WO2009080336A3 - Autothermes verfahren zur kontinuierlichen vergasung von kohlenstoffreichen substanzen - Google Patents

Autothermes verfahren zur kontinuierlichen vergasung von kohlenstoffreichen substanzen Download PDF

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Publication number
WO2009080336A3
WO2009080336A3 PCT/EP2008/010999 EP2008010999W WO2009080336A3 WO 2009080336 A3 WO2009080336 A3 WO 2009080336A3 EP 2008010999 W EP2008010999 W EP 2008010999W WO 2009080336 A3 WO2009080336 A3 WO 2009080336A3
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WIPO (PCT)
Prior art keywords
carbon
processing chamber
rich
substances
vertical processing
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PCT/EP2008/010999
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English (en)
French (fr)
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WO2009080336A2 (de
Inventor
Roland Möller
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Ecoloop Gmbh
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Publication date
Priority to EP08864268A priority Critical patent/EP2231828A2/de
Priority to BRPI0821292-9A priority patent/BRPI0821292A2/pt
Priority to AU2008340602A priority patent/AU2008340602B2/en
Priority to KR1020107015842A priority patent/KR101304154B1/ko
Priority to CA2710168A priority patent/CA2710168C/en
Priority to JP2010538491A priority patent/JP2011506711A/ja
Priority to CN200880121676.9A priority patent/CN101903501B/zh
Priority to US12/809,350 priority patent/US8632614B2/en
Application filed by Ecoloop Gmbh filed Critical Ecoloop Gmbh
Priority to UAA201008501A priority patent/UA97305C2/uk
Priority to RU2010129542/05A priority patent/RU2471856C2/ru
Publication of WO2009080336A2 publication Critical patent/WO2009080336A2/de
Publication of WO2009080336A3 publication Critical patent/WO2009080336A3/de
Priority to ZA2010/03910A priority patent/ZA201003910B/en
Priority to HK11102528.4A priority patent/HK1148550A1/xx

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/22—Arrangements or dispositions of valves or flues
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/15—Details of feeding means
    • C10J2200/152—Nozzles or lances for introducing gas, liquids or suspensions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C10J2300/1675—Integration of gasification processes with another plant or parts within the plant with the production of electricity making use of a steam turbine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1687—Integration of gasification processes with another plant or parts within the plant with steam generation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1693—Integration of gasification processes with another plant or parts within the plant with storage facilities for intermediate, feed and/or product
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1838—Autothermal gasification by injection of oxygen or steam
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Die Erfindung befasst sich mit einem autothermen Verfahren zur kontinuierlichen Vergasung von kohlenstof freichen Substanzen (14) in einem vertikalen Prozessraum (100) mit einer Kalzinierzone (C) und einer Oxidationszone (D), in welcher die kalzinierten kohlenstoffreichen Substanzen mit sauerstoffhaltigem Gas oxidieren, wobei die gasförmigen Reaktionsprodukte an der Oberseite (G) des vertikalen Prozessraumes (100) abgezogen werden. Der vertikale Prozessraum wird in der Form eines Vertikalschachtofens (100) ausgebildet, der von einem im Kreislauf geführten Schüttgut (13), das selbst nicht oxidiert wird, kontinuierlich von oben nach unten durchströmt wird, wobei die kohlenstoffreichen Substanzen (14) dem Schüttgut (13) vor dem Eintritt (3) in den Ofen beigegeben werden und das sauerstoffhaltige Gas in und/oder unterhalb der Oxidationszone (D) eingeleitet wird, wodurch der aufsteigende Gasstrom gefördert wird. Durch Einleitung wenigstens eines Teils des sauerstoffhaltigen Gases am unteren Ende (4) des Vertikalschachtofens (100) wird eine Nachkühlzone (F) ausgebildet, in welcher das Schüttgut auf unter 100°C abgekühlt wird.
PCT/EP2008/010999 2007-12-20 2008-12-22 Autothermes verfahren zur kontinuierlichen vergasung von kohlenstoffreichen substanzen WO2009080336A2 (de)

Priority Applications (12)

Application Number Priority Date Filing Date Title
CN200880121676.9A CN101903501B (zh) 2007-12-20 2008-12-22 高碳物质连续气化的自热方法
AU2008340602A AU2008340602B2 (en) 2007-12-20 2008-12-22 Autothermic method for the continuous gasification of substances rich in carbon
KR1020107015842A KR101304154B1 (ko) 2007-12-20 2008-12-22 탄소가 풍부한 물질의 연속 가스화를 위한 자열 방법
CA2710168A CA2710168C (en) 2007-12-20 2008-12-22 Autothermal method for the continuous gasification of carbon-rich substances
JP2010538491A JP2011506711A (ja) 2007-12-20 2008-12-22 炭素豊富物質を連続的にガス化する自熱法
EP08864268A EP2231828A2 (de) 2007-12-20 2008-12-22 Autothermes verfahren zur kontinuierlichen vergasung von kohlenstoffreichen substanzen
US12/809,350 US8632614B2 (en) 2007-12-20 2008-12-22 Autothermal method for the continuous gasification of carbon-rich substances
BRPI0821292-9A BRPI0821292A2 (pt) 2007-12-20 2008-12-22 Método autotérmico para a gaseificação contínua de substâncias ricas em carbono
UAA201008501A UA97305C2 (uk) 2007-12-20 2008-12-22 Автотермічний спосіб безперервної газифікації субстанцій з високим вмістом вуглецю
RU2010129542/05A RU2471856C2 (ru) 2007-12-20 2008-12-22 Автотермический способ непрерывной газификации субстанций с высоким содержанием углерода
ZA2010/03910A ZA201003910B (en) 2007-12-20 2010-06-01 Autothermic method for the continuous gasification of substances rich in carbon
HK11102528.4A HK1148550A1 (en) 2007-12-20 2011-03-14 Autothermic method for the continuous gasification of substances rich in carbon

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007062414A DE102007062414B4 (de) 2007-12-20 2007-12-20 Autothermes Verfahren zur kontinuierlichen Vergasung von kohlenstoffreichen Substanzen
DE102007062414.1 2007-12-20

Publications (2)

Publication Number Publication Date
WO2009080336A2 WO2009080336A2 (de) 2009-07-02
WO2009080336A3 true WO2009080336A3 (de) 2010-02-18

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ID=40688366

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/010999 WO2009080336A2 (de) 2007-12-20 2008-12-22 Autothermes verfahren zur kontinuierlichen vergasung von kohlenstoffreichen substanzen

Country Status (14)

Country Link
US (1) US8632614B2 (de)
EP (1) EP2231828A2 (de)
JP (1) JP2011506711A (de)
KR (1) KR101304154B1 (de)
CN (1) CN101903501B (de)
AU (1) AU2008340602B2 (de)
BR (1) BRPI0821292A2 (de)
CA (1) CA2710168C (de)
DE (1) DE102007062414B4 (de)
HK (1) HK1148550A1 (de)
RU (1) RU2471856C2 (de)
UA (1) UA97305C2 (de)
WO (1) WO2009080336A2 (de)
ZA (1) ZA201003910B (de)

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CN105112103B (zh) * 2015-08-18 2017-06-16 王晓峰 基于真空热分解的小粒径褐煤气化装置及其气化方法
EP3305876B1 (de) 2016-10-07 2019-06-05 Meva Energy AB Verbessertes vergasungssystem und verfahren
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CN108865277A (zh) * 2018-07-03 2018-11-23 余军 一种生物质垃圾气化炉
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BRPI0821292A2 (pt) 2015-06-16
US8632614B2 (en) 2014-01-21
US20110005136A1 (en) 2011-01-13
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RU2471856C2 (ru) 2013-01-10
UA97305C2 (uk) 2012-01-25
DE102007062414B4 (de) 2009-12-24
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DE102007062414A1 (de) 2009-07-02

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