WO2008117871A1 - 含窒素レドックス触媒 - Google Patents

含窒素レドックス触媒 Download PDF

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Publication number
WO2008117871A1
WO2008117871A1 PCT/JP2008/056164 JP2008056164W WO2008117871A1 WO 2008117871 A1 WO2008117871 A1 WO 2008117871A1 JP 2008056164 W JP2008056164 W JP 2008056164W WO 2008117871 A1 WO2008117871 A1 WO 2008117871A1
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WO
WIPO (PCT)
Prior art keywords
optionally substituted
redox catalyst
hydrogen atom
nitrogen
hydrocarbon group
Prior art date
Application number
PCT/JP2008/056164
Other languages
English (en)
French (fr)
Inventor
Yosuke Demizu
Osamu Onomura
Yoshihiro Matsumura
Original Assignee
Nagasaki University
Matsumura, Mie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nagasaki University, Matsumura, Mie filed Critical Nagasaki University
Priority to JP2009506386A priority Critical patent/JP5126856B2/ja
Publication of WO2008117871A1 publication Critical patent/WO2008117871A1/ja

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/56Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by isomerisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D451/00Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof
    • C07D451/02Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof containing not further condensed 8-azabicyclo [3.2.1] octane or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane; Cyclic acetals thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D451/00Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof
    • C07D451/02Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof containing not further condensed 8-azabicyclo [3.2.1] octane or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane; Cyclic acetals thereof
    • C07D451/04Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof containing not further condensed 8-azabicyclo [3.2.1] octane or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane; Cyclic acetals thereof with hetero atoms directly attached in position 3 of the 8-azabicyclo [3.2.1] octane or in position 7 of the 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring system
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D451/00Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof
    • C07D451/14Heterocyclic compounds containing 8-azabicyclo [3.2.1] octane, 9-azabicyclo [3.3.1] nonane, or 3-oxa-9-azatricyclo [3.3.1.0<2,4>] nonane ring systems, e.g. tropane or granatane alkaloids, scopolamine; Cyclic acetals thereof containing 9-azabicyclo [3.3.1] nonane ring systems, e.g. granatane, 2-aza-adamantane; Cyclic acetals thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D453/00Heterocyclic compounds containing quinuclidine or iso-quinuclidine ring systems, e.g. quinine alkaloids
    • C07D453/06Heterocyclic compounds containing quinuclidine or iso-quinuclidine ring systems, e.g. quinine alkaloids containing isoquinuclidine ring systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D487/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/08Bridged systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07Optical isomers

Abstract

 式(Ⅰ):(式中、  X1およびX2はそれぞれ、水素原子、ハロゲン原子、置換されていてもよい水酸基または置換されていてもよい炭化水素基を示し、あるいはX1およびX2は、一緒になってオキソ基を形成してもよく、  Yは、結合または酸素原子を示し、  R1は、水素原子、置換基を有する水酸基または置換されていてもよい炭化水素基を示し、  R2およびR3は、水素原子または置換されていてもよい炭化水素基を示し、  mは、0ないし2の整数を示し、  nは、1または2の整数を示す。) で表される化合物もしくはその誘導体を含む、レドックス触媒。
PCT/JP2008/056164 2007-03-28 2008-03-28 含窒素レドックス触媒 WO2008117871A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009506386A JP5126856B2 (ja) 2007-03-28 2008-03-28 含窒素レドックス触媒

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007084896 2007-03-28
JP2007-084896 2007-03-28

Publications (1)

Publication Number Publication Date
WO2008117871A1 true WO2008117871A1 (ja) 2008-10-02

Family

ID=39788602

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/056164 WO2008117871A1 (ja) 2007-03-28 2008-03-28 含窒素レドックス触媒

Country Status (2)

Country Link
JP (1) JP5126856B2 (ja)
WO (1) WO2008117871A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009116353A1 (ja) * 2008-03-18 2009-09-24 コニカミノルタホールディングス株式会社 電気化学的表示素子
WO2012070509A1 (ja) * 2010-11-24 2012-05-31 国立大学法人長崎大学 含窒素複素環の製造方法
CN102498112A (zh) * 2009-09-17 2012-06-13 沃泰克斯药物股份有限公司 制备氮杂二环化合物的方法
WO2013118118A1 (en) 2012-02-06 2013-08-15 Technion Research And Development Foundation Ltd. Alpha-hydrogen substituted nitroxyls and derivatives thereof as catalysts
WO2013191287A1 (ja) * 2012-06-22 2013-12-27 国立大学法人東北大学 アルコール酸化触媒及びそれを用いたアルコール酸化方法
CN111217809A (zh) * 2018-11-27 2020-06-02 江苏奥赛康药业有限公司 一类手性含氮双烯配体及其制备方法和应用

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105777538B (zh) * 2016-04-11 2018-07-10 安徽金泉生物科技股份有限公司 一种医药中间体苄基酯类化合物的合成方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1112776A (ja) * 1997-06-25 1999-01-19 Asahi Glass Co Ltd 修飾電極および該修飾電極を用いた電解酸化方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1112776A (ja) * 1997-06-25 1999-01-19 Asahi Glass Co Ltd 修飾電極および該修飾電極を用いた電解酸化方法

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ANELLI P.L. ET AL.: "Fast and Selective Oxidation of Primary Alcohols to Aldehydes or to Carboxylic Acids and of Secondary Alcohols to Ketones Mediated by Oxoammonium Salts under Two-Phase Conditions", THE JOURNAL OF ORGANIC CHEMISTRY, vol. 52, no. 12, 12 June 1987 (1987-06-12), pages 2559 - 2562, XP000567759 *
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5177219B2 (ja) * 2008-03-18 2013-04-03 コニカミノルタホールディングス株式会社 電気化学的表示素子
US8437067B2 (en) 2008-03-18 2013-05-07 Konica Minolta Holdings, Inc. Electrochemical display element
WO2009116353A1 (ja) * 2008-03-18 2009-09-24 コニカミノルタホールディングス株式会社 電気化学的表示素子
CN102498112B (zh) * 2009-09-17 2015-05-20 沃泰克斯药物股份有限公司 制备氮杂二环化合物的方法
CN102498112A (zh) * 2009-09-17 2012-06-13 沃泰克斯药物股份有限公司 制备氮杂二环化合物的方法
JP2013505259A (ja) * 2009-09-17 2013-02-14 バーテックス ファーマシューティカルズ インコーポレイテッド アザ二環式化合物を調製するプロセス
WO2012070509A1 (ja) * 2010-11-24 2012-05-31 国立大学法人長崎大学 含窒素複素環の製造方法
WO2013118118A1 (en) 2012-02-06 2013-08-15 Technion Research And Development Foundation Ltd. Alpha-hydrogen substituted nitroxyls and derivatives thereof as catalysts
US9475774B2 (en) 2012-02-06 2016-10-25 Technion Research And Development Foundation Ltd. Alpha-hydrogen substituted nitroxyls and derivatives thereof as catalysts
WO2013191287A1 (ja) * 2012-06-22 2013-12-27 国立大学法人東北大学 アルコール酸化触媒及びそれを用いたアルコール酸化方法
JPWO2013191287A1 (ja) * 2012-06-22 2016-05-26 国立大学法人東北大学 アルコール酸化触媒及びそれを用いたアルコール酸化方法
CN111217809A (zh) * 2018-11-27 2020-06-02 江苏奥赛康药业有限公司 一类手性含氮双烯配体及其制备方法和应用
CN111217809B (zh) * 2018-11-27 2021-06-08 江苏奥赛康药业有限公司 一类手性含氮双烯配体及其制备方法和应用

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JPWO2008117871A1 (ja) 2010-07-15
JP5126856B2 (ja) 2013-01-23

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