WO2010002154A3 - 신규한 유기염료 및 이의 제조방법 - Google Patents

신규한 유기염료 및 이의 제조방법 Download PDF

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Publication number
WO2010002154A3
WO2010002154A3 PCT/KR2009/003500 KR2009003500W WO2010002154A3 WO 2010002154 A3 WO2010002154 A3 WO 2010002154A3 KR 2009003500 W KR2009003500 W KR 2009003500W WO 2010002154 A3 WO2010002154 A3 WO 2010002154A3
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WO
WIPO (PCT)
Prior art keywords
preparing same
novel organic
organic dye
dye
present
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PCT/KR2009/003500
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English (en)
French (fr)
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WO2010002154A2 (ko
Inventor
이종찬
백종협
양회택
Original Assignee
주식회사 동진쎄미켐
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Application filed by 주식회사 동진쎄미켐 filed Critical 주식회사 동진쎄미켐
Priority to JP2011516139A priority Critical patent/JP5623396B2/ja
Priority to US13/000,807 priority patent/US20110094588A1/en
Priority to EP09773690.4A priority patent/EP2341107B1/en
Priority to CN2009801250355A priority patent/CN102076781A/zh
Publication of WO2010002154A2 publication Critical patent/WO2010002154A2/ko
Publication of WO2010002154A3 publication Critical patent/WO2010002154A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B57/00—Other synthetic dyes of known constitution
    • C09B57/008—Triarylamine dyes containing no other chromophores
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B49/00—Sulfur dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/0008—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/10—The polymethine chain containing an even number of >CH- groups
    • C09B23/105—The polymethine chain containing an even number of >CH- groups two >CH- groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/14—Styryl dyes
    • C09B23/148—Stilbene dyes containing the moiety -C6H5-CH=CH-C6H5
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B49/00—Sulfur dyes
    • C09B49/12—Sulfur dyes from other compounds, e.g. other heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B57/00—Other synthetic dyes of known constitution
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • H10K85/1135—Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/631—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
    • H10K85/633—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine comprising polycyclic condensed aromatic hydrocarbons as substituents on the nitrogen atom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/655—Aromatic compounds comprising a hetero atom comprising only sulfur as heteroatom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Hybrid Cells (AREA)
  • Photovoltaic Devices (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

본 발명은 신규한 유기염료 및 이의 제조방법에 관한 것으로, 본 발명의 염료 화합물은 염료감응태양전지(dye-sensitized solar cell, DSSC)에 사용되어 종래의 염료보다 향상된 몰흡광계수, Jsc(단회로 광전류 밀도) 및 광전기 변환효율을 나타내어 태양전지의 효율을 크게 향상시킬 수 있고, 고가의 칼럼을 사용하지 않고도 정제가 가능하여 염료 합성단가를 획기적으로 낮출 수 있다.
PCT/KR2009/003500 2008-06-30 2009-06-29 신규한 유기염료 및 이의 제조방법 WO2010002154A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2011516139A JP5623396B2 (ja) 2008-06-30 2009-06-29 新規な有機染料化合物及びその製造方法
US13/000,807 US20110094588A1 (en) 2008-06-30 2009-06-29 Novel organic dye and preparation thereof
EP09773690.4A EP2341107B1 (en) 2008-06-30 2009-06-29 Novel organic dye and method for preparing same
CN2009801250355A CN102076781A (zh) 2008-06-30 2009-06-29 新型有机染料及其制造方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20080062487 2008-06-30
KR10-2008-0062487 2008-06-30
KR10-2009-0057534 2009-06-26
KR1020090057534A KR101320999B1 (ko) 2008-06-30 2009-06-26 신규한 유기염료 및 이의 제조방법

Publications (2)

Publication Number Publication Date
WO2010002154A2 WO2010002154A2 (ko) 2010-01-07
WO2010002154A3 true WO2010002154A3 (ko) 2010-04-22

Family

ID=41813126

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2009/003500 WO2010002154A2 (ko) 2008-06-30 2009-06-29 신규한 유기염료 및 이의 제조방법

Country Status (7)

Country Link
US (1) US20110094588A1 (ko)
EP (1) EP2341107B1 (ko)
JP (1) JP5623396B2 (ko)
KR (1) KR101320999B1 (ko)
CN (1) CN102076781A (ko)
TW (1) TWI461490B (ko)
WO (1) WO2010002154A2 (ko)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI458787B (zh) 2009-05-15 2014-11-01 Ind Tech Res Inst 有機染料及包含其之光電轉換裝置
JP5791995B2 (ja) * 2011-08-02 2015-10-07 株式会社Adeka 新規化合物、光電変換材料及び光電変換素子
CN102604415B (zh) * 2012-02-28 2014-02-05 大连理工大学 一种噻吩吡嗪类染料的制备方法及其在染料敏化太阳能电池中的应用
JP2013181108A (ja) * 2012-03-01 2013-09-12 Kanto Natural Gas Development Co Ltd 色素増感型光電変換素子用の高活性完全有機色素化合物、およびそれを用いた光電変換素子
EP2831180A1 (en) * 2012-03-30 2015-02-04 Basf Se Quinolinium dyes with fluorinated counter anion for dye sensitized solar cells
CN102675898A (zh) * 2012-04-18 2012-09-19 复旦大学 一种具有双推拉电子基团的有机染料及其制备方法和应用
ITMI20120674A1 (it) * 2012-04-23 2013-10-24 Cnrs Ct Nat De La Rech He Scient Colorante organico per cella solare sensibile ai coloranti
CN103408963B (zh) * 2013-08-08 2014-08-27 陕西师范大学 脲供体双桥链有机染料及其应用
CN103450700B (zh) * 2013-08-23 2015-12-02 中山大学 一种基于咔唑或三苯胺衍生物的树状有机染料及其在制备染料敏化太阳能电池中的应用
ITMI20131899A1 (it) * 2013-11-15 2015-05-16 C N R S Ct Nat De La Rec Herche Scienti Colorante organico per una cella solare sensibilizzata da colorante
CN104086561A (zh) * 2014-07-08 2014-10-08 国家纳米科学中心 一种具有高填充因子的可溶性有机光伏小分子材料、制备方法及其用途
WO2023219042A1 (ja) * 2022-05-10 2023-11-16 富士フイルム株式会社 光電変換素子、撮像素子、光センサ、化合物

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030026984A (ko) * 2000-07-27 2003-04-03 니폰 가야꾸 가부시끼가이샤 색소 증감 광전 변환소자
JP2005135656A (ja) * 2003-10-28 2005-05-26 Shozo Yanagida 光電変換素子
KR20050116146A (ko) * 2003-03-14 2005-12-09 니폰 가야꾸 가부시끼가이샤 색소증감 광전 변환 소자
WO2007100033A1 (ja) * 2006-03-02 2007-09-07 Nippon Kayaku Kabushiki Kaisha 色素増感光電変換素子
KR20070102821A (ko) * 2006-04-17 2007-10-22 삼성에스디아이 주식회사 염료 감응 태양 전지용 염료 및 이로부터 제조된 염료 감응태양 전지
WO2007119525A1 (ja) * 2006-03-31 2007-10-25 National Institute Of Advanced Industrial Science And Technology 有機化合物及びそれを用いた半導体薄膜電極、光電変換素子、光電気化学太陽電池

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000106223A (ja) * 1998-09-29 2000-04-11 Fuji Photo Film Co Ltd 光電変換素子
JP4270381B2 (ja) * 2003-02-28 2009-05-27 国立大学法人京都大学 導電性重合体及びその製造方法並びにそれを用いた有機太陽電池
US8653279B2 (en) * 2006-04-17 2014-02-18 Samsung Sdi Co., Ltd. Dye for dye-sensitized solar cell, and solar cell prepared from same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030026984A (ko) * 2000-07-27 2003-04-03 니폰 가야꾸 가부시끼가이샤 색소 증감 광전 변환소자
KR20050116146A (ko) * 2003-03-14 2005-12-09 니폰 가야꾸 가부시끼가이샤 색소증감 광전 변환 소자
JP2005135656A (ja) * 2003-10-28 2005-05-26 Shozo Yanagida 光電変換素子
WO2007100033A1 (ja) * 2006-03-02 2007-09-07 Nippon Kayaku Kabushiki Kaisha 色素増感光電変換素子
WO2007119525A1 (ja) * 2006-03-31 2007-10-25 National Institute Of Advanced Industrial Science And Technology 有機化合物及びそれを用いた半導体薄膜電極、光電変換素子、光電気化学太陽電池
KR20070102821A (ko) * 2006-04-17 2007-10-22 삼성에스디아이 주식회사 염료 감응 태양 전지용 염료 및 이로부터 제조된 염료 감응태양 전지

Also Published As

Publication number Publication date
EP2341107A2 (en) 2011-07-06
US20110094588A1 (en) 2011-04-28
CN102076781A (zh) 2011-05-25
KR101320999B1 (ko) 2013-10-23
KR20100003215A (ko) 2010-01-07
EP2341107A4 (en) 2012-01-25
JP5623396B2 (ja) 2014-11-12
WO2010002154A2 (ko) 2010-01-07
JP2011526643A (ja) 2011-10-13
EP2341107B1 (en) 2014-07-30
TWI461490B (zh) 2014-11-21
TW201009026A (en) 2010-03-01

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