WO2009142434A3 - 중공사, 중공사 형성용 도프 용액 조성물 및 이를 이용한 중공사의 제조방법 - Google Patents

중공사, 중공사 형성용 도프 용액 조성물 및 이를 이용한 중공사의 제조방법 Download PDF

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Publication number
WO2009142434A3
WO2009142434A3 PCT/KR2009/002645 KR2009002645W WO2009142434A3 WO 2009142434 A3 WO2009142434 A3 WO 2009142434A3 KR 2009002645 W KR2009002645 W KR 2009002645W WO 2009142434 A3 WO2009142434 A3 WO 2009142434A3
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WO
WIPO (PCT)
Prior art keywords
hollow fiber
pores
manufacturing
forming
same
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Application number
PCT/KR2009/002645
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English (en)
French (fr)
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WO2009142434A2 (ko
Inventor
정철호
한상훈
이영무
박호범
Original Assignee
한양대학교 산학협력단
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Application filed by 한양대학교 산학협력단 filed Critical 한양대학교 산학협력단
Priority to EP09750756.0A priority Critical patent/EP2281926B1/en
Priority to JP2011510422A priority patent/JP5265763B2/ja
Priority to CN2009801281372A priority patent/CN102099512B/zh
Priority to MX2010012599A priority patent/MX2010012599A/es
Publication of WO2009142434A2 publication Critical patent/WO2009142434A2/ko
Publication of WO2009142434A3 publication Critical patent/WO2009142434A3/ko

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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0011—Casting solutions therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B01D69/087—Details relating to the spinning process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1042—Copolyimides derived from at least two different tetracarboxylic compounds or two different diamino compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/18—Polybenzimidazoles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/22—Polybenzoxazoles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/32—Polythiazoles; Polythiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • D01D5/247—Discontinuous hollow structure or microporous structure
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/08—Addition of substances to the spinning solution or to the melt for forming hollow filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/74—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polycondensates of cyclic compounds, e.g. polyimides, polybenzimidazoles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/025—Finger pores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/026—Sponge structure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Artificial Filaments (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

중공사의 중앙부에 위치하는 공동, 상기 공동 주변에 존재하는 매크로기공, 그리고 상기 매크로기공 주변에 존재하는 메조기공 및 피코기공을 포함하고, 상기 피코기공은 3차원적으로 서로 연결되어 3차원 네트워크를 형성하고 있는 구조를 가지는 중공사를 제공한다. 상기 중공사는 폴리이미드로부터 유도되는 고분자를 포함하고, 상기 폴리이미드는 아민기에 대하여 오르쏘 위치에 존재하는 적어도 하나의 작용기를 포함하는 방향족 디아민 및 디안하이드라이드로부터 제조된 반복단위를 포함한다.
PCT/KR2009/002645 2008-05-19 2009-05-19 중공사, 중공사 형성용 도프 용액 조성물 및 이를 이용한 중공사의 제조방법 WO2009142434A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP09750756.0A EP2281926B1 (en) 2008-05-19 2009-05-19 Hollow fiber and method for manufacturing a hollow fiber
JP2011510422A JP5265763B2 (ja) 2008-05-19 2009-05-19 中空糸、中空糸形成用ドープ溶液組成物、およびそれを用いた中空糸の製造方法
CN2009801281372A CN102099512B (zh) 2008-05-19 2009-05-19 中空纤维、用于形成中空纤维的掺杂溶液组合物和使用所述掺杂溶液组合物制备中空纤维的方法
MX2010012599A MX2010012599A (es) 2008-05-19 2009-05-19 Fibra hueca, composicion de solucion con aditivo para formar una fibra hueca y metodo para fabricar una fibrra hueca usando la misma.

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20080046127 2008-05-19
KR10-2008-0046127 2008-05-19
KRPCT/KR2008/002863 2008-05-22
KR2008002863 2008-05-22

Publications (2)

Publication Number Publication Date
WO2009142434A2 WO2009142434A2 (ko) 2009-11-26
WO2009142434A3 true WO2009142434A3 (ko) 2010-03-04

Family

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Family Applications (1)

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PCT/KR2009/002645 WO2009142434A2 (ko) 2008-05-19 2009-05-19 중공사, 중공사 형성용 도프 용액 조성물 및 이를 이용한 중공사의 제조방법

Country Status (6)

Country Link
EP (1) EP2281926B1 (ko)
JP (1) JP5265763B2 (ko)
CN (1) CN102099512B (ko)
MX (1) MX2010012599A (ko)
RU (1) RU2465380C2 (ko)
WO (1) WO2009142434A2 (ko)

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KR100932765B1 (ko) 2008-02-28 2009-12-21 한양대학교 산학협력단 폴리이미드-폴리벤조옥사졸 공중합체, 이의 제조방법, 및이를 포함하는 기체 분리막
CA2640517A1 (en) 2008-05-19 2009-11-19 Industry-University Cooperation Foundation, Hanyang University Polyamic acids dope composition, preparation method of hollow fiber using the same and hollow fiber prepared therefrom
MX2011003617A (es) * 2008-10-09 2011-08-08 Iucf Hyu Polimero y metodo de preparacion del mismo.
US8013103B2 (en) 2008-10-10 2011-09-06 Industry-University Cooperation Foundation, Hanyang University Polymer compounds and a preparation method thereof
US8487064B2 (en) 2008-10-10 2013-07-16 Industry-University Cooperation Foundation, Hanyang University Polymer compounds and a preparation method thereof
CA2739033C (en) * 2008-10-17 2017-06-20 Solvay Advanced Polymers, L.L.C. Fiber or foil from polymers with high tg and process for their manufacture
WO2011087344A2 (ko) * 2010-01-18 2011-07-21 한양대학교 산학협력단 다공성 지지체 및 이를 포함하는 연료 전지용 고분자 전해질 막
US20140047976A1 (en) * 2011-04-29 2014-02-20 Yin Fong Yeong Cardo-Polybenzoxazole Polymer/Copolymer Membranes For Improved Permeability And Method For Fabricating The Same
CN102560894A (zh) * 2011-11-17 2012-07-11 江西先材纳米纤维科技有限公司 聚苯并二噁唑纳米纤维非织造布的制备方法及其应用
US8753426B2 (en) * 2012-08-03 2014-06-17 Air Products And Chemicals, Inc. Polymers, polymer membranes and methods of producing the same
JP2016530343A (ja) * 2013-06-06 2016-09-29 キング アブドゥラー ユニバーシティ オブ サイエンス アンド テクノロジー トリプチセン系酸二無水物、ポリイミド、それぞれを製造する方法、及び使用方法
BR112015028307B1 (pt) * 2013-06-21 2022-04-05 Evonik Fibres Gmbh Método de produção de membranas de poliimida
KR101552517B1 (ko) * 2013-07-01 2015-09-11 한양대학교 산학협력단 가교구조를 갖는 열전환 폴리(벤즈옥사졸-이미드)공중합체, 이를 포함하는 기체분리막 및 그 제조방법
US9440197B2 (en) 2013-07-01 2016-09-13 ICUF-HYU (Industry-University Cooperation Foundation Hanyang University) Crosslinked thermally rearranged poly(benzoxazole-co-imide), gas separation membranes comprising the same and preparation method thereof
KR101571393B1 (ko) * 2013-09-26 2015-11-24 한양대학교 산학협력단 막 증류용 열전환 폴리(벤즈옥사졸-이미드) 공중합체 분리막 및 그 제조방법
CN110694495B (zh) * 2013-09-30 2022-09-16 佐治亚科技研究公司 具有改善的渗透性的不对称的改性碳分子筛中空纤维膜
KR102339152B1 (ko) * 2014-10-10 2021-12-15 도레이 카부시키가이샤 내열성 부직포 및 그 제조 방법
CN114130202B (zh) * 2021-12-15 2023-03-14 中国科学院长春应用化学研究所 一种微孔滤膜及其制备方法

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Also Published As

Publication number Publication date
EP2281926A4 (en) 2011-08-10
EP2281926B1 (en) 2018-09-05
RU2010149305A (ru) 2012-06-27
CN102099512B (zh) 2013-05-15
JP2011523683A (ja) 2011-08-18
MX2010012599A (es) 2011-04-26
EP2281926A2 (en) 2011-02-09
CN102099512A (zh) 2011-06-15
RU2465380C2 (ru) 2012-10-27
WO2009142434A2 (ko) 2009-11-26
JP5265763B2 (ja) 2013-08-14

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