WO2009006324A1 - Primaires multifonctionnels - Google Patents
Primaires multifonctionnels Download PDFInfo
- Publication number
- WO2009006324A1 WO2009006324A1 PCT/US2008/068626 US2008068626W WO2009006324A1 WO 2009006324 A1 WO2009006324 A1 WO 2009006324A1 US 2008068626 W US2008068626 W US 2008068626W WO 2009006324 A1 WO2009006324 A1 WO 2009006324A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- formulation
- primer
- multifunctional
- binder
- silicate
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/483—Polyacrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
- C04B41/63—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/70—Coating or impregnation for obtaining at least two superposed coatings having different compositions
- C04B41/71—Coating or impregnation for obtaining at least two superposed coatings having different compositions at least one coating being an organic material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/02—Polysilicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00491—Primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
Definitions
- This invention relates generally to a multifunctional primer for composite building materials, such as fiber cement building materials.
- it relates to an improved primer that functions as both a sealer and a primer.
- Production of a composite building materials often requires that the surface of the material be modified (e.g., smoother, rougher, textured).
- the surface of the material may be reduced in size by cutting (e.g., by saw or water jet), sanding, punching, shearing.
- Such modifications may not only change the appearance of the surface, they may also leave the surface burnished and/or with particulates and dust.
- coating materials e.g., sealer, primer, paint, stain. This is particularly true for cementitious materials, such as fiber cement. Dusty, burnished and/or smooth fiber cement surfaces are especially problematic and adhesion of a coating to such surfaces is difficult to achieve.
- the surface characteristics are often so different after such modifications that there is no adhesion of a first coating material to the building material (e.g., sealer to substrate) and/or no adhesion between a second coating and the first coating (e.g., topcoat to sealer or topcoat to primer).
- a first coating material e.g., sealer to substrate
- a second coating e.g., topcoat to sealer or topcoat to primer
- multifunctional primers for a composite building material such as a cementitious material, gypsum, or other inorganic composite materials, that overcome inadequacies described above.
- the multifunctional primer may be provided as a sealer and a primer and offers improved features for superior adhesion to composite building materials, such as saw cut or sanded surfaces.
- a multifunctional primer described herein includes a self-sealing primer.
- the binder included in the primer may be an acrylic silicate binder, an acrylic urethane binder, an acrylic siloxane binder or any combination thereof.
- the multifunctional primer formulation for a composite building material as described herein includes an emulsion with an acrylic silicate binder or an acrylic urethane binder or an acrylic siloxane binder that imparts a multifunctional action to the substrate and the topcoat applied thereafter.
- Such a formulation with an acrylic silicate binder may comprise a dispersant as a solution of a sodium salt of an acrylate copolymer, a surfactant as a nonionic surfactant, and/or a polysilicone defoamer.
- the acrylic is an acrylic latex.
- the acrylic- silicate binder ratio is typically between about 0.5 and about 1.5.
- the formulation further comprises a pigment, which may be in the form of titanium oxide or other suitable pigments. When the formulation comprises a filler, particles are typically less than 10 micron.
- the multifunctional action includes functioning as a primer and a sealer and the multifunctional action is maintained with addition of a topcoat.
- a formulation may comprise a dispersant as a solution of a sodium salt of an acrylate copolymer, a surfactant as a solution of alkylammonium salt of a polyfunctional polymer with anionic or non-ionic character and/or a non-silicon defoamer.
- the acrylic may be a hydroxyl-functional acrylic co-polymer.
- the formulation may further comprise a polyisocyanate cross-linker, a pigment such as titanium oxide, a filler with particles less than 1 micron, and/or a solvent of ethylene glycol monobutyl ether.
- the multifunctional action includes functioning as a primer and a sealer and the multifunctional action is maintained with addition of a topcoat.
- FlG. 1 illustrates wet adhesion as a function of pigment volume concentration in a multifunctional primer formulation described herein;
- FIG. 2 illustrates wet adhesion as a function of the weight ratio between silicate binder and acrylic binder in a multifunctional primer formulation described herein
- FIG 3 depicts a representative bar graph showing dry adhesion of a multifunctional primer formulation described herein when applied at varying thicknesses on sanded faces of a composite building material
- FIG 4 depicts a representative bar graph showing diy adhesion of a multifunctional primer formulation described herein when applied at varying thicknesses on saw cut edges of a composite building material
- FIG 5 depicts a representative bar graph showing wet adhesion of a multifunctional primer formulation described herein with a topcoat on sanded faces of a composite building material when the multifunctional primer is applied at different thicknesses
- FIG 6 depicts a representative bar graph showing wet adhesion of a multifunctional primer formulation described herein with a topcoat on sanded faces of a composite building material when the multifunctional primer is applied at different thicknesses
- primer formulations The primer has multifunctional capabilities and is self-sealing in which it acts as a sealer and a primer
- the term "sealer” is used herein in its general meaning of a substance (coating) applied to a substrate, typically as a basecoat for paints, stains, varnish, as examples
- the primer formulation is designed for use on building material substrates, preferably composite building materials, including fiber cement substrates having saw cut and sanded surfaces.
- Formulations for a multifunctional primer as described herein are identified in TABLE 1.
- a typical formulation includes at least one carrier, solvent, surfactant, dispersant, thickener, defoamer, pigment, filler, and resin binder.
- the resin binder is a silicate acrylic latex, silicate acrylic copolymer, silicate styrenated acrylic, urethane acrylic latex or any combination thereof.
- Multifunctional primer formulations may include a general range as presented in TABLE 1.
- the binder used typically with TABLE 1 includes an acrylic latex and silicate binder and/or an acrylic-urethane binder.
- the resin binder is silicate acrylic latex.
- the silicate binder may be sodium silicate and/or potassium silicate
- the surfactant is suitably a non-ionic surfactant, often, when desired octyl phenol ethoxylate.
- the dispersant typically acts as a stabilizer and includes a solution of a sodium salt of an acrylate copolymer.
- the thickener is typically a urethane-based rheology modifier.
- the filler is typically a fine calcium carbonate having particles less than 10 microns in size.
- the defoamer is typically an acetylenic-modif ⁇ ed polysiloxane-based defoamer or a parraffinic defoamer Often, when desired, both types of defoamers are provided to the formulation
- a pigments includes those typically used with primer formulations
- a suitable pigment is titanium dioxide
- the resin is an acryhc-urethane binder
- the surfactant is suitably a solution of an alkylammonium salt of a polyfunctional polymer with anionic/non-ionic character
- the dispersant typically acts as a stabilizer and includes a solution of a sodium salt of an acrylate copolymer
- the cross-lmker is typically a polyisocyanate cross-linker (with or without a blocker)
- the filler is typically talc having particles about 1 to 10 microns in size
- the defoamer is typically a non-silicone defoamer
- the solvent is generally ethylene glycol or ethylene glycol monobutyl ether
- a pigment is a typical pigment suitable for primer formulations, such as titanium dioxide in a quantity and, with the addition of other ingredients, help prevent undue settling [0022] Additional features of multifunctional primers described herein are shown m TABLE
- NVM solids content by mass
- NVV solids content by volume
- PVC pigment volume concentration
- CPVC critical pigment volume concentration
- An example of a formulation having an acrylic-silicate binder is provided in TABLE 3
- Resm binder A is in the form of, for example, an acrylic binder
- Resm binder B is in the form of, for example, a silicate binder
- Such a formulation as shown in TABLE 3 provides an NVM of less than 44%, an NVV of less than 27%, PVC of about 40% and CPVC of about 57%, when prepared as a formulation of about 10-11 lb/gal
- TABLE 4 An example of a foi ⁇ nulation having an acrylic-urethane binder is provided in TABLE 4. Such a formulation as shown in TABLE 4 provides an NVM of less than 60%, an NVV of less than 45%, PVC of about 30% and CPVC of about 52%, when prepared as a formulation of about 11-12 lb/gal.
- the formulation includes water as the carrier at about 50 lb/gal, a surfactant at about 1.0 lb/gal, a dispersant that is about 4.8 lb/gal, a solvent at 7.0 lb/gal, at least two titianium oxide pigments, one at about 30 lb/gal and the other at about 40 lb/gal, a filler at about 50 lb/gal, an acrylic binder that is at about 90 lb/gal and an isocyanate binder that is at about 75 lb/gal.
- An example of pigment volume concentration as a function of wet adhesion is depicted in FlG. 1.
- FIG. 1 wet adhesion was performed on outer saw cut edges of composite building material samples surfaced with a coating of a multifunctional primer formulation described herein and a topcoat, which was a water-based acrylic topcoat.
- the multifunctional primer included an acrylic-silicate binder, which was applied at a thickness of about 0.9 mil; the topcoat was applied at a thickness of about 1.6 mils.
- FIG. 1 illustrates that for such a formulation having a pigment volume concentration of between about 30% and 44% very good wet adhesion was achieved when applied to the composite building material which included a water-based acrylic topcoat.
- samples included cementitious composite building specimens provided as sanded and sawcut boards having the following approximate dimensions: 3.5 inch x 12 inch x 1 inch. Applied to edges of each specimen (that has been sanded and sawcut), at room temperature and under initial moisture conditions of 0%-50%, was about 0.9 mil DFT of a multifunctional primer described herein in the absence of a sealer. The multifunctional primer was cured at an elevated temperature (e.g., by baking to reach a surface temperature of about 140 to 190 degrees Fahrenheit) and allowed to cool. This was followed by application of a about 1.5 mil DFT of an acylic latex topcoat that was cured at a similar elevated temperature and allowed to cool.
- an elevated temperature e.g., by baking to reach a surface temperature of about 140 to 190 degrees Fahrenheit
- the silicate binder-to-acrylic binder ratio was about 1 : 1 (lb/lb).
- FIG. 2 An illustration of the silicate binder-to-acylic binder mass ratio is depicted in FIG. 2, in which specimens were prepared as described previously.
- wet adhesion was performed on saw cut edges of composite building material samples surfaced with a coating of a multifunctional primer formulation described herein and a topcoat of 100% acrylic latex.
- the multifunctional primer was applied at a thickness of about 0.9 mil and the topcoat was applied at a thickness of about 1.5 mils.
- FIG. 2 also shows that a suitable weight ratio is between about 0.75 and about 1.5 of a silicate binder to an acrylic binder.
- FIG. 3 illustrates the degree of dry adhesion, as a percentage of the multifunctional primer that is removed by the tape, after application of an acrylic-urethane multifunctional primer on sanded faces of cementitious building composite samples.
- the figure shows that regardless of thickness of the multifunctional primer applied to the sanded faces, the multifunctional primer showed very good dry adhesion with generally less than 6.5% of the multifunctional primer removed by the tape. Thickness did not substantially change the degree of adhesion.
- a thicker multifunctional primer may be used to reduce removal to less than 2.5%. Thickness of the primer described herein will also help manipulate the overall appearance of the primer on the coated article.
- FIG. 4 illustrates the degree of dry adhesion, as a percentage of the multifunctional primer that is removed by the tape, after application of an acrylic-urethane multifunctional primer to saw cut edges (sides) of cementitious building composite samples.
- the multifunctional primer showed very good dry adhesion with generally less than 7.5% of the multifunctional primer removed by the tape. The thickness did not substantially change the degree of adhesion.
- thickness of the multifunctional primer appears to effect degree of adhesion; a thicker multifunctional primer may be used to reduce removal of the primer from saw cut sides of a composite building material. Thickness of the primer described herein will also help manipulate the overall appearance on the coated article.
- FIG. 5 illustrates the degree of wet adhesion of an acrylic-urethane multifunctional primer, as a percentage of the coating that is removed by the tape, when measured for sanded faces of a cementitious building composite to which was applied a primer and an acrylic latex topcoat.
- FlG. 3 indicate that regardless of the thickness of the multifunctional primer applied, the coating adheres very well under wet conditions, with less than 8.0% removal by the tape. The thickness did not substantially change the degree of adhesion.
- a thicker multifunctional primer may be applied to reduce removal to less than 2.5%.
- FIG. 6 illustrates the degree of wet adhesion of an acrylic-urethane multifunctional primer, as a percentage of the coating that is removed by the tape, when measured for sawcut edges of a cementitious building composite to which a primer and an acrylic topcoat were applied thereon.
- the DFT of the multifunctional primer was found to positively affect adhesion when applied to the edges of a composite building material.
- a coating thickness of 0.75 mil or higher provided less than 11.3% removal of the coating (topcoat) under wet conditions.
- Specimens used herein were provided to represent a composite building material that is typically a porous material comprising one or more different materials, such as a gypsum composite, cement composite, geopolymer composite or other composites having an inorganic binder.
- the surface of the material may be sanded, saw-cut, punched, water jet cut, sheared, machined, polished, extruded, molded or otherwise formed into any desired size and shape by various processes known in the art.
- the composite building materials may be fully cured, partially cured or in the uncured "green" state.
- Composite building materials may further include gypsum board, fiber cement board, fiber cement board reinforced by a mesh or continuous fibers, gypsum board reinforced by short fibers, a mesh or continuous fibers, inorganic bonded wood and fiber composite materials, geopolymer bonded wood and fiber boards, concrete roofing tile material, and fiber-plastic composite material.
- Desireable fibers include various forms of cellulose fibers, such as treated or untreated, bleached or unbleached Kraft pulp. In addition, other forms of fibers may be used.
- Suitable examples are those from ceramic, glass, mineral wool, steel, and synthetic polymers (e.g., polyamides, polyester, polypropylene, polymethylpentene, polyacrylonitrile, polyacrylamide, viscose, nylon, PVC, PVA, rayon, glass ceramic, carbon, any mixtures thereof).
- synthetic polymers e.g., polyamides, polyester, polypropylene, polymethylpentene, polyacrylonitrile, polyacrylamide, viscose, nylon, PVC, PVA, rayon, glass ceramic, carbon, any mixtures thereof.
- Any additional additive may be optionally incorporated into a composite material including but not limited to density modifiers, dispersing agents, silica fume, geothermal silica, fire retardant, viscosity modifiers, thickeners, pigments, colorants, dispersants, foaming agents, flocculating agents, water- proofing agents, organic density modifiers, aluminum powder, kaolin, alumina trihydrate, mica, metakaolin, calcium carbonate, wollastonite, polymeric resin emulsions, hydrophobic agents, and mixtures thereof.
- density modifiers including but not limited to density modifiers, dispersing agents, silica fume, geothermal silica, fire retardant, viscosity modifiers, thickeners, pigments, colorants, dispersants, foaming agents, flocculating agents, water- proofing agents, organic density modifiers, aluminum powder, kaolin, alumina trihydrate, mica, metakaolin, calcium carbonate, wollastonite, polymeric resin emulsions, hydrophobic
- Embodiments of the multifunctional primer described herein provides improved physical and chemical properties to the building material substrate as compared with current primer formulations.
- the primer formulation described herein is multifunctional and may be applied as a sealer and primer in a single coating.
- a multifunctional primer formulation as described herein provides very good adhesion when applied to a composite building material.
- the pigment volume concentration for the formulation as well as a resin-to- binder ratio may be manipulated to provide even more of an improvement in properties when desired.
- a multifunctional primer as described herein is applied to a dusty or polished surface of a fiber cement substrate.
- the multifunctional primer improves adhesion between the substrate and the primer.
- the multifunctional primer also improves adhesion of a topcoat, such as paint, varnish, stain.
- a multifunctional primer formulation as described herein also provides a composite building material with improved adhesion to interior or exterior coatings. Importantly, the formulation as designed will offer superior durability and performance as compared with conventional products. By way of examples are those provided below, which are representative and non-limiting.
- Example 1 In a 1000 mL stainless steel container, 350 g distilled water, 1.6 g Triton ® X-100 surfactant (registered trademark of Rohm & Haas Company, Philadelphia, PA), 1.6 g BYK ® 155 dispersant (registered trademark of Byk-Cera, Germany), 1.6 g Acrysol TM RM-8W thickener (trademark of Rohm & Haas Company, Philadelphia, PA), and 0.5 g Surfynol DF66 defoamer registered (trademark of Air Products and Chemicals, Inc., Lehigh Valley, PA) were mixed at medium speed for 20 to 30 minutes until a homogeneous mixture was obtained.
- Triton ® X-100 surfactant registered trademark of Rohm & Haas Company, Philadelphia, PA
- BYK ® 155 dispersant registered trademark of Byk-Cera, Germany
- 1.6 g Acrysol TM RM-8W thickener trademark of Rohm & Haas
- a powder mixture containing 80 g TiO 2 , and 14O g calcium carbonate was added.
- the mixture was then grinded in a high speed disperser for 30 to 45 minutes until a Hegman fineness of 5-6 was achieved.
- the letdown procedure involved slowly adding 264 g UCAR TM 626 acrylic resin (trademark of Union Carbide Corporation, Houston, TX) while mixing a low speed for 10-15 minutes, followed by the addition of 264 g Kasil ® 1 potassium silicate resin (registered trademark of PQ Coiporation, Valley Forge, PA) and mixing at low speed for another 10-15 minutes.
- the multifunctional primer of Example 1 was applied, using a brush (e.g., foam brush; however, other methods of application known to one of ordinary skill may be used).
- a brush e.g., foam brush; however, other methods of application known to one of ordinary skill may be used.
- One or a number of surfaces may be coated with a multifunctional primer.
- a raw fiber cement substrate may have a top sanded face and four saw cut edges of raw. Some of all of the surfaces of the substrate may be coated.
- the amount of wet primer applied was controlled with an analytical balance to achieve the target dry film thicknesses on both face and edges.
- the typical size of fiber cement samples was 3.5 inch x 12 inch x 1 inch with the initial moisture content of 5 to 50% by weight and the initial board temperature of 50" to 180" F.
- the coated fiber cement samples (having wet primer on top face and edges) were then cured in a lab-size conveyor oven, with a temperature set point of 450" F and an adjustable belt speed, to achieve a board surface temperature of 160° to 190° F at the oven exit.
- topcoat When samples were further coated with a topcoat, primed boards, once exiting the oven, were allowed to cool down to about 90° to 140° F before application of the topcoat.
- the topcoat was a water-based, exterior grade, 100% acrylic latex.
- the amount of topcoat (applied by brush) was controlled with an analytical balance to achieve 1.5-2.5 mils DFT on its face and edges.
- the topcoated samples were cured in the conveyor oven to achieve a board surface temperature of 160° to 190° F at the oven exit. All coated samples were allowed to further cure at room conditions for at least 24 hours before additional analysis were performed.
- Example 2 In a 500 ml stainless steel container, 50 g distilled water, 7 g ethylene glycol monobutyl ether solvent, 1.0 g BYK ® 181 surfactant (registered trademark of Byk- Cera, Germany), 4.8 g BYK ® 155 dispersant (registered trademark of Byk-Cera, Germany), and 1.0 g Surfynol TM DF75 defoamer (trademark of Air Products and Chemicals, Inc., Lehigh Valley, PA) were mixed at medium speed for 20 to 30 minutes until a homogeneous mixture was obtained.
- BYK ® 181 surfactant registered trademark of Byk- Cera, Germany
- BYK ® 155 dispersant registered trademark of Byk-Cera, Germany
- Surfynol TM DF75 defoamer trademark of Air Products and Chemicals, Inc., Lehigh Valley, PA
- the letdown procedure involved slowly adding 90 g Carboset ® CR717 acrylic resin (registered trademark of The Lubrizol Corporation, Wickliffe, OH) while mixing at low speed for 10 to 15 minutes, followed by the addition of 75 g RhodocoatTM WT (trademark of Rhodia Inc., Cranbury, NJ) 1000 and mixing at low speed for another 10 to 15 minutes.
- pH of the primer mixture was measured and adjusted to 8 to 9, and the primer was finally filtered through a 200-micron filter paper.
- the multifunctional primer of Example 2 was applied, using one-inch foam brushes.
- the primer was applied to the top sanded face and four saw cut edges of raw, uncoated fiber cement samples.
- the amount of wet primer applied was controlled with an analytical balance to achieve a target dry film thickness on the face and edges.
- the typical size of a fiber cement samples was 3.5 inch x 12 inch x 1 inch with the initial moisture content of 5 to 50% by weight and the initial board temperature of 50 to 180 0 F.
- the fiber cement samples with wet primer on top face and edges were then cured in a lab-size conveyor oven, with a temperature set point of 450° F and an adjustable belt speed, to achieve a board surface temperature of 160 to 190" F at the oven exit.
- topcoat Some samples were further coated with a topcoat.
- primed boards once exiting the oven, were allowed to cool down to 90° to 140° F before application of the topcoat.
- the topcoat was a water-based, exterior grade, 100% acrylic latex.
- the amount of topcoat brushed on was controlled with the analytical balance to achieve 1.5 to 2.5 mils DFT on face and edges.
- the topcoated samples were cured in the conveyor oven to achieve a board surface temperature of 160° to 190° F at the oven exit. All coated samples were further cured at room conditions for at least 24 hours before any further analysis was performed.
- the examples and descriptions herein show multifunctional primer formulations described herein have improved adhesion to composite building materials.
- the multifunctional primer acts as a primer and sealer, in part from the binder provided in the formulation, which may comprise an acrylic latex and silicate binder, an acrylic siloxane binder, an acrylic-urethane binder or combinations thereof.
- Such formulations may be applied to a suitable composite substrate surface, even one that includes particulates or are dusty or polished.
- the multifunctional primer formulation when provided offers improved adhesion of a topcoat applied to the multifunctional primer.
- formulations disclosed herein when applied to a suitable substrate which is a generally porous composite material, provide excellent adhesion of a further coating, such as an interior or exterior paint, stain, and varnish, to the substrate, including those having manipulated, engineered, dusty and/or burnished surfaces.
- the multifunctional primer described herein improves the service life of a paint and/or topcoat when applied to the multifunctional primer and is capable of maintaining durable contact between the composite substrate and any exterior coating (e.g., stain or paint) applied thereon.
- An improved multifunctional primer formulation as described herein effectively blocks moisture from penetrating the composite building material.
- the multifunctional primer formulation when prepared and applied to a composite building material provides good wet and dry adhesion to the composite building material. Adhesion may be manipulated by varying the thickness of the applied multifunctional primer formulation.
- the multifunctional primer formulation when applied to a composite building material provides good wet and dry adhesion of a topcoat (e.g., stain or paint) when further applied to the composite building material.
- a topcoat e.g., stain or paint
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
- Sealing Material Composition (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2008269996A AU2008269996B2 (en) | 2007-06-29 | 2008-06-27 | Multifunctional primers |
EP08781114.7A EP2162473B2 (fr) | 2007-06-29 | 2008-06-27 | Primaires multifonctionnels |
CA2697184A CA2697184C (fr) | 2007-06-29 | 2008-06-27 | Primaires multifonctionnels |
NZ582054A NZ582054A (en) | 2007-06-29 | 2008-06-27 | Multifunctional primers for composite building materials |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US94725207P | 2007-06-29 | 2007-06-29 | |
US60/947,252 | 2007-06-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009006324A1 true WO2009006324A1 (fr) | 2009-01-08 |
WO2009006324A8 WO2009006324A8 (fr) | 2010-01-28 |
Family
ID=40161370
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2008/068626 WO2009006324A1 (fr) | 2007-06-29 | 2008-06-27 | Primaires multifonctionnels |
Country Status (6)
Country | Link |
---|---|
US (1) | US9051488B2 (fr) |
EP (1) | EP2162473B2 (fr) |
AU (1) | AU2008269996B2 (fr) |
CA (1) | CA2697184C (fr) |
NZ (1) | NZ582054A (fr) |
WO (1) | WO2009006324A1 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7758954B2 (en) | 2005-08-18 | 2010-07-20 | James Hardie Technology Limited | Coated substrate having one or more cross-linked interfacial zones |
US8501863B2 (en) | 2007-06-28 | 2013-08-06 | James Hardie Technology Limited | Paint |
WO2014149916A1 (fr) * | 2013-03-15 | 2014-09-25 | Behr Process Corporation | Composition de revêtement superhydrophile |
US9051488B2 (en) * | 2007-06-29 | 2015-06-09 | James Hardie Technology Limited | Multifunctional primers |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2160442A4 (fr) * | 2007-06-28 | 2013-05-29 | Hardie James Technology Ltd | Primaire pour des matériaux de construction composites |
KR100858995B1 (ko) * | 2007-11-23 | 2008-09-18 | 씨캠 주식회사 | 송전시설의 부식방지 및 전력손실을 방지하는 기능을 보유한 기능성도료 조성물 |
KR20140118879A (ko) * | 2013-03-28 | 2014-10-08 | 주식회사 엘지화학 | 양면형 편광판의 제조방법 및 이로부터 제조된 양면형 편광판 |
US10364196B2 (en) * | 2013-05-21 | 2019-07-30 | James Hardie Technology Limited | Multi-functional coating system for cementitious composite materials |
DE102014116614B4 (de) * | 2014-11-13 | 2018-06-21 | Köster Bauchemie AG | Zusammensetzung zur Hydrophobierung eines Substrats und deren Verwendung |
EP3067218A1 (fr) * | 2015-03-13 | 2016-09-14 | Eternit AG | Impression à jet d'encre sur des produits en fibrociment |
US10934449B2 (en) | 2016-07-29 | 2021-03-02 | Behr Process Corporation | Water based sealer with superior durability |
CN109996849A (zh) * | 2016-09-26 | 2019-07-09 | 图像电子公司 | 建筑材料的喷墨装饰 |
CN106634356B (zh) * | 2017-01-03 | 2018-12-18 | 阮潇禾 | 一种低收缩防污瓷砖美缝剂 |
WO2018164941A1 (fr) * | 2017-03-07 | 2018-09-13 | Armstrong World Industries, Inc. | Peinture de carrelage multifonctionnelle à base d'eau, à haute teneur en solides |
IT201800005605A1 (it) * | 2018-05-22 | 2019-11-22 | Corrado Izzo | Metodo per il rivestimento di una superficie |
CN108516772B (zh) * | 2018-06-25 | 2020-10-30 | 深圳市振惠建混凝土有限公司 | 一种透水混凝土及其制备方法 |
US11680170B2 (en) | 2020-01-29 | 2023-06-20 | Behr Process Corporation | Silicate-emulsion primer and paint |
CN113831769B (zh) * | 2021-09-29 | 2022-05-24 | 国网甘肃省电力公司 | 常温固化无机高分子钢筋防腐涂料及其制备方法和应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4226277A (en) * | 1978-06-29 | 1980-10-07 | Ralph Matalon | Novel method of making foundry molds and adhesively bonded composites |
US5059264A (en) * | 1989-12-26 | 1991-10-22 | The Glidden Company | Aqueous inpress primer sealer for hardboard manufacturing |
US20020171170A1 (en) * | 2001-03-19 | 2002-11-21 | Demasi Anne Seton | In-press coating method and composition |
US20070010612A1 (en) * | 2005-07-01 | 2007-01-11 | The Sherwin-Williams Company | Multi-Layer Coating System Including A Hydroxyl Modified Polyurethane Dispersion Binder |
Family Cites Families (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1958706A1 (de) | 1969-11-22 | 1971-05-27 | Lechler Bautenschutzchemie Kg | Verfahren und Masse zur Oberflaechenverguetung von poroesen Leichtbaustoffen |
US3884863A (en) † | 1970-11-27 | 1975-05-20 | Exxon Research Engineering Co | Zinc enriched lithium silicate-latex coating composition |
US3931448A (en) * | 1972-09-20 | 1976-01-06 | United States Steel Corporation | Coated articles |
DE2728861A1 (de) * | 1976-06-30 | 1978-01-05 | Ciba Geigy Ag | Verwendung waesseriger harzloesungen als binde- und impraegniermittel |
US4246148A (en) * | 1979-08-27 | 1981-01-20 | Celanese Corporation | Two component aqueous coating composition based on an epoxy-polyamine adduct and a polyepoxide |
GB2171030B (en) * | 1985-01-10 | 1988-09-28 | Kansai Paint Co Ltd | Coating method |
US5087405A (en) * | 1988-11-08 | 1992-02-11 | Coplas, Inc. | In mold overlay process for gel coated glass fiber reinforced laminates |
US5162407A (en) * | 1990-03-06 | 1992-11-10 | Investors Diversified Capital, Inc. | Silicone rubber sealant composition |
DE4021502A1 (de) | 1990-07-05 | 1992-01-16 | Basf Ag | Mit copolymerfilmen beschichteter betonstein |
KR100242754B1 (ko) † | 1991-05-31 | 2000-02-01 | 에프. 콘래드 그레고리 | 수성 유액계 피복 조성물 |
US5356716A (en) | 1992-09-04 | 1994-10-18 | Patel Pratim R | Waterproofing sealer/repellent compositions for concrete, masonry and porous surfaces |
FR2710552B1 (fr) * | 1993-09-30 | 1995-12-22 | Lvmh Rech | Utilisation de copolymères-blocs acryliques comme agents mouillants et/ou dispersants des particules solides et dispersions en résultant. |
JP3375699B2 (ja) † | 1993-11-17 | 2003-02-10 | 昭和高分子株式会社 | 無機板用プライマー組成物 |
US5445754A (en) * | 1994-03-28 | 1995-08-29 | P.S.A.M.S., Inc. | Water-based, thermal paint |
US5688642A (en) * | 1994-12-01 | 1997-11-18 | The United States Of America As Represented By The Secretary Of The Navy | Selective attachment of nucleic acid molecules to patterned self-assembled surfaces |
US5962602A (en) * | 1995-08-18 | 1999-10-05 | Sika Corporation Usa | Ultra-low viscosity epoxy sealer/healer |
US20040081706A1 (en) * | 1996-03-13 | 2004-04-29 | Eilidh Trainer | Alginate containing antimicrobial composition |
US6472472B2 (en) * | 1996-05-17 | 2002-10-29 | The Valspar Corporation | Powder coating compositions and method |
ZA973692B (en) * | 1996-05-17 | 1997-11-25 | Dexter Corp | Extrusion coating compositions and method. |
CN1105759C (zh) * | 1996-11-22 | 2003-04-16 | Sk化研株式会社 | 防污染涂料组合物 |
US6069217A (en) * | 1997-03-07 | 2000-05-30 | Rheox, Inc. | Urethane-acrylic copolymer thickening compositions for aqueous systems |
JPH10279831A (ja) | 1997-04-08 | 1998-10-20 | Mitsubishi Rayon Co Ltd | コンクリート用プライマー組成物 |
AUPO612097A0 (en) | 1997-04-10 | 1997-05-08 | James Hardie Research Pty Limited | Building products |
US6572927B1 (en) * | 1998-06-29 | 2003-06-03 | Gerd Pleyers | Method for sealing porous building materials and building components |
US6395804B1 (en) * | 1998-12-18 | 2002-05-28 | 3M Innovative Properties Company | Polyelectrolyte dispersants for hydrophobic particles in water-based systems |
FR2790263A1 (fr) * | 1999-02-26 | 2000-09-01 | Atochem Elf Sa | Materiaux composites contenant une couche d'un film antichoc |
US6359062B1 (en) * | 1999-03-02 | 2002-03-19 | The Valspar Corporation | Coating compositions |
US6235102B1 (en) * | 1999-03-09 | 2001-05-22 | The Valspar Corporation | Coating composition for metal substrates containing an acrylate copolymer having pendant glycidyl groups and an acid-terminated polyester |
DE19918052A1 (de) * | 1999-04-21 | 2000-10-26 | Basf Ag | Wässrige, pigmenthaltige Beschichtungsmittel |
US6423029B1 (en) * | 1999-04-29 | 2002-07-23 | Medtronic, Inc. | System and method for detecting abnormal medicament pump fluid pressure |
JP2000327453A (ja) | 1999-05-24 | 2000-11-28 | Sekisui Chem Co Ltd | セメントモルタル成形品の塗装方法 |
DE19954619A1 (de) * | 1999-11-12 | 2001-05-17 | Basf Ag | Wässrige Polymerdispersionen |
US6958379B2 (en) * | 1999-12-03 | 2005-10-25 | Acushnet Company | Polyurea and polyurethane compositions for golf equipment |
AU2001241466A1 (en) * | 2000-02-10 | 2001-08-20 | The Government of the United States of America as represented by the Administrator of the National Aeronautics Space Administration (NASA) | Phenylethynyl-containing imide silanes |
MXPA02008921A (es) | 2000-03-14 | 2004-10-15 | James Hardie Res Pty Ltd | Materiales de construccion de fibras-cemento, con aditivos de baja densidad. |
US6376579B1 (en) * | 2000-07-18 | 2002-04-23 | Illnois Tool Works | Low temperature curing, sag-resistant epoxy primer |
US20020058110A1 (en) * | 2000-09-25 | 2002-05-16 | Even Ralph Craig | Aqueous acrylic emulsion polymer composition |
US20020072562A1 (en) * | 2000-09-29 | 2002-06-13 | Siddhartha Asthana | Methods and compositions for coating a surface |
CN1568293A (zh) | 2000-10-04 | 2005-01-19 | 詹姆斯·哈迪研究有限公司 | 使用装载有无机和/或有机物质的纤维素纤维的纤维水泥复合材料 |
CN1246246C (zh) | 2000-10-04 | 2006-03-22 | 詹姆斯哈迪国际财金公司 | 使用上浆的纤维素纤维的纤维水泥复合材料 |
DE10049791A1 (de) * | 2000-10-09 | 2002-04-18 | Basf Ag | Pigmenthaltige Beschichtungsmittel auf Wasserbasis |
US6803004B1 (en) * | 2000-10-24 | 2004-10-12 | Valspar Sourcing, Inc. | High throughput process for reactive extrusion of epoxy resin |
US20020169271A1 (en) * | 2000-10-26 | 2002-11-14 | Weiling Peng | Adhesive mixture for bonding fluorohydrocarbon film to fibrous cementitious materials |
US7238391B2 (en) * | 2000-11-01 | 2007-07-03 | Valspar Sourcing, Inc. | Abrasion resistant coating for stacks of fiber cement siding |
US7244484B2 (en) * | 2000-11-08 | 2007-07-17 | Valspar Sourcing, Inc. | Multilayered package with barrier properties |
US6420479B1 (en) * | 2000-12-29 | 2002-07-16 | National Starch And Chemical Investment Holding Corporation | Star polymer colloidal stabilizers |
ATE391756T1 (de) * | 2001-02-22 | 2008-04-15 | Valspar Sourcing Inc | Beschichtungszusammensetzungen enthaltend verbindungen mit einem niedrigen gehalt an flüchtigen organischen verbindungen |
AU785016B2 (en) * | 2001-06-14 | 2006-08-24 | Rohm And Haas Company | Semi-continuous bimodal emulsion polymerization |
US6916541B2 (en) * | 2001-09-07 | 2005-07-12 | Penn State Research Foundation | Modified substrates for the attachment of biomolecules |
AU2002301310B2 (en) * | 2001-10-17 | 2007-12-20 | Rohm And Haas Company | Polymer composition |
DE60310694T2 (de) * | 2002-03-04 | 2007-10-04 | Valspar Sourcing, Inc., Minneapolis | Hochreflexionspolyesterbeschichtung |
JP4455886B2 (ja) * | 2002-03-08 | 2010-04-21 | バルスパー ソーシング,インコーポレイティド | 揮発性有機化合物含有量の低いコーティング |
EP1507830A4 (fr) * | 2002-05-03 | 2005-08-17 | Valspar Sourcing Inc | Vernis de surimpression souples |
AU2003231863C1 (en) * | 2002-05-29 | 2010-03-25 | Valspar Sourcing, Inc. | Low-hap and zero-hap polyester systems and articles |
US6933415B2 (en) * | 2002-06-06 | 2005-08-23 | Basf Ag | Low-VOC aqueous coating compositions with excellent freeze-thaw stability |
US7041727B2 (en) * | 2002-06-25 | 2006-05-09 | 3M Innovative Properties Company | Latex paint compositions and coatings |
US6770371B2 (en) * | 2002-07-08 | 2004-08-03 | The Boeing Company | Silane triol capped expoxy-amine adhesion promoter for adhesive-bonded metal substrates |
US20070001343A1 (en) * | 2002-08-12 | 2007-01-04 | Valspar Sourcing, Inc. | Blush-resistant marine gel coat composition |
MXPA05001740A (es) * | 2002-08-12 | 2005-08-16 | Valspar Sourcing Inc | Resina para revestimiento en gel a base de acrilato de uretano y metodo para elaborarla. |
BR0313403A (pt) * | 2002-08-15 | 2005-06-28 | Valspar Sourcing Inc | Substrato revestido, método de revestimento e fabricação de uma bobina, e, composição de revestimento |
US20050058689A1 (en) * | 2003-07-03 | 2005-03-17 | Reactive Surfaces, Ltd. | Antifungal paints and coatings |
ES2322994T3 (es) * | 2002-09-18 | 2009-07-03 | Valspar Sourcing, Inc. | Composicion de revestimiento al agua auto reticulable. |
AU2003901529A0 (en) * | 2003-03-31 | 2003-05-01 | James Hardie International Finance B.V. | A durable high performance fibre cement product and method of making the same |
EP1615966B2 (fr) * | 2003-04-02 | 2019-10-09 | Swimc Llc | Dispersions aqueuses et revetements |
US7728068B2 (en) * | 2003-06-12 | 2010-06-01 | Valspar Sourcing, Inc. | Coating compositions containing reactive diluents and methods |
BRPI0413077A (pt) * | 2003-07-28 | 2006-10-03 | Valspar Sourcing Inc | recipientes de metal possuindo uma extremidade de fácil abertura e método de fabricação dos mesmos |
JP4145261B2 (ja) * | 2003-08-04 | 2008-09-03 | ローム アンド ハース カンパニー | 水性トラフィックペイントおよび塗布方法 |
JP2007502350A (ja) * | 2003-08-13 | 2007-02-08 | ヴァルスパー ソーシング,インク. | 水系ポリウレタン‐ポリエチレン系組成物 |
CA2537749C (fr) * | 2003-09-08 | 2009-12-08 | Valspar Sourcing, Inc. | Procedes de frittage laser utilisant des compositions thermoplastiques |
WO2005083013A1 (fr) * | 2004-01-30 | 2005-09-09 | Millennium Chemicals | Composition de revetement presentant des proprietes de depollution de surface |
KR20070001160A (ko) * | 2004-02-12 | 2007-01-03 | 발스파 소싱 인코포레이티드 | 내부 용기 표면의 코팅 방법 및 내부 코팅을 함유하는 용기 |
EP1581031B1 (fr) * | 2004-03-25 | 2010-10-06 | FUJIFILM Corporation | Procédés de formation d'un motif et un motif conducteur |
US7435453B2 (en) * | 2004-08-04 | 2008-10-14 | Valspar Sourcing, Inc. | Method of finishing veneer surface of veneered wood product by application and curing of UV-curable coating layers having cationically and free-radically polymerizable moieties |
US7470751B2 (en) * | 2004-09-21 | 2008-12-30 | Basf Corporation | Stabilized water-borne polymer compositions for use as water-based coatings |
EP1819791A1 (fr) * | 2004-10-19 | 2007-08-22 | Valspar Sourcing, Inc. | Formules de couches de surface thermorésistantes, articles traités en surface, et méthodes |
ATE424376T1 (de) * | 2004-11-02 | 2009-03-15 | Valspar Sourcing Inc | Faserzementprodukte |
BRPI0518334A2 (pt) * | 2004-11-22 | 2008-11-11 | Valspar Sourcing Inc | composiÇço de revestimento, mÉtodo de revestimento, revestimento, e, mÉtodo para preparar uma composiÇço de revestimento |
MX279192B (es) * | 2004-12-17 | 2010-09-22 | Valspar Sourcing Inc | Composiciones acuosas de recubrimiento que contienen polimeros funcionales de acetoacetilo, recubrimientos, y metodos. |
US8609762B2 (en) * | 2004-12-17 | 2013-12-17 | Valspar Sourcing, Inc. | Aqueous coating compositions containing acetoacetyl-functional polymers, coatings, and methods |
US7479326B2 (en) * | 2005-03-08 | 2009-01-20 | Valspar Sourcing, Inc. | Oxygen scavenging polymers |
US7953274B2 (en) * | 2005-03-18 | 2011-05-31 | Valspar Sourcing, Inc. | Digital method for matching stains |
MX2007011299A (es) * | 2005-03-18 | 2007-10-05 | Valspar Sourcing Inc | Composiciones colorantes de pintura universales de compuestos organicos volatiles bajos. |
BRPI0614747B1 (pt) * | 2005-08-11 | 2018-02-06 | Valspar Sourcing, Inc. | Composição de revestimento para acondicionamento endurecível, método para revestir um substrato metálico com uma composição de revestimento para acondicionamento endurecível, e, recipiente metálico para gêneros alimentícios |
US7758954B2 (en) | 2005-08-18 | 2010-07-20 | James Hardie Technology Limited | Coated substrate having one or more cross-linked interfacial zones |
US20070045891A1 (en) * | 2005-08-23 | 2007-03-01 | Valspar Sourcing, Inc. | Infiltrated Articles Prepared by a Laser Sintering Method and Method of Manufacturing the Same |
US7763323B2 (en) * | 2005-09-06 | 2010-07-27 | Valspar Sourcing, Inc. | Cross-linked polyester protective coatings |
CN101316706B (zh) * | 2005-10-18 | 2014-01-15 | 威士伯采购公司 | 容器用涂料组合物和涂布方法 |
AU2006315105C1 (en) * | 2005-11-15 | 2012-08-16 | Swimc Llc | Crush resistant latex topcoat composition for fiber cement substrates |
US7963728B2 (en) * | 2006-01-06 | 2011-06-21 | Valspar Sourcing, Inc. | Method and apparatus for powder delivery system |
WO2007090131A1 (fr) * | 2006-01-31 | 2007-08-09 | Valspar Sourcing, Inc. | Systeme de revetement pour articles composites en ciment |
US20070178239A1 (en) * | 2006-02-01 | 2007-08-02 | Ecolab Inc. | Protective coating for painted or glossy surfaces |
MX2008014749A (es) * | 2006-05-19 | 2009-02-04 | Valspar Sourcing Inc | Sistema de recubrimiento para articulos compuestos de cemento. |
MX2008015356A (es) * | 2006-06-02 | 2009-01-30 | Valspar Sourcing Inc | Composiciones de recubrimiento acuoso de alto rendimiento. |
MX2008016511A (es) * | 2006-06-28 | 2009-06-02 | Valspar Sourcing Inc | Metodo y sistema para recubrimiento de borde de sustratos de madera. |
WO2008005483A2 (fr) * | 2006-07-05 | 2008-01-10 | Valspar Sourcing, Inc. | Polymère de polyuréthane dispersable dans l'eau |
WO2008006109A1 (fr) * | 2006-07-07 | 2008-01-10 | Valspar Sourcing, Inc. | Systèmes d'enrobage pour articles composites en ciment |
WO2009006333A1 (fr) | 2007-06-28 | 2009-01-08 | James Hardie International Finance B.V. | Formulation de peinture pour matériau de construction |
EP2160442A4 (fr) * | 2007-06-28 | 2013-05-29 | Hardie James Technology Ltd | Primaire pour des matériaux de construction composites |
WO2009006324A1 (fr) * | 2007-06-29 | 2009-01-08 | James Hardie International Finance B.V. | Primaires multifonctionnels |
-
2008
- 2008-06-27 WO PCT/US2008/068626 patent/WO2009006324A1/fr active Application Filing
- 2008-06-27 US US12/163,541 patent/US9051488B2/en active Active
- 2008-06-27 EP EP08781114.7A patent/EP2162473B2/fr active Active
- 2008-06-27 CA CA2697184A patent/CA2697184C/fr active Active
- 2008-06-27 NZ NZ582054A patent/NZ582054A/en unknown
- 2008-06-27 AU AU2008269996A patent/AU2008269996B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4226277A (en) * | 1978-06-29 | 1980-10-07 | Ralph Matalon | Novel method of making foundry molds and adhesively bonded composites |
US5059264A (en) * | 1989-12-26 | 1991-10-22 | The Glidden Company | Aqueous inpress primer sealer for hardboard manufacturing |
US20020171170A1 (en) * | 2001-03-19 | 2002-11-21 | Demasi Anne Seton | In-press coating method and composition |
US20070010612A1 (en) * | 2005-07-01 | 2007-01-11 | The Sherwin-Williams Company | Multi-Layer Coating System Including A Hydroxyl Modified Polyurethane Dispersion Binder |
Non-Patent Citations (1)
Title |
---|
See also references of EP2162473A4 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7758954B2 (en) | 2005-08-18 | 2010-07-20 | James Hardie Technology Limited | Coated substrate having one or more cross-linked interfacial zones |
US8501863B2 (en) | 2007-06-28 | 2013-08-06 | James Hardie Technology Limited | Paint |
US9051488B2 (en) * | 2007-06-29 | 2015-06-09 | James Hardie Technology Limited | Multifunctional primers |
WO2014149916A1 (fr) * | 2013-03-15 | 2014-09-25 | Behr Process Corporation | Composition de revêtement superhydrophile |
AU2014237704B2 (en) * | 2013-03-15 | 2017-08-24 | Behr Process Corporation | Superhydrophilic coating composition |
US10301477B2 (en) | 2013-03-15 | 2019-05-28 | Behr Process Corporation | Superhydrophilic coating composition |
Also Published As
Publication number | Publication date |
---|---|
CA2697184A1 (fr) | 2009-01-08 |
EP2162473B2 (fr) | 2020-04-15 |
AU2008269996A1 (en) | 2009-01-08 |
NZ582054A (en) | 2012-06-29 |
EP2162473A1 (fr) | 2010-03-17 |
US9051488B2 (en) | 2015-06-09 |
WO2009006324A8 (fr) | 2010-01-28 |
CA2697184C (fr) | 2015-10-27 |
EP2162473B1 (fr) | 2016-08-24 |
US20090005494A1 (en) | 2009-01-01 |
EP2162473A4 (fr) | 2012-10-31 |
AU2008269996B2 (en) | 2014-06-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US9051488B2 (en) | Multifunctional primers | |
WO2009006304A1 (fr) | Primaire pour des matériaux de construction composites | |
JP5004229B2 (ja) | コーティング剤 | |
CA2696569C (fr) | Formulation de peinture pour materiau de construction | |
AU2007282141B2 (en) | Multi-component coating method for porous substrates | |
KR101227380B1 (ko) | 습윤면에 부착성이 우수한 복합도막 구조를 이용한 콘크리트 구조물의 표면 도장공법 | |
CN102433050B (zh) | 一种纳米多功能衬底涂料及其制备方法 | |
CA2968517C (fr) | Articles revetus et leurs procedes de fabrication | |
JP6442474B2 (ja) | 疎水性の仕上げ剤を含むセメント質の物品 | |
JP5974323B2 (ja) | 漆喰塗布面の艶消し防汚処理材およびそれを用いた防汚仕上げ方法 | |
JP2020171926A (ja) | 被膜形成方法 | |
WO2015179476A1 (fr) | Composition de pâte de rebouchage contenant de la silice hydratée | |
CN114395309A (zh) | 水性环氧树脂乳液地坪涂漆及其施工工艺 | |
JP4732214B2 (ja) | 塗装方法 | |
CN112662281A (zh) | 一种透气环氧地坪涂料 | |
KR102483530B1 (ko) | 함수율이 높은 콘크리트 구조물의 표면 보호 및 보수용 도막재 조성물 및 이를 이용한 함수율이 높은 콘크리트 구조물의 표면 보호 및 보수 시공방법 | |
PL177972B1 (pl) | Dyspersja krzemoorganiczna do zabezpieczania materiałów budowlanych przed napisami graffiti | |
MX2008009772A (es) | Metodo de recubrimiento de componentes multiples para sustratos porosos | |
KR20160074130A (ko) | 피브이비 타일용 수용성 표면처리제 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 08781114 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008269996 Country of ref document: AU Ref document number: 582054 Country of ref document: NZ |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2697184 Country of ref document: CA |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
REEP | Request for entry into the european phase |
Ref document number: 2008781114 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008781114 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2008269996 Country of ref document: AU Date of ref document: 20080627 Kind code of ref document: A |