WO2012105434A1 - 高温空気燃焼用バーナ装置 - Google Patents
高温空気燃焼用バーナ装置 Download PDFInfo
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- WO2012105434A1 WO2012105434A1 PCT/JP2012/051774 JP2012051774W WO2012105434A1 WO 2012105434 A1 WO2012105434 A1 WO 2012105434A1 JP 2012051774 W JP2012051774 W JP 2012051774W WO 2012105434 A1 WO2012105434 A1 WO 2012105434A1
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- air
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- combustion
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- secondary air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D1/00—Burners for combustion of pulverulent fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C1/00—Combustion apparatus specially adapted for combustion of two or more kinds of fuel simultaneously or alternately, at least one kind of fuel being either a fluid fuel or a solid fuel suspended in a carrier gas or air
- F23C1/10—Combustion apparatus specially adapted for combustion of two or more kinds of fuel simultaneously or alternately, at least one kind of fuel being either a fluid fuel or a solid fuel suspended in a carrier gas or air liquid and pulverulent fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C6/00—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
- F23C6/04—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
- F23C6/045—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/08—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for reducing temperature in combustion chamber, e.g. for protecting walls of combustion chamber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D17/00—Burners for combustion conjointly or alternatively of gaseous or liquid or pulverulent fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L9/00—Passages or apertures for delivering secondary air for completing combustion of fuel
- F23L9/02—Passages or apertures for delivering secondary air for completing combustion of fuel by discharging the air above the fire
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2202/00—Fluegas recirculation
- F23C2202/30—Premixing fluegas with combustion air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/06041—Staged supply of oxidant
Definitions
- the present invention relates to a burner device for high-temperature air combustion in which pulverized fuel is burned with high-temperature air.
- Patent Document 1 discloses a burner device in which a high-temperature air nozzle, a fuel nozzle, and a secondary air nozzle are individually arranged in a vertical direction from the lower side on a wall surface of a furnace.
- pulverized coal is ejected from the fuel nozzle
- high-temperature air is injected from the high-temperature air nozzle toward the pulverized coal flow
- the pulverized coal is ignited and combusted
- secondary air is ejected from the secondary air nozzle above the flame.
- unburned fuel burns.
- the present invention provides a burner device for high-temperature air combustion that enables high-temperature air combustion with a simpler nozzle configuration.
- the present invention is provided with a heat shield having a throat provided facing the furnace, a burner nozzle provided on the axis of the throat, and jetting a pulverized coal mixed flow into the furnace through the throat, and contains the burner nozzle.
- a wind box provided at the end of the burner nozzle, an air register for injecting low-temperature secondary air from the wind box to the throat, and one end opened into the furnace through the heat shield.
- a high-temperature air nozzle whose other end opens into the wind box, and low-temperature secondary air is ejected to the throat via the air register, or high-temperature secondary air is injected into the furnace via the high-temperature air nozzle.
- a combustion air switching means for switching whether or not the air is to be ejected.
- low-temperature secondary air is supplied to the air register by the combustion air switching means.
- a pulverized coal mixed flow is ejected from the burner nozzle, and in high-temperature air combustion, high-temperature secondary air is ejected into the furnace through the high-temperature air nozzle by the combustion air switching means.
- a burner device for high-temperature air combustion configured to eject a mixed pulverized coal flow from the burner nozzle is also provided.
- the burner device for high temperature air combustion further comprises secondary air temperature adjusting means for adjusting the temperature of the secondary air by extracting the exhaust gas and mixing it with the secondary air flowing into the wind box.
- the combustion air switching means closes the high-temperature air nozzle, and the secondary air is ejected through the air register to adjust the secondary air temperature.
- the combustion air switching means closes the air register and ejects the secondary air through the high temperature air nozzle.
- the low-temperature secondary air is blown from a blower and heat-exchanged with exhaust gas through a heat exchanger, and the high-temperature secondary air is exhausted into the low-temperature secondary air.
- a burner device for high-temperature air combustion which is air that has been mixed and heated.
- the combustion air switching means opens the high-temperature air nozzle stepwise, and the air register is made to correspond to the opening of the high-temperature air nozzle.
- a burner device for hot air combustion that closes automatically is provided.
- the present invention also provides a burner device for high-temperature air combustion, wherein the burner nozzle has a pulverized coal burner nozzle, and an oil burner nozzle provided concentrically with the pulverized coal burner nozzle inside the pulverized coal burner nozzle.
- the burner device for high-temperature air combustion of the present invention having the above configuration, it is possible to execute steady combustion and high-temperature air combustion with a single high-temperature air combustion burner device with a simple nozzle configuration, and it is possible to reduce the device cost. Show the effect.
- FIG. 1 shows an example of a burner device for high-temperature air combustion according to this embodiment.
- the outline of the burner device for high-temperature air combustion will be described below with reference to FIG.
- 1, 1 indicates a furnace
- 2 indicates a furnace wall of the furnace 1
- the right side of the furnace wall 2 is a core in FIG. 1.
- the furnace wall 2 is provided with a high-temperature air combustion burner device 3, and the high-temperature air combustion burner device 3 forms a flame toward the core.
- the hot air combustion burner device 3 is arranged in a plurality of stages at predetermined intervals in the horizontal direction or vertically. Moreover, the arrangement
- positioning aspect is suitably determined by the scale of a furnace.
- the hot air combustion burner device 3 has a burner housing 4.
- the burner housing 4 has a cylindrical shape with a horizontal axis and is provided through the furnace wall 2. Further, the opening on the core side (hereinafter referred to as the front end side) of the burner housing 4 is closed by the heat shield 5, and a throat 6 is provided at the center of the heat shield 5.
- a flange substrate 7 is provided in the opening on the counter-core side (hereinafter referred to as the base end side) of the burner housing 4, and a cylindrical or substantially cylindrical window box 8 passes through the center of the flange substrate 7. It is provided concentrically with the burner housing 4 via the substrate 7.
- a burner nozzle 9 is provided on the center axis of the throat 6, and the burner nozzle 9 penetrates the base end plate 11 of the wind box 8, and the tip thereof reaches the vicinity of the throat 6.
- the wind box 8 houses the burner nozzle 9 and forms a buffer space into which secondary air flows around the burner nozzle 9.
- a disc-shaped swirl vane support substrate 12 is provided at a position retracted from the tip of the burner nozzle 9 by a predetermined distance, and the swirl vane support substrate 12 is provided with swirl vane rotating shafts 13 at a predetermined pitch on the same circumference.
- a swirl vane 14 is fixed to each blade rotation shaft 13. Further, the individual rotary blade rotating shafts 13 and 13 are connected by a link mechanism 15 and rotate in synchronization by the link mechanism 15.
- One of the swirl blade rotation shafts 13 is connected to an actuator such as an air cylinder, and the swirl blade rotation shafts 13 are rotated by the actuator, so that all the swirl blade rotation shafts 13 are connected to the actuators. Rotate synchronously with respect to 13. Further, due to the synchronous rotation of the swirl vane rotating shaft 13, the swirl vane 14 rotates synchronously.
- the swirl vane rotating shaft 13, swirl vane 14, link mechanism 15, etc. constitute an air register 16, and the periphery of the swirl vane support substrate 12 forms a secondary air inlet 17, and the air register from the secondary air inlet 17.
- the secondary air 18 flowing into 16 can be swirled by swirl vanes 14. Further, when the swirl vanes 14 are rotated to the maximum, the adjacent swirl vanes 14 overlap each other and the secondary air inflow cylinder 17 can be completely closed.
- the burner nozzle 9 is composed of a pulverized coal burner nozzle 20 and an oil burner nozzle 21 provided on the center line of the pulverized coal burner nozzle 20, and a base end portion 20 a of the pulverized coal burner nozzle 20 is bent and separated from the oil burner nozzle 21. It is connected to a pulverized coal mill (not shown).
- the oil burner nozzle 21 passes through the base end portion 20a and is connected to a fuel oil supply unit (not shown).
- the pulverized coal burner nozzle 20 and the air register 16 and the like constitute a pulverized coal burner
- the pulverized coal burner nozzle 20 and the oil burner nozzle 21 and the like constitute an oil burner
- a hot air nozzle 23 bent in an S shape is provided between the wind box 8 and the burner housing 4.
- a distal end portion 23 a of the high temperature air nozzle 23 penetrates the heat shield portion 5 and relates to the furnace 1, and a proximal end portion 23 b of the high temperature air nozzle 23 is opened inside the wind box 8.
- the center axes of the distal end portion 23 a and the base end portion 23 b are parallel to the center axis of the throat 6.
- the tip portion 23a is illustrated as being parallel to the center axis of the throat 6. However, the tip portion 23a is inclined in the horizontal and vertical directions so that optimum high-temperature air combustion can be obtained. Good.
- the damper 24 is provided in the base end part 23b, and the rotating shaft 25 of the damper 24 penetrates the window box 8 and protrudes outside.
- a bearing 26 is provided at a location where the rotary shaft 25 penetrates the window box 8, and the rotary shaft 25 is rotatably supported by the wind box 8 via the bearing 26.
- An opening setting lever 27 is attached to the tip of the rotating shaft 25.
- the opening setting plate 28 is provided at the tip of the bearing 26, and the outer surface of the opening setting plate 28 is parallel to the opening setting lever 27.
- the opening setting plate 28 has a fan shape with the rotation shaft 25 as the center.
- the opening setting plate 28 is formed with opening setting holes 29a to 29e on the same circumference at a predetermined angular pitch (22.5 ° in the drawing), and opening setting holes 29a and 29e located at both ends. Is 90 °.
- the opening setting lever 27 is provided with an opening setting pin 31 at a position having the same radius as the circumference where the opening setting hole 29 is formed so as to be detachable toward the outer surface of the opening correction plate 28. Yes.
- the opening setting pin 31 can be inserted into the opening setting hole 29 and opened by inserting the opening setting pin 31 into the opening setting hole 28 through the opening setting lever 27.
- the degree setting lever 27 can be fixed at a predetermined angle. Further, since the opening setting lever 27 and the damper 24 rotate integrally through the rotating shaft 25, the opening setting pin 31 is inserted into any of the opening setting holes 29a to 29e, thereby setting the opening.
- the lever 27 can be fixed at a predetermined angle, and the damper 24 can be fixed at a predetermined opening.
- the damper 24 With the opening setting pin 31 inserted into the opening setting hole 29a, the damper 24 completely closes the base end portion 23b, and with the opening setting pin 31 inserted into the opening setting hole 29e, If the damper 24 completely closes the base end portion 23b, the opening setting lever 27 penetrates the opening setting pin 31 and the opening setting holes 29a to 29e into which the opening setting pin 31 is inserted are selected.
- the opening degree of the damper 24 can be set stepwise from fully closed to fully open.
- the damper 24 is rotated 45 ° from the fully closed or fully opened state, and is in a half open state.
- two sets of the hot air nozzles 23 are provided at positions symmetrical with respect to the burner nozzle 9.
- two sets are provided in the horizontal direction. In FIG. 1, only one set is shown on the upper side and the other is not shown so that the positional relationship between the burner nozzle 9 and the hot air nozzle 23 is clear.
- the secondary air duct 33 communicates with the wind box 8, and the secondary air duct 33 is connected to a blower (not shown) via a secondary air supply line 34.
- An exhaust gas extraction line 35 communicates with the secondary air supply line 34, the exhaust gas extraction line 35 is connected to a boiler flue (not shown), and the exhaust gas extraction line 35 is provided with a flow rate adjusting valve 36.
- the exhaust gas extraction line 35 extracts high temperature exhaust gas 37 from the flue.
- the extracted gas merges with the secondary air 18 in the secondary air supply line 34 to raise the temperature of the secondary air 18.
- the flow rate adjusting valve 36 adjusts the amount of exhaust gas extracted, and the flow rate adjusting valve 36 adjusts the mixing ratio of the exhaust gas 37 and the secondary air 18. That is, the temperature of the secondary air 18 is adjusted by the flow rate adjusting valve 36.
- the exhaust gas extraction line 35 and the exhaust gas 37 constitute secondary air temperature adjusting means for increasing the temperature of the secondary air 18 by mixing high temperature exhaust gas with the secondary air 18.
- the secondary air 18 itself is heat-exchanged with exhaust gas by a gas-gas heat exchanger and heated to 200 ° C. to 350 ° C.
- the burner device 3 for high-temperature air combustion is unitized by using the burner housing 4 and the flange substrate 7, but the wind box 8 and the air register 16 are not connected to the burner housing 4 and the flange substrate 7. It is also possible to provide it on the furnace wall 2. In this case, a part of the furnace wall 2 functions as the heat shield 5.
- the damper 24 is in a state in which the high-temperature air nozzle 23 is fully closed at the time of starting the combustion of the burner device 3 for high-temperature air combustion and in the state of steady combustion (a state in which fuel and oxygen are mixed and burned).
- Oil is supplied to the oil burner nozzle 21 as fuel, and the oil is injected toward the throat 6 and ignited to perform auxiliary combustion. Auxiliary combustion is continued until the inside of the furnace rises to a predetermined temperature, the inside of the furnace reaches the predetermined temperature, and the secondary air 18 is at a temperature sufficient to cause the pulverized coal to self-combust by heat exchange with the exhaust gas.
- the pulverized coal mixed stream 38 is supplied to the pulverized coal burner nozzle 20.
- the pulverized coal mixed flow 38 flows while swirling around the oil burner nozzle 21, and is ejected from the tip of the pulverized coal burner nozzle 20. Further, the secondary air 18 is supplied to the wind box 8 through the secondary air duct 33, and the secondary air 18 is jetted toward the throat 6 through the air register 16.
- the flow rate of the secondary air 18 is adjusted and swirled by the swirl vanes 14 in the process of passing through the air register 16.
- the pulverized coal mixed stream 38 ejected from the pulverized coal burner nozzle 20 is mixed with the secondary air 18, and the pulverized coal is ignited and burned (pulverized coal combustion).
- the flow rate adjustment valve 36 is opened at a predetermined opening, and the exhaust gas 37 is extracted from a flue (not shown).
- the secondary air 18 is mixed with the secondary air 18 flowing through the secondary air supply line 34 via the exhaust gas extraction line 35, and the temperature of the secondary air 18 is raised to a predetermined value, that is, a temperature at which high-temperature air combustion is possible, for example, 800 ° C.
- the damper 24 is opened stepwise to correspond to the temperature rise state of the secondary air 18, the damper 24 is opened, and the air register 16 is stepped. It is preferable to close it.
- damper 24 and the air register 16 constitute combustion air switching means for switching between low temperature steady combustion secondary air and high temperature high temperature combustion secondary air.
- high-temperature air 18 ′ secondary air 18 having a high temperature from the high-temperature air nozzles 23 disposed on the left and right of the pulverized coal burner nozzle 20 is directed into the furnace and parallel to the pulverized coal mixed flow 38. Is erupted.
- the pulverized coal mixed stream 38 is gradually mixed with the high-temperature air 18 'and burned slowly (high-temperature air combustion) under low oxygen and high temperatures.
- the combustion state of pulverized coal becomes combustion in an environment with a low combustion concentration and no low oxygen concentration, and generation of nitrogen oxides (NO x ) can be suppressed.
- auxiliary combustion with an oil burner may be used in combination.
- the combustion mode can be shifted by one type of burner device 3 for high-temperature air combustion when shifting from the start of combustion to steady combustion and further to high-temperature air combustion.
- the configuration of the burner device is simplified and the equipment such as piping associated with the burner can be simplified, the device cost can be reduced and the equipment cost when the burner is installed can be reduced.
- the damper 24 is opened and closed by the actuator, and the actuator, the air register 16 and the flow rate adjusting valve 36 are driven by the control device, and the temperature at which the temperature of the exhaust gas is detected in the flue or furnace.
- a detector is provided, and based on the result of the temperature detector, the actuator, the air register 16, and the flow rate adjustment valve 36 are controlled to automatically shift from the start of combustion to the steady combustion and from the steady combustion to the high temperature air combustion. You may do it.
- the high temperature air nozzle 23 is provided so as to eject high temperature secondary air from the wind box 8 into the furnace.
- a high temperature secondary air supply line is provided separately, and the high temperature secondary air supply line is connected to the high temperature air nozzle 23.
- the high temperature secondary air may be connected directly to the high temperature air nozzle 23 without passing through the wind box 8.
- steady combustion and high-temperature air combustion can be executed by a single high-temperature air combustion burner device with a simple nozzle configuration, and the device cost can be reduced.
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Abstract
Description
本願は、2011年1月31日に日本に出願された特願2011-17518号に基づき優先権を主張し、その内容をここに援用する。
図1は、本実施例に係る高温空気燃焼用バーナ装置の一例を示している。以下、図1を参照して高温空気燃焼用バーナ装置の概略を説明する。
高温空気燃焼用バーナ装置3はバーナハウジング4を有する。バーナハウジング4は水平な軸心を有する円筒形状であり、炉壁2を貫通して設けられている。また、バーナハウジング4の炉心側(以下、先端側とする)の開口は遮熱部5によって閉塞され、遮熱部5の中心にはスロート6が設けられている。
Claims (4)
- 火炉に面して設けられ、スロートを有する遮熱部と、
このスロートの軸心上に設けられ、微粉炭混合流を前記スロートを通して炉内に噴出するバーナノズルと、
このバーナノズルを収納する様に設けられたウインドボックスと、
前記バーナノズルの先端部に設けられ、低温の2次空気を前記ウインドボックスから前記スロートに噴出させるエアレジスタと、
一端が前記遮熱部を通して炉内に開口し、他端が前記ウインドボックス内に開口する高温空気ノズルと、
低温の2次空気を前記エアレジスタを介して前記スロートに噴出させるか、高温の2次空気を前記高温空気ノズルを介して炉内に噴出させるかを切替える燃焼用空気切替え手段とを具備し、
定常燃焼では前記燃焼用空気切替え手段により低温の2次空気を前記エアレジスタを介して前記スロートに噴出させると共に前記バーナノズルより微粉炭混合流を噴出させ、高温空気燃焼では前記燃焼用空気切替え手段により高温の2次空気を前記高温空気ノズルを介して炉内に噴出させると共に前記バーナノズルより微粉炭混合流を噴出させる様構成し、更に、
排ガスを抽出して前記ウインドボックスに流入する2次空気に混合させ、2次空気の温度を調整する2次空気温度調整率段を具備し、
この2次空気温度調整手段が、排ガスを2次空気に混合させない状態では、前記燃焼用空気切替え手段が前記高温空気ノズルを閉止し、2次空気を前記エアレジスタを介して噴出させ、
2次空気温度調整手段が、排ガスを2次空気に混合させた状態では、前記燃焼用空気切替え手段が前記エアレジスタを閉止し、2次空気を前記高温空気ノズルを介して噴出させる様構成した、高温空気燃焼用バーナ装置。 - 前記低温の2次空気が、送風機から送風され、熱交換器を介して排ガスと熱交換された空気であり、前記高温の2次空気が前記低温の2次空気に排ガスが混合されて昇温された空気である請求項1の高温空気燃焼用バーナ装置。
- 定常燃焼から高温空気燃焼への移行時に、前記燃焼用空気切替え手段が前記高温空気ノズルを段階的に開口し、この高温空気ノズルの開口に対応させ、前記エアレジスタを段階的に閉止する請求項1の高温空気燃焼用バーナ装置。
- 前記バーナノズルが、微粉炭バーナノズルと、この微粉炭バーナノズルの内部に、微粉炭バーナノズルと同心に設けられたオイルバーナノズルとを有する請求項1の高温空気燃焼用バーナ装置。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/981,848 US9869468B2 (en) | 2011-01-31 | 2012-01-27 | Burner device for high-temperature air combustion |
AU2012211903A AU2012211903B2 (en) | 2011-01-31 | 2012-01-27 | Burner device for high-temperature air combustion |
EP12742305.1A EP2672180B1 (en) | 2011-01-31 | 2012-01-27 | Operation method of a burner device for high-temperature air combustion |
MYPI2013002819A MY185043A (en) | 2011-01-31 | 2012-01-27 | Burner device for high-temparature air combustion |
JP2012555833A JP5549747B2 (ja) | 2011-01-31 | 2012-01-27 | 高温空気燃焼用バーナ装置 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2011-017518 | 2011-01-31 | ||
JP2011017518 | 2011-01-31 |
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WO2012105434A1 true WO2012105434A1 (ja) | 2012-08-09 |
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US (1) | US9869468B2 (ja) |
EP (1) | EP2672180B1 (ja) |
JP (1) | JP5549747B2 (ja) |
AU (1) | AU2012211903B2 (ja) |
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CN103672906A (zh) * | 2013-12-12 | 2014-03-26 | 贵州安凯达实业股份有限公司 | 一种转炉煤气与煤粉混合燃烧装置 |
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- 2012-01-27 WO PCT/JP2012/051774 patent/WO2012105434A1/ja active Application Filing
- 2012-01-27 AU AU2012211903A patent/AU2012211903B2/en not_active Ceased
- 2012-01-27 US US13/981,848 patent/US9869468B2/en active Active
- 2012-01-27 JP JP2012555833A patent/JP5549747B2/ja active Active
- 2012-01-27 MY MYPI2013002819A patent/MY185043A/en unknown
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Also Published As
Publication number | Publication date |
---|---|
JP5549747B2 (ja) | 2014-07-16 |
EP2672180A1 (en) | 2013-12-11 |
MY185043A (en) | 2021-04-30 |
JPWO2012105434A1 (ja) | 2014-07-03 |
AU2012211903A1 (en) | 2013-08-22 |
US9869468B2 (en) | 2018-01-16 |
US20130305968A1 (en) | 2013-11-21 |
AU2012211903B2 (en) | 2015-09-10 |
EP2672180B1 (en) | 2018-04-25 |
EP2672180A4 (en) | 2016-11-16 |
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