WO2008145387A3 - Katalysator zur selektiven hydrierung acetylenischer kohlenwasserstoffe und verfahren zu seiner herstellung - Google Patents

Katalysator zur selektiven hydrierung acetylenischer kohlenwasserstoffe und verfahren zu seiner herstellung Download PDF

Info

Publication number
WO2008145387A3
WO2008145387A3 PCT/EP2008/004327 EP2008004327W WO2008145387A3 WO 2008145387 A3 WO2008145387 A3 WO 2008145387A3 EP 2008004327 W EP2008004327 W EP 2008004327W WO 2008145387 A3 WO2008145387 A3 WO 2008145387A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
producing
selective hydrogenation
support
acetylenic hydrocarbons
Prior art date
Application number
PCT/EP2008/004327
Other languages
English (en)
French (fr)
Other versions
WO2008145387A2 (de
Inventor
Sybille Ungar
Richard Fischer
Andreas Trautwein
Steve Blankenship
Jennifer Boyer
Michael Urbancic
Andrzej Rokicki
Original Assignee
Sued Chemie Ag
Sybille Ungar
Richard Fischer
Andreas Trautwein
Steve Blankenship
Jennifer Boyer
Michael Urbancic
Andrzej Rokicki
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sued Chemie Ag, Sybille Ungar, Richard Fischer, Andreas Trautwein, Steve Blankenship, Jennifer Boyer, Michael Urbancic, Andrzej Rokicki filed Critical Sued Chemie Ag
Priority to CN200880018334A priority Critical patent/CN101730588A/zh
Priority to EP08758898A priority patent/EP2155392A2/de
Priority to JP2010509739A priority patent/JP5323060B2/ja
Priority to US12/601,985 priority patent/US20100217052A1/en
Publication of WO2008145387A2 publication Critical patent/WO2008145387A2/de
Publication of WO2008145387A3 publication Critical patent/WO2008145387A3/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
    • C07C7/167—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation for removal of compounds containing a triple carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zur Herstellung eines Katalysators, insbesondere für die selektive Reduktion acetylenischer Verbindungen in Kohlenwasserstoff strömen, wobei: eine Imprägnierlösung bereitgestellt wird, welche als Lösungsmittel ein Gemisch aus Wasser und zumindest einem mit Wasser mischbaren organischen Lösungsmittel enthält, in welchem zumindest eine Aktivmetallverbindung sowie vorzugsweise zumindest eines Promotormetallverbindung gelöst ist; ein Träger bereitgestellt wird; der Träger mit der Imprägnierlösung imprägniert wird; der imprägnierte Träger kalziniert wird. Als Aktivmetall wird bevorzugt Palladium und als Promotormetall bevorzugt Silber verwendet. Ferner betrifft die Erfindung einen Katalysator, wie er mit dem Verfahren erhalten wird, sowie dessen bevorzugte Verwendung zur selektiven Hydrierung acetylenischer Verbindungen.
PCT/EP2008/004327 2007-05-31 2008-05-30 Katalysator zur selektiven hydrierung acetylenischer kohlenwasserstoffe und verfahren zu seiner herstellung WO2008145387A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN200880018334A CN101730588A (zh) 2007-05-31 2008-05-30 用于炔烃选择性加氢的催化剂及其制备方法
EP08758898A EP2155392A2 (de) 2007-05-31 2008-05-30 Katalysator zur selektiven hydrierung acetylenischer kohlenwasserstoffe und verfahren zu seiner herstellung
JP2010509739A JP5323060B2 (ja) 2007-05-31 2008-05-30 アセチレン系炭化水素の選択的な水素化のための触媒、該触媒の製造方法及び該触媒の使用
US12/601,985 US20100217052A1 (en) 2007-05-31 2008-05-30 Catalyst For The Selective Hydrogenation Of Acetylenic Hydrocarbons And Method For Producing Said Catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007025315.1 2007-05-31
DE102007025315A DE102007025315A1 (de) 2007-05-31 2007-05-31 Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung

Publications (2)

Publication Number Publication Date
WO2008145387A2 WO2008145387A2 (de) 2008-12-04
WO2008145387A3 true WO2008145387A3 (de) 2009-03-12

Family

ID=39717606

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/004327 WO2008145387A2 (de) 2007-05-31 2008-05-30 Katalysator zur selektiven hydrierung acetylenischer kohlenwasserstoffe und verfahren zu seiner herstellung

Country Status (9)

Country Link
US (1) US20100217052A1 (de)
EP (1) EP2155392A2 (de)
JP (1) JP5323060B2 (de)
KR (1) KR20100041714A (de)
CN (1) CN101730588A (de)
DE (1) DE102007025315A1 (de)
RU (1) RU2009145197A (de)
TW (1) TW200916189A (de)
WO (1) WO2008145387A2 (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007025223A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
EP2241393A1 (de) 2009-04-14 2010-10-20 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Geordnete Kobalt-Aluminium- und intermetallische Eisen-Aluminiumverbindungen als Hydrierungskatalysatoren
DE102009051462B4 (de) * 2009-10-30 2015-02-05 Clariant International Ag Verfahren zur Herstellung eines Kompositmaterials, Kompositmaterial und dessen Verwendung
EP2569086A4 (de) * 2010-05-10 2014-05-21 Advanced Catalyst Technologies Llc Nanostrukturierte katalysatorpellets, katalysatoroberflächenbearbeitung und hochselektiver katalysator zur ethylenepoxidierung
US9511359B2 (en) 2014-11-14 2016-12-06 Chevron Phillips Chemical Company Lp Selective hydrogenation catalyst and methods of making and using same
US10752563B2 (en) 2016-03-31 2020-08-25 Zeon Corporation Hydrogenation method
CN111085223A (zh) * 2018-10-24 2020-05-01 中国石油化工股份有限公司 银负载-锌掺杂雷尼铜催化剂及其制备方法和应用
FR3099389B1 (fr) 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel soufre repartie en croute
FR3099391B1 (fr) 2019-07-31 2021-10-29 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute
FR3099386B1 (fr) 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel repartie en croute et un alliage nickel cuivre
FR3099387B1 (fr) 2019-07-31 2021-10-29 Ifp Energies Now Catalyseur comprenant une phase active de nickel repartie en croute
FR3099388B1 (fr) 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute et un alliage nickel cuivre
CN112844407B (zh) * 2019-11-26 2024-06-28 中国石油天然气股份有限公司 一种碳三馏分选择加氢催化剂的制备方法
CN112934232B (zh) * 2019-11-26 2023-10-31 中国石油天然气股份有限公司 一种碳三馏分选择加氢的催化剂
FR3110862A1 (fr) 2020-05-29 2021-12-03 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute
FR3110867B1 (fr) 2020-05-29 2022-07-01 Ifp Energies Now Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute obtenu a partir de sels fondus
FR3110864B1 (fr) 2020-05-29 2022-07-01 Ifp Energies Now Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute et un alliage nickel cuivre
FR3110863A1 (fr) 2020-05-29 2021-12-03 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute obtenu a partir de sels fondus et un alliage nickel cuivre
FR3110865A1 (fr) 2020-05-29 2021-12-03 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute et un alliage nickel cuivre
FR3110866B1 (fr) 2020-05-29 2022-07-01 Ifp Energies Now Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute
KR20220049888A (ko) * 2020-10-15 2022-04-22 한국화학연구원 메탄의 비산화 메탄전환 및 아세틸렌의 선택적 수소화용 촉매 및 이의 제조방법
FR3125439A1 (fr) 2021-07-22 2023-01-27 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute via impregnation d’hexanol
FR3125440A1 (fr) 2021-07-22 2023-01-27 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de nickel repartie en croute via impregnation d’heptanol
EP4201523A1 (de) * 2021-12-21 2023-06-28 Clariant International Ltd Schalenkatalysator zur herstellung von alkenylcarbonsäureestern mit verbesserter pd-verteilung
FR3132647A1 (fr) 2022-02-14 2023-08-18 IFP Energies Nouvelles Procede de preparation d’un catalyseur comprenant une phase active de palladium et de cuivre
FR3132646A1 (fr) 2022-02-14 2023-08-18 IFP Energies Nouvelles Catalyseur comprenant une phase active de palladium et de cuivre
CN115888727A (zh) * 2022-11-28 2023-04-04 浙江卫星能源有限公司 用于丙炔选择性加氢合成丙烯的镍基耐硫催化剂、制备方法及其应用
CN118164817A (zh) * 2024-05-14 2024-06-11 湖南大学 一种在液相中光催化乙炔加氢生产乙烯的方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1283737A (en) * 1968-09-04 1972-08-02 Nat Distillers Chem Corp Method of catalyst preparation
DE4443705A1 (de) * 1994-12-08 1996-06-13 Studiengesellschaft Kohle Mbh Verfahren zur Herstellung von tensidstabilisierten Mono- und Bimetallkolloiden der Gruppe VIII und Ib des Periodensystems als isolierbare und in hoher Konzentration wasserlösliche Precursor für Katalysatoren
EP0899013A1 (de) * 1997-08-29 1999-03-03 Institut Français du Pétrole Neue Katalysatoren für die Umwandlungsreaktionen von organischen Verbindungen
US6492299B1 (en) * 1996-11-04 2002-12-10 Bp International Limited Process for the production of vinyl acetate
EP1452230A1 (de) * 2003-02-28 2004-09-01 President of Shizuoka University Katalysator für die Dampfreformierung von Dimethylether und Verfahren für seine Herstellung
WO2006045606A1 (en) * 2004-10-29 2006-05-04 Umicore Ag & Co Kg Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith

Family Cites Families (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2656323A (en) * 1949-04-12 1953-10-20 Universal Oil Prod Co Manufacture of phosphoric acidgroup iv metal oxide containing catalyst
NL291717A (de) * 1962-04-20
NL295858A (de) * 1962-07-27
FR1579327A (de) * 1967-09-07 1969-08-22
US3617489A (en) * 1969-06-25 1971-11-02 Chevron Res Hydrocracking catalyst comprising a layered clay-type crystalline aluminosilicate component, a group viii component and gold, process using said catalyst
DE2703801C3 (de) * 1977-01-29 1979-08-02 W.C. Heraeus Gmbh, 6450 Hanau Gegen glasige Schmelzen beständige Legierungen
DE2848978A1 (de) * 1978-11-11 1980-05-22 Bayer Ag Traegerkatalysatoren, ihre herstellung und verwendung
FR2482953A1 (fr) 1980-05-22 1981-11-27 Inst Francais Du Petrole Procede d'hydrogenation selective d'une di-olefine dans un melange d'hydrocarbures renfermant au moins 4 atomes de carbone et contenant une olefine -a
US4404124A (en) 1981-05-06 1983-09-13 Phillips Petroleum Company Selective hydrogenation catalyst
DE3125062C2 (de) * 1981-06-26 1984-11-22 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von abriebfesten Schalenkatalysatoren und Verwendung eines so erhaltenen Katalysators
US4844790A (en) * 1986-06-30 1989-07-04 Union Oil Company Of California Hydrocarbon conversion processes using delaminated clay catalysts
US4977126A (en) * 1987-05-07 1990-12-11 Exxon Research And Engineering Company Process for the preparation of surface impregnated dispersed cobalt metal catalysts
FR2619391B1 (fr) * 1987-08-14 1990-01-12 Eurecat Europ Retrait Catalys Procede de reduction d'un catalyseur de raffinage avant sa mise en oeuvre
DE3830850A1 (de) * 1988-09-10 1990-03-22 Gutec Gmbh Verfahren zur entfernung des nitrit- und/oder nitratgehaltes in wasser
US5213771A (en) * 1988-10-31 1993-05-25 Olin Corporation Gas injector for hypochlorous acid reactor
DE3839723C1 (de) * 1988-11-24 1989-07-20 Herbert 7853 Steinen De Huettlin
US5015453A (en) * 1989-04-28 1991-05-14 W. R. Grace & Co.-Conn. Crystalline group IVA metal-containing molecular sieve compositions
DE3934614A1 (de) * 1989-10-17 1991-04-18 Hoechst Ag Verfahren zur isolierung von vinylacetat
DE3938723A1 (de) * 1989-11-23 1991-05-29 Basf Ag Katalysator zur herstellung von hochmolekularen homo- oder copolymerisaten des ethens sowie dessen herstellung
DE4000572C1 (de) * 1990-01-10 1991-02-21 Herbert 7853 Steinen De Huettlin
US5175136A (en) * 1990-05-31 1992-12-29 Monsanto Company Monolithic catalysts for conversion of sulfur dioxide to sulfur trioxide
DE4039026A1 (de) * 1990-12-07 1992-06-11 Bayer Ag Verfahren zur herstellung von anilin
US5179056A (en) * 1991-05-06 1993-01-12 Union Carbide Chemicals & Plastics Technology Corporation Production of alkenyl alkanoate catalysts
DE4120492A1 (de) * 1991-06-21 1992-12-24 Hoechst Ag Verfahren zur herstellung von vinylacetat
TW330160B (en) * 1992-04-08 1998-04-21 Hoechst Ag Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate
NO179131C (no) * 1993-06-14 1996-08-14 Statoil As Katalysator, fremgangsmåte for dens fremstilling og fremgangsmåte for dehydrogenering av lette paraffiner
DE4323980C1 (de) * 1993-07-16 1995-03-30 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
DE4323981C1 (de) * 1993-07-16 1995-03-09 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
DE4323978C1 (de) * 1993-07-16 1995-02-16 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
CA2135021A1 (en) * 1993-11-19 1995-05-20 David J. Gulliver Process for the preparation of catalysts for use in the production of vinyl acetate
US6395676B2 (en) * 1994-02-22 2002-05-28 The Standard Oil Company Process for the preparation of fluid bed vinyl acetate catalyst
US5466652A (en) * 1994-02-22 1995-11-14 The Standard Oil Co. Process for the preparation of vinyl acetate catalyst
US5665667A (en) * 1994-06-02 1997-09-09 The Standard Oil Company Process for the preparation of vinyl acetate catalyst
EP0686615B2 (de) 1994-06-09 2007-06-27 Institut Francais Du Petrole Verfahren zur katalytischen Hydrierung und in diesem Verfahren zu verwendender Katalysator
US5753583A (en) * 1995-01-09 1998-05-19 Basf Aktiengesellschaft Supported palladium catalyst
DE19501891C1 (de) * 1995-01-23 1996-09-26 Degussa Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat
FR2742679B1 (fr) 1995-12-22 1998-01-16 Inst Francais Du Petrole Catalyseur d'hydrogenation selective et procede utilisant ce catalyseur
US5668074A (en) * 1995-07-12 1997-09-16 Phillips Petroleum Company Preparation of catalysts for alkane/cycloalkane isomerization
US5650371A (en) * 1995-12-26 1997-07-22 Exxon Research And Engineering Company Heterogeneous catalysts via impregnation process
US6207610B1 (en) * 1996-05-17 2001-03-27 Degussa-Huls Ag Compacts based on pyrogenically produced silicon dioxide
SA97180048B1 (ar) * 1996-05-24 2005-12-21 هوكست سيلانس كوربوريشن محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل
EP0917532B1 (de) * 1996-07-01 2002-02-13 The Dow Chemical Company Verfahren zur direkten oxidation von olefinen zu olefinoxiden
US5935889A (en) * 1996-10-04 1999-08-10 Abb Lummus Global Inc. Catalyst and method of preparation
DE19645549A1 (de) * 1996-11-05 1998-05-07 Bayer Ag Verfahren zur Herstellung von 2-Methyl-2,4-diaminopentan
TW377306B (en) * 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
US5888472A (en) * 1997-04-08 1999-03-30 Uop Llc Zirconium silicate molecular sieves and process using the same
DE19721601A1 (de) * 1997-05-23 1998-11-26 Hoechst Ag Polybetain-stabilisierte, Palladium-haltige Nanopartikel, ein Verfahren zu ihrer Herstellung sowie daraus hergestellte Katalysatoren zur Gewinnung von Vinylacetat
DE19723591A1 (de) * 1997-06-05 1998-12-10 Hoechst Ag Katalysator, Verfahren zu seiner Herstellung und seine Verwendung zur Herstellung von Vinylacetat
DE19734974A1 (de) * 1997-08-13 1999-02-25 Hoechst Ag Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat
DE19743100A1 (de) * 1997-09-30 1999-04-01 Degussa Verfahren zur Herstellung eines Schalenkatalysators
DE19750238A1 (de) * 1997-11-13 1999-05-27 Degussa Preßlinge auf Basis von pyrogen hergestelltem Siliciumdioxid
US6017847A (en) * 1998-06-02 2000-01-25 Celanese International Corporation Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper
ID26891A (id) * 1998-06-02 2001-02-15 Celanese Internasional Corp Katalis vinil asetat yang terdiri dari palladium logam dan emas yang dibuat dengan potasium aurat
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
DE19824532A1 (de) * 1998-06-03 1999-12-09 Basf Ag Verfahren zur Herstellung von Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen und so erhältliche Katalysatoren
DE19828491A1 (de) * 1998-06-26 1999-12-30 Degussa Formkörper auf Basis von Siliciumdioxid
DE19840373A1 (de) * 1998-09-04 2000-03-09 Basf Ag Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen
DE19843693A1 (de) * 1998-09-24 2000-03-30 Degussa Trägerkatalysator für die Produktion von Vinylacetatmonomer
US6358882B1 (en) * 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
DE19914066A1 (de) * 1999-03-27 2000-10-05 Celanese Chem Europe Gmbh Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung
US6143921A (en) * 1999-05-14 2000-11-07 Saudi Basic Industries Corporation Method for producing vinyl acetate monomer from ethane or ethylene oxidation
DE10015250A1 (de) * 2000-03-28 2001-10-04 Basf Ag Schalenkatalysator für die Gasphasenhydrierung
US6420308B1 (en) * 2000-07-07 2002-07-16 Saudi Basic Industries Corp Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
US6534438B1 (en) * 2000-07-26 2003-03-18 Bp Chemicals Limited Catalyst composition
US6797669B2 (en) * 2000-12-29 2004-09-28 China Petroleum & Chemical Corporation Catalyst for selective hydrogenation, its preparation process and application
KR100628620B1 (ko) * 2001-04-30 2006-09-26 더블유.알. 그레이스 앤드 캄파니-콘. 이종 크롬 촉매 및 이를 사용하는 올레핀의 중합 방법
FR2825296B1 (fr) * 2001-05-30 2003-09-12 Toulouse Inst Nat Polytech Procede de fabrication de nanoparticules metalliques supportees en lit fluidise
DE10129166C1 (de) * 2001-06-12 2003-01-16 Herbert Huettlin Vorrichtung zum Behandeln von partikelförmigem Gut
AU2002341704A1 (en) * 2001-10-15 2003-04-28 Catalytic Distillation Technologies Hydrogenation catalyst and hydrogenation process
DE10163180A1 (de) * 2001-12-21 2003-07-10 Degussa Trägerkatalysator
JP4421201B2 (ja) * 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
MY137042A (en) * 2002-06-14 2008-12-31 Chevron Phillips Chemical Co Hydrogenation palladium-silver catalyst and methods
US6822008B2 (en) * 2002-09-06 2004-11-23 Conocophillips Company Fischer-Tropsch catalysts using multiple precursors
DE10248116B3 (de) * 2002-10-07 2004-04-15 Hüttlin, Herbert, Dr.h.c. Vorrichtung zum Behandeln von partikelförmigem Gut mit einer Höhenverstellvorrichtung
US7569508B2 (en) * 2004-11-17 2009-08-04 Headwaters Technology Innovation, Llc Reforming nanocatalysts and method of making and using such catalysts
DE10344845A1 (de) * 2003-09-26 2005-04-14 Basf Ag Vorrichtung zum Mischen, Trocknen und Beschichten von pulvrigem, körnigem oder geformtem Schüttgut in einem Fließbett und Verfahren zur Herstellung von Trägerkatalysatoren unter Verwendung einer solchen Vorrichtung
TW200526321A (en) * 2003-09-26 2005-08-16 Basf Ag Process for producing a catalyst for gas-phase oxidations
TW201236754A (en) * 2003-12-19 2012-09-16 Celanese Int Corp Zirconia containing support materials for catalysts
DE202005003791U1 (de) * 2005-02-28 2006-07-06 Hüttlin, Herbert, Dr. h.c. Apparatur zur Behandlung von partikelförmigem Gut
BRPI0518825A2 (pt) * 2004-12-20 2008-12-09 Celanese Int Corp materias de suporte modificados para catalisadores
FR2882531B1 (fr) * 2005-02-25 2007-04-27 Inst Francais Du Petrole Procede de preparation de catalyseurs multimetalliques utilisables dans des reactions de transformation des hydrocarbures
US7638459B2 (en) * 2005-05-25 2009-12-29 Uop Llc Layered composition and processes for preparing and using the composition
DE102005029200A1 (de) * 2005-06-22 2006-12-28 Basf Ag Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen
DE102007025443A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
US20100140181A1 (en) * 2008-12-05 2010-06-10 Gilles Tastayre Regeneration of used cleaning solution

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1283737A (en) * 1968-09-04 1972-08-02 Nat Distillers Chem Corp Method of catalyst preparation
DE4443705A1 (de) * 1994-12-08 1996-06-13 Studiengesellschaft Kohle Mbh Verfahren zur Herstellung von tensidstabilisierten Mono- und Bimetallkolloiden der Gruppe VIII und Ib des Periodensystems als isolierbare und in hoher Konzentration wasserlösliche Precursor für Katalysatoren
US6492299B1 (en) * 1996-11-04 2002-12-10 Bp International Limited Process for the production of vinyl acetate
EP0899013A1 (de) * 1997-08-29 1999-03-03 Institut Français du Pétrole Neue Katalysatoren für die Umwandlungsreaktionen von organischen Verbindungen
EP1452230A1 (de) * 2003-02-28 2004-09-01 President of Shizuoka University Katalysator für die Dampfreformierung von Dimethylether und Verfahren für seine Herstellung
WO2006045606A1 (en) * 2004-10-29 2006-05-04 Umicore Ag & Co Kg Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith

Also Published As

Publication number Publication date
RU2009145197A (ru) 2011-07-10
EP2155392A2 (de) 2010-02-24
US20100217052A1 (en) 2010-08-26
KR20100041714A (ko) 2010-04-22
TW200916189A (en) 2009-04-16
DE102007025315A1 (de) 2008-12-11
WO2008145387A2 (de) 2008-12-04
CN101730588A (zh) 2010-06-09
JP5323060B2 (ja) 2013-10-23
JP2010527776A (ja) 2010-08-19

Similar Documents

Publication Publication Date Title
WO2008145387A3 (de) Katalysator zur selektiven hydrierung acetylenischer kohlenwasserstoffe und verfahren zu seiner herstellung
WO2010128137A3 (en) Improvements relating to hydrogenation of aromatics and other unsaturated organic compounds
EA200601733A1 (ru) Никелевый катализатор и способ получения катализаторов и способ селективного гидрирования
WO2010101736A3 (en) Selective hydrogenation catalyst and methods of making and using same
WO2007124359A3 (en) Regeneration of ionic liquid catalyst using a regeneration metal in the presence of added hydrogen
MY157274A (en) Processes for producing alkylbenzenes over solid acid catalyst at low benzene to olefin ratios and low heavies make
WO2009120026A3 (ko) 메탈로센 담지촉매 조성물 및 이를 이용한 폴리올레핀의 제조방법
WO2009062848A3 (en) Methods of preparing, optionally supported, ordered intermetallic palladium gallium compounds, the compounds as such, and their use in catalysis
MX2007012985A (es) Procedimiento y catalizadores para la epoxidacion de compuestos olefinicos en presencia de oxigeno.
WO2010075516A3 (en) Zeolite supported cobalt hybrid fischer-tropsch catalyst
WO2015025286A3 (en) Selective zeolite supported catalysts for propane and butane dehydrogenation
MX2009005433A (es) Proceso para producir alquenos de oxigenados utilizando catalizadores de heteropoliacidos soportados.
WO2009118095A3 (de) Verfahren zur regeneration eines mit schwefel in form von schwefelverbindungen vergifteten, ruthenium oder rutheniumverbindungen enthaltenden katalysators
MY168414A (en) Catalysts
AR084544A1 (es) Sistema catalitico y su uso para la fabricacion de cloruro de vinilo por adicion de cloruro de hidrogeno al acetileno
WO2010027987A3 (en) Process for ultra low benzene reformate using catalytic distillation
Liu et al. The crucial role of reaction pressure in the reaction paths for i-butane conversion over Zn/HZSM-5
WO2011096992A8 (en) Dehydrogenation process
UA90931C2 (ru) Способ очистки газовой смеси, содержащей оксид азота (и)
SG155162A1 (en) Catalyst system for olefin polymerization, its production and use
WO2009037281A3 (de) Verfahren zur hydrierenden spaltung von lignin an übergangsmetallcarbiden
WO2009138204A3 (de) Verfahren zur herstellung einer platinkatalysator-vorstufe
WO2009120508A3 (en) Process for production of triptane and triptene
WO2007060163A3 (de) Verfahren zum sicheren betreiben einer gasphasen-partialoxidation
WO2009013971A1 (ja) 炭化水素油の水素化精製方法

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880018334.4

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08758898

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 7715/DELNP/2009

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 2010509739

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2008758898

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 20097027581

Country of ref document: KR

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2009145197

Country of ref document: RU

WWE Wipo information: entry into national phase

Ref document number: 12601985

Country of ref document: US