WO2009079905A8 - 一种选择性加氢催化剂及其制备方法 - Google Patents

一种选择性加氢催化剂及其制备方法 Download PDF

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Publication number
WO2009079905A8
WO2009079905A8 PCT/CN2008/001780 CN2008001780W WO2009079905A8 WO 2009079905 A8 WO2009079905 A8 WO 2009079905A8 CN 2008001780 W CN2008001780 W CN 2008001780W WO 2009079905 A8 WO2009079905 A8 WO 2009079905A8
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Prior art keywords
catalyst
selective hydrogenation
carrier
hydrogenation
θform
Prior art date
Application number
PCT/CN2008/001780
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English (en)
French (fr)
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WO2009079905A1 (en
Inventor
梁顺琴
孙利民
吕龙刚
钱颖
郑云弟
吴杰
王廷海
李晓艳
Original Assignee
中国石油天然气股份有限公司
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Application filed by 中国石油天然气股份有限公司 filed Critical 中国石油天然气股份有限公司
Priority to EP08863972.9A priority Critical patent/EP2233208B1/en
Priority to US12/747,865 priority patent/US8211823B2/en
Priority to JP2010537232A priority patent/JP5298135B2/ja
Priority to KR1020107014866A priority patent/KR101521673B1/ko
Publication of WO2009079905A1 publication Critical patent/WO2009079905A1/zh
Publication of WO2009079905A8 publication Critical patent/WO2009079905A8/zh

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/10—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
PCT/CN2008/001780 2007-12-13 2008-10-22 A selective hydrogenation catalyst and the preparation thereof WO2009079905A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP08863972.9A EP2233208B1 (en) 2007-12-13 2008-10-22 A selective hydrogenation catalyst and the preparation thereof
US12/747,865 US8211823B2 (en) 2007-12-13 2008-10-22 Selective hydrogenation catalyst and the preparation thereof
JP2010537232A JP5298135B2 (ja) 2007-12-13 2008-10-22 選択的水素化触媒及びその製造
KR1020107014866A KR101521673B1 (ko) 2007-12-13 2008-10-22 선택적 수소화 촉매 및 그 제조 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200710179443.1 2007-12-13
CN200710179443.1A CN101433841B (zh) 2007-12-13 2007-12-13 一种选择性加氢催化剂及其制备方法

Publications (2)

Publication Number Publication Date
WO2009079905A1 WO2009079905A1 (en) 2009-07-02
WO2009079905A8 true WO2009079905A8 (zh) 2010-07-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2008/001780 WO2009079905A1 (en) 2007-12-13 2008-10-22 A selective hydrogenation catalyst and the preparation thereof

Country Status (7)

Country Link
US (1) US8211823B2 (zh)
EP (1) EP2233208B1 (zh)
JP (1) JP5298135B2 (zh)
KR (1) KR101521673B1 (zh)
CN (1) CN101433841B (zh)
MY (1) MY148501A (zh)
WO (1) WO2009079905A1 (zh)

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CN101423775B (zh) 2007-11-01 2010-05-12 中国石油天然气股份有限公司 一种选择性镍系加氢催化剂及其制备方法
CN103111314B (zh) * 2011-11-17 2015-05-13 中国科学院宁波材料技术与工程研究所 油脂连续化完全加氢制备硬脂酸甘油酯的催化剂及其制备方法
CN104703693B (zh) * 2012-10-11 2017-07-04 帝斯曼知识产权资产管理有限公司 特定类异戊二烯的逐步氢化
CN103706356A (zh) * 2014-01-10 2014-04-09 中国天辰工程有限公司 一种蛋壳型蒽醌加氢固定床催化剂的制备方法
CN103769094B (zh) * 2014-01-20 2015-09-23 中国科学院宁波材料技术与工程研究所 一种用于选择性加氢反应的蛋壳型催化剂、制备方法及应用
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CN107189811B (zh) * 2017-06-02 2019-01-25 钦州学院 一种全馏分裂解汽油一段选择性加氢方法
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CN107159279B (zh) * 2017-06-02 2019-05-17 钦州学院 一种裂解汽油一段选择性加氢催化剂及其制备方法
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CN107185567B (zh) * 2017-06-02 2019-05-17 钦州学院 一种镍系选择性加氢催化剂及其制备方法
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CN108043431B (zh) * 2017-12-15 2020-04-03 厦门大学 一种碳碳双键的选择性加氢用催化剂及其制备方法和应用
CN111229216B (zh) * 2018-11-29 2022-08-05 万华化学集团股份有限公司 一种蛋壳型银催化剂及其制备方法和应用
CN111375451B (zh) * 2018-12-29 2022-12-13 中国石油化工股份有限公司 氧化铝载体和碳二碳三馏分选择加氢催化剂
CN109939678A (zh) * 2019-02-14 2019-06-28 北京氦舶科技有限责任公司 一种单原子钯催化剂及其制备方法和应用
CZ201992A3 (cs) * 2019-02-18 2020-03-04 Unipetrol výzkumně vzdělávací centrum, a.s. Zařízení pro přerušení procesu broušení při výpadku elektrického proudu
JP7450346B2 (ja) * 2019-06-20 2024-03-15 株式会社キャタラー メタン浄化用触媒材料
KR102220225B1 (ko) * 2019-06-21 2021-02-24 희성촉매 주식회사 과산화수소 합성 및 재생 촉매 및 이의 제조방법
CN112547069B (zh) * 2019-09-10 2023-05-30 中国石油化工股份有限公司 镍铜催化剂及其制备方法以及制备甲基异丁基醇的方法
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CN114471619B (zh) * 2020-10-26 2023-09-01 中国石油化工股份有限公司 一种重整生成油加氢脱烯烃催化剂及其制备方法
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CN101433841A (zh) 2009-05-20
MY148501A (en) 2013-04-30
EP2233208A1 (en) 2010-09-29
KR20100100942A (ko) 2010-09-15
US20100331175A1 (en) 2010-12-30
US8211823B2 (en) 2012-07-03
JP2011506068A (ja) 2011-03-03
KR101521673B1 (ko) 2015-05-19
CN101433841B (zh) 2010-04-14
WO2009079905A1 (en) 2009-07-02
EP2233208A4 (en) 2013-01-09

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