WO2011111661A1 - 電池 - Google Patents
電池 Download PDFInfo
- Publication number
- WO2011111661A1 WO2011111661A1 PCT/JP2011/055262 JP2011055262W WO2011111661A1 WO 2011111661 A1 WO2011111661 A1 WO 2011111661A1 JP 2011055262 W JP2011055262 W JP 2011055262W WO 2011111661 A1 WO2011111661 A1 WO 2011111661A1
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- WIPO (PCT)
- Prior art keywords
- fitting
- core
- battery
- exterior body
- power generation
- Prior art date
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0431—Cells with wound or folded electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/538—Connection of several leads or tabs of wound or folded electrode stacks
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a battery, and more particularly, to a battery including a wound type power generation element in which a strip-shaped electrode sheet is wound.
- FIGS. 9 (a) and 9 (b) there are various types of batteries, one of which is a winding type in which strip-shaped electrode sheets S1 ′ and S2 ′ are wound as shown in FIGS. 9 (a) and 9 (b).
- Power generation element 2 ′ and a battery exterior body 3 ′ that accommodates the power generation element 2 ′, the battery exterior body 3 ′ having a box-shaped exterior body 30 ′ formed by opening one surface, and an exterior What is comprised with the cover body 31 'which obstruct
- an open portion of an exterior main body 30 ′ that houses a power generation element 2 ′ is sealed by a lid 31 ′, and a current collecting member 5 ′ electrically connected to the power generation element 2 ′ includes
- the lid 31 ′ (battery exterior body 3 ′) is fixed to the lid body 31 ′ (battery exterior body 3 ′) while being disposed in the exterior body 30 ′ (inner surface side of the lid body 31 ′). It is electrically connected to an external terminal 4 ′ protruding outward.
- the current collecting member 5 ′ supports the power generating element 2 ′ at a fixed position in the battery outer package 3 ′, and the current collecting member 5 ′ is connected to the current collecting member 5 ′ and the external terminal 4 ′ through the current collecting member 5 ′. It is configured so that electricity from the power generation element 2 ′ can be supplied to a connection object (cable, bus bar, etc.) connected to the external terminal 4 ′ (see, for example, Patent Documents 1, 2, and 3).
- the battery 1 ′ having the above configuration only the current collecting member 5 ′ supports the power generating element 2 ′, and therefore, when a vibration or impact is applied from the outside, the battery exterior body 3 ′ (exterior body 30 ′) As a result, the power generating element 2 'swings. Therefore, when the power generation element 2 ′ is swung, the battery 1 ′ having the above configuration concentrates an impact force and a bending action on the current collecting member 5 ′ that supports the power generation element 2 ′ and has an electric resistance. May rise.
- an insertion member such as a rivet for connecting the current collecting member 5 ′ and the external terminal 4 ′ is inserted through the lid 31 ′, and is inserted into the lid 31 ′.
- an impact force or force is applied to the current collecting member 5 ′ as the power generating element 2 ′ swings.
- a gap is formed between the insertion member connected to the current collecting member 5 ′ and the lid 31 ′, and the inside of the battery exterior body 3 ′ may not be maintained in an airtight state. Accordingly, the battery 1 ′ having the above configuration may be deteriorated in safety when external vibration or impact is applied.
- the entire power generation element 2 ′ is press-fitted into the exterior body 30 ′ to restrict the movement of the power generation element 2 ′, and the burden on the current collecting member 5 ′
- the power generation element 2 ′ repeats expansion and contraction due to charge and discharge, and thus the power generation element 2 ′.
- the power generation element 2 ′ does not come into pressure contact with the inner surface of the battery exterior body 3 ′ (exterior body 30 ′), and the current collecting member 5 ′ supports the power generation element 2 ′.
- the present invention increases the electrical resistance or internal airtightness without applying a concentrated force to the current collecting member connected to the power generation element even when external vibration or impact is applied. It is an object of the present invention to provide a battery capable of preventing deterioration of properties.
- the battery according to the present invention includes a wound-type power generation element in which a strip-shaped electrode sheet and a separator are wound, a box-shaped exterior body having an open portion, and a lid that closes the open portion, A battery outer body that accommodates an element; an external terminal that is disposed outside the battery outer body; and an electric terminal that is disposed within the battery outer body and is fixed to the lid and electrically connected to the power generation element and the external terminal.
- the power generation element includes a winding core having rigidity at the winding center, and at least one end of the winding core is supported on the inner wall surface of the exterior body.
- the power generating element includes a winding core having rigidity at the winding center, and at least one end of the winding core is supported on the inner wall surface of the exterior body, so that an impact or vibration from the outside is generated.
- the power generation element will be maintained at a fixed position without swinging even if the is applied, and a concentrated force (impact force) or the like is applied to the current collecting member fixed to the lid body or bending action is applied. It can be prevented from acting. Therefore, the battery having the above-described configuration can prevent the electrical resistance from increasing or the airtightness of the battery exterior body from being deteriorated.
- the core includes fitting protrusions that protrude outward from both ends orthogonal to the longitudinal direction of the electrode sheet, and the exterior body has a pair of inner wall surfaces facing each other. It is preferable that a recess for fitting is provided on the top, and a protrusion for fitting at both ends of the core is fitted into the recess for fitting.
- the winding core (power generation element) is supported and fixed by the battery exterior body by the fitting of the winding core (fitting protrusion) and the exterior body (fitting recess).
- the power generation element is maintained at a fixed position without swinging, and a concentrated force (impact force) is applied to the current collecting member fixed to the lid.
- a concentrated force impact force
- the battery having the above-described configuration can prevent the electrical resistance from increasing or the airtightness of the battery exterior body from being deteriorated.
- the fitting recess is formed in a groove shape extending from the open portion of the exterior body toward the back side, and the fitting protrusion is formed along the fitting recess. Is preferred. In this way, since many portions of the fitting protrusions are fitted into the fitting recesses, it is possible to reliably fix the power generating element.
- a positioning portion for positioning the fitting protrusion is formed at a terminal portion of the fitting recess on the back side of the exterior body, and the power generation element is arranged in a non-contact manner with at least the inner bottom surface of the exterior body. May be. If it does in this way, a power generation element (core) will interfere with a positioning part (end part of the above-mentioned fitting concave part), and it can prevent certainly a movement of a power generation element also in the direction where the concave part for fitting extends. it can.
- the fitting recess preferably extends from the open portion of the exterior body to a position between the open portion and the inner bottom surface.
- the core may be set to have an axial length such that an outer surface of the fitting projection is pressed against an inner surface of the fitting recess.
- the length in the axial direction may be set such that the outer surface of the fitting protrusion presses the inner surface of the fitting recess.
- the fitting protrusion may have a rectangular shape when viewed from a direction orthogonal to the winding center.
- each of the fitting protrusions is tapered from the electrode sheet side to the tip side, and the fitting recess is formed according to the shape of the fitting protrusion. May be formed.
- the protrusion for fitting has a triangular shape, a semicircular shape, or a trapezoidal shape as viewed from a direction orthogonal to the winding center. If it does in this way, the contact force which acts between the outer surface of the protrusion part for fitting and the inner surface of the recessed part for fitting will act in the crossing direction with respect to the axis line of a core, and a power generation element is made into a core. The movement in the two directions of the axial direction and the direction intersecting the axial direction can be reliably restricted.
- the core includes a core body provided with the fitting protrusions at both ends, and a covering portion covering the entire outer periphery of the core body, and the fitting The joint projecting portion is exposed from the covering portion, the core body is made of a metal material having thermal conductivity, and the covering portion is electrically insulating and elastic, and is made of a synthetic resin or a natural resin. It is preferable. If it does in this way, it will prevent that the edge part used as the winding start of an electrode sheet (electrode sheet for positive electrodes and negative electrodes laminated
- the winding state of the electrode sheet can be maintained in an appropriate state by the elasticity of the covering portion. That is, when the electrode sheet is wound around the core material, the covering portion is elastically deformed by the wrapping force (clamping force) of the electrode sheet on the covering portion, so that the restoring force of the covering portion (radially outward) The force of acting on the electrode sheet can be set to an appropriate state. Furthermore, since the core body is made of a metal material having excellent thermal conductivity, heat accompanying charging / discharging can be transferred to the exterior body having a large surface area through the core body, resulting in excellent heat dissipation. can do.
- the power generation element may be covered with a sheet having electrical insulation, and a resin film may be provided on the outer surface of the sheet.
- the fitting recess is partially formed on the inner wall surface of the exterior body, and at least one of the fitting protrusions provided in the winding core is an axis of the winding core. It may be possible to exit and exit in the direction.
- the winding core includes a biasing unit that biases the fitting protrusion outward.
- the core may be fixed to the inner wall surface of the exterior body by welding.
- the battery of the present invention even if external vibration or impact is applied, the electrical resistance increases or the internal airtightness deteriorates without applying concentrated force to the current collecting member connected to the power generation element. It is possible to achieve an excellent effect that it can be prevented.
- FIG. 2 shows a cross-sectional view taken along the line II of FIG. II-II sectional drawing of FIG. 4 is shown.
- FIG. 5 is a cross-sectional view taken along the line III-III in FIG.
- FIG. 4 is a partial cross-sectional view of a battery according to another embodiment of the present invention, wherein (a) is a partial cross-sectional view of the battery in which a semicircular fitting protrusion and a fitting recess are formed when viewed from the vertical direction.
- (B) is a partial cross-sectional view of a battery in which a trapezoidal fitting protrusion and a fitting recess are formed when viewed from the vertical direction, and (c) is a rectangular shape when viewed from the vertical direction.
- the partial cross-sectional view of the battery in which the protrusion part for fitting and the recessed part for fitting were formed is shown.
- It is explanatory drawing of the conventional battery Comprising: (a) shows the whole perspective view, (b) shows the disassembled perspective view of the state which removed the electric power generation element and the cover body from the exterior main body.
- the battery according to this embodiment is a chargeable / dischargeable lithium ion battery. As shown in FIGS. 1 to 3, such a battery has a power generating element 2 housed in a battery outer package 3 constituting an outer shell of the battery 1, and an external terminal 4 provided outside the battery outer package 3.
- the power generation element 2 is electrically connected to the power source.
- the battery 1 according to this embodiment includes a wound-type power generation element 2 around which belt-shaped electrode sheets S ⁇ b> 1 and S ⁇ b> 2 are wound, and the power generation element 2.
- a battery outer body 3 that accommodates the battery, a power collecting element 5 that is electrically connected to the power generation element 2, and is electrically connected to the current collecting member 5.
- an external terminal 4 disposed outside.
- the power generating element 2 is formed by winding a positive electrode sheet S1 and a negative electrode sheet S2 stacked via a sheet-like separator (not numbered) (hereinafter referred to as an electrode laminate) 20. ing.
- the power generation element 2 according to the present embodiment includes a winding core 21 having rigidity that serves as a winding center of the electrode sheets S1 and S2. That is, the power generation element 2 is formed by winding a belt-shaped electrode laminate 20 around a rigid core 21.
- “having rigidity” means a cantilever support in which one end is supported or a both-end support in which both ends are supported, and the bottom of the lid body 31 and the exterior body 30 described later in the battery exterior body 3. It is preferable that it is made of a metal material such as aluminum or stainless steel.
- the power generating element 2 is slightly displaced in the direction (hereinafter referred to as the short direction) in which the positive electrode sheet S1 and the negative electrode sheet S2 constituting the electrode laminate 20 are orthogonal to the longitudinal direction. From the edge in the short direction of the electrode sheet S2 for the negative electrode on one end side in the short direction (axial center direction of the core 21) while being wound around the core 21. One end portion (one side end portion) of the positive electrode sheet S1 projects in the short direction, and the short side direction of the positive electrode sheet S1 at the other end side in the short direction (axial direction of the core 21). The other end portion (the other side end portion) in the short direction of the electrode sheet S2 for negative electrode protrudes from the end edge of the negative electrode.
- the electrode laminate 20 is wound in a flat shape. Accordingly, the core 21 that is the center of the power generation element 2 is formed in a plate shape.
- the core 21 at least the outer periphery of the region where the electrode laminate 20 (electrode sheets S1 and S2) is wound has electrical insulation, and both ends of the core 21 are battery exterior bodies 3 (exteriors described later).
- the main body 30) is supported by a pair of inner wall surfaces facing each other. That is, the winding core 21 according to the present embodiment is supported at both ends by the inner wall surfaces of the battery outer body 3 facing each other inside the battery outer body 3.
- the winding core 21 has fitting protrusions 210 a and 210 b that protrude outward from both ends orthogonal to the longitudinal direction of the electrode sheets S ⁇ b> 1 and S ⁇ b> 2 (electrode laminate 20).
- electrode laminate 20 Electrode laminate 20
- the outer periphery between the fitting protrusions 210a and 210b has electrical insulation. That is, one end of the core 21 extends outward from one end edge in the short direction of the electrode sheet S1 for positive electrode, and the other end is the other in the short direction of the electrode sheet S2 for negative electrode.
- the outer periphery of the portion (between the fitting protrusions 210a and 210b) surrounded by the electrode laminate 20 has electrical insulation.
- the core 21 includes a core body 211 having the fitting protrusions 210a and 210b at both ends, and a core body 211 between the fitting protrusions 210a and 210b. And a covering portion 212 that covers the entire outer periphery.
- the core body 211 according to the present embodiment is made of a metal material having excellent thermal conductivity.
- the core body 211 according to the present embodiment is formed of the same material (for example, a non-ferrous metal such as aluminum or copper) over the entire length from one end to the other end in the axial direction that coincides with the winding center of the electrode laminate 20.
- the core main body 211 is also formed in a plate shape, and a direction that coincides with the winding center line of the electrode laminate 20 (hereinafter referred to as the width direction). ) Are formed on both ends of the projections 210a and 210b for fitting. That is, the core body 211 includes a plate part 210c having a square shape in plan view, and a pair of fitting protrusions 210a and 210b connected to both ends of the plate part 210c.
- the pair of fitting protrusions 210a and 210b are partially formed with respect to both end portions in the width direction of the plate portion 210c, or the end portions with respect to both end portions in the width direction of the plate portion 210c. It is formed over the entire length. In the battery 1 according to the present embodiment, fitting protrusions 210a and 210b are formed over the entire length of the end of the plate portion 210c.
- the fitting protrusions 210a and 210b are cut from a metal material and formed integrally with the plate portion 210c, or are welded to the plate portion 210c (plate material) to be integrated with the plate portion 210c. In the present embodiment, it is formed by cutting out a metal material together with the plate portion 210c.
- the core body 211 having the above-described configuration is formed in a curved shape in which both end surfaces in a direction orthogonal to the width direction (hereinafter referred to as a vertical direction) protrude flat or outward. It is formed in the curved surface shape which protruded toward the direction.
- the winding core 21 is configured such that the outer surfaces of the fitting protrusions 210a and 210b are in pressure contact with the inner surfaces of the fitting recesses 32a and 32b in a state where the fitting protrusions 210a and 210b are inserted into the fitting recesses 32a and 32b described later. Is set to the length in the width direction (axial direction). And the protrusions 210a and 210b for fitting provided in the both ends of the width direction of the winding core 21 (core main body 211) are formed to taper from the electrode sheets S1 and S2 side toward the front end side.
- each of the fitting protrusions 210a and 210b is formed so that the thickness in the direction perpendicular to the width direction and the vertical direction (hereinafter referred to as the thickness direction) decreases from the base end side to the tip end side.
- the thickness direction the thickness in the direction perpendicular to the width direction and the vertical direction
- the shape seen from the vertical direction has comprised the triangle shape.
- the covering portion 212 is made of a synthetic resin or natural resin having electrical insulation and elasticity.
- the covering portion 212 according to this embodiment is made of styrene-butadiene rubber (SBR).
- SBR styrene-butadiene rubber
- the covering portion 212 is formed with a length equal to or longer than that of the electrode laminate 20 in the width direction on the assumption that the fitting protrusions 210a and 210b made of a metal material are exposed. Since the power generation element 2 according to the present embodiment is formed by winding the electrode laminate 20 in a flat shape, the power generation element 2 is vertically disposed on the covering portion 212 so as to correspond to the curvature of the electrode laminate 20 accompanying the winding. The outer surface of the both ends of a direction is formed in the circular arc surface shape which protruded outward.
- the electrode laminated body 20 is in a close state over the entire circumference of the outer peripheral surface of the core 21 (the covering portion 212) on the innermost side.
- the electric power generation element 2 of the said structure is accommodated in the battery exterior body 3 in the state coat
- an elastic rubber sheet is used as the sheet B, and the rubber sheet B in which the power generation element 2 is sealed is pressed against the inner wall surface of the battery outer package 3. That is, in the battery 1 according to the present embodiment, the winding core 21 is stretched between the side walls 30b and 30c by fitting the fitting protrusions 210a and 210b of the winding core 21 into the fitting recesses 32a and 32b of the exterior body 30.
- the periphery of the sheet (rubber sheet) B in which the power generation element 2 is sealed is brought into pressure contact with the inner wall surface of the battery exterior body 3 to restrain the power generation element 2 from inside and outside.
- the rubber sheet B covered with the power generation element 2 is further covered with a resin film (PP (polypropylene) film or the like) (not shown) and then press-fitted into the exterior body 30.
- a resin film PP (polypropylene) film or the like
- Friction is generated between the power generation element 2 and the battery exterior body 2 so that the power generation element 2 is difficult to be press-fitted.
- the battery exterior body 3 is composed of a box-shaped exterior body 30 formed by opening one surface and a lid body 31 that closes an open portion of the exterior body 30.
- the exterior body 30 is formed by pressing a metal material or welding a metal material.
- the exterior body 30 according to the present embodiment is formed by press-molding a non-ferrous metal, and the material is the same as that of the core 21 (core body 211).
- the exterior body 30 has fitting recesses 32a and 32b formed on a pair of inner wall surfaces facing each other inside. More specifically, the exterior body 30 according to the present embodiment is connected to the bottom 30a having a rectangular shape in plan view, and both ends of the bottom 30a in the longitudinal direction (the direction corresponding to the width direction), A pair of side walls 30b, 30c rising from the bottom portion 30a and a pair of front and rear walls 30d, 30e standing from the bottom portion 30a are connected to both ends in a direction perpendicular to the longitudinal direction of the bottom portion 30a (the thickness direction). The adjacent edges of the side walls 30b, 30c and the front and rear walls 30d, 30e are connected to each other.
- the exterior body 30 is formed in a bottomed rectangular tube shape with one surface open.
- the exterior main body 30 which concerns on this embodiment is formed so that the said recessed parts 32a and 32b for fitting may mutually oppose with respect to each inner surface (inner wall surface) of a pair of side wall 30b, 30c.
- the recesses 32a and 32b for fitting according to the present embodiment are formed so as to extend from the open part of the exterior body 30 toward the back side. That is, each of the fitting recesses 32a and 32b is formed in a groove shape extending in the vertical direction.
- the fitting recesses 32a and 32b are for fitting the fitting protrusions 210a and 210b of the core 21, and are formed according to the form of the fitting protrusions 210a and 210b. Therefore, in the battery 1 according to the present embodiment, the fitting protrusions 210a and 210b provided at both ends of the core 21 are formed in a triangular shape when viewed from the vertical direction. 32a and 32b are also formed to have a triangular shape when viewed from the vertical direction. Thereby, the battery 1 is configured such that the outer surfaces of the fitting protrusions 210a and 210b are in contact with the inner surfaces of the fitting recesses 32a and 32b.
- the core 21 of the battery 1 has the fitting protrusions 210a and 210b fitted into the fitting recesses 32a and 32b, and the outer surfaces of the fitting protrusions 210a and 210b are fitted with the fitting recesses 32a and 210b.
- the length in the axial direction is set so as to be in pressure contact with the inner surface of 32b.
- the apexes (ridge lines) of the fitting protrusions 210a and 210b at both ends. ) (The dimension in the width direction of the core 21 (core main body 211)) coincides with the dimension between the merging portions (vertices) of the two surfaces that define the fitting recesses 32a and 32b at the positions facing each other. It is set slightly longer.
- the battery 1 according to the present embodiment is used for fitting in a state where both end portions (fitting protrusions 210a and 210b) of the core 21 of the power generating element 2 are fitted into the fitting recesses 32a and 32b of the exterior body 30.
- the outer surfaces of the protrusions 210a and 210b are configured to be in pressure contact with the inner surfaces of the fitting recesses 32a and 32b.
- the fitting recesses 32a and 32b are formed so as to extend straight from the open part of the exterior body 30 toward the back side, and therefore the core 21 (core body 211) of the power generating element 2 is formed.
- the plate portion 210c is in a posture along the fitting recesses 32a and 32b, and the fitting protrusions 210a and 210b are inserted into the fitting recesses 32a and 32b from the open side of the exterior body 30.
- the lid body 31 is made of a metal plate, and an outer peripheral edge portion is welded to a peripheral wall of the exterior body 30 in a state where the lid body 31 is disposed in an open portion of the exterior body 30. Therefore, the lid 31 is made of the same material as the exterior body 30 from the viewpoint of welding with the exterior body 30.
- the lid 31 is provided with a through hole H1 for electrically connecting the current collecting member 5 and the external terminal 4 and for inserting a rivet 250 for fixing the current collecting member 5 to the lid 31. (See FIG. 2).
- the lid body 31 according to the present embodiment is formed in a rectangular shape in plan view so as to be longitudinal in the width direction (a direction that coincides with the winding center line of the electrode stack 20 in the power generation element 2).
- the through hole H1 is formed on one end side and the other end side in the width direction.
- the fitting recesses 32a and 32b are positions where the fitting protrusions 210a and 210b are positioned so that the power generating element 2 is not in contact with the inner bottom surface of the exterior body 30 in a state where the fitting protrusions 210a and 210b are fitted.
- the determination part 320 is formed in the terminal part in the back
- the positioning part 320 according to the present embodiment is configured by the terminal ends of the fitting recesses 32a and 32b (see FIG. 4).
- the fitting recesses 32a and 32b are formed up to a midway position in the vertical direction on the inner wall surface, and the terminal ends at the midway position in the vertical direction on the inner wall surface interfere with the fitting protrusions 210a and 210b. It functions as a positioning portion 320 for positioning the fitting protrusions 210a and 210b.
- the battery 1 according to the present embodiment includes a positive electrode and a negative electrode as the current collecting member 5, both of which are arranged in the battery outer package 3 (inner surface side of the lid 31). More specifically, the current collecting member 5 is connected to the power generation element 2 and connected to the connection portion 50, and is fixed to the lid 31. And a connecting portion 51.
- the current collecting member 5 may be one in which the connecting portion 50 and the connecting portion 51 are separately formed and then connected (for example, welded) to each other, but in the current collecting member 5 according to the present embodiment,
- the connecting part 50 and the connecting part 51 are integrally formed. That is, the current collecting member 5 according to the present embodiment is formed by performing a predetermined bending process after cutting a metal plate.
- the connecting portion 50 of the current collecting member 5 is configured to sandwich the positive electrode sheet S1 or the negative electrode sheet S2 of the power generation element 2. That is, as shown in FIGS. 2 and 6, the connecting portion 50 includes a pair of sandwiching pieces 52 a and 52 b that are opposed to each other in the thickness direction and whose ends in the width direction are connected directly or indirectly.
- connection part 50 of the current collecting member 5 is formed in a U shape when viewed from the vertical direction. That is, the ends of the pair of sandwiching pieces 52a and 52b are connected to each other via the band plate-like portion 52c. And the connection part 50 which concerns on this embodiment narrows the space
- the battery 1 according to the present embodiment is provided with two current collecting members 5, each including two pairs of sandwiching pieces 52a and 52b. That is, since the electrode stack 20 is wound around the core 21 in the power generating element 2, the power generating element 2 is divided into two regions in the thickness direction via the core 21. Therefore, each current collecting member 5 is configured to connect independent connection portions 50 to the end portions of the electrode sheets S1 and S2 (laminated portions of the electrode sheets S1 and S2 having the same polarity) in the two regions. Yes.
- the connecting portion 51 is connected to the connecting portion 50 at one end. Since the current collecting member 5 according to the present embodiment includes two connection portions 50, these connection portions 50 merge with each other and are connected to the connecting portion 51.
- the connecting portion 51 is formed in a plate shape, and a through hole H2 corresponding to the through hole H of the lid body 31 is formed therein.
- the battery 1 which concerns on this embodiment is provided with the connecting rod 251 which consists of a metal plate, as shown in FIG.2 and FIG.4.
- the connection rod 251 is provided with a terminal insertion hole H ′ for attaching the external terminal 4, and a through hole H 3 for insertion of the rivet 250.
- the external terminal 4 is formed in a shaft shape.
- a large-diameter portion 40 having a larger diameter than the external terminal 4 is continuously provided at one end portion.
- the external terminal 4 is inserted into the terminal insertion hole H ′ of the connecting rod 251 from the lid body 31 side, and protrudes outward with the large-diameter portion 40 being prevented from coming off. ing.
- the battery 1 according to this embodiment is electrically connected between the current collecting member 5 (connecting portion 51) and the lid 31, between the connection rod 251 and the lid 31, and between the rivet 250 and the lid 31. Insulation packings P1 and P2 for insulation are interposed.
- the battery 1 according to the present embodiment is connected to the first insulating packing P1 that achieves electrical insulation between the current collecting member 5 (connecting portion 51) and the lid 31 and between the rivet 250 and the lid 31.
- a second insulating packing P ⁇ b> 2 is provided to achieve electrical insulation between the flange 251 and the lid 31.
- the first insulating packing P1 and the second insulating packing P2 are arranged inside and outside with the lid 31 in between. And since the 1st insulation packing P1 is interposed between the current collection member 5 (connection part 51) and the cover body 31, the through-hole (not numbered) for inserting the rivet 250 is drilled. Has been. Further, since the second insulating packing P2 is interposed between the connecting rod 251 and the lid 31, a through-hole for inserting the rivet 250 (not numbered) as with the first insulating packing P1. Is perforated (see FIG. 2).
- connection rod 251 is disposed outside the battery exterior body 3 (the outer surface side of the lid body 31), and the current collecting member 5 (the connecting portion 51) is disposed inside the battery exterior body 3.
- the current collecting member 5 is caulked on both ends of the connecting rod 251, the lid 31, and the rivet 250 inserted into the current collecting member 5 (connecting portion 51).
- the power generating element 2 and the external terminal 4 are fixed to the lid 31 and electrically connected via the current collecting member 5 and the rivet 250.
- the first insulating packing P1 and the second insulating packing P2 are interposed between the connecting rod 251, the lid 31 and the current collecting member 5 (connecting portion 51) as described above.
- the rivets 250 are caulked to cause elastic deformation, and the respective components are sealed (the inside of the battery outer package 3 is sealed) while achieving electrical insulation therebetween.
- the battery 1 according to the present embodiment has the above-described configuration, and can prevent an increase in resistance and an airtight defect of the battery outer package 3 even when an impact or vibration is applied from the outside.
- the battery 1 according to the present embodiment includes the winding core 21 having the rigidity in which the power generation element 2 serves as the winding center of the electrode sheets S1 and S2, and the winding core 21 includes the electrode sheet.
- the fitting projections 210a and 210b projecting outward from both ends orthogonal to the longitudinal direction of S1 and S2 are provided at both ends, and at least the outer periphery between the fitting projections 210a and 210b has electrical insulation,
- the main body 30 has fitting recesses 32a and 32b formed on a pair of inner wall surfaces facing each other, and the fitting protrusions 210a and 210b are fitted into fitting recesses 32a and 32b formed on the pair of inner wall surfaces.
- the power generating element 2 expands and contracts with charging and discharging. Be returned Ri, fitting recesses 32a, fit projection 210a, the fitting of the 210b will be maintained for 32b.
- the power generation element 2 is maintained at a fixed position without swinging in the width direction and the thickness direction even when an external impact or vibration is applied, and the current collecting member 5 fixed to the lid 31 is attached to the current collecting member 5.
- the electrical resistance increases, and the airtightness of the battery exterior body 3 ′ (between the first insulating packing P1 and the rivet 250 or between the insulating packing P1 and the lid 31) is increased. It can be prevented from getting worse.
- the core 21 of the battery 1 has the fitting protrusions 210a and 210b fitted into the fitting recesses 32a and 32b, and the outer surfaces of the fitting protrusions 210a and 210b are fitted with the fitting recesses 32a and 210b. Since the length in the axial direction is set so as to be in pressure contact with the inner surface of 32 b, both end portions (fitting protrusions 210 a and 210 b) of the winding core 21 are stretched and supported between the opposing inner wall surfaces of the exterior body 30. Thus, the power generation element 2 can be reliably (strongly) fixed to the exterior body 30.
- both the fitting protrusions 210a and 210b are tapered from the electrode sheets S1 and S2 to the tip side, and the fitting recesses 32a and 32b are the fitting protrusions 210a.
- the contact force (pressure contact force) acting between the outer surface of the fitting projections 210a and 210b and the inner surface of the fitting recesses 32a and 32b is reduced. It will act in the crossing direction with respect to the axis, and the movement of the power generating element 2 in the two directions of the axial direction of the core 21 and the direction crossing the axial direction can be reliably controlled.
- the said recessed parts 32a and 32b for fitting are formed in the groove shape extended toward the back
- the fitting recesses 32a and 32b are fitted so that the electrode sheets S1 and S2 constituting the power generating element 2 are not in contact with the inner bottom surface of the exterior body 30 with the fitting protrusions 210a and 210b fitted. Since the positioning portion 320 for positioning the combined protrusions 210a and 210b is formed at the end portion on the back side of the exterior body 30, the power generating element 2 (the core 21) is connected to the end portions of the fitting recess portions 32a and 32b ( This will interfere with the positioning portion 320), and the movement of the power generating element 2 can be reliably prevented even in the extending direction (vertical direction) of the fitting recesses 32a and 32b.
- the winding core 21 has a core body 211 having the fitting protrusions 210a and 210b at both ends, and the entire outer periphery of the core body 211 between the fitting protrusions 210a and 210b.
- the core body 211 is made of a metal material having excellent thermal conductivity
- the cover 212 is made of a synthetic resin (SBR) having electrical insulation and elasticity.
- SBR synthetic resin
- the winding state of the electrode sheets S1 and S2 can be maintained in an appropriate state by the elasticity of the covering portion 212. That is, when the electrode sheets S1 and S2 are wound around the core 21, the covering portion 212 is elastically deformed by the winding force (tightening force) of the electrode sheets S1 and S2 acting on the covering portion 212.
- the battery 1 which concerns on this embodiment can make the winding state of electrode sheet S1, S2 into an appropriate state with the restoring force (force which acts toward radial direction outward) of the coating
- the core body 211 is made of a metal material having excellent thermal conductivity, and therefore heat accompanying charging / discharging is transmitted to the exterior body 30 having a large surface area through the core body 211. Can be made excellent in heat dissipation.
- the lithium ion battery has been described.
- the present invention is not limited to this, and may of course be a battery such as a nickel metal hydride battery or a nickel cadmium battery. That is, it is only necessary that the current collecting member 5 arranged inside and outside the lid 31 and the external terminal 4 are electrically connected and the current collecting member 5 is fixed to the lid 31.
- the fitting recesses 32 a and 32 b extending from the open portion of the exterior body 30 toward the back are formed on the opposing inner wall surfaces of the exterior body 30 and the fitting protrusions 210 a and 210 b of the core 21 are formed.
- 210b is formed in a manner along the fitting recesses 32a and 32b.
- the present invention is not limited to this.
- fitting protrusions 210a and 210b of the winding core 21 are formed in a shorter direction in the longitudinal direction than the fitting recesses 32a and 32b, and the fitting protrusions 210a and 210b are formed in the fitting recesses 32a and 32b. May be formed so as to be in pressure contact with a part of the outer peripheral body 30, and the fitting recesses 32a and 32b of the outer body 30 are partially formed and the fitting protrusion of the core 21 is formed. 10a, 210 b of the fitting recess 32a, may be fitted can be formed in 32b.
- the outer surfaces of the fitting protrusions 210a and 210b are fitted into the fitting recesses 32a and
- the modes of the fitting recesses 32a and 32b and the fitting protrusions 210a and 210b can be variously changed so as to be in contact with or substantially in contact with the inner surface of 32b.
- the fitting protrusions 210a and 210b to be fitted into the fitting recesses 32a and 32b are configured at both ends of the core body 211 made of the same material, the present invention is not limited thereto.
- the recesses 32a and 32b for fitting are partially formed on the opposing inner wall surfaces, and at least one of the fitting protrusions 210a and 210b provided at both ends of the core 21 is movable in the axial direction.
- It may be configured to be capable of withdrawing / withdrawing in the battery outer package 3 (exterior main body 30).
- the fitting protrusions 210a and 210b are retracted, and the fitting protrusions 210a and 210b are partially formed.
- the fitting protrusions 210a and 210b protrude outward and fit into the fitting recesses 32a and 32b.
- urging means for urging the fitting protrusions 210a and 210b outward in the core body 211.
- the fitting protrusions 210a and 210b are formed in a triangular shape as viewed from the vertical direction so that the dimension in the thickness direction decreases from the base end side toward the tip end side.
- the present invention is not limited to this.
- the fitting protrusions 210a and 210b are formed in a semicircular shape when viewed from the vertical direction, and the fitting recesses 32a and 32b are made to correspond to the fitting protrusions 210a and 210b. It may be formed like a semicircular groove when viewed from the vertical direction, or as shown in FIG.
- the fitting protrusions 210a and 210b are formed in a trapezoidal shape when viewed from the vertical direction.
- the combination recesses 32a and 32b may be formed in a triangular shape or a trapezoidal shape when viewed from above.
- fitting protrusions 210a and 210b are not limited to those formed so that the dimension in the thickness direction decreases from the proximal end side to the distal end side.
- the fitting protrusions 210a and 210b may be formed in a square shape when viewed from the vertical direction, and the fitting recesses 32a and 32b may be formed in a shape corresponding to this.
- connection part 50 of the current collection member 5 is comprised by a strip
- the current collecting member 5 includes a pair of sandwiching pieces 52a ′ and 52b ′ that sandwich the ends of the electrode sheets S1 and S2, as shown in FIG. It may be.
- the current collecting member 5 is a strip piece connected to the connecting portion 51 as a configuration for electrically connecting to the power generating element 2 (a configuration corresponding to the connecting portion 50 in the above embodiment).
- 501 and a strip member 501 and a sandwiching member 502 that sandwiches the ends of the electrode sheets S1 and S2 of the power generating element 2 may be provided. That is, the current collecting member 5 includes a strip piece 501 disposed along the end portions of the electrode sheets S ⁇ b> 1 and S ⁇ b> 2 constituting the power generation element 2, and a connection in which the strip piece 501 is continuously provided and fixed to the lid 31.
- the current collector member main body 500 having the portion 51 and the sandwiching member 502 that sandwiches the end portions of the electrode sheets S1 and S2 together with the strip 501 may be used.
- the sandwiching member 502 is formed with a pair of sandwiching pieces 52 a ′ and 52 b ′ whose one ends are connected to each other and facing each other. That is, the sandwiching member 502 is formed by folding a single metal plate or metal sheet in two, thereby forming a pair of sandwiching pieces 52a 'and 52b' with the folding ridge line as a boundary.
- this type of current collecting member 5 includes a pair of sandwiching pieces 52a ′ and 52b, each having an end portion of the electrode sheets S1 and S2 and a strip piece 501 disposed along the end portions of the electrode sheets S1 and S2.
- a pair of sandwiching pieces 52a ′ and 52b each having an end portion of the electrode sheets S1 and S2 and a strip piece 501 disposed along the end portions of the electrode sheets S1 and S2.
- the covering portion 21 of the core 21 is made of SBR, but may be made of other synthetic resin or natural resin. That is, when the core 21 is composed of the core body 211 and the covering portion 212, the covering portion 212 may be made of a material having elasticity and electrical insulation.
- the core 21 was comprised with the core main body 211 and the coating
- the battery 1 including one power generation element 2 has been described.
- the present invention is not limited to this.
- the battery 1 including two or more power generation elements 2 may be used.
- each power generating element 2 is provided with a rigid core 21, and the fitting recesses 32 a and 32 b into which the fitting protrusions 210 a and 210 b of the core 21 of each power generating element 2 are fitted are provided as the power generating element 2 (core 21. ) May be provided together with the arrangement.
- the external terminal 4 is attached to the connection rod 251, and the external terminal 4 is connected to the power generation element 2 via the connection rod 251, the rivet 250, and the current collecting member 5.
- the external terminal 4 may be formed of a rivet material, and the end portion of the rivet material in the exterior main body 30 (in the lid body 31) may be connected to the connection portion 51 of the current collecting member 5.
- the power generation element 2 is sealed while the winding core 21 is stretched between the side walls 30b and 30c by fitting the fitting protrusions 210a and 210b of the winding core 21 into the fitting recesses 32a and 32b of the exterior body 30.
- the power generation element 2 is constrained from inside and outside by pressing the periphery of the sheet (rubber sheet) B against the inner wall surface of the battery exterior body 3, but the invention is not limited to this.
- the core 21 can be stretched between the side walls 30b and 30c by fitting the fitting protrusions 210a and 210b into the fitting recesses 32a and 32b of the exterior body 30.
- the battery exterior body 3 is made of metal, the power generation element 2 is wrapped in a resin sheet having electrical insulation so that the power generation element 2 and the battery exterior body 3 are electrically insulated. You may make it accommodate in the battery exterior 3.
- the fitting protrusions 210a and 210b are fitted into the fitting recesses 32a and 32b, and the outer surfaces of the fitting protrusions 210a and 210b are in pressure contact with the inner surfaces of the fitting recesses 32a and 32b (the fitting protrusions).
- the axial length of the core 21 is set so that the outer surfaces of the portions 210a and 210b act on the inner surfaces of the fitting recesses 32a and 32b).
- the length is not limited to this, and the winding is not limited thereto.
- the core 21 has the fitting protrusions 210a and 210b fitted into the fitting recesses 32a and 32b, and the outer surfaces of the fitting protrusions 210a and 210b contact or substantially contact the inner surfaces of the fitting recesses 32a and 32b (fitting).
- the axial length may be set so that the outer surfaces of the combined protrusions 210a and 210b come into contact with the inner surfaces of the fitting recesses 32a and 32b without applying a pressing force).
- the winding core 21 is supported (fixed) on the exterior body 30 (battery exterior body 3) by fitting the fitting protrusions 210a and 210b into the fitting recesses 32a and 32b.
- a convex portion is formed on the inner wall surface of the exterior body 30 and a concave portion is formed at the end of the core 21, and the convex portion of the exterior body 30 is fitted into the concave portion.
- the core 21 may be supported (fixed) on the exterior body 30.
- the support of the core 21 by the exterior body 30 is not limited to the concave-convex fitting.
- both ends of the core 21 are supported (fixed) on the inner wall surface of the exterior body 30 by welding or the like. Also good.
- both ends of the core 21 are supported by the exterior body 30.
- the core 21 is supported (fixed) on the inner wall surface of the exterior body 30 by welding or the like. ), It is not limited to the one in which both ends of the winding core 21 are supported, and one end of the winding core 21 may be supported on the inner wall surface of the exterior body 30.
- SYMBOLS 1 Lithium ion secondary battery, 2 ... Power generation element, 3 ... Battery exterior body, 4 ... External terminal, 5 ... Current collecting member, 20 ... Electrode laminated body, 21 ... Core, 30 ... Exterior body, 30a ... Bottom part, 30b, 30c ... side wall, 30d, 30e ... front and rear wall, 31 ... lid, 32a, 32b ... recessed part for fitting, 40 ... large diameter part, 50 ... connecting part, 51 ... connecting part, 52a, 52b ... clamping piece 210a, 210b ... projecting part for fitting, 210c ... plate part, 211 ... core body, 212 ... covering part, 250 ... rivet, 251 ... connecting rod, 320 ... positioning part, P1, P2 ... insulating packing, H1, H2 , H3, H '... hole, B ... sheet
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Secondary Cells (AREA)
- Connection Of Batteries Or Terminals (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Primary Cells (AREA)
Abstract
Description
Claims (15)
- 帯状の電極シートとセパレータとが巻回された巻回型の発電要素と、
開放部を有する箱状の外装本体及び前記開放部を閉塞する蓋体を含み、前記発電要素を収容する電池外装体と、
前記電池外装体の外部に配置された外部端子と、
前記電池外装体内に配置され、前記蓋体に対して固定されるとともに前記発電要素及び前記外部端子に電気的に接続された集電部材とを備え、
前記発電要素は、巻回中心に剛性を有する巻芯を備え、該巻芯の少なくとも一端が外装本体の内壁面に支持されている電池。 - 前記巻芯は、前記電極シートの長手方向と直交する両端のそれぞれから外方に突出した嵌合用突出部を備え、
前記外装本体は、内部で対向する一対の内壁面上に嵌合用凹部を備え、前記巻芯の両端にある嵌合用突出部が前記嵌合用凹部に嵌入されている請求項1に記載の電池。 - 前記嵌合用凹部は、前記外装本体の開放部から奥側に向けて延びる溝状に形成され、前記嵌合用突出部が前記嵌合用凹部に沿って形成されている請求項2に記載の電池。
- 前記嵌合用凹部における前記外装本体の奥側にある終端部に前記嵌合用突出部を位置決めする位置決部が形成され、前記発電要素が前記外装本体の少なくとも内底面と非接触で配置されている請求項3に記載の電池。
- 前記嵌合用凹部は、前記外装本体の開放部から該開放部と内底面との間の位置まで延びている請求項4に記載の電池。
- 前記巻芯は、前記嵌合用突出部の外面が前記嵌合用凹部の内面に圧接するように軸線方向の長さが設定されている請求項2乃至5の何れか1項に記載の電池。
- 前記巻芯は、前記嵌合用突出部の外面が前記嵌合用凹部の内面を押圧するように軸線方向の長さが設定されている請求項2乃至5の何れか1項に記載の電池。
- 前記嵌合用突出部は、前記巻回中心と直交する方向から見て方形状である請求項2乃至7の何れか1項に記載の電池。
- 前記嵌合用突出部のそれぞれは、前記電極シート側から先端側に向けて先細りに形成され、前記嵌合用凹部は、前記嵌合用突出部の形状に即して形成されている請求項2乃至5の何れか1項に記載の電池。
- 前記嵌合用突出部は、前記巻回中心と直交する方向から見て三角形状、半円状、又は台形状である請求項9に記載の電池。
- 前記巻芯は、両端部のそれぞれに前記嵌合用突出部を備えた芯本体と、該芯本体の外周全周を覆う被覆部とを備え、
前記嵌合用突出部は、前記被覆部から露出し、
前記芯本体は、熱伝導性を有する金属材料で構成され、
前記被覆部は、電気絶縁性及び弾性を有し、合成樹脂又は天然樹脂で構成されている請求項2乃至10の何れかに記載の電池。 - 前記発電要素は、電気絶縁性を有するシートで被覆され、該シートの外表面に樹脂フィルムを備える請求項2乃至11の何れか1項に記載の電池。
- 前記嵌合用凹部は、前記外装本体の内壁面に部分的に形成され、前記巻芯が備える前記嵌合用突出部の少なくとも何れか一方は、該巻芯の軸線方向で出退可能である請求項2乃至12の何れか1項に記載の電池。
- 前記巻芯は、内部に前記嵌合用突出部を外方に付勢する付勢手段を備える請求項13に記載の電池。
- 前記巻芯は、溶接によって前記外装本体の内壁面に固定される請求項1に記載の電池。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11753319.0A EP2546916B1 (en) | 2010-03-12 | 2011-03-07 | Battery |
US13/583,002 US20120328924A1 (en) | 2010-03-12 | 2011-03-07 | Battery |
CN201180016451.9A CN102859776B (zh) | 2010-03-12 | 2011-03-07 | 电池 |
KR1020127025449A KR101862232B1 (ko) | 2010-03-12 | 2011-03-07 | 전지 |
JP2012504451A JP5737631B2 (ja) | 2010-03-12 | 2011-03-07 | 電池 |
Applications Claiming Priority (2)
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JP2010-055361 | 2010-03-12 | ||
JP2010055361 | 2010-03-12 |
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WO2011111661A1 true WO2011111661A1 (ja) | 2011-09-15 |
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PCT/JP2011/055262 WO2011111661A1 (ja) | 2010-03-12 | 2011-03-07 | 電池 |
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US (1) | US20120328924A1 (ja) |
EP (1) | EP2546916B1 (ja) |
JP (1) | JP5737631B2 (ja) |
KR (1) | KR101862232B1 (ja) |
CN (1) | CN102859776B (ja) |
TW (1) | TWI458159B (ja) |
WO (1) | WO2011111661A1 (ja) |
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JP2013222598A (ja) * | 2012-04-16 | 2013-10-28 | Mitsubishi Motors Corp | 電池 |
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JPWO2013046349A1 (ja) * | 2011-09-28 | 2015-03-26 | 日立オートモティブシステムズ株式会社 | 角形電池 |
JP2016058224A (ja) * | 2014-09-09 | 2016-04-21 | 株式会社Gsユアサ | 蓄電素子 |
JP2016149370A (ja) * | 2016-03-28 | 2016-08-18 | 株式会社Gsユアサ | 蓄電素子、電極体及び芯材 |
WO2016174992A1 (ja) * | 2015-04-28 | 2016-11-03 | 日立オートモティブシステムズ株式会社 | 二次電池 |
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Cited By (13)
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JP2013041741A (ja) * | 2011-08-15 | 2013-02-28 | Toyota Industries Corp | 二次電池 |
JPWO2013046349A1 (ja) * | 2011-09-28 | 2015-03-26 | 日立オートモティブシステムズ株式会社 | 角形電池 |
JP2013077496A (ja) * | 2011-09-30 | 2013-04-25 | Gs Yuasa Corp | 蓄電素子 |
JP2013110045A (ja) * | 2011-11-24 | 2013-06-06 | Hitachi Ltd | 非水電解液捲回型二次電池 |
WO2013077156A1 (ja) * | 2011-11-24 | 2013-05-30 | 株式会社 日立製作所 | 非水電解液捲回型二次電池 |
EP2783406A1 (en) * | 2011-11-25 | 2014-10-01 | Shenzhen BYD Auto R&D Company Limited | Electric connector and battery comprising the same |
EP2783406A4 (en) * | 2011-11-25 | 2015-04-08 | Shenzhen Byd Auto R & D Co Ltd | ELECTRICAL CONNECTOR AND BATTERY COMPRISING THE SAME |
US9698405B2 (en) | 2011-11-25 | 2017-07-04 | Shenzhen Byd Auto R&D Company Limited | Electric connector and battery comprising the same |
JP2013222598A (ja) * | 2012-04-16 | 2013-10-28 | Mitsubishi Motors Corp | 電池 |
JP2016058224A (ja) * | 2014-09-09 | 2016-04-21 | 株式会社Gsユアサ | 蓄電素子 |
WO2016174992A1 (ja) * | 2015-04-28 | 2016-11-03 | 日立オートモティブシステムズ株式会社 | 二次電池 |
JPWO2016174992A1 (ja) * | 2015-04-28 | 2017-12-28 | 日立オートモティブシステムズ株式会社 | 二次電池 |
JP2016149370A (ja) * | 2016-03-28 | 2016-08-18 | 株式会社Gsユアサ | 蓄電素子、電極体及び芯材 |
Also Published As
Publication number | Publication date |
---|---|
TWI458159B (zh) | 2014-10-21 |
EP2546916B1 (en) | 2017-09-27 |
TW201205926A (en) | 2012-02-01 |
JPWO2011111661A1 (ja) | 2013-06-27 |
CN102859776A (zh) | 2013-01-02 |
EP2546916A1 (en) | 2013-01-16 |
US20120328924A1 (en) | 2012-12-27 |
CN102859776B (zh) | 2016-01-20 |
JP5737631B2 (ja) | 2015-06-17 |
KR101862232B1 (ko) | 2018-05-29 |
KR20130016242A (ko) | 2013-02-14 |
EP2546916A4 (en) | 2016-07-20 |
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