WO2014038896A1 - 열가소성 리그닌축중합체 및 이의 제조방법 - Google Patents

열가소성 리그닌축중합체 및 이의 제조방법 Download PDF

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Publication number
WO2014038896A1
WO2014038896A1 PCT/KR2013/008095 KR2013008095W WO2014038896A1 WO 2014038896 A1 WO2014038896 A1 WO 2014038896A1 KR 2013008095 W KR2013008095 W KR 2013008095W WO 2014038896 A1 WO2014038896 A1 WO 2014038896A1
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WO
WIPO (PCT)
Prior art keywords
lignin
condensation polymer
reaction
thermoplastic
acid
Prior art date
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Ceased
Application number
PCT/KR2013/008095
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English (en)
French (fr)
Korean (ko)
Inventor
남재도
김동관
남정훈
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Individual
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Application filed by Individual filed Critical Individual
Priority to US14/426,737 priority Critical patent/US9346904B2/en
Priority to CN201380058069.3A priority patent/CN104781310B/zh
Priority to JP2015531012A priority patent/JP6404818B2/ja
Priority to EP13835036.8A priority patent/EP2894187B1/en
Publication of WO2014038896A1 publication Critical patent/WO2014038896A1/ko
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G1/00—Lignin; Lignin derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/005—Lignin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/041—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/042—Graphene or derivatives, e.g. graphene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/70—Nanostructure
    • Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
    • Y10S977/742—Carbon nanotubes, CNTs

Definitions

  • Figure 4 is a photograph showing the appearance when the lignin condensation polymer obtained in a preferred embodiment of the present invention when heated to 200 °C.
  • Table 1 shows the schematic structure of the lignin molecule and the structural change with temperature change. Also shown is a schematic structure of the thermoplastic lignin condensation polymer according to the present invention.
  • the intermediate is prepared by reacting the lignin with a lactone-based compound, and the reactant having two or more acid reactors in dichloro acid, acid dianhydride and diacid.
  • the thermoplastic lignin condensation polymer may be prepared through an ester condensation reaction or a urethane reaction reaction with one or more reactants selected from the group having two or more isocyanate reactors. It demonstrates in order below.
  • thermoplastic lignin condensation polymer prepared in Example was prepared by the extrusion and injection process.
  • thermoplastic lignin condensation polymer was prepared by the extrusion and injection process, the mechanical properties were measured using the ASTM D638 method.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polyurethanes Or Polyureas (AREA)
PCT/KR2013/008095 2012-09-07 2013-09-06 열가소성 리그닌축중합체 및 이의 제조방법 Ceased WO2014038896A1 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US14/426,737 US9346904B2 (en) 2012-09-07 2013-09-06 Thermoplastic lignin condensation polymer, and preparation method therefor
CN201380058069.3A CN104781310B (zh) 2012-09-07 2013-09-06 一种热塑性木质素缩聚物及其制备方法
JP2015531012A JP6404818B2 (ja) 2012-09-07 2013-09-06 熱可塑性リグニン縮重合体及びその製造方法
EP13835036.8A EP2894187B1 (en) 2012-09-07 2013-09-06 Thermoplastic lignin condensation polymer, and preparation method therefor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020120099291A KR101336465B1 (ko) 2012-09-07 2012-09-07 열가소성 리그닌축중합체 및 이의 제조방법
KR10-2012-0099291 2012-09-07

Publications (1)

Publication Number Publication Date
WO2014038896A1 true WO2014038896A1 (ko) 2014-03-13

Family

ID=49987169

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2013/008095 Ceased WO2014038896A1 (ko) 2012-09-07 2013-09-06 열가소성 리그닌축중합체 및 이의 제조방법

Country Status (6)

Country Link
US (1) US9346904B2 (enExample)
EP (1) EP2894187B1 (enExample)
JP (1) JP6404818B2 (enExample)
KR (1) KR101336465B1 (enExample)
CN (1) CN104781310B (enExample)
WO (1) WO2014038896A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101616946B1 (ko) * 2013-11-28 2016-04-29 남재도 리그닌 고분자 나노복합재료 및 그 제조 방법
KR101701568B1 (ko) * 2014-11-13 2017-02-02 김동관 리그닌 함유 열가소성 수지 필름 및 이의 제조방법
KR101809327B1 (ko) * 2015-11-24 2017-12-14 주식회사 엔씨티 리그닌 기반 고분자 제조방법
JP6945295B2 (ja) * 2016-11-16 2021-10-06 旭有機材株式会社 摺動部材用成形材料、摺動部材及び製造方法
CN106750365A (zh) * 2017-01-20 2017-05-31 成都衔石科技有限公司 基于改善木质素口感的新型工艺
KR101889744B1 (ko) * 2017-07-04 2018-08-21 (주)폴리피아 리그닌-셀룰로오스-올레핀계 복합소재 조성물
CN109134883A (zh) * 2018-07-04 2019-01-04 北京林业大学 一种提高碱木质素熔融性能的制备方法及所得产物
KR102179075B1 (ko) 2019-07-23 2020-11-16 단국대학교 산학협력단 에폭시화 대두유로 개질된 리그닌의 제조 방법 및 개질된 리그닌을 포함하는 생분해성 고분자 복합재
KR102643510B1 (ko) 2021-06-01 2024-03-04 단국대학교 산학협력단 바이오매스 리그닌을 포함하는 폴리올레핀 발포체 제조용 수지 조성물 및 이를 이용한 친환경 폴리올레핀 발포체의 제조 방법
CN113771391A (zh) * 2021-11-01 2021-12-10 宁波嘉信化工实业有限公司 一种增强型低温热塑材料及其制备工艺
KR20230070095A (ko) 2021-11-12 2023-05-22 단국대학교 산학협력단 바이오매스 리그닌을 포함하는 폴리에스테르 수지 조성물 및 이를 이용하여 제조된 생분해성 수지 발포체

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR910018395A (ko) 1990-04-12 1991-11-30 에이. 디롱 에드워드 리그닌의 제조방법
JPH1129647A (ja) * 1991-11-15 1999-02-02 Nobuo Shiraishi リグノセルロース系発泡体の製造方法
JPH1171401A (ja) * 1997-08-28 1999-03-16 Agency Of Ind Science & Technol 生分解性高分子材料及びその製造方法
KR100242886B1 (ko) * 1992-12-31 2000-02-01 유현식 생분해성 환상에스테르계 고분자 그라프트 리그노셀루로오즈 유도체 및 그 제조방법
WO2012038259A1 (de) 2010-09-23 2012-03-29 Toho Tenax Europe Gmbh Thermoplastisches lignin zur herstellung von kohlenstofffasern
JP2012515241A (ja) * 2009-01-15 2012-07-05 トウホウ テナックス ユーロップ ゲゼルシャフト ミット ベシュレンクテル ハフツング リグニン誘導体、その誘導体を含む成形体、およびその成形体から製造される炭素繊維

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1278294C (en) 1987-09-17 1990-12-27 George S. Ritchie Method for fractionation of lignins from steam exploded lignocellulosics to provide fractions with different, but reproducible properties,and some methods for their interconversions and the products so produced
CN1340555A (zh) * 2000-09-01 2002-03-20 中国人民解放军国防科学技术大学 一种完全生物降解共聚物及其制备方法
JP2003113326A (ja) * 2001-10-04 2003-04-18 Sekisui Chem Co Ltd 生分解性樹脂組成物
BRPI0815822A2 (pt) * 2007-08-31 2017-05-16 Biojoule Ltd lignina e outros produtos a partir de material de planta, e métodos e composições para estes.
JP5184953B2 (ja) * 2008-04-22 2013-04-17 学校法人金井学園 生分解性に優れた熱プレス成形材料及びその製造方法、並びに熱プレス成形体
US8772406B2 (en) * 2009-08-06 2014-07-08 Robert J. Linhardt Synthetic wood composite
US8383784B2 (en) 2009-08-31 2013-02-26 Weyerhaeuser Nr Company Lignothermoplastic
JP5492746B2 (ja) * 2010-03-26 2014-05-14 キヤノン化成株式会社 電子写真装置用ブレード部材製造方法及び製造装置
WO2012018422A1 (en) * 2010-08-03 2012-02-09 Ferro Corporation Polymer composite foams

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR910018395A (ko) 1990-04-12 1991-11-30 에이. 디롱 에드워드 리그닌의 제조방법
JPH1129647A (ja) * 1991-11-15 1999-02-02 Nobuo Shiraishi リグノセルロース系発泡体の製造方法
KR100242886B1 (ko) * 1992-12-31 2000-02-01 유현식 생분해성 환상에스테르계 고분자 그라프트 리그노셀루로오즈 유도체 및 그 제조방법
JPH1171401A (ja) * 1997-08-28 1999-03-16 Agency Of Ind Science & Technol 生分解性高分子材料及びその製造方法
JP2012515241A (ja) * 2009-01-15 2012-07-05 トウホウ テナックス ユーロップ ゲゼルシャフト ミット ベシュレンクテル ハフツング リグニン誘導体、その誘導体を含む成形体、およびその成形体から製造される炭素繊維
WO2012038259A1 (de) 2010-09-23 2012-03-29 Toho Tenax Europe Gmbh Thermoplastisches lignin zur herstellung von kohlenstofffasern

Also Published As

Publication number Publication date
EP2894187A1 (en) 2015-07-15
EP2894187A4 (en) 2016-02-24
EP2894187B1 (en) 2020-05-06
US20150225498A1 (en) 2015-08-13
CN104781310B (zh) 2017-06-20
KR101336465B1 (ko) 2013-12-04
CN104781310A (zh) 2015-07-15
US9346904B2 (en) 2016-05-24
JP6404818B2 (ja) 2018-10-17
JP2015529265A (ja) 2015-10-05

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