WO2010047023A1 - 光学的情報記録媒体及び製造方法 - Google Patents
光学的情報記録媒体及び製造方法 Download PDFInfo
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- WO2010047023A1 WO2010047023A1 PCT/JP2009/003917 JP2009003917W WO2010047023A1 WO 2010047023 A1 WO2010047023 A1 WO 2010047023A1 JP 2009003917 W JP2009003917 W JP 2009003917W WO 2010047023 A1 WO2010047023 A1 WO 2010047023A1
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- curable resin
- ultraviolet curable
- substrate
- information storage
- information recording
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/26—Apparatus or processes specially adapted for the manufacture of record carriers
- G11B7/263—Preparing and using a stamper, e.g. pressing or injection molding substrates
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/2403—Layers; Shape, structure or physical properties thereof
- G11B7/24035—Recording layers
- G11B7/24038—Multiple laminated recording layers
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/256—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers improving adhesion between layers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/21—Circular sheet or circular blank
Definitions
- the present invention relates to an optical information storage medium on which information is optically recorded or reproduced by irradiation with a laser beam and a method for manufacturing the same.
- the currently commercialized ⁇ 120 mm optical disc has a pit length of 0.1 ⁇ m to 0.2 ⁇ m and a capacity of about 15 GB to 30 GB.
- masters are made using Deep-UV laser light or electron beams.
- the shortest pit length produced by deep UV laser light the formation of very short pits of about 80 nm and about 40 nm for electron beams has been reported.
- the capacity is estimated to be about 500 GB / 12 cm.
- An optical disk substrate used for such high-density recording / reproduction is manufactured by an injection molding method using a stamper in which a replica pattern is transferred from the above-described master of the optical disk (see Patent Documents 1 to 3).
- an information recording layer is formed on the concavo-convex pattern on the optical disk substrate described above. And the 2nd uneven
- a plurality of multilayer optical disk media having a plurality of information recording layers in one optical disk medium as described above are stored in one cartridge. This aims to increase the capacity of the optical disk system.
- the background art described above has the following problems. That is, a plurality of multilayer optical disk media having a plurality of information recording layers in one optical disk medium are stored in one cartridge.
- the information recording layer is generally multi-layered.
- the total film thickness of the concave / convex pattern and the spacer layer forming each information recording layer is generally in the range of about 20 ⁇ m to 60 ⁇ m.
- the concave / convex pattern is formed of an ultraviolet curable resin
- the spacer layer is formed of an ultraviolet curable resin or a transparent sheet.
- FIG. 20 shows a cross-sectional view of an optical information recording medium having, for example, two information recording layers.
- the substrate 101 is formed with an uneven pattern by injection molding.
- a first information recording layer 102 is formed on the substrate 101.
- a transparent sheet is bonded onto the first information storage layer 102 via the ultraviolet curable resin 103.
- the transparent sheet functions as the spacer layer 104.
- An uneven pattern is formed on the transparent sheet by the ultraviolet curable resin 105.
- a second information recording layer 106 is formed on the ultraviolet curable resin 105.
- a substrate 108 is bonded onto the second information storage layer 106 via an ultraviolet curable resin 107.
- FIG. 21 shows a cross-sectional view of an optical information recording medium having four information recording layers.
- the substrate 101 is formed with an uneven pattern by injection molding.
- a first information recording layer 102 is formed on the substrate 101.
- An uneven pattern also serving as a spacer layer is formed on the first information storage layer 102 using the ultraviolet curable resin 103.
- the first information storage layer 102 and the ultraviolet curable resin 103 are sequentially formed and laminated. As a result, an optical information recording medium having four information recording layers is obtained.
- FIG. 22 shows a cross-sectional view of an optical information recording medium having another two information recording layers.
- the substrate 101 is formed with an uneven pattern by injection molding.
- a first information recording layer 102 is formed on the substrate 101.
- An uneven pattern also serving as a spacer layer is formed on the first information storage layer 102 using the ultraviolet curable resin 103.
- a second information recording layer 106 is formed on the ultraviolet curable resin 103.
- a substrate 108 is bonded onto the second information storage layer 106 via an ultraviolet curable resin 107.
- the first information recording layer 102 and the second information recording layer 106 are sequentially formed by the above-described procedure. At this time, some problem may occur in the formation of the concave / convex pattern for forming the second information recording layer 106 and the subsequent film formation process of the information recording layer. In this case, all the processes such as the formation of the concavo-convex pattern, film formation, and sheet bonding that have been performed are wasted.
- the optical information recording medium having the four information recording layers shown in FIG. 21 may cause some problems in the process of forming the concave / convex pattern of the last fourth layer and the film forming process. In this case, all the processes such as the formation of the concavo-convex pattern, film formation, and sheet bonding that have been performed are wasted. For this reason, the loss of time and cost is greater than that of the optical information recording medium having the two information recording layers described above.
- the first information recording layer 102 and the second information recording layer 106 are sequentially described in the same manner as the two-layer medium shown in FIG. Formed by the procedure. At this time, a problem may occur in the formation process of the concave / convex pattern and the spacer layer for forming the second information recording layer 106. In this case, all the processes such as the formation of the concavo-convex pattern and the film formation performed so far are wasted.
- the present invention has been made in view of such problems, and it is an object of the present invention to provide an optical information storage medium and a manufacturing method with good yield.
- an uneven pattern for guiding laser light is formed on both sides of a second substrate, an information recording layer is formed on the uneven pattern, and the second
- the first substrate is bonded to the film formation surface of one information storage layer of the second substrate via an ultraviolet curable resin, and the ultraviolet curable resin is applied to the film formation surface of the other information storage layer of the second substrate.
- a third substrate is bonded.
- a first ultraviolet curable resin is applied to one surface of a second substrate, and a fine pattern is formed in advance on the application surface of the first ultraviolet curable resin.
- the first ultraviolet curable resin is applied to the other surface of the second substrate by irradiating ultraviolet rays from the outside.
- another mold in which a fine pattern is formed in advance is bonded to the application surface of the first ultraviolet curable resin, and after the first ultraviolet curable resin is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- Second UV curable resin on the surface After applying, pasting the first substrate on the application surface of the second UV curable resin, developing the second UV curable resin by spin coating method, irradiating ultraviolet rays from the outside, The mold remaining on the substrate is separated at the interface with the first ultraviolet curable resin to transfer the uneven pattern, an information storage layer is formed on the transfer surface of the uneven pattern, and the information storage layer is formed
- a second UV curable resin is applied to the surface, a third substrate is bonded to the application surface of the second UV curable resin, the second UV curable resin is spread by a spin coat method, and then externally. Irradiate ultraviolet rays.
- a first ultraviolet curable resin is applied to one surface of a second substrate, and a fine pattern is formed in advance on the application surface of the first ultraviolet curable resin.
- Pasting the molded mold developing the first ultraviolet curable resin by spin coating, and then irradiating ultraviolet rays from the outside, and applying the first ultraviolet curable resin to the other surface of the second substrate
- After applying, pasting another mold on which the fine pattern has been formed in advance to the application surface of the first UV curable resin developing the first UV curable resin by spin coating, and then applying UV rays from the outside.
- the second ultraviolet curable resin is applied to the substrate, the first substrate is bonded to the application surface of the second ultraviolet curable resin, the second ultraviolet curable resin is spread by a spin coating method, and then the ultraviolet rays are externally applied. And the mold remaining on the second substrate are separated at the interface with the first ultraviolet curable resin to transfer the concavo-convex pattern, and an information storage layer is formed on the transfer surface of the concavo-convex pattern.
- the third substrate of the first structure The second ultraviolet curable resin is applied to the surface, the information storage layer film-forming surface of the second structure is bonded to the application surface of the second ultraviolet curable resin, and the second ultraviolet curable resin is spun. After spreading by the coating method, ultraviolet rays are irradiated from the outside.
- a first ultraviolet curable resin is applied to one surface of a second substrate, and a fine pattern is formed in advance on the application surface of the first ultraviolet curable resin.
- Pasting the molded mold developing the first ultraviolet curable resin by spin coating, and then irradiating ultraviolet rays from the outside, and applying the first ultraviolet curable resin to the other surface of the second substrate
- After applying, pasting another mold on which the fine pattern has been formed in advance to the application surface of the first UV curable resin developing the first UV curable resin by spin coating, and then applying UV rays from the outside.
- the third structure One of the third structures is coated with a second ultraviolet curable resin on the surface of the information storage layer, and the third substrate is bonded to the second ultraviolet curable resin coated surface. Then, after developing the second ultraviolet curable resin by a spin coating method, a fourth structure is produced by irradiating ultraviolet rays from the outside, and the second ultraviolet curable is applied to the third substrate of the fourth structure.
- a resin is applied, and a film formation surface of the information storage layer in the third structure on the other side is bonded to the application surface of the second ultraviolet curable resin, and the second ultraviolet curable resin is spin-coated. And then irradiating ultraviolet rays from the outside, separating the mold remaining on the third structure side on the other side at the interface with the first ultraviolet curable resin, transferring the concavo-convex pattern, An information storage layer is formed on the transfer surface of the film, and the information storage layer is formed
- the second ultraviolet curable resin is applied to the substrate, the third substrate is bonded to the application surface of the second ultraviolet curable resin, the second ultraviolet curable resin is spread by a spin coating method, and then the ultraviolet rays are externally applied.
- the mold remaining on the fourth structure side is separated at the interface with the first ultraviolet curable resin to transfer the uneven pattern, and an information storage layer is formed on the transfer surface of the uneven pattern
- the second ultraviolet curable resin is applied to the film formation surface of the information storage layer, the first substrate is bonded to the application surface of the second ultraviolet curable resin, and the second ultraviolet curable resin is spun. After spreading by the coating method, ultraviolet rays are irradiated from the outside.
- a first ultraviolet curable resin is applied to one surface of a second substrate, and a fine pattern is formed in advance on the application surface of the first ultraviolet curable resin.
- Pasting the molded mold developing the first ultraviolet curable resin by spin coating, and then irradiating ultraviolet rays from the outside, and applying the first ultraviolet curable resin to the other surface of the second substrate
- After applying, pasting another mold on which the fine pattern has been formed in advance to the application surface of the first UV curable resin developing the first UV curable resin by spin coating, and then applying UV rays from the outside.
- a cured resin is applied, and a film formation surface of one information storage layer in at least one fifth structure is bonded to the application surface of the second ultraviolet curable resin, and the second ultraviolet curable resin is spin-coated.
- the second ultraviolet curing resin is applied to the film-forming surface of the information storage layer on the other side of the fifth structure, and the second ultraviolet curing resin Bond the third substrate to the resin application surface,
- a step of developing the second ultraviolet curable resin by spin coating and then irradiating ultraviolet rays from the outside, and on the first substrate, the fifth structure and the third substrate, Laminate and paste alternately several times through UV curable resin.
- a transparent stamper was used as a mold.
- the transparent stamper is formed with a preformat or land and groove grooves for an optical disc.
- a stamper in which a pattern was engraved on quartz glass or a stamper in which a pattern was engraved on a polycarbonate (PC) substrate was used as necessary.
- a PC substrate having a thickness in the range of 90 ⁇ m to 1200 ⁇ m was used as necessary.
- the second substrate and the third substrate PC film substrates having a thickness in the range of 20 ⁇ m to 30 ⁇ m were used.
- each ultraviolet curable resin used in the examples described below was an ultraviolet curable resin that was previously degassed in a vacuum before coating. This is to prevent minute bubbles, which are rarely mixed when the ultraviolet curable resin is injected into the coating apparatus, from entering the applied ultraviolet curable resin.
- a polycarbonate stamper (PC stamper) was used as a mold. PC stampers are replicated in large quantities by injection molding.
- the first substrate is disposed on the side irradiated with the laser light.
- a flat polycarbonate substrate (PC substrate) having no uneven pattern formed on the surface was used.
- the thickness of the first substrate is 100 ⁇ m.
- the second substrate has a concavo-convex pattern formed on both surfaces (upper and lower surfaces) via an ultraviolet curable resin.
- a polycarbonate film substrate (PC film substrate) was used as the second substrate.
- the thickness of the second substrate is 25 ⁇ m.
- a polycarbonate film substrate (PC film substrate) was used as the third substrate.
- the thickness of the third substrate is 25 ⁇ m.
- the set film thicknesses of the first ultraviolet curable resin 21 and the second ultraviolet curable resin 22 were each 1 ⁇ m.
- the ultraviolet curable resin applied to form the concavo-convex pattern on both surfaces of the second substrate was the first ultraviolet curable resin, and the other ultraviolet curable resin was the second ultraviolet curable resin.
- FIG. 1A a first ultraviolet curable resin 21 is applied to one surface of the second substrate 12. And as shown to FIG. 1B and C, the mold 30 is bonded to the application surface of the 1st ultraviolet curable resin 21.
- FIG. A fine pattern is formed in advance on the mold 30. Further, after the first ultraviolet curable resin 21 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- the first ultraviolet curable resin 21 is also applied to the other surface of the second substrate 12. Then, as shown in FIGS. 2A and 2B, another mold 31 is bonded to the surface on which the first ultraviolet curable resin 21 is applied. A fine pattern is formed in advance on the mold 31. Further, after the first ultraviolet curable resin 21 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- one of the molds 31 is separated at the interface with the first ultraviolet curable resin 21 to transfer the uneven pattern.
- an information storage layer 41 is formed on the transfer surface of the uneven pattern.
- a second ultraviolet curable resin 22 is applied to the film formation surface of the information storage layer 41. Then, the first substrate 11 is bonded to the application surface of the second ultraviolet curable resin 22. Further, after the second ultraviolet curable resin 22 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- the mold 30 remaining on the second substrate 12 is separated at the interface with the first ultraviolet curable resin 21 to transfer the uneven pattern.
- an information storage layer 42 is formed on the transfer surface of the uneven pattern.
- the second ultraviolet curable resin 22 is applied to the film formation surface of the information storage layer 42. And the 3rd board
- a concavo-convex pattern for guiding laser light is formed on both sides of the second substrate 12, and information recording layers 41 and 42 are formed in the concavo-convex pattern.
- the second substrate 12 provided with the information recording layers 41 and 42 and the substrates 11 and 13 different from the substrate 12 are alternately laminated using the ultraviolet curable resin 22.
- a bonded type optical information storage medium having two information recording layers 41 and 42 is obtained. That is, on the both sides of the second substrate 12 having a thickness of 25 ⁇ m, the fine concavo-convex pattern for guiding the laser beam and the information recording layers 41 and 42 are formed on the first substrate 11 having a thickness of 100 ⁇ m.
- the third substrate 13 having a thickness of 25 ⁇ m is used as a dummy substrate.
- a concavo-convex pattern is formed and transferred almost simultaneously on both surfaces of the second substrate 12. Therefore, even if a problem occurs in the transfer process, the process can be stopped relatively early in the process. Therefore, it is not necessary to perform a useless process as in the production of a conventional optical information recording medium. Therefore, it is possible to stably provide a multilayer optical information recording medium capable of obtaining a reproduction signal of good quality without reducing the yield.
- the film thickness of the first ultraviolet curable resin 21 for forming the uneven pattern may be at least about 50 nm.
- the UV curable resin is applied and spread by a spin coating method, if the resin film thickness is as thin as about 50 nm, it is difficult to apply it cleanly due to the fine unevenness of the application surface and the influence of surface deposits.
- the resin film thickness after applying the resin, spin-developing and UV curing is in the range of 0.5 ⁇ m or more.
- the resin film thickness after UV curing was adjusted to 1 ⁇ m, it was confirmed by measuring the film thickness that the resin film thickness in the disk surface was in the range of 0.9 ⁇ m to 1.1 ⁇ m.
- the second ultraviolet curable resin 22 used for bonding the substrates is also preferably within a range of 0.5 ⁇ m or more after the resin is applied, spin-developed, and ultraviolet cured.
- the resin film thickness after UV curing was adjusted to 1 ⁇ m, it was confirmed by measuring the film thickness that the resin film thickness after adhesion was in the range of 0.9 ⁇ m to 1.1 ⁇ m. It can be seen that the fluctuations in the resin film thickness vary about plus / minus 10% with respect to the set film thickness, and there is a variation of 20% in the peak width.
- FIG. 23 is a sectional view showing a general multilayer optical information recording medium.
- a plurality of information recording layers (a total of n + 1 layers in the example of FIG. 23) are stacked on a substrate via spacer layers.
- each information recording layer is in the order of L0 as the information recording layer closest to the laser light incident surface, L1 as the second information recording layer from the laser incident surface, and L2 as the next information storage layer. Will be identified.
- the information recording layers L0, L1,... Ln in the drawing are provided on the concave / convex pattern, but the concave / convex pattern is omitted in the drawing.
- the spacer layer serves to bond a plurality of information recording layers.
- the crosstalk between layers indicates a reflected light component from another information storage layer as shown in FIG. 24 (here, reflected light from the information storage layer L1 during reproduction of the information storage layer L0). component).
- the reflected light component is included in a reproduction signal obtained at the time of reproduction from a predetermined information recording layer.
- the thickness of the spacer layer needs to be optimized in consideration of the trade-off between reduction of interlayer crosstalk and increase of spherical aberration. More specifically, as shown in FIG. 22, when the concave / convex pattern and the spacer layer for forming the information recording layer 106 are formed of an ultraviolet curable resin, the resin film thickness is about 20 ⁇ m at the minimum. Is required.
- this ultraviolet curable resin is generally applied and spread on a substrate by spin coating.
- the coating film thickness varies by approximately 10% to 20% of the coating film thickness.
- the coating film thickness fluctuates by about 2 ⁇ m to 4 ⁇ m affects the above-mentioned interlayer crosstalk and spherical aberration. This influence causes the quality of the reproduction signal to deteriorate.
- the thickness of the spacer layer needs to be optimized in the present invention in consideration of the trade-off between the reduction of interlayer crosstalk and the increase of spherical aberration.
- the spacer layer influencing the interlayer crosstalk is determined based on the film thickness of the second substrate 12 and the second substrate 12. This is the sum of the thicknesses of the concavo-convex patterns formed by the first ultraviolet curable resin 21 provided on both sides. That is, it can be seen that the spacer layer is in the range of 26.8 ⁇ m to 27.2 ⁇ m.
- This level of fluctuation does not have any level of influence on the above-described interlayer crosstalk and spherical aberration.
- the reason why the set value of the spacer layer is set to 27 ⁇ m is that the thickness of the second substrate 12 is 25 ⁇ m and the thickness of the first ultraviolet curable resin 21 provided on both sides thereof is 1 ⁇ m.
- the laser light passes through the first substrate 11 and enters the information storage layers L0 and L1.
- the film thickness of the first UV curable resin 21 and the second UV curable resin 22 exceeds 1 ⁇ m, it can be dealt with by correcting spherical aberration up to a certain range. However, when the aberration correction range is exceeded, the reproduction signal quality is deteriorated.
- Table 1 shows the film thickness of each ultraviolet curable resin and the information storage layer L0 when the set film thickness of the first ultraviolet curable resin 21 and the second ultraviolet curable resin 22 is changed in the range of 0.5 ⁇ m to 6 ⁇ m.
- the bit error rate relationship during playback is shown.
- the spacer layer has a thickness of the second substrate 12 and an uneven pattern film formed of the first ultraviolet curable resin 21 provided on both sides of the second substrate 12.
- the total thickness. Therefore, the thickness of the second substrate 12 is the sum of the film thickness of the second substrate 12 and the film thickness of the concave / convex pattern formed by the first ultraviolet curable resin 21 provided on both sides of the second substrate 12.
- the thickness of the second ultraviolet curable resin 22 is changed in the same manner as the first ultraviolet curable resin 21. It was. Here, the thickness of the second ultraviolet curable resin 22 does not directly affect interlayer crosstalk and spherical aberration.
- the variation of the resin film thickness can be reduced by reducing the thickness of the UV curable resin film which tends to cause the film thickness variation as much as possible. Therefore, the film thickness of the first ultraviolet curable resin 21 is desirably in the range of 0.5 ⁇ m to 5 ⁇ m (0.5 ⁇ m or more and 5 ⁇ m or less).
- the interlayer adhesive resin and the concave / convex pattern and pits for guiding the laser beam were formed of an ultraviolet curable resin of 5 ⁇ m or less. Therefore, a reproduction signal with high signal quality can be obtained in each information recording layer.
- the number of optical information recording media that can be accommodated in a cartridge of the same volume is dramatically increased. Therefore, the recording capacity per unit volume can be remarkably increased, and the capacity of the optical disc system can be easily increased.
- the thickness of the spacer layer shown in FIG. 22 was measured in the same manner as in the first example.
- the spacer layer also serves as a concavo-convex pattern formed using the ultraviolet curable resin 103 of an optical information recording medium having two information recording layers.
- molded by injection molding the PC board with a thickness of 0.6 mm was used.
- the dummy bonding substrate 108 a PC substrate having a thickness of 0.6 mm was used.
- Such an optical information recording medium has the same form as a commonly used optical information recording medium having two information recording layers.
- the film thickness of the spacer layer As a result of measuring the film thickness of the spacer layer, it was found that the film thickness was in the range of 24.3 ⁇ m to 29.5 ⁇ m with respect to the film thickness setting value of 27 ⁇ m. Thus, when the resin film thickness increases, the fluctuation range of the resin film thickness after ultraviolet curing also increases. The ratio is substantially equal to the fluctuation range shown in the first embodiment, and the fluctuation is about 20% of the set value at the peak width.
- the bit error rate is 1.8 ⁇ 10 ⁇ 4 , indicating that the error rate is slightly high.
- the spacer layer is formed of a film substrate having a constant thickness. Furthermore, it is preferable to form the adhesive layer and the portion of the fine concavo-convex pattern for guiding the laser beam with an ultraviolet curable resin. As a result, a multilayer optical information recording medium having excellent signal quality can be obtained.
- the total thickness of the medium is 154 ⁇ m.
- the optical information storage medium of the first embodiment can be compressed to a thickness of about 1/4 although there is no difference in the recording capacity of the two information recording layers.
- the optical information storage medium of the first embodiment can store 193 sheets and the optical information storage medium of this comparative example can store 44 sheets. . That is, the recording capacity can be increased about four times by using the optical information storage medium of the first embodiment.
- the optical information storage medium of the first embodiment is used as a first structure, and an optical information storage medium is formed together with the second structure.
- a polycarbonate stamper (PC stamper) was used as a mold. PC stampers are replicated in large quantities by injection molding.
- the first substrate is disposed on the uppermost layer and the lowermost layer.
- a flat polycarbonate substrate (PC substrate) having no uneven pattern formed on the surface was used.
- the thickness of the first substrate is 100 ⁇ m.
- the second substrate has a concavo-convex pattern formed on both surfaces (upper and lower surfaces) via an ultraviolet curable resin.
- a polycarbonate film substrate (PC film substrate) was used as the second substrate.
- the thickness of the second substrate is 25 ⁇ m.
- a polycarbonate film substrate (PC film substrate) was used as the third substrate.
- the thickness of the third substrate is 25 ⁇ m.
- the set film thicknesses of the first ultraviolet curable resin 21 and the second ultraviolet curable resin 22 were each 1 ⁇ m. Also in this example, the ultraviolet curable resin applied to form the uneven pattern on the second substrate was the first ultraviolet curable resin, and the other ultraviolet curable resin was the second ultraviolet curable resin.
- a procedure for manufacturing an optical information storage medium will be described below with reference to FIGS.
- a first ultraviolet curable resin 21 is applied to one surface of the second substrate 12.
- the mold 30 is bonded to the application surface of the first ultraviolet curable resin 21.
- a fine pattern is formed in advance on the mold 30.
- ultraviolet rays are irradiated from the outside.
- the first ultraviolet curable resin 21 is also applied to the other surface of the second substrate 12. Then, as shown in FIGS. 6A and 6B, another mold 31 is bonded to the application surface of the first ultraviolet curable resin 21. A fine pattern is formed in advance on the mold 31. Further, after the first ultraviolet curable resin 21 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- one of the molds 31 is separated at the interface with the first ultraviolet curable resin 21 to transfer the uneven pattern.
- an information storage layer 41 is formed on the transfer surface of the uneven pattern.
- a second ultraviolet curable resin 22 is applied to the film formation surface of the information storage layer 41. Then, as shown in FIG. 7B, the first substrate 11 is bonded to the application surface of the second ultraviolet curable resin 22. Further, after the second ultraviolet curable resin 22 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- the mold 30 remaining on the second substrate 12 is separated at the interface with the first ultraviolet curable resin 21 to transfer the uneven pattern.
- an information storage layer 42 is formed on the transfer surface of the uneven pattern. As a result, a second structure is produced.
- the second structure and the first structure manufactured according to the first embodiment are used, and the second substrate 13 of the first structure is used as the second structure.
- UV curable resin 22 is applied.
- the film formation surface of the information storage layer 42 in the second structure is bonded to the application surface of the second ultraviolet curable resin 22.
- an optical information recording medium having four information recording layers (L0 to L3) as shown in FIG. Is obtained.
- the concave / convex pattern for guiding the laser beam is formed on both sides of the second substrate 12, and the information recording layers 41 and 42 are formed in the concave / convex pattern.
- the second substrate 12 provided with the information recording layers 41 and 42 and the substrates 11 and 13 different from the substrate 12 are alternately laminated using the ultraviolet curable resin 22.
- the uneven pattern is formed and transferred on both surfaces of the second substrate 12 almost simultaneously. Therefore, even if a problem occurs in the transfer process, the process can be stopped relatively early in the process. Therefore, it is not necessary to perform a useless process as in the production of a conventional optical information recording medium. Therefore, it is possible to stably provide a multilayer optical information recording medium capable of obtaining a reproduction signal of good quality without reducing the yield.
- optical information storage medium having such a configuration, laser light is transmitted through the first substrate 11 and is incident on each information storage layer (L0 to L3), and information is recorded / reproduced.
- the total thickness of the optical information recording medium having the four information recording layers described above is about 208 ⁇ m.
- information is recorded on and reproduced from each information recording layer with the configuration shown in FIG.
- the thickness of the spacer layer that affects the interlayer crosstalk is the second substrate 12 and both sides thereof. It is the thickness of the uneven
- the film thickness variation of the first ultraviolet curable resin 21 affects the interlayer crosstalk. Therefore, the resin film thickness is desirably in the range of 0.5 ⁇ m to 5 ⁇ m as described in the first embodiment.
- the thickness of the spacer layer that affects the interlayer crosstalk is the second substrate 13 and the second layers formed on both sides thereof. This is the thickness of the adhesive layer made of the ultraviolet curable resin 22. In this case, the film thickness variation of the second ultraviolet curable resin 22 affects the interlayer crosstalk.
- Table 2 shows the film thickness of each resin and the information storage layer L1 when the set film thicknesses of the first UV curable resin 21 and the second UV curable resin 22 are changed in the range of 0.5 ⁇ m to 6 ⁇ m. The bit error rate relationship is shown.
- the thickness of the spacer layer that affects the interlayer crosstalk during the reproduction of the information storage layer L1 is the thickness of the third substrate 13 and the second ultraviolet light provided on both sides of the third substrate 13. This is the sum of the thicknesses of the concave and convex patterns formed with the cured resin 22.
- the thickness of the third substrate 13 is the sum of the thickness of the third substrate 13 and the thickness of the concave / convex pattern formed by the second ultraviolet curable resin 22 provided on both sides of the third substrate 13. It was changed in the range of 15 ⁇ m to 26 ⁇ m so as to always be 27 ⁇ m.
- the thickness of the second substrate 12 is the sum of the film thickness of the second substrate 12 and the film thickness of the concave / convex pattern formed by the first ultraviolet curable resin 21 provided on both sides of the second substrate 12. It was changed in the range of 15 ⁇ m to 26 ⁇ m so as to always be 27 ⁇ m.
- the variation of the resin film thickness can be reduced by reducing the thickness of the UV curable resin film which tends to cause the film thickness variation as much as possible. Therefore, the film thicknesses of the first UV curable resin 21 and the second UV curable resin 22 are preferably in the range of 0.5 ⁇ m to 5 ⁇ m, respectively.
- the interlayer adhesive resin and the concave / convex pattern and pits for guiding the laser beam were formed of an ultraviolet curable resin of 5 ⁇ m or less. Therefore, a reproduction signal with high signal quality can be obtained in each information recording layer.
- a thin substrate having a thickness of about 100 ⁇ m was used as the first substrate instead of the conventionally used thick substrate of 600 ⁇ m or 1200 ⁇ m.
- a plurality of information recording layers were sequentially stacked on the substrate.
- an optical information storage medium is formed by using the third structure and the fourth structure.
- a polycarbonate stamper (PC stamper) was used as a mold. PC stampers are replicated in large quantities by injection molding.
- the first substrate is disposed on the bottom layer.
- a flat polycarbonate substrate (PC substrate) having no uneven pattern formed on the surface was used.
- the thickness of the first substrate is 100 ⁇ m.
- An uneven pattern is formed on both surfaces (upper and lower surfaces) of the second substrate via an ultraviolet curable resin.
- a polycarbonate film substrate (PC film substrate) was used as the second substrate.
- the thickness of the second substrate is 25 ⁇ m.
- a polycarbonate film substrate (PC film substrate) was used as the third substrate.
- the thickness of the third substrate is 25 ⁇ m.
- the set film thicknesses of the first ultraviolet curable resin 21 and the second ultraviolet curable resin 22 were each 1 ⁇ m. Also in this example, the ultraviolet curable resin applied to form the uneven pattern on both surfaces of the second substrate was the first ultraviolet curable resin, and the other ultraviolet curable resin was the second ultraviolet curable resin.
- FIG. 10A a first ultraviolet curable resin 21 is applied to one surface of the second substrate 12. Then, as shown in FIGS. 10B and 10C, the mold 30 is bonded to the application surface of the first ultraviolet curable resin 21. A fine pattern is formed in advance on the mold 30. Further, after the first ultraviolet curable resin 21 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- the first ultraviolet curable resin 21 is also applied to the other surface of the second substrate 12. Then, as shown in FIGS. 11A and 11B, another mold 31 is bonded to the application surface of the first ultraviolet curable resin 21. A fine pattern is formed in advance on the mold 31. Further, after the first ultraviolet curable resin 21 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- one mold 31 is separated at the interface with the first ultraviolet curable resin 21 to transfer the uneven pattern.
- the information storage layer 41 is formed into a film in the transfer surface of the said uneven
- the second ultraviolet curable resin 22 is applied to the film formation surface of the information storage layer 41 in one of the third structures.
- substrate 13 is bonded to the application surface of the 2nd ultraviolet curing resin 22.
- the fourth structure is produced by irradiating ultraviolet rays from the outside.
- a second ultraviolet curable resin 22 is applied to the third substrate 13 of the fourth structure. And as shown to FIG. 13A, the film-forming surface of the information storage layer 41 in the 3rd structure of the other side is bonded to the application surface of the 2nd ultraviolet curable resin 22. FIG. Further, after the second ultraviolet curable resin 22 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- the mold 30 remaining on the third structure side on the other side is separated at the interface with the first ultraviolet curable resin 21 to transfer the uneven pattern.
- the information storage layer 42 is formed on the transfer surface of the uneven pattern.
- a second ultraviolet curable resin 22 is applied to the film formation surface of the information storage layer 42.
- substrate 13 is bonded to the application surface of the 2nd ultraviolet curable resin 22.
- ultraviolet rays are irradiated from the outside.
- the mold 30 remaining on the fourth structure side is separated at the interface with the first ultraviolet curable resin 21 to transfer the uneven pattern.
- an information storage layer 43 is formed on the transfer surface of the uneven pattern.
- the second ultraviolet curable resin 22 is applied to the film formation surface of the information storage layer 43.
- substrate 11 is bonded to the application surface of the 2nd ultraviolet curing resin 22.
- FIG. 15B after the second ultraviolet curable resin 22 is developed by a spin coating method, ultraviolet rays are irradiated from the outside. As a result, an optical information recording medium having four information recording layers (L0 to L3) is obtained.
- the concave / convex pattern for guiding the laser beam is formed on both sides of the second substrate 12, and the information recording layers 41 and 42 are formed in the concave / convex pattern.
- the second substrate 12 provided with the information recording layers 41 and 42 and a substrate different from the substrate 12 are alternately laminated using an ultraviolet curable resin.
- the uneven pattern is formed and transferred on both surfaces of the second substrate 12 almost simultaneously. Therefore, even if a problem occurs in the transfer process, the process can be stopped relatively early in the process. Therefore, it is not necessary to perform a useless process as in the production of a conventional optical information recording medium. Therefore, it is possible to stably provide a multilayer optical information recording medium capable of obtaining a reproduction signal with good quality without reducing the yield.
- optical information storage medium having such a configuration, laser light is transmitted through the first substrate 11 and is incident on each of the information storage layers L0 to L3, and information is recorded and reproduced.
- the total thickness of the optical information recording medium having the four information recording layers described above is about 208 ⁇ m.
- information is recorded on and reproduced from each information recording layer with the configuration shown in FIG.
- the bit error rate during reproduction of each of the information storage layers L0 to L3 of the optical information storage medium shown in FIG. 15C is in the range of 1.2 ⁇ 10 ⁇ 5 to 1.5 ⁇ 10 ⁇ 5 . For this reason, it was confirmed that the optical information storage medium produced by the process shown in this example was not particularly problematic.
- the interlayer adhesive resin and the concave / convex pattern and pits for guiding the laser beam were formed of an ultraviolet curable resin of 5 ⁇ m or less. Therefore, a reproduction signal with high signal quality can be obtained in each information recording layer.
- a thin substrate having a thickness of about 100 ⁇ m was used as the first substrate instead of the conventionally used thick substrate of 600 ⁇ m or 1200 ⁇ m.
- a plurality of information recording layers were sequentially stacked on the substrate.
- a polycarbonate stamper (PC stamper) was used as a mold. PC stampers are replicated in large quantities by injection molding.
- the first substrate is disposed on the bottom layer.
- a flat polycarbonate substrate (PC substrate) having no uneven pattern formed on the surface was used.
- the thickness of the first substrate is 100 ⁇ m.
- An uneven pattern is formed on both surfaces (upper and lower surfaces) of the second substrate via an ultraviolet curable resin.
- a polycarbonate film substrate (PC film substrate) was used as the second substrate.
- the thickness of the second substrate is 25 ⁇ m.
- a polycarbonate film substrate (PC film substrate) was used as the third substrate.
- the thickness of the third substrate is 25 ⁇ m.
- the set film thicknesses of the first ultraviolet curable resin 21 and the second ultraviolet curable resin 22 were each 1 ⁇ m. Also in this example, the ultraviolet curable resin applied to form the uneven pattern on both surfaces of the second substrate was the first ultraviolet curable resin, and the other ultraviolet curable resin was the second ultraviolet curable resin.
- FIG. 16A a first ultraviolet curable resin 21 is applied to one surface of the second substrate 12. Then, as shown in FIGS. 16B and 16C, the mold 30 is bonded to the application surface of the first ultraviolet curable resin 21.
- the mold 30 has a fine pattern formed in advance. Further, after the first ultraviolet curable resin 21 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- the first ultraviolet curable resin 21 is also applied to the other surface of the second substrate 12. Then, as shown in FIGS. 17A and 17B, another mold 31 is bonded to the application surface of the first ultraviolet curable resin 21.
- the mold 31 has a fine pattern formed in advance. Further, after the first ultraviolet curable resin 21 is developed by a spin coating method, ultraviolet rays are irradiated from the outside.
- one of the molds 31 is separated at the interface with the first ultraviolet curable resin 21 to transfer the uneven pattern.
- an information storage layer 41 is formed on the transfer surface of the uneven pattern.
- the mold 30 remaining on the second substrate 12 is separated at the interface with the first ultraviolet curable resin 21 to transfer the uneven pattern.
- an information storage layer 42 is formed on the transfer surface of the uneven pattern.
- a concavo-convex pattern is formed on both surfaces of the second substrate 12 by the first ultraviolet curable resin 21. Furthermore, information storage layers 41 and 42 are formed thereon.
- the fifth structure and the third substrate 13 are alternately laminated on the first substrate 11 a plurality of times via the second ultraviolet curable resin 22.
- the second ultraviolet curable resin 22 is applied to the first substrate 11, and the information storage layer 42 (however, the information in the fifth structure) is applied to the application surface of the second ultraviolet curable resin 22.
- the film formation surface of the memory layer 41 is also bonded.
- ultraviolet rays are irradiated from the outside.
- the second ultraviolet curable resin 22 is applied to the film forming surface of the information storage layer 41 on the other side (however, the information storage layer 42 is also possible) in the fifth structure, and the second ultraviolet curable resin 22 is applied.
- the third substrate 13 is bonded to the coated surface.
- ultraviolet rays are irradiated from the outside.
- substrate 13 are laminated
- the concave / convex pattern for guiding the laser beam is formed on both sides of the second substrate 12, and the information recording layers 41 and 42 are formed in the concave / convex pattern.
- the second substrate 12 provided with the information recording layers 41 and 42 and a substrate different from the substrate 12 are alternately laminated using an ultraviolet curable resin.
- the uneven pattern is formed and transferred on both surfaces of the second substrate 12 almost simultaneously. Therefore, even if a problem occurs in the transfer process, the process can be stopped relatively early in the process. Therefore, it is not necessary to perform a useless process as in the production of a conventional optical information recording medium. Therefore, it is possible to stably provide a multilayer optical information recording medium capable of obtaining a reproduction signal with good quality without reducing the yield.
- optical information storage medium having such a configuration, laser light is transmitted through the first substrate 11 and incident on each of the information storage layers L0 to Ln, and information is recorded and reproduced.
- the above-described optical information recording medium having a plurality of information recording layers also records and reproduces information with respect to each information recording layer with the configuration shown in FIG.
- the interlayer adhesive resin and the concave / convex pattern and pits for guiding the laser beam were formed of an ultraviolet curable resin of 5 ⁇ m or less. Therefore, a reproduction signal with high signal quality can be obtained in each information recording layer. That is, the ranges of the film thicknesses of the first ultraviolet curable resin 21 and the second ultraviolet curable resin 22 are the same as the ranges described in the first to third embodiments, and do not change at all.
- a thin substrate having a thickness of about 100 ⁇ m was used as the first substrate instead of the conventionally used thick substrate of 600 ⁇ m or 1200 ⁇ m.
- a plurality of information recording layers were sequentially stacked on the substrate.
- the first substrate 11 is interposed via the second ultraviolet curable resin 22. May be pasted together.
- a PC film substrate having a thickness of 100 ⁇ m is used as the first substrate 11 in order to reduce the thickness of the optical disk medium per sheet as much as possible. It was. However, there is no problem even if a substrate having a thickness of 90 ⁇ m to 1200 ⁇ m is used as required for the first substrate 11.
- a PC film substrate having a substrate thickness of 90 ⁇ m to 110 ⁇ m is used as the first substrate by the optical system as shown in FIG. Can be used.
- a plurality of information recording layers are stacked on a 1100 ⁇ m substrate like a blue-ray type optical disk medium already commercialized.
- a PC film substrate having a thickness of 90 ⁇ m to 110 ⁇ m may be used as the laser light incident side substrate.
- the disk rotation stabilizing plate (0.5 mmt) shown in FIG. 25 is disposed on the optical head side, and 0.2 mm is provided between the optical disk medium and the stabilizing plate.
- the thicknesses of the second substrate and the third substrate described in the first to fourth embodiments are not limited to the values described above. That is, it is appropriately selected according to the capability of the spherical aberration correction mechanism of the optical head to be used.
- a concavo-convex pattern may be formed on both sides of a second substrate having a thickness of 100 ⁇ m using a first ultraviolet curable resin.
- the third substrate may have a function as a spacer layer, but may be formed on the outermost surface of the optical disk medium.
- the thickness of the substrate is not limited to the value described above.
- a slightly thick substrate having a thickness of 100 ⁇ m may be used as the outermost surface.
- the thickness is appropriately selected according to the capability of the spherical aberration correction mechanism of the optical head to be used.
- All the bonding processes described in the first to fourth embodiments described above are all performed by a vacuum bonding method. That is, each bonding substrate is centered. Then, each board
- the thickness of the information recording layer that affects interlayer crosstalk and spherical aberration is largely changed.
- the thin PC film substrate was used.
- the interlayer adhesive resin and the concave / convex pattern and pits for guiding the laser beam were formed of an ultraviolet curable resin of 5 ⁇ m or less. Thereby, a reproduction signal with high signal quality can be obtained in each information recording layer. Further, this is different from a method of sequentially stacking information recording layers on a substrate as in a conventional method of manufacturing a multilayer optical information recording medium.
- an optical information recording medium having a multilayer structure is produced by appropriately combining structures having a concavo-convex pattern and an information recording layer formed as necessary. Thereby, the improvement of a yield and the loss of a manufacturing member can be suppressed.
- the present invention is applicable to an optical information medium on which information is optically recorded or reproduced by irradiation with a laser beam and a method for manufacturing the same.
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Abstract
Description
すなわち、一枚の光ディスク媒体に複数の情報記録層を有する多層光ディスク媒体を、一つのカートリッジに複数枚収納している。しかし、光ディスクシステム当りの記憶容量を大容量化するためには、一枚の光ディスク媒体の中に設ける情報記録層を可能な限り多くする必要がある。そのため、情報記録層の多層化が一般的に行われている。この場合、関連する技術では、各々の情報記録層を形成する凹凸パターンとスペーサ層の合計膜厚は概略20μm~60μmの範囲にあることが一般的である。ここで凹凸パターンは紫外線硬化樹脂、スペーサ層は紫外線硬化樹脂又は透明なシートで形成される。
以下、本発明の第一の実施例について、図1~図4を参照して具体的に説明する。ここでは、2層の情報記録層を有する光学的情報記録媒体の作製プロセスについて説明する。
先ず、図1Aに示すように、第二の基板12の一方の面に第一の紫外線硬化樹脂21を塗布する。そして、図1B、Cに示すように、第一の紫外線硬化樹脂21の塗布面にモールド30を貼合する。モールド30には、微細パターンが予め形成されている。さらに第一の紫外線硬化樹脂21をスピンコート法により展開した後、外部から紫外線を照射する。
本実施例の光学的情報記憶媒体における情報記憶層41(L0)を再生する場合には、層間クロストークの影響を及ぼすスペーサ層は、第二の基板12の膜厚と第二の基板12の両側に設けられた第一の紫外線硬化樹脂21で形成された凹凸パターンの膜厚を合計した部分になる。すなわち、スペーサ層は26.8μm~27.2μmの範囲にあることが判る。これは設定値27μmに対してプラス/マイナス0.7%程度の膜厚変動である。この程度の変動であれば、上述した層間クロストークや球面収差に何等影響を及ぼすレベルではない。ちなみに、スペーサ層の設定値を27μmとしたのは、第二の基板12の厚みが25μmであり、その両側に設けた第一の紫外線硬化樹脂21の厚みが各々1μmだからである。
比較例として、図22に示したスペーサ層の膜厚を第一の実施例と同様に計測した。当該スペーサ層は、2層の情報記録層を有する光学的情報記録媒体の紫外線硬化樹脂103を用いて形成された凹凸パターンを兼ねたものである。なお、射出成型で凹凸パターンが成型された基板101としては、厚さが0.6mmのPC基板を用いた。また、ダミーの貼合用基板108としては、厚みが0.6mmのPC基板を用いた。このような光学的情報記録媒体は一般的に用いられている2層の情報記録層を有する光学的情報記録媒体と同じ形態である。
次に、第二の実施例として、4層の情報記録層を有する光学的情報記録媒体の作製プロセスについて説明する。ちなみに、本実施例では、上記第一の実施例の光学的情報記憶媒体を第一の構造体として用いて、第二の構造体と共に光学的情報記憶媒体を成している。
先ず、図5Aに示すように、第二の基板12の一方の面に第一の紫外線硬化樹脂21を塗布する。そして、図5B、Cに示すように、第一の紫外線硬化樹脂21の塗布面に、モールド30を貼合する。モールド30には、微細パターンが予め形成されている。さらに当該第一の紫外線硬化樹脂21をスピンコート法により展開した後、外部から紫外線を照射する。
次に、第三の実施例として、第二の実施例とは異なる4層の情報記録層を有する光学的情報記録媒体の作製プロセスについて説明する。ちなみに、本実施例では、第三の構造体と第四の構造体とを用いて、光学的情報記憶媒体を成している。
先ず、図10Aに示すように、第二の基板12の一方の面に第一の紫外線硬化樹脂21を塗布する。そして、図10B、Cに示すように、第一の紫外線硬化樹脂21の塗布面に、モールド30を貼合する。モールド30には、微細パターンが予め形成されている。さらに当該第一の紫外線硬化樹脂21をスピンコート法により展開した後、外部から紫外線を照射する。
次に、第四の実施例として、第一の実施例~第三の実施例とは異なる多層の情報記録層を有する光学的情報記録媒体の製造の手順について説明する。
先ず、図16Aに示すように、第二の基板12の一方の面に第一の紫外線硬化樹脂21を塗布する。そして、図16B、Cに示すように、第一の紫外線硬化樹脂21の塗布面に、モールド30を貼合する。モールド30は、微細パターンが予め形成されている。さらに当該第一の紫外線硬化樹脂21をスピンコート法により展開した後、外部から紫外線を照射する。
また、従来の多層光学的情報記録媒体の製造方法のように基板上に順次、情報記録層を積層する方法とは異なる。つまり、凹凸パターンや情報記録層を成膜済みの構造体を適宜、必要に応じて組み合わせて多層構造を有する光学的情報記録媒体を作製する。これにより、歩留まりの改善や製造部材のロスを抑制できる。
12 第2の基板
13 第3の基板
21、22 紫外線硬化樹脂
30、31 モールド
41、41、43 情報記憶層
101 基板
102 情報記録層
103、105、107 紫外線硬化樹脂
104 スペーサ層
106 情報記録層
108 基板
Claims (13)
- 第二の基板の両側に、レーザ光をガイドするための凹凸パターンを形成し、
前記凹凸パターンに情報記録層を成膜し、
前記第二の基板における一方の情報記憶層の成膜面に、紫外線硬化樹脂を介して第一の基板を貼合し、
前記第二の基板における他方の情報記憶層の成膜面に、紫外線硬化樹脂を介して第三の基板を貼合することを特徴とする光学的情報記憶媒体の製造方法。 - 前記両面に情報記憶層が成膜された第二の基板と、前記第三の基板とは、紫外線硬化樹脂を介して複数、繰り返して貼合することを特徴とする請求項1に記載の光学的情報記憶媒体の製造方法。
- 第二の基板の一方の面に第一の紫外線硬化樹脂を塗布し、前記第一の紫外線硬化樹脂の塗布面に、微細パターンが予め形成されたモールドを貼合し、前記第一の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射し、
第二の基板の他方の面にも第一の紫外線硬化樹脂を塗布し、前記第一の紫外線硬化樹脂の塗布面に、微細パターンが予め形成された別のモールドを貼合し、前記第一の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射し、
前記いずれか一つのモールドを前記第一の紫外線硬化樹脂との界面で分離して凹凸パターンを転写し、前記凹凸パターンの転写面に情報記憶層を成膜し、
前記情報記憶層の成膜面に第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に第一の基板を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射し、
前記第二の基板に残存する前記モールドを、前記第一の紫外線硬化樹脂との界面で分離して凹凸パターンを転写し、前記凹凸パターンの転写面に情報記憶層を成膜し、
前記情報記憶層の成膜面に第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に第三の基板を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射することを特徴とする光学的情報記録媒体の製造方法。 - 第二の基板の一方の面に第一の紫外線硬化樹脂を塗布し、前記第一の紫外線硬化樹脂の塗布面に、微細パターンが予め形成されたモールドを貼合し、前記第一の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射する工程と、第二の基板の他方の面にも第一の紫外線硬化樹脂を塗布し、前記第一の紫外線硬化樹脂の塗布面に、微細パターンが予め形成された別のモールドを貼合し、前記第一の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射する工程と、前記いずれか一つのモールドを前記第一の紫外線硬化樹脂との界面で分離して凹凸パターンを転写し、前記凹凸パターンの転写面に情報記憶層を成膜する工程と、前記情報記憶層の成膜面に第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に第一の基板を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射する工程と、前記第二の基板に残存する前記モールドを、前記第一の紫外線硬化樹脂との界面で分離して凹凸パターンを転写し、前記凹凸パターンの転写面に情報記憶層を成膜する工程と、により第二の構造体を作製し、
前記請求項1又は2の製造方法により作製された第一の構造体と前記第二の構造体とを用い、前記第一の構造体の第三の基板に前記第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に第二の構造体における情報記憶層の成膜面を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射することを特徴とする光学的情報記録媒体の製造方法。 - 第二の基板の一方の面に第一の紫外線硬化樹脂を塗布し、前記第一の紫外線硬化樹脂の塗布面に、微細パターンが予め形成されたモールドを貼合し、前記第一の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射する工程と、第二の基板の他方の面にも第一の紫外線硬化樹脂を塗布し、前記第一の紫外線硬化樹脂の塗布面に、微細パターンが予め形成された別のモールドを貼合し、前記第一の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射する工程と、前記いずれか一つのモールドを前記第一の紫外線硬化樹脂との界面で分離して凹凸パターンを転写し、前記凹凸パターンの転写面に情報記憶層を成膜する工程と、により第三の構造体を二つ作製し、
一方の前記第三の構造体における情報記憶層の成膜面に第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に第三の基板を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射して第四の構造体を作製し、
前記第四の構造体の第三の基板に第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に、他方側の前記第三の構造体における情報記憶層の成膜面を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射し、
前記他方側の第三の構造体側に残存するモールドを、前記第一の紫外線硬化樹脂との界面で分離して凹凸パターンを転写し、前記凹凸パターンの転写面に情報記憶層を成膜し、
前記情報記憶層の成膜面に第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に第三の基板を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射し、
前記第四の構造体側に残存するモールドを、前記第一の紫外線硬化樹脂との界面で分離して凹凸パターンを転写し、前記凹凸パターンの転写面に情報記憶層を成膜し、
前記情報記憶層の成膜面に前記第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に第一の基板を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射することを特徴とする光学的情報記録媒体の製造方法。 - 第二の基板の一方の面に第一の紫外線硬化樹脂を塗布し、前記第一の紫外線硬化樹脂の塗布面に、微細パターンが予め形成されたモールドを貼合し、前記第一の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射する工程と、第二の基板の他方の面にも第一の紫外線硬化樹脂を塗布し、前記第一の紫外線硬化樹脂の塗布面に、微細パターンが予め形成された別のモールドを貼合し、前記第一の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射する工程と、前記いずれか一つのモールドを前記第一の紫外線硬化樹脂との界面で分離して凹凸パターンを転写し、前記凹凸パターンの転写面に情報記憶層を成膜する工程と、前記第二の基板に残存するモールドを前記第一の紫外線硬化樹脂との界面で分離して凹凸パターンを転写し、前記凹凸パターンの転写面に情報記憶層を成膜する工程と、を複数回繰り返して行い、前記第二の基板の両面に第一の紫外線硬化樹脂により凹凸パターンが形成され、さらにその上に情報記憶層が成膜された複数の第五の構造体を作製し、
第一の基板に第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に少なくとも一つの第五の構造体における一方の情報記憶層の成膜面を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射する工程と、前記第五の構造体における他方側の情報記憶層の成膜面に、第二の紫外線硬化樹脂を塗布し、前記第二の紫外線硬化樹脂の塗布面に第三の基板を貼合し、前記第二の紫外線硬化樹脂をスピンコート法により展開した後、外部から紫外線を照射する工程とを含み、第一の基板上に、第五の構造体と第三の基板とを、第二の紫外線硬化樹脂を介して、交互に複数回、積層、貼合することを特徴とする光学的情報記録媒体の製造方法。 - 前記第一の紫外線硬化樹脂の膜厚は0.5μm以上5μm以下の範囲にあることを特徴とする請求項3乃至6のいずれか1項に記載の光学的情報記録媒体の製造方法。
- 前記第二の紫外線硬化樹脂の膜厚は0.5μm以上5μm以下の範囲にあることを特徴とする請求項3乃至6のいずれか1項に記載の光学的情報記録媒体の製造方法。
- 前記第一の基板の板厚は90μm以上1200μm以下の範囲にあることを特徴とする請求項3乃至6のいずれか1項に記載の光学的情報記録媒体の製造方法。
- 請求項1乃至請求項9のいずれか1項に記載の光学的情報記録媒体の製造方法により作製したことを特徴とする光学的情報記録媒体。
- 前記第一の紫外線硬化樹脂の膜厚は0.5μm以上5μm以下の範囲にあることを特徴とする請求項10に記載の光学的情報記録媒体。
- 前記第二の紫外線硬化樹脂の膜厚は0.5μm以上5μm以下の範囲にあることを特徴とする請求項10に記載の光学的情報記録媒体。
- 前記第一の基板の板厚は90μm以上1200μm以下の範囲にあることを特徴とする請求項10に記載の光学的情報記録媒体。
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