WO2012104281A1 - Renfort composite gaine d'une couche de polymere auto-adherente au caoutchouc - Google Patents
Renfort composite gaine d'une couche de polymere auto-adherente au caoutchouc Download PDFInfo
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- WO2012104281A1 WO2012104281A1 PCT/EP2012/051518 EP2012051518W WO2012104281A1 WO 2012104281 A1 WO2012104281 A1 WO 2012104281A1 EP 2012051518 W EP2012051518 W EP 2012051518W WO 2012104281 A1 WO2012104281 A1 WO 2012104281A1
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- WIPO (PCT)
- Prior art keywords
- styrene
- thermoplastic
- elastomer
- reinforcement
- reinforcement according
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/0042—Reinforcements made of synthetic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/18—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
- B29D30/38—Textile inserts, e.g. cord or canvas layers, for tyres; Treatment of inserts prior to building the tyre
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/48—Tyre cords
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0606—Reinforcing cords for rubber or plastic articles
- D07B1/0666—Reinforcing cords for rubber or plastic articles the wires being characterised by an anti-corrosive or adhesion promoting coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
- B29D30/38—Textile inserts, e.g. cord or canvas layers, for tyres; Treatment of inserts prior to building the tyre
- B29D2030/383—Chemical treatment of the reinforcing elements, e.g. cords, wires and filamentary materials, to increase the adhesion to the rubber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/0007—Reinforcements made of metallic elements, e.g. cords, yarns, filaments or fibres made from metal
- B60C2009/0021—Coating rubbers for steel cords
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- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2001—Wires or filaments
- D07B2201/201—Wires or filaments characterised by a coating
- D07B2201/2012—Wires or filaments characterised by a coating comprising polymers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2042—Strands characterised by a coating
- D07B2201/2044—Strands characterised by a coating comprising polymers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/20—Rope or cable components
- D07B2201/2015—Strands
- D07B2201/2046—Strands comprising fillers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/2003—Thermoplastics
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/2075—Rubbers, i.e. elastomers
- D07B2205/2082—Rubbers, i.e. elastomers being of synthetic nature, e.g. chloroprene
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2501/00—Application field
- D07B2501/20—Application field related to ropes or cables
- D07B2501/2046—Tire cords
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
Definitions
- the field of the present invention is that reinforcing elements or "reinforcements", in particular metal, used for reinforcing articles or semi-finished products of diene rubber such as for example pneumatic tires.
- the present invention relates more particularly to reinforcements of the hybrid or composite type consisting of at least one core, in particular metal, said core being covered or sheathed with a layer or sheath of thermoplastic material.
- thermoplastic materials such as for example polyamide or polyester
- thermoplastic materials such as for example polyamide or polyester
- various external aggressions such as oxidation or abrasion
- structurally stiffen to bond together various sets of son or wire assemblies such as cables, and thus increase their particular buckling resistance.
- patent application EP 0 962 562 describes a reinforcement made of steel or aramid textile sheathed with a thermoplastic material such as polyester or polyamide, in order to improve its resistance to abrasion.
- the patent application FR 2 601 293 has described the sheathing of a wire rope with polyamide for use as a bead wire in a tire bead, this sheath advantageously making it possible to adapt the shape of this bead wire to the structure and operating conditions of the bead of the tire that it reinforces.
- These reinforcements and sheathed polyester or polyamide material have, in addition to the aforementioned advantages of corrosion resistance, abrasion resistance and structural rigidity, that not insignificant to be then glued to matrices of diene rubber using simple "RFL" textile glues (resorcinol-formaldehyde-latex) comprising at least one diene elastomer such as natural rubber, adhesives which, in known manner, confer a satisfactory adhesion between textile fibers such as polyester or polyamide fibers and a diene rubber.
- RTL textile glues
- metal reinforcements not coated with adhesive metal layers such as brass, as well as surrounding rubber matrices devoid of metal salts such as cobalt salts, which are necessary in a manner known to maintain adhesive performance over time can advantageously be used.
- metal salts such as cobalt salts
- the RFL glues above are not without drawbacks; they contain in particular as basic substance formaldehyde (or formaldehyde) and resorcinol that it is desirable to eventually remove adhesive compositions, because of the recent evolution of European regulations on this type of products.
- designers of diene rubber articles, including tire manufacturers are looking today for new adhesive systems or new reinforcements that overcomes all or part of the aforementioned drawbacks.
- a first object of the invention relates to a composite reinforcement comprising:
- thermoplastic polymer composition comprising at least one thermoplastic polymer whose glass transition temperature is positive, a poly (p-phenylene ether) (“PPE”), and a functionalized unsaturated thermoplastic styrene thermoplastic elastomer (“TPS”) whose glass transition temperature is negative, said TPS elastomer carrying functional groups chosen from epoxide, carboxyl, anhydride or acid ester groups.
- PPE poly (p-phenylene ether)
- TPS functionalized unsaturated thermoplastic styrene thermoplastic elastomer
- thermoplastic polymer composition makes it possible to ensure a direct and efficient adhesion of the composite reinforcement of the invention to a diene elastomer matrix or composition such as those commonly used in pneumatic tires. especially at elevated temperature.
- the invention also relates to a method of manufacturing the composite reinforcement above, said method being characterized in that individually sheathing the wire or each reinforcing wire, or collectively several reinforcing son, with a layer of thermoplastic polymer composition comprising a thermoplastic polymer whose glass transition temperature is positive, a poly (p-phenylene ether) (“PPE”), and a functionalized unsaturated thermoplastic styrene thermoplastic elastomer (“TPS”) whose glass transition temperature is negative, said TPS elastomer carrying functional groups selected from epoxide, carboxyl, anhydride or acid ester groups.
- a layer of thermoplastic polymer composition comprising a thermoplastic polymer whose glass transition temperature is positive, a poly (p-phenylene ether) (“PPE”), and a functionalized unsaturated thermoplastic styrene thermoplastic elastomer (“TPS”) whose glass transition temperature is negative, said TPS elastomer carrying functional groups selected from epoxide
- the present invention also relates to the use of the composite reinforcement of the invention as a reinforcing element for semi-finished articles or rubber products, particularly pneumatic tires, in particular those intended for equipping tourism-type motor vehicles, SUVs.
- “Sport Utility Vehicles” two wheels (including bicycles, motorcycles), aircraft, such as industrial vehicles selected from light trucks, "heavy goods vehicles” - that is to say, subway, bus, road transport equipment (trucks, tractors , trailers), off-the-road vehicles such as agricultural or civil engineering -, other transport or handling vehicles.
- the invention also relates per se to any article or semi-finished product made of rubber, in particular a tire, comprising a composite reinforcement according to the invention.
- any range of values designated by the expression "between a and b" represents the range of values from more than a to less than b (i.e. terminals a and b excluded) while any range of values designated by the term “from a to b” means the range from a to b (i.e., including the strict limits a and b).
- the composite reinforcement of the invention capable of adhering directly by firing to an unsaturated rubber composition, and which can be used especially for reinforcing diene rubber articles such as pneumatic tires, therefore has the essential characteristics of comprising: at least a thread (i.e., one or more threads) of reinforcement; individually covering said yarn, each yarn or collectively several yarns, a layer of a thermoplastic polymer composition comprising a thermoplastic polymer whose glass transition temperature (hereinafter Tgi) is positive (i.e.
- the composite reinforcement of the invention comprises a single thread or several reinforcing threads, said thread, individually each thread or collectively several threads being covered by a layer (monolayer) or sheath of the polymer composition thermoplastic stated above.
- the structure of the reinforcement of the invention is described in detail below.
- the term "reinforcing thread” is generally understood to mean any elongate element of great length relative to its cross section, whatever the shape of the latter, for example circular, oblong, rectangular or square. , or even flat, this wire may be rectilinear as non-rectilinear, for example twisted or corrugated.
- This reinforcing wire can take any known shape, it can act for example of a large elementary monofilament (for example and preferably equal to or greater than 50 ⁇ ), an elementary ribbon, a multifilament fiber (consisting of a plurality of elementary filaments of small diameter, typically less than 30 ⁇ ), a textile twist formed of several fibers twisted together, a textile or metal cable formed of several fibers or monofilaments cabled or twisted together, or an assembly, a group, a row of son such as for example a strip or strip comprising several of these monofilaments, fibers, twisted or cables grouped together, for example aligned in a main direction, rectilinear or not.
- a large elementary monofilament for example and preferably equal to or greater than 50 ⁇
- an elementary ribbon for example and preferably equal to or greater than 50 ⁇
- a multifilament fiber consisting of a plurality of elementary filaments of small diameter, typically less than 30 ⁇
- the wire or each reinforcing wire has a diameter which is preferably less than 5 mm, in particular within a range of 0.1 to 2 mm.
- the reinforcing wire is a metal reinforcing wire, in particular carbon steel such as those used in the "steel cords" type cables for tires; but it is of course possible to use other steels, for example stainless steels.
- carbon steel when a carbon steel is used, its carbon content is preferably between 0.4% and 1.2%, especially between 0.5% and 1.1%.
- the invention applies in particular to any steel of the steel cord type with standard resistance (called “NT” for “Normal Tensile “), high resistance (called” HT “for” High Tensile “), very high resistance (called” SHT “for” Super High Tensile ”) as ultra-high resistance (called” UHT “for” Ultra High "
- NT normal Tensile
- high resistance called "HT” for” High Tensile
- very high resistance called” SHT “for” Super High Tensile
- the steel could be coated with an adhesive layer such as brass or zinc, however, a clear, ie, uncoated, steel can be advantageously used.
- the rubber composition intended to be reinforced by a metal reinforcement according to the invention no longer requires the use in its formulation of metal salts such as cobalt salts.
- thermoplastic polymer composition constituting the above layer or sheath firstly comprises a thermoplastic polymer whose Tg (denoted Tgi) is by definition positive, preferably greater than + 20 ° C., more preferably greater than + 30 ° C. .
- the melting temperature (denoted by Tf) of this thermoplastic polymer is preferably greater than 100 ° C., more preferably greater than 150 ° C., in particular greater than 200 ° C.
- This thermoplastic polymer is preferably chosen from the group consisting of polyamides, polyesters and polyimides, more particularly from the group consisting of aliphatic polyamides and polyesters.
- polyesters that may be mentioned for example are PET (polyethylene terephthalate), PEN (polyethylene naphthalate), PBT (polybutylene terephthalate), PBN (polybutylene naphthalate), PPT (polypropylene terephthalate), PPN (polypropylene naphthalate).
- the aliphatic polyamides there may be mentioned in particular polyamides 4-6, 6, 6-6, 11 or 12.
- This thermoplastic polymer is preferably an aliphatic polyamide, more preferably a polyamide 6 or a polyamide 11.
- the second essential constituent of the thermoplastic polymer composition is a functionalized unsaturated styrenic thermoplastic elastomer, said elastomer carrying epoxide, carboxyl, acid anhydride or acid ester groups or functional groups.
- the functional groups are epoxide groups, that is to say that the thermoplastic elastomer is an epoxidized elastomer.
- the Tg (Tg 2 or first Tg or lowest Tg) of said elastomer is by definition negative, preferably below -20 ° C, more preferably below -30 ° C.
- the difference in glass transition temperatures (Tgi-Tg 2 ) between the thermoplastic polymer and the unsaturated TPS elastomer is greater than 40 ° C., more preferably greater than 60 ° C. vs.
- thermoplastic elastomers are thermoplastic elastomers in the form of block copolymers based on styrene.
- TPS thermoplastic elastomers
- intermediate structure between thermoplastic polymers and elastomers they consist in a known manner of rigid polystyrene blocks connected by flexible elastomer blocks, for example polybutadiene, polyisoprene or poly (ethylene / butylene).
- TPS copolymers are generally characterized by the presence of two glass transition peaks, the first peak (lowest temperature, negative, corresponding to Tg 2 ) being relative to the elastomer sequence of the TPS copolymer, the second peak (highest temperature, positive, typically around 80 ° C or higher) being relative to the thermoplastic portion (styrene blocks) of the TPS copolymer.
- These TPS elastomers are often triblock elastomers with two rigid segments connected by a flexible segment. The rigid and flexible segments can be arranged linearly, star or connected.
- These TPS elastomers may also be diblock elastomers with a single rigid segment connected to a flexible segment.
- each of these segments or blocks contains at least more than 5, usually more than 10 base units (e.g., styrene units and isoprene units for a styrene / isoprene / styrene block copolymer).
- base units e.g., styrene units and isoprene units for a styrene / isoprene / styrene block copolymer.
- random diene copolymer elastomers such as for example SIR (styrene-isoprene copolymers) or SBR (styrene-butadiene copolymers) which, in a well-known manner, have no thermoplastic character .
- an essential characteristic of the TPS elastomer used in the composite reinforcement of the invention is that it is unsaturated.
- unsaturated TPS elastomer is defined by definition and well known a TPS elastomer which is provided with ethylenic unsaturations, that is to say which has carbon-carbon double bonds (conjugated or not); conversely, a TPS elastomer said saturated is of course a TPS elastomer which is free of such double bonds.
- a second essential characteristic of the TPS elastomer used in the composite reinforcement of the invention is that it is functionalized and carries functional groups chosen from epoxide, carboxyl, anhydride or acid ester groups or functional groups.
- this TPS elastomer is an epoxidized elastomer, that is to say one carrying one or more epoxide groups.
- the unsaturated elastomer is a copolymer comprising, as base units, styrene blocks (that is to say polystyrene) and diene (ie polydiene) blocks, especially isoprene blocks (polyisoprene).
- butadiene polybutadiene
- elastomer is chosen in particular from the group consisting of styrene / butadiene (SB), styrene / isoprene (SI), styrene / butadiene / butylene (SBB), styrene / butadiene / isoprene (SBI), styrene / butadiene / styrene block copolymers (SBS), styrene / butadiene / butylene / styrene (SBB S), styrene / isoprene / styrene (SIS), styrene / butadiene / isoprene / styrene (SBIS) and mixtures of these copolymers.
- SB styrene / butadiene
- SI styrene /
- this unsaturated elastomer is a triblock type copolymer selected from the group consisting of styrene / butadiene / styrene (SBS), styrene / butadiene / butylene / styrene (SBB S), styrene / isoprene / styrene (SIS) block copolymers.
- SBS styrene / butadiene / soprene / styrene
- SBIS soprene / styrene
- mixtures of these copolymers more particularly, it is an SBS or SIS, in particular an SBS.
- the styrene content in the unsaturated TPS elastomer is between 5 and 50%. Outside the indicated range, there is a risk of seeing the desired technical effect, namely a compromise of adhesion which is no longer optimal with respect to a part of the thermoplastic polymer layer, other than part of the diene elastomer for which the reinforcement is intended on the other hand.
- the styrene content is more preferably between 10 and 40%.
- the number-average molecular weight (denoted Mn) of the TP S elastomer is preferably between 5,000 and 500,000 g / mol, more preferably between 7,000 and 450,000.
- Unsaturated and epoxidized TPS elastomers such as, for example, SBS, are known and commercially available, for example from Daicel under the name "Epofriend”.
- thermoplastic polymer composition comprises, in combination with the thermoplastic polymer and the functionalized unsaturated TPS elastomer described above, at least one polymer of poly (p-phenylene ether) (or poly (1,4-phenylene) -ether)) (abbreviated as "EPP").
- Thermoplastic polymers PPE are well known to those skilled in the art, they are solid resins at room temperature (20 ° C).
- the EPP used here has a glass transition temperature (hereinafter referred to as Tg 3 ) which is greater than 150 ° C., more preferably greater than 180 ° C.
- Tg 3 glass transition temperature
- Mn number-average molecular weight
- the EPP used is poly (2,6-dimethyl-1,4-phenylene ether) also sometimes referred to as polyphenylene oxide (or abbreviated as "PPO").
- PPO polyphenylene oxide
- Examples of such commercially available EPPs or PPOs are, for example, the “Xyron S202" PPEs from the Asahi Kasei company, or the “Noryl S Al 20" PPEs from the Sabic company.
- the amount of EPP polymer is adjusted so that the weight ratio of EPP is between 0.05 and 5 times, more preferably between 0.1 and Twice the weight content of styrene present in the functionalized TPS elastomer itself. Below the recommended minima, the adhesion of the composite reinforcement rubber can be decreased while beyond the maximum indicated, there is a risk of fragility of the layer.
- the weight ratio of PPE is more preferably still between 0.2 and 1.5 times the weight content of styrene in the TPS elastomer.
- Tg of the above thermoplastic polymers (Tgi, Tg 2 and Tg 3 ) is measured in a known manner by DSC (Differential Scanning Calorimetry), for example and unless otherwise specified in the present application, according to ASTM D3418 of 1999.
- the number-average molecular weight (Mn) is determined in a known manner by steric exclusion chromatography (SEC).
- SEC steric exclusion chromatography
- the sample is first solubilized in tetrahydrofuran at a concentration of about 1 g / l; then the solution is filtered on 0.45 ⁇ porosity filter before injection.
- the equipment used is a chromatographic chain "WATERS alliance”.
- the elution solvent is tetrahydrofuran, the flow rate 0.7 ml / min, the system temperature 35 ° C and the analysis time 90 min.
- a set of four WATERS columns in series, of trade names "STYRAGEL"("HMW7","HMW6E” and two "HT6E" is used.
- the injected volume of the solution of the polymer sample is 100 ⁇ .
- the detector is a differential refractometer "WATERS 2410" and its associated chromatographic data exploitation software is the “WATERS MILLENIUM” system.
- the calculated average molar masses relate to a calibration curve made with polystyrene standards.
- thermoplastic polymer functionalized unsaturated TPS elastomer and PPE
- PPE functionalized unsaturated TPS elastomer
- additives such as dye, filler, plasticizer, tackifier, antioxidant or other stabilizer, crosslinking or vulcanization system such as sulfur and accelerator could be optionally added to the thermoplastic polymer composition described above.
- FIG. 1 shows very schematically (without respecting a specific scale), in cross section, a first example of a composite reinforcement according to the invention.
- This composite reinforcement denoted R1 consists of a reinforcing thread (10) consisting of a unitary filament or monofilament of relatively large diameter (for example between 0.10 and 0.50 mm), for example made of carbon steel, which is covered with a layer (11) comprising a thermoplastic polymer whose Tg (Tgi) is positive, for example polyamide or polyester, a PPE such as PPO and a functionalised unsaturated TPS elastomer, for example SB, SB S, SBBS , SIS or SBIS of the epoxidized type, whose Tg (Tg 2 ) is negative; the minimum thickness of this layer is noted E m in this figure 1.
- FIG. 2 schematizes in cross-section a second example of a composite reinforcement according to the invention.
- This composite reinforcement R-2 consists of a reinforcing thread (20) consisting in fact of two single filaments or monofilaments (20a, 20b) of relatively large diameter (for example between 0, 10 and 0.50 mm) twisted or wired together, for example carbon steel; the reinforcing wire (20) is covered with a layer (21) of minimum thickness E m , comprising a thermoplastic polymer whose Tg (Tgi) is positive, for example polyamide or polyester, an EPP such as PPO and a functionalized unsaturated TPS elastomer, for example an epoxidized SBS or SIS, for example SB, SBS, SBBS, SIS or SBIS, whose Tg (Tg 2 ) is negative.
- FIG. 3 schematizes in cross-section another example of composite reinforcement according to the invention.
- This composite reinforcement denoted R-3 consists of three reinforcing threads (30) each consisting of two monofilaments (30a, 30b) of relatively large diameter (for example between 0, 10 and 0.50 mm) twisted or cabled together, by example of carbon steel; the assembly constituted by the three reinforcing son (30) for example aligned is covered with a layer (31) comprising a thermoplastic polymer whose Tg (Tgi) is positive, for example polyamide or polyester, a PPE such that PPO and an elastomer Functionalized unsaturated GST, for example SB, SBS, SBBS, SIS or SBIS of the epoxidized type, whose Tg (Tg 2 ) is negative.
- a layer (31) comprising a thermoplastic polymer whose Tg (Tgi) is positive, for example polyamide or polyester, a PPE such that PPO and an elastomer Functionalized unsaturated
- FIG. 4 schematizes, again in cross-section, another example of composite reinforcement according to the invention.
- This composite reinforcement R-4 comprises a reinforcing thread (40) consisting of a 1 + 6 structural steel wire, with a core wire or core wire (41a) and six filaments (41b) of the same diameter wound together in a helix around the central wire.
- This reinforcing wire or wire (40) is covered with a layer (42) of a polymer composition comprising a polyamide, a PPE such as PPO and a functionalized SBS elastomer, for example epoxidized.
- the minimum thickness E m of the sheath surrounding the reinforcing thread or threads may vary to a very large extent in according to the particular conditions of embodiment of the invention. It is preferably between 1 ⁇ and 2 mm, more preferably between 10 ⁇ and 1 mm.
- the coating layer or sheath can be deposited individually on each of the reinforcement threads (in particular on each of the cables) (as a reminder that these reinforcing threads are unitary or not), as illustrated for example in Figures 1, 2 and 4 commented previously, or collectively deposited on several of the reinforcing son (including several of the cables) arranged appropriately, for example aligned in a main direction, as illustrated for example in Figure 3.
- the composite reinforcement of the invention is prepared according to a specific process comprising at least the step according to which at least one (that is to say one or more) reinforcing thread is subjected to a sheathing operation, preferably by passing through through an extrusion head, by the above-described thermoplastic polymer composition layer comprising the thermoplastic polymer whose Tg (Tgi) is positive, functionalized unsaturated thermoplastic styrene elastomer of which the Tg (Tg 2 ) is negative, and the EPP whose Tg (Tg 3 ) is preferably greater than 150 ° C.
- the above cladding step is conducted in a manner known to those skilled in the art, online and continuously; it consists for example simply to pass the reinforcement wire, through dies of suitable diameter, in an extrusion head heated to an appropriate temperature.
- the reinforcement son or son are preheated, for example by induction or by IR radiation, before passing through the head extrusion.
- the reinforcing son or son and sheathed are then cooled sufficiently to solidify the polymer layer, for example with air or other cold gas, or by passing through a bath of water. followed by a drying step.
- the composite reinforcement according to the invention may optionally undergo heat treatment, directly at the extrusion outlet or subsequently after cooling.
- a sheathed reinforcing thread having a total diameter of approximately 1 mm the covering of a reinforcing wire of diameter close to 0.6 mm, for example of a cable metal consisting simply of two elemental monofilaments of diameter 0.3 mm twisted together (as illustrated for example in Figure 2), by a layer of a polyamide composition, functionalized TPS elastomer and EPP, of maximum thickness equal at approximately 0.4 mm, is produced on an extrusion-cladding line comprising two dies, a first die (counter-die or upstream die) of diameter equal to about 0.65 mm and a second die (or downstream die) of diameter about 0.95 mm, both arranged in an extrusion head heated to about 230 ° C.
- the polyamide mixture, functionalized TPS and PPE can be produced in situ, in the same extrusion head, the three components then being provided for example by three different feed hoppers; according to another possible embodiment, polyamide, TPS and EPP may also be used in the form of a premixed mixture, for example in the form of granules, a single feed hopper then being sufficient.
- the cable At the outlet of this cladding, the cable can be immersed in a tank filled with cold water, for cooling before passage of the receiving coil to the oven for drying.
- the cable (reinforcing wire) is advantageously preheated before passing through the extrusion head, for example by passing through an HF generator or through a heating tunnel.
- the composite reinforcement can for example pass through a tunnel furnace, for example several meters long, to undergo heat treatment under air.
- This treatment temperature is for example between 150 ° C and 300 ° C for treatment times of a few seconds to a few minutes depending on the case (for example between 10 s and 10 min), it being understood that the duration of treatment will be even shorter than the temperature will be high, and that the heat treatment should obviously not lead to reflow or even excessive softening of the thermoplastics used.
- the composite reinforcement of the invention is advantageously cooled, for example in air, to avoid problems of parasitic bonding during its winding on the final receiving coil.
- the previously described steps of the method of the invention may advantageously be completed by a final treatment of three-dimensional crosslinking of the reinforcement, to further reinforce the cohesion of its sheath, particularly in cases where this composite reinforcement is intended for use at a later date.
- relatively high temperature typically above 100 ° C.
- This crosslinking may be carried out by any known means, for example by physical crosslinking means such as ionic or electronic bombardment, or by chemical crosslinking means, for example by introducing a crosslinking agent (for example linseed oil) into the composition.
- a crosslinking agent for example linseed oil
- thermoplastic polymer for example during its extrusion, or by introducing into this composition a vulcanization system (that is to say a sulfur-based crosslinking system).
- Crosslinking may also be obtained during the baking of pneumatic tires (or more generally rubber articles) that the composite reinforcement of the invention is intended to reinforce, thanks to the own crosslinking system present in the diene rubber compositions constituting such bandages (or articles) and coming into contact with the composite reinforcement of the invention.
- the composite reinforcement of the invention can be used directly, that is to say without requiring any additional adhesive system, as a reinforcing element of a diene rubber matrix, for example in a tire. It is advantageously used for the reinforcement of pneumatic tires of all types of vehicles, in particular passenger vehicles or industrial vehicles such as heavy vehicles.
- the appended FIG. 5 shows very schematically (without respecting a specific scale) a radial section of a tire according to the invention for a tourism type vehicle.
- This tire 1 has a crown 2 reinforced by a crown reinforcement or belt 6, two sidewalls 3 and two beads 4, each of these beads 4 being reinforced with a rod 5.
- the crown 2 is surmounted by a tread represented in this schematic figure.
- a carcass reinforcement 7 is wound around the two rods 5 in each bead 4, the upturn 8 of this armature 7 being for example disposed towards the outside of the tire 1 which is shown here mounted on its rim 9.
- the carcass reinforcement 7 is in known manner constituted of at least one sheet reinforced by so-called "radial” cables, for example textile or metal, that is to say that these cables are arranged substantially parallel to each other and s' extend from one bead to the other so as to form an angle of between 80 ° and 90 ° with the median circumferential plane (plane perpendicular to the axis of rotation of the tire which is located halfway between the two beads 4 and goes through the middle of the crown frame 6).
- radial cables for example textile or metal
- This tire 1 of the invention for example has the essential feature that at least one of its crown or carcass reinforcement comprises a composite reinforcement according to the invention.
- it is for example the rods 5 which could consist of a composite reinforcement according to the invention.
- the starting reinforcing thread is a steel cord (known as "steel cord” for pneumatic tires (standard steel 0.7% by weight of carbon), of 1x2 construction consisting of two elementary or monofilaments of diameter 0.30. mm twisted together at a pitch of 10 mm and its diameter is 0.6 mm.
- thermoplastic blend consisting of polyamide 6 (pump flow of about 42 g / min), epoxidized SBS (pump flow of about 12.6 g / min) and PPE (pump flow of about 5.4 g / min) (at 79/21/9 epoxidized polyamide / SBS / PPE weight ratios), is brought to a temperature of 230 ° C. and thus covers the wire (preheated to about 174 ° C. by passage through a generator HF) moving at a speed of 60 m / min.
- the composite reinforcement obtained is immersed continuously in a cooling tank filled with water at 5 ° C to cool its thermoplastic sheath, and then dried by an air nozzle.
- the glass transition temperatures Tgi, Tg 2 and Tg 3 of the three types of polymers used above are respectively equal to approximately + 45 ° C., -95 ° C. and + 215 ° C. (for example, measured according to the procedure which follows: Mettler Toledo DSC "822-2", helium atmosphere, samples previously brought from room temperature (20 ° C) to 100 ° C (20 ° C / min), then cooled rapidly to -140 ° C , before final recording of the DSC curve from -140 ° C to + 300 ° C at 20 ° C / min).
- the assembly is subjected to a heat treatment of a duration of about 100 s, by passing at 3 m / min in a tunnel oven, under ambient atmosphere (air). raised to a temperature of 270 ° C.
- Composite reinforcements according to the invention (reinforcements R-2 as shown diagrammatically in FIG. 2) are thus obtained, consisting of the starting steel cable sheathed with its layer of thermoplastic polymer composition (polyamide 6, PPE and epoxidized SBS elastomer). ) whose adhesion properties are optimal.
- Test 2 Adhesion Tests The quality of the bond between the rubber and the composite reinforcements previously manufactured is then evaluated by a test in which the force necessary to extract the reinforcements from a vulcanized rubber composition, also called a vulcanizate, is measured.
- This rubber composition is a conventional composition used for calendering tire belt metal plies, based on natural rubber, carbon black and conventional additives.
- the vulcanizate is a rubber block consisting of two plates of dimensions 200 mm by 4.5 mm and thickness 3.5 mm, applied one on the other before firing (the thickness of the resulting block is then 7 mm). It is during the manufacture of this block that the composite reinforcements (15 strands in total) are trapped between the two rubber plates in the state green, at equal distance and leaving on both sides of these plates a composite reinforcing end of sufficient length for the subsequent traction.
- the block comprising the reinforcements is then placed in a suitable mold and then cooked under pressure.
- the temperature and the cooking time are adapted to the targeted test conditions and left to the initiative of those skilled in the art; for example, in this case, the firing of the block is carried out at 160 ° C for 15 min, at a pressure of 16 bar.
- the test thus formed of the vulcanized block and the reinforcements is put in place in the jaws of a traction machine adapted to allow each reinforcement to be pulled apart from the rubber, at a speed and given temperature (for example, in the present case at 50 mm / min and 100 ° C).
- the adhesion levels are characterized by measuring the so-called pulling force (denoted Fma X ) to tear off the reinforcements of the specimen (average over 15 pulls).
- the composite reinforcement of the invention by its self-adhesive nature is a particularly interesting alternative, given the very high levels of adhesion obtained, especially at high temperature (100 ° C. or more), composite reinforcements of the prior art sheathed by a thermoplastic material such as polyamide or polyester, requiring in known manner the use of an RFL-type adhesive to ensure their subsequent adhesion to the rubber.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Ropes Or Cables (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020137023224A KR20140046403A (ko) | 2011-02-03 | 2012-01-31 | 고무에 자가 접착성인 중합체의 층으로 쉬딩된 복합 보강재 |
US13/981,769 US9821606B2 (en) | 2011-02-03 | 2012-01-31 | Composite reinforcer sheathed with a layer of polymer that is self-adhesive to rubber |
EP20120703038 EP2670585B1 (fr) | 2011-02-03 | 2012-01-31 | Renfort composite gaine d'une couche de polymere auto-adherente au caoutchouc |
JP2013552179A JP6052555B2 (ja) | 2011-02-03 | 2012-01-31 | ゴムに自己接着性であるポリマー層でシーズされた複合補強材 |
CN201280007186.2A CN103338919B (zh) | 2011-02-03 | 2012-01-31 | 由自粘合至橡胶的聚合物层包覆的复合加强件 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1150858A FR2971188B1 (fr) | 2011-02-03 | 2011-02-03 | Renfort composite gaine d'une couche de polymere auto-adherente au caoutchouc |
FR1150858 | 2011-02-03 |
Publications (1)
Publication Number | Publication Date |
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WO2012104281A1 true WO2012104281A1 (fr) | 2012-08-09 |
Family
ID=44515149
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2012/051518 WO2012104281A1 (fr) | 2011-02-03 | 2012-01-31 | Renfort composite gaine d'une couche de polymere auto-adherente au caoutchouc |
Country Status (7)
Country | Link |
---|---|
US (1) | US9821606B2 (fr) |
EP (1) | EP2670585B1 (fr) |
JP (1) | JP6052555B2 (fr) |
KR (1) | KR20140046403A (fr) |
CN (1) | CN103338919B (fr) |
FR (1) | FR2971188B1 (fr) |
WO (1) | WO2012104281A1 (fr) |
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FR2986456B1 (fr) | 2012-02-08 | 2014-03-07 | Michelin & Cie | Renfort composite gaine d'une couche de polymere auto-adherente au caoutchouc |
-
2011
- 2011-02-03 FR FR1150858A patent/FR2971188B1/fr not_active Expired - Fee Related
-
2012
- 2012-01-31 EP EP20120703038 patent/EP2670585B1/fr active Active
- 2012-01-31 JP JP2013552179A patent/JP6052555B2/ja active Active
- 2012-01-31 CN CN201280007186.2A patent/CN103338919B/zh active Active
- 2012-01-31 US US13/981,769 patent/US9821606B2/en active Active
- 2012-01-31 KR KR1020137023224A patent/KR20140046403A/ko not_active Application Discontinuation
- 2012-01-31 WO PCT/EP2012/051518 patent/WO2012104281A1/fr active Application Filing
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Also Published As
Publication number | Publication date |
---|---|
JP6052555B2 (ja) | 2016-12-27 |
CN103338919B (zh) | 2016-01-20 |
EP2670585B1 (fr) | 2015-04-22 |
JP2014510800A (ja) | 2014-05-01 |
US9821606B2 (en) | 2017-11-21 |
FR2971188B1 (fr) | 2013-03-08 |
CN103338919A (zh) | 2013-10-02 |
KR20140046403A (ko) | 2014-04-18 |
FR2971188A1 (fr) | 2012-08-10 |
EP2670585A1 (fr) | 2013-12-11 |
US20140045983A1 (en) | 2014-02-13 |
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