WO2013167443A1 - Sensorelement mit cermet grundschicht und platin deckschicht - Google Patents
Sensorelement mit cermet grundschicht und platin deckschicht Download PDFInfo
- Publication number
- WO2013167443A1 WO2013167443A1 PCT/EP2013/059090 EP2013059090W WO2013167443A1 WO 2013167443 A1 WO2013167443 A1 WO 2013167443A1 EP 2013059090 W EP2013059090 W EP 2013059090W WO 2013167443 A1 WO2013167443 A1 WO 2013167443A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sensor element
- measuring electrode
- platinum
- ceramic
- base layer
- Prior art date
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229910052697 platinum Inorganic materials 0.000 title claims abstract description 19
- 239000011195 cermet Substances 0.000 title claims abstract description 13
- 239000000919 ceramic Substances 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 4
- 239000002245 particle Substances 0.000 claims description 7
- 239000004071 soot Substances 0.000 claims description 7
- 238000002485 combustion reaction Methods 0.000 claims description 3
- 239000004020 conductor Substances 0.000 description 5
- 239000000470 constituent Substances 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910016006 MoSi Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000002847 impedance measurement Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical group [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
- G01M15/00—Testing of engines
- G01M15/04—Testing internal-combustion engines
- G01M15/10—Testing internal-combustion engines by monitoring exhaust gases or combustion flame
- G01M15/102—Testing internal-combustion engines by monitoring exhaust gases or combustion flame by monitoring exhaust gases
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N15/00—Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
- G01N15/06—Investigating concentration of particle suspensions
- G01N15/0656—Investigating concentration of particle suspensions using electric, e.g. electrostatic methods or magnetic methods
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N15/00—Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
- G01N2015/0042—Investigating dispersion of solids
- G01N2015/0046—Investigating dispersion of solids in gas, e.g. smoke
Definitions
- the present invention relates to a sensor element for a sensor for detecting substances contained in a gas flow, in particular of soot particles in the exhaust gas of an internal combustion engine, with a support made of ceramic and an open-air gas jet arranged on the support. NEN measuring electrode.
- Such a sensor element is known and described for example in DE 10 2010 044 308 AI. It is used in particular as a soot sensor in the exhaust system of diesel engines.
- the measuring electrode By means of the measuring electrode, the proportion of soot particles contained in the exhaust gas flow is detected, for example via a resistance, capacitance or impedance measurement, and supplied in the form of electrical signals to a control device of the internal combustion engine.
- the measuring electrode is in this case designed as an open, exposed to the gas flow electrode and has, for example, the shape of an interdigital electrode (comb electrode). It consists of fine conductor tracks, which are applied to a carrier made of ceramic, in particular imprinted.
- the support is preferably formed as a plate-shaped elongated member and consists, as mentioned, of a ceramic material such as alumina.
- the conductor track structure of the measuring electrode is provided with corresponding conductor connections, which lead to corresponding connection contacts.
- Such sensor elements of Part. Kelsensoren are further provided with heating means to periodically clean the electrode exposed to the gas stream, on which the particles contained in the gas stream deposit with increasing measurement duration in an increasing manner. For this purpose, a heating takes place the measuring electrode and thereby a burning of the deposited particles, which are thereby removed from the measuring electrode.
- the present invention has for its object to provide a sensor element of the type described above, the measuring electrode is characterized by a particularly good adhesion to the carrier in avoiding unwanted deposits.
- the measuring electrode has a base layer arranged on the carrier, made of a ceramic-platinum cermet and a top layer of sintered platinum arranged on the base layer.
- the combination of cermet base layer and platinum top layer according to the invention achieves optimum adhesion to the ceramic carrier and deposit protection. It has been shown that the cermet layer has a very good adhesion to the ceramic carrier. However, since such a layer is also associated with a very high deposition tendency by exhaust particles (ash, sulfur, metal oxides, etc.), it is poorly suited as a cover layer or contact layer with the gas stream. Experiments have shown here that after about 2,000 hours of operation strong deposits have occurred.
- cover layer or contact layer is a layer of pure platinum. Such a layer has a good protection against unwanted deposits.
- Cermet or cermets are a group of materials of two separate phases (of a metallic and a ceramic component), which differ in certain properties, in particular hardness, melting point, from each other.
- An example of a ceramic-platinum cermet is a silicide-based one, such as a MoSi 2 -Pt cermet.
- the base layer is made of a ceramic-platinum printing paste.
- the measuring electrode is formed from a cermet base pressure and a platinum upper pressure.
- the measuring electrode is preferably produced by a combined printing technique, whereby an increase in the adhesion of the measuring electrode to the ceramic carrier and a minimization of undesired deposits on the measuring electrode are achieved.
- the sensor element designed according to the invention is used in particular in all sensors with open sensor contact materials, preferably in a soot sensor. dung.
- the measuring electrode is preferably designed as an interdigital electrode (comb electrode).
- the measuring electrode is designed to apply an alternating voltage. By applying an alternating voltage during operation of the measuring electrode, unwanted deposits can be further minimized.
- a glass-bound platinum paste can also be used as the base coat.
- FIG. 2 shows an enlarged partial section through the sensor element of FIG. 1.
- the measuring electrode 2 is formed as an open, the gas flow, for example, an exhaust system of a diesel engine, exposed electrode.
- the corresponding conductor tracks are applied to the carrier 5 shown in FIG. in the
- the measuring electrode 2 is made of a cermet basic pressure 6, which consists of a ceramic-platinum printing paste is manufactured, and a platinum-top pressure 7 together.
- the measuring electrode 2 is thus produced by a combined printing technique.
- the cermet base pressure increases the adhesion of the measuring electrode to the ceramic carrier, while the platinum top pressure minimizes unwanted deposits on the measuring electrode.
Landscapes
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pathology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Immunology (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Measuring Fluid Pressure (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13722336.8A EP2847571A1 (de) | 2012-05-09 | 2013-05-02 | Sensorelement mit cermet grundschicht und platin deckschicht |
JP2015510741A JP2015519558A (ja) | 2012-05-09 | 2013-05-02 | センサエレメントの製造方法 |
US14/399,768 US20150300919A1 (en) | 2012-05-09 | 2013-05-02 | Method for Producing a Sensor Element |
CN201380024331.2A CN104285141A (zh) | 2012-05-09 | 2013-05-02 | 带有金属陶瓷基层和铂覆盖层的传感元件 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012207761A DE102012207761A1 (de) | 2012-05-09 | 2012-05-09 | Sensorelement |
DE102012207761.8 | 2012-05-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013167443A1 true WO2013167443A1 (de) | 2013-11-14 |
Family
ID=48430697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2013/059090 WO2013167443A1 (de) | 2012-05-09 | 2013-05-02 | Sensorelement mit cermet grundschicht und platin deckschicht |
Country Status (6)
Country | Link |
---|---|
US (1) | US20150300919A1 (de) |
EP (1) | EP2847571A1 (de) |
JP (1) | JP2015519558A (de) |
CN (1) | CN104285141A (de) |
DE (1) | DE102012207761A1 (de) |
WO (1) | WO2013167443A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104285141A (zh) * | 2012-05-09 | 2015-01-14 | 大陆汽车有限责任公司 | 带有金属陶瓷基层和铂覆盖层的传感元件 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016101246A1 (de) | 2015-11-02 | 2017-05-04 | Epcos Ag | Sensoranordnung und Verfahren zur Herstellung einer Sensoranordnung |
US20180073973A1 (en) | 2016-09-12 | 2018-03-15 | Hyundai Motor Company | Particulate matters sensor device and manufacturing method of sensor unit provided in this |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2081908A (en) * | 1980-08-12 | 1982-02-24 | Nissan Motor | Method of producing solid electrolyte oxygen-sensing element of laminated structure with measuring electrode partially deposited from vapor phase |
EP0743431A2 (de) * | 1995-04-19 | 1996-11-20 | Ngk Insulators, Ltd. | Verfahren und Vorrichtung zum Feststellen der Verschlechterung eines Abgaskatalysators |
US5698267A (en) * | 1992-12-01 | 1997-12-16 | Robert Bosch Gmbh | Method for fabricating high-activity electrodes for exhaust gas sensors |
DE102005053120A1 (de) * | 2005-11-08 | 2007-05-10 | Robert Bosch Gmbh | Sensorelement für Gassensoren und Verfahren zum Betrieb desselben |
US20070234801A1 (en) * | 2003-07-25 | 2007-10-11 | Heribert Weber | Microstructured Chemical Sensor |
DE102007039567A1 (de) * | 2007-08-22 | 2009-02-26 | Robert Bosch Gmbh | Gassensor |
DE102010044308A1 (de) | 2010-09-03 | 2012-03-08 | Continental Automotive Gmbh | Sensorelement für einen Partikelsensor |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60108745A (ja) * | 1983-11-18 | 1985-06-14 | Ngk Insulators Ltd | 電気化学的装置 |
JPH01203964A (ja) * | 1988-02-10 | 1989-08-16 | Toyota Motor Corp | 酸素濃度センサ用電極の形成方法 |
DE4240267C2 (de) * | 1992-12-01 | 2003-03-20 | Bosch Gmbh Robert | Hochaktive Elektroden für Abgassensoren |
US6627259B1 (en) * | 1997-09-10 | 2003-09-30 | Oliver Jevons | Masking tapes and application methods |
US20030138845A1 (en) * | 2001-08-23 | 2003-07-24 | Changming Li | Protein and peptide sensors using electrical detection methods |
US6634210B1 (en) * | 2002-04-17 | 2003-10-21 | Delphi Technologies, Inc. | Particulate sensor system |
WO2006076607A1 (en) * | 2005-01-14 | 2006-07-20 | Cabot Corporation | Ink-jet printing of passive electricalcomponents |
JP2007121173A (ja) * | 2005-10-31 | 2007-05-17 | Denso Corp | ガスセンサ素子及びその製造方法 |
DE102006048354A1 (de) * | 2006-10-12 | 2008-04-17 | Robert Bosch Gmbh | Verfahren und Vorrichtung zur Bestimmung von Bestandteilen eines Gasgemisches |
US9140159B2 (en) * | 2007-09-18 | 2015-09-22 | Eugene V. Gonze | High exhaust temperature, zoned, electrically-heated particulate matter filter |
JP5051660B2 (ja) * | 2008-01-08 | 2012-10-17 | 日本特殊陶業株式会社 | ガスセンサ素子及びガスセンサ |
JP5115247B2 (ja) * | 2008-03-06 | 2013-01-09 | 株式会社デンソー | ガスセンサ素子 |
JP4512658B2 (ja) * | 2008-07-04 | 2010-07-28 | 日本碍子株式会社 | 粒子状物質検出装置 |
DE102008054617A1 (de) * | 2008-12-15 | 2010-06-17 | Robert Bosch Gmbh | Strukturierte Elektrode für keramische Sensorelemente |
DE102009000319A1 (de) * | 2009-01-20 | 2010-07-22 | Robert Bosch Gmbh | Teilchensensor |
JP2011080781A (ja) * | 2009-10-05 | 2011-04-21 | Nippon Soken Inc | パティキュレート検出素子及びこれを用いたパティキュレート検出センサ |
DE102012207761A1 (de) * | 2012-05-09 | 2013-11-14 | Continental Automotive Gmbh | Sensorelement |
-
2012
- 2012-05-09 DE DE102012207761A patent/DE102012207761A1/de not_active Withdrawn
-
2013
- 2013-05-02 CN CN201380024331.2A patent/CN104285141A/zh active Pending
- 2013-05-02 WO PCT/EP2013/059090 patent/WO2013167443A1/de active Application Filing
- 2013-05-02 JP JP2015510741A patent/JP2015519558A/ja active Pending
- 2013-05-02 EP EP13722336.8A patent/EP2847571A1/de not_active Withdrawn
- 2013-05-02 US US14/399,768 patent/US20150300919A1/en not_active Abandoned
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2081908A (en) * | 1980-08-12 | 1982-02-24 | Nissan Motor | Method of producing solid electrolyte oxygen-sensing element of laminated structure with measuring electrode partially deposited from vapor phase |
US5698267A (en) * | 1992-12-01 | 1997-12-16 | Robert Bosch Gmbh | Method for fabricating high-activity electrodes for exhaust gas sensors |
EP0743431A2 (de) * | 1995-04-19 | 1996-11-20 | Ngk Insulators, Ltd. | Verfahren und Vorrichtung zum Feststellen der Verschlechterung eines Abgaskatalysators |
US20070234801A1 (en) * | 2003-07-25 | 2007-10-11 | Heribert Weber | Microstructured Chemical Sensor |
DE102005053120A1 (de) * | 2005-11-08 | 2007-05-10 | Robert Bosch Gmbh | Sensorelement für Gassensoren und Verfahren zum Betrieb desselben |
DE102007039567A1 (de) * | 2007-08-22 | 2009-02-26 | Robert Bosch Gmbh | Gassensor |
DE102010044308A1 (de) | 2010-09-03 | 2012-03-08 | Continental Automotive Gmbh | Sensorelement für einen Partikelsensor |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104285141A (zh) * | 2012-05-09 | 2015-01-14 | 大陆汽车有限责任公司 | 带有金属陶瓷基层和铂覆盖层的传感元件 |
Also Published As
Publication number | Publication date |
---|---|
EP2847571A1 (de) | 2015-03-18 |
CN104285141A (zh) | 2015-01-14 |
US20150300919A1 (en) | 2015-10-22 |
JP2015519558A (ja) | 2015-07-09 |
DE102012207761A1 (de) | 2013-11-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1896838B1 (de) | SENSOR UND BETRIEBSVERFAHREN ZUR DETEKTION VON RUß | |
EP1623217B1 (de) | Sensor zur detektion von teilchen | |
DE10011562C2 (de) | Gassensor | |
DE2836002A1 (de) | Sensor zur ueberwachung der russfreiheit von abgasen | |
EP2130025A2 (de) | Sensorelement zur bestimmung von partikeln in einem messgas | |
WO2006027287A1 (de) | Sensorelement für partikelsensoren und verfahren zur herstellung desselben | |
WO2006094923A1 (de) | Sensorelement und sensor dieses enthaltend | |
WO2013167443A1 (de) | Sensorelement mit cermet grundschicht und platin deckschicht | |
WO2008025602A1 (de) | Sensor zur resistiven bestimmung von konzentrationen leitfähiger partikel in gasgemischen | |
DE10220783B4 (de) | Meßfühler | |
DE102006032741B4 (de) | Sensorelement für einen Partikelsensor | |
DE102007021910A1 (de) | Sensor zur Detektion von Teilchen in einem Gasstrom | |
DE102007046099A1 (de) | Sensorelement zur Detektion von Partikeln in einem Gasstrom und Verfahren zur Bestimmung und Kompensation des Nebenschlusswiderstands von Sensorelementen | |
DE102006002111A1 (de) | Sensorelement für Partikelsensoren und Verfahren zum Betrieb desselben | |
DE102010044308A1 (de) | Sensorelement für einen Partikelsensor | |
DE102018115623A1 (de) | Verfahren zur Messung von Stickoxiden und Vorrichtung zur Durchführung des Verfahrens | |
DE102006032549A1 (de) | Sensorelement eines Gassensors | |
EP3140632B1 (de) | Sensor zur detektion von teilchen | |
DE102017217637A1 (de) | Keramisches Sensorelement für einen Abgassensor | |
WO2020200542A1 (de) | Gassensor zur erfassung mindestens einer eigenschaft eines gases | |
EP3513166B1 (de) | Sensorelement zur erfassung von partikeln eines messgases in einem messgasraum | |
DE19901956C2 (de) | Sensor zur Analyse von Gasen | |
DE102016221372A1 (de) | Sensorelement zur Bestimmung von Partikeln in einem fluiden Medium | |
DE102018209907A1 (de) | Resistiver Partikelsensor | |
DE10117189A1 (de) | Sensoranordnung zur Indikation und/oder Bestimmung der Konzentration von gasförmigen Bestandteilen in einem Messgasgemisch und Verfahren |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 13722336 Country of ref document: EP Kind code of ref document: A1 |
|
DPE1 | Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101) | ||
REEP | Request for entry into the european phase |
Ref document number: 2013722336 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2013722336 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2015510741 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14399768 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |