WO2010084818A1 - 保護素子 - Google Patents
保護素子 Download PDFInfo
- Publication number
- WO2010084818A1 WO2010084818A1 PCT/JP2010/050335 JP2010050335W WO2010084818A1 WO 2010084818 A1 WO2010084818 A1 WO 2010084818A1 JP 2010050335 W JP2010050335 W JP 2010050335W WO 2010084818 A1 WO2010084818 A1 WO 2010084818A1
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- WO
- WIPO (PCT)
- Prior art keywords
- soluble conductor
- flux
- conductor
- protective element
- insulating cover
- Prior art date
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H37/00—Thermally-actuated switches
- H01H37/74—Switches in which only the opening movement or only the closing movement of a contact is effected by heating or cooling
- H01H37/76—Contact member actuated by melting of fusible material, actuated due to burning of combustible material or due to explosion of explosive material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H37/00—Thermally-actuated switches
- H01H37/74—Switches in which only the opening movement or only the closing movement of a contact is effected by heating or cooling
- H01H37/76—Contact member actuated by melting of fusible material, actuated due to burning of combustible material or due to explosion of explosive material
- H01H37/761—Contact member actuated by melting of fusible material, actuated due to burning of combustible material or due to explosion of explosive material with a fusible element forming part of the switched circuit
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/58—Electric connections to or between contacts; Terminals
- H01H1/5805—Connections to printed circuits
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H37/00—Thermally-actuated switches
- H01H37/74—Switches in which only the opening movement or only the closing movement of a contact is effected by heating or cooling
- H01H37/76—Contact member actuated by melting of fusible material, actuated due to burning of combustible material or due to explosion of explosive material
- H01H2037/768—Contact member actuated by melting of fusible material, actuated due to burning of combustible material or due to explosion of explosive material characterised by the composition of the fusible material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49107—Fuse making
Definitions
- the present invention relates to a protective element that cuts off a current by melting a soluble conductor by heat when an excessive current or voltage is applied to an electronic device or the like.
- protective elements mounted on secondary battery devices and the like have not only an overcurrent but also an overvoltage prevention function.
- This protective element is formed by laminating a soluble conductor composed of a heating element and a low-melting-point metal body on a substrate, and is formed so that the soluble conductor is blown by an overcurrent, and also when an overvoltage occurs
- the heating element inside is energized, and the soluble conductor is blown by the heat of the heating element.
- the melting of the fusible conductor is caused by good wettability with respect to the surface of the connected electrode when the fusible conductor, which is a low melting point metal, is melted.
- the molten low melting point metal is attracted onto the electrode, and as a result, the soluble conductor is divided and the current is interrupted.
- a soluble conductor of a low-melting-point metal body is disposed and sealed with an insulating cover, and a flux is applied to the soluble conductor. This flux is provided so as to prevent the surface of the soluble conductor from being oxidized and to melt the soluble conductor quickly and stably when the soluble conductor is heated.
- Such a protective element has a structure shown in FIG.
- a pair of electrodes 2 are provided on a base substrate 1, and a pair of electrodes (not shown) are also provided at opposing edges perpendicular to the electrodes 2.
- a heating element 5 made of a resistor is provided between electrodes (not shown), and a conductor layer 7 connected to one of a pair of electrodes (not shown) via an insulating layer 6 is provided.
- This protective element is provided with a soluble conductor 3 made of a low melting point metal foil between a pair of electrodes 2 formed on both ends of the base substrate 1. A central portion of the soluble conductor 3 is connected to the conductor layer 7.
- an insulating cover 4 is provided so as to face the fusible conductor 3 on the base substrate 1.
- the insulating cover 4 attached to the base substrate 1 is covered with the fusible conductor 3 by forming a predetermined space 8.
- a flux 9 is applied to the fusible conductor 3, and the flux 9 is accommodated in a space 8 in the insulating cover 4.
- a pair of passing current through a low melting point metal body as a means for reducing circuit interruption time due to aggregation at the time of melting of the low melting point metal body and reducing variation in operation time.
- a pair of passing current through a low melting point metal body as a means for reducing circuit interruption time due to aggregation at the time of melting of the low melting point metal body and reducing variation in operation time.
- two or more low melting point metal bodies or low melting point metal bodies having slits formed between the electrodes are provided with two or more low melting point metal bodies or low melting point metal bodies having slits formed between the electrodes.
- the low-melting point metal body between the electrodes is divided into independent states, the fusing start point in the low-melting point metal body is increased, and the operation time can be shortened and stabilized.
- a protective element with a flux on a low-melting-point metal soluble conductor acts as an activator for the flux to prevent the soluble conductor from being oxidized and to be melted by abnormal current / voltage. It affects speed.
- halogen-free flux that does not contain halogen components such as bromine (Br) is used to reduce the environmental burden in the manufacturing process and waste disposal of electronic devices, this type of flux has low activity.
- the flux state greatly affects the fusing speed and stability of the soluble conductor.
- the flux 9 on the fusible conductor 3 may not be stably held in the central portion of the space 8 and may be biased left and right.
- the molten metal of the soluble conductor 3 tends to flow into the place where the flux 9 can be held, and the situation where the soluble conductor 3 is difficult to melt in the portion where the flux 9 is insufficient appears until it is surely blown. There is a problem of extending the time.
- the present invention has been made in view of the above-mentioned background art, and can stably hold the flux on the soluble conductor at a predetermined position, and enables the rapid and accurate fusing of the soluble conductor at the time of abnormality.
- An object is to provide a protective element.
- the present invention includes a fusible conductor disposed on an insulating base substrate and connected to a power supply path of a device to be protected and fused by a predetermined abnormal power, covering the fusible conductor via a predetermined space, and An insulating cover attached to a base substrate; and a flux that is applied to the surface of the fusible conductor and located in the space.
- the fusible conductor A protective element that cuts off the current path by fusing, and is formed on the inner surface of the insulating cover so as to face the fusible conductor, and contacts the flux to hold the flux in a predetermined position in the space.
- the soluble element is a protective element in which a hole holding the flux is formed in the soluble conductor.
- the hole portion of the soluble conductor is a through hole formed in the central portion of the soluble conductor.
- the step portion is formed of a protrusion formed on the inner surface of the insulating cover so as to face the hole portion of the soluble conductor.
- the convex part may be formed in the surrounding surface of the said hole part of the center part of the said soluble conductor along a peripheral part.
- the soluble conductor may be formed with relatively small holes other than the central part of the soluble conductor, and the soluble conductor has a large number of small holes formed therein. But it ’s okay. Furthermore, an opening that is a through hole may be formed inside the step portion of the insulating cover.
- the step for holding the flux is provided inside the insulating cover and the hole is provided in the soluble conductor, the flux is stably held at a predetermined position of the soluble conductor. Things will be possible. Thereby, even when a flux with low activity (such as a halogen-free material) is used, uneven activity due to uneven flux holding state after flux application can be prevented. Furthermore, in the fusing operation of the fusible conductor, particularly in the low-power heat generation operation characteristic, the operation variation can be extremely reduced. In addition, by using a halogen-free flux, it is possible to provide a protective element with a small environmental load. The melted volume can be reduced while maintaining the conventional foil size of the soluble conductor, and it becomes easier to melt.
- a flux with low activity such as a halogen-free material
- the flux By forming a small hole in addition to the flux holding part of the fusible conductor, the flux can be reliably held around the fusible conductor and the fusing volume is reduced. Can be melted.
- the flux can be held more reliably, contributing to stabilization of the fusing characteristics.
- FIG. 2 is a cross-sectional view taken along the line AA of FIG. 1 with an insulating cover attached to the protection element of FIG. It is the top view (a) before attaching a soluble conductor to the protection element of 1st embodiment of this invention, and the top view (b) of a soluble conductor. It is a top view of the insulation cover of the protection element of 1st embodiment of this invention. It is a circuit diagram of the secondary battery device provided with the protection element of the first embodiment of the present invention. It is a top view of the state which removed the insulating cover of the protection element of 2nd embodiment of this invention. FIG.
- FIG. 7 is a cross-sectional view of FIG. 6AA in a state where an insulating cover is attached to the protective element of FIG. It is a top view of the state which removed the insulating cover of the protection element of 3rd embodiment of this invention.
- FIG. 9 is a cross-sectional view of FIG. 8AA in a state where an insulating cover is attached to the protection element of FIG. It is a top view of the state which removed the insulating cover of the protection element of 4th embodiment of this invention.
- FIG. 10A is a cross-sectional view taken along the line AA of FIG. 10 with an insulating cover attached to the protection element of FIG. It is a longitudinal cross-sectional view of the protection element of 5th Embodiment of this invention. It is a longitudinal cross-sectional view of the conventional protective element. It is a longitudinal cross-sectional view which shows the mode of the flux of the conventional protective element.
- the protection element 10 of this embodiment has a pair of electrodes 12 formed on both ends of the upper surface of the insulating base substrate 11, and another pair of electrodes 21 is also provided at opposing edges perpendicular to the pair of electrodes 12. Is provided.
- a heating element 15 made of a resistor is connected between the electrodes 21.
- a conductor layer 17 connected to one electrode 21 via an insulating layer 16 is laminated on the heating element 15.
- the conductor layer 17 is connected to the central portion of the fusible conductor 13, which is a fuse made of a low melting point metal connected to the pair of electrodes 12.
- the base substrate 11 is provided with an insulating insulating cover 14 so as to face the fusible conductor 13.
- the material of the base substrate 11 may be any material as long as it has insulating properties.
- an insulating substrate used for a printed wiring board such as a ceramic substrate or a glass epoxy substrate is preferable.
- a glass substrate, a resin substrate, an insulated metal substrate, or the like can be used as appropriate according to the intended use, but a ceramic substrate having excellent heat resistance and good thermal conductivity is more preferable.
- a metal foil such as copper or a conductor material whose surface is plated with Ag—Pt, Au or the like can be used. Further, a conductive layer and electrodes obtained by applying and baking a conductive paste such as an Ag paste may be used, or a metal thin film structure by vapor deposition or the like may be used.
- the fusible conductor 13 has a hole 13a formed of an annular through hole formed in the center thereof. As shown in FIG. 3, the hole 13 a is formed in a circular shape, and is concentrically positioned and faces a protruding portion 20 of the insulating cover 14 described later.
- the low melting point metal foil of the fusible conductor 13 is not particularly limited as long as it melts with a predetermined power, and various known low melting point metals can be used as the fuse material. For example, a BiSnPb alloy, BiPbSn alloy, BiPb alloy, BiSn alloy, SnPb alloy, SnAg alloy, PbIn alloy, ZnAl alloy, InSn alloy, PbAgSn alloy, or the like can be used.
- the resistor forming the heating element 15 is, for example, a conductive paste such as ruthenium oxide or carbon black, and an inorganic binder such as glass or an organic binder such as a thermosetting resin applied and fired. It is. Also, a thin film such as ruthenium oxide or carbon black may be printed and baked, or may be formed by plating, vapor deposition or sputtering, or may be formed by pasting, laminating, or the like, a film of these resistor materials. .
- the insulating cover 14 attached to the base substrate 11 is formed in a box shape with one side opened, and is covered with the base substrate 11 by forming a predetermined space 18 with respect to the soluble conductor 13.
- the insulating cover 14 may be made of an insulating material having heat resistance that can withstand the heat generated when the fusible conductor 13 is melted and mechanical strength as the protective element 10.
- various materials such as a substrate material used for a printed wiring board such as glass, ceramics, plastic, and glass epoxy resin can be applied.
- an insulating layer such as an insulating resin may be formed on the surface facing the base substrate 11 using a metal plate.
- a material having a high mechanical strength and insulating properties such as ceramics is preferable because it contributes to a reduction in the thickness of the entire protective element.
- a low cylindrical protrusion 20 having a concentric circular step 20 a is formed at a position facing the hole 13 a in the center of the fusible conductor 13. .
- the protruding portion 20 is formed integrally with the insulating cover 14, and the projection position onto the base substrate 11 is located on the heating element 15.
- a flux 19 is provided on the entire surface of the soluble conductor 13 in order to prevent oxidation of the surface.
- the flux 19 is preferably a halogen-free flux that does not contain a halogen element such as bromine.
- the flux 19 is filled in the hole 13 a of the soluble conductor 13 and further stays in the periphery thereof, and is held on the soluble conductor 13 by surface tension. Further, it is raised and accommodated in the space 18 of the insulating cover 14 due to surface tension, and as shown in FIG. 2, it adheres to the protrusions 20 formed on the inner surface 14a of the insulating cover 14 and is stepped by its wettability. It is stably held by the portion 20a. Thereby, the flux 19 is stably held in the space 18 of the insulating cover 14 without being displaced at the center of the soluble conductor 13.
- the protruding height of the protruding portion 20 from the inner surface 14a of the insulating cover is such that the surface of the flux 19 applied to the soluble conductor 13 is brought into contact with the surface of the flux 19 by the wettability and surface tension. It is a height that can be retained and is limited to the extent that the melted soluble conductor 13 of the low melting point metal melted by the abnormal power just contacts the spherically raised top by its surface tension, preferably A protruding height that does not contact the melted soluble conductor 13 is preferable.
- an overcurrent / overvoltage protection circuit 26 of a secondary battery device will be described with reference to FIG.
- the pair of electrodes 12 of the protection element 10 are connected in series between the output terminal A1 and the input terminal B1, and one terminal of the pair of electrodes 12 of the protection element 10 is connected to the input.
- the other electrode 12 is connected to the terminal B1 and the other electrode 12 is connected to the output terminal A1.
- the midpoint of the fusible conductor 13 is connected to one end of the heating element 15, and one terminal of the electrode 21 is connected to the other terminal of the heating element 15.
- the other terminal of the heating element 15 is connected to the collector of the transistor Tr, and the emitter of the transistor Tr is connected between the other input terminal A2 and the output terminal B2. Furthermore, the anode of the Zener diode ZD is connected to the base of the transistor Tr via the resistor R, and the cathode of the Zener diode ZD is connected to the output terminal A1.
- the resistor R is set to such a value that a voltage equal to or higher than the breakdown voltage is applied to the Zener diode ZD when a predetermined voltage set as abnormal is applied between the output terminals A1 and A2.
- an electrode terminal of a secondary battery 23 which is a protected device such as a lithium ion battery is connected, and the input terminals B1 and B2 are used by being connected to the secondary battery 23.
- An electrode terminal of a device such as a charger (not shown) is connected.
- the protection operation of the protection element 10 of this embodiment will be described.
- a secondary battery device such as a lithium ion battery to which the overcurrent / overvoltage protection circuit 26 of this embodiment is attached
- the predetermined predetermined set as abnormal With this voltage, a reverse voltage equal to or higher than the breakdown voltage is applied to the Zener diode ZD, and the Zener diode ZD becomes conductive. Due to the conduction of the Zener diode ZD, the base current ib flows through the base of the transistor TR, whereby the transistor Tr is turned on, the collector current ic flows through the heating element 15, and the heating element 15 generates heat.
- the flux 19 is held at the center of the fusible conductor 13, and is quickly and reliably blown at a predetermined fusing position. Further, even when an abnormal current flows toward the output terminal A1, the fusible conductor 13 is set to generate heat and blow.
- a convex cylindrical protrusion 20 is provided on the inner surface 14 a of the insulating cover 14 so as to face the soluble conductor 13, and the protrusion 20 faces the protrusion 20.
- the hole 13a is formed also in the center part of the soluble conductor 13, it becomes possible to hold
- a flux 19 such as a halogen-free flux having a low activity
- the fusing volume is reduced by the amount of the hole 13a of the soluble conductor 13, fusing at the time of abnormality is more reliably performed in a short time.
- the protection element 10 of this embodiment is provided with a cylindrical protrusion 20 having a stepped portion 20 a on the inner surface 14 a of the insulating cover 14 so as to face the soluble conductor 13.
- the convex part 22 is formed along the peripheral part of the hole 13a.
- the flux 19 can be more stably held at a certain position by the convex portion 22, and the fusing operation of the soluble conductor 13 can be performed more stably.
- the flux 19 can be stably held in the central portion by the hole 13a, and the flux 19 is also held in the small hole portion 13b at a position other than the central portion of the fusible conductor 13.
- the fusing characteristics of the fusible conductor 13 become more stable.
- the same members as those of the above-described embodiment are denoted by the same reference numerals, and description thereof is omitted.
- the inner surface 14 a of the insulating cover 14 has a protrusion 20 having a stepped portion 20 a, and is replaced by the hole 13 a at the center of the soluble conductor 13 and relatively to the entire soluble conductor 13.
- a small hole portion 13b which is a small hole portion is formed.
- the flux 19 can be stably held in the center by the protrusion 22 of the insulating cover 14 and the small hole 13b of the soluble conductor 13, and the center of the soluble conductor 13.
- the small hole portion 13b other than the portion the flux 19 is held also in the peripheral portion of the fusible conductor 13, so that the fusing characteristics are stable.
- an opening 24 is formed at the center of the inner surface 14a of the insulating cover 14 along with the cylindrical protruding portion 20 having the stepped portion 20a. It is provided.
- the holding state of the flux 19 can be visually recognized through the opening 24.
- the product inspection can be made easier and more reliable.
- the opening 24 may be closed with transparent glass or resin. Thereby, dust and the like can be prevented from entering from the opening 24. Further, the protruding portion 20 may not be formed by the step portion formed by the opening 24.
- the protective element of the present invention is not limited to the above embodiment, and may be any element provided with a shape of an insulating cover and a fusible conductor capable of holding flux at a predetermined position in the space in the insulating cover.
- the holding form does not matter.
- the material of a flux and an insulating cover is not ask
Abstract
Description
11 ベース基板
12,21 電極
13 可溶導体
13a 孔部
14 絶縁カバー
14a 内面
15 発熱体
16 絶縁層
18 空間
19 フラックス
20 突条部
20a 段部
Claims (7)
- 絶縁性のベース基板上に配置され保護対象機器の電力供給経路に接続されて所定の異常電力により溶断する可溶導体と、前記可溶導体を所定の空間を介して覆って前記ベース基板に取り付けられた絶縁カバーと、前記可溶導体表面に塗布され前記空間内に位置したフラックスとを有し、前記保護対象機器に前記異常電力が供給された場合に、前記可溶導体が溶断してその電流経路を遮断する保護素子において、
前記可溶導体に対向して前記絶縁カバーの内面に形成され、前記フラックスと接触して前記フラックスを前記空間内の所定の位置に保持する段部を備え、
前記可溶導体には前記フラックスを保持した孔部が形成されたことを特徴とする保護素子。 - 前記可溶導体の孔部は、前記可溶導体中央部に形成された透孔である請求項1記載の保護素子。
- 前記段部は、前記絶縁カバー内面に形成され、前記可溶導体の孔部と対面して設けられた突条部から成る請求項1記載の保護素子。
- 前記可溶導体の中央部の前記孔部の周囲表面には、周縁部に沿って凸部が形成されている請求項2記載の保護素子。
- 前記可溶導体には、前記可溶導体の中央部以外に、相対的に小さい孔部が形成されている請求項2記載の保護素子。
- 前記可溶導体は、多数の小さい孔部が形成されている請求項1記載の保護素子。
- 前記絶縁カバーの段部の内側には、透孔である開口部が形成された請求項1記載の保護素子。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010800032197A CN102239535B (zh) | 2009-01-21 | 2010-01-14 | 保护元件 |
KR1020117011869A KR101165602B1 (ko) | 2009-01-21 | 2010-01-14 | 보호소자 |
US13/145,455 US8803652B2 (en) | 2009-01-21 | 2010-01-14 | Protection element |
EP10733425.2A EP2381457A4 (en) | 2009-01-21 | 2010-01-14 | ELEMENT OF PROTECTION |
Applications Claiming Priority (2)
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JP2009011197A JP5130232B2 (ja) | 2009-01-21 | 2009-01-21 | 保護素子 |
JP2009-011197 | 2009-01-21 |
Publications (1)
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WO2010084818A1 true WO2010084818A1 (ja) | 2010-07-29 |
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PCT/JP2010/050335 WO2010084818A1 (ja) | 2009-01-21 | 2010-01-14 | 保護素子 |
Country Status (7)
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US (1) | US8803652B2 (ja) |
EP (1) | EP2381457A4 (ja) |
JP (1) | JP5130232B2 (ja) |
KR (1) | KR101165602B1 (ja) |
CN (1) | CN102239535B (ja) |
TW (1) | TWI395246B (ja) |
WO (1) | WO2010084818A1 (ja) |
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JP5130232B2 (ja) * | 2009-01-21 | 2013-01-30 | デクセリアルズ株式会社 | 保護素子 |
JP5260592B2 (ja) * | 2010-04-08 | 2013-08-14 | デクセリアルズ株式会社 | 保護素子、バッテリ制御装置、及びバッテリパック |
JP5844669B2 (ja) * | 2012-03-26 | 2016-01-20 | デクセリアルズ株式会社 | 保護素子 |
JP2014022050A (ja) * | 2012-07-12 | 2014-02-03 | Dexerials Corp | 保護素子 |
KR101388354B1 (ko) * | 2012-11-26 | 2014-04-24 | 스마트전자 주식회사 | 비정상상태의 전류 및 전압을 차단하는 복합보호소자 |
JP6297028B2 (ja) * | 2013-04-19 | 2018-03-20 | Littelfuseジャパン合同会社 | 保護装置 |
JP6151550B2 (ja) * | 2013-04-25 | 2017-06-21 | デクセリアルズ株式会社 | 保護素子 |
JP6227276B2 (ja) * | 2013-05-02 | 2017-11-08 | デクセリアルズ株式会社 | 保護素子 |
CN103594124B (zh) * | 2013-11-28 | 2016-05-25 | 中广核研究院有限公司 | 控制棒导向管及燃料组件 |
KR101533996B1 (ko) * | 2014-10-23 | 2015-07-06 | 주식회사 에스엠하이테크 | 온도 퓨즈 기능을 가진 smd형 마이크로 복합 퓨즈 및 그 제조방법 |
JP6436729B2 (ja) * | 2014-11-11 | 2018-12-12 | デクセリアルズ株式会社 | ヒューズエレメント、ヒューズ素子、保護素子、短絡素子、切替素子 |
JP6622960B2 (ja) * | 2014-12-18 | 2019-12-18 | デクセリアルズ株式会社 | スイッチ素子 |
CN105576598B (zh) * | 2015-02-17 | 2019-02-15 | 上海长园维安电子线路保护有限公司 | 一种薄型自控制型保护器及其制造方法 |
TWI684311B (zh) * | 2019-04-01 | 2020-02-01 | 聚鼎科技股份有限公司 | 保護元件 |
CN111816522B (zh) * | 2019-04-11 | 2022-08-30 | 聚鼎科技股份有限公司 | 保护元件 |
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- 2010-01-14 CN CN2010800032197A patent/CN102239535B/zh active Active
- 2010-01-14 WO PCT/JP2010/050335 patent/WO2010084818A1/ja active Application Filing
- 2010-01-14 EP EP10733425.2A patent/EP2381457A4/en not_active Withdrawn
- 2010-01-20 TW TW099101493A patent/TWI395246B/zh active
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Also Published As
Publication number | Publication date |
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KR101165602B1 (ko) | 2012-07-23 |
JP2010170802A (ja) | 2010-08-05 |
TW201030790A (en) | 2010-08-16 |
JP5130232B2 (ja) | 2013-01-30 |
CN102239535B (zh) | 2013-11-06 |
CN102239535A (zh) | 2011-11-09 |
US8803652B2 (en) | 2014-08-12 |
EP2381457A1 (en) | 2011-10-26 |
TWI395246B (zh) | 2013-05-01 |
EP2381457A4 (en) | 2014-04-23 |
US20120249283A1 (en) | 2012-10-04 |
KR20110089158A (ko) | 2011-08-04 |
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