WO2011105924A1 - Суспензионный концентрат гербицидной композиции - Google Patents
Суспензионный концентрат гербицидной композиции Download PDFInfo
- Publication number
- WO2011105924A1 WO2011105924A1 PCT/RU2010/000432 RU2010000432W WO2011105924A1 WO 2011105924 A1 WO2011105924 A1 WO 2011105924A1 RU 2010000432 W RU2010000432 W RU 2010000432W WO 2011105924 A1 WO2011105924 A1 WO 2011105924A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bis
- dimethoxypyrimidin
- suspension concentrate
- acid
- carbamide
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 24
- 239000004546 suspension concentrate Substances 0.000 title claims abstract description 18
- 239000004009 herbicide Substances 0.000 title claims abstract 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000004202 carbamide Substances 0.000 claims abstract description 20
- 235000013877 carbamide Nutrition 0.000 claims abstract description 20
- OILBJPSVPFZCBL-UHFFFAOYSA-N 2,6-bis(4,6-dimethoxypyrimidin-2-yl)-3-hydroxybenzoic acid Chemical compound COC1=NC(=NC(=C1)OC)C1=C(C(=O)O)C(=CC=C1O)C1=NC(=CC(=N1)OC)OC OILBJPSVPFZCBL-UHFFFAOYSA-N 0.000 claims abstract description 11
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 10
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000013543 active substance Substances 0.000 claims abstract description 8
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- VPTUPAVOBUEXMZ-UHFFFAOYSA-N (1-hydroxy-2-phosphonoethyl)phosphonic acid Chemical compound OP(=O)(O)C(O)CP(O)(O)=O VPTUPAVOBUEXMZ-UHFFFAOYSA-N 0.000 claims description 7
- 229910000975 Carbon steel Inorganic materials 0.000 abstract description 14
- 239000010962 carbon steel Substances 0.000 abstract description 14
- 230000007797 corrosion Effects 0.000 abstract description 10
- 238000005260 corrosion Methods 0.000 abstract description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 9
- 229910052708 sodium Inorganic materials 0.000 abstract description 9
- 239000011734 sodium Substances 0.000 abstract description 9
- 230000035699 permeability Effects 0.000 abstract description 8
- 238000009736 wetting Methods 0.000 abstract description 6
- 241000196324 Embryophyta Species 0.000 abstract description 5
- 229940083082 pyrimidine derivative acting on arteriolar smooth muscle Drugs 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 150000003230 pyrimidines Chemical class 0.000 abstract description 4
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 3
- 235000009566 rice Nutrition 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 abstract 2
- 240000007594 Oryza sativa Species 0.000 abstract 1
- XOHQAXXZXMHLPT-UHFFFAOYSA-N ethyl(phosphonooxy)phosphinic acid Chemical compound CCP(O)(=O)OP(O)(O)=O XOHQAXXZXMHLPT-UHFFFAOYSA-N 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 14
- RYVIXQCRCQLFCM-UHFFFAOYSA-N bispyribac Chemical compound COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C(O)=O)=N1 RYVIXQCRCQLFCM-UHFFFAOYSA-N 0.000 description 11
- 239000000725 suspension Substances 0.000 description 9
- -1 polyoxyethylene Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000003905 agrochemical Substances 0.000 description 6
- 229960001484 edetic acid Drugs 0.000 description 6
- 239000005488 Bispyribac Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 230000002528 anti-freeze Effects 0.000 description 5
- DQNHKYDRCUDFBR-UHFFFAOYSA-N COC1=NC(=NC(=C1)OC)[Na] Chemical compound COC1=NC(=NC(=C1)OC)[Na] DQNHKYDRCUDFBR-UHFFFAOYSA-N 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- FUHMZYWBSHTEDZ-UHFFFAOYSA-M bispyribac-sodium Chemical compound [Na+].COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C([O-])=O)=N1 FUHMZYWBSHTEDZ-UHFFFAOYSA-M 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- NXQDBZGWYSEGFL-UHFFFAOYSA-N Anilofos Chemical compound COP(=S)(OC)SCC(=O)N(C(C)C)C1=CC=C(Cl)C=C1 NXQDBZGWYSEGFL-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- CWKHJADKQVHTAU-UHFFFAOYSA-N difluoromethanesulfonamide Chemical class NS(=O)(=O)C(F)F CWKHJADKQVHTAU-UHFFFAOYSA-N 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 125000000714 pyrimidinyl group Chemical group 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
Definitions
- the invention relates to chemical weed control agents, in particular to aqueous suspension herbicidal compositions based on pyrimidine derivatives, for example, 2,6-bis (4,6-dimethoxypyrimidin-2-yl) sodium oxybenzoate, used for processing rice crops (Handbook of pesticides and agrochemicals approved for use on the territory of the Russian Federation in 2009) [1].
- pyrimidine derivatives for example, 2,6-bis (4,6-dimethoxypyrimidin-2-yl) sodium oxybenzoate
- Herbicidal compositions of pyrimidine derivatives are known, in particular 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) oxybenzoic acid or 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) sodium hydroxybenzoate to protect rice crops from weeds (US Pat. USA jNs 4248619, US Pat. RF JO 2028294) [2, 3].
- herbicidal compositions containing 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) sodium oxybenzoate for example anilophos (WO 2006072359) [4] or derivatives of difluoromethanesulfonamide (WO 2007079965) [5], or growth regulators, for example, 5-ethyl-5-hydroxymethyl-2 (furyl-2) -1,3-dioxane (US Pat. "22949) [6].
- composition of the ⁇ 400 SK aqueous agricultural chemical suspension [1] contains 400 g of active ingredient 2,6-bis (4,6-dimethoxypyrimidin-2-yl) sodium oxybenzoate, 16 g of sodium bicarbonate and 1.8 g of sodium carbonate as a buffering component, 10 g of polyoxyethylene styryl phenyl ether sulfate and 3 g of polyoxyethylene styryl phenyl ether as surfactants, 100 g of propylene glycol as antifreeze, 1.5 g of xanthan howling gum as a thickener and 467.7 g of water.
- the solubility of the active substance in this known composition was 14 g / l, pH 7.6 - 8.3, viscosity - 520 MPa ' s, surface tension - 45 - 60 nm 10 ⁇ 3 , initial contact angle, 68 ° - 71 °, and the final contact angle of wetting, 43 ° - 60 °.
- a high rate of corrosion of carbon steel was also noted - 0.0225 g / m * h and its permeability - 0.029 mm / year in the medium of the known composition of an aqueous agricultural-chemical suspension.
- the aim of the present invention is to provide a new suspension concentrate of the herbicidal composition based on the known pyrimidine derivatives with high physicochemical and operational properties, in particular low surface tension and contact angle, lowered corrosion activity with respect to structural materials.
- the object of the invention is a suspension concentrate of the herbicidal composition, which contains a combination of two agrochemically active components of 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) oxybenzoic acid and 2,6-bis- (4,6- dimethoxypyrimidin-2-yl) sodium oxybenzoate with carbamide in a molar ratio of the latter of 0.93 - 1, 79 to the active substance.
- the suspension concentrate of the herbicidal composition may contain a complex salt with urea in the presence of hydroxyethylene diphosphonic acid and the disodium salt of ethylenediaminetetraacetic acid, at least one of the agrochemically active components.
- a combination of two agrochemically active components of 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) hydroxybenzoic acid and 2,6-bis- (4,6-dimethoxypyrimidin-2-yl ) sodium oxybenzoate with urea, as well as their ratio 90% is optimal, as a result of which the resulting suspension concentrate of the herbicidal composition in which the liquid phase is an aqueous solution of urea, 2,6-bis- (4,6-dimethoxy-pyrimidin-2-yl) sodium oxybenzoate and 2.6 -bis- (4,6-dimethoxy-pyrimidin-2-yl) hydroxybenzoic acid, and solid - particles
- 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) oxybenzoic acid or 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) oxybenzoic acid and 2,6-bis- (4, 6-dimethoxypyrimidin-2-yl) sodium oxybenzoate has a surface tension not exceeding 32 n / m * 10 "3 and the initial and final contact angles of contact not higher than 56 ° and
- the technical result achieved is a suspension-150 concentrate of the herbicidal composition with a surface tension of 28 - 32 n / m * 10 " , the initial and final contact angles of contact not higher than 56 ° and 33 °, the corrosion rate is 0.00152 g / m 2 per hour, the permeability of carbon steel is 0.001 1 mm / year of carbon steel in a suspension concentrate medium, which simplifies dispersion, improves the distribution of the preparation over the sheet surface, significantly increasing the wetted surface area with reduced corrosion activity with respect to glerodistoy steel.
- Embodiments of the invention confirming its industrial applicability are illustrated by examples.
- Example 1 In a ball mill load 418 kg of technical sodium bispiribac containing 95% 2,6-bis- (4,6-dime
- the surface tension was 31, 4, n / m * 10 " , the contact angle: initial - 56 °, final - 32 °, corrosion rate of carbon steel 190 - 0.00152 g / m hour, permeability of carbon steel - 0.0011 mm / year.
- Example 2 In a ball mill, 476 kg of water, 100 kg of technical carbamide (C AS 57-13-6) GOST 2081-92, 40.6 kg of technical sodium bispyribac containing 95% of 2.6-bis- (4 6-dime
- centrate of the herbicidal composition contains 400 g / l of a combination of 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) hydroxybenzoic acid, 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) sodium hydroxybenzoate converted to 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) hydroxybenzoic acid, including 4.2 g / l of the complex salt of urea with 2,6-bis-
- Example 3 450 kg of water, 67.8 kg of technical carbamide ( ⁇ AS 57-13-6) GOST 2081-92, 302.9 kg of technical sodium bispyribac containing 95% 2,6-bis- (4) are loaded into a ball mill 6-dimethoxypyrimidin-2-yl) sodium oxybenzoate (CAS 125401-92-4), 210 kg of bispiribac acid containing 95% of 2,6-bis- (4,6-dimethoxy-pyrimidin-2-yl) hydroxybenzoic acid ( CAS 125401-92-5), 1 1, 5 kg of the wetting agent MPS (TU 2483-023-45663862-2005).
- the suspension concentrate of the herbicidal composition obtained after the second grinding contains 400 g / l of a combination of 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) oxybenzoic acid, 2,6-bis- (4,6-dimethoxypyrimidine -2-yl) sodium oxybenzoate in terms of 2.6-bis- (4,6-dimethoxypyrimidin-2-yl) hydroxybenzoic acid, including 4.2 g / l of the complex salt of urea with 2.6-bys- ( 4,6-dimethoxy-sipyrimidin-2-yl) hydroxybenzoic acid.
- the surface tension was 32 n / m * 10 " , the contact angle: initial - 54 °, final - 30 °, corrosion rate of carbon steel - 0.00152 g / m ' hour, permeability of carbon steel - 0.0011 mm / year.
- Example 4 450 kg of water, 19.2 kg of carbamide of technical GOST 2081-92 (CAS 57-13-6), 102.8 kg of technical sodium bispyribac containing 95% 2,6-bis- are loaded into a ball mill (4, 6- dimethoxypyrimidin-2-yl) sodium oxybenzoate (CAS 125401-92-4), 8.2 kg of technical bispiribac acid containing 95% of 2,6-bis (4,6-dimethoxypyrimidin-2-yl) hydroxybenzoic acid (CAS 125401 -92-5), 13.5 kg of the wetting agent MPS (TU 2483-023-45663862-2005).
- the suspension concentrate of the herbicidal composition obtained after the second grinding contains 100 g / l of a combination of 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) hydroxybenzoic acid, 2,6-bis- (4,6 -dimethoxypyrimidin-2-yl) sodium oxibenzoate in terms of 2,6-bis- (4,6-dimethoxypyrimidin-2-yl) hydroxybenzoic acid, including 4.2 g / l of the complex salt of carbamide with 2.6 bis- (4,6-dimethoxypyrimidin-2-yl) hydroxybenzoic acid.
- the surface tension was 32 n / m * 10 " , the contact angle: initial - 54 °, final - 30 °, the corrosion rate of carbon steel - 0.00152 g / m hour, the permeability of carbon steel - 0.001 1 mm / year.
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201080064728.0A CN102770025B (zh) | 2010-02-24 | 2010-08-04 | 除草剂组合物的悬浮液浓缩物 |
| BR112012019465A BR112012019465A8 (pt) | 2010-02-24 | 2010-08-04 | Concentrado de suspensão de composição herbicida |
| EA201101247A EA019718B1 (ru) | 2010-02-24 | 2010-08-04 | Суспензионный концентрат гербицидной композиции |
| KR1020127017531A KR101596764B1 (ko) | 2010-02-24 | 2010-08-04 | 제초제 조성물의 현탁액 농축물 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2010105982 | 2010-02-24 | ||
| RU2010105982/13A RU2440731C2 (ru) | 2010-02-24 | 2010-02-24 | Суспензионный концентрат гербицидной композиции и способ его получения |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2011105924A1 true WO2011105924A1 (ru) | 2011-09-01 |
Family
ID=44507073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/RU2010/000432 WO2011105924A1 (ru) | 2010-02-24 | 2010-08-04 | Суспензионный концентрат гербицидной композиции |
Country Status (8)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2015230646B2 (en) * | 2014-03-13 | 2020-01-16 | Jura Elektroapparate Ag | Method for cleaning and/or disinfecting a milk-carrying system of a coffee machine, and coffee machine |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2028294C1 (ru) * | 1987-12-22 | 1995-02-09 | Кумиай Кемикал Индастри Ко., Лтд. | Пиримидиновые производные |
| RU2104330C1 (ru) * | 1995-12-29 | 1998-02-10 | Общество с ограниченной ответственностью "Рол-классик" | Ингибитор коррозии для антифризов |
| RU2205540C1 (ru) * | 2002-01-08 | 2003-06-10 | Открытое акционерное общество "Химпром" | Смачиватель для пестицидов |
| RU2337549C2 (ru) * | 2003-07-25 | 2008-11-10 | Исихара Сангио Кайся, Лтд. | Гербицидная композиция с повышенным гербицидным действием и способ повышения гербицидного действия |
| RU2338376C2 (ru) * | 2003-04-17 | 2008-11-20 | Кумиай Кемикал Индастри Ко., Лтд. | Композиция водной сельскохозяйственно-химической суспензии |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007186460A (ja) * | 2006-01-13 | 2007-07-26 | Bayer Cropscience Kk | 水田用除草剤組成物 |
| CN100564283C (zh) * | 2007-11-06 | 2009-12-02 | 沈阳东大友联环保产业有限公司 | 一种高效缓蚀阻垢分散剂 |
-
2010
- 2010-02-24 RU RU2010105982/13A patent/RU2440731C2/ru active IP Right Revival
- 2010-08-04 EA EA201101247A patent/EA019718B1/ru not_active IP Right Cessation
- 2010-08-04 WO PCT/RU2010/000432 patent/WO2011105924A1/ru active Application Filing
- 2010-08-04 CN CN201080064728.0A patent/CN102770025B/zh not_active Expired - Fee Related
- 2010-08-04 BR BR112012019465A patent/BR112012019465A8/pt active Search and Examination
- 2010-08-04 MY MYPI2012700413A patent/MY158686A/en unknown
- 2010-08-04 KR KR1020127017531A patent/KR101596764B1/ko not_active Expired - Fee Related
-
2012
- 2012-08-21 EC ECSP12012113 patent/ECSP12012113A/es unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2028294C1 (ru) * | 1987-12-22 | 1995-02-09 | Кумиай Кемикал Индастри Ко., Лтд. | Пиримидиновые производные |
| RU2104330C1 (ru) * | 1995-12-29 | 1998-02-10 | Общество с ограниченной ответственностью "Рол-классик" | Ингибитор коррозии для антифризов |
| RU2205540C1 (ru) * | 2002-01-08 | 2003-06-10 | Открытое акционерное общество "Химпром" | Смачиватель для пестицидов |
| RU2338376C2 (ru) * | 2003-04-17 | 2008-11-20 | Кумиай Кемикал Индастри Ко., Лтд. | Композиция водной сельскохозяйственно-химической суспензии |
| RU2337549C2 (ru) * | 2003-07-25 | 2008-11-10 | Исихара Сангио Кайся, Лтд. | Гербицидная композиция с повышенным гербицидным действием и способ повышения гербицидного действия |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2015230646B2 (en) * | 2014-03-13 | 2020-01-16 | Jura Elektroapparate Ag | Method for cleaning and/or disinfecting a milk-carrying system of a coffee machine, and coffee machine |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112012019465A2 (enrdf_load_stackoverflow) | 2017-09-05 |
| CN102770025B (zh) | 2015-04-08 |
| CN102770025A (zh) | 2012-11-07 |
| EA201101247A1 (ru) | 2012-03-30 |
| BR112012019465A8 (pt) | 2017-12-05 |
| KR101596764B1 (ko) | 2016-02-23 |
| KR20130004897A (ko) | 2013-01-14 |
| RU2440731C2 (ru) | 2012-01-27 |
| ECSP12012113A (es) | 2012-09-28 |
| RU2010105982A (ru) | 2011-08-27 |
| MY158686A (en) | 2016-10-31 |
| EA019718B1 (ru) | 2014-05-30 |
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