WO2009080772A1 - Verfahren zur herstellung eines dekorativen laminats - Google Patents

Verfahren zur herstellung eines dekorativen laminats Download PDF

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Publication number
WO2009080772A1
WO2009080772A1 PCT/EP2008/068070 EP2008068070W WO2009080772A1 WO 2009080772 A1 WO2009080772 A1 WO 2009080772A1 EP 2008068070 W EP2008068070 W EP 2008068070W WO 2009080772 A1 WO2009080772 A1 WO 2009080772A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
core
printing
decor
cover layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/068070
Other languages
German (de)
English (en)
French (fr)
Inventor
Carsten Buhlmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzenta Paneele and Profile GmbH
Original Assignee
Akzenta Paneele and Profile GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to KR1020107016024A priority Critical patent/KR101421323B1/ko
Priority to EP08865432.2A priority patent/EP2227390B1/de
Priority to CN2008801251457A priority patent/CN101918210A/zh
Priority to BRPI0821799-8A priority patent/BRPI0821799B1/pt
Priority to PL08865432T priority patent/PL2227390T3/pl
Priority to ES08865432.2T priority patent/ES2459294T3/es
Application filed by Akzenta Paneele and Profile GmbH filed Critical Akzenta Paneele and Profile GmbH
Priority to US12/809,494 priority patent/US9174423B2/en
Priority to JP2010538770A priority patent/JP5711971B2/ja
Priority to CA2713123A priority patent/CA2713123C/en
Publication of WO2009080772A1 publication Critical patent/WO2009080772A1/de
Anticipated expiration legal-status Critical
Priority to ZA2010/04852A priority patent/ZA201004852B/en
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/14Printing or colouring
    • B32B38/145Printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/02Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board the layer being formed of fibres, chips, or particles, e.g. MDF, HDF, OSB, chipboard, particle board, hardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/06Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/10Applying flat materials, e.g. leaflets, pieces of fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/043Ornamental plaques, e.g. decorative panels, decorative veneers containing wooden elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B2038/0052Other operations not otherwise provided for
    • B32B2038/0076Curing, vulcanising, cross-linking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/08Coating on the layer surface on wood layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/12Coating on the layer surface on paper layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/75Printability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00Animal or vegetable based
    • B32B2317/12Paper, e.g. cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00Animal or vegetable based
    • B32B2317/16Wood, e.g. woodboard, fibreboard, woodchips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00Decorative or ornamental articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00Floor coverings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2479/00Furniture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • B32B2607/02Wall papers, wall coverings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/06Embossing

Definitions

  • the invention relates to a method for producing a decorative laminate, in particular a laminate with a support based on wood-based materials with a decor and at least one cover or protective layer arranged above it.
  • Such laminates are widely used, for example, for floors, wall and ceiling coverings, countertops and furniture.
  • the decor can imitate a different material, such as wood, ceramic, natural or artificial stone, or consider artistic or practical considerations.
  • the decor is protected from wear by a more or less transparent thermoset layer. It is also common to provide the surface of this cover layer with a structure which is spatially related to the decor and is referred to as a synchronous pore.
  • varnish layers are formed from compositions containing heat and / or radiation polymerizable and / or crosslinkable and thus curable components, such as acrylates, epoxies, maleimides.
  • the second material group used for the cover layers comprises the so-called aminoplasts.
  • aminoplasts This is understood as meaning polycondensation products of carbonyl compounds, in particular formaldehyde, and compounds containing amino groups, such as, for example, urea, melamine, urethane.
  • aqueous solutions of Condensation products of carbonyl compound and amine are used with an excess of the carbonyl compound, which crosslink during drying and heating to a thermoset structure. Since both the solvent present as well as the resulting in the condensation reaction water escapes in the form of vapor, the curing must be made at least substantially in a press, so that the product obtains the desired strength and surface quality.
  • the decor is conventionally realized in the form of a printed or otherwise patterned paper or other cellulosic material which is impregnated with a curable lacquer or resin and placed between the support and a wear-inhibiting outer cover layer.
  • the manufacture of the impregnated decorative paper requires separate operations of pressing and impregnation, which are usually performed in factories outside the actual laminate production and represent a significant cost factor. It is also necessary that the impregnating material of the decorative paper with the paint or resin of the top layer is compatible, which can not be expected in particular at the meeting of paint and resin.
  • WO 03/095202 Al proposes to solve this problem, to install a resin-containing intermediate layer on the support before placing the decor paper and to use a decorative paper that contains little or no impregnating resin.
  • this solution does not appear optimal, because the attachment of the intermediate layer means an additional step and the Decorative paper still needs to be printed before the laminate is produced.
  • DE 19532819 A1 discloses a method for producing a wood-based panel having an optically configurable surface, wherein the support panel is sequentially provided with a basic coloring, a seal, a printing base and a decor pressure. As the printing base in this case a surface finish is used. With this structure, therefore, no paper is contained in the decorative layer.
  • WO 2006/002917 A2 describes a method for producing a plate with a surface having a decoration, in which the surface to be provided with the decor is primed, smoothed with several filler layers and roller treatment and printed to produce the decoration.
  • the primer layer may be applied as a synthetic resin layer and the printed surface provided with a seal which may be made of synthetic resin.
  • Parkettmagazin 5/2007 pages 49 to 51, the structure of such a direct-printed plate is described, which has under the ink layer at least one primer and several rolling base layers.
  • the present invention has as its object to provide a method by which the decor can be attached to decorated laminates easier and cheaper. This object is achieved by a method according to the main claim.
  • the carrier or core of the laminate consists essentially of a preferably plate-shaped wood or a wood material. Preference is given to fiberboard, in particular HDF and MDF boards.
  • the cellulose fleece is adhered to the core.
  • either one side of the core and / or one side of the cellulose fleece is advantageously coated with adhesive.
  • the adhesive is preferably a liquid hardening glue, more preferably a urea-formaldehyde glue.
  • Cellulosic nonwoven is understood to mean here all sheetlike structures consisting essentially of cellulose fibers, including paper.
  • the different qualities of the nonwovens differ, for example, through thickness, fiber thickness and porosity. Depending on the desired detail resolution of the printed image, an upper limit for the pore size must be maintained. On the other hand, the porosity promotes the absorption of the ink and the anchoring with the adhesive.
  • the cellulose fleece is preferably a paper, in particular a so-called printing base paper.
  • printing base paper may already have a bright basic color of the decor, but it may also be white or have a different color.
  • Preference is given to papers having a basis weight of from 20 to 200 g / m 2 , more preferably from 40 to 80 g / m 2 .
  • liquid glue is used, then it is favorable to connect the fleece by at least partial curing of the glue under pressure and heat with the core.
  • an advantage of the method with liquid glue is also that the liquid glue during curing can compensate for unevenness of the surface of the core, whereby the contact between printing plate and substrate is improved and the quality of the pressure is increased. This is especially true when the pressure is exerted on the web by means of a calender roll.
  • the decor can be printed with a printing unit monochrome, which advantageously by the hue of the printing base paper a second color can be realized. It is also possible to print several colors in succession with several printing units.
  • the known synthetic resins and lacquers are basically suitable. So it is possible to apply also radiation-crosslinkable coatings as a topcoat. However, preference is given to cover layers of aminoplasts, in particular melamine-formaldehyde resins.
  • a particulate hard solid preferably alumina, silica, silicon carbide or boron nitride. This increases the abrasion resistance of the cover layer.
  • the solid has a suitable average particle size, for example 30 to 200 ⁇ m.
  • the cover layer is applied in the form of a so-called overlay.
  • This is a fibrous layer, for example a paper, which is impregnated with the curable aminoplast provided for the covering layer, for example melamine-formaldehyde resin.
  • the hard solid may also be incorporated.
  • the covering layer of aminoplast in the form of several partial layers and to dry each partial layer before applying the next one. hereby the mechanical properties of the cured topcoat are improved.
  • the particulate hard solid is preferably incorporated into the lower of the sub-layers and not into the outermost sub-layer. This ensures that the solid particles do not protrude from the surface of the finished laminate, which can be detrimental to both appearance and feel as well as lead to wear and damage of tools for further processing, such as the pressing surfaces.
  • the laminate After applying the topcoat, the laminate is heated under pressure.
  • pressures and temperatures to be used depend on the type of resin and the structure of the laminate layers. Suitable ranges are between 20 and 60 kN / cm 2 and 160 to 220 ° C.
  • shape of the pressing surface determines the final structure of the laminate surface.
  • the surface structure can be flexibly changed during the product change if a replaceable press plate or a press belt or a press film is preferably inserted between the press jaws and the laminate surface. So it is also possible, in a spatial relation to the decor standing positive (lowered) or negative (sublime) pore structure
  • the method according to the invention offers the particular advantage that irregularities in the layers are compensated during pressing without further intermediate or subsequent treatment, such as the application of sanding and putty lacquer layers or the treatment with a smoothing roll.
  • the synchronous pore can be realized in a simple manner if a digitally controlled method is used for the production of the press plate, press belt or the press film and for digital printing the same data set as for the press plate, press belt or press film, if necessary after conversion, is used because the printed image does not shrink after printing.
  • the laminate on the non-decorated side of the core is provided with a counter-pull to prevent deformation in changing climatic conditions.
  • a counter-pull to prevent deformation in changing climatic conditions.
  • the counter-train corresponds in its layer structure to the structure of the decorative side.
  • this counter-pull can be applied in each case at the same time with the corresponding layers of the decorative side, that is, if necessary gluing a Gegenzugpa- piers and applying the top layer corresponding layer or layers.
  • the preparation of the laminates for the direct printing compared to the prior art is much more economical because only one layer of cellulose fleece, especially paper, is applied and the multiple coating and smoothing operations required in the known processes omitted.
  • MDF boards of about 2 x 3 m in size are cleaned, smoothed and tempered.
  • an acid hardener for urea-formaldehyde glue (Hardener 2547-Akzo Nobel) is applied at an application weight of about 8 g per square meter at ambient temperature and slightly dried with an IR emitter.
  • a glue layer of about 40 g per square meter (urea-formaldehyde glue in the 1206-Akzo Nobel) is applied again.
  • a cream-colored printing base paper with a basis weight of 60 g per square meter is placed and pressed in a calender with 160 kN / cm and a roller temperature of 190 0 C, wherein the glue cures at least partially.
  • the outer surface of the paper remains unchanged, that is, it does not seize up any glue.
  • the paper is cut in the gap between the plates.
  • the plates are immediately conveyed to a printing station, in which a first color of the decor is printed by indirect gravure printing. In another printing station, the second and third colors are applied, with brief bleeding between the stations sufficient to dry the ink.
  • a thin layer of a melamine-formaldehyde resin (MFH, about 10 g / m 2 ) is applied and dried with an IR emitter until the surface is dust-dry. In this state, the plates can be stacked or stored.
  • the further processing of the decorated panels takes place either immediately after printing (without application of the thin MFH layer) or after application of this layer and storage.
  • a layer of a melamine resin in water, the particles of aluminum oxide is applied to the decor on the upper side of the plate or onto the thin MFH layer by means of an applicator roll (for the purpose of low wear of ceramic)
  • the viscosity of the resin solution is 120 mPas at a solids content of 60% by weight.
  • Resin solution is about 50 g / m, that of corundum 15-20 g / m.
  • the resin coating is not sufficient to completely cover the corundum particles.
  • the resin application weight corresponds to a layer thickness of about 40 ⁇ m (density 1.25 g / cm).
  • the resin application is dried to the extent that its surface is dust-dry and there is sufficient adhesion to the decor. In this case, an air flow is passed over the surface of the resin layer. Simultaneously with the application of resin to the top, an equal application, but without corundum, is applied and dried on the underside of the plate in return.
  • the plate rests during conveying on a suitable conveyor, for example, a known from the painting technique so-called disc transport, which carries the plate selectively and so allows drying of the underside of the plate. After drying, the plate lies on narrow rollers in the edge area. After drying, another layer of about 50 g / m of the aqueous melamine resin is applied to the decorative side and on the underside and again dried. This process is repeated up to three times. As a result, the resin layer now has a thickness of up to 250 ⁇ m and completely covers the corundum particles.
  • the now coated with wear layer and back plate is placed in a KT press and about 8 - 15 s at a temperature of the press plates of about 200 0 C (corresponding to about 160 0 C on

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Laminated Bodies (AREA)
PCT/EP2008/068070 2007-12-21 2008-12-19 Verfahren zur herstellung eines dekorativen laminats Ceased WO2009080772A1 (de)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US12/809,494 US9174423B2 (en) 2007-12-21 2008-12-19 Method for producing a decorative laminate
EP08865432.2A EP2227390B1 (de) 2007-12-21 2008-12-19 Verfahren zur herstellung eines dekorativen laminats
CN2008801251457A CN101918210A (zh) 2007-12-21 2008-12-19 制备装饰性层压材料的方法
BRPI0821799-8A BRPI0821799B1 (pt) 2007-12-21 2008-12-19 Processo para a produção de um laminado decorativo
PL08865432T PL2227390T3 (pl) 2007-12-21 2008-12-19 Sposób wytwarzania dekoracyjnego laminatu
KR1020107016024A KR101421323B1 (ko) 2007-12-21 2008-12-19 장식된 라미네이트의 제조방법
CA2713123A CA2713123C (en) 2007-12-21 2008-12-19 Process for producing a decorative laminate
ES08865432.2T ES2459294T3 (es) 2007-12-21 2008-12-19 Procedimiento para la fabricación de un laminado decorativo
JP2010538770A JP5711971B2 (ja) 2007-12-21 2008-12-19 装飾模様入り積層体を製造するための方法
ZA2010/04852A ZA201004852B (en) 2007-12-21 2010-07-09 Method for producing a decorative laminate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007062600A DE102007062600A1 (de) 2007-12-21 2007-12-21 Verfahren zur Herstellung eines dekorativen Laminats
DE102007062600.4 2007-12-21

Publications (1)

Publication Number Publication Date
WO2009080772A1 true WO2009080772A1 (de) 2009-07-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/068070 Ceased WO2009080772A1 (de) 2007-12-21 2008-12-19 Verfahren zur herstellung eines dekorativen laminats

Country Status (16)

Country Link
US (1) US9174423B2 (enExample)
EP (1) EP2227390B1 (enExample)
JP (1) JP5711971B2 (enExample)
KR (1) KR101421323B1 (enExample)
CN (1) CN101918210A (enExample)
BR (1) BRPI0821799B1 (enExample)
CA (1) CA2713123C (enExample)
DE (1) DE102007062600A1 (enExample)
ES (1) ES2459294T3 (enExample)
MY (1) MY152956A (enExample)
PL (1) PL2227390T3 (enExample)
PT (1) PT2227390E (enExample)
RU (1) RU2459708C2 (enExample)
UA (1) UA98688C2 (enExample)
WO (1) WO2009080772A1 (enExample)
ZA (1) ZA201004852B (enExample)

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011076916A1 (de) 2009-12-23 2011-06-30 Surface Technologies Gmbh & Co. Kg Verfahren und vorrichtung zur herstellung einer beidseitig beschichteten dekorierten platte
WO2014108331A1 (de) * 2013-01-11 2014-07-17 Carl Freudenberg Kg Beschichtungssystem
US8920874B2 (en) 2010-01-15 2014-12-30 Valinge Innovation Ab Method of manufacturing a surface layer of building panels
US8920876B2 (en) 2012-03-19 2014-12-30 Valinge Innovation Ab Method for producing a building panel
US9085905B2 (en) 2011-04-12 2015-07-21 Valinge Innovation Ab Powder based balancing layer
US9181698B2 (en) 2013-01-11 2015-11-10 Valinge Innovation Ab Method of producing a building panel and a building panel
US9255405B2 (en) 2008-04-07 2016-02-09 Valinge Innovation Ab Wood fibre based panels with a thin surface layer
US9296191B2 (en) 2010-04-13 2016-03-29 Valinge Innovation Ab Powder overlay
US9410319B2 (en) 2010-01-15 2016-08-09 Valinge Innovation Ab Heat and pressure generated design
US9556622B2 (en) 2007-11-19 2017-01-31 Valinge Innovation Ab Fibre based panels with a wear resistance surface
US9630404B2 (en) 2013-01-11 2017-04-25 Ceraloc Innovation Ab Dry ink for digital printing
US10016988B2 (en) 2012-07-26 2018-07-10 Ceraloc Innovation Ab Digital binder printing
US10017950B2 (en) 2011-08-26 2018-07-10 Ceraloc Innovation Ab Panel coating
US10035358B2 (en) 2012-07-17 2018-07-31 Ceraloc Innovation Ab Panels with digital embossed in register surface
US10041212B2 (en) 2013-02-04 2018-08-07 Ceraloc Innovation Ab Digital overlay
US10100535B2 (en) 2014-01-10 2018-10-16 Valinge Innovation Ab Wood fibre based panel with a surface layer
US10286633B2 (en) 2014-05-12 2019-05-14 Valinge Innovation Ab Method of producing a veneered element and such a veneered element
US10315219B2 (en) 2010-05-31 2019-06-11 Valinge Innovation Ab Method of manufacturing a panel
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US9174423B2 (en) 2015-11-03
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CA2713123C (en) 2013-02-19
UA98688C2 (ru) 2012-06-11
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