WO2007074851A1 - Baton cosmetique - Google Patents

Baton cosmetique Download PDF

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Publication number
WO2007074851A1
WO2007074851A1 PCT/JP2006/326005 JP2006326005W WO2007074851A1 WO 2007074851 A1 WO2007074851 A1 WO 2007074851A1 JP 2006326005 W JP2006326005 W JP 2006326005W WO 2007074851 A1 WO2007074851 A1 WO 2007074851A1
Authority
WO
WIPO (PCT)
Prior art keywords
pentaerythritol
wax
ester
cosmetic
mass
Prior art date
Application number
PCT/JP2006/326005
Other languages
English (en)
Japanese (ja)
Inventor
Yuuki Ogura
Original Assignee
Shiseido Company, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Company, Ltd. filed Critical Shiseido Company, Ltd.
Priority to JP2007551999A priority Critical patent/JPWO2007074851A1/ja
Publication of WO2007074851A1 publication Critical patent/WO2007074851A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/0229—Sticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair

Definitions

  • the present invention relates to a sticky cosmetic, and in particular, the lipstick cosmetic and the eye shadow cosmetic that have improved gloss when used, and that have good moldability and are not broken when used. It relates to cosmetics such as sticks.
  • cosmetics containing pentaerythritol derivative oils for example, cosmetics containing dipentaerythritol and esters of linear fatty acids (for example, Patent text 1), cosmetics containing esters obtained by reacting dipentaerythritol with straight chain fatty acids and dibasic acids (for example, Patent Document 2), tetra-2-ethylhexanoic acid pentaerythritol ester Contains cosmetics (for example, Patent Document 3), cosmetics formulated with an ester of pentaerythritol and a fatty acid and methoxy cinnamate (for example, Patent Document 4), and further contains a pentaerythritol derivative having a specific structure. Cosmetics (for example, Patent Document 5) are known.
  • Patent Document 1 Japanese Patent Laid-Open No. 55-85509
  • Patent Document 2 Japanese Patent Publication No. 61-7165
  • Patent Document 3 Japanese Patent Laid-Open No. 06-87730
  • Patent Document 4 Japanese Patent Laid-Open No. 10-45552
  • Patent Document 5 Japanese Patent Laid-Open No. 5-85981
  • an object of the present invention is to provide a sticky cosmetic that has a smooth, easy-to-stick odor that is smooth and smooth when applied, and that is glossy and has good moldability.
  • the present invention provides:
  • the IOB as a whole of the oil is 0.3 or more
  • Pentaerythritol full ester power The pentaerythritol represented by the following general formula (1) It also works with benzoate ester of sitolitol and 2-ethylhexanoic acid tetraester of pentaerythritol,
  • Benzoic acid ester power of the pentaerythritol is 20 to 72 mass% in all pentaerythritol fluoresters
  • the present invention provides a sticky cosmetic composition characterized by the above.
  • R 2 represents a hydrogen atom, a linear or branched fatty acid residue having 1 to 24 carbon atoms, or a benzoic acid residue.
  • R 1 of the ester of pentaerythritol and benzoic acid represented by the general formula (1) is a 2-ethylhexanoic acid residue, and R 2 has 1 to 24 carbon atoms.
  • the above stick-like cosmetic is characterized in that it is a linear or branched fatty acid residue or benzoic acid residue.
  • the present invention provides the above-mentioned sticky cosmetic, wherein the wax contains one or more selected from polyethylene wax, paraffin wax, and candelillaro force.
  • the present invention provides the above-mentioned sticky cosmetic composition characterized in that the oil component does not contain castor oil or contains 5% by mass or less.
  • the present invention provides the above-described stick-like cosmetic, wherein the stick-like cosmetic is a lipstick.
  • a stick-like cosmetic material which is excellent in gloss on the skin, which is smooth and easily applied when applied, and which has no odor change over time, and which has excellent moldability. can do.
  • the pentaerythritol full ester compounded in the sticky cosmetic composition of the present invention comprises pentaerythritol benzoate represented by the general formula (1), pentaerythritol 2-ethylhexanoic acid tetraester, It can also be a force.
  • R 1 is a 2-ethyl hexanoic acid residue having 8 carbon atoms
  • R 2 is an ester having a benzoic acid residue.
  • Those represented by the following formula (2) are preferred.
  • R 1 is a 2-ethylhexanoic acid residue having 8 carbon atoms
  • R 2 is a linear or branched fatty acid residue having 1 to 24 carbon atoms, particularly an ester of a behenic acid residue. Those are also preferable, but are not necessarily limited thereto.
  • the ester of this benzoic acid residue is obtained by reacting 1 mol of pentaerythritol with 3 mol of benzoic acid and 1 mol of 2-ethylhexanoic acid, followed by removal of unreacted substances, decolorization treatment, It can be obtained by deodorizing treatment.
  • the pentaerythritol benzoate ester represented by the general formula (1) and the pentaerythritol 2-ethylhexanoate tetraester are used in combination.
  • the acid ester is all pentaerythritol
  • glycol ester a 20 to 72 weight 0/0, is preferably 30 to 60 weight 0/0. If the ratio of the benzoate ester of pentaerythritol is too small, it will break easily, and if it is too much, the usability will be impaired.
  • the amount of pentaerythritol full ester more preferably preferably fixture 10 to 80 weight 0/0 30 to 60% by weight relative to the cosmetic. If the blending amount is less than 10% by mass, the characteristics of high gloss are impaired. If the blending amount exceeds 80% by mass, the properties (color and moldability) of the lipstick are impaired.
  • the IOB as a whole of the oil containing the pentaerythritol full ester is 0.3 or more.
  • IOB Inorganic Organic Balance
  • Satoshi Fujita Akira Fujita, Masami Akatsuka, Systematic Organic Qualitative Analysis (mixture)) 1974 , Published by Kyoritsu Publishing. It represents the polarity of the organic compound. The higher the value, the more polar the water becomes ⁇ .
  • the oil used in the present invention includes hydrocarbon oils such as squalene, liquid paraffin, and cerine, myristic acid, palmitic acid, stearic acid, 12-hydroxystearic acid, and behenine.
  • Higher fatty acids such as acids, higher alcohols such as cetyl alcohol, stearyl alcohol, oleyl alcohol, batyl alcohol, cetyl 2-ethyl hexanoate, 2-ethyl hexyl palmitate, 2-octyldodecyl myristate, neopentyl glycol 2-Ethylhexanoate, glyceryl trioctanoate, glyceryl triisostearate, glyceryl diisostearate, isopropyl myristate, myristyl myristate, glyceryl trioleate, olive oil, avocado oil, jojoba oil, castor oil Oil, safflower oil, coconut oil, macadamia nut oil, mink oil, lanolin, liquid lanolin, lanolin acetate, castor oil and other oils, dimethylpolysiloxane, methylphenol polysiloxane, highly polymerized gum dimethylpol
  • the amount of the oil containing pentaerythritol full ester is preferably in the range of 10 to 80% by mass.
  • Examples of the wax used in the present invention include carnapa wax, candelilla wax, beeswax, mole, ceresin wax, microcrystalline wax, and solid paraffin wax.
  • polyethylene wax alone from the viewpoint of moldability, it is also preferable to use polyethylene wax alone.
  • the stick-like cosmetic of the present invention is used in the usual cosmetics and pharmaceutical fields within the qualitative and quantitative ranges that do not impair the effects of the present invention, if necessary.
  • Other components can be blended, and examples of the humectant include polyhydric alcohol humectants such as glycerin, propylene glycol, and 1,3 butylene glycol.
  • emulsifiers various emulsifiers, surfactants, thickeners, gelling agents, metal sarcophagus, water-soluble polymers, oil-soluble polymers, drugs, antioxidants, pigments, dyes, pearl agents, lame agents, Organic, inorganic powders, fragrances, etc. can be blended.
  • the stick-shaped cosmetic of the present invention is produced by heating and stirring and mixing the above-mentioned blending components including the essential components, followed by deaeration, filling into a container, and cooling.
  • the dosage form of the cosmetic of the present invention is arbitrary, and can be, for example, a stick, pencil, paste or liquid, and a wZo emulsification system containing water and a humectant is also possible.
  • the sticky cosmetic of the present invention can be applied to general cosmetics such as lipstick cosmetics, eye shadow cosmetics, and hair cosmetics, and particularly sticks, pencils, etc. placed in a feeding container.
  • general cosmetics such as lipstick cosmetics, eye shadow cosmetics, and hair cosmetics, and particularly sticks, pencils, etc. placed in a feeding container.
  • cosmetics Particularly preferred are lipstick cosmetics, in this case other than lipstick Also, it can be applied to lip daros, lip balm, etc. that do not contain coloring materials.
  • the unit of the blending amount is mass%.
  • Each formulation component was heated to 100 ° C, stirred, mixed, degassed, filled into a lipstick mold, and evaluated for moldability when cooled to 5 ° C according to the following criteria.
  • Each formulation component shown in Table 1 below was heated to 100 ° C, stirred, mixed and degassed, then filled into a lipstick container and cooled to 5 ° C to obtain a lipstick.
  • Tetra-2-ethylhexanoic acid pentaerythritol ester (in the table, tetraethylhexanoic acid pentaerythritol ester) is the same as that described in Patent Document 3 above.
  • Comparative Example 1 and Comparative Example 2 in which the compounding amount of the wax was less than 5% by mass. Has poor moldability. In contrast, the lipstick cosmetics of Examples 1 to 4 and 9 were all moldable. Also, as in Example 4, when the amount of wax is 13% by mass, the gloss becomes slightly inferior.
  • Example 5 Comparative Examples 3 to 4 (examination of lipstick cosmetics and IOB)
  • Each formulation component shown in Table 2 below was heated to 100 ° C, stirred, mixed and degassed, then filled into a lipstick container and cooled to 5 ° C to obtain a lipstick.
  • Each formulation component shown in Table 3 below was heated to 100 ° C, stirred, mixed and degassed, then filled into a lipstick container and cooled to 5 ° C to obtain a lipstick.
  • the obtained lipstick cosmetics were evaluated in terms of moldability, gloss, smoothness, and whether or not they were broken during use. The results are also shown in Table 3 below.
  • the lipstick cosmetics of Examples 2, 6, 7, and 10 had a ratio of pentaerythritol benzoate in the total pentaerythritol full ester of 20 to 72% by mass. Although it is satisfactory in terms of smoothness and smoothness, the ratio of pentaerythritol benzoate is 0% by mass and 10% by mass in Comparative Example 5 and Comparative Example 6, and the pentaerythritol benzoate immediately breaks when used. It can be seen that Comparative Example 7 having a ratio of 92% by mass is inferior in smoothness.
  • Examples 1, 11, 12 (examination of lipstick cosmetic and wax type)
  • Each formulation component shown in Table 4 below was heated to 100 ° C, stirred, mixed and degassed, then filled into a lipstick container and cooled to 5 ° C to obtain a lipstick.

Abstract

La présente invention concerne un bâton cosmétique caractérisé en ce que : (1) il contient des composants gras comprenant une cire et des esters complets de pentaérythritol ; (2) le rapport inorganique/organique des composants gras totaux étant de 0,3 ou plus ; (3) les esters complets de pentaérythritol comprennent spécifiquement le benzoate de pentaérythritol et le tétra(2-éthylhexanoate) de pentaérythritol ; (4) la teneur en benzoate de pentaérythritol s'élève de 20 à 72 % en masse sur la base des esters complets de pentaérythritol totaux ; et (5) il contient de 5 à 13 % en masse de cire. La présente invention concerne un bâton cosmétique qui peut être aisément appliqué avec une applicabilité élevée en application, ne présente pas d'adhérence, ne subit pas de changement d'arôme au cours du temps, maintient un excellent éclat sur la peau et a un effet hydratant favorable.
PCT/JP2006/326005 2005-12-29 2006-12-27 Baton cosmetique WO2007074851A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007551999A JPWO2007074851A1 (ja) 2005-12-29 2006-12-27 スティック状化粧料

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005-380576 2005-12-29
JP2005380576 2005-12-29

Publications (1)

Publication Number Publication Date
WO2007074851A1 true WO2007074851A1 (fr) 2007-07-05

Family

ID=38218072

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2006/326005 WO2007074851A1 (fr) 2005-12-29 2006-12-27 Baton cosmetique

Country Status (3)

Country Link
JP (1) JPWO2007074851A1 (fr)
TW (1) TW200727915A (fr)
WO (1) WO2007074851A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009007359A (ja) * 2007-06-21 2009-01-15 L'oreal Sa ポリエステルと分枝鎖炭化水素化合物とを含む化粧料組成物
JP2009269880A (ja) * 2008-05-09 2009-11-19 Rohto Pharmaceut Co Ltd 棒状化粧料及び棒状化粧品
JP4772157B1 (ja) * 2010-07-15 2011-09-14 株式会社 資生堂 唇用化粧料

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08157323A (ja) * 1994-11-30 1996-06-18 Kose Corp 油性化粧料
JPH1045552A (ja) * 1996-08-02 1998-02-17 Shiseido Co Ltd 化粧料
JP2004107355A (ja) * 2003-10-20 2004-04-08 Kokyu Alcohol Kogyo Co Ltd 油性固形化粧料
JP2004339126A (ja) * 2003-05-14 2004-12-02 Kose Corp 化粧料
JP2004339128A (ja) * 2003-05-14 2004-12-02 Kose Corp 化粧料
JP2005145871A (ja) * 2003-11-14 2005-06-09 Shiseido Co Ltd 化粧料
JP2006131563A (ja) * 2004-11-08 2006-05-25 Shiseido Co Ltd 化粧料
JP2006265203A (ja) * 2005-03-25 2006-10-05 Shiseido Co Ltd 化粧料

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08157323A (ja) * 1994-11-30 1996-06-18 Kose Corp 油性化粧料
JPH1045552A (ja) * 1996-08-02 1998-02-17 Shiseido Co Ltd 化粧料
JP2004339126A (ja) * 2003-05-14 2004-12-02 Kose Corp 化粧料
JP2004339128A (ja) * 2003-05-14 2004-12-02 Kose Corp 化粧料
JP2004107355A (ja) * 2003-10-20 2004-04-08 Kokyu Alcohol Kogyo Co Ltd 油性固形化粧料
JP2005145871A (ja) * 2003-11-14 2005-06-09 Shiseido Co Ltd 化粧料
JP2006131563A (ja) * 2004-11-08 2006-05-25 Shiseido Co Ltd 化粧料
JP2006265203A (ja) * 2005-03-25 2006-10-05 Shiseido Co Ltd 化粧料

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009007359A (ja) * 2007-06-21 2009-01-15 L'oreal Sa ポリエステルと分枝鎖炭化水素化合物とを含む化粧料組成物
JP2009269880A (ja) * 2008-05-09 2009-11-19 Rohto Pharmaceut Co Ltd 棒状化粧料及び棒状化粧品
JP4772157B1 (ja) * 2010-07-15 2011-09-14 株式会社 資生堂 唇用化粧料

Also Published As

Publication number Publication date
TW200727915A (en) 2007-08-01
JPWO2007074851A1 (ja) 2009-06-04

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