WO2010108659A1 - Schichtsystem mit verbesserter korrosionsbeständigkeit - Google Patents
Schichtsystem mit verbesserter korrosionsbeständigkeit Download PDFInfo
- Publication number
- WO2010108659A1 WO2010108659A1 PCT/EP2010/001817 EP2010001817W WO2010108659A1 WO 2010108659 A1 WO2010108659 A1 WO 2010108659A1 EP 2010001817 W EP2010001817 W EP 2010001817W WO 2010108659 A1 WO2010108659 A1 WO 2010108659A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- metal
- alloy
- nickel
- tin
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1651—Two or more layers only obtained by electroless plating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
- C23C18/50—Coating with alloys with alloys based on iron, cobalt or nickel
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/021—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
- C23C28/025—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only with at least one zinc-based layer
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
- Y10T428/12715—Next to Group IB metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
- Y10T428/12722—Next to Group VIII metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12729—Group IIA metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12778—Alternative base metals from diverse categories
Definitions
- the present invention relates to a coating system for coating a substrate surface which has improved corrosion resistance.
- the substrates to be coated may be conductive, metallic components as well as non-conductive substrates such as plastic components.
- the deposited metal layers can on the one hand functionally change the substrate surfaces, on the other hand decorative. While the decorative coating of substrate surfaces is usually directed only to the visual impression of the deposited metal layers, in the field of functional deposition of metal layers, a change in the mechanical and / or chemical surface properties of the substrates is intended.
- the abrasion resistance, wear resistance, surface hardness or corrosion resistance of the surface of the substrate can be changed by deposition of suitable layers. Basically, both the galvanic deposition of layers, as well as the autocatalytic deposition of layers is known here.
- chromium layers which are used as a coating for metal surfaces in order to improve the metal surfaces in particular with regard to their wear resistance and corrosion resistance.
- chromium layers which are used as a coating for metal surfaces in order to improve the metal surfaces in particular with regard to their wear resistance and corrosion resistance.
- These layers are also characterized by good corrosion resistance.
- Hard chrome coatings are used, for example, in the field of design engineering for hydraulic components such as hydraulic cylinders and hydraulic pistons, for pressure rollers in the field of printing technology, or in the field of engine construction, for example for the coating of valve stems.
- a further disadvantage of the hard chrome layers known from the prior art is that they are usually deposited from chromium (VI) -containing electrolytes.
- chromium (VI) is suspected of being carcinogenic and the use of chromium (VI) -containing electrolytes should therefore be avoided.
- different approaches have been taken to deposit without the use of chromium (VI) -containing electrolytes layers having comparable mechanical and chemical properties.
- European Patent EP 0 672 763 B1 discloses a method of coating a metal surface, in which a nickel-phosphorus alloy layer is deposited on the metal surface in a first step, to which a silicon layer is then applied in a vacuum chamber using an ion beam ,
- a layer system for coating a substrate surface consisting of a first inner layer and an outer second layer deposited on the first layer, one layer comprising a metal-nickel alloy layer with a metal of the group of tin, copper, iron, tungsten and cobalt or an alloy of at least one of these metals and the other layer a layer of a metal of the group consisting of nickel, copper, tin, molybdenum, niobium, cobalt, chromium, vanadium, manganese, titanium and magnesium , or an alloy of at least one of these metals.
- a layer system consisting of a metal-nickel alloy layer with a metal of the group consisting of tin, copper, iron, tungsten and cobalt or an alloy of at least one of these metals and a layer of a metal of the group consisting of nickel , Copper, tin, molybdenum, niobium, cobalt, chromium, vanadium, manganese, titanium and magnesium, or an alloy of at least one of these metals results in a coating which meets the requirements placed on a hard chrome layer on the one hand in terms of their mechanical stability, on the other hand a superior Has corrosion resistance.
- a metal-nickel alloy layer is particularly a tin-nickel alloy layer into consideration.
- the substrates coated according to the invention are exposed to an aqueous solution containing iron (III) chloride in acidic conditions in accordance with ASTM standard G48.
- the coating systems according to the invention exhibit an outstanding corrosion resistance of more than 72 hours under these conditions, whereby this standard is fulfilled and the layer systems according to the invention are insofar seawater-proof, ie seawater-resistant.
- the metal-nickel alloy layer formed in particular as a tin-nickel alloy layer has a layer thickness of at least 1 ⁇ m, preferably of at least 5 ⁇ m and more preferably of at least 10 ⁇ m.
- the particular advantage of the layer systems according to the invention is that they can achieve excellent corrosion resistance with a comparatively thin layer thickness.
- the corrosion resistance referred to in ASTM standard G48 is already achieved with a layer thickness of only 3 ⁇ m
- the layer thickness of the layer systems according to the invention can be greater, if necessary in order to be able to withstand other, in particular mechanical effects.
- the layer thickness can also be 20 ⁇ m, 30 ⁇ m, 40 ⁇ m or even thicker, depending on the application.
- a layer system preferred according to the invention is a layer system in which a layer of a metal of the group consisting of nickel, copper, tin, molybdenum, niobium, cobalt, chromium, vanadium, manganese, titanium and magnesium, or an alloy of at least one of these metals a first layer is deposited on a substrate surface onto which is then deposited a metal-nickel alloy layer having a metal of the group consisting of tin, copper, iron, tungsten and cobalt or an alloy of at least one of these metals.
- a tin-nickel alloy layer is particularly preferable.
- the first inner layer is a bronze or nickel-phosphorus alloy layer.
- the object of the invention is achieved by a method for coating a substrate surface, in particular a metal substrate surface, which has at least the method steps:
- a metal-nickel alloy layer having a metal of the group consisting of tin, copper, iron, tungsten and cobalt or an alloy of at least one of these metals and as another layer a layer of a metal of the group consisting of nickel, copper, tin , Molybdenum, niobium, cobalt, chromium, vanadium, manganese, titanium and magnesium, or an alloy of at least one of these metals is deposited.
- a tin-nickel alloy layer is preferable as the metal-nickel alloy layer.
- the deposition of the metal-nickel alloy layer having a layer thickness of at least 1 .mu.m, preferably of 3 .mu.m, whereby thicker layer thicknesses of, for example, 10 .mu.m, 20 .mu.m or 30 .mu.m can be set.
- a bronze layer or a nickel-phosphorus alloy layer may be deposited.
- the deposition of the individual layers of the layer system can be carried out in the state-of-the-art, electroless or galvanic manner, depending on the type of layer.
- a bronze layer as the first inner layer
- an electrodeposition under application of a suitable deposition voltage between the substrate surface and a counter electrode and using a conventional bronze electrolyte (aqueous, copper and tin-containing electrolyte) is preferred, whereas the deposition of, for example, a nickel-phosphorus - Alloy layer preferably autocatalytically using a corresponding reducing agent such as sodium hypophosphite having electrolyte, but can also be deposited electrolytically.
- the deposition of the metal-nickel alloy layer to be provided according to the invention can also be carried out galvanically by applying a deposition voltage between the substrate surface and a suitable counterelectrode or by autocatalytic using suitable reducing agents.
- the layer systems deposited according to the invention are particularly suitable for coating components in the field of hydraulic engineering, such as pressure cylinders and pressure pistons, for the coating of pressure rollers in the field of printing press technology, for the coating of plant components and components in the field of marine engineering, in particular in the field of shipbuilding and the offshore extraction of natural gas and crude oil, as well as in the field of engine construction.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electroplating Methods And Accessories (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/260,270 US20120135270A1 (en) | 2009-03-24 | 2010-03-24 | Layer System with Improved Corrosion Resistance |
CN201080013693.8A CN102369310B (zh) | 2009-03-24 | 2010-03-24 | 具有改善的耐腐蚀性的层系统 |
EP10711148A EP2411562A1 (de) | 2009-03-24 | 2010-03-24 | Schichtsystem mit verbesserter korrosionsbeständigkeit |
RU2011141884/02A RU2536852C2 (ru) | 2009-03-24 | 2010-03-24 | Слоистая система с улучшенной коррозионной стойкостью |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09004162.5 | 2009-03-24 | ||
EP09004162A EP2233611A1 (de) | 2009-03-24 | 2009-03-24 | Schichtsystem mti verbesserter Korrosionsbeständigkeit |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010108659A1 true WO2010108659A1 (de) | 2010-09-30 |
WO2010108659A8 WO2010108659A8 (de) | 2011-11-10 |
Family
ID=41011799
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2010/001817 WO2010108659A1 (de) | 2009-03-24 | 2010-03-24 | Schichtsystem mit verbesserter korrosionsbeständigkeit |
Country Status (5)
Country | Link |
---|---|
US (1) | US20120135270A1 (de) |
EP (2) | EP2233611A1 (de) |
CN (1) | CN102369310B (de) |
RU (1) | RU2536852C2 (de) |
WO (1) | WO2010108659A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3064613A1 (de) * | 2015-03-03 | 2016-09-07 | MTV Metallveredlung GmbH & Co. KG | Schichtsystem mit verbesserter Korrosionsbeständigkeit und Verschleißfestigkeit |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2619509C (en) | 2005-08-12 | 2015-01-06 | Modumetal, Llc. | Compositionally modulated composite materials and methods for making the same |
BRPI1010877B1 (pt) | 2009-06-08 | 2020-09-15 | Modumetal, Inc | Revestimento de multicamadas resistente à corrosão e método de eletrodeposição |
US9163579B2 (en) * | 2011-11-28 | 2015-10-20 | Federal-Mogul Corporation | Piston with anti-carbon deposit coating and method of construction thereof |
CN103834946B (zh) * | 2012-11-26 | 2016-03-30 | 华为技术有限公司 | 镀层、通信设备及镀层的制备工艺 |
SI2770088T1 (sl) | 2013-02-22 | 2017-08-31 | Dr. Ing. Max Schloetter Gmbh & Co. Kg | Jekleni deli z visoko korozijsko odpornostjo in postopek za izdelavo le-teh |
DE202013001731U1 (de) | 2013-02-22 | 2013-03-11 | Dr.-Ing. Max Schlötter Gmbh & Co. Kg | Hochkorrosionsfeste Stahlteile |
WO2016044720A1 (en) | 2014-09-18 | 2016-03-24 | Modumetal, Inc. | A method and apparatus for continuously applying nanolaminate metal coatings |
BR112015022078B1 (pt) | 2013-03-15 | 2022-05-17 | Modumetal, Inc | Aparelho e método para eletrodepositar um revestimento nanolaminado |
EA032264B1 (ru) | 2013-03-15 | 2019-05-31 | Модьюметл, Инк. | Способ нанесения покрытия на изделие, изделие, полученное вышеуказанным способом, и труба |
EP2971261A4 (de) * | 2013-03-15 | 2017-05-31 | Modumetal, Inc. | Elektroplattierte zusammensetzungen und nanolaminierte legierungen für durch ein additivherstellungsverfahren hergestellte artikel |
BR112015022020A8 (pt) | 2013-03-15 | 2019-12-10 | Modumetal Inc | objeto ou revestimento e seu processo de fabricação |
CN104195496B (zh) * | 2014-08-20 | 2016-12-28 | 青岛申达众创技术服务有限公司 | 一种耐海水腐蚀金属涂层的制备方法 |
EA201790644A1 (ru) | 2014-09-18 | 2017-08-31 | Модьюметал, Инк. | Способы изготовления изделий электроосаждением и процессами послойного синтеза |
CN104453516A (zh) * | 2014-12-04 | 2015-03-25 | 常熟宝成五金制品有限公司 | 耐低温的合页 |
AR109584A1 (es) | 2016-09-08 | 2018-12-26 | Modumetal Inc | Procesos para proveer recubrimientos laminados sobre piezas de trabajo, y los artículos que se obtienen con los mismos |
CA3057836A1 (en) | 2017-03-24 | 2018-09-27 | Modumetal, Inc. | Lift plungers with electrodeposited coatings, and systems and methods for producing the same |
EP3612669A1 (de) | 2017-04-21 | 2020-02-26 | Modumetal, Inc. | Rohrförmige artikel mit galvanischen beschichtungen und systeme und verfahren zur herstellung derselben |
JP2020536177A (ja) * | 2017-09-28 | 2020-12-10 | マクステリアル インコーポレイテッド | 表面コーティングを含む物品およびこれらを生成するための方法 |
EP3784823A1 (de) | 2018-04-27 | 2021-03-03 | Modumetal, Inc. | Vorrichtungen, systeme und verfahren zur herstellung einer vielzahl von gegenständen mit nanolaminierten beschichtungen mittels rotation |
CN114561671B (zh) * | 2022-01-24 | 2023-08-18 | 包头市玺骏稀土有限责任公司 | 一种稀土金属电解阴极保护方法及阴极 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1484575A (en) * | 1973-08-20 | 1977-09-01 | Nasglo Int Corp | Electrodeposition of bright tin-nickel alloy |
US4429021A (en) * | 1980-12-29 | 1984-01-31 | Nippon Steel Corporation | Chromium-plated steel strip having excellent weldability and resistance to corrosion |
US4461679A (en) * | 1979-10-02 | 1984-07-24 | Nippon Steel Corporation | Method of making steel sheet plated with Pb-Sn alloy for automotive fuel tank |
GB2158842A (en) * | 1984-05-18 | 1985-11-20 | Toyo Kohan Co Ltd | Surface-treated steel sheets |
JPH06155479A (ja) * | 1992-11-24 | 1994-06-03 | Showa Denko Kk | ゴム成形用金型 |
EP0672763B1 (de) | 1994-03-18 | 1997-11-12 | Southwest Research Institute | Verfahren zum Beschichten metallischer Oberflächen |
US6194087B1 (en) * | 1997-12-06 | 2001-02-27 | Clyco-Metall-Werke Glyco B.V. & Co. Kg | Composite multilayer bearing material |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4037646A (en) * | 1975-06-13 | 1977-07-26 | Sumitomo Metal Industries, Ltd. | Molds for continuously casting steel |
DE2747545A1 (de) * | 1977-10-22 | 1979-05-03 | Glyco Metall Werke | Gleitlagerlegierung, insbesondere zur verwendung als gleitschicht, auf kupfer-blei-zinn-basis zur herstellung von mehrschichtgleitlagern |
CA1187833A (en) * | 1980-03-22 | 1985-05-28 | Seizun Higuchi | Steel sheet with nickel - tin and lead - tin layers for fuel tank |
CA1242669A (en) * | 1984-05-15 | 1988-10-04 | Nobuyoshi Shimizu | Chrome plated steel sheet with tin or tin-nickel and chromic oxide layers |
US4995838A (en) * | 1988-11-29 | 1991-02-26 | Amp Incorporated | Electrical terminal and method of making same |
IT1251401B (it) * | 1991-09-09 | 1995-05-09 | Pirelli | Filo metallico con doppio strato di rivestimento per il rinforzo di articoli in materiali elastomerici e articoli in materiali elastomerici rinforzati con detto filo. |
JP3176405B2 (ja) * | 1991-12-02 | 2001-06-18 | 臼井国際産業株式会社 | 内面の耐食性に優れた溶接管及びその製造方法 |
US5429882A (en) * | 1993-04-05 | 1995-07-04 | The Louis Berkman Company | Building material coating |
FR2763605B1 (fr) * | 1997-05-22 | 1999-07-02 | Snecma | Revetement de protection de pieces metalliques ayant une bonne resistance a la corrosion en atmosphere saline, et pieces metalliques comportant un tel revetement de protection |
JP4000729B2 (ja) * | 1999-12-15 | 2007-10-31 | 日立電線株式会社 | 同軸ケーブル及びその製造方法 |
DE19963385C1 (de) * | 1999-12-28 | 2001-01-25 | Federal Mogul Wiesbaden Gmbh | Schichtverbundwerkstoff für Gleitlager |
TWI258771B (en) * | 2001-12-04 | 2006-07-21 | Laird Technologies Inc | Methods and apparatus for EMI shielding |
KR101322549B1 (ko) * | 2005-06-17 | 2013-10-25 | 고쿠리츠다이가쿠호진 도호쿠다이가쿠 | 금속 부재의 보호막 구조 및 보호막 구조를 이용한 금속부품 그리고 보호막 구조를 이용한 반도체 또는 평판디스플레이 제조 장치 |
US8189317B2 (en) * | 2007-04-23 | 2012-05-29 | Illinois Tool Works Inc. | Grounding brush system for mitigating electrical current on rotating shafts |
US9035459B2 (en) * | 2009-04-10 | 2015-05-19 | International Business Machines Corporation | Structures for improving current carrying capability of interconnects and methods of fabricating the same |
-
2009
- 2009-03-24 EP EP09004162A patent/EP2233611A1/de not_active Withdrawn
-
2010
- 2010-03-24 CN CN201080013693.8A patent/CN102369310B/zh not_active Expired - Fee Related
- 2010-03-24 US US13/260,270 patent/US20120135270A1/en not_active Abandoned
- 2010-03-24 WO PCT/EP2010/001817 patent/WO2010108659A1/de active Application Filing
- 2010-03-24 RU RU2011141884/02A patent/RU2536852C2/ru not_active IP Right Cessation
- 2010-03-24 EP EP10711148A patent/EP2411562A1/de not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1484575A (en) * | 1973-08-20 | 1977-09-01 | Nasglo Int Corp | Electrodeposition of bright tin-nickel alloy |
US4461679A (en) * | 1979-10-02 | 1984-07-24 | Nippon Steel Corporation | Method of making steel sheet plated with Pb-Sn alloy for automotive fuel tank |
US4429021A (en) * | 1980-12-29 | 1984-01-31 | Nippon Steel Corporation | Chromium-plated steel strip having excellent weldability and resistance to corrosion |
GB2158842A (en) * | 1984-05-18 | 1985-11-20 | Toyo Kohan Co Ltd | Surface-treated steel sheets |
JPH06155479A (ja) * | 1992-11-24 | 1994-06-03 | Showa Denko Kk | ゴム成形用金型 |
EP0672763B1 (de) | 1994-03-18 | 1997-11-12 | Southwest Research Institute | Verfahren zum Beschichten metallischer Oberflächen |
US6194087B1 (en) * | 1997-12-06 | 2001-02-27 | Clyco-Metall-Werke Glyco B.V. & Co. Kg | Composite multilayer bearing material |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3064613A1 (de) * | 2015-03-03 | 2016-09-07 | MTV Metallveredlung GmbH & Co. KG | Schichtsystem mit verbesserter Korrosionsbeständigkeit und Verschleißfestigkeit |
Also Published As
Publication number | Publication date |
---|---|
CN102369310A (zh) | 2012-03-07 |
RU2011141884A (ru) | 2013-04-27 |
RU2536852C2 (ru) | 2014-12-27 |
EP2233611A1 (de) | 2010-09-29 |
US20120135270A1 (en) | 2012-05-31 |
CN102369310B (zh) | 2015-03-04 |
WO2010108659A8 (de) | 2011-11-10 |
EP2411562A1 (de) | 2012-02-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2010108659A1 (de) | Schichtsystem mit verbesserter korrosionsbeständigkeit | |
EP2324141B1 (de) | VERSCHLEIß- UND KORROSIONSHEMMENDER SCHICHTVERBUND | |
DE2005707A1 (de) | Gesintertes Hartmetall | |
DE102008046673A1 (de) | Verbundkörper | |
DE2600636C3 (de) | Chromatisiertes Stahlblech und Verfahren zur Herstellung von chromatisiertem, galvanisch verzinktem Stahlblech | |
DE102005059367A1 (de) | Verfahren zur Abscheidung rissfreier, korrosionsbeständiger und harter Chrom- und Chromlegierungsschichten | |
DE3809139C2 (de) | ||
DE102020106254A1 (de) | Verfahren zur Herstellung eines beschichteten Bauteils für eine Wasserarmatur | |
DE102009019601B3 (de) | Schichtverbundwerkstoff für Gleitelemente, Verfahren zu dessen Herstellung und Verwendung | |
EP2180088B1 (de) | Verfahren zur galvanischen Abscheidung von Hartchromschichten | |
EP1451392B1 (de) | Vorbehandlungsprozess für das beschichten von aluminiumwerkstoffen | |
EP1881090B1 (de) | Elektrolytzusammensetzung und Verfahren zur Abscheidung einer Zink-Nickel-Legierungsschicht auf einem Gusseisen- oder Stahlsubstrat | |
DE102008056776A1 (de) | Galvanisches Bad und Verfahren zur Abscheidung von zinkhaltigen Schichten | |
EP2770088B1 (de) | Hochkorrosionsfeste Stahlteile und Verfahren zu deren Herstellung | |
EP1117856B1 (de) | Verfahren zum beschichten von werkstücken | |
EP0651071B1 (de) | Verfahren zur Herstellung von Werkstücken mit verschleissfesten Überzügen | |
EP1997939B1 (de) | Hydraulikzylinder sowie dessen Herstellungsverfahren | |
WO1990002218A1 (de) | Verfahren zur plasmabeschichtung von gegenständen mit einem hartstoff | |
DE202008014947U1 (de) | Galvanisches Bad zur Abscheidung von zinkhaltigen Schichten | |
DE102021123832A1 (de) | Mehrschichtsystem, Bauteil sowie Verfahren zur Herstellung eines solchen Mehrschichtsystems oder Bauteils | |
EP4012074A1 (de) | Oberflächenbeschichtung und verfahren zu ihrer herstellung | |
DE102009008886A1 (de) | Verfahren zum Herstellen eines rotationssymmetrischen Bauelements und gemäß dem Verfahren hergestellte Walze oder Rolle | |
WO2010034511A2 (de) | Hydraulikzylinder sowie dessen herstellungsverfahren | |
DE102004039056A1 (de) | Verfahren zur Herstellung eines Substrats für Solarzellen, derartige Substrate sowie deren Verwendung | |
DE102012004356B4 (de) | Haftfeste, korrosionsbeständige technische Verchromung und Verfahren zur Herstellung derselben |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 201080013693.8 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 10711148 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2010711148 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2011141884 Country of ref document: RU Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 13260270 Country of ref document: US |