WO2008117871A1 - 含窒素レドックス触媒 - Google Patents
含窒素レドックス触媒 Download PDFInfo
- Publication number
- WO2008117871A1 WO2008117871A1 PCT/JP2008/056164 JP2008056164W WO2008117871A1 WO 2008117871 A1 WO2008117871 A1 WO 2008117871A1 JP 2008056164 W JP2008056164 W JP 2008056164W WO 2008117871 A1 WO2008117871 A1 WO 2008117871A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- optionally substituted
- redox catalyst
- hydrogen atom
- nitrogen
- hydrocarbon group
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by isomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D451/00—Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof
- C07D451/02—Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof containing not further condensed 8-azabicyclo [3.2.1] octane or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane; Cyclic acetals thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D451/00—Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof
- C07D451/02—Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof containing not further condensed 8-azabicyclo [3.2.1] octane or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane; Cyclic acetals thereof
- C07D451/04—Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof containing not further condensed 8-azabicyclo [3.2.1] octane or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane; Cyclic acetals thereof with hetero atoms directly attached in position 3 of the 8-azabicyclo [3.2.1] octane or in position 7 of the 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D451/00—Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof
- C07D451/14—Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof containing 9-azabicyclo [3.3.1] nonane ring systems, e.g. granatane, 2-aza-adamantane; Cyclic acetals thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D453/00—Heterocyclic compounds containing quinuclidine or iso-quinuclidine ring systems, e.g. quinine alkaloids
- C07D453/06—Heterocyclic compounds containing quinuclidine or iso-quinuclidine ring systems, e.g. quinine alkaloids containing isoquinuclidine ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
- C07D487/08—Bridged systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Abstract
式(Ⅰ):(式中、
X1およびX2はそれぞれ、水素原子、ハロゲン原子、置換されていてもよい水酸基または置換されていてもよい炭化水素基を示し、あるいはX1およびX2は、一緒になってオキソ基を形成してもよく、
Yは、結合または酸素原子を示し、
R1は、水素原子、置換基を有する水酸基または置換されていてもよい炭化水素基を示し、
R2およびR3は、水素原子または置換されていてもよい炭化水素基を示し、
mは、0ないし2の整数を示し、
nは、1または2の整数を示す。)
で表される化合物もしくはその誘導体を含む、レドックス触媒。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009506386A JP5126856B2 (ja) | 2007-03-28 | 2008-03-28 | 含窒素レドックス触媒 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007084896 | 2007-03-28 | ||
JP2007-084896 | 2007-03-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008117871A1 true WO2008117871A1 (ja) | 2008-10-02 |
Family
ID=39788602
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/056164 WO2008117871A1 (ja) | 2007-03-28 | 2008-03-28 | 含窒素レドックス触媒 |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP5126856B2 (ja) |
WO (1) | WO2008117871A1 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009116353A1 (ja) * | 2008-03-18 | 2009-09-24 | コニカミノルタホールディングス株式会社 | 電気化学的表示素子 |
WO2012070509A1 (ja) * | 2010-11-24 | 2012-05-31 | 国立大学法人長崎大学 | 含窒素複素環の製造方法 |
CN102498112A (zh) * | 2009-09-17 | 2012-06-13 | 沃泰克斯药物股份有限公司 | 制备氮杂二环化合物的方法 |
WO2013118118A1 (en) | 2012-02-06 | 2013-08-15 | Technion Research And Development Foundation Ltd. | Alpha-hydrogen substituted nitroxyls and derivatives thereof as catalysts |
WO2013191287A1 (ja) * | 2012-06-22 | 2013-12-27 | 国立大学法人東北大学 | アルコール酸化触媒及びそれを用いたアルコール酸化方法 |
CN111217809A (zh) * | 2018-11-27 | 2020-06-02 | 江苏奥赛康药业有限公司 | 一类手性含氮双烯配体及其制备方法和应用 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105777538B (zh) * | 2016-04-11 | 2018-07-10 | 安徽金泉生物科技股份有限公司 | 一种医药中间体苄基酯类化合物的合成方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1112776A (ja) * | 1997-06-25 | 1999-01-19 | Asahi Glass Co Ltd | 修飾電極および該修飾電極を用いた電解酸化方法 |
-
2008
- 2008-03-28 JP JP2009506386A patent/JP5126856B2/ja not_active Expired - Fee Related
- 2008-03-28 WO PCT/JP2008/056164 patent/WO2008117871A1/ja active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1112776A (ja) * | 1997-06-25 | 1999-01-19 | Asahi Glass Co Ltd | 修飾電極および該修飾電極を用いた電解酸化方法 |
Non-Patent Citations (10)
Title |
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ANELLI P.L. ET AL.: "Fast and Selective Oxidation of Primary Alcohols to Aldehydes or to Carboxylic Acids and of Secondary Alcohols to Ketones Mediated by Oxoammonium Salts under Two-Phase Conditions", THE JOURNAL OF ORGANIC CHEMISTRY, vol. 52, no. 12, 12 June 1987 (1987-06-12), pages 2559 - 2562, XP000567759 * |
ARIPOVA S.F. ET AL.: "Convoline - a new alkaloid from Convolvulus krauseanus", KHIMIYA PRIRODNYKH SOEDINENII, no. 6, 1983, pages 749 - 751 * |
BRODWELL F.G. ET AL.: "Solvent Effects on Homolytic Bond Dissociation Energies of Hydroxylic Acids", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 118, no. 44, 1996, pages 10819 - 10823 * |
CHOW Y.L. ET AL.: "The transannular electrophilic reaction of alkenyl nitroso compounds and the stereochemistry of nitrosyl chloride addition", CANADIAN JOURNAL OF CHEMISTRY, vol. 57, no. 22, 15 November 1979 (1979-11-15), pages 2923 - 2935 * |
KEANAN J.F.W. ET AL.: "Stereospecific Synthesis of Difunctionalized 2,5-Disubstituted cis-2,5-Dimethylpyrrolidine (Azethoxyl)Nitroxides by Oxidative Cleavage of Protected 8-Azabicyclo [3.2.1]octane Precursors", THE JOURNAL OF ORGANIC CHEMISTRY, vol. 50, no. 13, 28 June 1985 (1985-06-28), pages 2346 - 2351 * |
MALATESTA V. ET AL.: "Protonated Nitroxide Radicals", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 95, no. 19, 19 September 1973 (1973-09-19), pages 6404 - 6407 * |
MENDENHALL G.D. ET AL.: "Reactions of Bicyclic Nitroxides Involving Reduction of the NO Group", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 95, no. 19, 19 September 1973 (1973-09-19), pages 6395 - 6400 * |
NELSEN S.F. ET AL.: "Bredt's Rule Kinetically Stabilized Nitrogen-Centered Radical Cations and Radicals in the 9-Azabicyclo[3.3.1]nonyl System", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 102, no. 2, 16 January 1980 (1980-01-16), pages 702 - 711 * |
SEMMELHACK M.F. ET AL.: "Nitroxyl-Mediated Electrooxidation of Alcohols to Aldehydes and Ketones", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 105, no. 13, 29 June 1983 (1983-06-29), pages 4492 - 4494, XP001182269 * |
SHIBUYA M. ET AL.: "2-Azaadamantane N-Oxyl (AZADO) and 1-Me-AZADO: Highly Efficient Organocatalysts for Oxidation of Alcohols", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 128, no. 26, 14 June 2006 (2006-06-14), pages 8412 - 8413, XP007915500, DOI: doi:10.1021/ja0620336 * |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5177219B2 (ja) * | 2008-03-18 | 2013-04-03 | コニカミノルタホールディングス株式会社 | 電気化学的表示素子 |
US8437067B2 (en) | 2008-03-18 | 2013-05-07 | Konica Minolta Holdings, Inc. | Electrochemical display element |
WO2009116353A1 (ja) * | 2008-03-18 | 2009-09-24 | コニカミノルタホールディングス株式会社 | 電気化学的表示素子 |
CN102498112B (zh) * | 2009-09-17 | 2015-05-20 | 沃泰克斯药物股份有限公司 | 制备氮杂二环化合物的方法 |
CN102498112A (zh) * | 2009-09-17 | 2012-06-13 | 沃泰克斯药物股份有限公司 | 制备氮杂二环化合物的方法 |
JP2013505259A (ja) * | 2009-09-17 | 2013-02-14 | バーテックス ファーマシューティカルズ インコーポレイテッド | アザ二環式化合物を調製するプロセス |
WO2012070509A1 (ja) * | 2010-11-24 | 2012-05-31 | 国立大学法人長崎大学 | 含窒素複素環の製造方法 |
WO2013118118A1 (en) | 2012-02-06 | 2013-08-15 | Technion Research And Development Foundation Ltd. | Alpha-hydrogen substituted nitroxyls and derivatives thereof as catalysts |
US9475774B2 (en) | 2012-02-06 | 2016-10-25 | Technion Research And Development Foundation Ltd. | Alpha-hydrogen substituted nitroxyls and derivatives thereof as catalysts |
WO2013191287A1 (ja) * | 2012-06-22 | 2013-12-27 | 国立大学法人東北大学 | アルコール酸化触媒及びそれを用いたアルコール酸化方法 |
JPWO2013191287A1 (ja) * | 2012-06-22 | 2016-05-26 | 国立大学法人東北大学 | アルコール酸化触媒及びそれを用いたアルコール酸化方法 |
CN111217809A (zh) * | 2018-11-27 | 2020-06-02 | 江苏奥赛康药业有限公司 | 一类手性含氮双烯配体及其制备方法和应用 |
CN111217809B (zh) * | 2018-11-27 | 2021-06-08 | 江苏奥赛康药业有限公司 | 一类手性含氮双烯配体及其制备方法和应用 |
Also Published As
Publication number | Publication date |
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JPWO2008117871A1 (ja) | 2010-07-15 |
JP5126856B2 (ja) | 2013-01-23 |
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