WO2009066588A1 - 塗料用水性樹脂組成物および水性塗料 - Google Patents

塗料用水性樹脂組成物および水性塗料 Download PDF

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Publication number
WO2009066588A1
WO2009066588A1 PCT/JP2008/070500 JP2008070500W WO2009066588A1 WO 2009066588 A1 WO2009066588 A1 WO 2009066588A1 JP 2008070500 W JP2008070500 W JP 2008070500W WO 2009066588 A1 WO2009066588 A1 WO 2009066588A1
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Prior art keywords
aqueous
coating
reaction product
resin composition
produced
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PCT/JP2008/070500
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English (en)
French (fr)
Inventor
Shinichirou Tanimoto
Yuji Fujii
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Arakawa Chemical Industries, Ltd.
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Priority to JP2009542524A priority Critical patent/JPWO2009066588A1/ja
Priority to EP08851291.8A priority patent/EP2213708B1/en
Publication of WO2009066588A1 publication Critical patent/WO2009066588A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C08F283/105—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule on to unsaturated polymers containing more than one epoxy radical per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/064—Polymers containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
    • C08F290/14—Polymers provided for in subclass C08G
    • C08F290/144—Polymers containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D155/00—Coating compositions based on homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C09D123/00 - C09D153/00
    • C09D155/005—Homopolymers or copolymers obtained by polymerisation of macromolecular compounds terminated by a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10—Epoxy resins modified by unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Abstract

　本発明の塗料用水性樹脂組成物は、芳香族系エポキシ樹脂（１ａ－１）を含有するエポキシ樹脂（１ａ）およびアミン類（１ｂ）を少なくとも反応させてなる変性エポキシ樹脂（１）中で、カルボキシル基含有ビニル単量体（２ａ）を含有するビニル単量体成分（２）を重合して得られる反応生成物（３）を塩基性化合物により中和して水中に分散ないしは溶解させてなる、前記反応生成物（３）の水性物（Ａ）と、アクリル系樹脂エマルジョン（Ｂ）とを、使用重量比（（Ａ）／（Ｂ））５０～９５／５～５０重量部（固形物換算）の範囲で含有する。本発明の塗料用水性樹脂組成物は、耐水白化が生じにくく、かつ耐食性の低下がない水性塗料を提供することができる。
PCT/JP2008/070500 2007-11-19 2008-11-11 塗料用水性樹脂組成物および水性塗料 WO2009066588A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2009542524A JPWO2009066588A1 (ja) 2007-11-19 2008-11-11 塗料用水性樹脂組成物および水性塗料
EP08851291.8A EP2213708B1 (en) 2007-11-19 2008-11-11 Aqueous resin composition for coating, and aqueous coating

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-298955 2007-11-19
JP2007298955 2007-11-19

Publications (1)

Publication Number Publication Date
WO2009066588A1 true WO2009066588A1 (ja) 2009-05-28

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ID=40667413

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Country Link
EP (1) EP2213708B1 (ja)
JP (1) JPWO2009066588A1 (ja)
KR (1) KR20100083775A (ja)
TW (1) TWI429719B (ja)
WO (1) WO2009066588A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011089092A (ja) * 2009-10-26 2011-05-06 Toagosei Co Ltd 厚塗り用塗料組成物
CN104212215A (zh) * 2014-09-19 2014-12-17 江苏海晟涂料有限公司 一种长效防腐涂料及其制备方法
US20160289462A1 (en) * 2013-09-26 2016-10-06 Agency For Science, Technology And Research Polymers for Making Superhydrophobic Surfaces
CN108623758A (zh) * 2018-05-19 2018-10-09 华伦纳路新材料有限公司 一种水性氨基烤漆用环氧改性丙烯酸树脂及其制备方法
CN109971270A (zh) * 2017-12-28 2019-07-05 佛山市因诺维生物科技有限公司 一种陶瓷防腐涂料
JP2019137862A (ja) * 2018-02-13 2019-08-22 荒川化学工業株式会社 ビニル変性エポキシ樹脂組成物、水性被覆剤
JP7188634B1 (ja) * 2022-09-01 2022-12-13 荒川化学工業株式会社 変性エポキシ樹脂組成物、水性被覆剤

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITVA20070085A1 (it) * 2007-11-21 2009-05-22 Lamberti Spa Inibitori di rigonfiamento di argille
JP5622280B2 (ja) * 2011-04-21 2014-11-12 関西ペイント株式会社 水性塗料組成物及び塗装物品
CN106675234B (zh) * 2016-12-30 2018-01-26 广州铁路（集团）公司 一种沿海铁路房屋建筑钢结构用水性长效防腐涂料
CN107674146B (zh) * 2017-11-13 2020-12-11 中国海洋石油集团有限公司 高固含低voc水性聚丙烯酸酯树脂及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59135260A (ja) * 1982-12-30 1984-08-03 モ−ビル　オイル　コ−ポレ−ション 水性塗料組成物とその製造方法
JPH06329974A (ja) * 1993-05-20 1994-11-29 Kansai Paint Co Ltd 水性塗料組成物
JPH0790219A (ja) * 1993-09-24 1995-04-04 Japan Synthetic Rubber Co Ltd 水性塗料
JP2002146164A (ja) * 2000-08-30 2002-05-22 Dainippon Ink & Chem Inc 水性樹脂組成物及び該組成物の硬化塗膜を有する塗装金属材料
JP2003026739A (ja) 2001-07-12 2003-01-29 Arakawa Chem Ind Co Ltd ビニル変性エポキシ樹脂水性物、その製造方法および水性被覆剤
JP2005120340A (ja) 2003-09-25 2005-05-12 Arakawa Chem Ind Co Ltd ビニル変性エポキシ樹脂水性物、その製造方法および水性被覆剤
JP2005187679A (ja) * 2003-12-26 2005-07-14 Toyo Ink Mfg Co Ltd 水性塗料組成物及び被塗物

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5073315B2 (ja) * 2006-03-24 2012-11-14 関西ペイント株式会社 缶用塗料組成物

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59135260A (ja) * 1982-12-30 1984-08-03 モ−ビル　オイル　コ−ポレ−ション 水性塗料組成物とその製造方法
JPH06329974A (ja) * 1993-05-20 1994-11-29 Kansai Paint Co Ltd 水性塗料組成物
JPH0790219A (ja) * 1993-09-24 1995-04-04 Japan Synthetic Rubber Co Ltd 水性塗料
JP2002146164A (ja) * 2000-08-30 2002-05-22 Dainippon Ink & Chem Inc 水性樹脂組成物及び該組成物の硬化塗膜を有する塗装金属材料
JP2003026739A (ja) 2001-07-12 2003-01-29 Arakawa Chem Ind Co Ltd ビニル変性エポキシ樹脂水性物、その製造方法および水性被覆剤
JP2005120340A (ja) 2003-09-25 2005-05-12 Arakawa Chem Ind Co Ltd ビニル変性エポキシ樹脂水性物、その製造方法および水性被覆剤
JP2005187679A (ja) * 2003-12-26 2005-07-14 Toyo Ink Mfg Co Ltd 水性塗料組成物及び被塗物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2213708A4 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011089092A (ja) * 2009-10-26 2011-05-06 Toagosei Co Ltd 厚塗り用塗料組成物
US20160289462A1 (en) * 2013-09-26 2016-10-06 Agency For Science, Technology And Research Polymers for Making Superhydrophobic Surfaces
CN104212215A (zh) * 2014-09-19 2014-12-17 江苏海晟涂料有限公司 一种长效防腐涂料及其制备方法
CN109971270A (zh) * 2017-12-28 2019-07-05 佛山市因诺维生物科技有限公司 一种陶瓷防腐涂料
JP2019137862A (ja) * 2018-02-13 2019-08-22 荒川化学工業株式会社 ビニル変性エポキシ樹脂組成物、水性被覆剤
CN110156936A (zh) * 2018-02-13 2019-08-23 荒川化学工业株式会社 乙烯基改性环氧树脂组合物、水性包覆剂
JP7081522B2 (ja) 2018-02-13 2022-06-07 荒川化学工業株式会社 ビニル変性エポキシ樹脂組成物、水性被覆剤
CN110156936B (zh) * 2018-02-13 2023-04-07 荒川化学工业株式会社 乙烯基改性环氧树脂组合物、水性包覆剂
CN108623758A (zh) * 2018-05-19 2018-10-09 华伦纳路新材料有限公司 一种水性氨基烤漆用环氧改性丙烯酸树脂及其制备方法
JP7188634B1 (ja) * 2022-09-01 2022-12-13 荒川化学工業株式会社 変性エポキシ樹脂組成物、水性被覆剤

Also Published As

Publication number Publication date
EP2213708A1 (en) 2010-08-04
EP2213708B1 (en) 2014-07-16
KR20100083775A (ko) 2010-07-22
TWI429719B (zh) 2014-03-11
TW200940665A (en) 2009-10-01
JPWO2009066588A1 (ja) 2011-04-07
EP2213708A4 (en) 2011-03-02

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