WO2013022206A3 - 가교 폴리에틸렌 조성물 - Google Patents

가교 폴리에틸렌 조성물 Download PDF

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Publication number
WO2013022206A3
WO2013022206A3 PCT/KR2012/006084 KR2012006084W WO2013022206A3 WO 2013022206 A3 WO2013022206 A3 WO 2013022206A3 KR 2012006084 W KR2012006084 W KR 2012006084W WO 2013022206 A3 WO2013022206 A3 WO 2013022206A3
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Prior art keywords
weight parts
polyethylene composition
crosslinked polyethylene
achieving superior
water
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PCT/KR2012/006084
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English (en)
French (fr)
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WO2013022206A2 (ko
Inventor
선가람
박인규
남윤선
송영일
도상록
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(주) 엘지화학
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Priority to NO12821652A priority Critical patent/NO2743306T3/no
Priority to US14/124,300 priority patent/US9589700B2/en
Priority to CN201280036206.9A priority patent/CN103732677B/zh
Priority to EP12821652.0A priority patent/EP2743306B1/en
Priority to JP2014514824A priority patent/JP2014516118A/ja
Publication of WO2013022206A2 publication Critical patent/WO2013022206A2/ko
Publication of WO2013022206A3 publication Critical patent/WO2013022206A3/ko

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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/2813Protection against damage caused by electrical, chemical or water tree deterioration
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K5/13Phenols; Phenolates
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    • C08K5/00Use of organic ingredients
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    • C08K5/1345Carboxylic esters of phenolcarboxylic acids
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
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    • C08K5/375Thiols containing six-membered aromatic rings
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

본 발명은 (A) 폴리에틸렌 베이스 수지 100중량부에 대하여 (B) 힌더드 페놀계 산화방지제 0.1 내지 0.6중량부; (C) 가교제 1 내지 4중량부; (D) 산화마그네슘 0.2 내지 1.9중량부; 및 (E) 스코치 억제제 0.1 내지 1.0중량부를 포함함으로써 전력 케이블 절연체가 외부 수분과 전기장에 노출되어 발생하는 수트리에 대한 내성이 우수할 뿐만 아니라, 우수한 전기 절연특성을 가질 수 있는 효과가 있다.
PCT/KR2012/006084 2011-08-08 2012-07-31 가교 폴리에틸렌 조성물 WO2013022206A2 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
NO12821652A NO2743306T3 (ko) 2011-08-08 2012-07-31
US14/124,300 US9589700B2 (en) 2011-08-08 2012-07-31 Cross-linked polyethylene compositions
CN201280036206.9A CN103732677B (zh) 2011-08-08 2012-07-31 交联聚乙烯组合物
EP12821652.0A EP2743306B1 (en) 2011-08-08 2012-07-31 Crosslinked polyethylene composition
JP2014514824A JP2014516118A (ja) 2011-08-08 2012-07-31 架橋ポリエチレン組成物

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2011-0078715 2011-08-08
KR20110078715 2011-08-08
KR1020120081616A KR101362560B1 (ko) 2011-08-08 2012-07-26 가교 폴리에틸렌 조성물
KR10-2012-0081616 2012-07-26

Publications (2)

Publication Number Publication Date
WO2013022206A2 WO2013022206A2 (ko) 2013-02-14
WO2013022206A3 true WO2013022206A3 (ko) 2013-04-04

Family

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PCT/KR2012/006084 WO2013022206A2 (ko) 2011-08-08 2012-07-31 가교 폴리에틸렌 조성물

Country Status (7)

Country Link
US (1) US9589700B2 (ko)
EP (1) EP2743306B1 (ko)
JP (1) JP2014516118A (ko)
KR (2) KR101362560B1 (ko)
CN (1) CN103732677B (ko)
NO (1) NO2743306T3 (ko)
WO (1) WO2013022206A2 (ko)

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KR101362560B1 (ko) * 2011-08-08 2014-02-14 주식회사 엘지화학 가교 폴리에틸렌 조성물
EP3083796B1 (en) 2013-12-19 2019-05-22 Borealis AG A new crosslinked polymer composition, power cable insulation and power cable
WO2015090639A1 (en) 2013-12-19 2015-06-25 Borealis Ag A new polymer composition, power cable insulation and power cable
US11355260B2 (en) 2013-12-19 2022-06-07 Borealis Ag Low MFR polymer composition, power cable insulation and power cable
KR101644246B1 (ko) 2014-11-19 2016-08-01 주식회사 엘지화학 가교 폴리에틸렌 수지 조성물
CN108028098A (zh) * 2015-08-10 2018-05-11 住友电气工业株式会社 直流电缆、组合物以及直流电缆的制造方法
KR102178359B1 (ko) * 2016-11-10 2020-11-12 주식회사 엘지화학 가교 폴리에틸렌 조성물
CA3043252A1 (en) * 2016-11-16 2018-05-24 Dow Global Technologies Llc Composition with balance of dissipation factor and additive acceptance
CA3073767A1 (en) * 2017-08-29 2019-03-07 Dow Global Technologies Llc Polyethylene composition with treeing retardants
CN107828116B (zh) * 2017-12-07 2021-02-05 江苏德威新材料股份有限公司 ±500kV直流电缆用抗焦烧绝缘材料及其制备方法
WO2019178747A1 (en) * 2018-03-20 2019-09-26 Dow Global Technologies Llc Polyolefin-and-polyvinylpyrrolidone formulation
CN108610535B (zh) * 2018-03-30 2020-11-06 东南大学 一种耐超高压直流用交联聚乙烯复合材料及其制备方法
EP3814419A4 (en) 2018-06-29 2022-01-19 Dow Global Technologies LLC POLYOLEFIN FORMULATION WITH POLY(2-ALKYL-2-OXAZOLINE )
CN109251392A (zh) * 2018-08-14 2019-01-22 重庆瑞普电气实业股份有限公司 一种抗水树中压交联电缆
CA3150923A1 (en) * 2019-08-16 2021-02-25 Exxonmobil Upstream Research Company Methods of manufacturing highly crosslinked polymer particulate

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4900792A (en) * 1983-06-13 1990-02-13 Allied-Signal Inc. Crosslinkable polyethylene composition
KR20020079525A (ko) * 2001-04-10 2002-10-19 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 안정화된 중압 및 고압 케이블 절연 조성물
KR100718022B1 (ko) * 2006-04-25 2007-05-14 한화석유화학 주식회사 트리 내성 가교 폴리올레핀 조성물
WO2011057927A1 (en) * 2009-11-11 2011-05-19 Borealis Ag A polymer composition and a power cable comprising the polymer composition

Also Published As

Publication number Publication date
EP2743306B1 (en) 2018-01-24
US20140113133A1 (en) 2014-04-24
KR101447778B1 (ko) 2014-10-08
EP2743306A4 (en) 2015-03-25
WO2013022206A2 (ko) 2013-02-14
KR20130020741A (ko) 2013-02-27
JP2014516118A (ja) 2014-07-07
NO2743306T3 (ko) 2018-06-23
KR101362560B1 (ko) 2014-02-14
EP2743306A2 (en) 2014-06-18
CN103732677A (zh) 2014-04-16
KR20130028646A (ko) 2013-03-19
CN103732677B (zh) 2017-05-03
US9589700B2 (en) 2017-03-07

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