WO2008018186A1 - Composition d'adoucissant liquide - Google Patents

Composition d'adoucissant liquide Download PDF

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Publication number
WO2008018186A1
WO2008018186A1 PCT/JP2007/050112 JP2007050112W WO2008018186A1 WO 2008018186 A1 WO2008018186 A1 WO 2008018186A1 JP 2007050112 W JP2007050112 W JP 2007050112W WO 2008018186 A1 WO2008018186 A1 WO 2008018186A1
Authority
WO
WIPO (PCT)
Prior art keywords
silicone
liquid softener
polymer compound
softener composition
water
Prior art date
Application number
PCT/JP2007/050112
Other languages
English (en)
Japanese (ja)
Inventor
Hiroshi Akimoto
Takehiko Miyahara
Kiyoshi Mizuno
Noriko Takahashi
Original Assignee
Lion Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2006214569A external-priority patent/JP5328084B2/ja
Application filed by Lion Corporation filed Critical Lion Corporation
Priority to KR1020097002263A priority Critical patent/KR101358540B1/ko
Publication of WO2008018186A1 publication Critical patent/WO2008018186A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3738—Alkoxylated silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55—Epoxy resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61—Polyamines polyimines

Definitions

  • the present invention when clothes are air-dried, especially when they are worn and washed repeatedly for a long time, even when clothes are air-dried, or when they are air-dried under high humidity conditions such as in the rainy season, it is possible to provide a liquid softener composition that can eliminate unpleasant odors such as “freshly dried”, and that makes it difficult to leave the scent of clothes after drying.
  • the liquid softening agent composition of the present invention has a transparent or translucent appearance, and can exhibit excellent flexibility for textiles such as clothing. In addition, there is little irritation to the skin.
  • the component (A) of the present invention is a silicone polymer compound.
  • the silicone polymer compound preferably has a viscosity of 10 to 100000000 mm 2 / s (B-type viscometer, 25 ° C.). There is no particular limitation as long as flexibility and smoothness can be imparted when adsorbed on a fiber product.
  • Silicone polymer compounds generally used for fiber treatment include dimethyl silicone, polyether-modified silicone, methylphenol silicone, alkyl-modified silicone, higher fatty acid-modified silicone, methylhydrosilicone silicone, and fluorine-modifying silicone. Examples thereof include silicone, epoxy-modified silicone, carboxy-modified silicone, carbinol-modified silicone, and amino-modified silicone, and one of these can be used alone or as a mixture of two or more.
  • the molecular structure of this silicone polymer compound is linear or branched or crosslinked. May be.
  • the modified silicone polymer compound may be modified with one kind of organic functional group, or may be modified with two or more kinds of organic functional groups.
  • the silicone compound can be used as an oil or an emulsion dispersed with any emulsifier.
  • a silicone polymer compound containing no amino group is preferable.
  • dimethylsilicone which is preferably nonionic, is preferred because it enhances the effect of adsorbing the silicone polymer compound of component (A) on the fiber by component (B), which will be described later, and increases flexibility and slipping power.
  • Carbinol-modified silicone, epoxy-modified silicone, polyether-modified silicone, dimethyl silicone and polyether-modified silicone are more preferred.
  • particularly preferable silicone polymer compounds include polyether-modified silicones from the viewpoint of imparting flexibility and making the liquid softener composition transparent or translucent, thereby increasing commercial value.
  • the term “transparent” means that when a glass cell having an optical path length of 10 mm is used and ion-exchanged water is added to the control side cell, the light transmittance at a wavelength of 660 nm is 95% or more.
  • the term “translucent” means that the transmittance is 30% or more and less than 95%.
  • the silicone is suitable for obtaining a transparent liquid softening agent composition with less flexibility and good flexibility as compared with dimethyl silicone having no polyether group.
  • Preferable polyether-modified silicone includes a copolymer of alkyl (1 to 3 carbon atoms) siloxane and polyoxyalkylene (preferably having 2 to 5 carbon atoms of an alkylene group). Of these, dimethylsiloxane and polyoxyalkylene (polyoxyethylene, polyoxypropylene,
  • Coalescence is preferred.
  • Examples of such compounds include compounds represented by the following general formula (I) or ( ⁇ ).
  • M, N, a and b are average degrees of polymerization, R represents hydrogen or an alkyl group.
  • M is 10 to: LOOOO, preferably ⁇ is 50 to: LOOO, More preferably ⁇ is 100 to 300, N is 1 to 1000, preferably 5 to 300, more preferably 5 to 100, and M> N, ai or 2 to 100, preferably ⁇ or 5 ⁇ 50, more preferably ⁇ or 5 to 20, bi or 0 to 50, preferably ⁇ or 0 to 10.
  • R is more preferably hydrogen or an alkyl group having 1 to 4 carbon atoms.
  • the polyether-modified silicone represented by the above general formula (I) generally has an organohydrogenpolysiloxane having a Si— group and a carbon-carbon double bond such as polyoxyalkylene aryl ether. It can be produced by addition reaction with a terminal polyoxyalkylene alkyl ether.
  • A is from 5 to: L0000
  • B is from 2 to: L0000 S is preferable
  • h is from 2 to 100
  • i is preferably from 0 to 50.
  • R is preferably an alkyl group having 1 to 5 carbon atoms.
  • R ′ is preferably hydrogen or an alkyl group having 1 to 4 carbon atoms.
  • the weight average molecular weight of the block copolymer represented by the formula ( ⁇ ), the softness, and the smoothness are preferably 15,000 to 100,000,000.
  • SILWET FZ— 2104 SILWET FZ— 2120, SILWET FZ— 2161, SI LWET FZ — 2162, SILWET FZ— 2164, SILWET FZ— 2171, SILWET FZ2222, ABN SILWET FZ— Fl— 009— 01, ABN SILWET FZ— Fl— O 09— 02, ABN SILWET FZ— Fl— 009— 03, ABN SILWET FZ — Fl— O 09— 05, ABN SILWET FZ— Fl— 009— 09, ABN SILWET FZ— Fl— O 09— 11, ABN SILWET FZ— Fl— 009— 13, ABN SILWET FZ— Fl— O 09— 54,
  • the component (B) of the present invention is transparent when the water-soluble polymer compound lg is added to 100 g of water at 25 ° C. It has the effect of adsorbing compounds to fibers.
  • the water-soluble polymer compound having a cationic property a compound having a cationic property when dissolved in water can be used.
  • the water-soluble polymer compound having a cationic property includes an amino group, an amine group, a quaternary ammonia.
  • a water-soluble polymer compound having one or more cationic groups is also preferred.
  • Low molecular weight force Compared to thionic surfactants, the effect of adsorbing the fragrance component on the fiber surface is high, which is preferable.
  • the water-soluble polymer compound having a cationic property as component (B) preferably has a degree of cationization of 0.1% or more, for example 0.1 to 35, particularly 1.5% or more.
  • a good example is 2. 0-15.
  • the degree of cation is a polymer of a cationic monomer, a copolymer of a cationic monomer and a non-on monomer, and a part of a non-on polymer.
  • the polymer compound is a copolymer of a cationic monomer and a ionic monomer, and a cationic monomer.
  • a copolymer of an ionic monomer and a nonionic monomer it is defined as a value calculated by the following formula (2).
  • the Z-ion group of Z includes a carboxyl group and a sulfonic acid group contained in a monomer unit in a polymer chain. Specifically, it is a carboxylic acid in acrylic acid, etc. Does not include counter ion of cationic group.
  • MERQUAT 280 represented by the following formula (III):
  • NALCO made by NALCO
  • the degree of cationization of the polymer of the non-ionic monomer and the polymer of the cation monomer becomes zero.
  • the water-soluble polymer of component (B) preferably has a weight average molecular weight of 1,000 to 5,000,000 as measured by gel permeation chromatography using polyethylene glycol as a standard substance. More preferably, it is 3, 000-1, 000, 000, and still more preferably 5,000-500, 000. As a result, it is possible to effectively prevent odors, and it is possible to suppress the increase in viscosity and to improve the usability.
  • component (B) examples include MERQUAT 100 (manufactured by NALCO), Ade Kachi-Ace PD-50 (Asahi Denka Kogyo Co., Ltd.), Daidoru EC-004, Daidoru HEC, Daidoru EC (Daido Polymers of salt dimethyl diallyl ammonium such as Kasei Kogyo Co., Ltd., dimethyl chloride ammonium acrylamide such as MERQUAT 550, JL5 (NALCO), etc.
  • c and d each represent an average degree of polymerization and are each preferably in the range of 6 to 30000, more preferably in the range of 20 to 6000, and still more preferably in the range of 30 to 3000.
  • Examples of such polymers are MERQUAT 100 (manufactured by NALCO), Ade force Katsioace PD-50 (manufactured by Asahi Denki Kogyo Co., Ltd.), Daidoru EC-004, Daidoru HEC And Dydoll EC (manufactured by Daido Kasei Kogyo Co., Ltd.).
  • the above water-soluble polymer compound having a cationic property may be used alone or as a mixture.
  • the blending amount of the component (B) is not particularly limited, but it is preferable that the range is not imparted with rigidity to the fiber product.For example, on the basis of the total mass of the composition, 0.1 to 30% by mass is more preferable, and 0.5 to 15% by mass is more preferable.
  • the blending amount of component (B) in such a range, the effect of promoting the adsorption of the silicone polymer compound to the fiber product surface will be enhanced, and the effects such as flexibility and smoothness will be sufficient. Possible and In addition, the increase in viscosity can be suppressed and the usability can be improved.
  • the mass ratio of the component (A) to the component (B) is in the range of 99: 1 to 50:50. Preferably it is 95: 5-60: 40, More preferably, it is the range of 90: 10-70: 30.
  • the ratio is within such a range, functions having excellent texture such as flexibility and smoothness can be obtained for clothing such as polyester and cotton.
  • the adsorptivity of silicone to fibers can be improved.
  • Component (C) of the present invention is a fragrance composition containing a fragrance component having a boiling point of 250 ° C or lower.
  • the boiling point of fragrance components generally ranges from about 20 ° C to about 500 ° C, but when a boiling point of 250 ° C or less is used, residual fragrance is suppressed while suppressing unpleasant room drying odor.
  • a fragrance composition having low properties is obtained.
  • a fragrance composition containing one or more kinds selected from the group power consisting of citronellol, dihydromilucenol, tetrahydral linalool, beta-nonone, gera-ol and limonene is preferable.
  • these perfume ingredients commercially available ones can be used.
  • the present invention further includes (D) liquids such as antibacterial agents, deodorant bases, nonionic surfactants, water, water-soluble solvents, dyes, antioxidants, antifoaming agents, inorganic salts, and other additives.
  • Ingredients usually blended in the softener composition can be contained within a range not impairing the effects of the present invention.
  • the temperature from room temperature to the solvent reflux temperature is 0.5 to Soak for 24 hours, preferably 1-10 hours.
  • R 1 is an alkyl or alkyl group having 10 to 18 carbon atoms, preferably 12 to 18 carbon atoms
  • R 2 is an alkylene group having 2 or 3 carbon atoms, preferably an ethylene group.
  • R 1 has the same meaning as described above, and r is the average number of moles added, and is a number from 2 to 50, preferably 5 to 30.
  • R 1 has the same meaning as described above, s and t are the average number of moles added, s is 2 to 40, preferably Preferably, it is a number from 5 to 30, and t is a number from 1 to 20, preferably from 1 to 10.
  • s is 2 to 40, preferably Preferably, it is a number from 5 to 30, and t is a number from 1 to 20, preferably from 1 to 10.
  • the storage stability is further improved, which is preferable.
  • the blending amount is preferably 0.1 to 20% by mass based on the total mass of the composition, particularly preferably 0.5 to 15% by mass, and more preferably 1 to LO mass%.
  • water ion-exchanged water or distilled water, which is preferably water from which hardness components such as calcium and magnesium present in trace amounts and heavy metals such as iron are removed, can be used.
  • Water-soluble solvents that can contain a small amount of chlorine for the purpose of sterilizing or sterilizing water include ethanol, isopropanol, glycerin, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, hexylene glycol, and polyoxy It is preferable to blend a solvent component selected from ethylene vinyl ether and a water-soluble solvent represented by the following general formula (X).
  • R 3 is an alkyl group or a alkenyl group having 1 to 8, preferably 2 to 6 carbon atoms.
  • Y and z are the average number of moles attached, and y is 2 to 50, preferably Is a number between 2 and 30, z is a number between 0 and 50, and preferably is a number between 20 and 20).
  • preferred examples include ethanol, ethylene glycol, butyl carbitol, propylene glycol, diethylene glycolenomonopropylene glycolenomonobutylino ether H (C H O) (C H O) H] and the like.
  • the blending amount of these components is preferably 0.1 to 30% by mass, more preferably 2 to 20% by mass, more preferably 5 to 15% by mass, based on the total mass of the composition. It can
  • the dye is not particularly limited, but may be one or more of water-soluble dyes selected from acid dyes and direct dyes, even though water-soluble dyes are preferred because of their ease of addition. Like That's right. Specific examples of dyes that can be added include, for example, the Dye Handbook (edited by the Society of Synthetic Organic Chemistry, issued July 20, 1970, Maruzen Co., Ltd.), Dye Note 22nd Edition (Shokusha Co., Ltd.), Legal Dye Handbook (Edited by the Japan Cosmetic Industry Association, published on November 28, 1988, Yakuho Nippo Co., Ltd.), etc. are incorporated herein by reference.
  • the combined amount of the dye is preferably 0.01 to 50 ppm, more preferably 0.1 to 30 ppm, based on the total mass of the composition.
  • Isopropyl acid 1-hydroxyethylidene 1,1-diphosphonic acid (ethidronic acid), 4,5 dihydroxy —m-benzenesulfonic acid / sodium salt, dimethoxyphenol, catechol, methoxyphenol, carotenoids, furans, amino acids, etc. Can be mentioned.
  • the blending amount of the antioxidant is preferably in the range of 0.01 to 1% by mass based on the total amount of the composition.
  • the antifoaming agent examples include silicone-based antifoaming agents such as dimethyl silicone containing fine powder such as silica, alcohol-based antifoaming agents, ester-based antifoaming agents, mineral oil-based antifoaming agents, and vegetable oil-based antifoaming agents.
  • Antifoaming agents, synthetic oil-based antifoaming agents, and the like can be mentioned.
  • Silicone-based antifoaming agents are also preferable because they suppress foaming during measurement of the softening agent and improve the meterability.
  • Silicone defoamer Examples include oil-type antifoaming agents, compound-type antifoaming agents, self-emulsifying antifoaming agents, emulsion-type antifoaming agents, powder-type antifoaming agents, and solid-type antifoaming agents. ⁇ Type defoamer and emulsion type defoamer are preferred.
  • the blending amount of the antifoaming agent is not particularly limited, but can be 0.1 ppm to 1% by mass, more preferably 1 ppm to 0.05% by mass, based on the total mass of the composition. be able to.
  • the liquid softener composition of the present invention can contain an inorganic salt.
  • Inorganic salt is selected from salt-sodium, salt-potassium, salt-calcium and salt-magnesium strength.
  • LOOOppm preferably It is preferable to add 10 to 500 ppm.
  • the raw material of the composition may contain sodium salt and potassium salt, but the inorganic salt mixed in by these is not subject to the above restriction.
  • additives include cationic surfactants, partially esterified products of hexanoic acid and glycerin or pentaerythritol, sodium chloride, ammonium chloride, calcium chloride
  • Water-soluble salts such as magnesium chloride and potassium chloride, oils such as liquid paraffin and higher alcohols, urea, hydrocarbons, nonionic cellulose derivatives, UV screening agents, fluorescent brighteners, pH adjusters described later, etc. .
  • the inclusion of the cationic polymer compound (B) Less than the amount! /, It is better to mix in the amount.
  • additives and the like used in ordinary household finishes can be used as long as the effects of the present invention are not hindered.
  • additives include cationic surfactants, partially esterified products of hexanoic acid and glycerin or pentaerythritol, water-soluble salts such as ammonium chloride, liquid paraffin, and higher grades.
  • oils such as alcohol, urea, hydrocarbons, nonionic cellulose derivatives, ultraviolet absorbers, fluorescent brighteners, and pH adjusters described later.
  • the cationic polymer compound of component (B) is lower than the content of bismuth!
  • the pH of the liquid softening agent composition of the present invention is not particularly limited, but is preferably in the range of 3-8, more preferably in the range of 4-6. It is diluted in the rinse solution and enters the neutral zone.
  • the viscosity of the liquid softening agent composition of the present invention is not particularly limited, but is preferably 5 to 50 mPa's (B type viscometer (Piscometer (TOKIMEC), 25 ° C)). In this case, it is preferable because the usability is good.
  • the liquid softener composition of the present invention is preferably used in such an amount that the concentration of the component (A) is 5 ppm to 5000 ppm with respect to the total amount of water used when the textile product is actually subjected to soft finishing. More preferably, it is used in an amount such that it is 10 ppm to 300 ppm, and the concentration of component (B) is preferably used in such an amount that it is 0.5 ppm to 100 ppm. Is used in an amount of 3 ppm to 30 ppm.
  • BBD Skin shirt worn for more than 1 year at home is cut in half, and commercial detergent “Top” (manufactured by Lion Co., Ltd., ingredients: surfactant (sodium alpha-olefin sulfo fatty acid ester, sodium fatty acid, direct (Chain alkylbenzene, polyoxyethylene alkyl ether), water softener, alkali agent, enzyme, fluorescent whitening agent) for 5 minutes (detergent is used in standard amount, bath ratio 30 times, using tap water at 25 ° C) ), And rinsed twice for 3 minutes.
  • surfactant sodium alpha-olefin sulfo fatty acid ester, sodium fatty acid, direct (Chain alkylbenzene, polyoxyethylene alkyl ether), water softener, alkali agent, enzyme, fluorescent whitening agent
  • Average point is 1.1 to 2.0, ⁇ , 0.1 to 1.0, ⁇ , -1.0, 0 to 0, ⁇ , 2.00 to 1 1.1, and X to half IJ decided.
  • the control has a clear odor, less! / ⁇
  • Half-finished new skin shirt (BVD), commercial detergent “Top” (manufactured by Lion Co., Ltd.), ingredients: surfactant (sodium alpha-olefin sulfofatty acid ester, sodium fatty acid, linear alkylbenzene, polyoxyethylene alkyl) Ether), water softener, al Washed with potash, enzyme, fluorescent brightening agent) for 5 minutes (standard amount of detergent used, 30 times bath ratio, using 25 ° C water) and rinsed twice for 3 minutes.
  • 10 g of the liquid softener composition shown in the table was added to 30 liters of water, and the clothing was softened (30 times the bath ratio, using tap water at 25 ° C, 3 minutes). Then, after dehydrating and drying for 24 hours at 40% humidity and 25 ° C, the remaining fragrance was judged by 10 panelists according to the following criteria, and the average score was obtained.

Abstract

La présente invention concerne une composition d'adoucissant liquide qui peut empêcher la formation de mauvaises odeurs lors du lavage en machine et dont le parfum est moins susceptible de rester sur les tissus. La composition d'adoucissant liquide comprend : (A) un composé polymère siliconé ; (B) un composé polymère hydrosoluble cationique ; et (C) une composition de parfum comprenant un composant de parfum ayant une température d'ébullition inférieure ou égale à 250 °C.
PCT/JP2007/050112 2006-08-07 2007-01-10 Composition d'adoucissant liquide WO2008018186A1 (fr)

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KR1020097002263A KR101358540B1 (ko) 2006-08-07 2007-01-10 액체 유연제 조성물

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JP2006-214569 2006-08-07
JP2006214569A JP5328084B2 (ja) 2005-08-05 2006-08-07 液体柔軟剤組成物

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WO2008018186A1 true WO2008018186A1 (fr) 2008-02-14

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021086364A1 (fr) * 2019-10-31 2021-05-06 Colgate-Palmolive Company Compositions d'entretien de tissus présentant une robustesse microbiologique améliorée et procédés associés

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY171472A (en) * 2012-06-29 2019-10-15 Lion Corp Liquid softener composition
KR101880558B1 (ko) * 2016-06-10 2018-07-23 (주)엔바이오 천연친환경, 고내구성, 방오성, 피부무자극성의 항균대전방지 기능 구현을 위한 섬유가공제
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