WO2012086954A3 - 페놀수지 경화 발포체로 이루어진 진공단열재용 심재와 이를 이용한 진공단열재 및 그 제조 방법 - Google Patents

페놀수지 경화 발포체로 이루어진 진공단열재용 심재와 이를 이용한 진공단열재 및 그 제조 방법 Download PDF

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Publication number
WO2012086954A3
WO2012086954A3 PCT/KR2011/009481 KR2011009481W WO2012086954A3 WO 2012086954 A3 WO2012086954 A3 WO 2012086954A3 KR 2011009481 W KR2011009481 W KR 2011009481W WO 2012086954 A3 WO2012086954 A3 WO 2012086954A3
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WO
WIPO (PCT)
Prior art keywords
insulation panel
vacuum insulation
same
phenolic resin
core material
Prior art date
Application number
PCT/KR2011/009481
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English (en)
French (fr)
Other versions
WO2012086954A2 (ko
Inventor
김정근
이응기
이민희
김명희
Original Assignee
(주)엘지하우시스
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by (주)엘지하우시스 filed Critical (주)엘지하우시스
Priority to CN201180062627.4A priority Critical patent/CN103298865B/zh
Priority to US13/993,555 priority patent/US20130260078A1/en
Priority to JP2013546003A priority patent/JP5695212B2/ja
Priority to EP11850529.6A priority patent/EP2657278B1/en
Publication of WO2012086954A2 publication Critical patent/WO2012086954A2/ko
Publication of WO2012086954A3 publication Critical patent/WO2012086954A3/ko

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Classifications

    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78—Heat insulating elements
    • E04B1/80—Heat insulating elements slab-shaped
    • E04B1/803—Heat insulating elements slab-shaped with vacuum spaces included in the slab
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/046—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B7/00—Closing containers or receptacles after filling
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36—After-treatment
    • C08J9/365—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0285—Condensation resins of aldehydes, e.g. with phenols, ureas, melamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00—Buildings or parts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/026—Crosslinking before of after foaming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00—Thermal insulation in general
    • F16L59/06—Arrangements using an air layer or vacuum
    • F16L59/065—Arrangements using an air layer or vacuum using vacuum
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00—Adapting or protecting infrastructure or their operation
    • Y02A30/24—Structural elements or technologies for improving thermal insulation
    • Y02A30/242—Slab shaped vacuum insulation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/10—Insulation, e.g. vacuum or aerogel insulation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23—Sheet including cover or casing
    • Y10T428/231—Filled with gas other than air; or under vacuum

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Electromagnetism (AREA)
  • Acoustics & Sound (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Insulation (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Building Environments (AREA)
  • General Engineering & Computer Science (AREA)

Abstract

본 발명은 페놀수지로 이루어진 진공단열재용 심재와 이를 이용한 진공단열재 및 그 제조 방법에 관한 것으로, 보다 상세하게는 심재를 독립기포율(Closed Cell Content)이 20% 이하인 페놀수지 경화 발포체로 형성하되, 기포의 평균 입경을 50 ~ 500㎛로 조절하고, 각 기포의 표면에 0.5 ~ 30㎛의 미세 홀이 형성되도록 함으로써, 페놀수지 경하 발포체의 기공률이 50% 이상이 되어 우수한 단열 성능을 가지면서도, 구조적 강도를 확보할 수 있고, 제조 원가를 절감할 수 있는 발명에 관한 것이다.
PCT/KR2011/009481 2010-12-24 2011-12-08 페놀수지 경화 발포체로 이루어진 진공단열재용 심재와 이를 이용한 진공단열재 및 그 제조 방법 WO2012086954A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201180062627.4A CN103298865B (zh) 2010-12-24 2011-12-08 由酚醛树脂固化的泡沫形成的用于真空绝缘板的芯材和使用其的真空绝缘板及其制造方法
US13/993,555 US20130260078A1 (en) 2010-12-24 2011-12-08 Core material for a vacuum insulation panel formed of a phenolic resin-cured foam and vacuum insulation panel using same, and method for manufacturing same
JP2013546003A JP5695212B2 (ja) 2010-12-24 2011-12-08 フェノール樹脂硬化発泡体からなる真空断熱材用芯材とそれを用いた真空断熱材及びその製造方法
EP11850529.6A EP2657278B1 (en) 2010-12-24 2011-12-08 Core material for a vacuum insulation panel formed of a phenolic resin-cured foam and vacuum insulation panel using same, and method for manufacturing same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020100134982A KR101263577B1 (ko) 2010-12-24 2010-12-24 페놀수지 경화 발포체로 이루어진 진공단열재용 심재와 이를 이용한 진공단열재 및 그 제조 방법
KR10-2010-0134982 2010-12-24

Publications (2)

Publication Number Publication Date
WO2012086954A2 WO2012086954A2 (ko) 2012-06-28
WO2012086954A3 true WO2012086954A3 (ko) 2012-10-04

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PCT/KR2011/009481 WO2012086954A2 (ko) 2010-12-24 2011-12-08 페놀수지 경화 발포체로 이루어진 진공단열재용 심재와 이를 이용한 진공단열재 및 그 제조 방법

Country Status (6)

Country Link
US (1) US20130260078A1 (ko)
EP (1) EP2657278B1 (ko)
JP (1) JP5695212B2 (ko)
KR (1) KR101263577B1 (ko)
CN (1) CN103298865B (ko)
WO (1) WO2012086954A2 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9057472B2 (en) * 2012-11-01 2015-06-16 Ragui Ghali Insulation material
KR101521685B1 (ko) * 2012-12-06 2015-05-20 (주)엘지하우시스 멜라민 수지 경화 발포체로 이루어진 진공단열재용 심재와 이를 이용한 진공단열재 및 그 제조방법
JP2014214856A (ja) * 2013-04-30 2014-11-17 大日本印刷株式会社 真空断熱材の製造方法、および真空断熱材用外包材
KR102168978B1 (ko) * 2014-02-12 2020-10-22 허친슨 유기 에어로겔을 포함하는 진공 단열 패널
WO2016084763A1 (ja) * 2014-11-26 2016-06-02 旭硝子株式会社 真空断熱材およびその製造方法
WO2017151688A1 (en) * 2016-02-29 2017-09-08 Alienus Film Llc Vacuum insulating film

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JPH11277704A (ja) * 1998-03-31 1999-10-12 Asahi Chem Ind Co Ltd フェノール樹脂発泡体複合パネル
JPH11343681A (ja) * 1998-05-29 1999-12-14 Polyurethan Kasei Kk 連通気泡型ポリウレタンフォーム製断熱材及びその製造方法
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JP2010131848A (ja) * 2008-12-04 2010-06-17 Sekisui Chem Co Ltd フェノール樹脂断熱材

Also Published As

Publication number Publication date
EP2657278B1 (en) 2017-06-21
JP5695212B2 (ja) 2015-04-01
WO2012086954A2 (ko) 2012-06-28
EP2657278A4 (en) 2014-10-22
JP2014503054A (ja) 2014-02-06
EP2657278A2 (en) 2013-10-30
CN103298865A (zh) 2013-09-11
KR101263577B1 (ko) 2013-05-13
CN103298865B (zh) 2016-01-06
US20130260078A1 (en) 2013-10-03
KR20120073011A (ko) 2012-07-04

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