer, which may lead to a higher viscosity of the product and generation of a gel content. In order to prevent the isocyanuration reaction from proceeding during distillation purification, it is preferable to deactivate the isocyanuration catalyst by adding a catalyst terminator.
- the amount of catalyst used can be sufficiently suppressed by adding an inert compound (at least one compound selected from the group consisting of Compound A to Compound G), even when a catalyst stopper is added, Deformation and weather resistance can be sufficiently improved.
- an inert compound at least one compound selected from the group consisting of Compound A to Compound G
- the isocyanurate-forming catalyst compound B is preferred.
- the catalyst terminator for example, sulfuric acid, phosphoric acid, acidic phosphoric acid esters, hydrochloric acid, sulfonic acid compounds and the like can be used.
- the reaction product of the catalyst stopper and the catalyst is precipitated as a solid, it is preferably separated by a method such as filtration using a filter or celite.
- the isocyanurate formation reaction can be carried out in the presence or absence of a solvent, but it is desirable to carry out in the presence of a solvent from the viewpoint of ease of control of the reaction and ease of operation.
- a solvent which is inert to the polyisocyanate used and dissolves the starting isocyanate and the generated isocyanurate compound is selected.
- acetates such as ethyl acetate, butyl acetate, and amyl acetate
- aromatic hydrocarbons such as benzene, toluene, xylene, and monochlorobenzene can be used alone or in combination.
- the conversion rate of the isocyanurate reaction in the absence of a solvent is preferably 5% to 50%, more preferably 10% to 40%.
- the isocyanurate compound can be recovered, for example, by removing unreacted polyisocyanate and solvent from the reaction system.
- the removal method is not particularly limited, and unreacted polyisocyanate and solvent can be removed by, for example, distillation purification. Further, the removal is desirably performed at a low temperature. For example, the removal is preferably performed using a device having a large evaporation area with respect to a liquid such as a falling thin film evaporator, a thin film evaporator, a molecular distillation device, etc., and having a high evaporation efficiency. .
- the polyisocyanate concentration contained in the composition containing the isocyanate polymer is 1% by mass or less by removing these.
- the upper limit of the diisocyanate concentration is more preferably 0.7% by mass or less, still more preferably 0.5% by mass or less, and still more preferably 0.3% by mass or less.
- the average value of the number of isocyanate groups is preferably 2.3 or more. More preferably, it is 2.5 or more, More preferably, it is 2.7 or more, More preferably, it is 3.0 or more, More preferably, it is 3.2 or more.
- the polyisocyanate and at least one compound selected from the group consisting of the compounds A to G may be independently supplied to the reaction system, and the polyisocyanate, and After preparing a polyisocyanate composition containing at least one compound selected from the group consisting of the compounds A to G, the polyisocyanate composition may be subjected to a reaction system.
- the polyisocyanate composition used for the isocyanuration reaction or the like is, for example, 5.0 ⁇ 10 ⁇ 4 parts by mass to 2.0 parts by mass with respect to 100 parts by mass of polyisocyanate and polyisocyanate. And at least one compound selected from the group consisting of the above-mentioned compounds A to G.
- an isocyanuration reaction or the like can be carried out more easily.
- the content of polyisocyanate in the polyisocyanate composition may be 98% by mass or more or 99% by mass or more based on the total mass of the polyisocyanate composition.
- the polyisocyanate composition of this embodiment may further contain the compound represented by Formula (1).
- the content of the compound represented by the formula (1) is preferably 2.0 ⁇ 10 ⁇ 4 parts by mass or more and 1.0 parts by mass or less with respect to 100 parts by mass of the polyisocyanate.
- the polyisocyanate composition of the present embodiment may further contain an unsaturated bond compound.
- the content of the unsaturated bond compound is preferably 2.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass with respect to 100 parts by mass of the polyisocyanate.
- the polyisocyanate composition of this embodiment is suitable for production of an isocyanate polymer obtained by polymerizing polyisocyanate.
- the isocyanate polymer has a unit represented by the following formula (2), and has at least one unit among the units represented by the following formulas (3) to (9).
- the nitrogen atom which comprises an isocyanate polymer has couple
- R 3 represents a divalent hydrocarbon group
- R 4 represents a monovalent organic group
- a plurality of R 3 and R 4 may be the same or different.
- R 3 is a group derived from polyisocyanate.
- the polyisocyanate is a diisocyanate in which c is 2 and the compound represented by the formula (10), R 3 is the same as the definition of R 1 in the formula (1).
- R 4 depends on the compound used when the isocyanate polymer is produced. For example, when alcohol is used, the residue obtained by removing the hydroxy group (OH group) from the alcohol is used. It is a group.
- the method for producing an isocyanurate compound according to the present embodiment includes a step of obtaining an isocyanurate compound having an isocyanurate structure by an isocyanurate-forming reaction of an isocyanate compound having an isocyanate group, and the isocyanurate-forming reaction is performed using 100 masses of the isocyanate compound.
- the reaction is carried out in a reaction system in which 2.0 ⁇ 10 ⁇ 3 parts by mass or more and 2.0 parts by mass or less of benzyltoluene is added.
- the present inventors converted a specific amount of benzyltoluene to isocyanurate. It has been found that the isocyanuration reaction can be carried out with a smaller amount of catalyst by subjecting it to the reaction.
- the catalyst used in the production of the isocyanurate compound causes an increase in thermal yellowing of the isocyanurate compound and a deterioration in weather resistance. Therefore, by reducing the amount of the catalyst used, The remarkable effect that denaturation and weather resistance are improved is produced.
- the mechanism by which such an effect is manifested is not clear, it is presumed that the presence of benzyltoluene reduces the polarity in the reaction system and activates the catalyst.
- benzyltoluene There are three types of isomers represented by the following formulas (3-1), (3-2), and (3-3) in benzyltoluene.
- benzyltoluene is any of these. These isomers may be used, or a mixture of these isomers may be used.
- the content of benzyltoluene indicates the total content of isomers.
- the amount of benzyltoluene added to the reaction system of the isocyanurate reaction is preferably 5.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the isocyanate compound from the viewpoint of obtaining the above effect more effectively. More preferably, it is 2.0 ⁇ 10 ⁇ 3 parts by mass or more, and further preferably 3.0 ⁇ 10 ⁇ 2 parts by mass or more.
- the amount of benzyltoluene added to the reaction system of the isocyanurate reaction is 2.0% with respect to 100 parts by mass of the isocyanate compound. It is preferably no greater than part by mass, more preferably no greater than 1.3 parts by mass, and even more preferably no greater than 1.0 part by mass.
- benzyltoluene and the like may contain compounds represented by the following formulas (4-1) to (4-8).
- benzyltoluene containing these compounds is included. May be used as they are, or benzyltoluene purified by distillation purification or the like may be used.
- content of these compounds in the reaction system of isocyanurate formation reaction is 10 mass parts or less with respect to 100 mass parts of benzyl toluene.
- the isocyanate compound in the present embodiment is not particularly limited, and can be appropriately changed according to the target isocyanurate compound.
- aliphatic diisocyanate and / or alicyclic diisocyanate are preferred from the viewpoint of obtaining an isocyanurate compound that can be suitably used for applications requiring weather resistance.
- An aromatic diisocyanate can also be selected for the purpose of applying to a field where weather resistance or the like is not required.
- the isocyanate compound may be an isocyanate compound having two or more isocyanate groups, or may be an isocyanate compound having 2 to 4 isocyanate groups. May be an isocyanate compound having two.
- the isocyanate compound may be a compound represented by the following formula (10).
- c represents an integer of 2 to 4
- R 1 represents a c-valent organic group.
- R 1 examples include an aliphatic hydrocarbon group, an alicyclic hydrocarbon group (a hydrocarbon group having an alicyclic group), and an aromatic hydrocarbon group (a hydrocarbon group having an aromatic ring).
- Examples of the aliphatic hydrocarbon group include groups having 1 to 40 (preferably 4 to 30) carbon atoms. Specific examples of the aliphatic hydrocarbon group include butane (each isomer), pentane (each isomer), hexane (each isomer), heptane (each isomer), octane (each isomer), decane ( Each isomer), dodecane (each isomer), octadecane (each isomer) and the like, and a group obtained by removing c hydrogen atoms from an aliphatic hydrocarbon.
- Examples of the alicyclic hydrocarbon group include groups having 6 to 40 (preferably 8 to 30) carbon atoms. Specific examples of the alicyclic hydrocarbon group include cyclohexane, dimethylcyclohexane (each isomer), tetramethylcyclohexane (each isomer), dicyclohexylmethane, cycloheptane, cyclooctane, and other alicyclic hydrocarbons. And groups in which one hydrogen atom is removed.
- aromatic hydrocarbon group examples include groups having 6 to 40 (preferably 8 to 30) carbon atoms.
- Specific examples of the aromatic hydrocarbon group include groups in which c hydrogen atoms have been removed from an aromatic hydrocarbon such as benzene, toluene, xylene (each isomer), naphthalene, diphenylmethane, biphenyl and the like.
- R 1 may be a group in which a substituent such as a halogen atom, an alkoxy group, or an alkoxycarbonyl group is substituted on the above group.
- isocyanate compound examples include tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, 2,2,4-trimethyl-1,6-diisocyanatohexane, lysine diisocyanate, isophorone diisocyanate, 1,3-bis (isocyanate). Naphthomethyl) -cyclohexane, 4,4′-dicyclohexylmethane diisocyanate, 4,4′-diphenylmethane diisocyanate, toluene diisocyanate (each isomer), lysine triisocyanate and the like.
- hexamethylene diisocyanate and isophorone diisocyanate are preferred from the viewpoint of being suitable for applications requiring weather resistance and heat yellowing resistance and being easily available industrially.
- an isocyanate compound may be used individually or may be used together.
- the isocyanuration reaction can also be performed in a reaction system in which a compound formed by reacting a part or all of the isocyanate groups of the isocyanate compound with phenol to form a urethane bond is added. That is, when the isocyanate compound is a compound represented by the formula (10), a compound represented by the following formula (1) can be further provided for the isocyanuration reaction.
- the urethane group (—NHCOO—) may cause thermal yellowing or coloring when remaining in the isocyanurate compound, but the urethane group of the compound represented by the formula (1) has a thermal decomposition temperature of Since it is low, it is thermally decomposed by heating when the unreacted isocyanurate compound is separated by distillation after the isocyanuration reaction.
- the thermal decomposition products of the compound represented by the formula (1) are an isocyanurate compound and phenol, both of which are easily separated from the isocyanurate compound by distillation. Therefore, the isocyanurate compound is represented by the formula (1). Impurities derived from the resulting compounds are unlikely to remain. For this reason, the compound represented by Formula (1) has the advantage that it is unlikely to cause thermal yellowing or deterioration of weather resistance of the isocyanurate compound.
- the amount of the compound represented by the formula (1) used for the isocyanuration reaction is 2.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the isocyanate compound. It is preferable that it is 1.0 mass part or less.
- the amount of the compound represented by the formula (1) added to the reaction system of the isocyanuration reaction is 3.0 ⁇ 10 ⁇ 4 mass relative to 100 mass parts of the isocyanate compound. More preferably, it is 5.0 ⁇ 10 ⁇ 4 parts by mass or more, and further preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the amount of the compound represented by the formula (1) added to the reaction system of the isocyanurate reaction is 0.5 parts by mass or less with respect to 100 parts by mass of the isocyanate compound. More preferably, it is 0.3 mass part or less, More preferably, it is 0.1 mass part or less.
- the addition amount of the compound represented by Formula (1) is the total amount of the multiple types.
- the compound represented by formula (1) includes a compound represented by the following formula (1-3) and a compound represented by the following formula (1-4).
- R 1 represents the same divalent organic group as R 1 in Formula (1).
- the isocyanuration reaction can also be performed in a reaction system to which ⁇ -methylstyrene is further added.
- ⁇ -methylstyrene By subjecting ⁇ -methylstyrene to the isocyanuration reaction in addition to the benzyltoluene described above, the reactivity of the isocyanuration reaction can be further improved and the amount of catalyst can be further reduced.
- the present inventors speculate that the catalytic activity is enhanced by the coordination of the unsaturated bond of ⁇ -methylstyrene to the catalyst.
- the amount of ⁇ -methylstyrene used for the isocyanuration reaction is 2.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass with respect to 100 parts by mass of the isocyanate compound. The following is preferable.
- the amount of ⁇ -methylstyrene added to the reaction system of the isocyanuration reaction is 3.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the isocyanate compound. More preferably, it is 5.0 ⁇ 10 ⁇ 4 parts by mass or more, and further preferably 1.0 ⁇ 10 ⁇ 3 parts by mass or more.
- the amount of ⁇ -methylstyrene added to the reaction system of the isocyanurate reaction is more preferably 0.5 parts by mass or less with respect to 100 parts by mass of the isocyanate compound.
- the amount is more preferably 0.3 parts by mass or less, and still more preferably 0.1 parts by mass or less.
- the isocyanuration reaction is preferably performed in the presence of a catalyst (isocyanuration catalyst).
- a catalyst isocyanuration catalyst
- the isocyanuration catalyst include tetraalkylammonium hydroxide or organic weak acid salt such as tetramethylammonium, tetraethylammonium and tetrabutylammonium; trimethylhydroxypropylammonium, trimethylhydroxyethylammonium, triethylhydroxypropylammonium, triethylhydroxyethylammonium and the like
- Trialkylhydroxyalkylammonium hydroxides or organic weak acid salts alkali metal salts of alkyl carboxylic acids such as acetic acid, caproic acid, octylic acid and myristic acid; alkyl carboxylic acids such as acetic acid, caproic acid, octylic acid and myristic acid
- Metal salts such as tin, zinc and lead
- the amount of the isocyanurate catalyst added to the reaction system of the isocyanurate reaction can be appropriately adjusted according to the type of catalyst used, the concentration of other components in the reaction system, and the like. On the other hand, it can be 1.0 ⁇ 10 ⁇ 4 mass parts or more and 1.0 ⁇ 10 ⁇ 2 mass parts or less.
- the reaction temperature of the isocyanuration reaction is preferably 0 ° C. to 200 ° C., more preferably 50 to 120 ° C. If it is less than 0 ° C., the reaction rate is small and impractical, and if it is reacted at a high temperature exceeding 200 ° C., side reactions or extreme coloring of the product tends to occur.
- the reaction time of the isocyanuration reaction is not particularly limited, and can be carried out, for example, in the range of 10 seconds to 24 hours.
- the reaction solution can be sampled, and after confirming that the isocyanurate structure is contained in, for example, an infrared absorption spectrum, the reaction can be terminated, or a desired weight average molecular weight can be reached by gel permeation chromatography. After confirming that the reaction is complete, the reaction can be terminated.
- the ratio of the reacted isocyanate compound to the initial amount is preferably 50% or less (more preferably 40% or less, still more preferably 25% or less). Further, from the viewpoint of sufficiently obtaining the yield of the isocyanurate compound, the conversion rate of the reaction is preferably 5% or more, more preferably 10% or more, and more preferably 15% or more.
- the isocyanuration reaction when the isocyanuration reaction reaches the target conversion rate, the isocyanuration reaction can be stopped by adding a catalyst terminator to deactivate the catalyst.
- a catalyst terminator that can cause thermal yellowing, but the isocyanuration reaction proceeds during the distillation separation of the isocyanate compound described later, resulting in higher viscosity of the product and generation of gel content.
- the amount of catalyst used can be sufficiently suppressed by the addition of benzyltoluene, so that even when a catalyst terminator is added, thermal yellowing and weather resistance can be sufficiently improved.
- the catalyst terminator for example, sulfuric acid, phosphoric acid, phosphoric acid esters and the like can be used.
- the reaction product of the catalyst stopper and the catalyst is precipitated as a solid, it is preferably separated by a method such as filtration using a filter or celite.
- the isocyanuration reaction can be carried out either in the presence or absence of a solvent, but from the viewpoint of ease of control of the reaction and ease of operation, it can be carried out in the presence of a solvent. desirable.
- a solvent which is inert to the isocyanate compound used and dissolves the starting isocyanate compound and the generated isocyanurate compound is selected.
- acetates such as ethyl acetate, butyl acetate, and amyl acetate
- aromatic hydrocarbons such as benzene, toluene, xylene, and monochlorobenzene can be used alone or in combination.
- the conversion rate of the isocyanurate reaction in the absence of a solvent is preferably 5% to 50%, more preferably 10% to 40%.
- the isocyanurate compound can be recovered by removing the unreacted isocyanate compound and the solvent from the reaction system.
- the removal method is not particularly limited, and unreacted isocyanate and solvent can be removed by, for example, distillation separation. Further, the removal is desirably performed at a low temperature. For example, the removal is preferably performed using a device having a large evaporation area with respect to a liquid such as a falling thin film evaporator, a thin film evaporator, a molecular distillation device, etc., and having a high evaporation efficiency. .
- the isocyanate compound and ⁇ -methylstyrene may be independently supplied to the reaction system, and after preparing an isocyanate composition containing the isocyanate compound and ⁇ -methylstyrene in advance, the The isocyanate composition may be subjected to a reaction system.
- the isocyanate composition subjected to the isocyanuration reaction is, for example, an isocyanate compound having an isocyanate group and 5.0 ⁇ 10 ⁇ 4 parts by mass to 2.0 parts by mass with respect to 100 parts by mass of the isocyanate compound. Part or less of benzyltoluene.
- the isocyanuration reaction can be carried out more easily.
- the content of the isocyanate compound in the isocyanate composition may be 98% by mass or more and 99% by mass or more based on the total amount of the isocyanate composition.
- the isocyanate composition may further contain a compound represented by the formula (1), and the content thereof is 2.0 ⁇ 10 ⁇ 4 parts by mass or more with respect to 100 parts by mass of the isocyanate compound. It is preferably 0 parts by mass or less. Thereby, the isocyanuration reaction to which the compound represented by the formula (1) is added can be easily performed.
- the isocyanate composition may further contain ⁇ -methylstyrene, and the content thereof is 2.0 ⁇ 10 ⁇ 4 parts by mass to 1.0 part by mass with respect to 100 parts by mass of the isocyanate compound. Preferably there is. Thereby, the isocyanuration reaction to which ⁇ -methylstyrene is added can be easily carried out.
- the present invention can be said to be a method of reducing the amount of catalyst in the isocyanurate reaction of an isocyanate compound, and a method of improving the thermal yellowing of the isocyanurate compound produced in the isocyanurate reaction of the isocyanurate compound. You can also.
- ⁇ Use of isocyanate polymer> Using the composition containing various isocyanate polymers obtained by the method described above, a part or all of the isocyanate groups of the isocyanate polymer can be blocked with a blocking agent to produce a blocked isocyanate polymer. .
- a blocking agent which can be used here.
- the blocking agent is a compound having one active hydrogen in the molecule.
- the blocking agent is a compound having one active hydrogen in the molecule.
- alcohol alkylphenol, phenol, active methylene, mercaptan, acid amide, acid imide, imidazole, urea, oxime Type, amine type, imide type, pyrazole type compound and the like. Examples of more specific blocking agents are shown below.
- Ureas Urea, thiourea, ethylene urea, etc.
- amines diphenylamine, aniline, carbazole, di-n-propylamine, diisopropylamine, isopropylethylamine, etc.
- imines ethyleneimine, polyethyleneimine, etc.
- pyrazoles pyrazole, 3- Examples include methylpyrazole and 3,5-dimethylpyrazole.
- a preferred blocking agent is at least one selected from alcohols, oximes, acid amides, active methylenes, and pyrazoles.
- a hydrophilic group-modified isocyanate polymer composition obtained by modifying a part of the isocyanate groups of various isocyanate polymers obtained by the above method with an active hydrogen-containing hydrophilic compound. It can also be obtained.
- the active hydrogen-containing hydrophilic compound is selected from nonionic hydrophilic compounds, anionic hydrophilic compounds, and cationic hydrophilic compounds. Among these, nonionic hydrophilic compounds and anionic hydrophilic compounds are preferable from the viewpoint of ease of production, and nonionic hydrophilic compounds are more preferable. These hydrophilic compounds may be used alone or in combination of two or more.
- nonionic hydrophilic compounds include polyethylene glycol compounds having at least three consecutive ethylene oxide groups.
- the number average molecular weight of the nonionic hydrophilic compound is preferably 200 to 2,000.
- the lower limit of the number average molecular weight is more preferably 300, still more preferably 400.
- the upper limit of the number average molecular weight is more preferably 1500, still more preferably 1200, and most preferably 1000.
- the lower limit of the number average molecular weight is 200 or more, sufficient water dispersibility of the composition can be obtained.
- the upper limit of the number average molecular weight is 2000 or less, it is possible to suppress a decrease in coating properties such as water resistance after baking.
- the exemplified polyethylene glycol compound having at least three consecutive ethylene oxide groups may contain other oxyalkylene groups, specifically oxypropylene groups or oxystyrene groups, in the ethylene oxide unit.
- the molar ratio of the ethylene oxide group is preferably 60 mol% or more, more preferably 70 mol% or more, and most preferably 80 mol% or more.
- the compoundability in the water-based paint can be improved efficiently, which is preferable.
- polyethylene glycol compounds examples include monoalkoxy polyethylene glycol, polyethylene glycol or triol; Pluronic type polypropylene glycol or triol obtained by addition polymerization of ethylene oxide at the end of polypropylene glycol; polyoxypropylene polyoxyethylene copolymer diol or triol; Examples include polyoxypropylene polyoxyethylene block polymer diol or triol.
- monoalkoxy polyethylene glycol and polyethylene glycol are preferable, and monoalkoxy polyethylene glycol is more preferable.
- Monoalkoxy polyethylene glycol is a compound having a structure in which a monoalcohol is added to one end of polyethylene glycol.
- the monoalcohol that can be used in the monoalkoxy polyethylene glycol preferably has 1 to 8 carbon atoms, more preferably 1 to 6 carbon atoms, and still more preferably 1 to 4 carbon atoms. Most preferred are methyl alcohol and ethyl alcohol.
- monoalkoxy polyethylene glycols monomethoxy polyethylene glycol or monoethoxy polyethylene glycol is preferable, and monomethoxy polyethylene glycol is most preferable.
- polyethylene glycol compounds used as the active hydrogen-containing hydrophilic compound polyethylene glycol compounds in which a monoalcohol having 1 to 4 carbon atoms is added to one end having a number average molecular weight of 200 to 2000 are particularly preferable.
- polyethylene glycol examples include PEG200, 300, 400, 600, 1000 or 2000 manufactured by Nippon Oil & Fat Co., Ltd.
- monomethoxypolyethylene glycol examples include UNIOX M400, 550, 1000, 2000 manufactured by Nippon Oil & Fats Co., Ltd., and product MPG-081 manufactured by Nippon Emulsifier Co., Ltd.
- anionic hydrophilic compound examples include a carboxy group-containing compound and a sulfo group-containing compound.
- carboxy group-containing compound examples include monohydroxycarboxylic acid, dihydroxycarboxylic acid, and derivatives thereof. Among the carboxy group-containing compounds, monohydroxycarboxylic acid or dihydroxycarboxylic acid is preferable, and monohydroxycarboxylic acid is more preferable.
- carboxy group-containing compound examples include hydroxypivalic acid, 2,2-dimethylolpropionic acid, 2,2-dimethylolbutanoic acid, or derivatives such as polycaprolactone diol and polyether polyol using these as initiators. Can be mentioned.
- a carboxy group-containing compound it is preferable to neutralize with a neutralizing agent after the production of the block polyisocyanate composition.
- the neutralizing agent include tertiary amines such as alkali metals, alkaline earth metals, ammonia, trimethylamine, triethylamine, and dimethylethanolamine.
- the sulfo group-containing compound examples include aminoethylsulfonic acid, ethylenediamino-propyl- ⁇ -ethylsulfonic acid, 1,3-propylenediamine- ⁇ -ethylsulfonic acid, N, N-bis (2-hydroxyethyl) -2- Aminoethanesulfonic acid is mentioned.
- a neutralizing agent examples include tertiary amines such as alkali metals, alkaline earth metals, ammonia, trimethylamine, triethylamine, and dimethylethanolamine.
- a carboxy group-containing compound is preferable from the viewpoint of ease of production and blendability in water-based paints.
- cationic hydrophilic compounds include hydroxy group-containing amino compounds. Specific examples include dimethylethanolamine, diethylethanolamine, and hydroxypyridine. When a hydroxy group-containing amino compound is used, it is preferably neutralized with a neutralizing agent after the production of the block polyisocyanate composition as described above.
- the neutralizing agent include organic acids such as acetic acid, propionic acid, butanoic acid, and 2-ethylhexanoic acid.
- a hydrogen of a hydroxy group is exemplified as long as it is a nonionic hydrophilic compound.
- hydroxypivalic acid which is an anionic hydrophilic compound
- hydrogen of hydroxy group is exemplified
- aminoethylsulfonic acid hydrogen of amino group is exemplified.
- dimethylethanolamine which is a cationic hydrophilic compound
- hydrogen of a hydroxy group is illustrated.
- the amount of modification of these active hydrogen-containing hydrophilic compounds is such that B / (A + B) when the isocyanate group of the polyisocyanate composition is A mole and the active hydrogen group of the active hydrogen-containing hydrophilic compound is B mole. It is preferably 0.40 or less, more preferably 0.35 or less, still more preferably 0.30 or less, and most preferably 0.20 or less. When B / (A + B) is 0.40 or less, the crosslinkability is hardly lowered, and the water resistance of the crosslinked coating film using the polyisocyanate composition tends to be hardly lowered.
- the isocyanate polymer obtained in the embodiment may be reacted with a hydrophilic compound containing an active hydrogen.
- the reaction rate is high and coloring of the product after the reaction is also suppressed. That is surprising.
- the polyisocyanate composition of the present embodiment the method of performing distillation purification using the polyisocyanate composition, the distilled polyisocyanate composition containing the distilled polyisocyanate, and the above polyisocyanate composition
- the manufacturing method of the isocyanate polymer which makes the polyisocyanate contained in the product react, and the composition containing the said isocyanate polymer manufacture the manufacturing method of the composition in which coloring was suppressed, and the composition in which coloring was suppressed And is suitably used as a raw material for paints, adhesives and the like in fields where appearance quality is required.
- NCO content (NCO%) was determined as mass% by back titration with 1N hydrochloric acid after neutralizing the isocyanate group in the measurement sample with excess 2N amine.
- the number average molecular weight of the measurement sample was measured by gel permeation chromatography (GPC).
- the GPC measurement method was as follows. Equipment used: HLC-8120 (manufactured by Tosoh Corporation), Columns used: TSK GEL SuperH1000, TSK GEL SuperH2000, TSK GEL SuperH3000 (all manufactured by Tosoh Corporation), Sample concentration: 5 wt / vol% (50 mg of sample was dissolved in 1 mL of tetrahydrofuran (THF)), Carrier: THF, Detection method: parallax refractometer, Outflow amount: 0.6 mL / min, Column temperature: 30 ° C For the preparation of the calibration curve, polystyrene having a molecular weight of 1000 to 20000 and an isocyanurate of 1,6-diisocyanatohexane (trimer, pentamer and heptamer) were used.
- ⁇ Measurement of mass concentration of diisocyanate monomer in polyisocyanate composition First, a 20 mL sample bottle was placed on a digital balance, and 1 g of the sample was precisely weighed and added. Next, 0.03-0.04 g of nitrobenzene (internal standard solution) was precisely weighed and added to the sample bottle. Finally, 9 mL of ethyl acetate was added to the sample bottle and the lid was closed. And it was made to stir well and it was set as the measurement sample. The measurement sample was subjected to gas chromatography analysis under the following conditions to quantify the amount of diisocyanate monomer.
- Example A1 A polyisocyanate composition containing 98.7% by mass of hexamethylene diisocyanate and 2.1 mass ppm of ⁇ -methylstyrene was prepared.
- the prepared polyisocyanate composition was supplied to a continuous multistage distillation column (height 3000 mm, inner diameter 50 mm, using Dixon packing as a filler).
- the pressure at the top of the distillation column was 1 kPa (absolute pressure), and the amount of heat required for distillation was supplied from a reboiler. After the temperature distribution in the tower was stabilized, a fraction was extracted from a side cut line provided 600 mm below the top in the height direction.
- the content of hexamethylene diisocyanate was 99.9% by mass, and it was confirmed that sufficiently purified hexamethylene diisocyanate was obtained. Moreover, the Hazen color number (measured with APHA, Hazen meter) of the obtained fraction was 26.
- a mixed liquid containing hexamethylene diisocyanate and a hexamethylene diisocyanate multimer was recovered from the bottom of the column, and the fluidity of the mixed liquid was good.
- Examples A2 to A11 Except that the hexamethylene diisocyanate content and ⁇ -methylstyrene content in the polyisocyanate composition were changed as shown in Table 1, the content of hexamethylene diisocyanate was 99.9% by mass in the same manner as in Example A1. Fractions were obtained. The Hazen color number (APHA) of the obtained fraction was as shown in Table 1.
- Example A12 A polyisocyanate composition containing 98.1% by mass of hexamethylene diisocyanate, 250 mass ppm of ⁇ -methylstyrene, and 350 mass ppm of a compound represented by the following formula (5-1) or formula (5-2) was prepared. did.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A1, and a fraction having a hexamethylene diisocyanate content of 99.9% by mass was obtained.
- the Hazen color number (APHA) of the obtained fraction was 8.
- Example A13 Polyethylene containing 98.5% by mass of hexamethylene diisocyanate, 150% by mass of ⁇ -methylstyrene, 500 ppm by mass of the compound represented by formula (5-1) or formula (5-2), and 1300 ppm by mass of benzyltoluene An isocyanate composition was prepared. The prepared polyisocyanate composition was purified by distillation in the same manner as in Example A1, and a fraction having a hexamethylene diisocyanate content of 99.9% by mass was obtained. The Hazen color number (APHA) of the obtained fraction was 5.
- APHA Hazen color number
- Table 1 shows the results of each example and comparative example.
- HMDI indicates the content (mass%) of hexamethylene diisocyanate
- ⁇ MS indicates the content (mass ppm) of ⁇ -methylstyrene
- 5-1, 5-2 indicates The total content (mass ppm) of the compound represented by formula (5-1) or formula (5-2) is shown
- BT shows the content (mass ppm) of benzyltoluene.
- Example A14 A polyisocyanate composition containing 98.3% by mass of hexamethylene diisocyanate and 2.8 mass ppm of 2,4,4-trimethylpentene-1 was prepared.
- the prepared polyisocyanate composition was supplied to a continuous multistage distillation column (height 3000 mm, inner diameter 50 mm, using Dixon packing as a filler).
- the pressure at the top of the distillation column was 1 kPa (absolute pressure), and the amount of heat required for distillation was supplied from a reboiler. After the temperature distribution in the tower was stabilized, a fraction was extracted from a side cut line provided 600 mm below the top in the height direction.
- the content of hexamethylene diisocyanate was 99.9% by mass, and it was confirmed that sufficiently purified hexamethylene diisocyanate was obtained. Further, the Hazen color number (APHA) of the obtained fraction was 15. A mixed liquid containing hexamethylene diisocyanate and a hexamethylene diisocyanate multimer (compound having an isocyanurate ring structure) was recovered from the bottom of the column, and the fluidity of the mixed liquid was good.
- Examples A15 to A24 Except that the hexamethylene diisocyanate content and the 2,4,4-trimethylpentene-1 content in the polyisocyanate composition were changed as shown in Table 2, the hexamethylene diisocyanate content was the same as in Example A1. A fraction having an amount of 99.9% by mass was obtained. The Hazen color number (APHA) of the obtained fraction was as shown in Table 2.
- APHA Hazen color number
- Example A25 Contains 98.3% by mass of hexamethylene diisocyanate, 220 ppm by mass of 2,4,4-trimethylpentene-1, and 320 ppm by mass of the compound represented by the above formula (5-1) or formula (5-2)
- a polyisocyanate composition was prepared.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A1, and a fraction having a hexamethylene diisocyanate content of 99.9% by mass was obtained.
- the Hazen color number (APHA) of the obtained fraction was 4.
- Example A26 Hexamethylene diisocyanate 98.5% by mass, 2,4,4-trimethylpentene-1 at 150 ppm by mass, the compound represented by formula (5-1) or formula (5-2) at 600 ppm by mass, and n- A polyisocyanate composition containing 1200 mass ppm of hexadecane was prepared.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A1, and a fraction having a hexamethylene diisocyanate content of 99.9% by mass was obtained.
- the Hazen color number (APHA) of the obtained fraction was 3.
- Table 2 shows the results of each example and comparative example.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- TMP represents the content (mass ppm) of 2,4,4-trimethylpentene-1
- 5-1 , 5-2 indicates the total content (mass ppm) of the compound represented by formula (5-1) or formula (5-2)
- HD indicates the content (mass ppm) of n-hexadecane.
- Example A27 A polyisocyanate composition containing 98.3% by mass of hexamethylene diisocyanate and 2.2 mass ppm of 2-methylbutene was prepared.
- the prepared polyisocyanate composition was supplied to a continuous multistage distillation column (height 3000 mm, inner diameter 50 mm, using Dixon packing as a filler).
- the pressure at the top of the distillation column was 1 kPa (absolute pressure), and the amount of heat required for distillation was supplied from a reboiler. After the temperature distribution in the tower was stabilized, a fraction was extracted from a side cut line provided 600 mm below the top in the height direction.
- the content of hexamethylene diisocyanate was 99.9% by mass, and it was confirmed that sufficiently purified hexamethylene diisocyanate was obtained. Further, the Hazen color number (measured with APHA, Hazen meter) of the obtained fraction was 15. A mixed liquid containing hexamethylene diisocyanate and a hexamethylene diisocyanate multimer (compound having an isocyanurate ring structure) was recovered from the bottom of the column, and the fluidity of the mixed liquid was good.
- Examples A28 to A37 Except that the hexamethylene diisocyanate content and 2-methylbutene content in the polyisocyanate composition were changed as shown in Table 3, the content of hexamethylene diisocyanate was 99.9% by mass in the same manner as in Example A1. A fraction was obtained. The Hazen color number (APHA) of the obtained fraction was as shown in Table 3.
- APHA Hazen color number
- Example A38 A polyisocyanate composition containing 98.3% by mass of hexamethylene diisocyanate, 220 mass ppm of 2-methylbutene, and 310 mass ppm of a compound represented by the following formula (6-1) or formula (6-2) was prepared. .
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A27 to obtain a fraction having a hexamethylene diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 3.
- Example A39 Polyethylene containing 98.6% by mass of hexamethylene diisocyanate, 130% by mass of 2-methylbutene, 640 mass ppm of the compound represented by formula (6-1) or formula (6-2), and 1100 mass ppm of n-pentadecane An isocyanate composition was prepared.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A27 to obtain a fraction having a hexamethylene diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 2.
- Table 3 shows the results of each example and comparative example.
- HMDI indicates the content (mass%) of hexamethylene diisocyanate
- MB indicates the content (mass ppm) of 2-methylbutene
- 6-1,6-2 indicates the formula
- the total content (mass ppm) of the compound represented by (6-1) or formula (6-2) is shown
- PD shows the content (mass ppm) of n-pentadecane.
- Example A40 A polyisocyanate composition containing 98.2% by mass of isophorone diisocyanate and 8 ppm by mass of styrene was prepared.
- the prepared polyisocyanate composition was supplied to a continuous multistage distillation column (height 3000 mm, inner diameter 50 mm, using Dixon packing as a filler).
- the pressure at the top of the distillation column was 1 kPa (absolute pressure), and the amount of heat required for distillation was supplied from a reboiler. After the temperature distribution in the tower was stabilized, a fraction was extracted from a side cut line provided 600 mm below the top in the height direction.
- the content of isophorone diisocyanate was 99.9% by mass, and it was confirmed that sufficiently purified isophorone diisocyanate was obtained. Moreover, the Hazen color number (measured with APHA, Hazen meter) of the obtained fraction was 7. From the bottom of the column, a mixed liquid containing isophorone diisocyanate and a polymer of isophorone diisocyanate (compound having an isocyanurate ring structure) was recovered, and the fluidity of the mixed liquid was good.
- Example A41 A polyisocyanate composition containing 99.7% by mass of isophorone diisocyanate, 20% by mass of styrene, and 80 ppm by mass of a compound represented by the following formula (7-1) was prepared.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A40 to obtain a fraction having an isophorone diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 4.
- Example A42 A polyisocyanate composition containing 98.3% by mass of isophorone diisocyanate, 11 mass ppm of styrene, 100 mass ppm of the compound represented by the formula (7-1), and 1500 mass ppm of decyl ether was prepared.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A40 to obtain a fraction having an isophorone diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 3.
- Table 4 shows the results of each example and comparative example.
- IPDI indicates the content (mass%) of isophorone diisocyanate
- ST indicates the content of styrene (mass ppm)
- 7-1 is represented by formula (7-1).
- the content (mass ppm) of the compound to be produced is indicated
- DE represents the content (mass ppm) of decyl ether.
- Example A43 A polyisocyanate composition containing 98.9% by mass of isophorone diisocyanate and 14 mass ppm of nonene was prepared.
- the prepared polyisocyanate composition was supplied to a continuous multistage distillation column (height 3000 mm, inner diameter 50 mm, using Dixon packing as a filler).
- the pressure at the top of the distillation column was 1 kPa (absolute pressure), and the amount of heat required for distillation was supplied from a reboiler. After the temperature distribution in the tower was stabilized, a fraction was extracted from a side cut line provided 600 mm below the top in the height direction.
- the content of isophorone diisocyanate was 99.9% by mass, and it was confirmed that sufficiently purified isophorone diisocyanate was obtained.
- the Hazen color number (measured with APHA, Hazen meter) of the obtained fraction was 5. From the bottom of the column, a mixed liquid containing isophorone diisocyanate and a polymer of isophorone diisocyanate (compound having an isocyanurate ring structure) was recovered, and the fluidity of the mixed liquid was good.
- Example A44 A polyisocyanate composition containing 98.0% by mass of isophorone diisocyanate, 33% by mass of nonene, and 90% by mass of a compound represented by the following formula (8-1) was prepared.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A43 to obtain a fraction having an isophorone diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 3.
- Example A45 A polyisocyanate composition containing 97.7% by mass of isophorone diisocyanate, 12 mass ppm of nonene, 40 mass ppm of the compound represented by the formula (8-1), and 350 mass ppm of dibenzyl ether was prepared.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A43 to obtain a fraction having an isophorone diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 2.
- Table 5 shows the results of the examples and comparative examples.
- IPDI indicates the content (mass%) of isophorone diisocyanate
- N indicates the content of nonene (mass ppm)
- 8-1 is represented by the formula (8-1).
- the content (mass ppm) of the obtained compound is shown
- DBE shows the content (mass ppm) of dibenzyl ether.
- Example A46 A polyisocyanate composition containing 98.5% by mass of hexamethylene diisocyanate and 8% by mass of n-octene was prepared.
- the prepared polyisocyanate composition was supplied to a continuous multistage distillation column (height 3000 mm, inner diameter 50 mm, using Dixon packing as a filler).
- the pressure at the top of the distillation column was 1 kPa (absolute pressure), and the amount of heat required for distillation was supplied from a reboiler. After the temperature distribution in the tower was stabilized, a fraction was extracted from a side cut line provided 600 mm below the top in the height direction.
- the content of hexamethylene diisocyanate was 99.9% by mass, and it was confirmed that sufficiently purified hexamethylene diisocyanate was obtained.
- the Hazen color number (measured with APHA, Hazen meter) of the obtained fraction was 5.
- a mixed liquid containing hexamethylene diisocyanate and a hexamethylene diisocyanate multimer was recovered from the bottom of the column, and the fluidity of the mixed liquid was good.
- Example A47 A polyisocyanate composition containing 98.1% by mass of hexamethylene diisocyanate, 20 mass ppm of n-octene, and 40 mass ppm of the compound represented by the above formula (5-1) or formula (5-2) was prepared. .
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A46 to obtain a fraction having a hexamethylene diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 3.
- Example A48 Polyethylene containing 98.1% by mass of hexamethylene diisocyanate, 11 ppm by mass of n-octene, 20 ppm by mass of the compound represented by formula (5-1) or formula (5-2), and 100 ppm by mass of butyl phenyl ether An isocyanate composition was prepared. The prepared polyisocyanate composition was purified by distillation in the same manner as in Example A46 to obtain a fraction having a hexamethylene diisocyanate content of 99.9% by mass. The Hazen color number (APHA) of the obtained fraction was 2.
- APHA Hazen color number
- Table 6 shows the results of the examples and comparative examples.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- NO represents the content (mass ppm) of n-octene
- 5-1, 5-2 represents the formula
- the total content (mass ppm) of the compound represented by (5-1) or formula (5-2) is shown
- BPE shows the content (mass ppm) of butylphenyl ether.
- Example A49 A polyisocyanate composition containing 98.5% by mass of dicyclohexylmethane diisocyanate and 8% by mass of ⁇ -methylstyrene was prepared.
- the prepared polyisocyanate composition was supplied to a continuous multistage distillation column (height 3000 mm, inner diameter 50 mm, using Dixon packing as a filler).
- the pressure at the top of the distillation column was 1 kPa (absolute pressure), and the amount of heat required for distillation was supplied from a reboiler. After the temperature distribution in the tower was stabilized, a fraction was extracted from a side cut line provided 600 mm below the top in the height direction.
- the content of dicyclohexylmethane diisocyanate was 99.9% by mass, and it was confirmed that sufficiently purified dicyclohexylmethane diisocyanate was obtained.
- the Hazen color number (measured with APHA, Hazen meter) of the obtained fraction was 10. From the bottom of the column, a liquid mixture containing dicyclohexylmethane diisocyanate and a multimer of dicyclohexylmethane diisocyanate (compound having an isocyanurate ring structure) was recovered, and the fluidity of the liquid mixture was good.
- Example A50 A polyisocyanate composition containing 98.1% by mass of dicyclohexylmethane diisocyanate, 25 mass ppm of ⁇ -methylstyrene, and 20 mass ppm of a compound represented by the following formula (9-1) or formula (9-2) was prepared. did.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A49 to obtain a fraction having a dicyclohexylmethane diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 6.
- Example A51 Contains 98.1% by mass of dicyclohexylmethane diisocyanate, 33 ppm by mass of ⁇ -methylstyrene, 10 ppm by mass of the compound represented by formula (9-1) or formula (9-2), and 320 ppm by mass of decamethyltetrasiloxane.
- a polyisocyanate composition was prepared. The prepared polyisocyanate composition was purified by distillation in the same manner as in Example A49 to obtain a fraction having an isophorone diisocyanate content of 99.9% by mass. The Hazen color number (APHA) of the obtained fraction was 2.
- Table 7 shows the results of each example and comparative example.
- H-MDI represents the content (mass%) of dicyclohexylmethane diisocyanate
- ⁇ MS represents the content (mass ppm) of ⁇ -methylstyrene
- 9-1,9-2 Indicates the total content (mass ppm) of the compound represented by formula (9-1) or formula (9-2)
- DMTS indicates the content (mass ppm) of decamethyltetrasiloxane.
- Example A52 A polyisocyanate composition containing 98.5% by mass of hexamethylene diisocyanate and 2.8 ppm by mass of di (n-butyl) carbonate was prepared.
- the prepared polyisocyanate composition was supplied to a continuous multistage distillation column (height 3000 mm, inner diameter 50 mm, using Dixon packing as a filler).
- the pressure at the top of the distillation column was 1 kPa (absolute pressure), and the amount of heat required for distillation was supplied from a reboiler. After the temperature distribution in the tower was stabilized, a fraction was extracted from a side cut line provided 600 mm below the top in the height direction.
- the content of hexamethylene diisocyanate was 99.9% by mass, and it was confirmed that sufficiently purified hexamethylene diisocyanate was obtained. Moreover, the Hazen color number (measured with APHA, Hazen meter) of the obtained fraction was 18. A mixed liquid containing hexamethylene diisocyanate and a hexamethylene diisocyanate multimer (compound having an isocyanurate ring structure) was recovered from the bottom of the column, and the fluidity of the mixed liquid was good.
- Example A53 to A62 Except that the hexamethylene diisocyanate content and the di (n-butyl) carbonate content in the polyisocyanate composition were changed as shown in Table 8, the hexamethylene diisocyanate content was 99.99, as in Example A52. A 9% by mass fraction was obtained. The Hazen color number (APHA) of the obtained fraction was as shown in Table 8.
- Example A63 Polyisocyanate composition containing 98.6 mass% of hexamethylene diisocyanate, 250 massppm of di (n-butyl) carbonate, and 150 massppm of the compound represented by the following formula (10-1) or formula (10-2) A product was prepared.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A52 to obtain a fraction having a hexamethylene diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 10.
- Example A64 Hexamethylene diisocyanate 98.4 mass%, di (n-butyl) carbonate 150 mass ppm, compound represented by formula (10-1) or formula (10-2) 100 mass ppm, and dibenzyl ether 200 mass ppm
- a polyisocyanate composition containing was prepared.
- the prepared polyisocyanate composition was purified by distillation in the same manner as in Example A52 to obtain a fraction having a hexamethylene diisocyanate content of 99.9% by mass.
- the Hazen color number (APHA) of the obtained fraction was 8.
- Table 8 shows the results of the examples and comparative examples.
- HMDI indicates the content (mass%) of hexamethylene diisocyanate
- DBC indicates the content (mass ppm) of di (n-butyl carbonate)
- 10-1,10-” “2” represents the total content (mass ppm) of the compound represented by formula (10-1) or formula (10-2)
- DBE represents the content (mass ppm) of dibenzyl ether.
- Example B1 A polyisocyanate composition containing 98.5% by mass of hexamethylene diisocyanate and 22 ppm by mass of benzyltoluene (isomer mixture) (“mass ppm” indicates “ ⁇ 10 ⁇ 4 mass%”) was prepared. 1000 g of the prepared polyisocyanate composition was placed in a glass four-necked flask equipped with a thermometer, a stirrer, and a nitrogen seal tube, and the air in the flask was replaced with nitrogen and heated to 70 ° C. with stirring.
- Examples B2 to B15 An isocyanuration reaction was performed in the same manner as in Example B1, except that the hexamethylene diisocyanate content and the benzyltoluene content in the polyisocyanate composition were changed as shown in Table 9.
- Example B16 Hexamethylene diisocyanate 99.0% by mass, benzyltoluene (isomer mixture) 1300 ppm by mass, and a mixture of a compound represented by the following formula (11-1) and a compound represented by the following formula (11-2)
- a polyisocyanate composition containing 530 mass ppm (as two mixtures) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was carried out in the same manner as in Example B1. At this time, the amount of catalyst necessary to achieve a conversion of 20% was 75 ppm by mass relative to the polyisocyanate composition used in the reaction.
- Example B17 Hexamethylene diisocyanate 99.0 mass%, benzyltoluene (isomer mixture) 1200 mass ppm, ⁇ -methylstyrene 610 mass ppm, and a compound represented by formula (11-1) and the following formula (11-2)
- a polyisocyanate composition containing 380 ppm by weight (as a mixture of two) with the compounds represented was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was carried out in the same manner as in Example B1. The amount of catalyst necessary to achieve a conversion of 20% was 70 ppm by weight based on the polyisocyanate composition used in the reaction.
- the weather resistance of the isocyanurate compound was evaluated by the following method. Isocyanurate compound and polyester polyol (trade name Setal 166 manufactured by Nuplex Resin) were blended so that the equivalent ratio of isocyanate group / hydroxy group was 1.0, and the solid content mass of the isocyanurate compound and polyol was 50%. A mixed solution of ethyl acetate / toluene / butyl acetate / xylene / propylene glycol monomethyl ether acetate (mass ratio 30/30/20/15/5) was added to obtain a coating solution.
- the paint solution was dried on a white enameled plate and then coated with an applicator so as to have a film thickness of 40 ⁇ m. After curing the coating film at 20 ° C. and a humidity of 63% for 1 week, the weather resistance of the coated plate was evaluated. Dew panel weather meter (made by Suga Test Instruments) was used for the weather resistance evaluation. Evaluation conditions were in accordance with JIS D0205, irradiation illuminance of 30 W / m 2 , panel temperature of 60 ° C., irradiation time and dew condensation time were cycled every 4 hours. When the exposure time was 1200 hours, the gloss retention was 80% or more, and “B” was less than 80%. The results are shown in Table 9.
- Table 9 shows the composition of the polyisocyanate composition and the catalyst amount required for a conversion rate of 20% in Examples and Comparative Examples.
- HMDI indicates the content (mass%) of hexamethylene diisocyanate
- BT indicates the content (mass ppm) of benzyltoluene
- 11-1, 11-2 indicates the formula ( 11-1) represents the total content (mass ppm) of the compound represented by formula (11-2)
- ⁇ MS represents the content (mass ppm) of ⁇ -methylstyrene
- “required catalyst amount” Indicates the amount of catalyst required to achieve a conversion of 20% (ratio to the total amount of the polyisocyanate composition, mass ppm).
- Example B18 A polyisocyanate composition containing 98.1% by mass of hexamethylene diisocyanate and 25 mass ppm of n-hexadecane was prepared.
- the catalyst amount was 230 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- the reaction solution is filtered, and the unreacted hexamethylene diisocyanate is removed at the first 160 ° C. (27 Pa) and the second 150 ° C. (13 Pa) using a flow-down type thin-film distillation apparatus. An isocyanurate compound was obtained.
- Examples B19 to B32 Isocyanuration reaction was performed in the same manner as in Example B1, except that the hexamethylene diisocyanate content and n-hexadecane content in the polyisocyanate composition were changed as shown in Table 10.
- Example B33 Hexamethylene diisocyanate 99.2% by mass, n-hexadecane 1400 ppm by mass, and a mixture of the compound represented by the above formula (11-1) and the compound represented by the above formula (11-2) (two kinds of A polyisocyanate composition containing 630 ppm by weight (as a mixture) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was performed in the same manner as in Example B18. At this time, the amount of catalyst necessary to achieve a conversion of 20% was 65 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- Example B34 Hexamethylene diisocyanate 99.1 mass%, n-hexadecane 1500 mass ppm, 2,4,4-trimethylpentene-1 120 mass ppm, and the compound represented by the above formula (11-1) and the above formula (11 -2)
- a polyisocyanate composition containing 430 mass ppm of a mixture (as a mixture of two kinds) with the compound represented by (2) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was performed in the same manner as in Example B18. The amount of catalyst necessary to achieve a conversion of 20% was 55 ppm by weight based on the polyisocyanate composition used in the reaction.
- Table 10 shows the composition of the polyisocyanate composition and the catalyst amount required for a conversion rate of 20% in Examples and Comparative Examples.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- HD represents the content (mass ppm) of n-hexadecane
- 11-1, 11-2 represents the formula The total content (mass ppm) of the compound represented by (11-1) or formula (11-2) is shown
- TMP represents the content (mass ppm) of 2,4,4-trimethylpentene-1.
- Necessary catalyst amount indicates the amount of catalyst required to achieve a conversion rate of 20% (ratio to the total amount of the polyisocyanate composition, mass ppm).
- Example B35 A polyisocyanate composition containing 99.1% by mass of hexamethylene diisocyanate and 22% by mass of n-pentadecane was prepared.
- the catalyst amount was 210 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- the reaction solution is filtered, and the unreacted hexamethylene diisocyanate is removed at the first 160 ° C. (27 Pa) and the second 150 ° C. (13 Pa) using a flow-down type thin-film distillation apparatus. An isocyanurate compound was obtained.
- Examples B36 to B49 Isocyanurate-forming reaction was performed in the same manner as in Example B1, except that the hexamethylene diisocyanate content and the n-pentadecane content in the polyisocyanate composition were changed as shown in Table 11.
- Example B50 Hexamethylene diisocyanate 98.2 mass%, n-pentadecane 180 mass ppm, and a mixture of a compound represented by the following formula (12-1) and a compound represented by the following formula (12-2) (two kinds of A polyisocyanate composition containing 20 ppm by weight (as a mixture) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was carried out in the same manner as in Example B35. At this time, the amount of catalyst necessary to achieve a conversion of 20% was 70 ppm by mass relative to the polyisocyanate composition used in the reaction.
- Example B51 Hexamethylene diisocyanate 98.1 mass%, n-pentadecane 200 mass ppm, 2-methylbutene 20 mass ppm, and the compound represented by the formula (12-1) and the compound represented by the above formula (12-2) And a polyisocyanate composition containing 30 ppm by weight (as a mixture of the two).
- a polyisocyanate composition containing 30 ppm by weight (as a mixture of the two).
- an isocyanuration reaction was carried out in the same manner as in Example B35.
- the amount of catalyst necessary to achieve a conversion of 20% was 60 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- Table 11 shows the compositions of the polyisocyanate compositions and the catalyst amount required for a conversion rate of 20% in Examples and Comparative Examples.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- PD represents the content (mass ppm) of n-pentadecane
- 12-1, 12-2 represents the formula (12-1) represents the total content (mass ppm) of the compound represented by the formula (12-2)
- “MB” represents 2-methylbutene content (mass ppm)
- “required catalyst amount” Indicates the amount of catalyst required to achieve a conversion of 20% (ratio to the total amount of the polyisocyanate composition, mass ppm).
- Example B52 A polyisocyanate composition containing 98.8% by mass of hexamethylene diisocyanate and 120% by mass of dibenzyl ether was prepared.
- the catalyst amount was 230 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- the reaction solution is filtered, and the unreacted hexamethylene diisocyanate is removed at the first 160 ° C. (27 Pa) and the second 150 ° C. (13 Pa) using a flow-down type thin-film distillation apparatus. An isocyanurate compound was obtained.
- Example B53 Hexamethylene diisocyanate 98.2 mass%, dibenzyl ether 130 mass ppm, and a mixture of the compound represented by the above formula (11-1) and the compound represented by the above formula (11-2) (two kinds of A polyisocyanate composition containing 10 ppm by weight (as a mixture) was prepared. Using the prepared polyisocyanate composition, an isocyanurate-forming reaction was performed in the same manner as in Example B52. At this time, the amount of catalyst necessary to achieve a conversion of 20% was 65 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- Example B54 Hexamethylene diisocyanate 98.9 mass%, dibenzyl ether 22 mass ppm, n-octene 10 mass ppm, a compound represented by formula (11-1) and a compound represented by formula (11-2) And a polyisocyanate composition containing 10 ppm by mass (as a mixture of the two).
- a polyisocyanate composition containing 10 ppm by mass (as a mixture of the two).
- an isocyanurate-forming reaction was performed in the same manner as in Example B52.
- the amount of catalyst necessary to achieve a conversion of 20% was 55 ppm by weight based on the polyisocyanate composition used in the reaction.
- Table 12 shows the composition of the polyisocyanate composition and the amount of catalyst required for a conversion rate of 20% in Examples and Comparative Examples.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- DBE represents the content (mass ppm) of dibenzyl ether
- 11-1, 11-2 represents the formula (11-1) represents the total content (mass ppm) of the compound represented by formula (11-2)
- NO represents the content (mass ppm) of n-octene
- “required catalyst amount” Indicates the amount of catalyst required to achieve a conversion of 20% (ratio to the total amount of the polyisocyanate composition, mass ppm).
- Example B55 A polyisocyanate composition containing 98.5% by mass of hexamethylene diisocyanate and 130 ppm by mass of decyl ether was prepared.
- the catalyst amount was 120 ppm by mass relative to the polyisocyanate composition used in the reaction.
- the reaction solution is filtered, and the unreacted hexamethylene diisocyanate is removed at the first 160 ° C. (27 Pa) and the second 150 ° C. (13 Pa) using a flow-down type thin-film distillation apparatus. An isocyanurate compound was obtained.
- Example B56 Hexamethylene diisocyanate 98.4 mass%, decyl ether 160 mass ppm, and a mixture of the compound represented by the above formula (11-1) and the compound represented by the above formula (11-2) (two kinds of mixtures) As) a polyisocyanate composition containing 20 ppm by weight was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was performed in the same manner as in Example B55. At this time, the amount of catalyst necessary to achieve a conversion of 20% was 55 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- Example B57 Hexamethylene diisocyanate 99.1 mass%, decyl ether 190 mass ppm, styrene 25 mass ppm, and a mixture of the compound represented by the formula (9-1) and the compound represented by the above formula (9-2)
- a polyisocyanate composition containing 25 ppm by weight (as two mixtures) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was performed in the same manner as in Example B55. The amount of catalyst required to achieve a conversion of 20% was 50 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- Table 13 shows the composition of the polyisocyanate composition and the catalyst amount required for a conversion rate of 20% in Examples and Comparative Examples.
- HMDI indicates the content (mass%) of hexamethylene diisocyanate
- DE indicates the content (mass ppm) of decyl ether
- 9-1, 9-2 indicates the formula ( 9-1) indicates the total content (mass ppm) of the compound represented by formula (9-2)
- ST indicates the styrene content (mass ppm)
- “necessary catalyst amount” indicates conversion.
- the amount of catalyst required to achieve the rate of 20% is shown.
- Example B58 A polyisocyanate composition containing 99.1% by mass of isophorone diisocyanate and 500 ppm by mass of butyl phenyl ether was prepared.
- an isocyanurate compound was prepared in the same manner as in Example B1, the amount of the catalyst was 100 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- the reaction solution is filtered, and the unreacted isophorone diisocyanate is removed at the first 180 ° C. (27 Pa) and the second 170 ° C. (13 Pa) by using a flow-down type thin-film distillation apparatus to obtain a polymer of isophorone diisocyanate.
- An isocyanurate compound was obtained.
- Example B59 A polyisocyanate composition containing 99.2% by mass of isophorone diisocyanate, 450 mass ppm of butyl phenyl ether, and 30 mass ppm of a compound represented by the following formula (13-1) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was carried out in the same manner as in Example B58. At this time, the amount of catalyst necessary to achieve a conversion of 20% was 65 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- Example B60 A polyisocyanate composition containing 98.4% by mass of isophorone diisocyanate, 390 ppm by mass of butyl phenyl ether, 20 ppm by mass of nonene, and 30 ppm by mass of the compound represented by formula (13-1) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was carried out in the same manner as in Example B58. The amount of catalyst necessary to achieve a conversion of 20% was 55 ppm by weight based on the polyisocyanate composition used in the reaction.
- Table 14 shows the compositions of the polyisocyanate compositions and the amount of catalyst required for a conversion rate of 20% in Examples and Comparative Examples.
- IPDI represents the content (mass%) of isophorone diisocyanate
- BPE represents the content (mass ppm) of butylphenyl ether
- 13-1 represents the formula (13-1).
- N represents the content of nonene (mass ppm)
- the “necessary catalyst amount” is the amount of catalyst required to achieve a conversion rate of 20%. (Ratio to the total amount of polyisocyanate composition, mass ppm).
- Example B61 A polyisocyanate composition containing 99.0% by mass of isophorone diisocyanate and 50 mass ppm of o-dichlorobenzene was prepared.
- the catalyst amount was 220 ppm by mass relative to the polyisocyanate composition used in the reaction.
- the reaction solution is filtered, and the unreacted isophorone diisocyanate is removed at the first 180 ° C. (27 Pa) and the second 170 ° C. (13 Pa) by using a flow-down type thin-film distillation apparatus to obtain a polymer of isophorone diisocyanate. An isocyanurate compound was obtained.
- Example B62 A polyisocyanate composition containing 98.8% by mass of isophorone diisocyanate, 50 ppm by mass of o-dichlorobenzene, and 15 ppm by mass of the compound represented by the above formula (13-1) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was performed in the same manner as in Example B61. At this time, the amount of catalyst necessary to achieve a conversion of 20% was 85 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- Example B63 A polyisocyanate composition containing 98.8 mass% isophorone diisocyanate, 50 mass ppm o-dichlorobenzene, 40 mass ppm ⁇ -methylstyrene, and 15 mass ppm of the compound represented by formula (13-1) was prepared. did. Using the prepared polyisocyanate composition, an isocyanuration reaction was performed in the same manner as in Example B61. The amount of catalyst necessary to achieve a conversion of 20% was 70 ppm by weight based on the polyisocyanate composition used in the reaction.
- Table 15 shows the compositions of the polyisocyanate compositions and the amount of catalyst required for a conversion rate of 20% in Examples and Comparative Examples.
- IPDI represents the content (mass%) of isophorone diisocyanate
- OD represents the content (mass ppm) of o-dichlorobenzene
- 13-1 represents the formula (13-1).
- ⁇ MS represents the content (mass ppm) of ⁇ -methylstyrene
- “necessary catalyst amount” is necessary to achieve a conversion of 20%.
- the catalyst amount (a ratio to the total amount of the polyisocyanate composition, mass ppm) is shown.
- Example B64 A polyisocyanate composition containing 98.2% by mass of isophorone diisocyanate and 120% by mass of decamethyltetrasiloxane was prepared.
- an isocyanurate compound was prepared in the same manner as in Example B1, the amount of the catalyst was 100 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- the reaction solution is filtered, and the unreacted isophorone diisocyanate is removed at the first 180 ° C. (27 Pa) and the second 170 ° C. (13 Pa) by using a flow-down type thin-film distillation apparatus to obtain a polymer of isophorone diisocyanate.
- An isocyanurate compound was obtained.
- Example B65 A polyisocyanate composition containing 98.4% by mass of isophorone diisocyanate, 200 ppm by mass of decamethyltetrasiloxane, and 40 ppm by mass of the compound represented by the following formula (14-1) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was carried out in the same manner as in Example B64. At this time, the amount of catalyst necessary to achieve a conversion of 20% was 65 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- Example B66 A polyisocyanate composition containing 98.3% by mass of isophorone diisocyanate, 180 mass ppm of decamethyltetrasiloxane, 50 mass ppm of n-octene, and 40 mass ppm of the compound represented by formula (14-1) was prepared. . Using the prepared polyisocyanate composition, an isocyanurate-forming reaction was carried out in the same manner as in Example 64. The amount of catalyst necessary to achieve a conversion of 20% was 55 ppm by weight based on the polyisocyanate composition used in the reaction.
- Table 16 shows the composition of the polyisocyanate composition and the amount of catalyst required for a conversion rate of 20% in Examples and Comparative Examples.
- IPDI represents the content (mass%) of isophorone diisocyanate
- DMTS represents the content (mass ppm) of decamethyltetrasiloxane
- 14-1 represents the formula (14-1 )
- NO indicates the content (mass ppm) of n-octene
- “Necessary catalyst amount” indicates the amount of catalyst (poly) required to achieve a conversion rate of 20%.
- Example B67 A polyisocyanate composition containing 98.2% by mass of hexamethylene diisocyanate and 150 ppm by mass of dibenzyl ether was prepared.
- an isocyanurate compound was prepared in the same manner as in Example B1, the amount of the catalyst was 100 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- the reaction solution is filtered, and the unreacted hexamethylene diisocyanate is removed at the first 160 ° C. (27 Pa) and the second 150 ° C. (13 Pa) using a flow-down type thin-film distillation apparatus. An isocyanurate compound was obtained.
- Example B68 Hexamethylene diisocyanate 98.3% by mass, dibenzyl ether 130 mass ppm, and a mixture of a compound represented by the following formula (15-1) and a compound represented by the above formula (15-2) (two kinds of A polyisocyanate composition containing 60 ppm by weight (as a mixture) was prepared. Using the prepared polyisocyanate composition, an isocyanuration reaction was performed in the same manner as in Example B67. At this time, the amount of catalyst necessary to achieve a conversion of 20% was 65 ppm by mass with respect to the polyisocyanate composition used in the reaction.
- Example B69 Hexamethylene diisocyanate 98.1 mass%, dibenzyl ether 130 mass ppm, di (n-butyl) carbonate 60 mass ppm, and the compound represented by formula (15-1) and the above formula (15-2)
- a polyisocyanate composition containing 80 mass ppm of a mixture with the compounds represented (as two mixtures) was prepared.
- an isocyanuration reaction was performed in the same manner as in Example B67.
- the amount of catalyst necessary to achieve a conversion of 20% was 55 ppm by weight based on the polyisocyanate composition used in the reaction.
- Table 17 shows the composition of the polyisocyanate composition and the catalyst amount required for a conversion rate of 20% in the examples.
- HMDI indicates the content (mass%) of hexamethylene diisocyanate
- DBE indicates the content (mass ppm) of dibenzyl ether
- 15-1, 15-2 indicates the formula (15-1) represents the total content (mass ppm) of the compound represented by formula (15-2)
- DRC represents the content (mass ppm) of di (n-butyl) carbonate
- Necessary catalyst amount indicates the amount of catalyst required to achieve a conversion rate of 20% (ratio to the total amount of the polyisocyanate composition, mass ppm).
- Example C1 Preparation of Polyisocyanate Composition Hexamethylene diisocyanate 98.8% by mass, compounds represented by the following formulas (16-1) and (16-2) (a mixture of two) 3.5 ppm by mass (“ppm by mass”) ”Indicates“ ⁇ 10 ⁇ 4 mass% ”.) was prepared.
- Step (1-1) The inside of a four-necked flask equipped with a stirrer, a temperature system, a condenser tube and a probe for FT-IR (manufactured by METTLER TOLEDO, React-IR, AgX probe) was purged with nitrogen, and 1200 g of the prepared polyisocyanate composition, A polyester polyol “Placcel 305” (trade name of Daicel Chemical Industries) derived from a trihydric alcohol and ⁇ -caprolactone was added and heated at 130 ° C. with stirring. The reaction was carried out while confirming the amount of urethane groups produced by FT-IR, and the completion of the reaction was confirmed in about 1.7 hours.
- FT-IR manufactured by METTLER TOLEDO, React-IR, AgX probe
- Step (1-2) Subsequently, 0.5 g of a 20% octanol solution of zirconyl 2-ethylhexanoate was added to carry out an allophanatization reaction.
- a 2-ethyl-1-hexanol solution containing 10% solids of pyrophosphoric acid made by Taihei Chemical Industry, trade name “phosphoric acid (105%)” (Diluted with ethyl-1-hexanol) was added to stop the reaction. After filtering the reaction solution, distillation was performed at 160 ° C.
- the obtained residue was a polyisocyanate composition, the yield was 280 g, the NCO content (NCO%) was 14.9%, and the Hazen color number (APHA) of the obtained polyisocyanate was 90. Moreover, the hexamethylene diisocyanate remaining in the obtained polyisocyanate composition was 1.5% by mass.
- Example C1 except that the content of hexamethylene diisocyanate in the polyisocyanate composition and the content of the compound represented by formula (16-1) and formula (16-2) were changed as shown in Table 18. Steps (1-1) and (1-2) were carried out in the same manner as above to obtain a polyisocyanate composition.
- the time required from the start of the urethanization reaction to the completion of the reaction in step (1-1) was as shown in Table 18.
- Table 19 shows the NCO%, Hazen color number (APHA), and residual amount of hexamethylene diisocyanate of the polyisocyanate composition obtained in each example.
- Example C13 An isocyanate composition containing 98.1% by mass of hexamethylene diisocyanate, 400 mass ppm of the compounds represented by formulas (16-1) and (16-2), and 1100 mass ppm of ⁇ -methylstyrene was prepared. Except having used the prepared polyisocyanate composition, it carried out similarly to Example C1, and performed the process (1-1) and the process (1-2), and obtained the polyisocyanate composition. In step (1-1), the time required from the start of the urethanization reaction to the completion of the reaction was 0.5 hour. The obtained polyisocyanate composition had NCO%, Hazen color number (APHA), and hexamethylene diisocyanate residual amount as shown in Table 19.
- APHA Hazen color number
- Example C14 Contains 98.1% by mass of hexamethylene diisocyanate, 420 ppm by mass of compounds represented by formulas (16-1) and (16-2), 930 ppm by weight of ⁇ -methylstyrene, and 620 ppm of benzyltoluene (isomer mixture)
- a polyisocyanate composition was prepared. Except having used the prepared isocyanate composition, it carried out similarly to Example C1, and performed the process (1-1) and the process (1-2), and obtained the polyisocyanate composition.
- step (1-1) the time required from the start of the urethanization reaction to the completion of the reaction was 0.5 hour.
- the obtained polyisocyanate composition had NCO%, Hazen color number (APHA), and hexamethylene diisocyanate residual amount as shown in Table 19.
- the time required for Step (1-1) was as shown in Table 18.
- Example C1 except that the content of hexamethylene diisocyanate in the polyisocyanate composition and the content of the compound represented by formula (5-1) and formula (5-2) were changed as shown in Table 18. Steps (1-1) and (1-2) were carried out in the same manner as above to obtain a polyisocyanate composition.
- the time required from the start of the urethanization reaction to the completion of the reaction in step (1-1) was as shown in Table 18.
- NCO%, Hazen color number (APHA), and hexamethylene diisocyanate residual amount of the polyisocyanate composition obtained in each comparative example were as shown in Table 19.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- 16-1, 16-2 is represented by Formula (16-1) or Formula (16-2).
- the total content (mass ppm) of the compound is shown
- ⁇ MS shows the content (mass ppm) of ⁇ -methylstyrene
- BT shows the content of benzyltoluene (mass ppm)
- Step (1 "-1) indicates the time (time) required from the start of the urethanization reaction to the completion of the reaction in the step (1-1).
- HMDI residual amount indicates the residual amount (mass%) of hexamethylene diisocyanate in the polyisocyanate composition.
- Example C15 Preparation of Polyisocyanate Composition Hexamethylene diisocyanate 98.2% by mass, a compound represented by the following formula (17-1) and the following formula (17-2) (a mixture of two kinds) of 3.0 mass ppm ( “Ppm by mass” indicates “ ⁇ 10 ⁇ 4 mass%”).
- Step (2-1) The inside of a four-necked flask equipped with a stirrer, a temperature system, a condenser tube and a probe for FT-IR (manufactured by METTLER TOLEDO, React-IR, AgX probe) was purged with nitrogen, and 1200 g of the prepared polyisocyanate composition, A polyester polyol “Placcel 305” (trade name of Daicel Chemical Industries) derived from a trihydric alcohol and ⁇ -caprolactone was added and heated at 130 ° C. with stirring. The reaction was carried out while confirming the amount of urethane groups produced by FT-IR, and the completion of the reaction was confirmed in about 1.6 hours.
- FT-IR manufactured by METTLER TOLEDO, React-IR, AgX probe
- Step (2-2) Subsequently, 0.5 g of a 20% octanol solution of zirconyl 2-ethylhexanoate was added to carry out an allophanatization reaction.
- a 2-ethyl-1-hexanol solution containing 10% solids of pyrophosphoric acid made by Taihei Chemical Industry, trade name “phosphoric acid (105%”
- the reaction was stopped by adding 4.0 g of a solution diluted with -ethyl-1-hexanol. After filtering the reaction solution, distillation was performed at 160 ° C.
- the obtained residue was a polyisocyanate composition, the yield was 280 g, the NCO content (NCO%) was 15.0%, and the Hazen color number (APHA) of the obtained polyisocyanate was 40. Moreover, the hexamethylene diisocyanate remaining in the obtained polyisocyanate composition was 1.4% by mass.
- Example C16 to C26 Except that the content of the hexamethylene diisocyanate in the polyisocyanate composition and the content of the compound represented by the formula (17-1) and the formula (17-2) were changed as shown in Table 20, Example C15 The steps (2-1) and (2-2) were carried out in the same manner as in to obtain a polyisocyanate composition.
- the time required from the start of the urethanization reaction to the completion of the reaction in step (2-1) was as shown in Table 20.
- Table 21 shows the NCO%, the Hazen color number (APHA), and the remaining amount of hexamethylene diisocyanate of the polyisocyanate composition obtained in each example.
- Example C27 An isocyanate containing 98.6% by mass of hexamethylene diisocyanate, 300 ppm by mass of the compounds represented by formulas (17-1) and (17-2), and 700 ppm by mass of 2,4,4-trimethylpentene-1.
- a composition was prepared. Except having used the prepared polyisocyanate composition, it carried out similarly to Example C15, and performed the process (2-1) and the process (2-2), and obtained the polyisocyanate composition. In Step (2-1), the time required from the start of the urethanization reaction to the completion of the reaction was 0.4 hour.
- the obtained polyisocyanate composition had NCO%, Hazen color number (APHA), and hexamethylene diisocyanate residual amount as shown in Table 21.
- Example C28 Hexamethylene diisocyanate 99.0 mass%, compounds represented by formulas (17-1) and (17-2) 220 mass ppm, 2,4,4-trimethylpentene-1 is 500 mass ppm, and n-pentadecane A polyisocyanate composition containing 100 ppm was prepared. Except having used the prepared isocyanate composition, it carried out similarly to Example C15, and performed the process (2-1) and the process (2-2), and obtained the polyisocyanate composition. In Step (2-1), the time required from the start of the urethanization reaction to the completion of the reaction was 0.5 hour. The obtained polyisocyanate composition had NCO%, Hazen color number (APHA), and hexamethylene diisocyanate residual amount as shown in Table 21. Further, in Example C28, the time required for the step (2-1) was as shown in Table 20.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- 17-1, 17-2 is represented by formula (17-1) or formula (17-2).
- TMP indicates the content (mass ppm) of 2,4,4-trimethylpentene-1
- PD indicates the content (mass ppm) of n-pentadecane.
- Step (2-1) indicates the time (time) required from the start of the urethanization reaction to the completion of the reaction in Step (2-1).
- HMDI residual amount indicates the residual amount (mass%) of hexamethylene diisocyanate in the polyisocyanate composition.
- Example C29 Preparation of polyisocyanate composition Hexamethylene diisocyanate 99.0% by mass, compound represented by the following formula (18-1) and the following formula (18-2) (mixture of two kinds) 100 mass ppm (“mass ppm” ”Indicates“ ⁇ 10 ⁇ 4 mass% ”.) was prepared.
- Step (3-1) The inside of a four-necked flask equipped with a stirrer, a temperature system, a condenser tube and a probe for FT-IR (manufactured by METTLER TOLEDO, React-IR, AgX probe) was purged with nitrogen, and 1200 g of the prepared polyisocyanate composition, A polyester polyol “Placcel 305” (trade name of Daicel Chemical Industries) derived from a trihydric alcohol and ⁇ -caprolactone was added and heated at 130 ° C. with stirring. The reaction was carried out while confirming the amount of urethane groups produced by FT-IR, and the completion of the reaction was confirmed in about 1.8 hours.
- FT-IR manufactured by METTLER TOLEDO, React-IR, AgX probe
- Step (3-2) Subsequently, 0.5 g of a 20% octanol solution of zirconyl 2-ethylhexanoate was added to carry out an allophanatization reaction.
- a 2-ethyl-1-hexanol solution containing 10% solids of pyrophosphoric acid made by Taihei Chemical Industry, trade name “phosphoric acid (105%)” (Diluted with ethyl-1-hexanol) was added to stop the reaction. After filtering the reaction solution, distillation was performed at 160 ° C.
- the obtained residue was a polyisocyanate composition, the yield was 280 g, the NCO content (NCO%) was 14.9%, and the Hazen color number (APHA) of the obtained polyisocyanate was 30. Moreover, the hexamethylene diisocyanate remaining in the obtained polyisocyanate composition was 1.4% by mass.
- Example C30 An isocyanate composition containing 98.3% by mass of hexamethylene diisocyanate, 100 mass ppm of the compounds represented by formulas (18-1) and (18-2), and 100 mass ppm of styrene was prepared. Steps (3-1) and (3-2) were carried out in the same manner as in Example C29 except that the prepared polyisocyanate composition was used to obtain a polyisocyanate composition. In Step (3-1), the time required from the start of the urethanization reaction to the completion of the reaction was 0.5 hour. The obtained polyisocyanate composition had NCO%, Hazen color number (APHA), and hexamethylene diisocyanate residual amount as shown in Table 22.
- APHA Hazen color number
- Example C31 Preparation of polyisocyanate composition containing 98.3% by mass of hexamethylene diisocyanate, 120 mass ppm of compounds represented by formula (18-1) and formula (18-2), 130 mass ppm of styrene, and 220 ppm of dibenzyl ether did. Steps (3-1) and (3-2) were performed in the same manner as in Example C29 except that the prepared isocyanate composition was used to obtain a polyisocyanate composition. In Step (3-1), the time required from the start of the urethanization reaction to the completion of the reaction was 0.5 hour. Table 23 shows NCO%, Hazen color number (APHA), and residual amount of hexamethylene diisocyanate of the obtained polyisocyanate composition. Further, in Example C31, the time required for the step (3-1) was as shown in Table 22.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- 18-1, 18-2 is represented by formula (18-1) or formula (18-2).
- the total content (mass ppm) of the compound is indicated
- ST indicates the content (mass ppm) of styrene
- DBE indicates the content (mass ppm) of dibenzyl ether
- step (3-1) ") Indicates the time (time) required from the start of the urethanization reaction to the completion of the reaction in the step (3-1).
- HMDI residual amount indicates the residual amount (mass%) of hexamethylene diisocyanate in the polyisocyanate composition.
- Example C32 Preparation of Polyisocyanate Composition 98.3% by mass of isophorone diisocyanate and 80 mass ppm of the compound represented by the following formula (19-1) (where “mass ppm” represents “ ⁇ 10 ⁇ 4 mass%”). ) Containing a polyisocyanate composition.
- Step (4-1) The inside of a four-necked flask equipped with a stirrer, a temperature system, a condenser tube and a probe for FT-IR (manufactured by METTLER TOLEDO, React-IR, AgX probe) was purged with nitrogen, and 1200 g of the prepared polyisocyanate composition, A polyester polyol “Placcel 305” (trade name of Daicel Chemical Industries) derived from a trihydric alcohol and ⁇ -caprolactone was added and heated at 130 ° C. with stirring. The reaction was carried out while confirming the amount of urethane groups produced by FT-IR, and the completion of the reaction was confirmed in about 1.7 hours.
- FT-IR manufactured by METTLER TOLEDO, React-IR, AgX probe
- Step (4-2) Subsequently, 0.5 g of a 20% octanol solution of zirconyl 2-ethylhexanoate was added to carry out an allophanatization reaction.
- a 2-ethyl-1-hexanol solution containing 10% solids of pyrophosphoric acid made by Taihei Chemical Industry, trade name “phosphoric acid (105%)” (Diluted with ethyl-1-hexanol) was added to stop the reaction. After filtering the reaction solution, distillation was performed at 180 ° C.
- the obtained residue was a polyisocyanate composition, the NCO content (NCO%) was 15.1%, and the Hazen color number (APHA) of the obtained polyisocyanate was 30. Further, the isophorone diisocyanate remaining in the obtained polyisocyanate composition was 1.5% by mass.
- Example C33 An isocyanate composition containing 98.3% by mass of isophorone diisocyanate, 80 mass ppm of the compound represented by the formula (19-1), and 300 mass ppm of nonene was prepared. Steps (4-1) and (4-2) were carried out in the same manner as in Example C32 except that the prepared polyisocyanate composition was used to obtain a polyisocyanate composition. In Step (4-1), the time required from the start of the urethanization reaction to the completion of the reaction was 0.5 hour. The obtained polyisocyanate composition had NCO%, Hazen color number (APHA), and residual amount of isophorone diisocyanate as shown in Table 25.
- APHA Hazen color number
- Example C34 A polyisocyanate composition containing 98.6% by mass of isophorone diisocyanate, 90 mass ppm of the compound represented by the formula (19-1), 130 mass ppm of nonene, and 120 ppm of decamethyltetrasiloxane was prepared. Steps (4-1) and (4-2) were carried out in the same manner as in Example C32 except that the prepared isocyanate composition was used to obtain a polyisocyanate composition. In Step (4-1), the time required from the start of the urethanization reaction to the completion of the reaction was 0.5 hour. The obtained polyisocyanate composition had NCO%, Hazen color number (APHA), and residual amount of isophorone diisocyanate as shown in Table 25. Further, in Example C36, the time required for the step (4-1) was as shown in Table 24.
- IPDI represents the content (mass%) of isophorone diisocyanate
- 19-1 represents the content (mass ppm) of the compound represented by formula (19-1)
- “NN” represents the content (mass ppm) of nonene
- “DMTS” represents the content (mass ppm) of decamethyltetrasiloxane
- step (4-1) is the same as in step (4-1). The time (hour) required from the start of the urethanization reaction to the completion of the reaction is shown.
- IPDI residual amount indicates the residual amount (% by mass) of hexamethylene diisocyanate in the polyisocyanate composition.
- Example C35 Preparation of Polyisocyanate Composition 98.3% by mass of isophorone diisocyanate and 50 ppm by mass of the compound represented by the following formula (20-1) (where “mass ppm” indicates “ ⁇ 10 ⁇ 4 mass%”). ) Containing a polyisocyanate composition.
- Step (5-1) The inside of a four-necked flask equipped with a stirrer, a temperature system, a condenser tube and a probe for FT-IR (manufactured by METTLER TOLEDO, React-IR, AgX probe) was purged with nitrogen, and 1200 g of the prepared polyisocyanate composition, A polyester polyol “Placcel 305” (trade name of Daicel Chemical Industries) derived from a trihydric alcohol and ⁇ -caprolactone was added and heated at 130 ° C. with stirring. The reaction was carried out while confirming the amount of urethane groups formed by FT-IR, and the completion of the reaction was confirmed between about 1.8.
- FT-IR manufactured by METTLER TOLEDO, React-IR, AgX probe
- Step (5-2) Subsequently, 0.5 g of a 20% octanol solution of zirconyl 2-ethylhexanoate was added to carry out an allophanatization reaction.
- a 2-ethyl-1-hexanol solution containing 10% solids of pyrophosphoric acid made by Taihei Chemical Industry, trade name “phosphoric acid (105%)” (Diluted with ethyl-1-hexanol) was added to stop the reaction. After filtering the reaction solution, distillation was performed at 160 ° C.
- the obtained residue was a polyisocyanate composition, the yield was 280 g, the NCO content (NCO%) was 14.9%, and the Hazen color number (APHA) of the obtained polyisocyanate was 30. Further, the isophorone diisocyanate remaining in the obtained polyisocyanate composition was 1.5% by mass.
- Example C36 An isocyanate composition containing 98.4% by mass of isophorone diisocyanate, 45% by mass of the compound represented by the formula (20-1), and 40% by mass of ⁇ -methylstyrene was prepared. Except having used the prepared polyisocyanate composition, it carried out similarly to Example C35, and performed the process (5-1) and the process (5-2), and obtained the polyisocyanate composition. In step (5-1), the time required from the start of the urethanization reaction to the completion of the reaction was 0.5 hour. The obtained polyisocyanate composition had NCO%, Hazen color number (APHA), and residual isophorone diisocyanate as shown in Table 27.
- APHA Hazen color number
- Example C37 A polyisocyanate composition containing 98.4% by mass of isophorone diisocyanate, 50 mass ppm of the compound represented by the formula (20-1), 50 mass ppm of ⁇ -methylstyrene, and 110 mass ppm of butylphenyl ether was prepared. Except having used the prepared isocyanate composition, it carried out similarly to Example C35, and performed the process (5-1) and the process (5-2), and obtained the polyisocyanate composition. In step (5-1), the time required from the start of the urethanization reaction to the completion of the reaction was 0.5 hour. The obtained polyisocyanate composition had NCO%, Hazen color number (APHA), and residual isophorone diisocyanate as shown in Table 26. In Example C37, the time required for Step (5-1) was as shown in Table 26.
- IPDI represents the content (mass%) of isophorone diisocyanate
- 20-1 represents the content (mass ppm) of the compound represented by the formula (20-1)
- ⁇ MS indicates the content (mass ppm) of ⁇ -methylstyrene
- BPE indicates the content (mass ppm) of butylphenyl ether
- Step (5-1) refers to Step (5-1). Shows the time (time) required from the start of the urethanization reaction to the completion of the reaction.
- IPDI residual amount indicates the residual amount (mass%) of isophorone diisocyanate in the polyisocyanate composition.
- Example D1 An isocyanate composition containing 98.5% by mass of hexamethylene diisocyanate and 22 ppm by mass of benzyltoluene (isomer mixture) (“mass ppm” indicates “ ⁇ 10 ⁇ 4 mass%”) was prepared.
- the obtained reaction liquid (unreacted diisocyanate monomer concentration: 65% by mass) was fed to a scraping-type thin film distiller at a vacuum degree of 655 Pa and a temperature of 160 ° C. at 500 g / hr.
- the obtained biuret-type polyisocyanate polymer composition having a diisocyanate monomer concentration of 5% by mass and a urea dimer concentration of 1.5% by mass was held in a nitrogen atmosphere at a liquid temperature of 140 ° C. for 30 minutes for urea dimer. The concentration was 0.2% by mass or less and the transmittance was 93%.
- This polyisocyanate composition is fed again to a scraping-type thin film distiller (vacuum degree 67 Pa, temperature 160 ° C.), diisocyanate monomer concentration 0.3 mass%, urea dimer concentration 0.2 mass% or less, Hazen color number A composition of (APHA) 35 biuret type polyisocyanate polymer was obtained.
- Example D2 to D8 A biuretization reaction was performed in the same manner as in Example D1, except that the hexamethylene diisocyanate content and the benzyltoluene content in the polyisocyanate composition were changed as shown in Table 28.
- Table 28 shows the Hazen color number (APHA) of the obtained polyisocyanate composition.
- Example D9 Hexamethylene diisocyanate 99.0% by mass, benzyltoluene (isomer mixture) 1300 ppm by mass, and a mixture of a compound represented by the following formula (21-1) and a compound represented by the following formula (21-2)
- a polyisocyanate composition containing 530 mass ppm (as two mixtures) was prepared. Using the prepared polyisocyanate composition, a biuretization reaction was performed in the same manner as in Example D1. Table 28 shows the Hazen color number (APHA) of the obtained polyisocyanate composition.
- Example D10 Hexamethylene diisocyanate 99.0% by mass, benzyltoluene (isomer mixture) 1200 mass ppm, ⁇ -methylstyrene 610 mass ppm, and a compound represented by formula (21-1) and formula (21-2)
- An isocyanate composition containing 380 ppm by weight (as a mixture of the two) was prepared.
- a biuretization reaction was performed in the same manner as in Example D1, using the prepared isocyanate composition.
- Table 28 shows the Hazen color number (APHA) of the obtained polyisocyanate composition.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- BT represents the content (mass ppm) of benzyltoluene
- 21-1, 21-2 represents the formula ( 21-1) represents the total content (mass ppm) of the compound represented by formula (21-2)
- ⁇ MS represents the ⁇ -methylstyrene content (mass ppm).
- Example D11 An isocyanate composition containing 98.1% by mass of hexamethylene diisocyanate and 25 ppm by mass of n-pentadecane (“mass ppm” indicates “ ⁇ 10 ⁇ 4 mass%”) was prepared.
- the obtained reaction liquid (unreacted diisocyanate monomer concentration: 65% by mass) was fed to a scraping-type thin film distiller at a vacuum degree of 655 Pa and a temperature of 160 ° C. at 500 g / hr.
- the obtained biuret-type polyisocyanate polymer composition having a diisocyanate monomer concentration of 5% by mass and a urea dimer concentration of 1.5% by mass was held in a nitrogen atmosphere at a liquid temperature of 140 ° C. for 30 minutes for urea dimer.
- the concentration was 0.2% by mass or less and the transmittance was 93%.
- This polyisocyanate composition is fed again to a scraping-type thin film distiller (vacuum degree 67 Pa, temperature 160 ° C.), diisocyanate monomer concentration 0.3 mass%, urea dimer concentration 0.2 mass% or less, Hazen color number A composition of (APHA) 30 biuret type polyisocyanate polymer was obtained.
- Example D12 to D18 A biuretization reaction was performed in the same manner as in Example D11 except that the hexamethylene diisocyanate content and the n-pentadecane content in the polyisocyanate composition were changed as shown in Table 29.
- Table 29 shows the Hazen color number (APHA) of the obtained polyisocyanate composition.
- Example D19 Hexamethylene diisocyanate 98.1% by mass, n-pentadecane 300 ppm by mass, and a mixture of the compound represented by the above formula (21-1) and the compound represented by the above formula (21-2) (two kinds of A polyisocyanate composition containing 210 ppm by weight (as a mixture) was prepared. A biuretization reaction was performed in the same manner as in Example D11 using the prepared polyisocyanate composition. Table 29 shows the Hazen color number (APHA) of the obtained polyisocyanate composition.
- APHA Hazen color number
- Example D20 Hexamethylene diisocyanate 98.4 mass%, n-pentadecane 300 mass ppm, 2,4,4-trimethylpentene-1 110 mass ppm, and the compound represented by formula (21-1) and formula (21-2)
- An isocyanate composition containing 200 mass ppm of a mixture (as a mixture of two kinds) with a compound represented by (1) was prepared.
- the biuretization reaction was performed like Example D11 using the prepared isocyanate composition.
- Table 29 shows the Hazen color number (APHA) of the obtained polyisocyanate composition.
- Example D3 to D4 A biuretization reaction was performed in the same manner as in Example D11 except that the hexamethylene diisocyanate content and the n-pentadecane content in the isocyanate composition were changed as shown in Table 29.
- Table 29 shows the Hazen color number (APHA) of the obtained polyisocyanate composition in each comparative example.
- Table 29 shows the composition of the isocyanate composition in Examples and Comparative Examples and the Hazen color number (APHA) of the obtained polyisocyanate composition.
- HMDI represents the content (mass%) of hexamethylene diisocyanate
- PD represents the content (mass ppm) of n-pentadecane
- 21-1, 21-2 represents the formula The total content (mass ppm) of the compound represented by (21-1) or formula (21-2) is shown
- TMP represents the content (mass ppm) of 2,4,4-trimethylpentene-1. Show.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
[1]ポリイソシアネート組成物の全質量を基準として、97重量%以上のポリイソシアネートと、2.0質量ppm以上1.0×104質量ppm以下の、前記ポリイソシアネートと異なる化合物であり少なくとも1つの不飽和結合を有する化合物、又は、5.0質量ppm以上2.0×104質量ppm以下の、炭化水素化合物、エーテル化合物、スルフィド化合物、ハロゲン化炭化水素化合物、含ケイ素炭化水素化合物、含ケイ素エーテル化合物及び含ケイ素スルフィド化合物からなる群より選ばれる少なくとも1種の不活性化合物と、を含有するポリイソシアネート組成物。
[2]前記ポリイソシアネートと、前記少なくとも1つの不飽和結合を有する化合物とを含有し、前記不飽和結合が、炭素-炭素間の二重結合、又は、炭素-酸素間の二重結合であり、前記炭素-炭素間の二重結合が、芳香環を構成する炭素-炭素間の二重結合ではない、[1]に記載の組成物。
[3]前記少なくとも1つの不飽和結合を有する化合物が、炭酸誘導体を含む、[2]に記載の組成物。
[4]前記炭酸誘導体が、炭酸ジメチル、炭酸ジエチル、炭酸ジブチル、炭酸ジペンチル及び炭酸ジヘキシルからなる群より選ばれる少なくとも1種の炭酸エステル又はN-無置換カルバミン酸エステルである、[3]に記載の組成物。
[5]前記少なくとも1つの不飽和結合を有する化合物が、下記式(1)で表される化合物を更に含む、[3]又は[4]に記載の組成物。
[6]前記炭化水素化合物、前記エーテル化合物、前記スルフィド化合物、前記ハロゲン化炭化水素化合物、前記含ケイ素炭化水素化合物、前記含ケイ素エーテル化合物及び前記含ケイ素スルフィド化合物からなる群より選ばれる少なくとも1種の不活性化合物を更に含有する、[5]に記載の組成物。
[7]前記ポリイソシアネートと、前記少なくとも1つの不飽和結合を有する化合物とを含有し、前記少なくとも1つの不飽和結合を有する化合物が、下記式(1)で表される化合物を含む、[1]に記載の組成物。
[8]前記炭化水素化合物、前記エーテル化合物、前記スルフィド化合物、前記ハロゲン化炭化水素化合物、前記含ケイ素炭化水素化合物、前記含ケイ素エーテル化合物及び前記含ケイ素スルフィド化合物からなる群より選ばれる少なくとも1種の不活性化合物を更に含有する、[7]に記載の組成物。
[9]前記ポリイソシアネートと、前記炭化水素化合物、前記エーテル化合物、前記スルフィド化合物、前記ハロゲン化炭化水素化合物、前記含ケイ素炭化水素化合物、前記含ケイ素エーテル化合物及び前記含ケイ素スルフィド化合物からなる群より選ばれる少なくとも1種の不活性化合物と、を含有する、[1]に記載の組成物。
[10]前記少なくとも1つの不飽和結合を有する化合物を更に含有し、前記不飽和結合が、炭素-炭素間の二重結合、又は、炭素-酸素間の二重結合であり、前記炭素-炭素間の二重結合が、芳香環を構成する炭素-炭素間の二重結合ではない、[9]に記載の組成物。
[11]前記少なくとも1つの不飽和結合を有する化合物が、炭酸誘導体を含む、[10]に記載の組成物。
[12]前記炭酸誘導体が、炭酸ジメチル、炭酸ジエチル、炭酸ジブチル、炭酸ジペンチル及び炭酸ジヘキシルからなる群より選ばれる少なくとも1種の炭酸エステル又はN-無置換カルバミン酸エステルである、[11]に記載の組成物。
[13]前記式(1)で表される化合物が、下記式(1-3)又は(1-4)で表される化合物である、[5]又は[7]に記載の組成物。
[14]前記R1が、ヘキサメチレン基である、[13]に記載の組成物。
[15]前記不活性化合物が、ベンジルトルエン、ジベンジルエーテル及びヘキサデカンからなる群より選ばれる少なくとも1種の化合物である、[6]、[8]又は[9]に記載の組成物。
[16]前記少なくとも1つの不飽和結合を有する化合物が、スチレン、α-メチルスチレン、ペンテン及びオクテンからなる群より選ばれる少なくとも1種の化合物である[2]又は[10]に記載の組成物。
[17]ポリイソシアネートの蒸留精製における着色を防止する方法であって、前記蒸留精製の前に、前記ポリイソシアネートに、該ポリイソシアネートと異なる化合物であり少なくとも1つの不飽和結合を有する化合物を、前記ポリイソシアネートの全量基準で2.0質量ppm以上1.0×104質量ppm以下添加する工程を備える、方法。
[18][17]に記載の方法によって蒸留精製されたポリイソシアネートを含む、ポリイソシアネート組成物。
[19][1]~[16]及び[18]のいずれかに記載の組成物に含有されるポリイソシアネートを反応させるイソシアネート重合体の製造方法であって、前記組成物に含有されるポリイソシアネートがジイソシアネートであり、前記イソシアネート重合体が、下記式(2)で表される単位と、下記式(3)、(4)、(5)、(6)、(7)、(8)及び(9)でそれぞれ表される単位からなる群より選ばれる少なくとも1種の単位と、を有し、前記イソシアネート重合体を構成する窒素原子が、炭素原子と結合している、方法。
[20][19]に記載の方法によって製造される、イソシアネート重合体を含む組成物。
本実施形態に係るポリイソシアネートとしては、イソシアネート基を2以上有する化合物であれば、特に限定されないが、下記式(10)で表される化合物が好ましく使用される。
1)R1基が、脂肪族基及び/又は芳香族基で置換されていてもよい芳香環を1以上含有する炭素原子数6~85の基であり、R1基中の芳香族基をイソシアネート基が置換し、cが2~5の整数である芳香族ポリイソシアネート、
2)R1基が、芳香族基で置換されていてもよい、炭素原子数1~85の脂肪族基であり、cが2又は3の脂肪族ポリイソシアネートである。
1)芳香族ポリイソシアネート
R1基が、脂肪族及び/又は芳香族置換されていてもよい芳香環を1以上含有する炭素原子数6~85の基であり、R1基中の芳香族基の1つ以上の水素原子がイソシアネート基で置換され、aが2である芳香族ポリイソシアネートである。好ましくは、R1基が炭素原子数6~70の基であり、cが2~5の整数である芳香族ポリイソシアネートであり、流動性等を考慮して、更に好ましくはR1基が、1つ以上の“イソシアネート基で置換された”芳香環を含有する炭素原子数6~13の基であり、cが2~5の整数である芳香族ポリイソシアネートであり、上記芳香環は更にアルキル基、アリール基、アラルキル基で置換されていてもよい。
式(10)で表されるポリイソシアネートは、R1基が、炭素原子数1~85の脂肪族基であり、cが2又は3の脂肪族ポリイソシアネートである。上記脂肪族基は更に芳香族基で置換されていてもよい。更に好ましいポリイソシアネートは、上記脂肪族基が、鎖状炭化水素基、環状炭化水素基、及び、鎖状炭化水素基と環状炭化水素基とから構成される基である脂肪族ポリイソシアネートである。より好ましくはR1基が脂肪族基であって、炭素原子数1~70の非環式炭化水素基及び環式炭化水素基、並びに、非環式炭化水素基と環式炭化水素基とから構成される基であり、cが2又は3の脂肪族ポリイソシアネートである。工業的に大量に製造する際の流動性等の観点から、最も好ましくはR1基が、炭素原子数6~13の非環式炭化水素基及び環式炭化水素基、並びに、非環式炭化水素基と環式炭化水素基とから構成される基である脂肪族ポリイソシアネートである。すなわち、R1基が、直鎖及び/又は分岐鎖状のアルキル基、シクロアルキル基、並びに、直鎖及び/又は分岐鎖状のアルキル基と上記シクロアルキル基とから構成される基である。
本実施形態のポリイソシアネート組成物は、ポリイソシアネートと共に、ポリイソシアネート以外の少なくとも1つの不飽和結合を有する化合物、及び/又は後述する化合物A~化合物Eからなる群から選ばれる少なくとも1種の化合物と、を含有する。
不飽和結合化合物が炭酸誘導体である場合について説明する。本実施形態に係る炭酸誘導体とは、下記式(22)で表される化合物を指す。
炭酸エステルとは、炭酸CO(OH)2のうち、1又は2個の水素原子を、脂肪族基又は芳香族基で置換した化合物を指す。本実施形態においては、下記式(25)で表される化合物が好ましく使用される。
本実施形態に係る不飽和結合化合物として、下記式(1)で表される化合物が挙げられる。
(i)水素原子、
(ii)ハロゲン原子、
(iii)構成する炭素原子数が1~44の炭素官能基であり、α位の炭素原子に、各々独立に、炭素原子数1~43の鎖状アルキル基、炭素原子数1~43のシクロアルキル基、炭素原子数1~43のアルコキシ基、炭素原子数2~43であって末端にヒドロキシ基を有しないポリオキシアルキレンアルキルエーテル基、炭素原子数6~43のアリール基、炭素原子数7~43のアラルキル基及び炭素原子数7~43のアラルキルオキシ基から選ばれる基、
(iv)炭素原子数1~44の芳香族基であり、上記芳香族基が水素原子、炭素原子数1~38の鎖状アルキル基、炭素原子数4~38のシクロアルキル基、炭素原子数1~38のアルコキシ基、炭素原子数2~38であって末端にヒドロキシ基を有しないポリオキシアルキレンアルキルエーテル基、炭素原子数6~38の芳香族基、炭素原子数7~38のアラルキル基、炭素原子数7~38のアラルキルオキシ基、及び1種以上の前記した基が結合した基から選ばれる基、
(v)炭素原子数1~44の酸素官能基であり、炭素原子数1~44のアルキル基、炭素原子数1~44のシクロアルキル基、炭素原子数1~44のアルコキシ基、炭素原子数2~44であって末端にヒドロキシ基を有しないポリオキシアルキレンアルキルエーテル基、炭素原子数6~44の芳香族基、炭素原子数7~44のアラルキル基、炭素原子数7~44のアラルキルオキシ基、1種以上の前記した基が結合した基。
本実施形態における炭素-炭素間の不飽和結合を有する化合物として、下記式(21)で表される化合物が挙げられる。
本実施形態の組成物は、炭化水素化合物、エーテル化合物、スルフィド化合物、ハロゲン化炭化水素化合物、含ケイ素炭化水素化合物、含ケイ素エーテル化合物及び含ケイ素スルフィド化合物からなる群より選ばれる少なくとも1種の化合物(以下、「不活性化合物」ともいう。)を含有してもよい。不活性化合物は、下記化合物A~化合物Gに分類される。
化合物B:脂肪族炭化水素基で置換されていてもよい芳香族炭化水素化合物。
化合物C:エーテル結合又はスルフィド結合と、脂肪族炭化水素基とを有する化合物であり、同種又は異種の脂肪族炭化水素化合物が、エーテル結合又はスルフィド結合を介して結合した化合物。
化合物D:エーテル結合又はスルフィド結合と、芳香族炭化水素基とを有する化合物であり、同種又は異種の芳香族炭化水素化合物が、エーテル結合又はスルフィド結合を介して結合した化合物。
化合物E:エーテル結合又はスルフィド結合と、脂肪族炭化水素基と、芳香族炭化水素基とを有する化合物。
化合物F:脂肪族炭化水素化合物を構成する少なくとも1つの水素原子、又は、芳香族炭化水素化合物を構成する少なくとも1つの水素原子がハロゲン原子に置換されたハロゲン化物。
化合物G:上記化合物A~化合物Eの炭素原子の一部又は全部がケイ素原子に置換された化合物。
本実施形態に係る精製されたポリイソシアネートの製造方法は、上述のポリイソシアネート組成物からポリイソシアネートを蒸留精製して、精製されたポリイソシアネートを得る工程を備える。
本実施形態のポリイソシアネート組成物は、イソシアネート基を有するポリイソシアネートと、α-メチルスチレンとを含有する。ポリイソシアネート組成物において、ポリイソシアネートの含有量はポリイソシアネート組成物の全質量基準で97質量%以上であり、α-メチルスチレンの含有量はポリイソシアネート組成物の全質量基準で2.0質量ppm以上1.0×104質量ppm(0.0002質量%以上1質量%以下)である。
本実施形態に係る精製されたポリイソシアネート(以下、場合により「ポリイソシアネート精製物」という。)の製造方法は、上述のポリイソシアネート組成物からポリイソシアネートを蒸留分離して、ポリイソシアネート精製物を得る工程を備える。
本実施形態のポリイソシアネート組成物は、その全質量基準で、97質量%以上のポリイソシアネートと、2.0質量ppm以上1.0×104質量ppm以下の下記式(1)で表される化合物とを含有する。
本実施形態では、ポリイソシアネートとポリオール化合物とのウレタン化反応(縮合重合反応)によってウレタン化合物が得られ、次いで、ポリイソシアネートとウレタン化合物とのアロファネート化反応(ウレタン結合にイソシアネートが付加する反応)によって、アロファネート化合物が得られる。
イソシアネート基数の平均値(fn)=(イソシアネート重合体の数平均分子量×イソシアネート基の質量%×0.01)/42
本実施形態に係るポリイソシアネート組成物は、式(1)で表されるイソシアネート化合物と、ヒドロキシ基を2つ以上有するポリオール化合物との反応によって得られるものであり、少なくとも1つのアロファネート基及び2つ以上のイソシアネート基を有するアロファネート化合物を含有する。
(ポリイソシアネート組成物のfn)=(数平均分子量)×NCO%/4200
1H-NMRの測定方法例:
ポリイソシアネート組成物を重水素クロロホルムに10質量%の濃度で溶解し、ポリイソシアネート組成物に対して0.03質量%のテトラメチルシランを添加する。化学シフトの基準をテトラメチルシランの水素原子のシグナルとし、該シグナルを0ppmとして定義する。1H-NMR測定をおこない、8.5ppm付近の、アロファネート基の窒素原子に結合した水素原子(アロファネート基1molに対して、1molの水素原子)のシグナルの面積と、テトラメチルシランの水素原子のシグナルの面積との比から、アロファネート基を定量することができる。また、イソシアヌレート基は、3.85ppm付近の、イソシアヌレート基に隣接したメチレン基の水素原子(イソシアヌレート基1molに対して、6molの水素原子)のシグナルの面積と、テトラメチルシランの水素原子のシグナルの面積との比から定量することができる。また、ウレタン基は、4~5ppm付近のウレタン基の窒素に結合した水素原子(ウレタン基1molに対して、1molの水素原子)のシグナルの面積と、テトラメチルシランの水素原子のシグナルの面積との比から定量することができる。
本実施形態に係るポリイソシアネート組成物の製造方法は、イソシアネート化合物とポリオール化合物との反応によって得られる。より具体的には、イソシアネート化合物とポリオール化合物との縮合重合物であるウレタン化合物のウレタン結合に、イソシアネート化合物を付加させて得ることができる。
本実施形態のポリイソシアネート組成物によれば、上記式(1)で表される化合物を含むことにより、ポリイソシアネートとビウレット化剤との反応によるイソシアネート重合体の生成において、イソシアネート重合体を効率良く得ることができるという効果を奏する。
また、プロピレングリコール系溶剤としては、プロピレングリコールモノメチルエーテルアセテート、プロピレングリコールモノエチルエーテルアセテート、プロピレングリコールモノ-n-プロピルエーテルアセテート、プロピレングリコールモノイソプロピルエーテルアセテート、プロピレングリコールモノ-n-ブチルエーテルアセテート、プロピレングリコールジアセテート、プロピレングリコールジメチルエーテル、プロピレングリコールジエチルエーテル、プロピレングリコールジ-n-プロピルエーテル、プロピレングリコールジイソプロピルエーテル、プロピレングリコールジ-n-ブチルエーテル、プロピレングリコールメチルエチルエーテル、プロピレングリコールメチルイソプロピルエーテル、プロピレングリコールメチル-n-ブチルエーテル、プロピレングリコールエチル-n-プロピルエーテル、プロピレングリコールエチルイソプロピルエーテル、プロピレングリコールエチル-n-ブチルエーテル、プロピレングリコール-n-プロピル-n-ブチルエーテル、プロピレングリコールイソプロピル-n-ブチルエーテル、ジプロピレングリコールモノメチルエーテルアセテート、ジプロピレングリコールモノエチルエーテルアセテート、ジプロピレングリコールモノ-n-プロピルエーテルアセテート、ジプロピレングリコールモノイソプロピルエーテルアセテート、ジプロピレングリコールモノ-n-ブチルエーテルアセテート、ジプロピレングリコールジアセテート、ジプロピレングリコールジメチルエーテル、ジプロピレングリコールジエチルエーテル、ジプロピレングリコールジ-n-プロピルエーテル、ジプロピレングリコールジイソプロピルエーテル、ジプロピレングリコールジ-n-ブチルエーテル、ジプロピレングリコールメチルエチルエーテル、ジプロピレングリコールメチルイソプロピルエーテル、ジプロピレングリコールメチル-n-プロピルエーテル、ジプロピレングリコールメチル-n-ブチルエーテル、ジプロピレングリコールエチルイソプロピルエーテル、ジプロピレングリコールエチル-n-プロピルエーテル、ジプロピレングリコールエチル-n-ブチルエーテル、ジプロピレングリコール-n-プロピル-n-ブチルエーテル、ジプロピレングリコールイソプロピル-n-ブチルエーテル等が挙げられる。
本実施形態のポリイソシアネート組成物は、その全質量基準で、97質量%以上のポリイソシアネートと、20質量ppm以上2.0×104質量ppm以下の不活性化合物(化合物A~化合物Gからなる群から選ばれる少なくとも1種の化合物)とを含有する。
イソシアヌレート化反応は、好ましくはイソシアヌレート化触媒の存在下で行う。
(i)テトラアルキルアンモニウム(テトラメチルアンモニウム、テトラエチルアンモニウム等)のヒドロキシド又は有機酸塩(例えば、酢酸塩、酪酸塩、デカン酸塩等の塩)、
(ii)トリアルキルヒドロキシアルキルアンモニウム(トリメチルヒドロキシプロピルアンモニウム、トリメチルヒドロキシエチルアンモニウム、トリエチルヒドロキシプロピルアンモニウム、トリエチルヒドロキシエチルアンモニウム等)のヒドロキシド又は有機酸塩(例えば、酢酸塩、酪酸塩、デカン酸塩等の塩)、
(iii)酢酸、カプリン酸、オクチル酸、ミリスチン酸等のアルキルカルボン酸の金属塩(例えば、スズ塩、亜鉛塩、鉛塩、ナトリウム塩、カリウム塩等)、
(iv)ナトリウム、カリウム等の金属アルコキシド、
(v)アミノシリル基含有化合物(例えば、ヘキサメチルジジラサン等)。
(vi)トリブチルホスフィン等の燐系化合物。
(vii)フッ素化合物又はポリフッ化水素化合物(例えば、テトラメチルアンモニウムフルオリド水和物、テトラエチルアンモニウムフルオリド等のテトラアルキルアンモニウムフルオリド等)
(viii)下記式(28)又は式(29)で表される構造を含む化合物(例えば、3,3,3-トリフルオロプロパン酸;3,3,4,4,4-ペンタフルオロブタン酸;3,3,4,4,5,5,5-ヘプタフルオロペンタン酸;3,3-ジフルオロプロパ-2-エン酸等)と、第4級アンモニウムイオン又は第4級ホスホニウムイオンとからなる化合物。
R19=CR’-C(=O)O- (28)
R20-CR’2-C(=O)O- (29)
(式中、R19及びR20は、各々独立に、炭素原子数1~30のパーフルオロアルキル基を示し、R’は、各々独立に、水素原子、炭素原子数1~20のアルキル基、及び芳香族基からなる群から選ばれる1種を示し、これらはヘテロ原子を含有してもよい。)
本実施形態のポリイソシアネート組成物は、ポリイソシアネートを重合して得られるイソシアネート重合体の製造に好適である。イソシアネート重合体は、ポリイソシアネートがジイソシアネートの場合、下記式(2)で表される単位を有し、下記式(3)~(9)で表される単位のうち少なくとも1つ以上の単位を有する。なお、イソシアネート重合体を構成する窒素原子は炭素原子と結合している。
本実施形態に係るイソシアヌレート化合物の製造方法は、イソシアネート基を有するイソシアネート化合物のイソシアヌレート化反応によって、イソシアヌレート構造を有するイソシアヌレート化合物を得る工程を備え、イソシアヌレート化反応を、イソシアネート化合物100質量部に対して2.0×10-3質量部以上2.0質量部以下のベンジルトルエンを添加した反応系中で行うことを特徴とする。
上記で記載した方法により得られた各種イソシアネート重合体を含む組成物を使用して、イソシアネート重合体のイソシアネート基の一部又は全てをブロック剤で封鎖し、ブロックイソシアネート重合体を製造することもできる。ここで用いることのできるブロック剤として、次に挙げるものを例示することができる。
(i)アルコール類:メチルアルコール、エチルアルコール、2-プロピルアルコール、n-ブチルアルコール、sec-ブチルアルコール、2-エチル-1-ヘキシルアルコール、2-メトキシエチルアルコール、2-エトキシエチルアルコール、2-ブトキシエチルアルコール等
(ii)アルキルフェノール類:炭素原子数4以上のアルキル基を置換基として有するモノ及びジアルキルフェノール類であって、例えばn-プロピルフェノール、イソプロピルフェノール、n-ブチルフェノール、sec-ブチルフェノール、t-ブチルフェノール、n-ヘキシルフェノール、2-エチルヘキシルフェノール、n-オクチルフェノール、n-ノニルフェノール等のモノアルキルフェノール類、ジ-n-プロピルフェノール、ジイソプロピルフェノール、イソプロピルクレゾール、ジ-n-ブチルフェノール、ジ-t-ブチルフェノール、ジ-sec-ブチルフェノール、ジ-n-オクチルフェノール、ジ-2-エチルヘキシルフェノール、ジ-n-ノニルフェノール等のジアルキルフェノール類
(iii)フェノール類:フェノール、クレゾール、エチルフェノール、スチレン化フェノール、ヒドロキシ安息香酸エステル等
(iv)活性メチレン類:マロン酸ジメチル、マロン酸ジエチル、アセト酢酸メチル、アセト酢酸エチル、アセチルアセトン等
(v)メルカプタン類:ブチルメルカプタン、ドデシルメルカプタン等
(vi)酸アミド類:アセトアニリド、酢酸アミド、ε-カプロラクタム、δ-バレロラクタム、γ-ブチロラクタム等
(vii)酸イミド類:コハク酸イミド、マレイン酸イミド等
(viii)イミダゾール類:イミダゾール、2-メチルイミダゾール等
(ix)尿素類:尿素、チオ尿素、エチレン尿素等
(x)オキシム類:ホルムアルドオキシム、アセトアルドオキシム、アセトオキシム、メチルエチルケトオキシム、シクロヘキサノンオキシム等
(xi)アミン類:ジフェニルアミン、アニリン、カルバゾール、ジーn-プロピルアミン、ジイソプロピルアミン、イソプロピルエチルアミン等
(xii)イミン類:エチレンイミン、ポリエチレンイミン等
(xiii)ピラゾール類:ピラゾール、3-メチルピラゾール、3,5-ジメチルピラゾール等がある。
活性水素含有親水性化合物は、ノニオン系親水性化合物、アニオン系親水性化合物、カチオン系親水性化合物から選ばれる。これらの中でも、製造容易性から、ノニオン系親水性化合物、アニオン系親水性化合物が好ましく、更に好ましくは、ノニオン系親水性化合物である。これらの親水性化合物は、単独で用いてもよいし、2種以上を併用して用いてもよい。
活性水素含有親水性化合物として用いられるこれらのポリエチレン系グリコール化合物の中でも、数平均分子量200~2000の片末端に炭素原子数1~4のモノアルコールが付加したポリエチレングリコール系化合物が特に好ましい。
NCO含有率(NCO%)は、測定試料中のイソシアネート基を過剰の2Nアミンで中和した後、1N塩酸による逆滴定によって質量%として求めた。
測定試料の数平均分子量は、ゲルパーミエーションクロマトグラフィー(GPC)によって測定した。GPCの測定方法は以下の通りであった。
使用機器:HLC-8120(東ソー社製)、
使用カラム:TSK GEL SuperH1000、TSK GEL SuperH2000、TSK GEL SuperH3000(いずれも東ソー社製)、
試料濃度:5wt/vol%(試料50mgを1mLのテトラヒドロフラン(THF)に溶解させた)、
キャリア:THF、
検出方法:視差屈折計、
流出量:0.6mL/分、
カラム温度:30℃
検量線の作成には、分子量1000~20000のポリスチレンと、1,6-ジイソシアナトヘキサンのイソシアヌレート体(3量体、5量体、7量体)を用いた。
まず、20mLサンプル瓶をデジタル天秤に乗せ、試料を1g精秤し加えた。次に、ニトロベンゼン(内部標準液)を0.03~0.04g精秤し、サンプル瓶に加えた。最後に、酢酸エチル9mLをサンプル瓶に加えて、蓋を閉めた。そして、しっかり撹拌させて測定試料とした。測定試料を、以下の条件でガスクロマトグラフィー分析を行い、ジイソシアネートモノマー量を定量した。
装置:SHIMADZU社製、「GC-8A」
カラム:信和化工社製、「Silicone OV-17」
カラムオーブン温度:120℃
インジェクション/ディテクター温度:160℃
<ハーゼン色数>
ハーゼン色数は、ハーゼンメーターにて測定して得られた数値を記載した。
ヘキサメチレンジイソシアネート98.7質量%、α-メチルスチレン2.1質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を、連続多段蒸留塔(高さ3000mm、内径50mm、充填材としてディクソンパッキンを使用)に供給した。蒸留塔の塔頂部での圧力は1kPa(絶対圧)とし、蒸留に必要な熱量はリボイラーより供給した。塔内の温度分布が安定したのち、頭頂部より高さ方向で600mm下に具備するサイドカットラインより留分を抜き出した。得られた留分をガスクロマトグラフィーで分析したところ、ヘキサメチレンジイソシアネートの含有量は99.9質量%であり、十分に精製されたヘキサメチレンジイソシアネートが得られたことが確認された。また、得られた留分のハーゼン色数(APHA、ハーゼンメーターにて測定)は26であった。なお、塔底部からは、ヘキサメチレンジイソシアネート、ヘキサメチレンジイソシアネートの多量体(イソシアヌレート環構造を有する化合物)を含む混合液が回収され、該混合液の流動性は良好であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びα-メチルスチレン含有量を表1に記載のとおり変更したこと以外は、実施例A1と同様にして、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、表1に記載のとおりであった。
ヘキサメチレンジイソシアネート98.1質量%、α-メチルスチレン250質量ppm、及び、下記式(5-1)又は式(5-2)で表される化合物350質量ppmを含有するポリイソシアネート組成物を調製した。
ヘキサメチレンジイソシアネート98.5質量%、α-メチルスチレン150質量ppm、式(5-1)又は式(5-2)で表される化合物500質量ppm、及び、ベンジルトルエン1300質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A1と同様の方法により蒸留精製を行い、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、5であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びα-メチルスチレン含有量を表1に記載のとおり変更したこと以外は、実施例A1と同様にして、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、表1に記載のとおりであった。
ヘキサメチレンジイソシアネート98.3質量%、2,4,4-トリメチルペンテン-1を2.8質量ppm含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を、連続多段蒸留塔(高さ3000mm、内径50mm、充填材としてディクソンパッキンを使用)に供給した。蒸留塔の塔頂部での圧力は1kPa(絶対圧)とし、蒸留に必要な熱量はリボイラーより供給した。塔内の温度分布が安定したのち、頭頂部より高さ方向で600mm下に具備するサイドカットラインより留分を抜き出した。得られた留分をガスクロマトグラフィーで分析したところ、ヘキサメチレンジイソシアネートの含有量は99.9質量%であり、十分に精製されたヘキサメチレンジイソシアネートが得られたことが確認された。また、得られた留分のハーゼン色数(APHA)は15であった。なお、塔底部からは、ヘキサメチレンジイソシアネート、ヘキサメチレンジイソシアネートの多量体(イソシアヌレート環構造を有する化合物)を含む混合液が回収され、該混合液の流動性は良好であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及び2,4,4-トリメチルペンテン-1の含有量を表2に記載のとおり変更したこと以外は、実施例A1と同様にして、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、表2に記載のとおりであった。
ヘキサメチレンジイソシアネート98.3質量%、2,4,4-トリメチルペンテン-1を220質量ppm、及び、上記式(5-1)又は式(5-2)で表される化合物320質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A1と同様の方法により蒸留精製を行い、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、4であった。
ヘキサメチレンジイソシアネート98.5質量%、2,4,4-トリメチルペンテン-1を150質量ppm、式(5-1)又は式(5-2)で表される化合物600質量ppm、及び、n-ヘキサデカン1200質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A1と同様の方法により蒸留精製を行い、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、3であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及び2,4,4-トリメチルペンテン-1の含有量を表2に記載のとおり変更したこと以外は、実施例A14と同様にして、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、表2に記載のとおりであった。
ヘキサメチレンジイソシアネート98.3質量%、2-メチルブテン2.2質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を、連続多段蒸留塔(高さ3000mm、内径50mm、充填材としてディクソンパッキンを使用)に供給した。蒸留塔の塔頂部での圧力は1kPa(絶対圧)とし、蒸留に必要な熱量はリボイラーより供給した。塔内の温度分布が安定したのち、頭頂部より高さ方向で600mm下に具備するサイドカットラインより留分を抜き出した。得られた留分をガスクロマトグラフィーで分析したところ、ヘキサメチレンジイソシアネートの含有量は99.9質量%であり、十分に精製されたヘキサメチレンジイソシアネートが得られたことが確認された。また、得られた留分のハーゼン色数(APHA、ハーゼンメーターにて測定)は15であった。なお、塔底部からは、ヘキサメチレンジイソシアネート、ヘキサメチレンジイソシアネートの多量体(イソシアヌレート環構造を有する化合物)を含む混合液が回収され、該混合液の流動性は良好であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及び2-メチルブテン含有量を表3に記載のとおり変更したこと以外は、実施例A1と同様にして、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、表3に記載のとおりであった。
ヘキサメチレンジイソシアネート98.3質量%、2-メチルブテン220質量ppm、及び、下記式(6-1)又は式(6-2)で表される化合物310質量ppmを含有するポリイソシアネート組成物を調製した。
ヘキサメチレンジイソシアネート98.6質量%、2-メチルブテン130質量ppm、式(6-1)又は式(6-2)で表される化合物640質量ppm、及び、n-ペンタデカン1100質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A27と同様の方法により蒸留精製を行い、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、2であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びα-メチルスチレン含有量を表3に記載のとおり変更したこと以外は、実施例A1と同様にして、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、表3に記載のとおりであった。
イソホロンジイソシアネート98.2質量%、スチレン8質量ppm含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を、連続多段蒸留塔(高さ3000mm、内径50mm、充填材としてディクソンパッキンを使用)に供給した。蒸留塔の塔頂部での圧力は1kPa(絶対圧)とし、蒸留に必要な熱量はリボイラーより供給した。塔内の温度分布が安定したのち、頭頂部より高さ方向で600mm下に具備するサイドカットラインより留分を抜き出した。得られた留分をガスクロマトグラフィーで分析したところ、イソホロンジイソシアネートの含有量は99.9質量%であり、十分に精製されたイソホロンジイソシアネートが得られたことが確認された。また、得られた留分のハーゼン色数(APHA、ハーゼンメーターにて測定)は7であった。なお、塔底部からは、イソホロンジイソシアネート、イソホロンジイソシアネートの多量体(イソシアヌレート環構造を有する化合物)を含む混合液が回収され、該混合液の流動性は良好であった。
イソホロンジイソシアネート99.7質量%、スチレン20質量ppm、及び、下記式(7-1)で表される化合物80質量ppmを含有するポリイソシアネート組成物を調製した。
イソホロンジイソシアネート98.3質量%、スチレン11質量ppm、式(7-1)で表される化合物100質量ppm、及び、デシルエーテル1500質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A40と同様の方法により蒸留精製を行い、イソホロンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、3であった。
イソホロンジイソシアネート98.9質量%、ノネンを14質量ppm含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を、連続多段蒸留塔(高さ3000mm、内径50mm、充填材としてディクソンパッキンを使用)に供給した。蒸留塔の塔頂部での圧力は1kPa(絶対圧)とし、蒸留に必要な熱量はリボイラーより供給した。塔内の温度分布が安定したのち、頭頂部より高さ方向で600mm下に具備するサイドカットラインより留分を抜き出した。得られた留分をガスクロマトグラフィーで分析したところ、イソホロンジイソシアネートの含有量は99.9質量%であり、十分に精製されたイソホロンジイソシアネートが得られたことが確認された。また、得られた留分のハーゼン色数(APHA、ハーゼンメーターにて測定)は5であった。なお、塔底部からは、イソホロンジイソシアネート、イソホロンジイソシアネートの多量体(イソシアヌレート環構造を有する化合物)を含む混合液が回収され、該混合液の流動性は良好であった。
イソホロンジイソシアネート98.0質量%、ノネン33質量ppm、及び、下記式(8-1)で表される化合物90質量ppmを含有するポリイソシアネート組成物を調製した。
イソホロンジイソシアネート97.7質量%、ノネン12質量ppm、式(8-1)で表される化合物40質量ppm、及び、ジベンジルエーテル350質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A43と同様の方法により蒸留精製を行い、イソホロンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、2であった。
ヘキサメチレンジイソシアネート98.5質量%、n-オクテンを8質量ppm含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を、連続多段蒸留塔(高さ3000mm、内径50mm、充填材としてディクソンパッキンを使用)に供給した。蒸留塔の塔頂部での圧力は1kPa(絶対圧)とし、蒸留に必要な熱量はリボイラーより供給した。塔内の温度分布が安定したのち、頭頂部より高さ方向で600mm下に具備するサイドカットラインより留分を抜き出した。得られた留分をガスクロマトグラフィーで分析したところ、ヘキサメチレンジイソシアネートの含有量は99.9質量%であり、十分に精製されたヘキサメチレンジイソシアネートが得られたことが確認された。また、得られた留分のハーゼン色数(APHA、ハーゼンメーターにて測定)は5であった。なお、塔底部からは、ヘキサメチレンジイソシアネート、ヘキサメチレンジイソシアネートの多量体(イソシアヌレート環構造を有する化合物)を含む混合液が回収され、該混合液の流動性は良好であった。
ヘキサメチレンジイソシアネート98.1質量%、n-オクテン20質量ppm、及び、上記式(5-1)又は式(5-2)で表される化合物40質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A46と同様の方法により蒸留精製を行い、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、3であった。
ヘキサメチレンジイソシアネート98.1質量%、n-オクテン11質量ppm、式(5-1)又は式(5-2)で表される化合物20質量ppm、及び、ブチルフェニルエーテル100質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A46と同様の方法により蒸留精製を行い、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、2であった。
ジシクロヘキシルメタンジイソシアネート98.5質量%、α-メチルスチレンを8質量ppm含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を、連続多段蒸留塔(高さ3000mm、内径50mm、充填材としてディクソンパッキンを使用)に供給した。蒸留塔の塔頂部での圧力は1kPa(絶対圧)とし、蒸留に必要な熱量はリボイラーより供給した。塔内の温度分布が安定したのち、頭頂部より高さ方向で600mm下に具備するサイドカットラインより留分を抜き出した。得られた留分をガスクロマトグラフィーで分析したところ、ジシクロヘキシルメタンジイソシアネートの含有量は99.9質量%であり、十分に精製されたジシクロヘキシルメタンジイソシアネートが得られたことが確認された。また、得られた留分のハーゼン色数(APHA、ハーゼンメーターにて測定)は10であった。なお、塔底部からは、ジシクロヘキシルメタンジイソシアネート、ジシクロヘキシルメタンジイソシアネートの多量体(イソシアヌレート環構造を有する化合物)を含む混合液が回収され、該混合液の流動性は良好であった。
ジシクロヘキシルメタンジイソシアネート98.1質量%、α-メチルスチレン25質量ppm、及び、下記式(9-1)又は式(9-2)で表される化合物20質量ppmを含有するポリイソシアネート組成物を調製した。
ジシクロヘキシルメタンジイソシアネート98.1質量%、α-メチルスチレン33質量ppm、式(9-1)又は式(9-2)で表される化合物10質量ppm、及び、デカメチルテトラシロキサン320質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A49と同様の方法により蒸留精製を行い、イソホロンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、2であった。
ヘキサメチレンジイソシアネート98.5質量%、炭酸ジ(n-ブチル)2.8質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を、連続多段蒸留塔(高さ3000mm、内径50mm、充填材としてディクソンパッキンを使用)に供給した。蒸留塔の塔頂部での圧力は1kPa(絶対圧)とし、蒸留に必要な熱量はリボイラーより供給した。塔内の温度分布が安定したのち、頭頂部より高さ方向で600mm下に具備するサイドカットラインより留分を抜き出した。得られた留分をガスクロマトグラフィーで分析したところ、ヘキサメチレンジイソシアネートの含有量は99.9質量%であり、十分に精製されたヘキサメチレンジイソシアネートが得られたことが確認された。また、得られた留分のハーゼン色数(APHA、ハーゼンメーターにて測定)は18であった。なお、塔底部からは、ヘキサメチレンジイソシアネート、ヘキサメチレンジイソシアネートの多量体(イソシアヌレート環構造を有する化合物)を含む混合液が回収され、該混合液の流動性は良好であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及び炭酸ジ(n-ブチル)含有量を表8に記載のとおり変更したこと以外は、実施例A52と同様にして、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、表8に記載のとおりであった。
ヘキサメチレンジイソシアネート98.6質量%、炭酸ジ(n-ブチル)250質量ppm、及び、下記式(10-1)又は式(10-2)で表される化合物150質量ppmを含有するポリイソシアネート組成物を調製した。
ヘキサメチレンジイソシアネート98.4質量%、炭酸ジ(n-ブチル)150質量ppm、式(10-1)又は式(10-2)で表される化合物100質量ppm、及び、ジベンジルエーテル200質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物について、実施例A52と同様の方法により蒸留精製を行い、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、8であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及び炭酸ジ(n-ブチル)含有量を表8に記載のとおり変更したこと以外は、実施例A52と同様にして、ヘキサメチレンジイソシアネートの含有量が99.9質量%の留分を得た。得られた留分のハーゼン色数(APHA)は、表8に記載のとおりであった。
ヘキサメチレンジイソシアネート98.5質量%、ベンジルトルエン(異性体混合物)22質量ppm(なお、「質量ppm」は「×10-4質量%」を示す。)を含有するポリイソシアネート組成物を調製した。
温度計、撹拌機、窒素シール管を備えたガラス製四つ口フラスコに、調製したポリイソシアネート組成物1000gを入れ、フラスコ内の空気を窒素で置換し撹拌しながら70℃に加熱した。反応液の屈折率測定により、ヘキサメチレンジイソシアネートの転化率が20%になるまで触媒(テトラメチルアンモニウムヒドロキシド)を徐々に添加し、20%になった時点で85%リン酸水溶液を0.5g添加して反応を停止した。このとき、転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して220質量ppmであった。
反応後、反応液を濾過し、流下式薄膜蒸留装置を用いて、1回目160℃(27Pa)、2回目150℃(13Pa)で未反応のヘキサメチレンジイソシアネートを除去し、ヘキサメチレンジイソシアネートの重合体であるイソシアヌレート化合物を得た。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びベンジルトルエン含有量を表9に記載のとおり変更したこと以外は、実施例B1と同様にして、イソシアヌレート化反応を行った。
ヘキサメチレンジイソシアネート99.0質量%、ベンジルトルエン(異性体混合物)1300質量ppm、及び、下記式(11-1)で表される化合物と下記式(11-2)で表される化合物との混合物(2種の混合物として)530質量ppmを含有するポリイソシアネート組成物を調製した。
ヘキサメチレンジイソシアネート99.0質量%、ベンジルトルエン(異性体混合物)1200質量ppm、α-メチルスチレン610質量ppm、並びに、式(11-1)で表される化合物と下記式(11-2)で表される化合物との混合物(2種の混合物として)380質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B1と同様にして、イソシアヌレート化反応を行った。転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して70質量ppmであった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びベンジルトルエン含有量を表9に記載のとおり変更したこと以外は、実施例B1と同様にして、イソシアヌレート化反応を行った。
イソシアヌレート化合物の耐候性評価は、次の方法により行った。
イソシアヌレート化合物とポリエステルポリオール(Nuplex Resin製の商品名Setal166)をイソシアネート基/ヒドロキシ基の当量割合が1.0になるように配合し、イソシアヌレート化合物とポリオールを加えた固形分質量が50%になるように、酢酸エチル/トルエン/酢酸ブチル/キシレン/プロピレングリコールモノメチルエーテルアセテート(質量比30/30/20/15/5)の混合液を加え、塗料溶液を得た。その塗料溶液を白エナメル塗板に乾燥後膜厚40μmになるようにアプリケーター塗装し、20℃、湿度63%の条件で1週間塗膜養生を行った後、その塗板について耐候性を評価した。耐候性評価は、デューパネルウェザーメーター(スガ試験機製)を用いた。評価条件は、JIS D0205に従い、照射照度30W/m2、パネル温度60℃、照射時間と結露時間は4時間ごとのサイクル運転で行った。
暴露時間が1200時間となった時点の光沢保持率が80%以上のものを「A」とし、80%未満のものを「B」とした。その結果を表9に示す。
ヘキサメチレンジイソシアネート98.1質量%、n-ヘキサデカン25質量ppmを含有するポリイソシアネート組成物を調製した。
実施例B1と同様の方法によりイソシアヌレート化合物の調製をおこなったところ、触媒量は、反応に用いたポリイソシアネート組成物に対して230質量ppmであった。
反応後、反応液を濾過し、流下式薄膜蒸留装置を用いて、1回目160℃(27Pa)、2回目150℃(13Pa)で未反応のヘキサメチレンジイソシアネートを除去し、ヘキサメチレンジイソシアネートの重合体であるイソシアヌレート化合物を得た。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びn-ヘキサデカン含有量を表10に記載のとおり変更したこと以外は、実施例B1と同様にして、イソシアヌレート化反応を行った。
ヘキサメチレンジイソシアネート99.2質量%、n-ヘキサデカン1400質量ppm、及び、上記式(11-1)で表される化合物と上記式(11-2)で表される化合物との混合物(2種の混合物として)630質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B18と同様にして、イソシアヌレート化反応を行った。このとき、転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して65質量ppmであった。
ヘキサメチレンジイソシアネート99.1質量%、n-ヘキサデカン1500質量ppm、2,4,4-トリメチルペンテン-1を120質量ppm、並びに、上記式(11-1)で表される化合物と上記式(11-2)で表される化合物との混合物(2種の混合物として)430質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B18と同様にして、イソシアヌレート化反応を行った。転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して55質量ppmであった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びベンジルトルエン含有量を表10に記載のとおり変更したこと以外は、実施例B18と同様にして、イソシアヌレート化反応を行った。
ヘキサメチレンジイソシアネート99.1質量%、n-ペンタデカン22質量ppmを含有するポリイソシアネート組成物を調製した。
実施例B1と同様の方法によりイソシアヌレート化合物の調製をおこなったところ、触媒量は、反応に用いたポリイソシアネート組成物に対して210質量ppmであった。
反応後、反応液を濾過し、流下式薄膜蒸留装置を用いて、1回目160℃(27Pa)、2回目150℃(13Pa)で未反応のヘキサメチレンジイソシアネートを除去し、ヘキサメチレンジイソシアネートの重合体であるイソシアヌレート化合物を得た。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びn-ペンタデカン含有量を表11に記載のとおり変更したこと以外は、実施例B1と同様にして、イソシアヌレート化反応を行った。
ヘキサメチレンジイソシアネート98.2質量%、n-ペンタデカン180質量ppm、及び、下記式(12-1)で表される化合物と下記式(12-2)で表される化合物との混合物(2種の混合物として)20質量ppmを含有するポリイソシアネート組成物を調製した。
ヘキサメチレンジイソシアネート98.1質量%、n-ペンタデカン200質量ppm、2-メチルブテンを20質量ppm、並びに、式(12-1)で表される化合物と上記式(12-2)で表される化合物との混合物(2種の混合物として)30質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B35と同様にして、イソシアヌレート化反応を行った。転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して60質量ppmであった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びベンジルトルエン含有量を表11に記載のとおり変更したこと以外は、実施例B35と同様にして、イソシアヌレート化反応を行った。
ヘキサメチレンジイソシアネート98.8質量%、ジベンジルエーテル120質量ppmを含有するポリイソシアネート組成物を調製した。
実施例B1と同様の方法によりイソシアヌレート化合物の調製をおこなったところ、触媒量は、反応に用いたポリイソシアネート組成物に対して230質量ppmであった。
反応後、反応液を濾過し、流下式薄膜蒸留装置を用いて、1回目160℃(27Pa)、2回目150℃(13Pa)で未反応のヘキサメチレンジイソシアネートを除去し、ヘキサメチレンジイソシアネートの重合体であるイソシアヌレート化合物を得た。
ヘキサメチレンジイソシアネート98.2質量%、ジベンジルエーテル130質量ppm、及び、上記式(11-1)で表される化合物と上記式(11-2)で表される化合物との混合物(2種の混合物として)10質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B52と同様にして、イソシアヌレート化反応を行った。このとき、転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対し65質量ppmであった。
ヘキサメチレンジイソシアネート98.9質量%、ジベンジルエーテル22質量ppm、n-オクテンを10質量ppm、並びに、式(11-1)で表される化合物と上記式(11-2)で表される化合物との混合物(2種の混合物として)10質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B52と同様にして、イソシアヌレート化反応を行った。転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対し55質量ppmであった。
ヘキサメチレンジイソシアネート98.5質量%、デシルエーテル130質量ppmを含有するポリイソシアネート組成物を調製した。
実施例B1と同様の方法によりイソシアヌレート化合物の調製をおこなったところ、触媒量は、反応に用いたポリイソシアネート組成物に対して120質量ppmであった。
反応後、反応液を濾過し、流下式薄膜蒸留装置を用いて、1回目160℃(27Pa)、2回目150℃(13Pa)で未反応のヘキサメチレンジイソシアネートを除去し、ヘキサメチレンジイソシアネートの重合体であるイソシアヌレート化合物を得た。
ヘキサメチレンジイソシアネート98.4質量%、デシルエーテル160質量ppm、及び、上記式(11-1)で表される化合物と上記式(11-2)で表される化合物との混合物(2種の混合物として)20質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B55と同様にして、イソシアヌレート化反応を行った。このとき、転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して55質量ppmであった。
ヘキサメチレンジイソシアネート99.1質量%、デシルエーテル190質量ppm、スチレンを25質量ppm、並びに、式(9-1)で表される化合物と上記式(9-2)で表される化合物との混合物(2種の混合物として)25質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B55と同様にして、イソシアヌレート化反応を行った。転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して50質量ppmであった。
イソホロンジイソシアネート99.1質量%、ブチルフェニルエーテル500質量ppmを含有するポリイソシアネート組成物を調製した。
実施例B1と同様の方法によりイソシアヌレート化合物の調製をおこなったところ、触媒量は、反応に用いたポリイソシアネート組成物に対して100質量ppmであった。
反応後、反応液を濾過し、流下式薄膜蒸留装置を用いて、1回目180℃(27Pa)、2回目170℃(13Pa)で未反応のイソホロンジイソシアネートを除去し、イソホロンジイソシアネートの重合体であるイソシアヌレート化合物を得た。
イソホロンジイソシアネート99.2質量%、ブチルフェニルエーテル450質量ppm、及び、下記式(13-1)で表される化合物30質量ppmを含有するポリイソシアネート組成物を調製した。
イソホロンジイソシアネート98.4質量%、ブチルフェニルエーテル390質量ppm、ノネンを20質量ppm、並びに、式(13-1)で表される化合物30質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B58と同様にして、イソシアヌレート化反応を行った。転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して55質量ppmであった。
イソホロンジイソシアネート99.0質量%、o-ジクロロベンゼン50質量ppmを含有するポリイソシアネート組成物を調製した。
実施例B1と同様の方法によりイソシアヌレート化合物の調製をおこなったところ、触媒量は、反応に用いたポリイソシアネート組成物に対して220質量ppmであった。
反応後、反応液を濾過し、流下式薄膜蒸留装置を用いて、1回目180℃(27Pa)、2回目170℃(13Pa)で未反応のイソホロンジイソシアネートを除去し、イソホロンジイソシアネートの重合体であるイソシアヌレート化合物を得た。
イソホロンジイソシアネート98.8質量%、o-ジクロロベンゼン50質量ppm、及び、上記式(13-1)で表される化合物15質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B61と同様にして、イソシアヌレート化反応を行った。このとき、転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して85質量ppmであった。
イソホロンジイソシアネート98.8質量%、o-ジクロロベンゼン50質量ppm、α-メチルスチレンを40質量ppm、並びに、式(13-1)で表される化合物15質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B61と同様にして、イソシアヌレート化反応を行った。転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して70質量ppmであった。
イソホロンジイソシアネート98.2質量%、デカメチルテトラシロキサン120質量ppmを含有するポリイソシアネート組成物を調製した。
実施例B1と同様の方法によりイソシアヌレート化合物の調製をおこなったところ、触媒量は、反応に用いたポリイソシアネート組成物に対して100質量ppmであった。
反応後、反応液を濾過し、流下式薄膜蒸留装置を用いて、1回目180℃(27Pa)、2回目170℃(13Pa)で未反応のイソホロンジイソシアネートを除去し、イソホロンジイソシアネートの重合体であるイソシアヌレート化合物を得た。
イソホロンジイソシアネート98.4質量%、デカメチルテトラシロキサン200質量ppm、及び、下記式(14-1)で表される化合物40質量ppmを含有するポリイソシアネート組成物を調製した。
イソホロンジイソシアネート98.3質量%、デカメチルテトラシロキサン180質量ppm、n-オクテンを50質量ppm、並びに、式(14-1)で表される化合物40質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例64と同様にして、イソシアヌレート化反応を行った。転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対して55質量ppmであった。
ヘキサメチレンジイソシアネート98.2質量%、ジベンジルエーテル150質量ppmを含有するポリイソシアネート組成物を調製した。
実施例B1と同様の方法によりイソシアヌレート化合物の調製をおこなったところ、触媒量は、反応に用いたポリイソシアネート組成物に対して100質量ppmであった。
反応後、反応液を濾過し、流下式薄膜蒸留装置を用いて、1回目160℃(27Pa)、2回目150℃(13Pa)で未反応のヘキサメチレンジイソシアネートを除去し、ヘキサメチレンジイソシアネートの重合体であるイソシアヌレート化合物を得た。
ヘキサメチレンジイソシアネート98.3質量%、ジベンジルエーテル130質量ppm、及び、下記式(15-1)で表される化合物と上記式(15-2)で表される化合物との混合物(2種の混合物として)60質量ppmを含有するポリイソシアネート組成物を調製した。
ヘキサメチレンジイソシアネート98.1質量%、ジベンジルエーテル130質量ppm、炭酸ジ(n-ブチル)を60質量ppm、並びに、式(15-1)で表される化合物と上記式(15-2)で表される化合物との混合物(2種の混合物として)80質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例B67と同様にして、イソシアヌレート化反応を行った。転化率20%を達成するために必要な触媒量は、反応に用いたポリイソシアネート組成物に対し55質量ppmであった。
ポリイソシアネート組成物の調製
ヘキサメチレンジイソシアネート98.8質量%、下記式(16-1)及び(16-2)で表される化合物(2種の混合物)3.5質量ppm(なお、「質量ppm」は「×10-4質量%」を示す。)を含有するポリイソシアネート組成物を調製した。
攪拌器、温度系、冷却管及びFT-IR用プローブ(メトラートレド社製、React-IR、AgXプローブ)を取り付けた四ツ口フラスコの内部を窒素置換し、調製したポリイソシアネート組成物1200gと、3価アルコール及びε-カプロラクトンから誘導されるポリエステルポリオール「プラクセル305」(ダイセル化学社の商品名)130gとを入れ、撹拌しながら130℃で加熱した。FT-IRにてウレタン基の生成量を確認しながら反応をおこない、約1.7時間で反応の終了を確認した。
工程(1-2)
続いて、2-エチルヘキサン酸ジルコニルの20%オクタノール溶液を0.5g添加しアロファネート化反応をおこなった。反応液の屈折率の上昇が0.0051となった時点で、ピロリン酸の固形分10%2-エチル-1-ヘキサノール溶液(太平化学産業製、商品名「リン酸(105%)」を2-エチル-1-ヘキサノールで希釈したもの)を3.9g加え、反応を停止した。
反応液を濾過後、薄膜蒸留装置(柴田社製、伝熱面積0.1m2)を用いて、160℃、0.027kPaで蒸留をおこない、残渣を回収した。この残渣を更に、薄膜蒸留装置を用いて、150℃、0.013kPaで蒸留し、残渣を回収した。
得られた残渣はポリイソシアネート組成物であり、収量280g、NCO含有率(NCO%)14.9%であり、得られたポリイソシアネートのハーゼン色数(APHA)は90であった。また、得られたポリイソシアネート組成物に残存しているヘキサメチレンジイソシアネートは1.5質量%であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネートの含有量と式(16-1)及び式(16-2)で表される化合物の含有量を、表18に記載のとおり変更したこと以外は、実施例C1と同様にして、工程(1-1)及び工程(1-2)を行い、ポリイソシアネート組成物を得た。なお、各実施例において、工程(1-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は、表18に記載のとおりであった。
各実施例において得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表19に記載のとおりであった。
ヘキサメチレンジイソシアネート98.1質量%、式(16-1)及び式(16-2)で表される化合物400質量ppm、並びに、α-メチルスチレン1100質量ppmを含有するイソシアネート組成物を調製した。調製したポリイソシアネート組成物を用いたこと以外は実施例C1と同様にして、工程(1-1)及び工程(1-2)を行い、ポリイソシアネート組成物を得た。なお、工程(1-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.5時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表19に記載のとおりであった。
ヘキサメチレンジイソシアネート98.1質量%、式(16-1)及び式(16-2)で表される化合物420質量ppm、α-メチルスチレン930質量ppm、並びにベンジルトルエン(異性体混合物)620ppmを含有するポリイソシアネート組成物を調製した。調製したイソシアネート組成物を用いたこと以外は実施例C1と同様にして、工程(1-1)及び工程(1-2)を行い、ポリイソシアネート組成物を得た。なお、工程(1-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.5時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表19に記載のとおりであった。また、実施例C14において、工程(1-1)に要した時間は、表18に記載のとおりであった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネートの含有量と式(5-1)及び式(5-2)で表される化合物の含有量を、表18に記載のとおり変更したこと以外は、実施例C1と同様にして、工程(1-1)及び工程(1-2)を行い、ポリイソシアネート組成物を得た。なお、各比較例において、工程(1-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は、表18に記載のとおりであった。
各比較例において得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表19に記載のとおりであった。
ポリイソシアネート組成物の調製
ヘキサメチレンジイソシアネート98.2質量%、下記式(17-1)及び下記式(17-2)で表される化合物(2種の混合物)3.0質量ppm(なお、「質量ppm」は「×10-4質量%」を示す。)を含有するポリイソシアネート組成物を調製した。
攪拌器、温度系、冷却管及びFT-IR用プローブ(メトラートレド社製、React-IR、AgXプローブ)を取り付けた四ツ口フラスコの内部を窒素置換し、調製したポリイソシアネート組成物1200gと、3価アルコール及びε-カプロラクトンから誘導されるポリエステルポリオール「プラクセル305」(ダイセル化学社の商品名)130gとを入れ、撹拌しながら130℃で加熱した。FT-IRにてウレタン基の生成量を確認しながら反応をおこない、約1.6時間で反応の終了を確認した。
工程(2-2)
続いて、2-エチルヘキサン酸ジルコニルの20%オクタノール溶液を0.5g添加しアロファネート化反応をおこなった。反応液の屈折率の上昇が0.0051となった時点で、ピロリン酸の固形分10%2-エチル-1-ヘキサノール溶液(太平化学産業製、商品名「リン酸(105%)」を2-エチル-1-ヘキサノールで希釈したもの)を4.0g加え、反応を停止した。
反応液を濾過後、薄膜蒸留装置(柴田社製、伝熱面積0.1m2)を用いて、160℃、0.027kPaで蒸留をおこない、残渣を回収した。この残渣を更に、薄膜蒸留装置を用いて、150℃、0.013kPaで蒸留し、残渣を回収した。
得られた残渣はポリイソシアネート組成物であり、収量280g、NCO含有率(NCO%)15.0%であり、得られたポリイソシアネートのハーゼン色数(APHA)は40であった。また、得られたポリイソシアネート組成物に残存しているヘキサメチレンジイソシアネートは1.4質量%であった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネートの含有量と式(17-1)及び式(17-2)で表される化合物の含有量を、表20に記載のとおり変更したこと以外は、実施例C15と同様にして、工程(2-1)及び工程(2-2)を行い、ポリイソシアネート組成物を得た。なお、各実施例において、工程(2-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は、表20に記載のとおりであった。
各実施例において得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表21に記載のとおりであった。
ヘキサメチレンジイソシアネート98.6質量%、式(17-1)及び式(17-2)で表される化合物300質量ppm、並びに、2,4,4-トリメチルペンテン-1を700質量ppm含有するイソシアネート組成物を調製した。調製したポリイソシアネート組成物を用いたこと以外は実施例C15と同様にして、工程(2-1)及び工程(2-2)を行い、ポリイソシアネート組成物を得た。なお、工程(2-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.4時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表21に記載のとおりであった。
ヘキサメチレンジイソシアネート99.0質量%、式(17-1)及び式(17-2)で表される化合物220質量ppm、2,4,4-トリメチルペンテン-1を500質量ppm、並びにn-ペンタデカン100ppmを含有するポリイソシアネート組成物を調製した。調製したイソシアネート組成物を用いたこと以外は実施例C15と同様にして、工程(2-1)及び工程(2-2)を行い、ポリイソシアネート組成物を得た。なお、工程(2-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.5時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表21に記載のとおりであった。また、実施例C28において、工程(2-1)に要した時間は、表20に記載のとおりであった。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネートの含有量と式(17-1)及び式(17-2)で表される化合物の含有量を、表20に記載のとおり変更したこと以外は、実施例C15と同様にして、工程(2-1)及び工程(2-2)を行い、ポリイソシアネート組成物を得た。なお、各比較例において、工程(2-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は、表20に記載のとおりであった。
各比較例において得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表21に記載のとおりであった。
なお、表20中、「HMDI」はヘキサメチレンジイソシアネートの含有量(質量%)を示し、「17-1,17-2」は式(17-1)又は式(17-2)で表される化合物の合計含有量(質量ppm)を示し、「TMP」は2,4,4-トリメチルペンテン-1の含有量(質量ppm)を示し、「PD」はn-ペンタデカンの含有量(質量ppm)を示し、「工程(2-1)」は、工程(2-1)において、ウレタン化反応の反応開始から反応完了までに要した時間(時間)を示す。表21中、「HMDI残留量」は、ポリイソシアネート組成物におけるヘキサメチレンジイソシアネートの残留量(質量%)を示す。
ポリイソシアネート組成物の調製
ヘキサメチレンジイソシアネート99.0質量%、下記式(18-1)及び下記式(18-2)で表される化合物(2種の混合物)100質量ppm(なお、「質量ppm」は「×10-4質量%」を示す。)を含有するポリイソシアネート組成物を調製した。
攪拌器、温度系、冷却管及びFT-IR用プローブ(メトラートレド社製、React-IR、AgXプローブ)を取り付けた四ツ口フラスコの内部を窒素置換し、調製したポリイソシアネート組成物1200gと、3価アルコール及びε-カプロラクトンから誘導されるポリエステルポリオール「プラクセル305」(ダイセル化学社の商品名)130gとを入れ、撹拌しながら130℃で加熱した。FT-IRにてウレタン基の生成量を確認しながら反応をおこない、約1.8時間で反応の終了を確認した。
工程(3-2)
続いて、2-エチルヘキサン酸ジルコニルの20%オクタノール溶液を0.5g添加しアロファネート化反応をおこなった。反応液の屈折率の上昇が0.0051となった時点で、ピロリン酸の固形分10%2-エチル-1-ヘキサノール溶液(太平化学産業製、商品名「リン酸(105%)」を2-エチル-1-ヘキサノールで希釈したもの)を3.9g加え、反応を停止した。
反応液を濾過後、薄膜蒸留装置(柴田社製、伝熱面積0.1m2)を用いて、160℃、0.027kPaで蒸留をおこない、残渣を回収した。この残渣を更に、薄膜蒸留装置を用いて、150℃、0.013kPaで蒸留し、残渣を回収した。
得られた残渣はポリイソシアネート組成物であり、収量280g、NCO含有率(NCO%)14.9%であり、得られたポリイソシアネートのハーゼン色数(APHA)は30であった。また、得られたポリイソシアネート組成物に残存しているヘキサメチレンジイソシアネートは1.4質量%であった。
ヘキサメチレンジイソシアネート98.3質量%、式(18-1)及び式(18-2)で表される化合物100質量ppm、並びに、スチレン100質量ppmを含有するイソシアネート組成物を調製した。調製したポリイソシアネート組成物を用いたこと以外は実施例C29と同様にして、工程(3-1)及び(3-2)を行い、ポリイソシアネート組成物を得た。なお、工程(3-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.5時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表22に記載のとおりであった。
ヘキサメチレンジイソシアネート98.3質量%、式(18-1)及び式(18-2)で表される化合物120質量ppm、スチレン130質量ppm、並びにジベンジルエーテル220ppmを含有するポリイソシアネート組成物を調製した。調製したイソシアネート組成物を用いたこと以外は実施例C29と同様にして、工程(3-1)及び(3-2)を行い、ポリイソシアネート組成物を得た。なお、工程(3-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.5時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びヘキサメチレンジイソシアネート残存量は、表23に記載のとおりであった。また、実施例C31において、工程(3-1)に要した時間は、表22に記載のとおりであった。
ポリイソシアネート組成物の調製
イソホロンジイソシアネート98.3質量%、及び、下記式(19-1)で表される化合物80質量ppm(なお、「質量ppm」は「×10-4質量%」を示す。)を含有するポリイソシアネート組成物を調製した。
攪拌器、温度系、冷却管及びFT-IR用プローブ(メトラートレド社製、React-IR、AgXプローブ)を取り付けた四ツ口フラスコの内部を窒素置換し、調製したポリイソシアネート組成物1200gと、3価アルコール及びε-カプロラクトンから誘導されるポリエステルポリオール「プラクセル305」(ダイセル化学社の商品名)170gとを入れ、撹拌しながら130℃で加熱した。FT-IRにてウレタン基の生成量を確認しながら反応をおこない、約1.7時間で反応の終了を確認した。
工程(4-2)
続いて、2-エチルヘキサン酸ジルコニルの20%オクタノール溶液を0.5g添加しアロファネート化反応をおこなった。反応液の屈折率の上昇が0.0051となった時点で、ピロリン酸の固形分10%2-エチル-1-ヘキサノール溶液(太平化学産業製、商品名「リン酸(105%)」を2-エチル-1-ヘキサノールで希釈したもの)を3.9g加え、反応を停止した。
反応液を濾過後、薄膜蒸留装置(柴田社製、伝熱面積0.1m2)を用いて、180℃、0.027kPaで蒸留をおこない、残渣を回収した。この残渣を更に、薄膜蒸留装置を用いて、170℃、0.013kPaで蒸留し、残渣を回収した。
得られた残渣はポリイソシアネート組成物であり、NCO含有率(NCO%)15.1%であり、得られたポリイソシアネートのハーゼン色数(APHA)は30であった。また、得られたポリイソシアネート組成物に残存しているイソホロンジイソシアネートは1.5質量%であった。
イソホロンジイソシアネート98.3質量%、式(19-1)で表される化合物80質量ppm、及び、ノネン300質量ppmを含有するイソシアネート組成物を調製した。調製したポリイソシアネート組成物を用いたこと以外は実施例C32と同様にして、工程(4-1)及び(4-2)を行い、ポリイソシアネート組成物を得た。なお、工程(4-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.5時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びイソホロンジイソシアネート残存量は、表25に記載のとおりであった。
イソホロンジイソシアネート98.6質量%、式(19-1)で表される化合物90質量ppm、ノネン130質量ppm、及び、デカメチルテトラシロキサン120ppmを含有するポリイソシアネート組成物を調製した。調製したイソシアネート組成物を用いたこと以外は実施例C32と同様にして、工程(4-1)及び(4-2)を行い、ポリイソシアネート組成物を得た。なお、工程(4-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.5時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びイソホロンジイソシアネート残存量は、表25に記載のとおりであった。また、実施例C36において、工程(4-1)に要した時間は、表24に記載のとおりであった。
ポリイソシアネート組成物の調製
イソホロンジイソシアネート98.3質量%、及び、下記式(20-1)で表される化合物50質量ppm(なお、「質量ppm」は「×10-4質量%」を示す。)を含有するポリイソシアネート組成物を調製した。
攪拌器、温度系、冷却管及びFT-IR用プローブ(メトラートレド社製、React-IR、AgXプローブ)を取り付けた四ツ口フラスコの内部を窒素置換し、調製したポリイソシアネート組成物1200gと、3価アルコール及びε-カプロラクトンから誘導されるポリエステルポリオール「プラクセル305」(ダイセル化学社の商品名)170gとを入れ、撹拌しながら130℃で加熱した。FT-IRにてウレタン基の生成量を確認しながら反応をおこない、約1.8間で反応の終了を確認した。
工程(5-2)
続いて、2-エチルヘキサン酸ジルコニルの20%オクタノール溶液を0.5g添加しアロファネート化反応をおこなった。反応液の屈折率の上昇が0.0051となった時点で、ピロリン酸の固形分10%2-エチル-1-ヘキサノール溶液(太平化学産業製、商品名「リン酸(105%)」を2-エチル-1-ヘキサノールで希釈したもの)を3.9g加え、反応を停止した。
反応液を濾過後、薄膜蒸留装置(柴田社製、伝熱面積0.1m2)を用いて、160℃、0.027kPaで蒸留をおこない、残渣を回収した。この残渣を更に、薄膜蒸留装置を用いて、150℃、0.013kPaで蒸留し、残渣を回収した。
得られた残渣はポリイソシアネート組成物であり、収量280g、NCO含有率(NCO%)14.9%であり、得られたポリイソシアネートのハーゼン色数(APHA)は30であった。また、得られたポリイソシアネート組成物に残存しているイソホロンジイソシアネートは1.5質量%であった。
イソホロンジイソシアネート98.4質量%、式(20-1)で表される化合物45質量ppm、及び、α-メチルスチレン40質量ppmを含有するイソシアネート組成物を調製した。調製したポリイソシアネート組成物を用いたこと以外は実施例C35と同様にして、工程(5-1)及び工程(5-2)を行い、ポリイソシアネート組成物を得た。なお、工程(5-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.5時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びイソホロンジイソシアネート残存量は、表27に記載のとおりであった。
イソホロンジイソシアネート98.4質量%、式(20-1)で表される化合物50質量ppm、α-メチルスチレン50質量ppm、及び、ブチルフェニルエーテル110質量ppmを含有するポリイソシアネート組成物を調製した。調製したイソシアネート組成物を用いたこと以外は実施例C35と同様にして、工程(5-1)及び工程(5-2)を行い、ポリイソシアネート組成物を得た。なお、工程(5-1)において、ウレタン化反応の反応開始から反応完了までに要した時間は0.5時間であった。
得られたポリイソシアネート組成物のNCO%、ハーゼン色数(APHA)、及びイソホロンジイソシアネート残存量は、表26に記載のとおりであった。また、実施例C37において、工程(5-1)に要した時間は、表26に記載のとおりであった。
ヘキサメチレンジイソシアネート98.5質量%、ベンジルトルエン(異性体混合物)22質量ppm(なお、「質量ppm」は「×10-4質量%」を示す。)を含有するイソシアネート組成物を調製した。
攪拌機、温度計、環流冷却管及び窒素吹き込み管を備えたガラス製四つ口フラスコを窒素雰囲気にした後、調製したポリイソシアネート組成物700g、トリメチル燐酸:150g、メチルセロソルブアセテート:150g、水:15g(HMDI/水モル比=5)を入れ、液温度を160℃で1時間保持した。得られた反応液(未反応ジイソシアネートモノマー濃度:65質量%)を真空度655Pa、温度160℃の掻き取り式薄膜蒸留器に500g/hrでフィードした。得られた、ジイソシアネートモノマー濃度5質量%、尿素2量体濃度1.5質量%のビウレット型ポリイソシアネート重合体の組成物を窒素雰囲気下、液温度140℃で30分保持後の尿素2量体濃度は0.2質量%以下、透過率93%であった。このポリイソシアネート組成物を再度掻き取り式薄膜蒸留器(真空度67Pa、温度160℃)にフィードし、ジイソシアネートモノマー濃度0.3質量%、尿素2量体濃度0.2質量%以下、ハーゼン色数(APHA)35のビウレット型ポリイソシアネート重合体の組成物を得た。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びベンジルトルエン含有量を表28に記載のとおり変更したこと以外は、実施例D1と同様にして、ビウレット化反応を行った。得られたポリイソシアネート組成物のハーゼン色数(APHA)を表28に示す。
ヘキサメチレンジイソシアネート99.0質量%、ベンジルトルエン(異性体混合物)1300質量ppm、並びに、下記式(21-1)で表される化合物と下記式(21-2)で表される化合物との混合物(2種の混合物として)530質量ppmを含有するポリイソシアネート組成物を調製した。
ヘキサメチレンジイソシアネート99.0質量%、ベンジルトルエン(異性体混合物)1200質量ppm、α-メチルスチレン610質量ppm、及び、式(21-1)で表される化合物と式(21-2)で表される化合物との混合物(2種の混合物として)380質量ppmを含有するイソシアネート組成物を調製した。
調製したイソシアネート組成物を用いて、実施例D1と同様にして、ビウレット化反応を行った。得られたポリイソシアネート組成物のハーゼン色数(APHA)を表28に示す。
イソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びベンジルトルエン含有量を表28に記載のとおり変更したこと以外は、実施例D1と同様にして、ビウレット化反応を行った。各比較例において、得られたポリイソシアネート組成物のハーゼン色数(APHA)を表28に示す。
なお、表中、「HMDI」はヘキサメチレンジイソシアネートの含有量(質量%)を示し、「BT」はベンジルトルエンの含有量(質量ppm)を示し、「21-1,21-2」は式(21-1)又は式(21-2)で表される化合物の合計含有量(質量ppm)を示し、「αMS」はα-メチルスチレンの含有量(質量ppm)を示す。
ヘキサメチレンジイソシアネート98.1質量%、n-ペンタデカン25質量ppm(なお、「質量ppm」は「×10-4質量%」を示す。)を含有するイソシアネート組成物を調製した。
攪拌機、温度計、環流冷却管及び窒素吹き込み管を備えたガラス製四つ口フラスコを窒素雰囲気にした後、調製したポリイソシアネート組成物700g、トリメチル燐酸:150g、メチルセロソルブアセテート:150g、水:15g(HMDI/水モル比=5)を入れ、液温度を160℃で1時間保持した。得られた反応液(未反応ジイソシアネートモノマー濃度:65質量%)を真空度655Pa、温度160℃の掻き取り式薄膜蒸留器に500g/hrでフィードした。得られた、ジイソシアネートモノマー濃度5質量%、尿素2量体濃度1.5質量%のビウレット型ポリイソシアネート重合体の組成物を窒素雰囲気下、液温度140℃で30分保持後の尿素2量体濃度は0.2質量%以下、透過率93%であった。このポリイソシアネート組成物を再度掻き取り式薄膜蒸留器(真空度67Pa、温度160℃)にフィードし、ジイソシアネートモノマー濃度0.3質量%、尿素2量体濃度0.2質量%以下、ハーゼン色数(APHA)30のビウレット型ポリイソシアネート重合体の組成物を得た。
ポリイソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びn-ペンタデカン含有量を表29に記載のとおり変更したこと以外は、実施例D11と同様にして、ビウレット化反応を行った。得られたポリイソシアネート組成物のハーゼン色数(APHA)を表29に示す。
ヘキサメチレンジイソシアネート98.1質量%、n-ペンタデカン300質量ppm、並びに、上記式(21-1)で表される化合物と上記式(21-2)で表される化合物との混合物(2種の混合物として)210質量ppmを含有するポリイソシアネート組成物を調製した。
調製したポリイソシアネート組成物を用いて、実施例D11と同様にして、ビウレット化反応を行った。得られたポリイソシアネート組成物のハーゼン色数(APHA)を表29に示す。
ヘキサメチレンジイソシアネート98.4質量%、n-ペンタデカン300質量ppm、2,4,4-トリメチルペンテン-1を110質量ppm、及び、式(21-1)で表される化合物と式(21-2)で表される化合物との混合物(2種の混合物として)200質量ppmを含有するイソシアネート組成物を調製した。
調製したイソシアネート組成物を用いて、実施例D11と同様にして、ビウレット化反応を行った。得られたポリイソシアネート組成物のハーゼン色数(APHA)を表29に示す。
イソシアネート組成物におけるヘキサメチレンジイソシアネート含有量及びn-ペンタデカン含有量を表29に記載のとおり変更したこと以外は、実施例D11と同様にして、ビウレット化反応を行った。各比較例において、得られたポリイソシアネート組成物のハーゼン色数(APHA)を表29に示す。
実施例及び比較例におけるイソシアネート組成物の組成及び得られたポリイソシアネート組成物のハーゼン色数(APHA)を表29に示す。なお、表中、「HMDI」はヘキサメチレンジイソシアネートの含有量(質量%)を示し、「PD」はn-ペンタデカンの含有量(質量ppm)を示し、「21-1,21-2」は式(21-1)又は式(21-2)で表される化合物の合計含有量(質量ppm)を示し、「TMP」は2,4,4-トリメチルペンテン-1の含有量(質量ppm)を示す。
Claims (20)
- ポリイソシアネート組成物の全質量を基準として、
97重量%以上のポリイソシアネートと、
2.0質量ppm以上1.0×104質量ppm以下の、前記ポリイソシアネートと異なる化合物であり少なくとも1つの不飽和結合を有する化合物、又は、5.0質量ppm以上2.0×104質量ppm以下の、炭化水素化合物、エーテル化合物、スルフィド化合物、ハロゲン化炭化水素化合物、含ケイ素炭化水素化合物、含ケイ素エーテル化合物及び含ケイ素スルフィド化合物からなる群より選ばれる少なくとも1種の不活性化合物と、
を含有するポリイソシアネート組成物。 - 前記ポリイソシアネートと、前記少なくとも1つの不飽和結合を有する化合物とを含有し、
前記不飽和結合が、炭素-炭素間の二重結合、又は、炭素-酸素間の二重結合であり、前記炭素-炭素間の二重結合が、芳香環を構成する炭素-炭素間の二重結合ではない、請求項1に記載の組成物。 - 前記少なくとも1つの不飽和結合を有する化合物が、炭酸誘導体を含む、請求項2に記載の組成物。
- 前記炭酸誘導体が、炭酸ジメチル、炭酸ジエチル、炭酸ジブチル、炭酸ジペンチル及び炭酸ジヘキシルからなる群より選ばれる少なくとも1種の炭酸エステル、又は、N-無置換カルバミン酸エステルである、請求項3に記載の組成物。
- 前記炭化水素化合物、前記エーテル化合物、前記スルフィド化合物、前記ハロゲン化炭化水素化合物、前記含ケイ素炭化水素化合物、前記含ケイ素エーテル化合物及び前記含ケイ素スルフィド化合物からなる群より選ばれる少なくとも1種の不活性化合物を更に含有する、請求項5に記載の組成物。
- 前記炭化水素化合物、前記エーテル化合物、前記スルフィド化合物、前記ハロゲン化炭化水素化合物、前記含ケイ素炭化水素化合物、前記含ケイ素エーテル化合物及び前記含ケイ素スルフィド化合物からなる群より選ばれる少なくとも1種の不活性化合物を更に含有する、請求項7に記載の組成物。
- 前記ポリイソシアネートと、前記炭化水素化合物、前記エーテル化合物、前記スルフィド化合物、前記ハロゲン化炭化水素化合物、前記含ケイ素炭化水素化合物、前記含ケイ素エーテル化合物及び前記含ケイ素スルフィド化合物からなる群より選ばれる少なくとも1種の不活性化合物と、を含有する、請求項1に記載の組成物。
- 前記少なくとも1つの不飽和結合を有する化合物を更に含有し、
前記不飽和結合が、炭素-炭素間の二重結合、又は、炭素-酸素間の二重結合であり、前記炭素-炭素間の二重結合が、芳香環を構成する炭素-炭素間の二重結合ではない、請求項9に記載の組成物。 - 前記少なくとも1つの不飽和結合を有する化合物が、炭酸誘導体を含む、請求項10に記載の組成物。
- 前記炭酸誘導体が、炭酸ジメチル、炭酸ジエチル、炭酸ジブチル、炭酸ジペンチル及び炭酸ジヘキシルからなる群より選ばれる少なくとも1種の炭酸エステル、又は、N-無置換カルバミン酸エステルである、請求項11に記載の組成物。
- 前記R1が、ヘキサメチレン基である、請求項13に記載の組成物。
- 前記不活性化合物が、ベンジルトルエン、ジベンジルエーテル及びヘキサデカンからなる群より選ばれる少なくとも1種の化合物である、請求項6、8又は9に記載の組成物。
- 前記少なくとも1つの不飽和結合を有する化合物が、スチレン、α-メチルスチレン、ペンテン及びオクテンからなる群より選ばれる少なくとも1種の化合物である、請求項2又は10に記載の組成物。
- ポリイソシアネートの蒸留精製における着色を防止する方法であって、
前記蒸留精製の前に、前記ポリイソシアネートに、該ポリイソシアネートと異なる化合物であり少なくとも1つの不飽和結合を有する化合物を、前記ポリイソシアネートの全量基準で2.0質量ppm以上1.0×104質量ppm以下添加する工程を備える、方法。 - 請求項17に記載の方法によって蒸留精製されたポリイソシアネートを含む、ポリイソシアネート組成物。
- 請求項19に記載の方法によって製造されるイソシアネート重合体を含有する組成物。
Priority Applications (17)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SG11201501009RA SG11201501009RA (en) | 2012-11-01 | 2013-10-31 | Polyisocyanate composition and isocyanate polymer composition |
JP2014544598A JP6302838B2 (ja) | 2012-11-01 | 2013-10-31 | ポリイソシアネート組成物及びイソシアネート重合体組成物 |
IN1129DEN2015 IN2015DN01129A (ja) | 2012-11-01 | 2013-10-31 | |
KR1020177021522A KR101902724B1 (ko) | 2012-11-01 | 2013-10-31 | 폴리이소시아네이트 조성물 및 이소시아네이트 중합체 조성물 |
CA2881289A CA2881289A1 (en) | 2012-11-01 | 2013-10-31 | Polyisocyanate composition and isocyanate polymer composition |
EP13851480.7A EP2915803B1 (en) | 2012-11-01 | 2013-10-31 | Polyisocyanate composition and isocyanate polymer composition |
EP19166063.8A EP3536683B1 (en) | 2012-11-01 | 2013-10-31 | Polyisocyanate composition and isocyanate polymer composition |
BR112015006288-1A BR112015006288B1 (pt) | 2012-11-01 | 2013-10-31 | composição de poliisocianato, e, método de fabricação de um polímero de isocianato |
KR1020157005771A KR20150041052A (ko) | 2012-11-01 | 2013-10-31 | 폴리이소시아네이트 조성물 및 이소시아네이트 중합체 조성물 |
BR122020002442-9A BR122020002442B1 (pt) | 2012-11-01 | 2013-10-31 | Composição de poliisocianato, e, método de fabricação de um polímero de isocianato |
CN201380047522.0A CN104619682B (zh) | 2012-11-01 | 2013-10-31 | 多异氰酸酯组合物和异氰酸酯聚合物组合物 |
EP18164645.6A EP3372579B1 (en) | 2012-11-01 | 2013-10-31 | Polyisocyanate composition and isocyanate polymer composition |
EA201590299A EA201590299A1 (ru) | 2012-11-01 | 2013-10-31 | Полиизоцианатная композиция и композиция изоцианатного полимера |
US14/425,671 US10125212B2 (en) | 2012-11-01 | 2013-10-31 | Polyisocyanate composition and isocyanate polymer composition |
KR1020177033915A KR20170132359A (ko) | 2012-11-01 | 2013-10-31 | 폴리이소시아네이트 조성물 및 이소시아네이트 중합체 조성물 |
BR122020002424-0A BR122020002424B1 (pt) | 2012-11-01 | 2013-10-31 | Composição de poliisocianato, e, método de fabricação de um polímero de isocianato |
US15/588,892 US10301417B2 (en) | 2012-11-01 | 2017-05-08 | Polyisocyanate composition and isocyanate polymer composition |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012242141 | 2012-11-01 | ||
JP2012242136 | 2012-11-01 | ||
JP2012242139 | 2012-11-01 | ||
JP2012-242136 | 2012-11-01 | ||
JP2012-242139 | 2012-11-01 | ||
JP2012-242141 | 2012-11-01 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/425,671 A-371-Of-International US10125212B2 (en) | 2012-11-01 | 2013-10-31 | Polyisocyanate composition and isocyanate polymer composition |
US15/588,892 Continuation US10301417B2 (en) | 2012-11-01 | 2017-05-08 | Polyisocyanate composition and isocyanate polymer composition |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014069605A1 true WO2014069605A1 (ja) | 2014-05-08 |
Family
ID=50627502
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2013/079639 WO2014069605A1 (ja) | 2012-11-01 | 2013-10-31 | ポリイソシアネート組成物及びイソシアネート重合体組成物 |
Country Status (12)
Country | Link |
---|---|
US (2) | US10125212B2 (ja) |
EP (3) | EP3536683B1 (ja) |
JP (5) | JP6302838B2 (ja) |
KR (3) | KR20170132359A (ja) |
CN (5) | CN104619682B (ja) |
BR (3) | BR112015006288B1 (ja) |
CA (1) | CA2881289A1 (ja) |
EA (1) | EA201590299A1 (ja) |
IN (1) | IN2015DN01129A (ja) |
SG (1) | SG11201501009RA (ja) |
TW (1) | TWI530510B (ja) |
WO (1) | WO2014069605A1 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019131855A1 (ja) | 2017-12-27 | 2019-07-04 | 旭化成株式会社 | 有機アミンの回収方法 |
EP3564344A1 (en) * | 2012-11-20 | 2019-11-06 | Dow Global Technologies Llc | Distillable fuel markers |
US11118001B2 (en) | 2016-10-14 | 2021-09-14 | Asahi Kasei Kabushiki Kaisha | Isocyanate composition, method for producing isocyanate composition, and method for producing isocyanate polymer |
US11174337B2 (en) | 2016-10-14 | 2021-11-16 | Asahi Kasei Kabushiki Kaisha | Isocyanate composition, method for producing isocyanate polymer and isocyanate polymer |
JP2022515701A (ja) * | 2018-10-31 | 2022-02-22 | ダウ グローバル テクノロジーズ エルエルシー | 有機溶液からモノイソシアネートを除去するための方法 |
US11548975B2 (en) | 2016-10-14 | 2023-01-10 | Asahi Kasei Kabushiki Kaisha | Isocyanate composition and method for producing isocyanate polymer |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109843952B (zh) * | 2016-10-14 | 2021-11-12 | 旭化成株式会社 | 多异氰酸酯组合物、封端多异氰酸酯组合物、亲水性多异氰酸酯组合物、涂料组合物和涂膜 |
FR3062214B1 (fr) | 2017-01-20 | 2022-10-21 | Centre Nat Rech Scient | Sonde pour microscope a force atomique equipe d'un resonateur optomecanique, et microscope a force atomique comportant une telle sonde |
CN109705305B (zh) * | 2018-12-11 | 2021-04-20 | 万华化学集团股份有限公司 | 含有多不饱和基团异氰酸酯缩二脲及其制备和应用 |
CN109824865B (zh) * | 2018-12-26 | 2021-09-07 | 万华化学集团股份有限公司 | 具有储存稳定性的多异氰酸酯固化剂制备方法及固化剂 |
EP3712188B1 (en) * | 2019-03-11 | 2022-05-11 | Asahi Kasei Kabushiki Kaisha | Polyisocyanate composition, blocked polyisocyanate composition, coating material composition, and coating film |
Citations (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB994890A (en) | 1961-12-18 | 1965-06-10 | Ici Ltd | New organic polyisocyanates and their manufacture |
US3976622A (en) | 1973-02-17 | 1976-08-24 | Bayer Aktiengesellschaft | Process for the production of polyisocyanates with a biuret structure |
US4176132A (en) | 1977-03-01 | 1979-11-27 | Asahi Kasei Kogyo Kabushiki Kaisha | Reaction of organic diisocyanates with water |
US4290969A (en) | 1980-08-14 | 1981-09-22 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for the continuous production of polyisocyanate |
US4324879A (en) | 1978-09-08 | 1982-04-13 | Bayer Aktiengesellschaft | Process for the preparation of polyisocyanates containing isocyanurate groups and the use thereof |
JPS5747139B2 (ja) | 1973-05-08 | 1982-10-07 | ||
US4412073A (en) | 1981-02-03 | 1983-10-25 | Rhone-Poulenc Specialites Chimiques | Isocyanurate preparation by catalytic, aminosilyl initiated cyclotrimerization of isocyanates |
JPS6241496B2 (ja) | 1979-02-16 | 1987-09-03 | Asahi Chemical Ind | |
JPS6357577A (ja) | 1986-08-29 | 1988-03-12 | Asahi Chem Ind Co Ltd | ポリイソシアネ−トの製造方法 |
US4837359A (en) | 1987-01-07 | 1989-06-06 | Bayer Aktiengesellschaft | Process for the production of polyisocyanates with biuret structures |
JPH023682A (ja) * | 1988-02-27 | 1990-01-09 | Bayer Ag | イソシアヌレート基含有ポリイソシアネートの製造方法およびそれらの使用 |
JPH02228317A (ja) | 1989-01-03 | 1990-09-11 | Bayer Ag | ウレツトジオン基及びイソシアヌレート基を含有する変性ポリイソシアネート並びに二成分系ポリウレタン被覆用組成物 |
US4983762A (en) | 1986-07-04 | 1991-01-08 | Rhone-Poulenc Chimie De Base | Preparation of biureto polyisocyanates |
JPH04226966A (ja) * | 1990-05-11 | 1992-08-17 | Bayer Ag | イソシアヌレートポリイソシアネートの製造方法、この方法により得られる化合物およびその使用 |
JPH04253951A (ja) * | 1991-02-05 | 1992-09-09 | Asahi Chem Ind Co Ltd | カルバミン酸エステルの熱分解方法 |
JPH07304724A (ja) | 1994-05-09 | 1995-11-21 | Bayer Ag | アロファネート基を含有する光安定性ポリイソシアネートの製造方法 |
JPH08291129A (ja) | 1995-04-24 | 1996-11-05 | Nippon Polyurethane Ind Co Ltd | 着色の低減した有機イソシアネートの製造方法 |
US5641851A (en) | 1994-12-09 | 1997-06-24 | Basf Aktiengesellschaft | Preparation of biuret-containing polyisocyanates |
JP2000119240A (ja) * | 1998-10-13 | 2000-04-25 | Nippon Polyurethane Ind Co Ltd | 多官能ポリイソシアネート組成物の製造方法 |
WO2009139061A1 (ja) * | 2008-05-15 | 2009-11-19 | 旭化成ケミカルズ株式会社 | 炭酸ジアリールを用いるイソシアネートの製造方法 |
JP2012506465A (ja) | 2008-10-22 | 2012-03-15 | ビーエーエスエフ ソシエタス・ヨーロピア | 無色なポリイソシアネートの製造方法 |
WO2012046734A1 (ja) * | 2010-10-04 | 2012-04-12 | 旭化成ケミカルズ株式会社 | 分離方法及びイソシアネートの製造方法 |
JP2012153708A (ja) * | 2009-08-21 | 2012-08-16 | Asahi Kasei Chemicals Corp | N−置換カルバミン酸エステルの製造方法、該n−置換カルバミン酸エステルを用いるイソシアネートの製造方法 |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2885423A (en) * | 1956-01-27 | 1959-05-05 | Du Pont | Stabilization of organic isocyanates |
US2885424A (en) * | 1956-01-27 | 1959-05-05 | Du Pont | Stabilization of organic isocyanates |
US2885420A (en) * | 1956-01-27 | 1959-05-05 | Du Pont | Stabilization of organic isocyanates |
US3281444A (en) * | 1963-05-09 | 1966-10-25 | Union Carbide Corp | Stabilization of organic isocyanates with alkenyl ketones and esters |
US3549504A (en) * | 1966-05-05 | 1970-12-22 | Takeda Chemical Industries Ltd | Method for the purification of organic polyisocyanates by fractional distillation in presence of an inert gas or superheated vapor of an organic solvent |
FR1555517A (ja) * | 1966-05-10 | 1969-01-31 | ||
US3585230A (en) * | 1968-07-17 | 1971-06-15 | Kaiser Aluminium Chem Corp | Stable liquid polyisocyanate compositions |
US4152348A (en) | 1978-02-22 | 1979-05-01 | The Upjohn Company | Stabilized isocyanate compositions |
JPS5747319A (en) * | 1980-09-03 | 1982-03-18 | Nippon Polyurethan Kogyo Kk | Preparation of aliphatic isocyanurate compound |
JPS5747139A (en) | 1980-09-04 | 1982-03-17 | Hitachi Reinetsu Jiyuusetsu Kk | Heat pump type hot-water supply system |
DE3440912A1 (de) | 1984-11-09 | 1986-05-15 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von waermefarbbestaendigen aliphatischen und/oder cycloaliphatischen diisocyanaten und ihre verwendung zur herstellung von farbverbesserten, modifizierten polyisocyanaten |
US4758614A (en) * | 1986-04-25 | 1988-07-19 | Ciba-Geigy Corporation | Compositions stabilized with substituted amino carbamates |
US6765111B1 (en) * | 1988-02-27 | 2004-07-20 | Bayer Aktiengesellschaft | Process for the production of polyisocyanates containing isocyanurate groups and their use |
DE4006978A1 (de) * | 1990-03-06 | 1991-09-12 | Basf Ag | Verfahren zur herstellung von mischungen aus diphenylmethan-diisocyanaten und polyphenyl-polymethylen-polyisocyanaten mit einer verbesserten iodfarbzahl |
US5157128A (en) | 1990-11-30 | 1992-10-20 | Warner-Lambert Company | Certain optically active substituted α,α-dialkyl-pyrrolidine-3-methamines useful as intermediates |
DE4124318A1 (de) | 1991-07-23 | 1993-01-28 | Bayer Ag | Verfahren zur reinigung von polyisocyanaten, die so gereinigten polyisocyanate und ihre verwendung |
DK0538500T3 (da) * | 1991-10-19 | 1995-04-10 | Basf Corp | Fremgangsmåde til fremstilling af polymethylenpolyphenylenpolyisocyanater med formindsket farve- og chloridindhold |
US5312971A (en) * | 1992-07-23 | 1994-05-17 | Miles Inc. | Color reduction of polymethylene polyphenyl polyisocyanates |
DE4232769A1 (de) * | 1992-09-30 | 1994-03-31 | Basf Ag | Verfahren zur Herstellung von Mischungen aus Diphenylmethandiisocyanaten und Polyphenyl-polymethylen-polyisocyanaten mit einer verminderten Iodfarbzahl |
DE4331083A1 (de) | 1993-09-13 | 1995-03-16 | Basf Ag | Lagerstabile, nach phosgenfreien Verfahren erhältliche Polyisocyanatzusammensetzungen, ein Verfahren zu ihrer Herstellung und ihre Verwendung |
DE4331085A1 (de) | 1993-09-13 | 1995-03-16 | Basf Ag | Stabile, nach phosgenfreien Verfahren erhältliche Polyisocyanatzusammensetzungen und ein Verfahren zu ihrer Herstellung |
JPH11246508A (ja) | 1998-03-04 | 1999-09-14 | Mitsubishi Gas Chem Co Inc | イソシアネート化合物の安定化方法および組成物 |
DE10123416A1 (de) | 2001-05-14 | 2002-11-21 | Bayer Ag | Verfahren zur Herstellung von Polyisocyanaten |
JP4247735B2 (ja) | 2002-09-10 | 2009-04-02 | 日本ポリウレタン工業株式会社 | ポリメチレンポリフェニレンポリイソシアネートの着色低減方法 |
JP4314631B2 (ja) * | 2002-11-05 | 2009-08-19 | 日本ポリウレタン工業株式会社 | 低減された色数を有するジフェニルメタンジイソシアネート系ポリイソシアネートの製造方法 |
TW200844080A (en) | 2007-01-11 | 2008-11-16 | Asahi Kasei Chemicals Corp | Process for producing isocyanate |
EP2132244B1 (de) | 2007-03-27 | 2018-08-22 | Basf Se | Verfahren zur herstellung von farblosen isocyanuraten von diisocyanaten |
KR101429834B1 (ko) * | 2009-12-24 | 2014-08-12 | 미쓰이 가가쿠 가부시키가이샤 | 아이소사이아네이트 잔사의 처리 방법 및 카보네이트의 처리 방법 |
US9612240B2 (en) | 2010-06-29 | 2017-04-04 | The Trustees Of The University Of Pennsylvania | Biomimetic chemical sensors using nanoelectronic readout of olfactory receptors |
KR101507251B1 (ko) | 2011-02-21 | 2015-03-30 | 아사히 가세이 케미칼즈 가부시키가이샤 | 카르보닐 화합물의 제조 방법 |
-
2013
- 2013-10-30 TW TW102139278A patent/TWI530510B/zh not_active IP Right Cessation
- 2013-10-31 JP JP2014544598A patent/JP6302838B2/ja active Active
- 2013-10-31 BR BR112015006288-1A patent/BR112015006288B1/pt active IP Right Grant
- 2013-10-31 CN CN201380047522.0A patent/CN104619682B/zh active Active
- 2013-10-31 IN IN1129DEN2015 patent/IN2015DN01129A/en unknown
- 2013-10-31 CN CN201610333477.0A patent/CN105924370A/zh active Pending
- 2013-10-31 BR BR122020002424-0A patent/BR122020002424B1/pt active IP Right Grant
- 2013-10-31 KR KR1020177033915A patent/KR20170132359A/ko active IP Right Grant
- 2013-10-31 EP EP19166063.8A patent/EP3536683B1/en active Active
- 2013-10-31 CN CN201610333694.XA patent/CN106008269B/zh active Active
- 2013-10-31 US US14/425,671 patent/US10125212B2/en active Active
- 2013-10-31 CN CN201711284336.5A patent/CN107963982B/zh active Active
- 2013-10-31 EP EP18164645.6A patent/EP3372579B1/en active Active
- 2013-10-31 EA EA201590299A patent/EA201590299A1/ru unknown
- 2013-10-31 KR KR1020177021522A patent/KR101902724B1/ko active IP Right Grant
- 2013-10-31 BR BR122020002442-9A patent/BR122020002442B1/pt active IP Right Grant
- 2013-10-31 WO PCT/JP2013/079639 patent/WO2014069605A1/ja active Application Filing
- 2013-10-31 EP EP13851480.7A patent/EP2915803B1/en active Active
- 2013-10-31 KR KR1020157005771A patent/KR20150041052A/ko active Application Filing
- 2013-10-31 SG SG11201501009RA patent/SG11201501009RA/en unknown
- 2013-10-31 CN CN201611183613.9A patent/CN107056656A/zh active Pending
- 2013-10-31 CA CA2881289A patent/CA2881289A1/en not_active Abandoned
-
2016
- 2016-09-14 JP JP2016179935A patent/JP6212187B2/ja active Active
-
2017
- 2017-05-08 US US15/588,892 patent/US10301417B2/en active Active
- 2017-09-11 JP JP2017174339A patent/JP6546233B2/ja active Active
- 2017-09-14 JP JP2017177066A patent/JP6475301B2/ja active Active
-
2019
- 2019-06-19 JP JP2019114045A patent/JP6869290B2/ja active Active
Patent Citations (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB994890A (en) | 1961-12-18 | 1965-06-10 | Ici Ltd | New organic polyisocyanates and their manufacture |
US3976622A (en) | 1973-02-17 | 1976-08-24 | Bayer Aktiengesellschaft | Process for the production of polyisocyanates with a biuret structure |
US3976622B1 (ja) | 1973-02-17 | 1984-03-27 | ||
JPS5747139B2 (ja) | 1973-05-08 | 1982-10-07 | ||
US4176132A (en) | 1977-03-01 | 1979-11-27 | Asahi Kasei Kogyo Kabushiki Kaisha | Reaction of organic diisocyanates with water |
US4324879A (en) | 1978-09-08 | 1982-04-13 | Bayer Aktiengesellschaft | Process for the preparation of polyisocyanates containing isocyanurate groups and the use thereof |
JPS6241496B2 (ja) | 1979-02-16 | 1987-09-03 | Asahi Chemical Ind | |
US4290969A (en) | 1980-08-14 | 1981-09-22 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for the continuous production of polyisocyanate |
US4412073A (en) | 1981-02-03 | 1983-10-25 | Rhone-Poulenc Specialites Chimiques | Isocyanurate preparation by catalytic, aminosilyl initiated cyclotrimerization of isocyanates |
US4983762A (en) | 1986-07-04 | 1991-01-08 | Rhone-Poulenc Chimie De Base | Preparation of biureto polyisocyanates |
JPS6357577A (ja) | 1986-08-29 | 1988-03-12 | Asahi Chem Ind Co Ltd | ポリイソシアネ−トの製造方法 |
US4837359A (en) | 1987-01-07 | 1989-06-06 | Bayer Aktiengesellschaft | Process for the production of polyisocyanates with biuret structures |
JPH023682A (ja) * | 1988-02-27 | 1990-01-09 | Bayer Ag | イソシアヌレート基含有ポリイソシアネートの製造方法およびそれらの使用 |
JPH02228317A (ja) | 1989-01-03 | 1990-09-11 | Bayer Ag | ウレツトジオン基及びイソシアヌレート基を含有する変性ポリイソシアネート並びに二成分系ポリウレタン被覆用組成物 |
JPH04226966A (ja) * | 1990-05-11 | 1992-08-17 | Bayer Ag | イソシアヌレートポリイソシアネートの製造方法、この方法により得られる化合物およびその使用 |
JPH04253951A (ja) * | 1991-02-05 | 1992-09-09 | Asahi Chem Ind Co Ltd | カルバミン酸エステルの熱分解方法 |
JPH07304724A (ja) | 1994-05-09 | 1995-11-21 | Bayer Ag | アロファネート基を含有する光安定性ポリイソシアネートの製造方法 |
US5641851A (en) | 1994-12-09 | 1997-06-24 | Basf Aktiengesellschaft | Preparation of biuret-containing polyisocyanates |
JPH08291129A (ja) | 1995-04-24 | 1996-11-05 | Nippon Polyurethane Ind Co Ltd | 着色の低減した有機イソシアネートの製造方法 |
JP2000119240A (ja) * | 1998-10-13 | 2000-04-25 | Nippon Polyurethane Ind Co Ltd | 多官能ポリイソシアネート組成物の製造方法 |
WO2009139061A1 (ja) * | 2008-05-15 | 2009-11-19 | 旭化成ケミカルズ株式会社 | 炭酸ジアリールを用いるイソシアネートの製造方法 |
JP2012506465A (ja) | 2008-10-22 | 2012-03-15 | ビーエーエスエフ ソシエタス・ヨーロピア | 無色なポリイソシアネートの製造方法 |
JP2012153708A (ja) * | 2009-08-21 | 2012-08-16 | Asahi Kasei Chemicals Corp | N−置換カルバミン酸エステルの製造方法、該n−置換カルバミン酸エステルを用いるイソシアネートの製造方法 |
WO2012046734A1 (ja) * | 2010-10-04 | 2012-04-12 | 旭化成ケミカルズ株式会社 | 分離方法及びイソシアネートの製造方法 |
Non-Patent Citations (2)
Title |
---|
"Chemistry Dictionary 7 pocket edition", 1 October 2003, KYORITSU SHUPPAN CO., LTD. |
"Organic Chemistry and Biochemistry Nomenclature, revised second edition", 1992, JAPAN, NANKODO CO., LTD. |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3564344A1 (en) * | 2012-11-20 | 2019-11-06 | Dow Global Technologies Llc | Distillable fuel markers |
US11118001B2 (en) | 2016-10-14 | 2021-09-14 | Asahi Kasei Kabushiki Kaisha | Isocyanate composition, method for producing isocyanate composition, and method for producing isocyanate polymer |
US11174337B2 (en) | 2016-10-14 | 2021-11-16 | Asahi Kasei Kabushiki Kaisha | Isocyanate composition, method for producing isocyanate polymer and isocyanate polymer |
US11548975B2 (en) | 2016-10-14 | 2023-01-10 | Asahi Kasei Kabushiki Kaisha | Isocyanate composition and method for producing isocyanate polymer |
WO2019131855A1 (ja) | 2017-12-27 | 2019-07-04 | 旭化成株式会社 | 有機アミンの回収方法 |
EP3872062A1 (en) | 2017-12-27 | 2021-09-01 | Asahi Kasei Kabushiki Kaisha | Organic amine collection method |
JP2022515701A (ja) * | 2018-10-31 | 2022-02-22 | ダウ グローバル テクノロジーズ エルエルシー | 有機溶液からモノイソシアネートを除去するための方法 |
JP7397865B2 (ja) | 2018-10-31 | 2023-12-13 | ダウ グローバル テクノロジーズ エルエルシー | 有機溶液からモノイソシアネートを除去するための方法 |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6475301B2 (ja) | ポリイソシアネート組成物及びイソシアネート重合体組成物 | |
JP6666459B2 (ja) | イソシアネート組成物、イソシアネート組成物の製造方法、及びイソシアネート重合体の製造方法 | |
JP7107986B2 (ja) | イソシアネート組成物及びイソシアネート重合体の製造方法 | |
JPH0834774A (ja) | ポリイソシアネート、その製造用のジイソシアネートおよびそれらの製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 13851480 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2014544598 Country of ref document: JP Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2881289 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 201590299 Country of ref document: EA Ref document number: 2013851480 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14425671 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 20157005771 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: IDP00201501427 Country of ref document: ID |
|
WWE | Wipo information: entry into national phase |
Ref document number: 122020002442 Country of ref document: BR |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112015006288 Country of ref document: BR |
|
ENP | Entry into the national phase |
Ref document number: 112015006288 Country of ref document: BR Kind code of ref document: A2 Effective date: 20150320 |