WO2013018322A1 - 燃料電池セパレータ用ステンレス鋼 - Google Patents
燃料電池セパレータ用ステンレス鋼 Download PDFInfo
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- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
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- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
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- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
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- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
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- C23G1/08—Iron or steel
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- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y10T428/00—Stock material or miscellaneous articles
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- Y10T428/12993—Surface feature [e.g., rough, mirror]
Definitions
- the present invention relates to a stainless steel for fuel cell separators having excellent corrosion resistance and excellent contact electrical resistance characteristics, as well as stainless steel for fuel cell separators.
- This fuel cell reacts hydrogen and oxygen (reaction (of hydrogen with oxygen) to generate electricity, and its basic structure has a sandwich-like structure (a sandwich structure), and an electrolyte membrane ( an electrolyte membrane, ion-exchange membrane, two electrodes (a fuel electrode and an air electrode), hydrogen and oxygen (air) diffusion layer, and two separators (separators).
- an electrolyte membrane an electrolyte membrane, ion-exchange membrane, two electrodes (a fuel electrode and an air electrode), hydrogen and oxygen (air) diffusion layer, and two separators (separators).
- phosphoric acid form phosphoric acid fuel cell
- molten carbonate form molten sodium carbonate fuel cell
- solid oxide form solid oxide fuel cell
- alkaline form alkaline fuel cell
- solid Polymer type solid-polymer fuel-cell
- the polymer electrolyte fuel cell is (1) the operating temperature is about 80 ° C. is much lower than the molten carbonate type and phosphoric acid type fuel cells, etc. It has features such as light weight and small size, (3) quick start-up (a short transient time), fuel efficiency (fuel efficiency), and high output density (output density). For this reason, polymer electrolyte fuel cells are attracting the most attention today for use as electric power sources for electric vehicles (vehicles) and small distributed power sources (compacts, distributed power sources, for homes). Is one of the fuel cells.
- the polymer electrolyte fuel cell is based on the principle of extracting electricity from hydrogen and oxygen through a polymer membrane, and the structure is shown in Fig. 1 (b).
- MEA 10Membrane-Electrode Assembly, thickness 10 to several 100 ⁇ m
- the gas diffusion layer is often integrated with the MEA.
- Several tens to hundreds of single cells are connected in series to form a fuel cell stack (form a fuel cell stack).
- the separator has (1) conductors that carry generated electrons (conductors carrying electrons generated), (2) oxygen (air) and hydrogen channels ( channels for oxy (air) and hydrogen) (air channel 6 and hydrogen channel 7 in Fig. 1 respectively) and (3) generated water and exhaust gas discharge channels (channels for water and exhaust gas) (Fig. 1 respectively) Functions as the air flow path 6 and the hydrogen flow path 7) are required.
- Patent Document 1 discloses a technique in which a metal that easily forms a passive film is used as a separator.
- a metal that easily forms a passive film causes an increase in contact resistance, leading to a decrease in power generation efficiency.
- these metal materials have problems to be improved such as a contact resistance larger than that of the carbon material and inferior in corrosion resistance.
- Patent Document 2 discloses a technique for reducing contact resistance and ensuring high output by applying gold plating to the surface of a metal separator such as SUS304 (a metallic separator plated with gold). It is disclosed. However, it is difficult to prevent the occurrence of pinholes with thin gold plating, and conversely, thick gold plating costs high.
- Patent Document 3 discloses a method for obtaining a separator having improved electrical conductivity by dispersing carbon powders in a ferritic stainless steel substrate.
- the surface treatment of the separator requires a considerable cost.
- the separator subjected to the surface treatment has a problem that the corrosion resistance (corrosion resistance) is remarkably lowered when scratches or the like are generated during assembly.
- the present invention has been made in view of such circumstances, and an object thereof is to provide a stainless steel for a fuel cell separator excellent in contact resistance characteristics and practicality.
- the present inventors diligently studied to improve the contact resistance characteristics in the stainless steel for fuel cell separators. As a result, it has been found that the contact resistance characteristics are improved by controlling the fine surface shape. It has also been found that it is preferable to control the component composition from the standpoint of securing practical corrosion resistance and mechanical properties as stainless steel and cost.
- the present invention is based on the above findings, and features are as follows.
- Stainless steel for fuel cell separators characterized by a surface modulus of 1.02 or more when measured.
- the surface area ratio is the area ratio of the surface with irregularities to the area of the completely smooth surface.
- the stainless steel further contains, in mass%, C: 0.03% or less, Si: 1.0% or less, Mn: 1.0% or less, S: 0.01% or less, P: Contains 0.05% or less, Al: 0.20% or less, N: 0.03% or less, Cr: 16-40%, Ni: 20% or less, Cu: 0.6% or less, Mo: 2.5% or less, and the balance Is a stainless steel for fuel cell separators, characterized by comprising Fe and inevitable impurities.
- the fuel according to any one of [1] to [3], wherein the stainless steel further contains 1.0% or less in total of at least one of Nb, Ti, and Zr by mass%. Stainless steel for battery separator.
- a stainless steel for a fuel cell separator having stable contact resistance characteristics and excellent practicality can be obtained.
- an inexpensive fuel cell can be provided and the spread of the fuel cell can be promoted.
- the stainless steel used as a material is not particularly limited in the steel type or the like as long as it has the corrosion resistance required under the operating environment of the fuel cell.
- it is necessary to contain 16% by mass or more of Cr.
- the Cr content is less than 16% by mass, the separator cannot be used for a long time.
- it is 18 mass% or more.
- the Cr content exceeds 40% by mass, the toughness may decrease due to precipitation of the ⁇ phase, and therefore the Cr content is preferably 40% by mass or less.
- C 0.03% or less C reacts with Cr in the stainless steel, and precipitates as Cr carbide in the grain boundary (precipitate chromium carbonitride in the grain boundary), resulting in a decrease in corrosion resistance. Therefore, the smaller the C content, the better. If C is 0.03% or less, the corrosion resistance is not significantly reduced. More preferably, it is 0.015% or less.
- Si 1.0% or less Si is an effective element for deoxidation, and is added at the melting stage of stainless steel. However, if excessively contained, the stainless steel becomes hardened (decrease ductility), so when Si is added, 1.0% or less is preferable. More preferably, it is 0.01% or more and 0.6% or less.
- Mn 1.0% or less Mn combines with inevitably mixed S, has the effect of reducing S dissolved in stainless steel, suppresses segregation of sulfur at the grain boundary, and performs hot rolling. It is an effective element for preventing cracking of the steel sheet during hot rolling. However, even if added over 1.0%, there is almost no increase in the effect of addition. On the other hand, an excessive addition causes an increase in cost. Therefore, when it contains Mn, 1.0% or less is preferable.
- S 0.01% or less S is an element that lowers the corrosion resistance by binding to Mn to form MnS, and is preferably lower. If it is 0.01% or less, the corrosion resistance will not be significantly reduced. Therefore, when it contains S, 0.01% or less is preferable.
- P 0.05% or less P lowers the ductility because it lowers the ductility. However, if it is 0.05% or less, the ductility is not significantly reduced. Therefore, when it contains P, 0.05% or less is preferable.
- Al 0.20% or less
- Al is an element used as a deoxidizing element.
- ductility will fall. Therefore, when it contains Al, 0.20% or less is preferable.
- N 0.03% or less N is an element effective for suppressing local corrosion such as crevice corrosion of stainless steel. However, if added over 0.03%, it takes a long time to add N in the melting stage of the stainless steel, resulting in a decrease in productivity and a decrease in the formability of the steel. Therefore, when adding N, 0.03% or less is preferable.
- Ni 20% or less
- Cu 0.6% or less
- Mo 2.5% or less
- Ni 20% or less
- Ni is an element that stabilizes the austenitic phase, and is added when producing austenitic stainless steel. At this time, if the Ni content exceeds 20%, excessive consumption of Ni causes an increase in cost. Therefore, the Ni content is preferably 20% or less.
- Cu: 0.6% or less Cu is an element effective for improving the corrosion resistance of stainless steel. However, if added over 0.6%, hot workability deteriorates, leading to a decrease in productivity, and adding Cu excessively increases the cost. Therefore, when adding Cu, 0.6% or less is preferable.
- Mo 2.5% or less Mo is an element effective in suppressing crevice corrosion of stainless steel. However, if added over 2.5%, the stainless steel becomes extremely brittle and productivity is lowered, and excessive consumption of Mo leads to an increase in cost. Therefore, when adding Mo, 2.5% or less is preferable.
- one or more of Nb, Ti, and Zr can be added to improve intergranular corrosion resistance in addition to the elements described above. However, if the total exceeds 1.0%, the ductility is reduced. Moreover, in order to avoid the cost increase by element addition, when adding, it is preferable that Ti, Nb, and Zr are 1.0% or less in total.
- the balance is Fe and inevitable impurities.
- the stainless steel of the present invention has a surface area ratio of 1.02 or more when the surface shape is measured with a scanning electron microscope with a spatial resolution of 0.1 ⁇ m or less. Preferably it is 1.04 or more.
- FIG. 2 is a scanning electron microscope image showing the result of observing fine surface shapes of steel plate A and steel plate B with a high magnification of 10,000 times or more and 1 ⁇ m or less with a scanning electron microscope.
- Steel A is a ferritic material
- steel B is an example of an austenitic material.
- Both Steel A and Steel B are hot-rolled and then annealed at a temperature of 800 to 1100 ° C., and then cold-rolled and annealed repeatedly to obtain stainless steel.
- the condition before the treatment is as annealed, and the condition after the treatment is after annealing, electrolytic treatment in a 55 ° C. 3% sulfuric acid solution, and immersion treatment in the hydrofluoric acid solution. From FIG.
- both the steel A and the steel B have much finer surface irregularities after the treatment than before the treatment.
- the surface contact resistance of steel A and steel B before and after treatment was measured. Both steel A and B were 100 m ⁇ ⁇ cm 2 or more before treatment, but both were 10 m ⁇ ⁇ cm after treatment. 2 was below.
- the contact resistance is a resistance value when a carbon paper CP120 manufactured by Toray Industries, Inc. is used, the carbon paper CP120 is brought into contact with the steels A and B, and a load of 20 kGf / cm 2 is applied.
- the surface area ratio was determined using a three-dimensional SEM equipped with a field-emission electron gun.
- the surface area ratio is the ratio of the surface area with irregularities to the area of a completely smooth surface, and was determined as follows. Acquisition of SEM data was performed at an acceleration voltage of 5 kV on the surface where Au was vapor-deposited on the surface.
- the surface area ratio was obtained from the average of three or more visual fields measured in a 20,000-times field of view so as not to be affected by the grain boundaries.
- the surface area ratios of Steel A and Steel B before and after treatment were 1.01 to 1.05.
- FIG. 3 shows surface SEM images of carbon paper and carbon cloth, which are carbon materials.
- the contact with the stainless steel plate is a dispersed carbon fiber having a diameter of about 10 microns. In order to ensure the conductivity of the contact portion, it is necessary to apply pressure at the contact point.
- FIG. 3 shows that the contact resistance is 10 m ⁇ ⁇ cm 2 or less when the surface area ratio is 1.02 or more. In addition, when the surface area ratio is 1.04 or more, a result of lower contact resistance is obtained.
- the surface area ratio is 1.02 or more, preferably 1.04 or more.
- the surface area ratio is within the range of the present invention by controlling the processing conditions such as changing the processing time and the temperature of the processing solution when immersed in the acidic solution after electrolytic treatment in the acidic solution after annealing. be able to. It is advantageous to increase the surface area by setting the temperature higher and increasing the time.
- the measurement of the surface area ratio is not particularly limited.
- the surface area ratio can be obtained using a three-dimensional SEM equipped with a field emission electron gun.
- a field emission electron gun For example, an atomic force microscope or the like may be used.
- the contact type roughness meter since the tip diameter of the stylus is on the order of microns, it is impossible to perform such unevenness evaluation. It is also possible to evaluate with a cross-sectional TEM (transmissiontranselectron microscope).
- 3D SEM is considered the most suitable for evaluating many fields of view and obtaining representativeness.
- a slab adjusted to a suitable component composition is heated to a temperature of 1100 ° C or higher, hot-rolled, and then annealed at a temperature of 800-1100 ° C, followed by cold rolling and annealing. Repeat to make stainless steel.
- the thickness of the obtained stainless steel plate is preferably about 0.02 to 0.8 mm.
- the electrolytic treatment was performed in the bath shown in Table 2, the solution temperature was 55 ° C., the current density was 2 A / dm 2 , the treatment time was 30 seconds, and the pickling was performed in the solutions shown in Table 2, and the solution temperature was The treatment time was 55 seconds at 30 ° C.
- the acid treatment was performed for 120 seconds at the solution and bath temperature shown in Table 2.
- the contact resistance was measured and the shape was measured by 3D-SEM to evaluate the surface area ratio.
- the contact resistance was measured by using a carbon paper CP120 manufactured by Toray Industries, Inc., contacting the carbon paper CP120 and steels A and B, and applying a load of 20 kGf / cm 2 .
- ERA-8800FE made by Elionix at an acceleration voltage of 5 kV.
- Elionix's ERA-8800FE is equipped with four secondary electron detectors facing the sample direction, an image that emphasizes the difference in composition from the sum and difference signals of secondary electrons, and an image that reflects irregularities in a specific direction. It is a device that can display.
- the measurement was performed by setting pixels in an area of 6 ⁇ m ⁇ 4.5 ⁇ m at intervals of 0.01 ⁇ m, and the image processing was performed by performing a 1 / 2 ⁇ second-order Gaussian high-pass filter process. In addition, at least 5 visual fields or more were observed for each sample, and the average was obtained. Furthermore, since the effect of the level difference is large in the image straddling the grain boundary, it was calculated using the data in the grain. The results obtained as described above are shown in Table 3.
- the contact resistance is 10 m ⁇ ⁇ cm 2 or less in the present invention example having a surface area ratio of 1.02 or more. Furthermore, when the surface area ratio is 1.04 or more, there are many cases where the contact resistance is 8 m ⁇ ⁇ cm 2 or less, and it can be seen that the contact resistance characteristics are further excellent.
- Example 1 steel numbers 2 and 3 in Table 1 were used.
- electrolytic treatment was performed in a 3% sulfuric acid solution.
- the solution temperature was 55 ° C.
- the current density was 2 A / dm 2
- the treatment time was 30 seconds.
- Acid dipping as an acid treatment was performed with a mixed solution of 5% hydrofluoric acid and 1% nitric acid for Steel 2 and 5% hydrofluoric acid solution for Steel 3.
- the temperature of the acid solution was 55 ° C.
- the immersion time was 40 to 120 seconds.
- a sample not immersed in acid was also prepared.
- the surface of the obtained sample was subjected to contact resistance measurement, shape measurement by 3D-SEM, and surface area evaluation.
Abstract
Description
[1]Crを16質量%(mass%)以上含有するステンレス鋼であって、該ステンレス鋼の表面を走査型電子顕微鏡(scanning electron microscope)により0.1μm以下の空間分解能(spatial resolution)で表面形状測定をした場合に、表面積率(surface modulus)が1.02以上であることを特徴とする燃料電池セパレータ用ステンレス鋼。ここで、表面積率とは、完全に平滑な表面の面積に対して凹凸がある表面の面積比である。
[2]前記[1]において、前記表面積率が1.04以上であることを特徴とする燃料電池セパレータ用ステンレス鋼。
[3]前記[1]または[2]において、前記ステンレス鋼が、さらに、質量%で、C:0.03%以下、Si:1.0%以下、Mn:1.0%以下、S:0.01%以下、P:0.05%以下、Al:0.20%以下、N:0.03%以下、Cr:16~40%を含み、Ni:20%以下、Cu:0.6%以下、Mo:2.5%以下の一種以上を含有し、残部がFe および不可避的不純物からなることを特徴とする燃料電池セパレータ用ステンレス鋼。
[4]前記[1]~[3]のいずれかにおいて、前記ステンレス鋼が、さらに、質量%で、Nb、Ti、Zrの一種以上を合計で1.0%以下を含有することを特徴とする燃料電池セパレータ用ステンレス鋼。
従来の高価なカーボンや金めっきに代わり、本発明のステンレス鋼をセパレータとして用いることで、安価な燃料電池を提供でき、燃料電池の普及を促進させることが可能となる。
Cは、ステンレス鋼中のCrと反応し、粒界にCr炭化物として析出(precipitate chromium carbonitride in the grain boundary)するため、耐食性の低下をもたらす。したがって、Cの含有量は少ないほど好ましく、Cが0.03%以下であれば、耐食性を著しく低下させることはない。さらに好ましくは 0.015%以下である。
Siは、脱酸のために有効な元素であり、ステンレス鋼の溶製段階で添加される。しかし過剰に含有させるとステンレス鋼が硬質化(causes hardening of the stainless steel sheet)し、延性が低下する(decrease ductility)ので、Siを添加する場合は、 1.0%以下が好ましい。さらに好ましくは、0.01%以上0.6%以下である。
Mnは、不可避的に混入したSと結合し、ステンレス鋼に固溶したSを低減する効果を有し、Sの粒界偏析を抑制(suppresses segregation of sulfur at the grain boundary)し、熱間圧延時の割れを防止する(prevents cracking of the steel sheet during hot rolling)のに有効な元素である。しかし、1.0%を超えて添加しても添加する効果の増加はほとんどない。かえって、過剰に添加することによってコストの上昇を招く。よって、Mnを含有する場合は1.0%以下が好ましい。
SはMnと結合しMnSを形成することで耐食性を低下させる元素であり低い方が好ましい。0.01%以下であれば耐食性を著しく低下させることはない。よって、Sを含有する場合は0.01%以下が好ましい。
Pは延性の低下をもたらすため、低いほうが望ましいが、0.05%以下であれば延性を著しく低下させることはない。よって、Pを含有する場合は0.05%以下が好ましい。
Alは、脱酸元素として用いられる元素である。一方で、過剰に含有すると延性の低下をもたらす。よって、Alを含有する場合は0.20%以下が好ましい。
Nは、ステンレス鋼の隙間腐食等の局部腐食を抑制するのに有効な元素である。しかし、 0.03%を超えて添加すると、ステンレス鋼の溶製段階でNを添加するために長時間を要するので生産性の低下を招くとともに、鋼の成形性が低下する。したがってNを添加する場合は、 0.03%以下が好ましい。
Ni:20%以下
Niは、オーステナイト相を安定化させる元素であり、オーステナイト系ステンレスを製造する場合に添加する。その際、Ni含有量が20%を超えると、Niを過剰に消費することによってコストの上昇を招く。したがってNi含有量は、20%以下が好ましい。
Cu:0.6%以下
Cuは、ステンレス鋼の耐食性を改善するのに有効な元素である。しかし、0.6%を超えて添加すると、熱間加工性が劣化し、生産性の低下を招くばかりでなく、Cuを過剰に添加することによってコストの上昇を招く。したがってCuを添加する場合は、0.6%以下が好ましい。
Mo:2.5%以下
Moは、ステンレス鋼の隙間腐食(crevice corrosion)を抑制するのに有効な元素である。しかし、2.5%を超えて添加すると、ステンレス鋼が著しく脆化して生産性が低下するとともに、Moを過剰に消費することによってコストの上昇を招く。したがってMoを添加する場合は、2.5%以下が好ましい。
本発明では、上記した元素の他に、耐粒界腐食性向上のためにNb、Ti、Zrの一種以上を添加することができる。しかし、合計で1.0%を超えると延性の低下を招く。また、元素添加によるコスト上昇を避けるため、添加する場合は、Ti、Nb、Zrを合計で 1.0%以下が好ましい。
本発明のステンレス鋼は、表面を走査型電子顕微鏡により0.1μm以下の空間分解能で表面形状測定をした場合に、表面積率が1.02以上である。好適には 1.04以上である。
図2より、鋼A、鋼Bのいずれも、処理前に比べ処理後は表面の微細凹凸が格段に細かく、多くなっていることがわかる。
また、鋼A、鋼Bの処理前および処理後の表面の接触抵抗を測定したところ、処理前には鋼A、Bともに100mΩ・cm2以上であったが、両者ともに処理後は10mΩ・cm2を以下となっていた。なお、上記接触抵抗とは東レ(株)製のカーボンペーパーCP120を用い、前記カーボンペーパーCP120と鋼A、Bを接触させて、20kGf/cm2の荷重を付加したときの抵抗値である。
以上の結果、鋼A、鋼Bの処理前および処理後の表面積率は1.01~1.05であった。また、図3に示すように表面積率が大きい方が接触抵抗は小さい傾向にあることがわかった。このような傾向となった理由は以下のように考えられる。図4はカーボン素材であるカーボンペーパー及びカーボンクロスの表面SEM像を示したものである。ステンレス鋼板との接触は分散した直径約10ミクロンのカーボン繊維である。接触部の導電性を確保するためには、接触点において圧力が加わる必要がある。微細凹凸が多く、表面積率が大きい方が接触部の圧力上昇を生じやすい接触点を多数形成できるため、接触抵抗がより低減しているものと推定している。接触面積を増やす効果を生ずるためではないかと考えられる。図3より、表面積率を1.02以上とすることで接触抵抗10mΩ・cm2以下となることがわかる。また、表面積率が1.04以上ではさらに接触抵抗が低い結果が得られている。
引き続き、焼鈍を施し、表2に示す条件で前処理(電解処理もしくは酸洗)、酸洗溶液に浸漬する酸処理を行った。なお、電解処理は表2に示す浴にて、溶液温度は55℃で電流密度は2A/dm2、処理時間は30秒にて行い、酸洗は表2に示す溶液にて、溶液温度は55℃で処理時間は30秒にて行った。また、酸処理は表2に示す溶液および浴温度で120秒間行った。
得られたSEM像をもとに、付属の画像処理ソフト(三次元表面形状解析ソフト「SUMMIT」)を用いて、表面積率を、表面積率=(1+Sdr/100)により算出した。測定は6μm×4.5μmの領域を0.01μm間隔で画素を設定することにより実施し、画像処理に際しては1/2λの2次のGaussianハイパスフィルター処理を行って計算した。また、各試料について少なくとも5視野以上を観察し、その平均とした。さらに、粒界を跨ぐ画像ではその段差の影響が大きいため、粒内のデータを用いて算出した。
以上により得られた結果を表3に示す。
以上に示したように、走査型電子顕微鏡を用いて0.1μm以下の空間分解能で表面形状を測定した場合に、その表面積率が1.02以上好ましくは1.04以上とすることにより、接触抵抗特性に優れた燃料電池セパレータ用ステンレス鋼を実現することができる。
2 ガス拡散層
3 ガス拡散層
4 セパレータ
5 セパレータ
6 空気流路
7 水素流路
Claims (6)
- Crを16質量%以上含有するステンレス鋼であって、
該ステンレス鋼の表面を走査型電子顕微鏡により0.1μm以下の空間分解能で表面形状測定をした場合に、表面積率が1.02以上であることを特徴とする燃料電池セパレータ用ステンレス鋼。 - 前記表面積率が1.04以上であることを特徴とする請求項1に記載の燃料電池セパレータ用ステンレス鋼。
- 前記ステンレス鋼が、さらに、質量%で、C:0.03%以下、Si:1.0%以下、Mn:1.0%以下、S:0.01%以下、P:0.05%以下、Al:0.20%以下、N:0.03%以下、Cr:16~40%を含み、Ni:20%以下、Cu:0.6%以下、Mo:2.5%以下の一種以上を含有し、残部がFe および不可避的不純物からなることを特徴とする請求項1または2に記載の燃料電池セパレータ用ステンレス鋼。
- 前記ステンレス鋼が、さらに、質量%で、Nb、Ti、Zrの一種以上を合計で1.0%以下を含有することを特徴とする請求項1に記載の燃料電池セパレータ用ステンレス鋼。
- 前記ステンレス鋼が、さらに、質量%で、Nb、Ti、Zrの一種以上を合計で1.0%以下を含有することを特徴とする請求項2に記載の燃料電池セパレータ用ステンレス鋼。
- 前記ステンレス鋼が、さらに、質量%で、Nb、Ti、Zrの一種以上を合計で1.0%以下を含有することを特徴とする請求項3に記載の燃料電池セパレータ用ステンレス鋼。
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US11326224B2 (en) | 2017-09-19 | 2022-05-10 | Nippon Steel Stainless Steel Corporation | Stainless steel sheet and method of manufacturing the same, separator for solid polymer fuel cell, solid polymer fuel cell, and solid polymer fuel cell battery |
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TWI581490B (zh) | 2017-05-01 |
EP2738279A1 (en) | 2014-06-04 |
US20140193668A1 (en) | 2014-07-10 |
TW201306371A (zh) | 2013-02-01 |
CN103717772B (zh) | 2016-10-26 |
CN103717772A (zh) | 2014-04-09 |
KR20140039326A (ko) | 2014-04-01 |
JPWO2013018322A1 (ja) | 2015-03-05 |
JP5972877B2 (ja) | 2016-08-17 |
EP2738279A4 (en) | 2015-10-21 |
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